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PROCEEDINGS 


or  THB 


AMERICAN   ACADEMY 


or 


ARTS  AND  SCIENCES. 


Vol.  XLV. 


FROM  MAY  1909,  TO  MAY  1910. 


BOSTON: 

PUBLISHED   BY   THE   ACADEMY. 

1910. 


Digitized  byLaOOQlC 


John  Wiubom  amd  Som,  Cambbidob,  U.S.A. 


Digitized  by  VjOOQIC 


CONTENTS. 


•\ 


Page 
I.    Friction  in  Oases  cU  Low  Pressure,   Bt  J.  L.  Hooo 1 

II.     The  Quantitaiive  Determination  of  Antimony  by  the  GtUzeit  Method, 

Bt  C.  R.  Sangeb  and  £.  R.  Riegel 19 

III.  The  Equivalent  Circuits  of  Composite  Lines  in  the  Steady  State,   Bt 

A.  E.  KSNNELLT 29 

IV.  Ilepi  ^«J<rewf.    A  Study  of  the  Conception  of  Nature  among  the 

Pre^ocratics,    Bt  W.  A.  Heidel 77 

V.  A  Revision  of  the  Atomic  Weight  of  Phosphorus.  First  Paper.  — 
The  Analysis  of  Silver  Phosphate,  Bt  G.  P.  Baxter  and 
G.  Jones     135 

VI.    The  Reactions  of  Amphibians  to  Light.   Bt  A.  S.  Peabse  .   ...     156 

VII.    Average  Chemical  Compositions  of  Igneous-Rock  Types.   Bt  R.  A. 

Dalt 209 

VIII.    On  the  A  pplicabUity  of  the  Law  of  Corresponding  States  to  the  Joule- 
Thomson  Effect  in  Water  and  Carbon  Dioxide.   Bt  H.  N.  Davis    241 

IX.    Notes  on  Certain  Thermal  Properties  of  Steam,   Bt  H.  N.  Davis  .     265 

X.     The  Spectrum  of  a  Carbon  Compound  in  the  Region  of  Extremely 

ShoH  Wave-Lengths,   Bt  T.  Ltm an 313 

XI.    Experiments  on  the  Electrical  Oscillations  of  a  Hertz  Rectilinear 

Oscillator,    Bt  G.  W.  Fierce 323 

\l  XII.    The  Conception  of  the  Derivative  of  a  Scalar  Point  Function  with 

1, 


Respect  to  Another  Similar  Function,   Bt  B.  O.  Peircb     .    .    .     337 


Digitized  by 


Goo 


J^ 


IV  CONTENTS. 

Paob 
XIII.     The  Effect  of  Leakage  cU  the  Edges  upon  the  Temperatures  loUhin  a 

Homogeneous  Lamina  through  which  Heat  is  being  Conducted, 

By  B.  O.  Pbibcb 363 

XIV.    On  Evaporation  from  the  Surface  of  a  Solid  Sphere,    By  H.  W. 

MoBSE    , 361 

XV.    Some  Minute  Phenomena  of  Electrolysis,   ByH.W.  Mobsb     .   .^369 

XVI.    Air  Resistance  to  Falling  Inch  Spheres,   By  E.  H.  Hall    ....     377 

XVII.  (I.)  A  preliminary  Synopsis  of  the  Genus  Echeandia.    By  C.  A. 

Weatherby;  (II.)  SpermatophyteSf  new  or  reclassified^  chiefly 
RubiaceaeandOentianaceae,  By  B.  L.  Robinson;  (III.)  Amer' 
ican  Forms  of  Lycopodium  complanatum.  By  C.  A. 
Weathebby;  (IV.)  New andlittle  known  Mexican  Plants jChufiy 
Lainatae,  By  L.  M.  Fbrnald;  (V.)  Mexican  Phanerogams,  — 
Notes  and  new  species,  Bt  C.  A.  Weatherby 385 

XVIII .  (LIII  .)Onthe  Equilibrium  of  the  System  consisting  of  Lime,  Carbon, 

Calcium  Carbide  and  Carbon  Monoxide,  By  M.  D.  Thompson  .     429 

XIX.    Discharges  of  Electricity  through  Hydrogen,  By  J.  Trowbridge    .     453 

XX.    Buddhaghosa's  Dhammapada  Commentary,    By  £.  W.  Burlin- 

GAMB 465 

XXI.    Records  OP  Meetings 651 

OpPICERS  AND  COMMITTBBSPOR  1910-11 577 

List  OP  Fellows  AND  Foreign  Honorary  Members 579 

Statutes  AND  Standing  Votes 591 

RuMPORD  Prbmixtm 602 

Index 603 


Digitized  by  VjOOQIC 


Proceedings  of  the  American  Academy  of  Arts  and  Sciences. 
Vol.  XLV.  No.  1.  — August,  1909. 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,   HARVARD  UNIVERSITY. 


FRICTION  IN  GAS^S  AT  LOW  PRESSURES. 


By  J.  L.  IIoGQ. 


Digitized  by  VjOOQIC 


Digitized  by  VjOOQIC 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,   HARVARD  UNIVERSITY. 

FRICTION  IN  GASES  AT  LOW  PRESSURES. 
Bt  J.  L.  HooG. 

Preaented  by  John  Trowbridge  June  29, 1909 ;  received  June  29, 1909. 

Under  the  title  "  Friction  and  Force  due  to  Transpiration  as  de- 
pendent on  Pressure  in  Grases,"  there  was  published  ^  some  time  ago 
an  account  of  some  experiments  made  to  determine  the  relation  be- 
tween the  friction  of  a  gas  and  the  pressure  in  it,  and  also  the  relation 
between  the  force  exerted  by  a  lamp  on  a  mica  vane,  blackened  on  the 
&ice  which  is  turned  towards  the  lamp,  and  the  mean  pressure  in  the 
gas  in  which  the  vane  is  placed.  The  three-fold  purpose  of  the  inves- 
tigation was  pointed  out  there,  viz. : 

First,  to  investigate  the  relation  between  friction  and  pressure  where 
the  pressures  were  so  small  that  "slip  "  is  appreciable;  second,  to  de- 
termine the  relation  of  transpiration  force  in  the  special  form  of  appa- 
ratus described  there ;  ^  and,  third,  to  make  use,  if  possible,  of  these  two 
relations  to  test  the  validity  of  the  McLeod  gauge  measurements  of 
pressure,  and,  if  these  measurements  should  prove  unreliable,  to  make 
use  of  one  of  the  relations  named  above  to  measure  gas  pressure. 

There  has  been  much  delay  in  carrying  out  the  investigation  with 
the  apparatus  improved  in  the  manner  indicated  in  the  closing  para- 
graphs of  that  paper,  but  now  some  results  have  been  obtained  in  so 
far  as  the  friction  problem  is  concerned. 

As  was  pointed  out  in  the  paper  mentioned,  the  investigation  was 
defective  in  two  respects.  It  was  found  that,  in  spite  of  the  care  which 
was  taken  to  exclude  mercury  vapor  from  the  apparatus,  some  of  this 
vapor  was  undoubtedly  present  This  no  doubt  was  due  to  the  fact 
that  the  whole  apparatus  had  to  be  maintained  at  a  high  temperature 
for  long  periods  to  insure  dr3ring,  and  thus  the  presence  of  the  least 
speck  of  liquid  mercury  would  cause,  when  evaporation  took  place,  the 
diffusion  of  comparatively  large  quantities  of  the  vapor  through  the 

^  Proc.  Am.  Acad.,  42,  6  (1906).  *  See  p.  129  of  that  paper. 


Digitized  by 


GooqI 


OQ^ 


4  PKOCEEDINGS  OF  THE   AMERICAN   ACADEMY. 

apparatus.  Again,  the  logarithmic  decrement  due  to  the  friction  in 
the  suspending  fibre  was  not  determined  directly  by  experiment,  and 
in  the  discussion  of  the  results  obtained  its  value  was  calculated. 

The  details  of  the  method  since  used  to  exclude  the  mercury  vapor 
and  to  determine  the  decrement  due  to  friction  in  the  fibre  will  ap- 
pear later.  Meanwhile  a  summary  of  what  has  been  accomplished  is 
given  here. 

Firsts  the  decrement  due  to  the  friction  in  the  suspending  fibre  of 
the  viscosity  apparatus  has  been  determined  experimentally. 

Second^  mercury  vapor  has  been  excluded  to  such  a  degree  that,  even 
when  the  whole  appara^s,  in  which  the  presence  of  the  vapor  would 
be  objectionable,  was  kept  at  a  temperature  of  150°  C,  the  mercury 
lines  were  absent  from  tbe  spectrum  of  the  gas  enclosed. 

Third,  the  value  of  the  decrement  has  been  obtained  for  hydrogen 
over  a  range  of  pressures  extending  from  atmospheric  pressure  to 
0.000016  mm.  an  indicated  by  the  McLeod  gauge. 

Fowrth,  an  equation  relating  pressure  to  decrement  has  been  ob- 
tained which  applies  well  at  all  pressures  below  0.1  mm.  as  far  as  pres- 
sures have  been  measured.  The  equation,  above  mentioned,  is  of  the 
form  of  Sutherland's  equation  given  tentatively  in  the  former  paper. 
It  is 


(z^-O-^ 


In  this  equation  k  and  c  are  constants  to  be  determined  from  the  ob- 
servations ;  /  is  the  decrement  due  to  whatever  friction  there  is  in  the 
gas  under  examination  and  to  the  friction  in  the  fibre  ;  p  is  pressure ; 
in  is  the  decrement  due  to  the  friction  in  the  fibre.  Its  value  has  been 
measured  directly.  The  significance  of  the  two  slightly  difiTering  values 
of  fs  namely,  ft  =  0.000020  and  fi  =  0.000022,  which  are  found  in  the 
following  table,  will  appear  later  when  the  measurement  is  discussed  in 
detail.  The  first  column  of  the  table  contains  a  series  of  values  of 
the  decrement  for  hydrogen,  each  of  which  corresponds  to  a  definite 
pressure  in  the  gas.  The  various  values  of  the  pressure  are  given 
in  the  second  column.  The  first  three  of  them  were  obtained  from 
a  manometer,  lliose  which  are  marked  thus,*,  were  obtained  firom 
measurements  made  with  the  McLeod  gauge,  while  the  others  were 
obtained  from  a  curve  plotted  from  the  directly  observed  values  of  the 
decrement  and  pressure.  From  two  values  of  /?,  the  corresponding 
values  of  /,  and  the  value  of  /*,  there  are  obtained  two  equations  for 
the  determination  of  the  constants  k  and  c  in  the  above  equation. 
These  determined,  it  is  clear  that  from  any  value  of  /,  within  the  range 


Digitized  by  LjOOQIC 


HOGG.  —  FRICTION    IN    GASES   AT    LOW    PRESSURES. 


TABLE   I. 
Htdrooen. 


Log.  Dec. 

p  (obscived). 

p  (calculated) 
ti  -  0.000020. 

p  (calculated) 
ta  =  0.000022. 

0.07942 

760.0 

0.07937 

435.0 

0.07927 

103.0 

0.07768* 

8.89* 

0.06902* 

1.24* 

0.05123* 

0.410* 

0.02861* 

0.105* 

0.109 

0.109 

0.01140 

0.0300 

0.0302 

0.0302 

0.01056 

0.0275 

0.0276 

0.0275 

0.00936* 

0.0239* 

0.00887 

0.0225 

0.0225 

0.0225 

0.00710 

0.0175 

0.0174 

0.0174 

0.00620 

0.0150 

0.00525 

0.0125 

0.0125 

0.0125 

0.00434* 

0.0102* 

0.0102 

0.0102 

0.00426 

0.0100 

0.00998 

0.00998 

0.00306* 

0.00704* 

0.00702 

0.00702 

0.00220 

0.00500 

0.00497 

0.00496 

0.00112 

0.00250 

0.00247 

0.00246 

0.000459* 

0.00098* 

0.00097 

0.00097 

0.000215* 

0.00042* 

0.00043 

0.00043 

0.000029* 

0.000016* 

0.000020 

0.000015 

Digitized  by  LjOOQIC 


b  PROCEEDINGS   OF  THE   AMERICAN   ACADEMY. 

indicated  above,  the  correspondiDg  value  of />  can  be  obtained  from  the 
formula  by  a  simple  calculation.  The  numbers  thus  obtained  for  the 
various  values  of  /  are  given  in  the  third  and  fourth  columns. 

It  would,  therefore,  seem  highly  probable  that  so  far  as  hydrogen  is 
concerned  the  McLeod  gauge  can  be  relied  upon  for  pressures  as  low 
as  the  lowest  used,  and  which  are  recorded  in  Table  I ;  and  that,  in 
the  case  of  hydrogen,  the  measurement  of  friction  can  be  used  as  a 
convenient  and  accurate  method  of  measuring  pressure,  provided  care 
is  taken  to  exclude  mercury  vapor.  This  matter  will  be  discussed  at 
length  later. 

The  details  of  the  methods  used  to  overcome  the  difficulties  named 
above  follow: 

Measurement  of  Decrement  due  to  the  Friction  in  the  Fibre. 

Referring  to  Figure  1  it  will  be  seen  that  the  tube  C  is  inserted  in 
such  a  position  that  nothing  can  pass  to  the  viscosity  apparatus  from  the 
McLeod  gauge,  B,  or  from  the  pump,  which  is  connected  to  D,  without 
passing  through  it.  This  tube,  C,  therefore,  replaces  the  tubes  of  sul- 
phur and  silver  whose  purpose  was  explained  in  the  earlier  paper.  0 
is  filled  with  granular  charcoal,  and  is  so  arranged  that  either  a  cylin- 
drical electrical  heater  or  a  long  Dewar  vessel  can  enclose  it.  When 
C  had  been  placed  in  position  and  sealed  in  place,  the  whole  apparatus 
was  exhausted  through  D  by  means  of  the  mechanical  pump,  and  then 
dry  air  was  allowed  to  pass  in  through  an  opening  placed  near  the 
pump.  The  exhaustion  was  again  performed  and  the  admission  of  dry 
air  repeated.  This  exhaustion  and  admission  of  air  were  carried  out 
alternately  many  times  for  the  purpose  of  removing  the  comparatively 
large  quantities  of  moisture  which  had  been  formed  in  the  vessel  dur- 
ing the  process  of  making  the  various  joints  in  the  construction  of  the 
apparatus.  When  it  was  certain  that  the  whole  apparatus  had  been 
made  fitirly  dry,  the  cylindrical  electric  heater  was  placed  about  the 
tube  C,  and  while  the  exhaustion  proceeded  the  tube  was  raised  to  a 
temperature  of  about  150°  C,  to  hasten  the  removal  of  the  gas  present 
in  large  quantities  in  the  pores  of  the  charcoal  at  atmospheric  pres- 
sure, and  which  separates  frx)m  the  charcoal  rather  slowly  under  re- 
duced pressure  if  the  temperature  is  kept  low.  When  the  mercury 
pump  had  been  used  to  secure  a  &irly  high  vacuum  the  other  parts  of 
the  apparatus,  viz.,  the  McLeod  gauge,  the  viscosity  apparatus,  and 
the  connecting  tubes  were  heated  to  about  150°  C.,  for  the  purpose  of 
removing  from  the  glass  the  occluded  gases.  After  the  pumping  had 
proceeded  for  some  time  under  these  conditions,  the  heater  was  re- 


Digitized  by  LjOOQIC 


HOGG.  —  FRICTION    IN    GASES    AT    LOW    PRESSURES. 


Digitized  by  VjOOQIC 


8  PROCEEDINGS  OF  THE  AMERICAN   ACADEMY. 

moved  from  C  and  the  Dewar  vessel  containing  liquid  air  ^  was  substi- 
tuted for  it,  and  the  other  part  of  the  apparatus  was  allowed  to  cool 
down.  The  charcoal  was  allowed  to  absorb  what  it  would  at  the  tem- 
perature of  the  liquid  air.  Altogether  the  liquid  air  was  kept  sur- 
rounding the  charcoal  for  about  eighty  hours,  and  from  time  to  time 
during  this  interval  a  measurement  of  the  decrement,  /,  was  made.  At 
first  the  diminution  in  the  value  of  the  decrement  was  fairly  rapid,  but 
after  the  first  day  the  change  was  very  slow.  This,  no  doubt,  was  due 
in  part  to  the  slow  passage  of  the  gas  towards  the  charcoal  through 
the  somewhat  extended  form  of  the  apparatus.  It  was,  also,  probably 
due  to  the  &ct,  which  was  noted  later  in  the  investigation,  that  at  a 
given  stage  of  exhaustion  the  raising  of  the  free  surface  of  the  liquid 
air  in  the  Dewar  vessel  surrounding  C  invariably  produced  a  very 
appreciable  diminution  in  the  gas  pressure  in  the  apparatus,  and  the 
lowering  of  the  free  surface  as  the  evaporation  of  the  liquid  air  pro- 
ceeded resulted  in  a  distinct  rise  in  the  gas  pressure.  It  is  to  be  un- 
derstood that  the  free  surfiice  was  never  allowed  to  fall  as  low  as  the 
top  of  the  tube  C,  so  that  all  of  the  charcoal  was  always  below  the  free 
surface  of  the  liquid  air. 

The  following  results  show  how  the  decrement  changed  with  the 
time  in  the  final  forty-eight  hours  : 

May  29,  12  M.  to  2: 53  A.  M.  Decrement  0.000051 

7;  15  p.  M.  to  8:  58  0.000037 

10:  53  P.  M.  to  1:  36  A.  M.  (May  30)  0.000031 

May  30,  1 :  36  a.  M.  to  4: 48  0.000028 

11:  11  a.  m.  to  2:06  P.  M.  0.000037* 

2:  06  P.  M.  to  5:  27  0.000024* 

5:27  P.  M.  to  8:  21  0.000028* 

8:21  P.  M.  to  11:49  0.000022 

The  smallest  value  of  the  decrement  obtained  was  0.000022,  and  this 
could  be  measured  moderately  well.  Its  error  cannot,  I  think,  be  as 
much  as  ten  per  cent.  Of  course,  it  is  clear  that  the  true  value  of  the 
decrement  due  to  the  friction  in  the  fibre  is  somewhat  less  than  this, 
for  there  is  still,  doubtless,  some  gas  left  to  offer  resistance  to  the 
moving  disk,  so  that  the  number  to  be  used  for  /ia  in  the  above  equa- 
tion should  be  somewhat  smaller  than  ().0(K)022.     I  have  ventured  to 

*  The  liquid  air  used  in  this  investigation  was  obtained  at  the  Chemical 
Laboratory,  Harvard  University. 

♦  These  were  taken  in  the  afternoon  when  there  is  considerable  jarring  of 
the  apparatus  and  are  probably  not  so  accurate  as  the  others. 


Digitized  by  LjOOQIC 


HOGG.  —  FRICTION   IN   GASES   AT   LOW    PRESSURES.  9 

make  use  of  the  yalae  0.000020  as  the  true  value  to  which  the  decre- 
ment will  approach  as  the  exhaustion  is  pushed  higher  and  higher.  It 
will  be  seen  from  Table  I  that  the  calculations  are  carried  through  not 
only  with  this  value,  but  also  with  the  actually  measured  value 
0.000022.  This  is  done  simply  to  show  what  effect  such  a  change  in 
ihe  value  of  fi  has  on  the  series  of  results  obtained. 

It  may  be  of  interest  to  state  that,  at  the  stage  of  exhaustion  when 
ft  =  0.000022  was  obtained,  the  McLeod  gauge  indicated  a  pressure 
certainly  less  than  0.000001mm.  It  is,  to  be  sure,  of  little  value  to  give 
the  measurement  of  a  pressure  by  the  gauge  where  a  column  of  mercury 
a  fraction  of  a  millimeter  high  requires  to  be  measured,  and  especially 
is  tins  true  where  the  tube  containing  the  mercury  has  been  heated 
and  cooled  repeatedly.  The  mercury  has  a  habit  of  sticking  to  the 
glass  to  such  an  extent  that  pressure  measurements  under  the  condi- 
tions mentioned  are  surely  not  reliable.  The  value  of  the  pressure 
given  above,  then,  only  indicates  the  order  of  magnitude  of  the  pres- 
sure. Though  the  &ctor  of  the  gauge  used  was  95813,  yet  it  was 
quite  inadequate  to  measure  the  pressure  of  the  gas  in  ^he  vessel 

Removal  op  Water  Vapor  and  Mercury  Vapor  from  the 
Hydrogen  in  the  Viscosity  Apparatus. 

For  this  purpose  it  was  necessary  to  make  arrangements  by  which 
no  vapor  should  be  carried  into  the  apparatus  with  the  entering  gas, 
and  also  all  the  vapor  which  was  already  in  the  apparatus  might  be 
taken  out.  The  following  arrangement  was  finally  adopted,  Figure  2. 
E  is  a  U-tube  of  small  bore,  and  bent  so  that  it  may  enter  the  long 
Dewar  vessel  already  mentioned.  For  reasons  which  will  appear  later 
it  was  found  necessary  for  the  remainder  of  the  investigation  to  replace 
the  tube  C,  Figure  1,  by  this  tube  K  F  is  a  tube  leading  from  the 
gas  generator.  It  enters  G,  which  is  similar  to  G  of  Figure  1.  It  can 
be  surrounded  by  a  heater  or  a  Dewar  vessel  as  circumstances  may  re- 
quire. A  connecting  tube  leads  from  G  to  a  point  on  the  tube  H, 
which  connects  E  to  the  viscosity  apparatus  A,  Figure  1.  I  leads  to 
the  pump  and  McLeod  gauge.  Anything  which  proceeds  from  the 
pump  or  McLeod  gauge  towards  the  viscosity  apparatus  must  pass 
through  E.  Moreover,  the  gas  entering  from  tiie  generator  will,  with 
the  given  arrangement,  retard  the  diffusion  of  mercury  vapor  from  the 
pump  and  gauge  towards  the  viscosity  apparatus.  If  there  is  no  vapor 
entering  with  the  gas,  there  can  be  none  entering  the  viscosity  appara- 
tus without  passing  through  E,  and,  since  throughout  the  experiment 
tliis  tube  was  kept  surrounded  by  the  liquid  air,  the  pressure  of  the 


Digitized  by 


Goo^e 


10 


PROCEEDINGS   OF   THE   AMERICAN   ACADEMY. 


vapor  due  to  diffasion  from  the  mercury  in  the  pump  or  gauge  could 
never  exceed  the  vapor  pressure  of  mercury  at  the  temperature  of  the 
liquid  air.  The  tube  G,  when  surrounded  with  the  liquid  air,  was  suf- 
ficient safeguard  against  the  entrance  of  water  vapor  with  the  gas. 

The  method  of  removing  all  water  vapor  and  mercury  vapor  already 
in  the  apparatus  beyond  the  tube  E  was  that  of  repeated  exhaustion 
_  and  filling  with  the  gas  to  be  exper- 

imented with,  the  whole  apparatus 
meanwhile  being  kept  at  a  high 
temperature.* 

At  the  first  exhaustion,  when  the 
pressure  had  been  reduced  to  a 
few  centimeters  of  mercury,  the  tube 
G  was  surrounded  by  the  electric 
heater,  and  the  heat  was  applied 
to  the  oven  in  which  the  viscosity 
apparatus  is  placed.  Practically  the 
whole  apparatus,  except  the  gas 
generator,  was  kept  hot  while  the 
pumping  proceeded.  After  a  fsdr 
vacuum  was  reached  the  pump  was 
stopped  and  the  hydrogen  firom  the 
generator  was  allowed  to  enter  very 
slowly,  passing  first  over  phosphoric 
pentoxide,  and  then  over  spongy 
platinum,  heated  in  a  combustion 
tube,  before  entering  the  tube  G.  This  filling  process  was  followed 
by  another  exhaustion  under  the  same  conditions.  After  the  appara- 
tus had  been  exhausted  and  filled  a  number  of  times  in  this  way, 
when  it  seemed  certain  that  the  apparatus  and  the  pores  of  the  char- 
coal were  filled  with  fitirly  pure  hydrogen,  the  heater  was  removed 
from  G,  and  the  vessel  containing  the  liquid  air  substituted  for  it. 
The  same  process  of  alternately  exhausting  and  filling  was  continued, 
great  care  being  taken  in  filling  to  allow  the  hydrogen  to  pass  very 
slowly  so  that  the  drying  process  might  be  completa  Keeping  the 
apparatus  at  a  temperature  of  about  150®  C.  served  to  promote  the  evap- 
oration of  the  mercury,  which  in  all  probability  adhered  to  the  inner 
glass  surfigu>es.  Comparatively  large  quantities  of  pure  dry  hydrogen 
were  allowed  to  pass  into  the  vessel  and  were  then  taken  out.  Each 
exhaustion  would  assuredly  sweep  out  some  vapor  if  it  was  present. 


I 

B  O 

! 


Fia.8 


*  The  suspended  disk  was,  of  course,  lowered  before  this  operation  began. 


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HOGG.  —  FRICTION   IN    GASES    AT    LOW    PRESSURES.  11 

It  would  DAturally  collect  at  R  We  shall  have  evidence  as  to  this 
later.  After  some  days  of  incesseoit  work  ike  expected  result  was  at- 
tained, as  the  character  of  the  spectrum,  obtained  from  the  spectrum 
tube,  S,  showed.  Even  when  the  temperature  of  the  viscosity  appara- 
tus was  150^0.  the  mercury  lines  were  absent  The  apparatus  was 
then  very  slowly  filled  with  hydrogen.  The  glass  tube  connecting  G 
and  H  was  tiien  sealed  off  so  that  there  were  left  no  stop-cock  joints 
to  give  trouble  by  leaking. 

The  Dewar  vessel  was  removed  fix)m  G,  but  the  one  surrounding  E 
still  remained.  After  the  apparatus  had  cooled  down  to  room  temper- 
ature the  disk  of  the  viscosity  apparatus  was  raised  and  adjusted  as 
described  in  the  former  paper.^ 

Method  op  Experiment. 

The  investigation  of  the  relation  of  friction  to  pressure  consists  in 
measuring,  for  a  given  density  of  the  gas,  the  logarithmic  decrement 
of  the  suspended  disk  which  is  made  to  oscillate  as  a  torsion  pendulum 
between  die  two  fixed  plates  of  the  apparatus.®  The  method  of  pro- 
cedure was  to  measure  the  gas  pressure  in  the  apparatus  by  means  of 
a  manometer  when  the  pressure  was  large,  and  by  the  McLeod  gauge 
when  it  was  small,  and  then  to  set  the  disk  of  the  apparatus  swinging 
and  measure  the  decrement  Since  the  latter  can  be  shown  to  be  pro- 
portional to  the  resistance  experienced  by  the  disk,  one  gets  data  for 
Uie  determination  of  the  relation  between  friction  and  pressure. 

It  may  be  of  interest  to  state  here  that  in  the  first  arrangement  of 
Uie  apparatus  for  the  determination  of  the  above  relation  instead  of 
the  simple  bent  tube  E,  a  tube  containing  charcoal,  similar  to  the  tube 
C,  was  used.  With  this  arrangement  the  mercury  vapor  was  removed, 
but  when  observations  on  the  decrement  at  different  pressures  were  un- 
dertaken a  difficulty  presented  itself.  Although  all  of  the  tube  contain- 
ing the  charcoal  was  immersed  in  the  liquid  air,  the  sur&ce  of  which 
was  always  several  inches  above  the  top  of  the  charcoal,  yet  it  was 
found  impossible  to  obtain  a  steady  condition.  As  the  evaporation  of 
the  liquid  air  proceeded,  sufficient  gas  was  given  off  from  the  charcoal 
to  produce  a  large  increase  in  pressure ;  as  much  as  thirty  per  cent  was 
observed.  When  a  fresh  supply  of  the  liquid  air  was  added  the  pres- 
sure diminished  again.  The  difficulty  became  more  serious  as  the 
pressure  at  which  the  observations  were  made  became  smaller. 

The  phenomenon  was  probably  due  to  the  fact  that  ihe  fresh  supply 
of  liquid  air  was  richer  in  nitrogen  than  it  was  after  the  process  of 

*  See  pp.  133,  1.34.  •  See  pp.  124,  125  of  former  paper. 


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12      ^  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

boiling  bad  proceeded  for  some  bours.  Tbe  nitrogen  is  tbe  more  vola- 
tile, and  so  tbe  boiling  will  proceed  more  vigorously  just  after  a  fresb 
supply  of  air  bas  been  added  tban  at  any  otber  time.  Consequently 
tbe  temperature  of  tbe  boiling  liquid  will  be  lower  at  first  tban  it  is 
later,  and  tbe  cbarcoal  will  tbus  absorb  better  at  eacb  addition  of 
liquid  air  to  tbe  Dewar  vessel.  Tbe  cbarcoal  is  necessary  for  tbe  pbe- 
nomenon,  for  wben  tbe  tube  E  was  substituting  for  tbe  tube  containing 
tbe  cbarcoal,  tbe  effect  disappeared,  oY  became  inappreciable. 

It  was  suggested  earlier  in  tbe  paper  tbat  tbere  would  be  adduced 
evidence  to  sbow  tbat  tbe  mercury  driven  out  from  tbe  apparatus  col- 
lected in  tbe  tube  K  After  tbe  measurement  of  pressure  and  decre- 
ment bad  proceeded  down  to  tbe  least  value  given  in  tbe  table,  tbe 
supply  of  liquid  air  in  tbe  Dewar  vessel  in  wbicb  E  was  placed  was  al- 
lowed to  disappear  gradually.  As  tbe  evaporation  proceeded,  it  was 
found  tbat  the  decrement  increased  mucb  more  rapidly  tban  tbe 
pressure  as  indicated  by  tbe  McLeod  gauge,  sbowing  tbat  vapor  was 
finding  its  way  into  tbe  apparatus. 

Results. 

In  tbe  first  and  second  columns  of  Table  I  are  contained  tbe  corre- 
sponding values  of  tbe  decrement  and  pressure.  Not  all  tbe  numbers 
given  in  tbese  columns  were  obtained  by  actual  measurement  Only 
tbose  wbicb  are  marked  witb  an  asterisk  were  obtained  in  tbis  way. 
Tbe  otbers  were  obtained  as  follows:  A  curve  was  plotted  using  the 
values  of  tbe  pressure  which  were  measured  as  abscissas  and  the  corre- 
sponding values  of  tbe  decrement  as  ordinates.  Tbis  curve  was  drawn 
on  such  a  scale  tbat  tbe  value  of  tbe  decrement,  corresponding  to  any 
arbitrarily  chosen  pressure,  could  be  obtained  from  tbe  curve  as  accu- 
rately as  it  could  be  measured  by  tbe  apparatus.  Tbe  unmarked  num- 
bers in  tbe  first  two  columns  were  obtained  by  choosing  arbitrarily  a 
pressure  and  reading  off  fix)m  tbe  curve  the  corresponding  value  of  tbe 
decrement    In  no  case  bas  tbis  procedure  involved  an  extrapolation. 

After  failing  to  obtain  an  anal3rtical  expression  for  tbe  relation 
between  tbe  logarithmic  decrement  and  the  pressure  wbicb  would  be 
applicable  over  tbe  whole  range  extending  from  very  small  pressures 
right  up  to  atmospheric  pressure,  it  w&s  decided  to  find,  if  possible,  an 
expression  wbicb  would  be  applicable  up  to  a  certain  pressure  within 
tbe  range  for  which  it  is  known  tbat  tbe  McLeod  gauge  measurements 
are  quite  reliable.  Rayleigh  ^  bas  shown  tbat  Boyle's  Law  holds  down 
to  0.01mm.  of  mercury,  and  Baly  and  Ramsay®  found  tbe  McLeod 

^  Phil.  Trans.,  196  (1901).  •  Pliil.  Mgg.,  38  (1894). 


Digitized  by  LjOOQIC 


HOGG.  —  FRICTION    IN   GASES    AT    LOW    PRESSURES.  13 

gauge  measurements  reliable  for  hydrogen.  Recently  Scfaeel  and 
Heuse*  have  applied  a  membrane  manometer,  devised  by  them,  to  test 
Boyle's  Law,  and  McLeod  gauge  measurements  for  air,  and  they  state 
that  they  find  both  valid  down  to  about  0.0001  mm.,  provided  proper 
care  is  taken  in  drying  the  gas. 

An  examination  of  the  results  at  pressures  less  than  0.1  mm.  showed 
that  the  equation  given  above,  viz. : 


(/^-0^=''' 


served  the  purpose  exceedingly  well,  if  the  experimentally  determined 
value  of  fx.  given  above  was  used,  and  if  the  constants  c  and  k  were 
determined  by  means  of  values  ofp  between  0.1  mm.  and  0.0 1  mm.  of 
mercury,  and  the  corresponding  values  of  /. 

Tlie  pressures  chosen  for  the  determination  of  these  constants  were 
0.0239  mm.  and  0.0150  mm.,  the  former  of  these  being  a  pressure 
actually  measured  by  the  gauge,  while  the  latter  was  chosen  arbitrarily. 
The  measurement  of  /  corresponding  to  the  former  was  0.00936,  while 
the  value  of  /  corresponding  to  the  latter  was  0.00620,  and  was  obtained 
firom  the  curve  as  described  above.  The  values  of  {he  constants  calcu- 
lated from  the  above  data  are 

c  =  0.1491 
k  =  0.0676. 

The  equation  now  takes  the  form 

/      0.0676  A         r...^. 

0- 0.000020 -0^  =  '-^''^' 

How  well  the  equation  gives  the  relatioli  existing  between  p  and  /  can 
be  seen  by  a  comparison  of  the  numbers  in  the  second  and  third  columns 
of  the  table.  A  number  in  the  third  column  is  obtained  by  choosing 
a  value  of  /  from  the  first  column,  inserting  it  in  the  equation  and 
deducing  the  value  otp,  which  is  then  placed  in  the  third  column  in  the 
same  horizontal  row  as  the  chosen  value  of  /.  It  will  be  seen  that  the 
various  numbers  in  this  column  agree  very  well  with  the  corresponding 
numbers  in  the  second  column,  except  at  the  very  lowest  pressure, 
0.000016  mm.  used,  when  the  diflference  is  about  twenty-five  per  cent. 

•  Verhandl.  d.  Deutsch.  Physikal.  Gesellsch.,  11,  1  (1909). 


Digitized  by  LjOOQIC 


14  PEOCEEDINGS   OF  THE   AMERICAN   ACADEMY. 

If  instead  of  using  the  value  0.000020  for  /ia,  we  make  use  of  0.000022, 
which  was  the  smallest  value  of  the  decrement  aotuaUy  measured,  the 
values  of  c  and  k  are 

c  =  0.1494 
k  =  0.0677 

and  the  fourth  column  gives  the  values  of  p  calculated,  in  the  way 
described,  from  the  equation  with  these  values  for  the  constants  instead 
of  those  used  in  the  preceding  case.  This  calculation  is  carried  out  to 
call  attention  to  the  magnitude  of  the  change  produced  by  a  slight 
change  in  the  value  of  the  constant,  /jl,  which  is  subject  to  some  uncer- 
tainty, as  has  been  shown.  It  will  be  seen  that  it  is  only  where  the 
decrement^  /,  is  very  small  that  the  difference  between  the  two  results 
is  appreciable.  The  smallest  value  of />  in  the  fourth  column  is  nearer 
to  tiie  corresponding  value  of  j9,  measured  by  the  McLeod  gauge ;  but 
ihe  measured  value  is  subject  to  an  inaccuracy  about  as  great  as  the 
difference  between  the  measured  and  calculated  values  of  j9. 

The  results  given  above  make  it  highly  probable  that  the  measure- 
ments of  pressure  by  the  McLeod  gauge  are  reliable  in  the  case  of  pure, 
dry  hydrogen  for  pressures  as  low  as  the  smallest  pressure  recorded 
in  the  table. 

It  is  to  be  observed  that  for  pressures  below,  say,  0.01  mm.  of 
mercury  the  friction  with  which  we  have  to  do  is  largely  external 
friction,  and  this  is  proportional  to  the  density  of  the  gas  and  the  mean 
molecular  speed.  The  friction,  and,  therefore,  the  decrement,  corre- 
sponding to  a  given  pressure  will  be  smaller  for  hydrogen  than  for, 
say,  oxygen,  or  mercury  vapor.  In  the  case  of  mercury  vapor  the 
decrement  at  a  given  low  pressure  ought  to  be  about  ten  times  as  great 
as  it  is  for  hydrogen  at  the  same  pressure,  since  the  molecular  weight 
of  mercury  is  about  one  hundred  times  that  of  hydrogen,  while  the 
mean  molecular  speed  is  about  one-tenth  as  great  as  it  is  for  hydrogen. 

To  be  sure  it  does  not  follow  that  the  decrement  of  a  mixture  of 
hydrogen  and  mercury  vapor,  in  such  proportions  that  the  partial 
pressures  of  the  two  are  the  same,  is  simply  the  sum  of  the  two  decre- 
ments obtained  when  the  gas  and  vapor  are  separate.  If  one  accepts 
the  expression  deduced  by  Meyer  ^^  for  the  external  friction  of  a  gas, 
and  applies  the  same  method  in  considering  external  friction  of  mixtures 
as  he  does  in  dealing  with  the  internal  friction  of  mixtures,  he  will  be 
able  better  to  understand  how  the  external  friction  of  a  mixture  of 


"  Kinetic  Theory  of  Gases,  p.  210  (Eng.  Trans.). 


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HOGG.  —  FRICTION   IN    GASES   AT    LOW    PRESSURES.  15 

gases  depends  apon  the  proportion  in  which  the  gases  are  mixed. 
Meyer  shows  that  the  coefficient  of  external  friction  is  given  by 

where  tn  is  the  molecular  weight  of  the  gas ;  N  is  the  number  of 
molecules  per  unit  volume ;  O  is  the  mean  molecular  speed ;  and  fi  is 
a  constant  depending  upon  the  solid  surface.  He  gives  some  experi- 
mental evidence  to  show  that  P  is  independent  of  the  gas. 

In  the  case  of  a  mixture  of  gases  where  there  are  Ni  molecules  of 
one  kind  and  N't  molecules  of  another,  in  each  unit  volume  we  have, 
if  i\r  is  the  total  number  of  molecules  in  the  unit  volume, 

and  the  mean  molecular  weight  is  given  by 

Nitrii  +  Nftnt 


m  = 


N 


where  mi  and  mt  are  the  molecular  weights  of  the  two  gases  mixed. 
Since  the  temperatures  of  the  two  gases  are  the  same, 

Therefore, 


N       mi  N 

If  Boyle's  Law  holds,  which  seems  a  fair  inference  from  the  results  given 
above,  then  we  may  write 


p       mi  p 

where  jth  and  j9s  are  the  partial  pressures  and  p  is  the  whole  pressure 
under  the  given  conditions.  If  fi  is  independent  of  the  nature  of  the 
gas  it  follows  that  the  ratio  of  the  external  friction  of  the  mixture  to 
the  external  friction  of  the  gas  whose  partial  pressure  is  pu  if  it  were 
in  the  vessel  alone,  is 


jV«,a/^  +  -*-^ 


NmCl    _        ^   ^     p       mi  p  _  N  iJpi      m^,  p% 
NimiQi  ""  NimiQi  "  Ni     p       mi  p' 


Digitized  by  VjOOQIC 


16  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

If  the  mixture  is  one  of  hydrogen  and  mercury  vapor  such  thatjoi  = /?«, 
the  above  ratio  becomes  about  14.  This  means  that  if  the  pressure  is 
measured  by  the  McLeod  gauge,  which  takes  no  account  of  the  mercury 
vapor,  the  friction  of  the  mixture  would  be  about  fourteen  times  as 
much  as  it  would  be  with  the  same  hydrogen  pressure  as  in  this  case, 
but  with  the  mercury  vapor  absent.  If  pi  =  1000/?a,  the  ratio  is 
about  1.05,  and  itpi  =  10,000^8,  it  becomes  about  1.005. 

It  might  be  urged  with  regard  to  the  method  described  above  for 
freeing  the  hydrogen  from  mercury  vapor  that  the  lowest  pressure  of 
vapor  obtainable  by  the  method  used  is  the  pressure  of  mercury  vapor 
at  the  temperature  of  liquid  air  boiling  at  atmospheric  pressure.  This 
pressure  at  0°  C  is  about  0.0005  mm.,  but  what  it  is  at  the  lower 
temperature  mentioned  can  hardly  even  be  conjectured.  We  have 
simply  to  fidl  back  upon  the  spectroscopic  test.  The  above  discussion 
shows,  however,  that  if  this  pressure  is  less  than  0.001  of  the  pressure 
of  the  hydrogen  it  will  not  very  seriously  affect  the  results.  If  it 
is  as  low  as  0.0001  of  the  hydrogen  pressure,  then  the  error  in 
the  observations  will  easily  be  greater  than  any  error  introduced  in 
this  way.  Considering  the  lowest  pressure  reached,  namely,  0.000016 
mm.,  the  vapor  pressure  of  mercury  at  the  temperature  of  liquid 
air,  boiling  under  atmospheric  pressure,  would  require  to  be  as  low  as 
0.000,000,016  in  order  that  the  ratio  of  the  partial  pressures  should 
be  1:1000. 

This  case  serves  to  show  how  important  it  may  be  to  consider 
mercury  vapor  when  we  are  dealing  with  these  very  low  pressures. 
It  indicates  that,  in  all  high  vacua  work  where  we  are  considering  the 
properties  of  a  particular  gas,  it  is  important  that  great  care  should  be 
taken  to  exclude  this  vapor.  The  McLeod  gauge,  of  course,  takes  no 
cognizance  of  it,  and  in  fact  serves  to  introduce  the  vapor  where  it  is 
not  wanted.  In  all  cases  where  the  vacuum  is  high,  and  it  is  desirable 
to  know  the  pressure  in  the  vessel,  and  yet  keep  the  gas  pure,  it  would 
be  desirable  to  have  a  gauge  which  would  not  introduce  any  impurity. 

If  the  inference  made  above  as  to  the  validity  of  the  McLeod  gauge 
measurements  on  gas  pressure  is  allowed,  then  we  can  say  that  reliance 
may  be  placed  upon  the  measurements  of  pressure  from  decrement 
measurements  in  the  apparatus  used  in  this  investigation.  This  method 
need  introduce  no  mercury  vapor,  but  it  takes  account  of  all  that  is  in 
the  vessel.  Moreover,  a  discussion  similar  to  that  used  for  mercury 
vapor  will  show  that  in  the  case  of  oxygen  the  decrement,  correspond- 
ing to  a  certain  gas  pressure,  will  be  about  four  times  as  great  as  it  is 
in  the  case  of  hydrogen.  In  the  case  of  oxygen,  therefore,  a  pressure 
of  0.00001  mm.  should  be  measured  with  an  accuracy  of  from  five  to 


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HOGG.  —  FRICTION    IN    GASES    AT    LOW    PRESSURES.  17 

ten  per  cent    This  woald  indicate  an  absolute  error  of  less  than 
0.000,001  mm. 

The  investigation  is  now  being  extended  to  the  case  of  oxygen  and 
nitrogen.  The  data  obtained  by  using  these  gases,  besides  showing 
whether  their  behavior  is  like  that  of  hydrogen,  should  give  some  more 
information  regarding  the  quantity,  P^  which  enters  the  foregoing 
discussion. 

Jefferson  Physical  Laboratory, 
Cambridge,  Mass. 


VOL.  XLV.  —  2 


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Sanger  and  Riegel.  — Determination  of  Antimony. 


« 

M 

m 

0.5    0.8     1.0     2.0      5.0     10.0 


5      10      15     20    25     30     35    40    50    60   70 

Standard  Antimony  Bands  in  Micromilligrams  of  SbiO« 
Ammonia  Development. 


Proc.  Amer.  Acad.  Arts  and  Sciences.   Vol.  XLV. 


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'.'■'.      •  .''8  0'"  the  ^:aeri    .a  Lo.no  h"  cf  ^  ^i>  au(^  f  I;  * . -si. 


Li      U  .Ti  ■    SvN,,.  ^    A^'i.   F...^K   IV^  V.  -x      '• 


W'lH   A    Pla:  '  . 


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(1 


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Prooeedingt  of  tlie  American  Academy  of  Arts  and  Sciences. 
Vol.  XLV.  No.  2.  — Octobbb,  1909. 


CONTRIBUTIONS  FROM  THE  CHEMICAL  LABORATORY  OF 
HARVARD  COLLEGE. 


THE    QUANTITATIVE   DETERMINATION    OF 
ANTIMONY  BY   THE  GUTZEIT  METHOD. 


Bt  Charles  Robert  Sanger  and  Emile  Raymond  Rieqel. 


With  a  Plate. 


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CONTRIBUTIONS  FROM   THE  CHEMICAL   LABORATORY 
OF  HARVARD   COLLEGE. 

THE  QUANTITATIVE  DETERMINATION  OP  ANTIMONY  BY 
THE  GUTZEIT  METHOD. 

Bt  Chables  Robert  Sanger  and  Emile  Ratmond  Riegel. 
Presented  August  31, 1909.    Received  August  31.  1909. 

The  application  of  the  so-called  Outzeit  reactions  to  the  quantitative 
determination  of  arsenic  has  been  studied  by  Sanger  and  Blaok^,  vho 
were  able  to  use  the  general  method  of  Outzeit^  for  the  convenient  and 
reasonably  accurate  estimation  of  small  amounts  of  arsenic.  In  study- 
ing the  interference  of  the  hydrides  of  sulphur,  phosphorus,  and  anti- 
mony with  the  reaction  of  arsine  on  paper  sensitized  with  mercuric 
chloride,  the  po^ibility  of  the  quantitative  determination  of  antimony 
by  this  method  was  apparent 

The  action  of  stibine  o)i  mercuric  chloride  was  first  investigated  by 
Franceschi',  who  obtained  a  white  body,  to  which  he  gave  the  formula 
SbHHgiCli,  analogous  to  the  red  compound  formed  by  the  action  of 
arsine  on  mercuric  chlorida  This  substance  decomposes  easily  in 
moist  air,  turning  dark,  probably  from  the  separation  of  mercury. 
When  stibine  is  allowed  to  act  upon  sensitized  mercuric  chloride  paper, 
as  shown  by  Sanger  and  Black^,  no  color  is  given  to  the  strip  from 
amounts  of  antimonious  oxide  up  to  about  70  micromilligrams  (mmg.). 
Hjrdrochloric  acid  develops  no  color.  But  if  the  strip  is  treated  mih 
ammonia^  a  black  band  ensues,  the  length  and  intensity  of  which  are 
proportional  to  the  amount  of  antimonious  oxide  present.  On  this  re- 
action we  have  based  the  following  method  for  the  determination  of 
small  amounts  of  antimony. 

»  These  Proceedings,  43,  297  (1907);  Jour.  Soc.  Chem.  Ind.,  26,  1115 
(1907);  Zeitsch.  f.  anorg.  Chem.,  68,  121  (1907);  Suppl.  ann.  enciclop.  chim., 
24,  372  (1907-08). 

«  Phann.  Zeitung,  24,  263  (1879).  In  the  original  Gutzeit  method,  the 
evolved  arsine  was  allowed  to  act  upon  paper  containing  argentic  nitrate. 
From  FlUckiger  in  1889  (Archiv  d.  Phann.,  227,  1)  came  the  suggestion  of 
using  mercuric  chloride. 

»  L'Orosi,  13,  397  (1890). 


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22 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


Thb  Method. 

The  procedure  does  not  vary  greatly  from  that  used  in  the  determi- 
nation of  arsenic  as  described  by  Sanger  and  Black^.  Some  details, 
therefore,  of  that  methgd  are  necessarily  repeated  here. 

Sensitized  Mercuric  Chloride  Paper.  A  smooth  filter  paper  of  close 
texture,  or  a  Whatman  drawing  paper  of  about  160  grams  per  square 
meter,  is  out  into  strips  of  a  uniform  width  of  4  millimeters.  The 
strips  are  sensitized  by  drawing  them  repeatedly  through  a  five  per 
cent  solution  of  recrystallized  mercuric  chloride  until  thoroughly 
soaked.    They  are  then  dried  on  a  horizontal  rack  of  glass  tubing,  and, 

Owhen  dry,  are  at  once  cut  into  lengths 
of  six  to  seven  centimeters.    The  small 
pieces    are   kept    in  the  dark  until 
>  needed,  in   a  stoppered  bottle  over 

calcic  chloride. 
The  Reduction  Apparatus.  (See  Figure.)  For  rea- 
sons that  will  be  explained  later,  the  construction  of  this 
differs  slightly  firom  that  used  in  the  arsenic  method. 
It  will  be  easily  seen  from  the  figure.  The  bottle  is 
of  30  C.C.  capacity,  closed  by  a  pure  rubber  stopper  with 
two  holes.  The  thistle  tube,  which  is  constricted  at  its 
lower  end  to  an  opening  of  about  2  mm.,  passes  to  the 
bottom  of  the  bottle  and  has  a  length  of  17  to  18  cm. 
In  the  second  hole  of  the  stopper  is  inserted  a  straight- 
walled  funnel  tube  of  17  to  20  mm.  bore,  carrying  a  pure 
rubber  stopper,  through  which  passes  a  right  angle  depo- 
sition tube,  9  to  10  cm.  in  length,  the  inner  diameter  of 
which  should  be  as  near  4  mm.as  possible,  but  not  less. 
Beagents,  These  are  exactly  the  same  as  in  the  arsenic  method,  and 
are  entirely  firee  from  antimony.  The  zinc.  Bertha  spelter,  is  from  the 
New  Jersey  Zinc  Company  of  New  York,  and  has  been  proved  by  re- 
peated tests  to  be  free  from  arsenic.  The  hydrochloric  acid,  from  the  Ba- 
ker and  Adamson  Company  of  Easton,  Pennsylvania,  contains  not  over 
0.02  milligram  of  arsenious  oxide  per  liter.  The  quantity  of  diluted 
acid  (one  part  to  six  of  water)  used  in  the  analysis  would  not  contain 
over  0.00004  milligram  of  arsenious  oxide,  an  amount  beyond  the  ab- 
solute delicacy  of  the  method  as  applied  to  arsenic  and  hence  of  no 
influence  in  the  determination  of  antimony. 

Moisture  Conditions  in  the  Deposition  Tube.  As  in  the  arsenic 
method,  the  moisture  of  the  evolv^  hydrogen  has  an  important  bearing 
on  the  uniformity  of  the  color  bands.    While  excess  of  moisture  must 


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8ANGEB   AND   RIEGEL.  —  DETERMINATION    OF   ANTIMONY.         23 

be  avoided  in  the  arsenic  method  by  a  cotton  wool  filter,  it  is  necessary 
to  have  a  much  greater  degree  of  sataration  in  order  to  obtain  compact 
and  uniform  deposits  on  the  strips  from  stibine.  If  the  hydrogen  is 
partially  dried  by  cotton  wool  before  impinging  upon  the  sensitized 
paper,  the  bands  are  long,  irregular  and  not  comparabla  By  increasing 
the  saturation  and  by  maJking  it  as  uniform  as  possible  we  have  suc- 
ceeded in  determining  the  conditions  under  which  the  bands  are  shorty 
regular,  and  perfectly  comparable. 

To  effect  this  and  at  the  same  time  to  hold  back  any  hydrogen  sul- 
phide which  might  be  formed  in  the  reduction,  we  use  disks  of  lead 
acetate  paper  inserted  in  the  straight-walled  funnel  tube  and  moistened 
with  a  definite  amount  of  water.  These  disks  are  of  filter  paper  of 
medium  thickness,  cut  in  quantity  by  means  of  a  wad  cutter  or  cork 
borer  so  as  to  fit  loosely  the  bore  of  the  funnel  tube.  They  are  saturated 
with  normal  lead  acetate,  dried,  and  kept  in  a  well  stoppered  bottle. 

Procedure.  The  deposition  tube  and  funnel  tube  of  the  apparatus 
are  cleaned  and  thoroughly  dried.  A  lead  acetate  disk  is  then  inserted 
in  the  funnel  tube  and  moistened  with  one  drop  of  water,  delivered  on 
the  centre  of  the  disk,  so  that  the  water  spreads  evenly  to  the  circum- 
ferenca  Three  grams  of  uniformly  granulated  zinc  are  placed  in  the 
bottle,  a  strip  of  sensitized  paper  is  slipped  wholly  within  the  deposi- 
tion tube  to  a  definite  distance,  and  the  apparatus  is  put  together. 
Five  or  ten  cubic  centimeters  of  diluted  acid  (1  to  6 ;  normality,  about 
1.5)  are  then  added  through  the  thistle  tube  and  allowed  to  act  for 
about  ten  minutes.  The  acid  is  then  poured  off  and  fifteen  cubic 
centimeters  of  fresh  acid  added.  This  procedure  ensures  a  uniform 
degree  of  moisture  saturation  in  the  deposition  tube,  and  the  absence 
of  arsenic  in  the  reagents  and  apparatus  is  assured.  The  zinc  is  also 
rendered  more  sensitive,  and  a  regular  flow  of  hydrogen  is  quickly  ob- 
tained on  the  second  addition  of  acid. 

In  five  minutes  after  this  addition,  the  solution  to  be  tested  is  intro- 
duced, either  wholly  or  in  aliquot  part,  which  may  be  determined  by 
weighing  or  measuring.  In  case  it  were  necessary  firom  the  nature  of 
the  analysis  to  prove  the  absolute  freedom  of  the  apparatus  and 
reagents  from  arsenic  and  antimony  before  adding  the  solution,  the 
evolution  of  hydrogen  would  be  continued  for  a  longer  time  and  the 
strip  developed.  The  absence  of  contamination  being  thus  assured,  a 
fresh  strip  would  be  substituted  before  adding  the  solution  to  be  tested. 
In  ordinary  work,  however,  this  precaution  is  quite  unnecessary. 

After  the  solution  is  introduced,  the  reduction  is  continued  for  30 
to  40  minutes.  No  effect  on  the  sensitized  paper  is  observed  unless 
the  amount  of  antimony  added  is  above  70  mmg.,  when  a  slight  gray 


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24  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

color  may  appear.  Larger  amounts  would  turn  the  paper  still  darker. 
If  any  color  appears,  it  is  an  indication  that  the  amount  will  be  difficult 
to  estimate,  and  hence  another  trial  should  be  made  with  a  smaller 
portion  of  the  solution,  or  from  less  of  the  original  substance. 

The  strip  is  now  placed  in  a  test  tube  and  covered  with  normal 
ammonic  hydroxide,  which  is  allowed  to  act  for  five  minutes.  A  black 
band  is  slowly  developed,  somewhat  duller  and  considerably  shorter 
than  would  be  obtained  from  the  same  amount  of  arsenic,  the  latter 
diflference  being  chiefly  due  to  the  moisture  conditions  in  the  deposi- 
tion tube.  The  band  is  then  compared  with  a  set  of  standard  bands. 
The  amount  of  antimony  in  the  entire  solution  follows  from  that  deter- 
mined in  the  aliquot  pait 

Standard  Bands,  A  standard  solution  is  made  from  pure,  recrys- 
tallized  tartar  emetic,  shown  to  be  free  from  arsenic.  2.3060  grams 
are  dissolved  in  water  and  made  up  to  one  liter.  This  solution  (I) 
contains  1.0  mg.  of  antimonious  oxide  per  cubic  centimeter.  From 
this,  by  dilution,  are  made  two  solutions  containing  respectively  0.01 
mg.  (II)  and  0.001  mg.  (Ill)  per  cubic  centimeter.  From  definite  por- 
tions of  solutions  II  or  III  a  series  of  bands  is  made  by  the  above 
procedure,  using  a  flresh  charge  of  zinc  and  acid  for  each  portion.  The 
lower  half  of  the  Plate  shows  the  actua}  size  and  shading  of  the  set  of 
bands,  corresponding  to  the  following  amounts  of  antimonious  oxide  in 
micromilligrams :  5,  10,  15,  20,  25,  30,  35,  40,  50,  60,  70. 

These  bands  have  shown  a  fair  degree  of  permanency,  but  &ule  slowly 
on  exposure  to  moisturp  and  light.  They  may  be  sealed  in  glass  tubes 
with  quicklime,  if  desired,  as  in  the  case  of  the  corresponding  ammonia- 
developed  arsenic  bands,  but  we  have  found  it  sufficient  to  mount  them 
on  a  dry  glass  plate,  which  is  covered  by  a  dry  plate  of  the  same  size. 
The  two  plates  are  then  cemented  together  and  bound  with  passepar- 
tout paper.  The  set  thus  mounted,  if  kept  in  a  desiccator  away  from 
the  light,  will  last  for  some  time.  In  case  a  fresh  set  of  standards  is 
not  available,  a  band  may  be  approximately  estimated  from  the  accom- 
panying. Plate  ;  the  more  accurate  determination  being  made,  if  neces- 
sary, by  comparison  with  freshly  prepared  bands  from  selected 
amounts. 

Analytical  Notes. 

General  Precautions.  As  in  the  arsenic  method,  the  solution  to  be 
reduced  should  contain  no  interfering  organic  matter,  except  that  any 
oxide  of  antimony  obtained  in  the  preparation  for  analysis  may  be 
eventually  dissolved  in  tartaric  acid.  Sulphur  in  any  form  reducible 
to  hydrogen  sulphide  should  be  removed  as  completely  as  possible,  but 


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SANGER    AND    RIEGEL.  —  DETERMINATION    OF    ANTIMONY.         25 

small  qnantities  of  hydrogen  sulphide  will  be  completely  retained  by 
the  lead  acetate  disk.  There  is  little  danger  from  phosphine,  for  phos- 
phites and  h3rpophosphites  would  be  oxidized  in  any  treatment  of  the 
substance  to  be  analyzed  which  would  convert  the  antimony  to  the 
oxide.  Traces  of  phosphine  would  be  readily  recognized  in  presence  of 
antimony*,  but  are  likely  to  interfere  with  its  estimation.  It  is  obvi- 
ous that  there  must  be  a  very  thorough  separation  from  arsenic. 

The  Evolution  qf  Stibine  in  the  Reduction  Bottle,  Sanger  and  Gib- 
son^ have  shown  that  amounts  of  antimony  under  one  milligram  are 
practically  all  converted  to  hydride  in  the  presence  of  zinc  and  hydro- 
chloric acid,  hence  a  retention  of  antimony  by  precipitation  upon  the 
zinc  is  not  to  be  considered  in  the  estimation  of  the  small  amounts  pro- 
vided for  by  this  method. 

Special  Precautions.  In  order  to  be  certain  of  uniformity  in  length 
and  density  of  bands  from  the  same  concentration  of  solution,  the  fol- 
lowing points  must  be  observed  : 

1.  The  reduction  bottles  must  be  of  equal  capacity,  and  other  parts 
of  the  apparatus  of  equal  dimensions. 

2.  The  amount  of  zinc  must  always  be  the  same,  similarly  sensitized, 
and  the  granulation  must  be  uniform. 

3.  The  volume  and  concentration  of  the  acid  must  be  definite. 

4.  The  moisture  conditions  in  the  deposition  tube  must  be  carefully 
regulated,  as  explained  above. 

In  the  "  Analjrtical  Notes "  of  the  article  by  Sanger  and  Black^, 
many  suggestions  will  be  found  which  will  contribute  to  a  clearer  un- 
derstanding of  this  method  as  well,  but  which  are  not  included  here 
for  the  sake  of  brevity. 

Analytical  Data. 

The  method,  as  &r  as  it  concerns  the  determination  of  antimony  in 
a  solution  properly  prepared  for  reduction,  was  tested  by  the  analysis 
of  solutions  containing  varjring  amounts  of  antimony,  which  were  un- 
known to  the  analyst    See  Table,  p.  26. 

We  do  not  claim  for  the  method  a  greater  accuracy  than  within  ten 
per  cent 

The  Delicacy  of  the  Method. 

Amounts  of  antimony  as  small  as  five  micromilligrams  are  readily 
recognized  by  use  of  the  4  mm.  strip.    Less  than  this  quantity  may  be 

*  See  Table  II,  Sanger  and  Black*. 

»  These  Proceedings,  42, 719  (1907) ;  Jour.  Soc.  Chem.  Ind.,  26, 585  (1907) ; 
Zeitschr.  f.  anorg.  Chem.,  66,  205  (1907). 


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26 


PBOCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


TABLE. 


No.  of 
Analysis. 

SbjO,  tak- 
en.    Tar- 
tar Emetic 
Solution. 

Total 
Weight 
Diluted 
Solution. 

Wt.  Diluted 
Solution 
taken  for 
Analysis. 

Reading 
of  BancT 

Fountl. 

Found. 
Mean. 

Per  Cent 
Found. 

4 

mg. 
0.06 

gm. 
25.15 

gm. 

4.67 

8.62 

10.63 

mmg. 

8 

15 

25 

mg. 
0.043 
0.044 
0.059 

mg. 
0.049 

82 

2 

0.12 

25.92 

4.31 
2.61 
7.11 

20 
10 
35 

0.120 
0.099 
0.128 

0.116 

97 

6 

0.20 

23.04 

2.59 
1.72 
4.23 

25 
17 
40 

0.222 
0.228 
0.218 

0.223 

112 

2,  a 

0.25 

26.07 

5.18 
3.43 
1.05 

45 
35 

10 

0.227 
0.266 
0.248 

0.247 

99 

9 

0.60 

21.63 

0.79 
0.97 
1.09 

22 
26 
32 

0.602 
0.580 
0.635 

0.606 

101 

8 

1.20 

23.74 

0.81 
0.84 

35 
35 

1.03 
0.99 

1.01 

84 

8,  a 

1.50 

24.30 

0.46 
0.61 
0.59 

30 
40 
40 

1.58 
1.59 
1.65 

1.61 

107 

7 

1.60 

21.32 

0.39 
0.27 
0.53 

35 
20 
45 

1.91 
1.58 
1.81 

1.77 

111 

4,  a 

2.50 

27.76 

0.44 
0.44 
0.44 

45 
40 
45 

2.84 
2.52 
2.84 

2.73 

109 

3,  a 

3.00 

29.99 

0.56 
0.56 
0.54 

50 
60 
60 

2.68 
3.21 
3.33 

3.07 

102 

Average 

Percentage 

100 

indicated,  but  the  estimation  is  difficult.  By  using  smaller  strips,  how- 
ever, a  more  accurate  reading  of  the  band  may  be  obtained  and  the 
delicacy  of  the  method  increased.  These  small  strips,  as  in  the  arsenic 
method,  are  made  by  cutting  the  large  strip  in  two  and  again  dividing 


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SANQEB   AND    RIEGEL.  —  DETERMINATION    OF   ANTIMONY.         27 

these  pieces  lengthwise,  giving  a  piece  2  mm.  wide  and  35  mm.  long. 
This  is  inserted  in  a  tabe  of  2  mm.  diameter,  affixed  to  the  usual  depo- 
sition tube  by  a  rubber  connector.  A  series  of  standards  is  then  made 
of  any  amounts  of  the  smaller  quantities  of  which  it  may  be  desirable 
to  get  an  approximate  estimate.  The  upper  part  of  the  Plate  shows 
the  bands  obtained  from  amounts  of  antimony  equivalent  to  0.5,  0.8, 
1.0,  2.0,  5.0,  and  10.0  nmig.  of  antimonious  oxide. 

The  bands  obtained  from  0.5  and  0.8  nmig.  are  perfectly  distinct,  but 
not  always  differentiated  with  clearness.  From  amounts  below  0.5 
mmg.  we  have  not  been  able  to  obtain  any  indication  on  the  2  mm. 
strip.  It  is  safe,  therefore,  to  set  the  practical  limit  of  the  delicacy  of 
the  method  at  1  mmg.  (0.001  mg.)  of  antimonious  oxide  (0.0008  mg. 
of  antimony).  The  absolute  delicacy,  however,  is  very  nearly  half  of 
this  amount^  — 0.0005  mg.  of  antimonious  oxide,  which  is  equivalent 
to  0.0004  mg.,  or  one  twenty-five-hundredth  of  a  milligram  of  an- 
timony. 

Sanger  and  Gibson^  were  able  to  detect  and  identify  by  the  Berzelius- 
Marsh  method  0.005  mg.  of  antimonious  oxide,  but  the  deposit  in  the 
tube  from  0.001  mg.  was  fkiat  It  will  thus  be  seen  that  the  "  band  " 
method  is  much  more  delicate  than  the  *' mirror  "  method.  It  is  also 
more  convenient  and  accurate,  for  the  bands  are  subject  to  no  irregu- 
larity of  formation  comparable  to  the  difficulty  of  obtaining  a  mirror  of 
metallic  antimony  entirely  free  from  oxida  The  mirror  method,  how- 
ever, is  still  of  value  as  a  confirmation  of  the  other  and  a  check  upon 
its  results.  The  two  methods  can  be  applied,  if  desired,  to  different 
portions  of  the  solution  which  has  been  prepared  for  analysis. 

The  application  of  the  method  to  the  analysis  of  products  containing 
antimony  is  under  consideration  in  this  laboratory,  but  we  have  con- 
tented ourselves  for  the  present  with  showing  that  very  small  amounts 
of  antimony  may  be  estimated  by  it  in  a  solution  properly  prepared  for 
analysis.  A  study  of  its  application  should  include  the  separation  of 
small  amounts  of  arsenic  or  antimony  from  relatively  large  amounts 
of  the  other,  concerning  which  we  have  now  no  reliable  information. 

Harvard  UNiVERsnT,  CAMBRmoE,  Mass., 
U.  S.  A.,  August,  1909. 


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Prooeedings  of  fhe  Ammioan  Academy  of  Arte  and  Sdenoet. 
Vol.  XLV.  No.  3.  — November,  1909. 


THE  EQUIVALENT  CIRCUITS  OF  COMPOSITE 
LINES  IN  THE  STEADY  STATE. 


By  a.  E.  Kennelly. 


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THE  EQUIVALENT   CIRCUITS  OF   COMPOSITE   LINES   IN 
THE  STEADY  STATE. 

By  a.  E.  Kennellt. 
PraMntad  October  2, 1909;  Received  October  4, 1909. 

Definitions  and  Purposb. 

A  composite  line  may  be  defined  as  an  electrically  conducting  line 
formed  of  two  or  more  successive  sections,  each  section  having  its  own 
length  and  its  own  particular  uniformly  distributed  resistance,  induc- 
tance, capacitance,  and  leakanca  Each  such  section,  considered  sepa- 
rately, may  be  described  as  a  single  line,  A  composite  line  is,  therefore, 
a  successive  connection  of  single  lines  which  differ  in  linear  constants. 

It  has  been  shown  by  the  writer  in  a  preceding  paper  ^  that  any 
uniform  single  line,  operated  in  the  steady  state,  either  by  single- 
frequency  alternating  currents  or  by  continuous  currents,  may  be 
externally  imitated  by  a  symmetrical  triple  conductor.  The  triple 
conductor  which  can  be  substituted  for  a  single  line  in  a  steady  sys- 
tem of  electric  flow  without  disturbing  the  potentials,  or  currents,  at 
or  outside  of  the  line  terminals,  may  be  defined  as  an  equivalent  circuit 
of  the  line.  A  star-connected  equivalent  circuit,  with  two  equal  line 
branches  and  a  single  leak,  may  be  called  an  equivalent  T ;  while  a 
delta-connected  equivalent  circuit  with  two  equal  leaks,  and  a  single 
line-resistance  or  impedance  between  them,  may  be  called  an  equiva- 
lent n .  It  is  the  object  of  this  paper  to  extend  the  laws  of  equivalent 
circuits  firom  single  lines  to  composite  lines,  with  or  without  loads,  and 
also  to  present  formulas  for  the  distribution  of  current  and  potential 
over  such  composite  lines. 

Important  Practical  Application  qf  the  Problem, 

An  important  application  of  this  problem  is  found  in  telephony. 
With  given  sending  and  receiving  apparatus,  the  commercial  opera- 
tiveness  of  a  telephonic  metallic  circuit  apparently  depends  only  on 
the  strength  of  alternating  current,  at  a  certain  standard  frequency,  in 

>  "Artificial  Lines  for  Coixtinuous  Currents  in  the  Steady  State."  See 
appended  Bibliography. 


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32  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

the  receiver.  That  is,  it  depends  on  the  "receiving-end  impedance" 
of  the  circuit,  or  the  ratio  of  the  impressed  standajrd-frequency  alter- 
nating emf.  at  the  sending  end,  to  the  current-strength  at  the  receiving 
end.  If  this  receiving-end  impedance  of  the  circuit,  including  the  im- 
pedance of  the  receiving  apparatus,  is  not  greater  than  25,000  ohms 
(12,500  ohms  per  wire),  at  the  angular  velocity  «  =  5000  radians  per 
second,  commercial  telephony  will  readily  be  possible  with  the  standard 
Bell  telephone  apparatus  used  in  the  CFnit^  States ;  unless  the  dis- 
tortion of  the  speech-waves,  due  to  unequal  attenuation  at  different 
frequencies,  is  unusually  great.  If  the  circuit  receiving-end  impedance 
exceeds  200,000  ohms  (100,000  ohms  per  wire)  at  <i>  =  5000  radians  per 
second,  even  expert  telephonists  will  ordinarily  be  unable  to  converse 
with  this  apparatus  over  the  line. 

It  is  easy,  with  the  aid  of  formulas  given  in  the  above-mentioned 
preceding  paper,  to  find  the  equivalent  fl  of  a  simple  single  telephone 
line  of  given  length,  uniform  linear  constants,  and  assigned  terminal 
conditions.  But  for  most  practical  purposes  this  is  not  enough.  Most 
long  telephone  lines  in  practical  service  are  not  single,  but  composite. 
Consider  the  case  of  a  subscriber  A,  in  Boston,  talking  to  a  subscriber 
B,  in  New  York.  First  there  is  the  terminal  apparatus  at  A ;  then, 
say,  a  few  kilometers  of  underground  line  in  Boston.  Next  comes  the 
long-distance  overhead  line  firom  Boston  to  New  York,  perhaps  con- 
sisting of  more  than  one  section  and  size  of  wire.  Then  come  one  or 
more  sections  of  underground  wire  in  New  York,  before  we  end  the 
circuit  in  B's  apparatus.  At  two  or  three  intermediate  exchanges  in 
this  circuit  there  may  also  be  casual  loads,  formed  by  supervisory  re- 
lays, or  other  instruments.  The  critical  receiving-end  impedance  must 
not  be  exceeded  in  this  compositer  circuity  if  the  talking  is  to  be  of  sat- 
is&ctory  quality.  Actual  trial  of  the  line  by  conversation  will  deter- 
mine, with  a  &ir  degree  of  precision,  whether  the  limiting  permissible 
receiving-end  impedance  has  been  exceeded  by  the  line.  But  the  de- 
signing telephone  engineer  seeks  to  know,  in  advance,  whether  a  certain 
projected  composite  line  will,  when  constructed,  fall  within  the  per- 
missible limit  of  receiving-end  impedance.  If  working  formulas  can  be 
developed,  that  are  not  too  lengthy  and  complicated,  for  determining 
the  receiving-end  impedance  of  composite  lines,  they  may  help  the 
designing  engineer  to  decide  questions  of  line  construction. 

In  this  paper  the  discussion  will  be  principaUy  confined  to  direct- 
current  composite  lines.  The  formulas  thus  derived  are  all  easily 
presented,  grasped,  and  checked  by  Ohm's  law,  since  they  involve 
only  real  numerical  quantities.  In  the  direct-current  case  the  hyper- 
bolic quantities  used  are  all  functions  of  simple  real  numerics,  for  which 


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KENNELLY.  —  EQUIVALENT   CIKCUTTS   OF   COMPOSITE   LINES.       33 

published  tables  are  available.  Identically  the  same  formulas  are,  how- 
ever, applicable  to  siugle-frequency  alternating-current  cases,  by  ex- 
panding their  interpretation  from  real  to  complex  numbers ;  or  fit)m 
one  space-dimension  into  two,  using  impedances  for  resistances  and 
plane-vectors  for  potentials  and  currents.  Unfortunately,  however, 
we  have  no  tables  of  hyperbolic  sines,  cosines,  and  tangents  available, 
as  yet,  for  complex  arguments  except  for  the  particular  case  of  semi- 
iinaginaries,^  or  plane-vectors  of  45** ;  so  that  in  working  out  the  alter- 
nating-current cases,  as,  for  example,  in  telephony,  the  engineer  is  de- 
layed by  having  to  assume  the  duties  of  a  computer,  and  to  work  out 
his  own  hyperbolic  sines,  cosines,  and  tangents.  However,  even  thus 
handicapped,  it  is  claimed  that  the  formulas  here  presented  will  not 
be  too  lengthy  for  the  engineer  to  use  in  important  cases.  If  hyper- 
bolic tables  of  complex  arguments  were  worked  out  and  published,  the 
formulas  could,  with  their  help,  be  applied  almost  as  quickly  and  con- 
veniently to  alternating-current  cases  as  they  can  be  applied  at  present 


^»La 


-•B 


FiGUBE  1.    Uniform  line  with  distributed  resistance  and  leakance. 

to  direct-current  cases.  If,  however,  attempts  are  made  to  obtain 
alternating-current  results  of  like  precision  without  the  use  of  hyper- 
bolic functions,  there  seems  to  be  no  hope  of  helping  the  engineer. 
Only  specially  trained  mathematicians  could  handle  the  long  and  com- 
plex resulting  formulas. 

Preliminary  Review  op  Single-Linb  Formulas. 

In  order  to  pass  to  composite  lines,  we  may  first  briefly  review  the 
laws  of  equivalent  circuits  for  single  lines.  The  fundamental  formulas 
will  be  given  for  direct-current  (D.  C.)  and  for  alternating-current 
(A.  G.)  circuits,  in  parallel  columns. 

Let  AB,  Figure  1,  be  a  uniform  single  line  operated  to  ground,  or 
zero-potential,  return  circuit. 
L  =  the  length  of  the  line  in  kilometers  (or  miles). 

*  See  Table  appended  to  *'  The  Alternating-Current  Theory  of  Transmission- 
Speed  over  Submarine  Cables/'  referred  to  in  the  Bibliography. 
VOL.  xlv.  —  3 


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34  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

r  =  the  linear  resistance  of  the  line  (ohms  per  wire  km.). 
g  =  the  linear  leakance  of  the  line  (mhos  per  wire  km.). 
/  =  the  linear  inductance  of  the  line  (henry s  per  wire  km.). 
c  =  the  linear  capacitance  of  the  line  (farads  per  wire  km.). 
n  =  the  frequency  of  the  impressed  emf  at  A  (cycles  per  second). 
CD  =  2  TT  n,  tiie  angular  velocity  of  the  impressed  emf  at  A  (radians 
per  second). 

The  attenuation  constant  of  the  line  is 

D.C.    a=V^      ^;     A.C.    a=V(r+i&o)07+ica,)^'Z. 

(1) 
In  the  D.  G.  case  a  is  a  real  numerical  quantity  which  we  may,  for  conven- 
ience of  subsequent  operation,  define  as  a  "  linear  hyperbolic  angle/'  or 
"  hyperbolic  angle  "  per  km.  of  length.  Although  it  is  a  simple  numeric 
per  unit  length  of  line,  yet,  since  it  forms  the  basis  of  argument  in  hyper- 
bolic tables,  we  may  call  it  a  "  hyperbolic  angle  "  per  unit  length  of 
line,  and  denote  a  hyperbolic  unit  angle  as  a  **  hyp."  In  the  A.  C.  case 
d  is  a  plane- vector  "hyperbolic  angle,"  or  complex  quantity,  per  unit 
length  of  line. 
The  hyperbolic  angle  subtended  by  the  line  AB  is 

D.  C.  6  =  La  hyps;  A.  C.  0  =  La  hypsZ.  (2) 

^  is  a  real  numeric  for  the  D.  C.  case,  and  a  plane- vector,  or  numeric  at 
a  definite  angle  in  the  reference  plane,  for  the  A.  C.  case.  The  surge- 
resistance,  or  surge-impedance,  of  the  line  is 


D.  C.   ;?  =  i/-      ohms  ;        A.  C.    ;^  =  a/L±J^      ohms  Z.  (3) 

The  surge-impedance  of  an  A.  C.  line  is  the  impedance  that  the  line 
offers  at  any  point  of  its  length  to  the  propagation  of  waves  of  the  fre- 
quency considered.  It  is  a  vector  resistance,  or  impedance,  often  closely 
approximating  numerically  to  a^I/c,  The  surge-admittance  of  a  line  is 
the  reciprocal  of  its  surge-impedance. 

In  wave-propagation  theory,  and  also  in  the  steady-state  theory  here 
considered,  0  and  z^  the  h3rperbolic  angle  and  surge-impedance  of  a  line, 
are  its  ftindamental  characteristics ;  while  r,  ^,  /,  and  c  are  its  sec- 
ondary or  incidental  characteristics. 


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KENNELLY.  —  EQUIVALENT   CIRCUITS   OF    COMPOSITE   LINES.       35 


Single  Line  Freed  at  Distant  End. 

If  the  line  AB  is  freed  at  B,  its  resistance  at  A,  measared  to 
ground,  is 

R^^  =  z  coth  Q  ohms.  (4) 

In  the  D.  C.  case  the  hyperbolic  angle  ^  is  a  simple  real  quantity,  z 
is  a  simple  numerical  resistance,  and  coth  0  is  the  h3rperbolic  cotangent 
of  ^,  a  real  numeric,  obtainable  from  tables  of  hyperbolic  functions. 
Consequently,  Rf^  is  a  simple  resistance  in  ohms.  In  the  A.  C.  case, 
however,  2;  is  an  impedance,  or  vector  resistance,  0  is  also  a  vector  quan- 
tity, and  the  hyperbolic  cotangent  of  this  vector  is  not  ordinarily  ob- 
tainable from  any  tables  thus  fiu*  published.  It  must  be  computed,  say, 
with  the  aid  of  formula  (142).  The  product  of  z  and  this  cotangent  is, 
therefore,  a  vector  resistance,  or  impedance,  R/a-  Similarly,  all  the 
remaining  formulas  of  this  paper  may  be  regarded  as  applying  either 
to  D.  G.  or  to  A.  G.  cases ;  but  the  D.  G.  reasoning  will  be  followed,  for 
simplicity  of  numerical  check. 

At  any  point  P  (Figure  1)  along  the  line,  distant  X  km.  from  B,  its 
hyperbolic  angular  distance  from  B  will  be 

8  =  fa  hyps.  (5) 

The  potential  at  P  is 

tt,  =  fi^cosh8  volts,  (6) 

where  u^  is  the  potential  at  the  &r  free  end  B,  defined  by  the  condition 

tt^  =  fi^/coshtf  volts;  (7) 

whence 

The  curve  of  potential,  or  voltage  to  ground,  plotted  as  ordinates 
along  the  line  AB  is,  therefore,  a  curve  of  h3rp.  cosines,  or  a  cate- 
nary. In  the  A.  G.  case  the  curve  of  vector  lengths,  or  numerical 
values,  of  potential,  plotted  as  ordinates  along  AB,  is  a  sinusoid 
superposed  upon  a  catenary. 

The  current-strength  at  the  point  P  is 

.  sinhS  ,^. 

*'  =  '^55h^  amperes,  (9) 

where  i^  is  the  current  entering  the  line  at  A.  The  curve  of  current- 
strength  plotted  as  ordinates  along  AB  is,  therefore,  in  the  D.  G.  case, 
a  curve  of  hyp.  sines,  or  curve  of  catenary-slope. 


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36 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


The  resistance  of  the  line,  at  and  beyond  the  point  P,  measured  to 
ground  is 

Mfp  =  zoothS  ohms,  (10) 

or 

cothS 


Mfp  =  Hi 


'^^  QOthO 


ohms.  (11) 


Single  Line  Grounded  at  Distant  End. 

If  the  line,  instead  of  being  freed  at  B  (Figure  1),  is  grounded  at  B, 
its  resistance  at  A  is 

Bg^  =  z  tanh  $  ohms.  (12) 

At  any  point  P,  angularly  distant  S  hyps  from  B,  the  line  resistance 
beyond  P,  measured  to  ground,  is 


Bgp  =  z  tanh  < 


or 


Bgp  =    jRft 


tanhS 


'^  tanh^ 

The  potential  at  P,  in  terms  of  the  potential  w^  at  A,  is 

sinhS 


Up  =  Uj, 


sinh^ 


ohms,  (13) 
ohms,  (14) 

volts.  (15) 


The  current-strength  at  P,  in  terms  of  the  current-strength  i^  enter- 
ing the  line  at  A,  is 

cosh  5 


tp  —  tj, 


cosh^ 


amperes.  (16) 


For  example,  consider  a  line,  AB,  Figure  1,  of  Z  ==  100  km.,  with  a 
linear  resistance  r  of  20  ohms  per  wire-km.,  and  a  linear  leakance  g  of 
20  X  10"*  mho  per  wire  km.  (20  micromhos  per  km.),  corresponding 
to  a  linear  insulation-resistance  of  50,000  km-ohms.  The  attenuation- 
constant  of  this  line  is  a  =  2  X  10"^  hyp.  per  km.  by  (1),  and  the 
hjrperbolic  angle  subtended  by  the  line  is  ^  =  2  hyps,  by  (2).  The 
surge-resistance  of  the  line  \n  z—  1000  ohms  by  (3).  Then  the  re- 
.sistance  ofifered  by  the  line  at  A,  when  freed  at  B,  is,  by  (4), 

Bf^  =  1000  coth  2  =  1000  X  1.037315  =  1,037.315  ohms, 
and  when  grounded  at  B,  by  (12), 

Bgj^  -  1000  tanh  2  =  1000  X  0.964026  =  964.026  ohms. 


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KENNELLY.  —  EQUIVALENT   CIRCUITS   OF   COMPOSITE   LINES.       37 


EQinvALKNT  Cmcurrs  op  Single  Link. 


The  eqaiyalent  T  of  this  lino  is  a  star-connectioa  of  three  resist- 
ances AO,  GO,  BO  (Figure  2),  two  of  which — the  line-branches  AO,  OB, 
—  are  eqoal ;  while  OG  is  a  leak- 


age-resistance  to  ground.  This 
equivalent  T,  when  correctly  pro- 
portioned, has  the  property  of  ^* 
being  able  to  replace  the  uni- 
formly leaky  line  AB,  without 
disturbing  in  any  manner  the 
system  of  potentials  and  currents 
outside  the  terminals  ABG.  Let 
^  =  \IB!  be  the  conductance  of 
the  leak  OG';  then 

/  =  y  sinh  Q    mhos,  (17) 

where  y  =  \lz  mhos,  the  recipro- 
cal of  the  surge-resistance.    We      Figxtbs  2. 
may  call  y  the  surge-conductance 
(A.  C.  surge-admittance). 
Let  p'  be  the  resistance  of  each  line-branch  AO,  OB ;  then 


J-3J3xr!. 

W)3xW-». 

^  '■ 

o^ 

v> 

5 

J3 

X 

o 

s 

«^ 

B^ 

«« 

n 

w 

*A 

•B 


G 

Equivalent  T  of  imif orm 
line. 


=  z  tanh  ft  =  « 


%  m 

yo\36Z6'86'^ 

A  T3 

;^   E-75JE05x)0-*« 

^ 

tt'       y 

tt 

■» 

s^ 

*«d^ 

0\ 

C* 

2^ 

u> 

5; 

iZ 

^ 

• 

X 

o 

1 

9 

• 
t 

X 

9 

t 

Figure  3. 


and 


Equivalent  n  of  imifonn 
line. 


cothtf-^  =  ^/-^    mhos.  (18) 

Thus,  for  the  line  above  con- 
sidered, /  =  0.001  X  sinh  2  = 
0.001  X  3.62686  =  3.62686  X 
10-*  mho ;  while  B'  =  1//  = 
275.7205  ohms.  p'=1000coth2 
—  275.7205  =  761.594  ohms. 

The  equivalent  n  of  the  line 
is  a  delta-connection  of  three 
resistances  AB,  AG",  BG" 
(Figure  3),  the  two  "  pillars  "  or 
leaks  AG",  BG",  being  equal 
conductances  of  g"  mhos  each, 
and  the  "architrave  "  AB  being 
the  line-resistance  p". 


p"  =  z  sinh  0  ohms  (19) 

$ 

/'  =  1/^'  =  y  tanh  -  n      mhos 

=  ycoth^-y"  =  (y^-y'  mhos,  (20) 


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38  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

where  y"  =  \lg"  is  the  acchitrave  conductance,  and  Gg  =  \IBg  is  the 
conductance  to  groand  of  the  line  at  one  end,  when  grounded  at  the 
other  end. 

Thus,  for  the  line  considered,  p"  =  1000  sinh  2  =  3626.86  ohms,  and 
/'  =  0.001  coth  2  -  2.757204  X  10"*  =  7.6159  X  10"*  mho. 

Single  Line  Corresponding  to  a  Symmetrical  t  or  n. 

Reciprocally,  any  star  connection  of  three  resistances  AO,  GO,  BO 
(Figure  2),  having  two  equal  line-branches  AO  and  OB  of  p  ohms,  with  a 
leak  to  ground  oi  R  =  1//  ohms,  corresponds  to  some  smooth  uniform 
line  of  angle,  

d  =  2  sinh-^  j/-^  hyps,  (21) 

and  of  surge-resistance, 

z  =  Vp'  (p  +  2ie)  ohms.  (22) 

Likewise,  any  delta-connection  ABG"G"  (Figure  3)  with  two  equal 
grounded  leaks  of  resistance  R*  =  \/^'  ohms,  connected  by  an  archi- 
trave of  p''  ohms,  corresponds  to  a  smooth  uniform  line  of  angle, 

tf  =  2  tanh-^  \^2R'"x  p"  ^^'  ^^^^ 

and  of  surge-resistance, 

z  =  R'  tanh  -  ohms.  (24) 

Equivalent  Circuits  op  Single  Line  in  Terms  op  Resistances  of 
Line  Free  and  Grounded. 

If  the  line  be  first  freed  and  then  grounded  at  one  end,  say  B  (Figure 
1),  and  the  resistance  of  the  line  be  measured  correctly  at  the  other  end 
in  each  case  {R/  and  Rg  respectively),  we  have  for  the  equivalent  T  of 
the  line,  

p'  ^Rf(l-  \/  \^?l\  ohms,  (25) 

R  =  Rf\/  l-^  ohms.  (26) 

Rf 

Similarly,  we  have  for  the  equivalent  n  of  the  line, 

p"  =  Rgl\/  1  -  ^Ii  ohms,  (27) 


Digitized  by  LjOOQIC 


KENNELLY,  —  EQUIVALENT   CIRCUITS    OF   COMPOSITE    LINES.       39 


From  which 


Ilf'  =  B^fl  +  ^l-^\  ohms.  (28) 

^'  ^^'  ^Rj.  ohms.  (29) 

rig  =  B:'p'  =  iTp"  =  RfR^  =  ^         (ohms)^  (30) 

tf  =  Za  =  tanh- V§  liyps-  (31) 

The  last  two  formulas  serve  to  evaluate  z  and  0  for  any  single  line, 
when  the  sending-end  impedances  of  that  line  {R/  and  R^  have  been 
correctly  measured. 

Looped  or  Metallic-Return  Single  Circuits. 

If  we  consider  single  metallic  circuits,  like  those  of  wire-telephony, 
or  of  single-phase  power- transmission. 

Let  r„  =  the  linear  resistance  (ohms  per  loop  km.). 

^„  =  the  linear  leakance  (mhos  per  loop  km.). 
/„  =  the  linear  inductance  (henrys  per  loop  km.). 
c„  =  the  linear  capacitance  (farads  per  loop  km.). 


Then 


r„  =  2  r 

ohms  per  km.  "| 

g^^  =  5^/2 

mhos  per  km. 

/„  =  21 

henrys  per  km. 

c„  =  c/2 

farads  per  km.  ^ 

(32) 


where  r,  g,  l,  and  c  are  the  corresponding  linear  constants  per  wire  km. 
Substituting  in  equations  (1),  (2),  and  (3),  we  have 

a„  =  a  hypa  per  loop  km.,  (33) 

0„  =  0  hyps,  (34) 

and  z„  =  2z  ohms.  (35) 

That  is,  the  attenuation-constant^  and  the  angle  subtended  by  the 
looped  line>  are  respectively  identical  with  the  attentuation-constant 
and  angle  subtended  by  one  wire  only  operated  to  zero  potential.  The 
surge-impedance  of  the  metallic  circuit  is  double  the  surge-impedance 
of  one  wire  to  ground,  or  zero  potential.  The  voltage  impressed  upon 
the  loop  is,  however,  double  the  voltage  impressed  on  each  wire  singly 


Digitized  by  VjOOQIC 


40 


PROCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 


worked  to  zero-potential  plane,  so  that  the  current-strength  in  the 
circuit  is  the  same  with  either  method  of  computation. 
The  above  conditions  are  illustrated  in  Figure  4,  where  ABB'A  repre- 

-3 . -2^— «. 


K B 

12. '-; Z^M 

1'  B' 


tm•ny^si^n'.ls' 


A  2iO»JfPfr^ir  2W'f*T^*r>r  Jt 


mfxwofrr  240>74f  Br^ 


A  tW^T^ranr  Z^iT^isui^B' 


Figure  4. 


Equivalent  circuits  of  lines  with  ground  return  and 
metallic  return. 


sents  a  simple  metallic-return  telephone  circuit  with  a  transmitter 
induction  coil  of  impedance  Zs  at  A,  and  a  receiver  of  impedance  Zr  at 
B.  One  half  of  this  circuit,  with  only  one  wire  and  ground  return,  is 
indicated  at  AB  on  the  right  hand.  The  length  of  the  circuit  has  been 
taken  as  X  =  50  km.  (31.068  statute  miles),  and  the  following  linear 
constants  have  been  assumed: 


Digitized  by 


KENNELLY.  —  EQUIVALENT   aRCUITS    OF    COMPOSITE    LINES.       41 

r„  =  55.92  ohms  per  loop  km.  (90  ohms  per  loop-mile) ;  ^„  =  0 
/„  =  0.70  X  10"*  henry  per  loop  km.  (1.126  millihenry  per  loop-mile) 
c„  =  0.049,7  X  10^  farad  per  loop  km.  (0.08  X  lO"*  &rad  per  loop-mile): 
Yalues  which  correspond  to 

r  =  27.96  ohms  per  wire  km. 

/  =  0.35  X  10"^  henry  per  wire  km. 

c  =  0.099,4  X  10-^  &rad  per  wire  km. 

Sahstituting  the  above  values  in  (1),  (2),  and  (3),  we  obtain  at  cu  = 
5,000  radians  per  second : 

a„  =  a  =  0.117,976,6  /46°  47'  26'"  hyps  per  loop  km.,  or  per  wire*  km. 

e„=0=^  5.898,83  /46°  47'  26'^  hyps  for  both  the  double  line  and  the 

single  line. 
«„  =  474.755  \43"  12'  34"  ohms  for  the  loop  circuit 
z  =  237.377,5  \43°  12^  34"  ohms  for  the  single  Una 

The  equivalent  n  and  T  of  one  wire  are  indicated  at  AB6G'  and  A0B6 
in  Figure  4.  The  architrave  impedance  AB  is  6,736.96/156"  51'  15" 
ohms,  which  is  also  the  receiving-end  impedance  of  each  line,  exclud- 
ing the  receiving  instrument  Zr ;  because,  if  we  ground  the  line  at  B, 
the  current  which  wiU  flow  to  ground  at  B  will  be  the  impressed  poten- 
tial at  A  divided  by  this  architrave  impedance. 

The  equivalent  circuits  of  the  loop  line  are  indicated  at  ABB" A" 
and  AOBB'O'A'  (Figure  4).  The  former  is  a  rectangle  of  impedances, 
and  the  latter  an  I  of  impedances.  It  will  be  seen  that  the  rec- 
tangle ABB" A"  is  merely  a  doublet  of  the  single  line  n,  ABG'6; 
while  the  I,  AOBB'O'A'  is  merely  a  doublet  of  the  single  line  T, 
AOBG.  The  receiving-end-impedance  of  the  loop-circuit  is  evidently 
2  X  6,736.96/156"  51'  15"  =  13,473.92/156"  51'  15"  ohms,  excluding 
the  receiving  instrument  Zr- 

Since,  then,  the  equivalent  circuits  of  metallic-circuit  or  loop-lines 
are  mere  doublets  of  those  for  their  component  single  wires,  and  the 
latter  are  easier  to  think  about  and  discuss,  we  will  confine  our  atten- 
tion to  the  latter. 


Digitized  by  ^ 


;|og 


GdoQle 


42  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

COMPOSITE  LINES. 

First  Case.  Sections  of  the  same  Attenuation-Constant  and  of  the 
same  Surge- Impedance. 

If  a  line  AB  (Figure  5)  of  2^  km.  is  connected  to  a  line  CD  of  Z2  km., 
and  each  has  the  same  attenuation  constant  a,  and  the  same  surge- 
resistance  z  ohms  (conditions  which  imply  the  same  linear  constants), 
the  line  angles  will  be  ^1  =  Lia  and  B^  =  -£««  hyps  respectively. 
Then,  if  we  free  the  composite  line  at  D,  the  resistance  at  A  is 

7?/  =  «  coth  (^1  H-  e^  ohms,  (36) 

while,  if  the  composite  line  be  grounded  at  D,  the  resistance  at  A  is 

Rg  —  z  tanh  (^1  +  0^  ohms.  (37) 


ft        b;c ft. 


Figure  5.    Composite  line  with  sections-of  the  same  attenuation- 
constant  and  surge-resistance. 

Reciprocally,  freeing  and  grounding  the  composite  line  at  A,  we  get 
resistances  Ry^  and  Rg  at  D,  respectively  the  same  as  in  (3G)  and  (37). 
It  is  evident^  then,  that  the  composite  line  differs  in  no  way,  except 
in  length,  from  either  of  the  component  sections.     The  angle  subtended 
by  the  whole  line  KD  is  the  sum  of  the  component  section  line-angles. 

Second  Case.  Sections  qf  different  Attenuation-Constant  but  of  the 
same  Surge- Impedance, 

If  a  section  CD  (Figure  5)  of  Z,  km.  be  connected  to  a  section  AB  of 
Zi  km.,  and  their  respective  linear  constants  rs,  ^s,  and  n,  gi  are  such 
that  their  attenuation  constants  ai,  oj  differ ;  while  their  surge-resist- 
ances z  are  the  saiue,  we  a.-^sigu  the  angles  subtended  by  the  sections 
61  =  Liai  and  6^  =  L^a^  hyps.  The  angle  subtended  by  the  whole 
line  will  then  be  ^1  +  ^a,  as  in  the  preceding  case.  That  is,  except 
for  a  disproportionality  between  the  section-angles  and  their  line- 
lengths,  two  sections  of  different  attenuation-constant,  but  of  the 
same  surge-resistance,  connect  together  like  two  sections  of  one  and 


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KENNELLY.  —  EQUIVALENT   CIRCUITS   OF    COMPOSITE    LINES.      43 

the  same  type  of  line.  This  is  for  the  reason  that  in  the  unsteady 
state,  or  period  of  current  building  prior  to  the  formation  of  the  steady 
state  here  discussed,  there  is  neither  wave  reflection  nor  discontinuity 
of  wave  propagation  at  the  junction  BC,  when  the  surge  resistance  or 
impedance  z  is  the  same  on  each  side  thereof. 

In  order,  however,  to  simplify  the  transition  to  complex  cases  later 
on,  we  may  pause  to  consider  the  following  case  of  two  sections,  with 
different  a  but  the  same  z. 

ii  =  100  km.,  fx  =  20  ohmsAm.,  ^i  =  2  X  10"*  mhoAm. 
ij  =  100  km.,  rj  =  10  ohmsAm.,  g%  =  10~*  mhoAm. 

Whence  ai  =  0.02  hypAm.,  z^  =  1000  ohms ; 

a,  =  0.01  hypAm.,  z^  =  1000  ohms. 

Merger  Equivalent  Circuits  qf  Composite  Lines. 

Figure  6  shows  the  two  lines  at  AB  and  CD  respectively.  It  also 
shows  the  fl  and  T  equivalent  circuits  of  AB  at  A"B"G"G"  and 
A'OFG',  likewise  of  CD  at  C'D^'G^G"  and  C'OD'G'.  If  we  connect 
the  sections  together  at  BC,  into  a  composite  line  AD,  we  virtually 
connect  together  some  one  pair  of  the  combinations  of  equivalent  cir- 
cuits Hj^DcD,  Tab^cdj  ^AB^cDi  '^ AB  ^ CD-  Thc first  two  combinations  are 
shown  at  ABCDGGG  and  A'OBCOIXG'G'.  If  we  merge  together  the 
two  elements  of  any  such  pair  by  known  formulas,^  we  arrive  either  at 
the  equivalent  n,  ADGG;  or  the  equivalent  T,  AODG,  of  the  com- 
posite line. 

The  equivadent  PI  or  T  of  a  composite  line,  computed  by  the  merging  of 
the  ris  or  Ts  of  the  component  sections,  may  be  called  the  "  merger  n  " 
or  "merger  T"  of  the  line,  to  distinguish  them  fix)m  the  n  or  T  com- 
puted directly  fix)m  the  composite  lines  by  the  formulas  to  be  presented 
later.  The  latter  may  be  called,  for  distinction,  the  "  h3rperbolic  n  " 
or  T.  For  a  given  degree  of  precision,  it  will  be  found  much  easier  to 
compute  the  hyperbolic  PI  or  T  of  a  composite  line  than  to  compute  the 
merger  fl  or  T.  In  all  the  examples  given  in  this  paper  the  equiva- 
lent n  and  T  of  the  various  composite  lines  considered  have  both  been 
derived  hyperbolicallyi  but  have  also  been  checked  by  the  merging 
process. 

•  "The  Equivalence  of  Triangles  and  Three-Pointed  Stars  in  Conducting 
Networks,"  A.  E.  Kennelly,  Electrical  World  and  Engineer,  Vol.  34,  No.  12, 
Sept.  16,  1899,  pp.  413-414. 


Digitized  by  VjOOQIC 


44 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


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Figure  6.    Composition  of  two  sections  with  the  same  suige-resistanoe 
but  with  different  attenuation-constants. 

Equivalent  D. 

In  order  to  oompnte  hj^rbolically  the  equivalent  n  of  the  composite 
line  AD  (Figure  6)  we  proceed  as  follows: 

Ground  either  end  of  the  composite  line  AD,  say  the  end  D.  Assign 
the  junction-angle  0^  at  BG.  Then  the  angle  subtended  by  the  com- 
posite line  at  A  will  be  3^  =  ^^  -f  ^s  hyps.  The  sending-end  resistance 
of  the  composite  line  at  A  is,  by  (12)  and  (37), 

BgA  =  zi  tanh  8^  ohms  (38) 

=  1,000  tanh  3  =  995.055  ohms. 

Ggjt  =  l/SgA  =  yi  ooth  8^  mhos  (39) 

=  0.001  X  coth  3  =  10.049,7  X  10"*  mha 


Digitized  by  LjOOQlf 


KZNNELLY.  —  EQUIVALENT   CIRCUITS   OF   COMPOSITE   LINES.       45 

Then  the  architraye  resistance  AD  of  the  composite  fl  will  be: 

p"  =  zi  sinh  8^  ohms  (40) 

=  1,000  sinh  3  =  10,017.87  ohms, 
j/'  =  l/p"  =  0.998,212,5  X  10"*  mho. 

The  conductance  /'^  of  the  leak  at  A  is,  by  (20), 

g'\  =  yi  coth  8^  -  y"  mho  (41) 

=  9.051,49  X  10-*  mho. 

K  we  ground  the  composite  line  at  A  instead  of  at  D,  the  angle  sub- 
tended by  the  whole  line  at  D  will  be  Si,  =  ^i  +  ^i  =  5^.  The  archi- 
traye resistance  DA  will  be  the  same  as  that  given  in  (40).  The 
sending-end  resistance  Bgj,  and  conductance  Ggj,  will  be  identical  with 
Bg^  and  GgA  respectively,  by  (38)  and  (39) ;  so  that  the  leak-conduct- 
tance  </'i>  at  D  will  be  identical  with  ^\  by  (41).  This  completes 
Uie  hypo-bolic  Fl,  ADGIG  of  the  composite  line. 

Equivalent  T. 

To  find  the  hjrperbolic  equivalent  T  of  the  composite  line  AD  (Figure 
6),  free  the  line  at  one  end,  say  D.  Then  the  angle  subtended  by  the 
line  at  A  will  be,  as  before,  8^  =  ^i  +  6t  hyps. 

The  sending-end  resistance  of  the  line  at  A  will  be,  by  (4), 

B^^  =  z  ooth  S^  ohms  (42) 

=  1,000  coth  3  =  1,004.97  ohms. 

The  conductance  of  the  leak  OG  is,  by  (17), 

/  =  y  sinh  8^  mhos  (43) 

'  =  0.001  sinh  3  =  10.017,87  X  lO"*  mhoa 

and  its  resistance  is 

^  =  1//  =  99.821,25  ohms. 

The  resistance  of  the  AO  branch  is,  then,  by  (18), 

P  ^Bf^-lX  ohms  (44) 

=  1,004.97  -  99.821  =  905.149  ohms. 

Similarly,  if  we  free  the  composite  line  at  A,  instead  of  at  D,  the  angle 
subtended  by  the  line  at  D  will  be  8j).     As  before,  82,  =  ^2  +  ^i  =  K 


Digitized  by  VjOOQIC 


46  PROCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 

hyps.  The  sending-end  resistance  offered  by  the  Uoe  at  D  will  then 
be,  by  (4)  and  (42),  identical  with  that  foand  previously  at  A.  The 
condactance  of  the  leak  will,  by  (17)  and  (43),  be  the  same  as  that 
found  firom  A.  Finally,  the  resistance  of  the  DO  line-branch  will,  by 
(18)  and  (44),  be  identical  with  that  of  the  AO  branch  (905.149-). 
This  completes  the  T  of  the  composite  line. 

"We  may  infer  from  the  above  reasoning,  and  it  may  be  readily  dem- 
onstrated formally,  that  when  a  composite  line  is  composed  of  sections 
differing  in  linear  constants,  but  having  the  same  surge-impedance,  the 
angle  subtended  by  the  whole  line  is  the  same  at  either  end,  and 
whether  the  distant  end  be  freed  or  grounded.  Consequently  the 
equivalent  n  and  T  of  the  composite  line  will  be  symmetrical  That 
is,  the  two  leaks  of  the  n  are  equal  and  the  two  line  branches  of  the  T 
are  equal 

CJonversely,  it  follows,  fix)m  equations  (21)  to  (24),  that  any  com- 
posite line  made  up  of  sections  differing  in  attenuation  constant,  but 
with  the  same  surge-impedance,  may  be  replaced  by  an  equivalent 
single  line  of  uniform  attenuation  and  linear  constants. 

Third  and  General  Case.    Sections  with  Different  Surge- Impedances, 

Let  a  section  AB  of  100  km.  (Figure  7)  be  connected  to  a  section  CD 
of  300  km.,  and  let  their  respective  linear  constants  be  as  follows: 

n  =  20  ohms/km. ;  ^i  =  20  X  10^  mho/km. 
r,  =  10  ohms/km. ;  g^  =  2.5  X  10"*  mhoAm. 
fix)m  which 

tti  =  0.02  hyp/km. ;  ^i  =  2  hjrps ;  Zi  =  1,000  ohms ; 
o,  =  0.005  hyp/km. ;  B^  =  1.5  hyps ;  Zt  =  2,000  ohms, 

so  that  the  surge-resistance  of  the  two  sections  are  unequal  It  follows 
that  the  angle  subtended  by  the  composite  line  will  differ  at  the  two 
ends,  and  will  also  differ  according  to  whether  the  distant  end  is  fi^ed 
or  grounded. 

Equivalent  11. 

Let  us  ground  the  end  As  of  the  composite  line  AsDs  (Figure  7). 
Then  by  formula  (12),  the  sending-end  resistance  at  B  of  the  section 
BA  grounded,  will  be 

-Bp*  =  «itanh^  ohms  (45) 

=  1,000  tanh  2.0  =  964.026,5  ohms. 


Digitized  by  VjOOQIC 


KlINNELLT.  —  EQUIVALENT  CIRCUITS   OP   COMPOSITE   LINES.       47 


The  angle  of  the  section  AB,  at  its  end  B,  is  3^  «  2  hyps.  At  the 
junction  BC,  however,  the  line-angle  changes  abruptly,  owing  to  the 
change  in  sarge-iesistanoe,  and  at  C,  just  across  the  junction  it  is 

Sc  =  tanh-^  (^  tanh  ^i^  =  tanh"^  (^\  hypa  (46) 


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FiGUBE  7.    Composition  of  two  sections  of  different  surge-resistances 
and  different  attenuation-constants. 

That  is,  the  hyp-tangent  of  the  new  angle  is  the  ratio  of  the  sending-end 
resistance  at  B  to  the  surge-resistance  of  the  new  section  CD.    In  this 

8c=  tanh-^  (^^ty^)  =  **^"'  0.964,026,5 ; 

or,  by  tables  of  hyperbolic  tangents,  8c "«  0.525,608  hyp.  We  mark 
tWs  angle  opposite  to  C  on  the  line  AjDi  (Figure  7).  The  angle  sub- 
tended at  Ds  by  the  composite  line  is,  therefore, 


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48  PROCEEDINGS   OF   THE  AMERICAN  ACADEMY. 

5^  =  ^,  +  Sc  =  2.025,608  hyps. 

The  sending-end  resistance  of  the  grounded  composite  line  is  then, 
at  Da,  by  (12),  (37),  (38),  and  (45), 

RgD  =  *2  tanh  8 J,  ohms  (47) 

=  2,000  tanh  2.025,608  =  1931.58  ohms, 

and  the  sending-end  conductance, 

GffD  =  ^t  coth  8p  =  l/BgD  mhos  (48) 

=  0.000,517,71  mho. 

The  formula  for  finding  the  architrave  resistance  of  the  equivalent  n 
of  the  line  AD  is 

p'  =  Zi  sinh  Sx,  •  — ~TrY  ohms  (49) 

cosh  2  0 
=  2,000  sinh  2.025,608  X  — .    .  r.^^^. 
'  *  cosh  0.525,608 

=  24,553.55  ohms 
and  /'  =  1 V  =  0.407,273  X  10"*  mho. 

Formula  (49)  differs  from  the  corresponding  formula  (40)  of  the  pre- 
ceding case  by  the  application  of  the  ratio     ' ,  ^^  or  the  ratio  of  the 

cosines  of  the  line-angles  across  the  junction  BC. 

The  formula  for  finding  the  conductance  of  the  leak  at  D  is,  as  before 
(20)  and  (41), 

^'n  =  G,n  -  /'  =  l/B,n  -  /'  mhoS  (50) 

=  4.769,785  X  10"^  mho. 

In  order  to  complete  the  equivalent  D  of  the  line  AD  hyperbolically, 
we  must  repeat  the  above  process  from  the  opposite  end,  by  grounding 
the  end  Di,  as  shown  at  AiDi  (Figure  7).  The  line  angle  at  C  is  Sc  = 
1.5  hyps.     Across  the  junction  BC  this  angle  changes  suddenly  to 

S,  =  tanh-^(5^-^^)  hyps  (51) 

=  tanh-'  1.810,296. 

This  involves  at  first  sight  an  impossible  result ;  but  in  all  cases  of  a 
hyperbolic  tangent  greater  than  unity,  we  may  resort  to  the  following 
formulas: 


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GooQie 


KENNELLY.  —  EQUIVALENT   CIRCUITS   OF   COMPOSITE    LINES.       49 


sinh  la^±j-]=^±  jooshar^ 

oosh  [a:±jj-\=±  jsinh  x 
\  J 

tanh  (  ^  ±  i  -  )  =  ooth  x 
coth  (  ^  ±  i- j  =  tanha? 


nameric.  (52) 


We  thos  obtain 


and 


3.-^2  =  ^*  A— i;—) 

=  coth-^  1.810,296 
=  0.621,818  hyp 

8^  =  0.621,818 +i|  hyp. 


hyps  (53) 


This  difficulty  with  seemingly  impossible  antitangents  or  antiootangents 
is  not  enooantered  in  the  A.  G.  case. 

We  inscribe  this  valae  of  S^  opposite  B  on  the  line  AD.    The  angle 
subtended  by  the  whole  line  at  A  will  then  be 


,ir 


^1  +  8*  =  8^  =  2.621,818  +ir  hyps- 

The  sending-end  resistance  of  the  groonded  composite  line  is  then  at 
Ai,  by  (12),  (37),  (38),  and  (47), 

BgA  =  ^1  tanh  3^  ohms  (54) 

=  1,000  tanh  (2.621,818  +i^  J 

=  1,000  coth  2.621,618  =  1,010.64  ohms, 

and  the  sending-end  conductance,  as  in  (48), 

G^^  =  yi00th8^ 

=  yi  coih  {  2.621,818  +  i^  j 

=  0.001  tanh  2.621,818  =  9.894,966  X  10-*  mho. 

The  architrave  resistance,  as  in  (49),  is 

VOL.  XLV.  —  4 


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50  PROCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 

p"  =  zi  sinhS^  •  — r^  ohms  (55) 

=  1.000  eoBh  2.621.818.  ^j^^|yA_    . 

=  24,553.55  ohms 
and  y"  =  1/p"  =  0.407,273  X  10-*  mho. 

The  oondactanoe  of  the  11  leak  at  A  is,  as  in  (50), 

=  9.487,693  X  10"*  mha 

Equivalent  T. 

To  oompnte  the  equivalent  T  of  the  composite  line  AD  (Fignre  7), 
free  the  line  at  one  end,  say  Dg,  and  find  the  sending-end  resistance  at 
C  in  this  condition.    It  is,  by  (4),  (36),  and  (42), 

=±=  2,000  coih  1.5  =  2,209.59  ohms. 

The  line-angle  changes  abruptly  at  the  junction  BG  from  8c  =  1.5  to 
S3  =  0.487,935  hyp,  by  the  condition 

&s  =  coth-^  (^^-^)  =  co^-^  (^)  typs  (56) 

=  coth-^  2.209,59  =  0.487,935  hyp. 

The  line-angle  at  the  end  A,  is  thus  ^1  4-  8^  =  2.487,935  hyps. 
The  sending-end  resistance  at  A«  is  finally,  by  (4), 

B/A  =  zi  coth  8^  ohms  (57) 

=  1,000  coth  2.487,935  =  1,013.897  ohma 
The  conductance  of  the  leak  OG'  is,  by  (43), 

/  =  yi  sinh8^  •  ^^  mhos  (58) 

=  0.001  X  sinh 2.487,935  X      f^^,!l^^^^  =  12.537,3  X  lO"*  mho. 

COSn  0.48 7, 935 

The  resistance  of  the  leak  OG'  is,  therefore,  ^  =  1//  =  79.762  ohms. 
The  resistance  of  the  AO  branch  is  then,  by  (18)  and  (44), 


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KENNELLT.  —  EQUIVALENT   CIRCUTTa  OP   COMPOSITE   LINES.        51 

p^^Bf^  —  Bf  ohms  (59) 

=  1,013.897  -  79.762  =  984.135  ohms. 

In  order  to  complete  the  eqaivalent  T  of  the  line  AD,  we  must  repeat 
the  above  process  from  the  opposite  end,  by  freeing  the  end  A,  as  shown 
at  A4D4  (Figure  7).  The  line-angle  at  B  is  S^  =  2.0.  Across  the  janc- 
tion  BG  this  angle  changes  suddenly  to 

Sc  =  ooth-("-i^')  hyps  (60) 

=  ooth-'  (^1^)  =  ooA-  0.518,657,5. 

In  order  to  avoid  an  impossible  operation,  apply  formula  (52) 
Sc  -i 5  =  tanh-^ 0.518,657,5  =  0.574,50  hyp 
Sc  =  0.574,5 +i|  hype. 
The  line-angle  at  the  end  D^  is  thus  O^  +  ^c^^  2.074,5  +  j^  hyps. 
The  sending-end  resistance  at  D4  is  finally,  by  (4)  and  (57), 
Rfj^  =  zt  coth  82,  ohms  (61) 

=  2,000  coth  (  2.074,5  +i| )  =  2,000  tanh  2.074,5  =  1,937.873 

^  ^  ohms. 

The  conductance  of  the  leak  06'  is^  therefore,  by  (43)  and  (58), 
^  =  y,  sinh  hj, '  — 1-~  mhos  (62) 


=  0.001  sinh  ^2.074,5  +j^\ 


cosh  2.0 


cosh 


^0.574,5 +i^) 


=  0.001  cosh  2.074,5  •  .??^,f:^,  =  12.537,3  X  lO"*  mho. 
^      smh  0.574,5 

The  resistance  of  the  leak  06'  is,  therefore,  B'  =  1//  =  79.762  ohms. 
The  resistance  of  the  DO  branch  is  then,  by  (18)  and  (59), 

p'  ^Bfn  —  B!  ohms  (63) 

=  1,937.873  -  79.762  ==  1,858.111  ohms. 

This  completes  the  T  of  the  composite  line. 


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52  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

It  may  be  inferred  from  the  preceding  reasoning  that  for  the  case  of 
a  composite  line  of  two  sections  with  different  surge-impedances,  the 
receiving-end  impedance  of  the  line  in  the  absence  of  r^eiving  instru- 
ments, which  is  the  architrave  of  the  line-FI,  has  the  same  value  from 
each  end  of  the  line.  The  leak  of  the  composite  line-T  has  also  one 
and  the  same  value,  computed  from  either  end.  Both  the  fl  and  the 
T  are,  however,  dissymmetrical.  Each  requires  two  separate  computa- 
tions and  line-angle  distributions,  one  from  each  end. 

Summary  qf  Two-Section  Formulas. 

If  we  expand  formulas  (40)  and  (49),  we  obtain  for  the  architrave  of 
the  composite  line  fl 

p"  =  zi  sinh  Ox  cosh  6^  +  z^  cosh  Ox  sinh  B^  ohms  (64) 

=  ^^-^  sinh  {0,  -f  6^)  +  ?^=-^  sinh  (Ox  -  ^,)  ohms  *  (65) 
=  zx  sinh  Ox   .  .  ^  ohms  (line  grounded  at  A)  (66) 


'c 


sinh  3, 
cosh3j| 


=  Z2  sinh  S/,  — y-j-  ohms  (line  grounded  at  A)  (67) 

=  Zi  sinh  62   .  y^  ohms  (line  grounded  at  D)  (68) 

=  Zx  sinh  8^  — r-r-  ohms  (line  grounded  at  D).  (69) 

Similarly,  if  we  expand  formulas  (58)  and  (62),  we  obtain 

/  =  yi  sinh  Ox  cosh  O2  +  y^  cosh  Ox  sinh  0^  mhos  (70) 

=  ^^^-y^  sinh  (Ox  -f-  ^,)  -h  ^-^^^  sinh  (^1  -  0^)  mhos  (71) 

=  yx  sinh  Ox   ,  .^  mhos  (line  freed  at  A)  (72) 

=  y^  sinh  hj,  — ^  mhos  (line  freed  at  A)  (73) 

=  yt  sinh  0^   .  .J^  mhos  (line  freed  at  D)  (74) 

=  yx  sinh  8^  — r-^^  mhos  (line  freed  at  D).  (75) 

*  Formulas  (64)  and  (65)  were  first  published  as  receiving-end  impedances 
of  a  two-section  composite  line  by  Dr.  G.  dl  Pirro.    See  Bibliography. 


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KENNELLY.  —  EQUIVALENT   CIRCUITS   OF   COMPOSITE    LINES.       53 

Single  Lines  Equivalent  to  a  Dissymmetrical  n  or  T. 

It  is  evident  that  formulas  (21)  to  (24)  apply  only  to  a  symmetrical 
n  or  T.  Moreover,  it  may  be  seen  that  no  single  smooth  and  uniform 
line  can  correspond  to  a  dissymmetrical  D  or  T.  This  means  that,  in 
general,  no  single  smooth  and  uniform  line  can  be  the  counterpart  of  a 
composite  line  having  sections  of  different  surge-resistance. '  But  if  we 
reduce  a  di8S3rmmetrical  fl  to  a  symmetrical  n  and  a  terminal  leak,  we 
may  apply  equations  (23)  and  (24)  to  transform  the  sjrmmetrical  fl  into 
an  equivalent  single  line.  It  follows  that  any  composite  line  may  be 
resolved  into  one  and  only  one  uniform  smooth  line  of  the  same  length 
with  a  leak  permanently  applied  to  one  end ;  or  to  an  infinitude  of  such 
single  uniform  smooth  lines  having  a  leak  at  each  end. 

Similarly,  the  T  of  a  composite  line  may  be  reduced  to  a  symmetrical 
T  plus  a  line-impedance  at  one  end.  By  the  use  of  equations  (21)  and 
(22),  we  may  substitute  a  single  smooth  uniform  line  for  the  symmetri- 
cal T.  Consequently,  any  composite  line  may  be  resolved  into  one  and 
only  one  uniform  smooth  line  of  the  same  length  with  a  line-impedance 
at  one  end ;  or,  to  an  infinitude  of  such  single  uniform  smooth  lines 
having  a  line-impedance  at  each  end. 

CoBiPosiTB  Line  with  Three  Sections  of  Different  Surge- 
Impedances. 

A  three-section  composite  line  is  indicated  in  Figure  8. 

AB  has  a  length  Lx  of  100  km. 
CD  "  "  is  of  300  km. 
EF     "         "      ^  of  50  km. 

The  respective  linear  constants  are 

n  =  20  ohms/km. ;  r,  =  10  ohms/km. ;  rg  =  25  ohms/km. 
^1  =  20  X  10"*  mho/km. ;  g^  =  2.5  X  lO"'  mhoAm. ; 

^»  =  4  X  10~'  mho/km. 
ai  =  0.02  hyp/km. ;  a,  =  0.005  hyp/km. ;  a.  =  0.01  hyp/km. 
tfi  =  2  hyps ;  6^  =  1.5  hyps ;  Bt  =  0.5  hyp. 
Zi  =  1000  ohms  ;  z^  =  2000  ohms ;  Zt  =  2500  ohms. 

Equivalent  fl.    First  Method. 

We  proceed  to  compute  the  equivalent  n  of  the  composite  line  AF 
in  the  same  manner  as  in  connection  with  Figure  7.  Ground  the  end 
Fl  and  develop  the  line-angles  towards  Ai.    As  before. 


8„  =  tanh-^  [^^         and  8^  =  tanh"^  {j^\       hyps. 


(76) 


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64 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


M^m  IPOO- 


*B 


\-« 


•X 


I? 


1:5^ 


••2 


AJ '-i^ Bjc  »*»  DJE&v  ^1  ' »-« — Bic_jLi:iiiiiEva^ 

^*       2^«  1000*'  ^.  sooo*        iH»Vr*       ^»        4^.1000*  ^.topo-      5.«m-** 


?:5  ?; 


44J47* 


O*2260«4x;o~^* 


O  O  G' 

Figure  8.    Composition  of  three  sections  of  different  surge-resistances. 


The  architraye  resistance  is  then,  following  (49), 

o"  =  z  sinh  8   x  ^^^^^  x  ^^^^^ 
*  "*      cosh  8^      coshSi, 

.^r.r.       1.  «  r^^  -«      cosh  2.158,924 
=  1000  cosh  2.567,48  X     .  ^  ^  .^j  .^   X 


ohms  (77) 
cosh  0.5 


sinh  0.567,48       cosh  0.658,923,6 
=  44,247  ohms. 

The  sending-end  resistance  at  A  is,  as  in  (47), 

BgA  =  zi  tanh  8^  ohms  (78) 

=  1,000  coth  2.567,48  ==  1,011.84  ohms 

The  conductance  of  the  n  leak  at  A  is,  as  in  (50), 

g'^  =  1/RgA -  1/p'  mhos.  (79) 


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KENNIXLY.  —  EQUIVALENT   CIRCUITS   OP    COMPOSITE    LINES.       65 

In  order  to  complete  the  n,  we  ground  the  line  at  As  (Figure  8),  and 
develop  the  line-angles  towards  F^.    The  architrave  resistance  is  then 

,t  •  u  ©   v^  ^sh  8u      cosh  8^  ,        .  _  ^v 

p   =  z^  sinh  hw  X  — r-5-  X  — r-^  ohms  (80) 

'^         •  coshS^     cosh  8c 

=  44,247  ohms. 

The  sending-end  resistance  at  F  is 

i?,,=  2r,  tanh8,  ohms  (81) 

=  2,500  tanh  1.526,83  =  2,274.71  ohms. 
Again, 

/'^=:  \IB,,-  1/p"  mhos.  (82) 

Equivalents.    Second  Method. 

An  alternative  method  of  arriving  at  the  architrave  resistance, 
which  we  may  call  the  second  method,  is  by  following  (66)  and  (68). 
Grounding  at  As,  we  have 

and,  grounding  at  Fi, 

=  44,247  ohms. 

Equivalent  T.    First  Method. 

"We  proceed  to  compute  the  equivalent  T  of  the  composite  line  AF 
m  the  same  manner  as  the  T  in  Figure  7.  Free  the  end  Fs  and  develop 
the  line-angles  towards  A«.    As  before, 

8^  =  coth-*  f^\        and  8^  =  coth"*  C^^  hyps.  (85) 


The  T  leak  conductance  is  then,  following  (58)  and  (75), 

cosh  8^ 
cosh8x> 
cosh  1.888,071  cosh  0.5 


^=«™'"-^-^.         "^w 


=  0.001  sinh  2.519,86 


cosh  0.519,860     cosh  0.388,071 
=  19.2016  X  10-*  mho 
If  =  52.079  ohms. 


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56  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

The  sending-end  resistance  at  At,  as  before,  is 

Ji^^=,zi  cothS^  ohms  (87) 

=  1,013.04  ohms. 

The  AO  line  branch  is  therefore  Ru—  R  =  960.961  ohms. 

Repeating  the  process  from  A4  towards  F4,  we  have  for  the  T  leak 
condactance,  as  in  (80), 

The  sending-end  resistance  at  F  is  likewise 

R/F  —  s^  coth  h,  ohms  (89) 

=  2.500  tanh  1.533,091  =  2,277.39  ohms, 
from  which  the  resistance  of  the  line  branch  FO  followa 

Equivalent  T.    Second  Method. 

The  second  method  of  arriving  at  the  T-leak  condactance  is  by  fol- 
lowing (83)  and  (84).    Freeing  at  A4,  we  have 

,  •  1  /»      sinh  S^     sinh  8^  ,        ,_ . . 

^  =  y'  «"^<''  •  iSETc  •  ^Skh.  '^•^  <*^> 

and  filing  at  F„  after  developing  the  line  angles,  we  have 

,  ...       sinh  8c     sinh  8^  ,        . 

^  =  ^»  ^^^'  '  riih^  •  sinhi;  "^^  (^^> 

Composite  Line  ofn  Sections. 

To  compute  the  equivalent  fl  of  a  composite  line  of  n  saccessive 
sections,  ground  the  line  at  the  A  end  and  develop  the  line-angles 
towards  the  opposite  end,  following  the  process  of  (76).  Find  the 
architrave  impedance  according  to  formula  (80)  or  (83).  This  may  be 
regarded  as  formula  (19)  modified  by  the  application  of  (n  —  1)  ratios 
of  cosines  in  (80),  or  of  (n  —  1)  ratios  of  sines  in  (83).  The  opposite 
end  leak  admittance  will  then  be  the  sending-end  admittance  minm 
the  architrave  admittanoa  The  process  must  be  repeated  afber  ground- 
ing the  line  at  the  distant  end  and  developing  line-angles  towards  A. 

To  compute  the  equivalent  T,  free  the  line  at  the  A  end  and  develop 
the  line-angles  towarids  the  opposite  end,  following  the  process  of  (85). 


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KENNELLY.  —  EQUIVALENT   CIBCOTTS   OP   COMPOSITE   UNES.       57 

Pmd  the  T-leak  admittance  by  following  formula  (88)  or  (90).  This 
may  be  r^arded  as  formula  (17)  modified  by  the  application  of  n— 1 
ratios  of  cosines  in  (88),  or  of  n— 1  ratios  of  sines  in  (90)  ;  that  is,  one 
such  ratio  for  each  junction.  The  opposite-end  line-branch  impedance 
will  then  be  the  sending-end  impedance  minus  the  leak  impedance. 
The  process  must  be  repeated  after  freeing  the  line  at  the  distant  end 
imd  developing  line-angles  towards  A. 

One  complete  equivalent  circuit,  say  the  n,  of  a  composite  line  of 
n  sections  calls  then  for  the  determination  n— 1  line-angles  first  in  one 
direction  and  then  in  the  other.  The  formulas  are  well  adapted  to 
logarithmic  computation.  If,  however,  only  the  receiving-end  impe- 
dance of  the  composite  line  is  required,  then  we  need  only  develop  the 
line  Ingles  in  one  direction  over  the  line  so  as  to  apply  one  of  the 
architrave  formulas,  and  neglect  the  pillars  of  the  fl. 

Loaded  Gompositb  Lines. 
Dejinittans, 

Loads  in  a  line  may  be  either  regular  or  casual  Uvular  loads  are 
such  as  are  applied  at  r^ular  intervals,  in  order  to  improve  the  cur- 
rent delivery  on  telephone  lines.  Casual  loads  are  of  an  irregular  or 
incidental  character,  such  as  might  occur  at  section-junctions  or  at 
the  ends  of  a  composite  line.  In  the  former  case  they  would  be  inter- 
mediate casual  loads,  and  in  the  latter  case,  terminal  casual  loads. 
Only  easual  loads  will  be  here  discussed ;  because  it  is  easy,  with  the 
aid  of  formulas  already  known,  to  substitute  an  equivalent  smooth 
unloaded  line  for  any  uniformly  loaded  line. 

Loads  may  also  be  divided  into  two  classes;  namely,  (1)  those 
applied  in  series  with  the  line,  or  impedance  loads,  such  as  coils  of 
impedance  or  resistance,  and  (2)  those  applied  in  derivation  to  the  line, 
or  leak  loads. 

Intebiiediate  Impedance  Load& 

The  case  of  an  intermediate  impedance  load,  of  100  ohms,  inserted 
at  the  junction  BG  in  the  composite  line  last  considered,  is  presented 
in  Figure  9.  The  system  differs  firom  that  of  Figure  8  only  in  the 
additioh  of  this  load. 

Equivalent  fl.     First  Method. 

To  compute  the  equivalent  n,  A''F'GG  (Figure  9),  hyperbolically, 
ground  the  line  at  one  end,  say  as  at  Fi,  and  develop  the  line-angles 
towards  Ai.  The  only  change  in  this  process  affected  by  the  load  is  at 
the  junction  GB.    The  sending-end  impedance  at  G  is 


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58 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


Rgo  =  zt  tanb  8(7  ohms  (92) 

=  2,000  tanh  2.158,924  =  1,947.385  ohms. 

Consequently,  if  o-  is  the  impedance  of  the  load  BG  in  ohms,  the 
sending-end  resistance  at  B  is 


I^gB  =  o-  -^  Z2  tanh  8(7 

=  100  +  1,947.385  =  2,047.385  ohms, 


ohms  (93) 


K^t 


^mW9tr 


I  * 


i4        %i  4 

Z,  •  lOOO* 


f  i 


•#wft 


i  3 


^  I 


•«■« 


^«WM- 


«l.« 


II, 


I. 


??  ? 


2      ? 


1^ « 


A- 

f  J  744- J* 

jr* 

O'tlVKM'*. 

r 

*• 

t 

M 

!* 

« 

O 

w 

4 

5 

9 

X 

". 

•• 

•* 

c 

» 

C 

1. 

Figure  9.    Three-section  composite  line  with  an  intermediate 
impedance  load. 


hyps  (94) 


and  the  new  line-angle  at  B  is 

=  tanh-(H^ 

Having  established  the  angle  of  the  whole  line  at  Ai,  the  architrave 
impedance  follows  by  formula  (77)  without  further  change.  The 
A-leak  is  also  obtained  by  formulas  (78)  and  (79).  In  order  to  obtain 
the  F-leak,  and  complete  the  n,  the  line  is  grounded  at  the  other  end 
as  at  As  and  the  line-angles  are  developed  towards  Fs.    At  C,  we  have 


047.385 
000 


)=0. 


534 +i^  hyp. 


Digitized  byLaOOQlC 


KENNEUT.  —  EQUIVALENT   CIRCUITS   OF    COMPOSITE   LINES.      69 

Formulas  (80),  (81),  and  (82)  then  apply  without  change. 

Equivalent  n.    Second  Method, 

The  altematiye  method  for  computing  the  arohitraye  resistance  of 
the  line  when  grounded  at  At,  and  developed  in  angles,  is 

«''  — ^  «;,,k/j     si^^D    sinhSj.    E,o  i^„    /q^n 

'   =^'^°*^^^'^Shi;'s"Sh8-/:«r.  ohms,  (95) 

and  when  grounded  at  Fi  it  is 

That  is,  the  effect  of  the  load  i^  to  increase  the  architrave  impedance 
in  the  ratio  of  the  change  of  sending-end  impedance  across  the  load. 
In  (95)  this  ratio  is  1,064.026/964.026,  and  in  (96)  it  is  2,047.385/ 
1,947.385. 

Equivalent  T.    First  Method. 

To  compute  the  equivalent  T  of  the  loaded  line  in  Figure  9,  free  the 
line  at  one  end,  as  at  Fg,  and  develop  the  line-angles  towards  As,  as  in 
(85).  The  only  change  effected  by  the  load  is  in  the  angles  at  and 
beyond  B.    The  sending-end  impedance  at  C  is 

B^^ZtOothSo  ohms  (97) 

=  2,000  coth  1.888,071  =  2,093.82  ohms. 

The  sending-end  impedance  at  B  is,  therefore, 

^/i  =  0-  +  Zt  coth  So  ohms  (98) 

=  100  +  2,093.82  =  2,193.82  ohms.  (98) 

The  new  line-angle  at  B  is  then 

8,  =  coth-*r^)  hyps  (99) 

=  <^^"{^^)  =  0-^92,025  hyp. 


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60  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

The  T-leak  admittance  is  now 

,  .  ,  5,      cosh  Bo    cosh  8,    G/c  i       /-  ^^v 

^  =  ^^«^^^^^-^^^/^^shy/^  mhos  (100) 


=  0.001 -sinh  2.492,025 


cosh  1.888,071        cosh  0.5         2,193.82 


cosh  0.492,025  cosh  0.388,071   2,093.82 
=  19.815  X  10-»  mho. 

Formula  (87)  then  applies  without  change. 

Repeating  the  process  from  the  opposite  end  of  the  line,  as  at  A4F4, 
we  have 

,  .  ,  «,      cosh  Sj,    cosh  h^    Gf^  1       /  ^  V 

=  19.815  X  10"*  mho. 

Formula  (89)  then  applies  without  change. 

The  efifect  of  the  load  on  the  T-ieak  admittance  formulas  (86)  and 
(88)  is  to  alter  them  in  the  ratio  of  the  impedances  or  admittances 
across  the  load,  applying  the  said  ratio  in  such  a  manner  as  to  increase 
the  result  in  the  direct-current  case. 

Equivalent  T.    Second  Method, 

Formulas  (90)  and  (91)  of  the  alternative  method  are  not  altered  by 
an  intermediate  impedance  load,  after  the  line-angles  have  been  prop- 
erly assigned. 

Equivalence  0/  Alternating-Current  Tran^ormers  to  Impedance  Loads. 

It  may  be  observed  that  since  the  insertion  of  a  transformer  into  a 
circuit,  as,  for  example,  the  insertion  of  a  "  repeating-coil "  into  a  tele- 
phone circuit,  is  theoretically  equivalent  to  the  insertion  of  impedance 
into  the  circuit  without  rupture  of  continuity,  all  cases  of  line  trans- 
formers are  capable  of  being  dealt  with  by  substituting  for  such  trans- 
formers their  equivalent  intermediate  impedance  loads.^ 

Terminal  Impedance  Loads. 

A  terminal  impedance  load  is  likely  to  present  itself  in  a  composite 
line,  owing  to  the  presence  of  terminal  apparatus.  The  architrave  im- 
pedance of  a  composite  line  n,  computed  without  any  terminal  load, 
can  only  represent  the  receiving-end  impedance  of  the  line  when  the 

•  "On  the  Predetermination  of  the  Regulation  of  Alternating-Current 
Transformers,"  A.  E.  Kennelly,  Electrical  World  and  Engineer,  Sept.  2,  1899, 
Vol.  34,  p.  343. 


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KENNELLY.  —  EQUIVALENT   CIRCUITS   OF    COMPOSITE    UNES.       61 

reoeiying  apparatus  is  short-circaited.  For  example,  in  the  case  of 
Figure  4,  if  we  short  circuit  the  receiver  Zr  the  receiving-end  impe- 
dance of  each  line  is  6,736.96/156"  5V  15"  ohms.  With  the  receiver 
Zr  inserted,  the  receiving-end  impedance  is  considerably  changed,  and 
this  is  the  condition  met  with  in  practice.    By  applying  half  the  im- 


1    100- 


^•2 


;:5 


■uw 


F, 


\«  »ooo- 


^mfiOOO*' 


«.« 


loo"  lA 


e,«g 


e..iy 


1 


\m  1000* 


Z^mZOOO" 


♦M»90l" 

CO 

a* 

5 

,  HJto-96ro«J«5r  _ 

o■^osi^^  x  io"*» 
:2                       f 

W                                            O 

^                                 o 
8 

X 

o 

< 

0-449)nxilV 

3 

to 
•1 

Figure  10.    Three-section  composite  line  with  a  terminal  impedance  load. 

pedance  of  the  receiver  as  a  terminal  load  to  the  line,  the  architrave 
of  the  new  equivalent  n  gives  the  receiving-end  impedance  with  the 
receiver  included.  If  this  is  the  result  sought,  it  becomes  unnecessary 
to  compute  the  values  of  the  leaks  of  this  n. 

Equivalent  d.     First  Method, 

Figure  10  represents  the  three-section  composite  line  of  Figure  8, 
with  a  terminal  impedance  of  100  ohms  applied  at  A.    To  compute 


Digitized  by  VjOOQIC 


62 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


the  equivalent  ri  of  the  loaded  line,  ground  F,  as  at  Fi.  Develop  the 
line-angles  towards  A  in  the  usual  way.  No  change  from  the  corre- 
sponding conditions  of  Figure  8  occurs  until  after  we  have  reached  8^. 
We  then  have 

RgA  =  Zx  tanh  5^  ohms 

=  1,000  coth  2.567,48  =  1,011.607  ohms, 

and  if  (T  he  the  impedance  of  the  terminal  load  at  A^ 

BfMi  ^fr  +  zi  tanh  8^  ohms  (103) 

=  ^0  tanh  8^  ohms  (104) 

=  1,111.84  ohms, 

where  a^  is  the  apparent  surge-impedance  of  the  line  at  A^ ;  or 


Zo  =  zi-j-  a  coth  8^ 

=  1,098.829  ohms. 
The  architrave  resistance  is  then,  following  (77), 

,,  •  1.  o      cosh  8c    cosh  8^ 

=x  48,619.7  ohms. 
The  A-leak  of  the  n,  as  in  the  case  of  Figure  (8),  is 


ohms  (105) 
ohms  (106) 


ohms  (107) 


mhos.  (108) 


To  complete  the  n,  we  ground  the  loaded  line  at  A,  as  at  A^Fji,  and 
develop  the  line-angles  towards  F,  commencing  with 


8^  =  tanh 


■ii) 


hyps  (109) 


=  tanh-^  (^)  =  0.100,336  hyp. 
The  architrave  impedance  is  then 

ff  .  t  e      cosh 82,    cosh 8^    cosh  0        ,        ,,,.v 

p"  =  ..8mhS,.3^^^.^3^^.^3^^     ohms  (110) 

=  48,619.7  ohms. 

The  F-leak  is  then  computed  as  in  (82). 


ligitized  by  VjOOQIC 


E£NN£LX.T.  —  EQUIVALENT   CIRCUITS   OF   COMPOSITE    LINES.      63 

Equivalent  n.    Second  Method. 
The  alternatiye  method  gives 

„  sinhS^    siDhSp    sinhS,  ,         .^.^^ 


//  -1/1      sinhfic    sinhS^    Rgj^        ,         /<<ft\ 


with  the  line  groiinded  at  A^  and 

p"  =  Z9  sinh 
with  the  line  grounded  at  F. 

Equivalent  T. 

To  arrive  at  the  equivalent  T  of  a  composite  line  loaded  with  a  ter- 
minal impedance,  all  that  is  necessary  is  to  find  the  T  of  the  same  line 
unloaded,  by  preceding  formulas,  and  then  to  add  the  terminal  impe- 
dance to  the  proper  line-branch  of  this  T. 


ac  Dg 


^^^»w<¥»M  ^B^— 1^1^^— a^M— £L» 


4tM7' 


-P  it.M-1' 


^»VWWV»AAjfci^—— —— lllfc  lip      ^5^(6  •S*' 


^P  Pi    ^,?C^       ^   45;6fO* 


■^S SE  y..i«r,^  Hin- 


FiGiTRB  11.    Diagram  showing  the  influence  of  the  location  of  an  impedance 
load  on  the  receiving-end  resistance  of  a  three-section  composite  line. 

Influence  op  Location  op  an  Impedance  Load  on  the  RECEiviNa- 
End  Impedance  op  a  Composite  Line. 

It  has  been  shown  in  a  preceding  paper  that  if  a  single  smooth  uni- 
form line  is  terminally  loaded  with  a  given  impedance,  the  change  in 
the  receiving-end  impedance  due  to  the  load  is  the  same,  whichever 
end  of  the  line  the  load  may  be  applied  to ;  i.  ^.,  whether  the  load  is 
applied  at  the  sending  or  at  the  receiving  end.  In  the  case  of  a  com- 
posite line,  however,  this  proposition  generally  Mh.  The  effect  of  a 
resistance  coil  of  100  ohms  on  the  receiving-end  resistance  of  the  three- 
section  composite  line  above  discussed,  is  shown  in  Figure  11.    With- 


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64  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

out  the  load,  the  receiving-end  resistance  of  the  line,  or  the  architrave 
of  its  equivalent  n,  is,  by  Figure  8,  44,247  ohms.  If  the  load  is  added 
at  the  A  end  of  the  line,  the  receiving-end  resistance  becomes  48,619.7 
ohms ;  but  if  added  at  the  F  end,  it  is  only  46,192.  When  the  same 
coil  is  inserted  as  an  intermediate  load,  its  influence  on  the  receiving- 
end  resistance  is  not  so  great.  In  A.  G.  composite  lines,  the  opportuni- 
ties for  such  variations  are  more  marked.  In  all  cases,  however,  the 
application  of  a  terminal  impedance  cr  to  a  line  (single  or  composite), 
increases  the  receiving-end  or  architrave  impedance  of  that  line  in  the 

ratio  — ^p— ;  where  Rg  is  the  sending-end-impedance  of  the  line  at 

the  loaded  end  before  the  load  is  applied.  This  is  true  whether  the 
loaded  end  is  made  the  sending  or  receiving  end  of  the  circuit  For 
single  lines,  Rg  has  the  same  value  at  either  end,  and  therefore  the 
ratio  of  increase  in  receiving-end  impedance  is  the  same  at  whichever 
end  of  a  single  line  the  load  o-  is  applied ;  whereas,  for  composite  lines, 
we  have  seen  that  Rg  is  dififerent,  in  general,  at  the  two  ends. 

Intermediate  Leak  Loads. 

Equivalent  D.    First  Method, 

Suppose  a  leak  load  to  be  applied  at  a  junction  between  sections 
such  as  at  DE  (Figure  12).  We  proceed  to  compute  the  equivalent  n 
of  the  loaded  composite  line  by  grounding  one  end,  as  at  Fi.  We 
develop  the  line-angles  towards  Ai.  On  arriving  at  E  we  have 
R,E  =  zi  tanh  0^  =  1,155.292  ohms.  Hence  G>^  =  I/R^e  = 
8.655,82  X  10'^  mho.  To  this  sending-end  admittance  we  add  the 
admittance  y  of  the  leak ;  so  that  the  sending-end  admittance  at  D, 
including  the  leak,  is 

Ggj,=^y+  GgM  mhos  (113) 

=  13.655,82  X  10-*  mho. 

Consequently  the  sending-end  resistance  at  D,  including  the  leak,  is 

RfD-l/GgD  ohms,  (114) 

=  732.289  ohms. 
The  line-angle  at  D  is  then 

8^  =  tanh-^r^)  hyps  (115) 

=r  0.383,964  hyp. 
The  remaining  line-angles  are  found  in  the  regular  way. 


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KENNELLY.  —  EQUIVALENT   aRCUITS   OP   COMPOSITE    LINES.      66 

The  architraye  impedance  is  then 
p"  =  zi  sinh  8^ 


ooshSc     C08h8,  ^,         ohms  (116) 


MgD 


cosh  Bjg     cosh  Sj, 
=  60,240  ohms. 

The  A-leak  is  computed  regularly  from  (78)  and  (79), 


Stmt 


\m  lOCO' 


•B 


<^«  1  s 


-D 


Jj.iOOD-^. 


X^»20OO* 


^. 


I 


: 


<i.» 


^•1000* 


«.< 


I,,  woe' 


I 


Bin   4->^  D-E»i- 


I 


•T 

?!  I 


BO    h-»    DEV" 


fcoz^o" 


0-i66doix  10** 


A'- 


HV^U"  O  m9'19* 


Minixjo'* 


I 


Figure  12.   Composite  line  of  three  sections  with  intermediate  leak  load. 

To  complete  the  n,  ground  the  line  at  the  opposite  end,  as  at  As, 
and  develop  the  line-angles  towards  Fs,  in  the  same  manner  as  above. 
The  architrave  impedance  is  then 


"      ^   -;^k  *       coshfi^    ooshSj     Ego 


OM 


=  60,240  ohms. 


The  F-leak  is  computed  regularly  from  (81)  and  (82). 

VOL.  XLV.  —  5 


ohms  (117) 


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66  PROCEEDINGS  OF   THE   AMERICAN   ACADEMY. 

Equivalent  n.    Second  Method. 

In  the  alterDatiye  method  we  have  the  regular  formulas  (83)  and 
(84),  unchaDged  by  the  intermediate  leak  load. 

Equimlent  T.    First  Method. 

To  complete  the  equivalent  T,  free  one  end  of  the  line,  say  F,  as  at 
Fs  (Figure  12),  and  develop  the  line-angles  towards  At.  At  the  loaded 
junction  DE  we  have 

Gfj,^y+GyM  mhos,  (118) 

=  6.848,47  X  10-*  mho, 
and,  following  (114)  and  (115), 

8„  =  coth-^  (^\  hyps,  (119) 

=  0.928,914 +i^  hyp. 

The  remaining  line-angles  follow  regularly.  The  T-leak  conductance 
also  follows  from  (86)  without  change,  and  the  line-branch  AG  is  com- 
puted regularly  by  (18),  (57),  (59),  and  (87). 

To  complete  the  T,  free  the  other  end  of  the  line  as  at  Ai,  and  pro- 
ceed, as  above,  to  develop  the  line-angles  towards  F4.  The  T-admit- 
tance  must  then  conform  to  (88),  and  the  line-branch  impedance  FO 
to  (89). 

Equivalent  T.    Second  Method. 

The  alternative  method  of  arriving  at  the  T-leak  admittance  is  by 
following  (83)  and  (84).    Freeing  at  A4  (Figure  12),  we  have 

,  .  ,  ^      sinhSi,     sinhSjp     G/a  ,        ,,^^. 

^ =y«  '""^^^  •  SEES.  •  ^  •  ^        "^^  <i2<» 

and  similarly,  freeing  at  F4,  we  have 


Terminal  Leak  Loads. 

Equivalent  fl. 

To  arrive  at  the  equivalent  n  of  a  composite  line  loaded  with  a  termi- 
nal leak,  such  as  that  represented  at  AF  in  Figure  13,  first  compute 


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KENNELLT.  —  BQUIVALENT   aRCUlTS   OF   COBCPOSITE   UNES.      67 


the  equivalent  11  of  the  same  line  anloaded,  by  preceding  formulas,  and 
then  to  the  proper  leak  of  the  n  add  the  terminal  load  leak,  numerically 
in  the  D.  G.  case,  yectorially  in  an  A.  G.  case. 

Equivalent  T.    First  Method. 

To  compute  the  equivalent  T,  free  one  end  of  the  line,  say  F,  as  at 
Ft  (Figure  13),  and  develop  the  line-angles  towards  A.  We  commence 
with 


^ 


St»f0O0* 


if 


^•1000* 


l^.MMT    V 


j* ^ 


7.  •AMI*        c.>«B^       * 


15 


44247" 


O'tii004  ntOm 


9- 
t 


s 

i 


FiQUBB  13.    Composite  line  of  three  sections  with  terminal  leak  load. 

S,  =  coth-^  (^^  hyps  (122) 


.^ 


=  1.098,6 +i- hyps, 

where  y  is  the  admittance  of  the  load  in  an  A.  G.  case  or  conductance 
of  the  load  in  the  D.  G.  case  (mhos). 
The  T-leak  admittance  is  then 

,  .  ,  5,      cosh Sc     coshS,     coshO  ,       /-^«v 

flr'  =  vi  sinh  8^  •  — t--^  •  — r-^  •  — r-z-        mhos  (123) 
^       ^*  ^     cosh  8,     coshSx,     cosh  8^  ^      ^ 

=  41.066  X  10-»  mho, 
and  the  line-branch  impedance  AO  follows  at  once  from  (87). 


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68  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

To  complete  the  T,  the  line  is  freed  at  A,  as  at  A4  (Figure  13),  and 
the  line-angles  are  developed  toward  F.  We  then  have  for  the  sending- 
end  admittance  at  F, 

Gj,  =  yt  tanhS,  mhos.  (124) 

The  sending-end  conductance  at  F^^  including  the  leak  admittance 

Gft^  =  y  +  y,  tanh  8,  mhos.  (125) 

The  apparent  surge-admittance  y^  at  Fq  is  defined  by  the  condition, 

Gjg^  =  y^\^hh,  mhos,  (126) 

whence 

yo  =  y»  +  y  «>*  *^  ^^^^  (127) 

The  T-leak  admittance  will  then  conform  to 

and  the  line-branch  impedance  FO  follows  at  once  from  (89). 

Equivalent  T.     Second  Method. 

By  the  altematiye  method,  the  T-leak  admittance,  when  the  line  is 
freed  at  A,  is 

J  .1/1      sinh  SjT)     sinh  8.     Gf».  ,       ,^  .^v 

=  41.066  X  l(r»  mho. 

Similarly,  when  the  line  is  freed  at  Fq  (Figure  13),  and  the  correspond- 
ing line-angles  are  set, 

.  sinhd.     sinh  Sc     sinhS^  ,        /.«.v 

^  =  ^«^3^,-riSh8;-iiSS-,  mhos.  (131) 

The  line-branch  impedances  are  determined  in  the  regular  way. 

R&UM^  OP  Rules  applying  to  Casual  Loads  in  Composite  Lines. 

In  the  accompanying  Table  the  changes  effected  by  loads  in  the 
formulas  for  p'  and  ^  are  collected  together  as  an  aid  to  computation. 


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KENNELLY,  —  EQUIVALENT   CIRCUITS   OF   COMPOSITE    LINES.      69 

It  will  be  seen  that  there  is  a  certain  symmetry  in  these  changes  that 
assists  their  application.  Moreover,  it  is  possible,  after  consulting  the 
Table,  to  select  in  some  particular  case  a  method  which  avoids  addi- 
tional computation.  Thus,  in  dealing  with  an  intermediate  leak,  the 
first  method  calls  for  the  application  of  the  impedance  ratio  across  the 
leak,  to  the  formula  for  fl' ;  whereas  the  second  method  calls  for  no 
change  in  its  formula. 

Table  showing  Changes  made  bt  Casual  Loads  in  the  Composite-Linb 

fobmulas  fob  the  equivalent  tt- architrave  and 

Equivalent  T-Leak. 


Nature  of  Load. 

Change  in  the  Fonnula  for  ^'. 

Change  in  the  Formula  for  0^. 

By  First 
Method. 

BvSecx>nd 
Method. 

ByFirat 
Method. 

BySec»nd 
Method. 

Intennediate 
impedance 

Intermediate 
leak 

None 
Rfn/RgN 

R9MIR9N 
None 

Ggm/Ggi, 
None 

None 
G.mIG.^ 

Terminal 
impedance: 

At  far  end 
At  near  end 

coshO/coshdj^ 

R.AO/R0A  or 
subst.  2o  for  Zi 

Subst.: 
sinh  Zs-x 
coshdivo 

for  sinh  Bn 

RfAo/RfA 

Terminal  leak: 
At  far  end 

At  near  end 

co8h0/coeh«jr 

GfA^GjA  or 
subst.  Vo  for  vi 

Subst.: 
sinh  3jr_i 

cosh^Ao 
for  sinh  9g 

GfAo/GfA 

The  ratios  RgM/Rgir  and  Ggn/Gga  denote  respectively  the  ratios  of  sending- 
end  impedance  and  sending-end  admittance  across  the  load,  the  ratio  being 
taken  in  each  case  such  that  in  the  D.  C.  case  it  is  greater  than  unity. 

The  far  end  is  in  all  cases  the  end  of  the  composite  line  which  is  to  be  con- 
sidered as  freed  or  grounded  for  the  purposes  of  the  computation,  and  the 
near  end  is  the  opposite  end,  or  the  end  towards  which  the  line-angles  are 
developed. 

It  has  been  assumed  for  the  purposes  of  the  Table  that  the  A  end  of  the 
line  happens  to  be  the  near  end  in  all  cases,  and  the  N  end  the  far  end. 


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70 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


Plurality  op  Loads. 

When  several  oasaal  loads  exist  simultaneonsly  in  a  composite  line, 
each  requires  to  be  considered  separately  in  the  formulas  for  p'  and  ^, 
although  no  special  treatment  is  inyolved  thereby  in  computing  ^'  or 
p'.    A  particular  case  of  this  kind  is  shown  in  Figure  14,  where  the 


A* 


Of 2 


.u>oo- 


^■1000 


-B 


15 


fl^sir 


\<miM0'' 


ills 
if?!    ; 


\\ 


il 


H«if 


^•too<r 


fl^.u 


^•2000' 


T-D 


=^ 


8: 


S3    5! 

?5   5 


A- 


gi-*         ^«c.«C     ^-'^  DJ:^^!^ 


^•lOOOl" 


til  11 


»H 


:S 


/       »•' 


2^«I0P0* 


\Mtoo«r  ^'^ud 


rifciy-o" 


o/w?******^ 


H" 


Figure  14.    Composite  line  of  three  sections  with  two  tenninal  and 
one  intermediate  load. 

composite  line  of  Figure  8  is  loaded  with  an  intermediate  resistance  of 
100  ohms  at  the  junction  BG,  a  terminal  resistance  of  200  ohms  at  F 
and  also  with  a  terminal  leak  of  5000  ohms  at  F.  The  presence  of  the 
terminal  resistance  OH,  however,  converts  the  leak  into  an  intermediate 
leak  so  fieir  as  concerns  the  process  of  computation. 

Equivalent  n.     First  Method, 

In  order  to  compute  the  equivalent  n,  ground  the  line  at  one  end, 
as  at  k%  (Figure  14),  and  develop  the  line-angles  towards  H  by  preced- 
ing formulas.  Referring  to  the  Table,  we  have  (a)  one  intermediate 
impedance  at  BC ;  (b)  one  intermediate  leak  at  F6,  and  (c)  one  termi- 
nal impedance  at  the  near  end  H,  the  distant  end  being  grounded. 


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KENNELLY.  —  EQUIVALENT   CIRCUITS   OF  COMPOSITE    LINES.      71 

Consequently,  so  &t  as  concerns  the  first  method,  we  should  make  no 
change  in  the  formula  for  p'  on  account  of  (a),  but  introduce  the  ratio 
Rgr/Rgoiov  (b)  and  substitute  z^  for  Zt  on  account  of  (c).  Conse- 
quently, following  (77)  with  these  changes, 

„  .  ,  ^      cosh^/)    cosh  8^    Rg,  ,        /,o«\ 

,no/,o,    -utroco,™     C08h2.092,95        C08h2.0  1809.74 

=  1.936.87  siBh  1.535.312  •  ^^  1.035.31  "  cosh  0.592.95  '  156514 
=  51,615  ohms. 
The  H-leak  is  then  found  in  the  usual  way. 

Equivalent  TT.     Second  Method. 

Similarly,  by  reference  to  the  Table,  for  changes  in  the  p"  formula 
under  the  second  method,  we  should  introduce  the  ratio  Rgc/RgB  for 
(a),  make  no  change  for  (b),  but  introduce  the  ratio  Rgg/Rgo  for  (c). 
Consequently,  following  (83)  with  these  changes, 

,f  .  ,  >,     sinhS/)    sinhSjp    Rgc   RgH  i        /,oo\ 

=  51,615  ohms. 
The  A-leak  is  then  computed  in  the  regular  manner. 
If  now  we  ground  the  line  at  the  H-end,  we  obtain  similarly,  by  the 
first  method, 

coshSc    cosh  Sg     coshO    Rgo      ,         . 


p     -.,o.uuu^       ^^^^ 

cosh  ^D 

cosh  2 

F     RqF 

=  51,615  ohms. 

and  by  the  second  method, 

,,     ^  sinhSjp     sinhSc 

sinh  8^ 

i?,. 

G„ 

^        '*  sinh  6p    sinh  Bj, 

sinh  Sb 

RgC 

GgO 

-^       ohms.  (135) 

Equivalent  T.     First  Method, 
Freeing  the  line  at  H,  as  at  AjH  (Figure  14),  we  have 
J  '  Y.^      cosh  8c    coshSjp    cosh  So     G>c  i       /,o/.\ 

^ = y»  ^'"'^  «^  •  S3^.  •  c-3^  •  ^3ihy,  •  ^  '°'^««  (136) 

=  0.001  .  8inh2.504,81  -  ^^^^,  ■  ^SS  " 
cosh  0.504,81     cosh  0.733,54 

1  2,146.46 

cosh  0.549,31  *  2,046.46 
=  28.851,7  X  10-»  mho, 


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72  PROCEEDINGS    OF  THE   AMEBICAN   ACADEMY. 

and  freeiDg  the  line  at  A,  as  at  Ai,  we  have 

,  .  ,  5,      cosh  Bf,    cosh  Bjg    G/b    Gr,  i        /-  o-v 

g  —Vfi  sinhS^  •  — r-^- t-^  '  tt^  '  tt^       rsAxa^  (137) 

^       ^"  cosh  8,    cosh  8c    G^a    G/g  ^      ^ 

Equivalent  T.    Second  Method. 
Freeing  at  H,  we  have 

,  sinhS^    sinh8c    sinh  8^  ,        .      . 

^  =  ^'SS^h8;'  SKh8^  •  Sh8;  "'^^^  (^^^> 

and  freeing  at  A, 

,  •  L  /I     sinh  8/)    sinh  8jf    G/q  ,        ,,  .^v 

flr=y.8inh<»..^^^^.^j^^.^  mhos.   (139) 

Methods  of  Cobiputation  adapted  to  Alternating-Curebnt  Gases. 

There  is  especial  need  for  brief  methods  of  computation  when 
A.  C.  cases  are  dealt  with,®  owing  to  the  complexity  of  the  vector 
arithmetic.  In  practice,  the  degree  of  precision  desired  will  usually  be 
much  lower  than  that  aimed  at  in  the  arithmetical  examples  of  this 
paper,  where  the  numerical  values  have  been  carried  to  six  significant 
digits.  Graphical  methods  may  be  frequently  used  with  advantage, 
especially  in  the  vector  addition  of  complex  hyperbolic  angles.  Trav- 
erse Tables  as  used  by  navigators  may  also  be  used  with  advantage 
for  the  resolution  of  vectors  into  complex  quantities. 

The  following  formulas  are  also  useful: 


cosh  {p  ±jq)  =  Vcosh^/?  —  sin'g  /±  tan'^tanh P  -  tan  q)      (140) 
sinh  (p  ±jq)  =  Vsinh'jp  -f  sin^^/±  tan-^coth p  *  tan  y)      (141) 

tanh(p±i7) ^""^^^ ±j     ,  "°^g (142) 

tanb->(,iy,)  =  ilog.4/^{^+i| l±^i U_d  ■ 

(143) 

•  A  table  of  hyperbolic  tangents  of  a  vector  variable  or  of  tanh  r/B,  is 
being  prepared  by  the  writer  for  values  of  r  between  0  and  6,  by  steps  of  0.1 
or  less;  and  for  virtually  all  angles  B^  by  steps  of  one  degree. 


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kennellt.  —  equivalent  circuits  of  cobipoaite  une8.    73 

Conclusions. 

Any  composite  line  of  any  nnmber  of  sections,  with  or  without  loads 
of  any  kind,  operated  in  the  steady  state  either  by  a  direct  current^  or 
by  an  alternating  current  of  one  frequency,  has  the  same  receiving-end 
impedance  from  each  end ;  so  that,  if  one  volt  be  applied  to  each  end 
in  turn,  the  current  strength  received  at  the  other  end  will  be  the 
s&ma^ 

The  equivalent  circuits  of  such  lines  may  always  be  computed  either 
for  the  D.  C.  or  A.  G.  case  by  the  formulas  given  in  this  paper.  That 
is,  any  such  line  may  always  be  replaced  by  one  delta  connection  or  by 
one  star  connection  of  impedance,  without  disturbing  the  electrical 
conditions  outside  of  the  line. 


Notation  Employed 

a,  a^^  ai,  os,  a,    ....  attenuation-constants  of  a  single  line,  of  a 

loop-line,  and  of  different  sections  of  a 
composite  line  (hyps,  per  km.). 

c,  Cj.y  c^c^yCt linear  capacitance  of  single  line,  loop-line, 

and  sections  (£urads/km.). 

8,  8^,  8^ the  hyp.  angles  of  points  on  a  line  (hyps). 

Gi  Gg,  Ggj^, ...  G>>  G/4, ...  the  sending-end  admittance  (D.  C.  conduc- 
tance) of  a  line,  the  admittance  beyond  a 
point  on  the  same,  when  the  faa  end  is 
grounded,  and  when  the  faa  end  is  free 
(mhos). 

ffi  ff/j9  9u  ^s»  ^t   •   •   •   •  linear  conductance  of  single  line,  loop-line, 

and  sections  (mhos/km.). 

^  =  l/B^ conductance  of  leak  of  a  T  (mhos). 

^'  =  1/Bf' conductance  of  leak  of  a  n  (mhos). 

y conductance  of  a  leak  load  (mhos). 

t,  (a,  ip current  strength,  at  the  sending-end,  and  at 

a  point  on  the  line  (amperes). 

J V-1  . 

/,  l^^  liy  lit  Iz linear  inductance  of  single  line,  loop-line,  and 

sections  (henrys/km.). 
Z,  Zi,  Z2,  Zs length  of  a  line  and  of  sections  (km.). 

^  An  exception  should  be  noted  in  the  case  of  any  part  of  the  composite 
line  not  obeying  Ohm's  law,  as,  for  example,  a  fault  in  the  insulation ;  so  that 
the  current  through  the  fault  is  not  proportional  to  the  potential  at  the  same. 


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74  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

t distance  of  a  point  on  a  line  from  its  &t  end 

(km.). 

n frequency  of  single  A.  C.  (cycles  per  second). 

0) angular  velocity  of  A.  C.  (radians  per  second). 

p^q cartesian  coordinates  of  a  point  in  a  plane. 

r,  r^fl  rj,  r^^r% linear  resistance  of  a  single  line,  loop-line, 

and  sections  (ohms/km.). 
5,  Rg,  Rg^ ...,  Rfi  Rfj, ...   resistance  of  a  line  beyond  a  point  on  the 

same,  the  resistance  when  the  fiir  end  is 

grounded,  and  when  the  far  end  is  free, 

A.  G.  impedance  (ohms). 
R!  =  1/^ resistance  (A.  C.  impedance)  of  leak  of  a  T 

(ohms). 
RI'  =  1//' resistance  (A.  C.  impedance)  of  leak  of  a  n 

(ohms), 
p'  =  i/y resistance  (A.  C.  impedance)  of  line-branch  of 

T  (ohms), 
p"  =  l/y" resistance  (A.  C.  impedance)  of  architrave  of 

n  (ohms). 
<T resistance  (A.  G.  impedance)  of  impedance 

load  (ohms). 
^>  ^//>  ^h^'^^%    ....  hyperbolic  angle  subtended  by  a  single  line, 

loop-line,  and  sections  (hyps). 
y  =  \lz surge-admittance  (D.  C.  conductance)  of  a 

line  (mhos). 
if  =  1/p' admittance  (D.  C.  conductance)  of  a  line- 
branch  of  a  T  (mhos), 
y  =  1/p'' admittance  (D.  C.  conductance)  of  architrave 

of  a  n  (mhos). 
^i^An^F potential,  at  the  sending-end,  and  at  a  point 

on  the  line  (volts). 
Zr^Z, impedance  of  a  terminal  receiver,  of  terminal 

sending  apparatus  (ohms). 
«^»  «//.  ^>  z^^^t     ....  surge-impedance  of  a  line,  a  loop-line,  and 

sections  (ohms). 
Zo     apparent  surge-impedance  of  a  line  to  which 

an  impedance  load  is  prefixed  (ohms). 


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KCNNELLT.  —  EQUIVALENT   CIRCUITS   OF   COMPOSITE    LINES.       75 
BiBLIOQRAPHY. 

O.  Heavlflide.    Eleotrioal  Papers,  ii,  248.    London,  Macmillan  &  Co., 

1892. 
BC  I.  Pnpin.    Propagation  of  Long  Electrical  Waves.    Trans.  Amer. 

Inst  Electr.  Engrs.,  1899,  xvi,  93. 
Wave  Transmission  over  Non-Uniform  Cables  and  Long-Dis- 

tance  Air-Lines.    Trans.  Amer.  List.  Electr.  Engrs.,  1900, 

xvii,  445. 
Wave  Propagation  over  Non-Uniform  Conductors.   Trans.  Amer. 

Math.  Soc.,  1900,  i,  259. 
M.  Ifeblanc.    Formula  for  Calculating  the  Electromotive  Force  at  any 

Point  of  a  Transmission  Line  for  Alternating  Current  Trans. 

Amer.  Inst  Electr.  Engrs.,  1902,  xix,  759. 
O.  A.  Campbell.    Loaded  Lines  in  Telephonic  Transmissions.    Phil. 

Mag.,  1903,  ser.  6,  v,  313. 
O.  Roeasler.    Die  Femleitung  von  Wechselstromen.    Berlin,  Julius 

Springer,  1905. 
O.  Di  Pirro.    Sui  Circuiti  non  uniformi.    Atti  dell'  Assoc.  Elettrotech., 

1909,  xii.  No.  6;  La  Lumi^re  Electrique,  1909,  ser.  2,  vii, 

227. 
A.  B.  KenneUy.    A  Contribution  to  the  Theory  of  Telephony.    Electr. 

World,  1894,  rriii,  208. 
Resonance  in  Alternating  Current  Lines.    Trans.  Amer.  Inst 

Electr.  Engrs.,  1895,  xii,  133. 
Electric  Conducting  Lines  of  Uniform  Conductor  and  Insulation 

Resistance  in  the  Steady  State.    Harv.  Eng.  Joum.,  1903,  ii, 

135. 
The  Alternating  Current  Theory  of  Transmission  Speed  over 

Submarine  Cables.     Trans.   Intemat   Electr.  Cong,  of  St 

Louis,  1904,  i,  66. 
High-Frequency  Telephone  Circuit  Tests.    Trans.   Intemat 

Electr.  Cong.  St  Louis,  1904,  iii,  414. 
The  Distribution  of  Pressure  and  Current  over  Alternating 

Current  Circuits.     Harv.  Eng.  Joum.,  1905,  iv,  149. 
The  Process  of  Building  up  the  Voltage  and  Current  in  a  Long 

Alternating  Current  Circuit    These  Proceedings,  1907,  xlii, 

701. 
Artificial  Lines  for  Continuous  Currents  in  the  Steady  State. 

These  Proceedings,  1908,  xliv,  97. 

Harvabd  University,  Cambridge,  Mass., 
September,  1909. 


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Froceedingi  of  the  Amflrican  Academy  of  Arts  and  Sciences. 
Vol.  XLV.  No.  4.  — January,  1910. 


IIcpl   iia^w. 

A  STUDY  OF  THE  CONCEPTION  OF  NATURE  AMONG  THE 
PRESOCRATICS, 


By  Wiluam  Arthur  Heidel, 
pBorB880R  or  Qbeek  in  Wbslktan  Uni^'cbsitt. 


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IIcpl  §il<rc<»$. 

A  STUDY  OF  THE  CXDNCEPTION  OF  NATURE  AMONG  THE 
PRE-SOCRATICS.* 

Bt  William  Arthxjb  Heidel. 
Present«d  1^  M.  H.  Morgan,  October  13, 1909;  Received  November  3, 1909. 

Professor  John  Burnet  says  : '  "So  far  as  I  know,  no  historian  of 
Greek  philosophy  has  clearly  laid  it  down  that  the  word  used  by  the 
early  cosmologists  to  eicpress  this  idea  of  a  permanent  and  primary  sub- 
stance was  none  other  than  <l>vai^ ;  *  and  that  the  title  Ilcpl  </>vo-€o>9,  so 
commonly  given  to  philosophical  works  of  the  sixth  and  fifth  centuries 
B.  c.,*  means  simply  Concerning  the  Primary  Substance,  Both  Plato 
and  Aristotle  use  the  term  in  this  sense  when  they  are  discussing  the 

*  This  paper  was  begun  in  the  spring  of  1908,  and  was  read  in  substance  befoi-e 
the  Classical  Clul)  of  Princeton  University,  Dec.  17,  1908. 

«  Early  Oruk  Philoaophy,  2d  ed.,  1908,  p.  12  foil. 

*  Burnet,  ibid,,  p.  13  foil.,  p.  57,  n.  1,  rejects  the  traditional  view  that  Anaxi- 
mander  so  used  dpx^t  which,  he  says,  "is  in  this  sense  purely  Aristoteliau."  This 
statement,  and  the  other  that  **To  Anaximnnder  dpx^  could  only  have  meant  begin- 
ning,** are  open  to  question  ;  cp.  Hippocrates,  11.  i^oiatcw,  61  (7,  684  Littre)  iurb  tGjv 
dpx^  SdffTarai  Cjv  €tpriKd  ol  vdm-a,  and  ibid.  (7,  690  Littr^)  5icwj  ipyd^otrrat  al  dpxal 
tIjv  04pfirfP  Kal  Ttiv  rapax^  ti^  ^pI*  Owdyovffai  ii  vovaov.  Cp.  Philolaus,  fr.  6  ivel  Zk 
raX  dpxal  inrdpxo^  ovx  ifjLOuu  oW  6/t50vXot  (ffffcUf  fr.  8  iipup  puovdi  wj  di*  dpxh  o^a 
irdrrciw,  fr.  11  dpxd  koL  dycfidov,  though  1  lay  no  stress  on  these,  believing  that  all  the 
so-called  fragments  of  Philolaus,  excf'pting  fr.  16,  which  occurs  in  the  Eudemian 
Ethics,  are  spurious.  Cp.  also  note  166,  below.  This  use  of  dpx'h  -  causal  principle 
may  well  have  been  old  ;  cp.  irifyij  and  jiij^iM  —  oroix^lov.  The  *  Aristotelian  *  sense 
of  dpx^  occurs  in  Plato,  Tim,  48  B ;  cp.  Diels,  ElemaUum,  p.  20.  Burnet  also 
says  (p.  66)  **That  Anaximander  called  this  something  [i.e.  his  "Aretpov]  by  the 
name  of  ^<J<rtf,  is  clear  from  the  doxographers."  This  statement  likewise  may  fairly 
be  challenged. 

*  Burnet  here  adds  in  a  note :  **I  do  not  mean  to  imply  that  the  philosophers 
used  this  title  themselves ;  for  early  prose  writings  had  no  titles.  The  writer  men- 
tioned his  name  and  the  subject  of  his  work  in  the  first  sentence,  as  Herodotus,  for 
instance,  does."  As  the  titles  were,  in  all  probability,  added  later  it  is  interesting 
to  note  the  words  of  Galen,  de  Elem.  see,  Bippocr.  i.  9,  p.  487  Kiihn :  tA  ydp  tQjv 
iraXatwr  firoi^a  irepJ  ^i^€(at  iTiy^pavrai^  rd  MeXiffffov,  tA  HapfMylSov,  tA  *E/utc8o- 
icXiovs,  *AXKfjLaU<aif6s  re  koI  Topylov,  kcU  UpoSlKOVf  ical  r(a»  HXKiav  dTdvT<ap,  It  was  there- 
fore, as  we  shall  see,  a  sort  of  blanket- title. 


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80  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

earlier  philosophy,*  and  its  history  shows  clearly  enough  what  its  origi- 
nal meaning  must  have  been.  In  Greek  philosophical  language,  ^vo-cs 
always  means  that  which  is  primary,  fundamental,  and  persistent, 
as  opposed  to  what  is  secondary,  derivative,  and  transient ;  what  is 
'given,'  as  opposed  to  that  which  is  made  or  becomes.  It  is  what  is 
there  to  begin  with." 

"  There  is  one  important  conclusion,"  says  Professor  Burnet^*  "  that 
follows  at  once  from  the  account  just  given  of  the  meaning  of  <t>v<n^^ 
and  it  is,  that  the  search  for  the  primary  substance  really  was  the  thing 
that  interested  the  Ionian  philosophers.  Had  their  main  object  been, 
as  Teichmiiller  held  it  was,  the  explanation  of  celestial  and  meteorolog- 
ical phenomena^  their  researches  would  not  have  been  called^  IIcpl 

<fkv<r€iai  ioTopirj,  but  rather  IIcpl  ovpavov  or  IIcpl  fiCTcaipaiv." 

Considering  its  source,  this  declaration  is  of  sufficient  importance  to 
justify  an  extended  examination  for  its  own  sake,  especially  as  it  has 
not  been  adequately  met  by  students  of  Greek  thought ;  •  but  the  pur- 
pose of  this  study  is  somewhat  different  The  words  quoted  from  Fro- 
fessor  Burnet  serve,  therefore,  chiefly  as  a  point  of  departure  It  is 
proposed  to  consider  three  subjects,  which  are  of  importance  in  relation 
to  the  works  entitled  IIcpl  ^vcrccus :  (1)  the  historical  relation  of  the 
studies  so  entitled  to  mythology  and  poetry ;  (2)  the  senses  in  which 
<tvVi?  was  employed  before  400  b.  a  ;  (3)  the  probable  connotation  of 
the  title  IIcpl  <;^wr€(i»9,  judging  by  the  direction  of  interest  of  the  writers 
as  indicated  by  the  problems  they  raised. 

Before  proceeding  to  the  consideration  of  these  questions,  however, 
it  may  be  proper  to  touch  briefly  on  several  subjects  suggested  by  the 

»  Burnet  here  refers  to  Arist  Phys,  193  a  21  foil,  and  to  Plato,  Legg.  892  C 
^^uf  poj^Xorrai  X^euf  yivtaiw  r^v  repl  rA  rpunxi.  Here  he  interprets  y4v€<nv  with 
tA  ii  o5  ylyvtrau  Though  this  use  of  7^i^<rtf  is  as  old  as  Homer  (S  201,  246),  and 
though  Plato  could  employ  it  in  allusion  to  Homer  ( Tfieaet.  180  D),  it  would  be  ill- 
chosen  to  explain  ^^is.  Ast  in  his  ed.  (vol.  in.  158)  has,  as  it  seems  to  me,  cor- 
rectly rendei^d  the  words:  **Volunt  illi  naturam  dici  generatiouem  eorum,  quae 
primum  orta  sint,"  unless  one  prefers  "quae  prima  sint."  Cp.  inrip rijs  rdy  aroixtlwv 
^Offcm,  Diels,  Forsolcr,  ii.  511,  15.  Burnet  might  have  referred  with  more  propriety 
to  Plato,  Legg,  891  C,  but  it  is  to  be  noted  that  <p{fais  is  singular. 

•  Ibid.  p.  14. 

•  Burnet  here  refers  to  Plato,  PJiaedo  96  A  and  Eurip.,  fr.  910.  We  may  add 
Theophrastus,  Ph.  0.  fr.  5  (Diels,  Dox.  480,  7)  and  fr.  9  {ibid,  485,  1).  In  the  latter 
case  if  r.  ^t^o-eus  laropla  is  opposed  (speaking  of  Plato)  to  ^  xpay/xarela  Tcpl  rift 
Tpiinfft  <^\o<ro^at,  Cp.  n,  206,  below.  From  Theophrastus  the  phrase  was  imssed 
on  to  the  doxographers.  Thus  Simplic.  in  Phys,  (p.  28.  29  Diels)  says :  OaX^s  W 
TpQnot  Tapa848oTai  r^  T€pl  ^Caews  laroplop  rois'^Wrfcaf  iK^rjpai, 

•  Burnet's  view  has  been  briefly  criticised  by  Professor  Millerd,  On  the  Interpreta- 
tion of  Empedocles,  Chicago,  1908,  pp.  18  folL 


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HEIDEL.  —  IIcpl  ^^criMf.  81 

TTords  quoted  from  Professor  Burnet  It  is  probably  true  that  early 
prose  writings  had  no  formal  titles ;  but  our  information  on  this  point 
is  really  too  scanty  to  admit  of  dogmatic  statement.*  It  is  reasonably 
certain  that  philosophical  works  were  £a.miliarly  quoted  as  bearing  the 
title  Ilcpt  <l>va'€iaq  some  time  before  the  close  of  the  fifth  century,  as  we 
may  see  from  the  works  of  Hippocrates ;  ^®  and  from  the  time  of  Xeno- 
phon,  Plato,  and  Aristotle  ^^  onwards  it  must  have  been  the  accepted 
designation.  In  regard  to  the  scope  of  the  title  IIcpl  <f>v(r€m  and  Pro- 
fessor Burnet's  attempt  to  limit  it  narrowly  to  the  meaning  Concerning 
the  Primary  Substance,  and  to  distinguish  it,  as  if  coordinate,  from 
such  titles  as  IIcpl  ovpavov  and  IIcpl  ficrcoipojv,  we  shall  be  in  better  posi- 
tion to  decide  at  the  conclusion  of  our  inquiry.  But,  while  it  is  clearly 
impossible,  without  writing  a  history  of  Greek  philosophy,  to  reftite  his 

*  Besides  Herodotus,  we  have  incorporated  titles  from  Hecataeus  (fr.  332  Miiller), 
Antiochus  of  Syracuse  (fr.  3  Miiller),  Alcmaeon  (fr.  1),  and  Thucydides.  It  is  possi- 
ble that  the  Mucpdr  AidKOfffiot  of  Democritus  had  such  a  title  ;  cp.  Diog.  Laert.  ix.  41. 
Wc  have,  however,  what  are  said  to  be  the  opening  wonls  of  other  works,  but  mention 
neither  the  name  of  the  author  nor  the  subject ;  e.  g.  Heraclitus,  fr.  1  ;  Archytas, 
fr.  1 ;  Anaxagoras,  fr.  1 ;  Protagoras,  fr.  1  and  4  ;  Diogenes  of  Apollonia,  fr.  1.  For 
those  who  hold  the  fragments  attributed  to  him  to  be  genuine  I  may  add,  Philolaus, 
fr.  1.  One  may,  of  course,  assume  that  the  incorporated  title  was  in  these  cases 
disregarded,  either  because  a  formal  title  had  been  substituted  for  it,  or  because  it 
was  considered  negligible.  The  works  of  Hippocrates,  however,  do  not  have  incor- 
porated titles  naming  the  author ;  but  have  in  some  cases  an  introductory  sentence 
which  announces  the  subject :  e.  g.  E.  yvi^atKelrfs  ^i^tof  (7,  312  Littr^)  irepi  U  ttjs 
ywaucelrft  ^^los  koI  vociifidTwv  rdSe  X^w ;  similarly  Democritus,  fr.  165  X^w  rdSt 
x€pi  T«r  ^viirdrrw,  Cp.  also  Hippocrates  (Littr^)  8,  10  ;  8,  408  ;  8,  466  ;  8,  666  ; 
8,  612. 

*•  Hippocr.  n.  dpX'  IrrrptKrjit.  20  (1,  620  Littr^)  relpci  dk  a&roU  6  X670J  ii  ^i\o<ro- 
^rip,  KoJBdTtp  'E/tredoicX^f  ^  dXXoi  ol  Tcpl  ^6ffios  ycypd^aiP.  iyu)  Si  toOto  /u^,  8<Ta 
Tipi  €tprrjfrai  ij  (ro^torj  ^  IrrPV  ^  yiy pairrai  vtpl  ip6<notf  1i<r<ror  vopi^  tJ  Irp-piicj  r^x^ 
wpov-fiKfUf  fj  ry  ypa^iici.  U.  aapKMP,  15  (8,604  Littr^)  kuI  €1(tI  rivts  ot  fKe^av  ^6auf 
(uyypd^om-et  8ti  6  iyK4<pa\6i  icrof  d  ^x^^^*  I"  Hippocrates  we  find  such  titles  as 
n.  ^Offios  6<rr^«r,  H.  tpiaiot  TcuSloVf  U.  ^i^tos  A»Bpii)irov,  H.  tf»i<Tioi  ywaiKeirfs,  The 
meaning  of  these  titles  will  be  seen,  I  trust,  in  the  sequel.  It  may  excite  com- 
ment that  I  quote  Hippocrates  indiscriminately.  I  do  so  because  to  do  otherwise 
were  to  prejudge  a  question  not  yet  settled  —  hardly  even  fairly  put.  I  incline  to 
,  the  opinion  that  the  works  of  the  Corpus  Eippocrateum  (with  possibly  one  or  two 
exceptions)  belong  to  the  fifth  century  ;  at  any  rate,  the  conceptions  and  points  of 
view  they  present  show  few  traces  of  the  influence  of  Soci-atic  thought. 

^  Xen.  Mem,  l.  1,  14  tCjp  re  repl  riji  ruir  irdin-wp  tf»6<r€bn  fiepipjfihmav  ;  Plato, 
Legg,  891  C ;  Phaedo  96  A  (see  above,  note  7)  iydf  ydp,  i^fij  (sc.  6  ZuKpdrrji)^  v4oi  ujv 
BavfMorGn  on  iweOifirfaa  ra&rris  rijs  <ro4>tai  ^p  dij  KoKotkri  re/oi  ^6<r€us  UrropiaVy  which  is 
of  great  importance  since  in  this  connexion  Plato  most  clearly  defines  the  relation 
of  tiie  Socratic- Platonic  philosophy  to  that  of  the  ^hhfikoI  ;  for  Aristotle  it  is  hanlly 
necessary  to  do  more  ^han  refer  to  Bonitz's  Index  under  the  expressions  ol  ^nxriKolt  ol 
wepl  ^(^ecM,  ol  ^wTuiKiiyoii  (pwnoKoy^Xp, 
VOL.  XLV.  —  6 


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82  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

further  statements  that  "  the  search  for  the  primary  substance  really 
was  the  thing  that  interested  the  Ionian  philosophers"  and  that "  Greek 
philosophy  began,  as  it  ended,  with  the  search  for  what  was  abiding  in 
the  flux  of  things ;"  it  must  be  said  that  so  to  define  the  scope  of  Greek 
philosophy  were  to  reduce  it  to  terms  which  are  well-nigh  nugatory. 
Greek  philosophy  did,  indeed,  seek  the  permanent  amid  the  flowing ; 
but,  as  the  first  determined  efibrt  of  the  human  mind  to  frame  a  sci- 
ence, it  sought  an  explanation  of  the  fleeting  phenomena.  This  ex- 
planation it  found  ultimately  in  that  which  abides,  and  gave  to  it 
various  names :  but  it  was  not  the  permanence,  but  the  causality,  of 
the  \nroK€Lfi€vov  to  which,  as  scientists,  the  Greek  philosophers  devoted 
their  chief  attention.^*  Aristotle  was  clearly  right  in  refusing  to  regard 
the  Eleatics,  in  so  far  as  they  adhered  to  their  metaphysical  principles 
which  excluded  causality  and  motion,  as  <^vcrtKoi. 

I. 

"  One  may  say  that  primitive  man  has  only  religious  apperceptive 
masses.''  "No  matter  what  historical  phenomenon  we  may  trace  to 
a  remote  past,  we  come  at  last  to  religion.  All  human  conceptions,  so 
far  as  they  fall  within  the  intellectual  horizon  of  a  pre-scientific  age, 
have  developed  out  of  mythical  conceptions ;  but  religious  ideas  con- 
stitute the  content,  or  at  least,  the  garb  of  myth."  These  words  from 
the  pen  of  the  lamented  Professor  Usener  ^'  strike  the  key-note  of  this 
portion  of  our  study. 

As  later  Greek  philosophy,  so  fer  as  it  was  a  philosophy  of  nature, 
grew  out  of  the  teachings  of  the  pre-Socratics  with  only  here  and  there 
a  clearly  marked  infusion  of  metaphysics,  ultimately  derived  from  So- 
crates :  so  Greek  philosophy  as  a  whole  was  not  a  creation  e  nikilo. 
Long  before  the  dawn  of  philosophy,  properly  so-called,  the  reflective 
thought  of  the  Greeks  had  busied  itself  with  many  of  the  problems 
which  later  engaged  the  attention  of  the  philosophers.^*  Even  if  we 
had  no  evidence  to  prove  it,  we  should  still  have  to  assume  it  as  a  fact 
We  are  not,  of  course,  in  position  to  trace  even  in  the  most  general 

*^  In  my  study,  TTie  Necessary  and  the  Contingent  in  (ke  Aristotelian  System, 
Chicago,  1896,  pp.  7-10,  I  gave  a  brief  analysis  of  the  movement  of  pre-Socratic 
thought  in  logical  tenns.  Somewhat  more  at  length  a  similar  study  appeared  in  7%« 
Logic  of  the  Pre-Socratic  Philosophy,  published  as  Chapter  IX.  of  Studies  in  Logical 
Tlitory,  by  John  Dewey,   Chicago,  1903. 

**   Vortrdge  und  Aufsdtze,  pp.  43  and  45. 

**  There  is  much  philosophy  held  in  solution  in  Greek  mythology  ;  but  it  is 
impossible  to  utilize  it  for  historical  purposes,  because  the  early  history  of  the  myths 
is  unknown.     Unfortunately  this  is  likely  always  to  be  the  case.* 


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HETDEL.  —  IIcpl  ^vo-CttS.  83 

outlines  the  stages  in  the  process  of  organizing  the  confused  mass  of 
primitive  human  experience  into  a  unified  world  of  thought.  We  may 
be  sure,  however,  that  there  never  was  a  time  when  the  human  mind 
held  even  two  wholly  unrelated  experiences ;  and  there  will  never  come 
a  time  when  all  human  experiences  shall  constitute  a  perfect  Koafios. 
Somewhere  between  these  limits  history  moves,  the  mind  now  energeti- 
cally striving  to  achieve  a  synthesis,  now  supinely  acquiescing  in  "  the 
cult  of  odds  and  ends." 

When  the  curtain  of  history  rises  on  the  Greeks,  we  find  in  Homer 
a  strange  condition.  In  the  foreground  there  is  a  relatively  well  or- 
dered society  of  gods  and  men  ;  while  in  the  shadows  of  the  background 
lurk  remnants  of  an  ancient  barbarism.  Politically  society  is  in  unsta- 
ble equilibrium,  momentarily  held  together  by  a  common  cause  :  par- 
ticularism clearly  preceded,  particularism  follows.  One  can  with 
difficulty  banish  the  thought  that  the  union  of  the  Greeks  under  the 
suzerainty  of  Agamemnon  was  only  a  poet's  dream,  —  an  ideal  never 
realized  and  perhaps  never  to  be  realized.  Homeric  religion  is  in  much 
the  same  case  :  Zeus  is  king  of  all  the  gods,  but  even  after  his  vic- 
tory over  the  turbulent  sons  of  Earth,  his  rule  is  precarious.  The 
Titans  fume ;  and  the  wife  of  his  bosom  nurses  thoughts  of  treason. 

As  for  the  occurrences  of  daily  life,  they  are  the  expression  of  divine 
powers  ^*  lurking  everywhere  and  acting  more  or  less  capriciously.  Noth- 
ing that  occurs  occasions  much  surprise,  ^*  and  a  ready  explanation  for 
even  the  most  unexpected  event  is  suggested  by  the  inscrutable  oper- 
ations of  the  gods.  This  is  not  the  atmosphere  which  surrounds  and 
stimulates  the  birth  of  philosophy.  But  while  Homer,  on  the  whole, 
writes  for  entertainment  and  tells  such  tales  as  may  fitly  cheer  a  pleas- 
ant feast,  there  are  not  wanting  in  the  Hiad  passages  which  show  that 
the  Greeks  of  that  age  sometimes  thought  in  a  less  light-hearted  vein. 
Two  portions  in  particular,  the  Aw  'A^an;  ^^  and  the  ©coftaxto,  !•  con- 
tain unmistakable  vestiges  of  earlier  theogonic  and  cosmogonic  poem^ 
The  tendency  here  appearing  in  Homer  finds  increasing  fisivor  with 
Hesiod  and  the  cosmogonists  of  the  eighth  and  seventh  centuries  b.c. 

For  reasons  hardly  intelligible  to  me  it  has  become  common  to  dis- 

*•  Cp.  Adam,  The  lUligioiis  Teachers  of  Greece,  p.  22.  If  Thales  said  rdm-a  rXiipri 
6€Qm^  it  WIS  a  survival  of  *  Homeric '  thought  out  of  harmony  with  the  new  philo- 
sophical movement.    Such  survivals,  however,  are  common  in  all  ages. 

*•  Cp.  Adam,  ibid,,  p.  24. 

^  n,  XIV. 

^  II,  XX,  XXI.  That  this  passage  is  cosmological  was  seen  by  Theagenes  in  the 
fdxth  century,  B.C.  (see  Schol,  H.  B  on  T,  67),  and  emphasized  by  Murray,  JRisc  of 
the  Greek  Epic,  p.  239  ff.,  and  by  Gilbert,  Die  mcUorologischen  Theorien  des  griechi- 
wchem  AlUrtums,  p.  25,  n.  2. 


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84  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

tingnish  these  interesting  early  thinkers  from  the  illostrious  company 
of  the  philosophers,  headed  by  Thales,  as  if  they  belonged  to  different 
orders  of  existence.  Certain  it  is  that  Aristotle  was  not  aware  of  any 
such  fundamental  difference.  "  Even  a  lover  of  myth,"  he  says,^*  "  is 
in  a  sense  a  philosopher."  Thales  he  calls  the  founder  of  the  school  of 
philosophy  which  inquires  into  the  material  cause  of  things ;  but  he 
adds,'®  almost  in  the  same  breath,  that  "some  think  that  the  ancients 
who  lived  long  before  the  present  generation,  and  first  framed  accounts 
of  the  gods,  had  a  similar  view  of  nature."  By  late  writers  no  distinc- 
tion whatever  is  made  between  the  two  classes  of  thinkers ;  thus  Hip- 
polytus  says,'^  "The  poet  Hesiod  himself  declares  that  he  thus  heard 
the  Muses  speak  IIcpl  <;^ixr<(i>9."  Plato,  on  the  other  hand,  says  in  a 
playful  vein  of  the  early  philosophers,**  **  Each  appears  to  me  to  re- 
count a  myth  for  our  entertainment,  as  if  we  were  children.  One  says 
that  the  things  that  are  are  three  in  number,  and  that  certain  of  these 
somehow  go  to  war  with  one  another  firom  time  to  time ;  then  again 
they  become  reconciled,  contract  marriages,  beget  children,  and  rear 
their  offspring.  Another  says  there  is  a  pair,  —  Moist  and  Dry,  or 
Hot  and  Cold,  — and  gives  away  the  bride  and  lets  the  pair  cohabit 
The  Eleatic  tribe  out  our  way,  however,  going  back  to  Xenophanes  and 
even  £a.rther,  recounts  its  tales  as  if  all  beings,  so  called,  were  one." 
However  we  may  interpret  the  passage  in  detail,  it  is  obvious  that 
Plato  notes  and  emphasizes  the  fundamental  identity  in  point  of  view 
between  the  early  cosmogonists  and  the  golden  tribe  of  philosophers. 
He  shows  how  easy  it  is  to  state  philosophical  conceptions  in  mytho- 
logical terms,  and  suggests  by  implication  that  the  opposite  procedure 
is  equally  easy. 

Aristotle  also  clearly  correlates  tfeoXoyoi  and  OtoXoyia,  with  <f>wrvoKoyoi 
and  <l>vcrio\oyia  in  such  sort  as  to  show  that  in  his  view  words  and 
concepts  run  alike  parallel.'*  He  likens  the  earliest  philosophy  to  a 
lisping  child,'^  and  makes  repeated  attempts  to  restate  in  more  accept- 
able form  the  opinions  of  his  predecessors.'*    He  would  doubtless  have 

"  Met.  982*  18. 

»•  Met.  983*  20  and  27  foil.,  transl.  Ross.  It  is  noteworthy  that,  though  Aris. 
totle  does  not  expressly  assent  to  the  interpretation  of  the  myth,  be  evidently  has 
no  thought  of  refuting  it. 

»  Philo8.  26  (Diels,  Dox.  674,  14). 

»  Plato,  Soph.  242  C.     For  this  passage  see  Diels,  Fortokr.*  40,  §  29. 

»  Cp.,  e.e.,  Met.  1071*  26  foil..  1076*  26  foil. 

••  Met.  993*  15  foil.  Cp.  the  interesting  prelude  to  the  myth,  Plato,  Polit.  268  E. 
This  conception  powerfully  stimulated  the  tendency  to  allegorical  interpretation,  and 
accounts  for  Aristotle's  freedom  in  reinterpreting  his  predecessors. 

s*  I  directed  attention  to  several  instances  of  somewhat  violent  reinterpretation 


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H£U>EL.  —  n^l  ^^criMf .  85 

offered  a  like  apology,  only  with  larger  charity,  for  the  still  earlier  oosmog- 
onists.  Theophrastus  **  in  the  same  spirit  remarked  upon  the '  poetic ' 
diction  of  Anaximander  because  he  referred  to  the  matual  encroach- 
ment of  the  elements  as  '  injustice.'  Indeed,  the  mythical  cast  of  much 
of  the  earlier  philosophy  is  so  marked  as  to  constitute  a  serious  prob- 
lem to  the  historical  student,  who  desires  to  interpret  fairly  the  thought 
of  the  age.  This  &ct,  duly  considered,  throws  light  in  both  directions. 
It  shows,  on  the  one  hand,  that  theogonists  and  cosmogonists  em- 
ployed the  names  of  divinities  to  designate  philosophical,  or  at  any 
rate,  quasi-philosophical  concepts ;  but  it  also  shows  that  the  philoso- 
phers were  not  themselves  conscious  of  a  complete  break  with  the  past 
Thus,  while  the  theogonists  pictured  the  origin  and  operations  of  the 
world  in  terms  of  the  history  and  behavior  of  mythical  characters, 
often  so  vaguely  and  imperfectly  conceived  '^  as  at  once  to  betray  their 
£su3titiou8  nature,  the  philosophers  applied  to  their  principles  and  ele- 
ments names  and  epithets  proper  to  the  gods.'*  This  course  was, 
indeed,  extraordinarily  easy  and  natural  to  the  Greeks,  whose  religion 
was  in  its  higher  phases  essentially  a  worship  of  Nature.'*  But  this 
very  worship  of  Nature  in  her  more  significant  aspects  was  in  itself 
one  of  the  chief  influences  which  predisposed  the  Greeks  to  a  philoso- 
phy of  Nature. 

There  are  certain  picturesque  effects  of  this  intimate  historical  con- 
nexion of  speculation  on  nature  with  theology  (in  the  Greek  sense), 
which  are  perhaps  worth  noting.  Aristotle  repeatedly  uses  the  ex- 
pression KocfjLov  ycwov  alongside  icoo-fioTroiciv  or  Koa-fiovoua  in  reference 

of  his  precanors  in  my  stady,  Qualitative  Change  in  Pte-Soeratic  Philosophy  (Archi7. 
for  G«8ch.  der  Philos.,  1906).  There  seem  still  to  remain  a  few  scholium  who,  even 
after  the  illustrations  of  this  tendency  noted  by  Natorp  (e.  g.,  Philos.  Monatsbefte, 
XXX.  345)  and  Bamet,  are  unaccountably  blind  to  it. 

«•  Apud  Simpl.  In  Phys.  I.  2,  p.  24,  20  (Diels). 

^  See,  e.g.,  Diels,  Parmenides  Lehrgedieht,  p.  10 ;  Bohde,  Psyche,  n.  114  and 
115,  n.  2;  Ed.  Meyer,  Oesch.  dee  AUertume,  I,  a  (2d  ed.),  p.  100  foil.;  Burnet, 
Early  Greek  Philosophy,  (2d  ed.)  p.  74  foil. 

^  Gp.  Otto  Gilbert,  lonier  und  Elealen,  Rh.  M.,  N.  F.,  64,  p.  1S9.  Empedocles 
deifies  the  Sphere,  the  elements,  and  the  efficient  causes,  Love  and  Strife.  The  practice 
continues  throughout  Greek  thought.  The  question  is  where  religious  belief  ends 
and  metaphor  begins :  see  Millerd,  On  the  InterprettUion  of  Empedocles,  p.  84.  I  do 
not  doubt  that  Professor  Millerd,  as  well  as  Gilbert  (1.  c.  and  Meteorol,  Theorien,  etc., 
p.  110,  n.  1)  and  Adam,  The  Religious  Teachers  of  Oreeee,  pp.  184-190,  248,  250,  go 
too  far  in  accepting  as  sober  belief  what  was  in  fact '  poetic '  metaphor.  See  Burnet, 
p.  74  folL,  p.  288  foil.  Rohde  says  {Psyche  ii.  2)  "  Wer  unter  Griechen  unsterblich 
sagt,  sagt  Oott :  das  sind  Wechselbegriffe."  This  statement  certainly  requires  quali- 
fication  ;  but  this  is  not  the  place  to  discuss  the  matter  at  length. 

s*  Ed.  Meyer,  Gesch.  des  AlUrtums,  I,  a  (2d  ed.),  pp.  97-100,  distinguish'es,  — 
aside  from  purely  magical  beings,— two  classes  of  gods:  I.   universal  gods,  con- 


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86  PROCEEDINGS  OP  THE  AMERICAN  ACADEMY. 

to  philosophioal  accounts  of  creation ;  '^  and  deriyatiye  forms  of  exis- 
tence are  called  Icyovoi  or  d^dyovot  of  the  elements.*^  In  other  words, 
the  philosophers  were  in  effect  giving  the  genealogy  of  the  world.*' 

ceived  as  presiding  over  certain  spheres  of  the  (physical  or  intellectual)  world  every, 
where  and  for  all  men  ;  II.  particular  gods,  having  locally  or  tribally  circumscribed 
spheres.  There  is,  of  course,  a  certain  overlapping.  The  gods  of  the  first  class  exist 
as  permanent  beings  by  reason  of  the  eternally  identical  activities  proceeding  from 
them  ;  those  of  the  second  class  attain  permanence  and  personality  by  reason  of  the 
institution  of  a  fixed  cult  Many  gods  of  the  first  class  poMsess  little  or  no  cult,  but 
stand  as  representatives  of  natural  laws.  '*No  one,"  says  Professor  Burnet,  p.  75, 
n.  1,  *' worshipped  Okeanos  and  Tethys,  or  even  Ouranos."  Since  the  superior  gods 
of  Greece  are  largely  of  this  class,  it  is  not  difiicult  to  see  how  i-eligion  proved  a 
schoolmaster  to  lead  the  Greeks  to  philosophy. 

••  For  examples  see  Bonitz's  Index,  150*  7  foil.  Cp.  such  expressions  as  7«vw<r« 
8i  [xaBriTtKad  Swdfuii]  t6  Otpft^  koI  i^vxP^  Kparoxhrra  rrjt  OXi;f,  Meteor.  379*  1 ;  M^rd 
W  ro^TTovi  KoX  rAf  roia&ras  dpx^h  <^  «^X  ^ojrw  o(fff(a¥  ytnnjffai  r^  tCjv  tmaif  0i^tr, 
Met.  984^  8.     Cp.  Plato,  TheaU.  153  A. 

•*  Similar  expreasions  abound,  as,  e.g.  tA  bk  (DCKa  ix  ro&ruv.  See  my  article. 
Qualitative  Change  in  Pre-Socratic  Philosophy,  notes  86  and  41. 

•*  In  this  connexion  it  is  proper  to  refer  to  the  beginnings  of  Greek  historiography 
—  both  are  laroplai.  In  each  case  it  is  the  desire  of  the  tarup  to  go  back  to  first 
principles.  Professor  Millerd  speaks  of  Empedocles'  Il€pl  4f^€ui  as  a  '*  world  story  ; " 
such  in  truth  it  is.  History  appears  to  have  grown  up  among  the  Greeks  in  con- 
nexion with  Genealogy,  dealing  with  icrlaeis  and  other  similar  events.  In  Xeno- 
phanes,  according  to  tradition,  the  two  interests  of  Urropla  were  naturally  united. 
His  physical  derivation  of  the  present  world  constituted  his  natural  philosophy ; 
on  the  historical  side,  he  is  reported  to  have  composed  poems  on  the  founding  of 
Colophon  and  the  colonization  of  Elea.  While  this  latter  statement  may  be  ques- 
tioned (see  Hiller,  Rh.  M.,  N.  F.  88,  529)  on  external  grounds,  it  is  not  per  se 
improbable.  The  Book  of  Genesis  similarly  unites  interest  in  creation  and  the 
derivation  and  early  history  of  a  people.  It  seems  to  be  natural  to  the  human 
mind  to  put  explanation  in  the  form  of  a  story ;  even  where  it  is  a  question  of 
explaining  how  present  phenomena  occur,  it  is  usual  to  cast  the  answer  into  the 
form  of  origines.  This  tendency  has  misled  historians  of  Greek  philosophy  at  many 
points  into  the  vain  endeavor  to  distinguish  between  the  current  cosmic  processes 
and  the  story  of  creation.  Another  matter  of  much  interest  is  the  relation  of 
creation-story  and  genealogy,  which  are  thus  united  in  Urroplri  xepi  ^i^eo^,  to  the 
religious  Upbs  Xiyos  or  gospel.  Of  this  I  have  spoken  incidentally  in  another  con- 
nexion ;  but  it  is  obvious,  even  at  a  glance,  that  in  Genesis,  for  example,  they  are 
virtually  identical.  In  later  schools  of  Greek  philosophy  the  naiurae  ratio  was 
clearly  and  consciously  felt  to  be  a  gospel.  It  is  therefore  interesting  to  note  that 
of  the  four  Christian  Gospels,  three  in  various  ways  link  the  gospel  story  proper 
with  the  story  of  creation.  Mark,  the  **  human  Gospel,"  omits  this  essential  link. 
The  later  Gospels  supply  it :  Matthew  is  content  to  trace  the  genealogy  of  Jesus  to 
Abraham,  from  which  point  the  story  was  familiar ;  Luke  carries  it  back  to  Adam, 
"the  son  of  God;"  John  goes  back  to  the  "beginning"  and  finds  the  A670J,  or 
Gospel  Incarnate,  with  God  before,  and  preparatory  to,  creation.  Hence  he  can 
dispe'hse  with  a  genealogy.  One  must  bear  in  mind  the  supposed  compelling  force 
of  genealogy  in  prayers.    Among  many  peoples  we  find  the  practice  of  addressing 


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HEIDEL.  —  n^l  ^iciff.  87 

The  iDtimate  oonnezioii  of  physical  philosophy  with  theogony  and 
cosmogony  has  thus  been  emphasized  because  it  appears  fundamental 
to  any  intelligent  inquiry  into  the  meaning  and  nature  of  the  former ; 
yet  no  one  would  deny  that  there  is  a  distinction  to  be  drawn  between 
these  cognate  forms  of  speculation  on  the  origin  and  operations  of  the 
world.  The  important  point  to  determine  is  just  wherein  the  essential 
difference  consists. 

In  Plato  there  is  a  clear  distinction  drawn  between  fiv$o^  and  Aoyo? ; 
with  him  fivOoKoyla  is  associated  with  iroirjai^^  and,  when  contrasted 
with  Xoyos  or  urropia^  denotes  that  which  is  fictitious  as  opposed  to 
sober  truth.  Herein  Plato  reflects  the  spirit  of  the  sixth  and  fifth  cen- 
turies, B.  c,  which  brought  science  to  the  birth.  Of  that  period  Xeno- 
phanes  is  an  interesting  representative.  We  have  seen  that  he  com- 
bined the  various  interests  of  urropio,  and  he  naturally  found  himself 
in  hostility  to  Homer  ••  and  all  for  which  Homer  stood.  Homer  stood 
for  epic  poetry,  and  epic  poetry  stood  for  fivOo^.  To  the  mind  of  Xeno- 
phanes  the  myths  of  Titans,  Giants,  and  Centaurs  are  vkdo-fAara  rlov 
wporifHoy  ,  .  .  tomt'  ov&h^  xprforov  o'cori.  Indeed,  what  could  such  fic- 
tions profit  an  age  that  was  busily  engaged  in  sweeping  the  mists  firom 
the  crest  of  Ol3rmpus  to  let  in  the  dry  light  of  reason  ?  Hecataeus,  an- 
other child  of  the  sixth  century  and  a  Xoyoypa^os  or  devotee  of  'urropLo, 
in  the  introductory  sentence  of  his  Genealogies,  says  : •*  "I  write  the 
following  as  it  seems  to  me  in  tnith ;  for  the  tales  (Aoyoi)  of  the  Greeks 
are  many  and,  as  I  think,  absurd.''  He  employs  the  term  Xoyoi  where 
a  later  writer  would  probably  have  said  fAvOoi ;  for  he  refers  to  Greek 
mythical  genealogies.  Yet  Xoyo$  had  even  in  his  day  come  to  mean 
prose  ••  as  opposed  to  epic  composition,  and  Hecataeus  proposed  to  use 
the  new  vehicle  of  artistic  expression  in  the  service  of  sober  truth  or 
toTopto.**    It  is  noteworthy  that  he  criticises  the  stories  of  "the 

the  gods  in  prayer  and  enforcing  the  fnlfilment  of  the  request  by  giving  the  genealogy 
(or  as  Herodotus,  i.  132  says,  the  deoyoviri)  of  the  divinities.  This  is  in  turn  con- 
nected with  the  magical  procedure,  which  consists  in  ''assigning  the  cause"  and 
telling  how  that  which,  e.  g.,  produced  the  wound  (say,  iron)  originated,  thus  con- 
trolling the  cause  and  effecting  a  cure.  On  this  see  Stewart,  The  Myths  of  Plato, 
p.  10  folL,  who  calls  this  the  **aetiological  myth." 

••  See  Diels,  Parmenides  Lehrgedichl,  p.  10. 

»*  Fr.  832.  MUUer. 

••  What  the  substitution  of  prose  for  verse  meant  to  philosophical  thought  can  be 
best  appreciated,  perhaps,  in  connexion  with  Parmenides  and  Em])edocles.  Par- 
menides tried  to  write  verse  like  a  philosopher,  and  was  ridiculed  as  a  shabby  poet ; 
Empedocles  tried  to  write  philosophy  like  a  poet,  and  is  regarded  as  a  fifth-rate 
thinker  for  his  pains. 

••  For  IffToplri  see  Stein  on  Hdt.  i.  1  ;  for  XAyof,  ibid,,  i,  21.  For  the  whole 
matter,  see  Bury,  Ancient  Greek  Historians,  p.  16. 


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88  PROCEEDINGS  OF  THE  AMEBICAN  ACADEMT. 

Greeks,"  •^  finding  them  utterly  ridiculous.  The  new  era  of  travel  and 
research  had  brought  to  light  many  an  evidence  that  things  were  not 
what  they  seemed,  at  least  that  much  which  passed  for  true  and  un- 
questionable among  the  Greeks  was  differently  conceived  or  otherwise 
done  in  other  lands.**  The  age  of  the  Sophists  merely  made  common 
property  what  had  for  a  hundred  years  exercised  the  wits  of  the  great 
leaders  of  the  new  thought. 

We  have  seen  that  Greek  religion  in  the  Homeric  age  harbored  two 
conceptions  which  contained  the  promise  of  disintegration,  though  they « 
still  dwelt  peacefully  side  by  side.  According  to  the  one  conception 
every  event  was  equally  divine  and  so  equally  "  natural,"  occasioning 
no  surprise ;  according  to  the  other,  certain  provinces  of  the  world, 
physical  and  intellectual,  were  apportioned  to  the  "  wide-ruling  gods  " 
of  Olympus.  The  former  tended  to  dull  the  fiwulty  of  curiosity,  the 
latter  to  stimulate  it  For,  in  a  sense,  the  Olympians  were  personified 
laws  of  Nature.  With  the  increasing  organization  of  experience  came 
greater  emphasis  upon  the  "  Gotterstaat "  and  overlordship  of  Zeus,  who 
assumed  more  and  more  the  title  of  0co9  par  excellence  and  subordinated 
the  lesser  gods  to  himself,  reducing  them  in  the  end  to  expressions  of 
his  sovereign  pleasure.  But  back  of  Zeus,  even  in  Homer,  lurks  the 
mysterious  power  of  MoTpo,  before  whose  might  even  the  "  pleasure  " 
of  Zeus  avails  littla  As  Zeus  subdues  the  lesser  gods,  so  Fate  or  Law 
subdues  Zeus  to  her  inexorable  will.  But  the  bright  patterns  woven 
into  Greek  mythology,  based  as  they  were  upon  personal  caprice  and 

•T  Bernays,  Abh.  der  Berl.  Akad.,  1882,  p.  70,  refers  to  Anaxagoras  (fr.  17  Diels  : 
rd  8i  yUf€(r$ai  kuI  dv6\\vir6ai  oitK  dpSCis  pofil^ovffip  ol  'EXXiyi^es),  to  Hecataeus  (fr.  SS2), 
Philodemtis  (II.  eifjeptlas  p.  84,  Gomp.:  Ihrovs  4>aaltf  ol  IlaviWrpftt  tfeoi/f)  and  adds  : 
*'  Es  ist  die  Tornehme  Art  der  Philosophen  von  dem  Volk  zii  reden."  Compare  also 
Empedocles,  fr.  8  and  9  (Diels).  The  feeling  is  deeper  than  mere  pride :  it  marks  the 
exaltation  of  the  philosophical  Xinyos,  as  the  statement  of  ^^is,  over  the  popular 
X&fos  which  stands  for  »6fios  and  fivBos,  Bury,  Ancient  Greek  Historians^  p.  51,  n.  2, 
remarks  that  when  Herodotus  quotes  aud  criticises  oi  'EWipfts  he  is  contrasting  the 
Greek  tradition  with  that  of  Phcenicians,  Persians,  or  Eg}'ptian8,  and  ''is  really 
quoting  criticisms  of  Hecataeus  on  oL  'EWiTrcf,  that  is,  on  the  current  mythology  of 
epic  tradition." 

••  It  would  be  foolish  to  claim  for  any  one  cause  the  determining  influence  in 
giving  direction  and  scope  to  the  nascent  rationalism  of  the  sixth  century.  Travel 
and  research  could  furnish  the  content  and  supply  the  materials  for  reflective  thought ; 
but  both  presuppose  the  divine  curiosity  which  is  the  parent  of  philosophy.  Many 
influences  conspired  to  produce  the  revolution  in  thought ;  but  travel  may  well  have 
contributed  most  to  convert  curiosity  into  astonishment  The  curious  collections  of 
strange  and  shocking  customs,  of  which  we  find  echoes  in  Herodotus,  Hippocrates, 
the  AuiX^^etf,  etc.,  clearly  originated  in  the  sixth  century,  and  supplied  the  arsenal  of 
the  militant  Sophists. 


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HEIDEL.  —  n^l  ^^trm9.  89 

anUiropomorphic  passions,  ill  comported  with  the  growth  of  reason 
which  demanded  submission  to  universal  law.  Greek  religion  experi- 
enced the  inevitable  conflict  between  the  imagination,  the  flowering  of 
the  capricions  fisMmlties  of  yoath,  and  the  reflective  reason,  in  which  the 
maturing  powers  assert  their  right  to  fixed  habits  of  thought 

Now  ifnxrvoXoyia  is  simply  Xoyo?  or  Urropia  wc/ji  ^vcrcco^,  — ^  the  child 
of  the  maturing  age  which  set  itself  to  discard  or  disregard  childish 
things  and  to  see  things  as  they  are.  Thus  Xoyos  vtpl  Ktiwrtoys  succeeds 
fivOoq  wtpl  Oaav.  The  transition  is  natural ;  but  it  involves  an  element 
of  opposition  which  could  not  help  but  be  painful  and  even  bitter  as 
the  extent  and  bearings  of  the  inevitable  conflict  came  to  consciousness. 
The  history  of  pre-Socratic  philosophy  is  the  history  of  this  conflict ; 
bat  the  opposition  was  not  final  The  strain  of  conflicting  ideals  re- 
salted  in  a  new  synthesis.  Plato  and  Aristotle  sought  to  effect  such 
a  83mthesis,  and  the  endeavor  to  perfect  it  is  the  characteristic  of 
the  main  current  of  post- Aristotelian  philosophy  firom  the  Stoics  to 
Flotinus. 

Gibbon's  sajring,**  "  Freedom  is  the  first  step  to  curiosity  and  knowl- 
edge," nowhere  finds  fuller  application  or  illustration  than  in  the  history 
of  Greek  philosophical  thought;  and  nowhere  did  the  early  Greek 
thinkers  so  much  feel  the  need  of  asserting  their  freedom  as  in  the 
sphere  of  opinion  where  there  was  an  actual  or  possible  clash  with  the 
received  theology  in  the  guise  of  fivOo^.  From  the  first,  philosophers 
had  broken  with  it  in  intention,  however  much  haunted  they  might 
have  been  individually  or  collectively  by  presuppositions  formulated  in 
their  mythology.  It  should  occasion  no  surprise  to  find  inconsisten- 
cies and  lapses  firom  their  principles ;  for  such  are  common  in  all  ages, 
because  of  the  imperfect  fluidity  of  the  mental  content^  which  refuses 
to  be  reshaped  at  a  cast  Nor  should  we  expect  to  find  the  principles 
operating  to  the  regeneration  of  thought  explicitly  stated  at  the  be- 
ginning :  it  is  the  rule  that  the  clear  enunciation  of  principles  follows, 
often  t£krdily,  the  tacit  application  of  them.  Plato  speaks  of  the  ancient 
feud  between  poetry  and  philosophy ;  and  the  point  of  contention  con- 
cerns fivOo^,^  Plato  also  well  expresses  the  fundamental  difference  be- 
tween the  two.  To  him  the  poet  is  a  OeTo^  avT^p,^^  a  seer  who  works  by 
inspiration ;  ^'  the  philosopher  must  follow  the  argument,  even  against 


••  Decline  and  Fall,  ch.  66. 

*•  Bepub.  607  B.    See  Adam's  note  ad  loe.  and  TKe  Eeligioui  Teachers  qf  Greece, 

2  foil.,  401  foil. 

^  Kqnib,  868  A  (with  Adam's  note). 

«s  Jpol.  22  A  foU.,  etc. 


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90  PROCEEDINGS  OF  THE  AMEBICAN  ACADEBiT. 

his  inclination :  6  yap  Aoyo?  17/Mas  jjpci,  he  says  of  himself*'  in  apol- 
ogizing for  expelling  Homer  from  the  ideal  state  of  the  philosopher- 
king. 

In  the  Epicurean  Epistle  to  Pythocles  **  a  distinction  is  drawn  be- 
tween such  phenomena  as  admit  of  but  one  rational  explanation  and 
such  as  admit  of  several  explanations  equally  consonant  with  the  data 
of  sense.  In  the  former,  the  conclusion  must  be  categorically  affirmed ; 
in  regard  to  the  latter,  one  must  suspend  judgment :  "for  one  must 
conduct  investigations  into  the  operations  of  nature,  not  in  accordance 
with  vain  dogmas  and  ex-cathedra  pronouncements,  but  according  as  the 
phenomena^demand.  .  .  .  But  when  one  fails  to  state  one  possible  ex- 
planation and  rejects  another  that  is  equally  consonant  with  the  data 
of  sense,  it  is  evident  that  one  fedls  wholly  outside  the  breastworks  of 
science  and  lapses  into  ftvtfo«."  *• 

From  the  first  <^v<rtoXayta  or  urropla  ir€p\  ^vo-cws  is  characterized  by 
the  &uot  that  it  wholly  disregards  religious  authority  **  (yofio6€a'ia  of 

*•  Repiih.  607  B.  Following  the  lead  of  the  argument  is  a  commonplace  in  Plato  : 
cp.  Euthyph.  14  C,  Theaet.  172  D,  Oorg.  627  E,  Phaed,  82  D,  115  B,  Hepub.  865  D, 
894  D,  415  D,  Legg,  667  A. 

**  Diog.  Laert.  x.  86-87. 

*•  The  fear  of  fivdos  was  ever-present  to  Epicams  and  his  followers.  See  my 
Epicurea  (American  Journal  of  Philology,  xxiii.  p.  194)  and  compare  Ei)puii  A6^i, 
xi.-xiii.  and  Lucretius  i.  68  foil.,  102  foil.,  151  foil.,  v.  1183  foil.  See  also  Zeller, 
Phil,  der  Gricchen,  in.  (a),  397,  n.  2.  .  Epicurus  was,  however,  herein  only  following 
Democritus,  fr.  297  (Diels) :  htoi  Bprjrijs  <p6<r€<as  SidXinrtp  oi/c  elSbres  dtfOpunroty  ffw€idi^€i 
Si  TTJs  iv  Tip  pi(fi  KaKOirpaytiOff^rjs,  rbv  Tr}t  Piottjs  xP^^of  iv  rapaxcui  xal  06/3oif  raXoiirci^ 
piovffi,  ^ciJ5ea  xepl  rov  fierd  rijv  TeXevrijp  fivdowXaffTioyrci  XP^^^'  Bohde,  Psyche j  II, 
171,  n.  cast  suspicion  on  the  genuineness  of  this  fragment ;  but  it  has  been  well 
discussed  by  Nestle,  Philol.  67,  548.  Epicurus  required  that  one  judge  concerning 
what  cannot  be  seen  {rd  ASriXa)  on  the  analogy  of  that  which  is  visible.  In  this  also  he 
followed  the  pre-Socratics.  See  Sext.  Emp.,  vii.  140  At&rifios  di  rpla  Kar  avrhv  (i.  e. 
Democritus)  ^€7€i'  itvai  KpiT'^pia  •  t^j  fih  rOv  dfiiJXwy  icaraXiJ^ewt  rd  (pawhpuepo, '  **  ^^tf 
7df)  rCiv  dJiJXwi'  rd  0au'6/t«u,"  Cn  ^ifaiM  'Ava^y6pai  (fr.  21  a,  Diels),  df  irl  ro&rtp  Atf- 
fA6KptTos  ivaiMei.  The  same  injunction  was  given  to  the  physician  ;  see  Hippocrates, 
n.  Sialrris ;  1. 12  (6,  488  Littr^).  Epicurus  was  ridiculed  for  offering  explanations  which 
were  foolish  :  cp.  the  delectable  skit  in  Usener's  Epicurea,  p.  854,  27  foil.,  where  he  is 
taunted  with  believing  a  fwOapltp  ypaiiSei,  But  the  charge  was  disingenuous,  since  the 
explanation  in  question  was  only  one  of  several  among  which  he  allowed  his  followers 
to  choose,  since  the  matter  was  not  one  of  which  strict  account  was  required  of  the 
faithful. 

*•  It  would  be  impossible  to  prove  this  without  showing  in  detail  —  what  is  easy 
but  requires  more  space  than  can  be  allotted  to  it  here  —  how  the  conclusions  of  phi- 
losophers ran  from  the  first  counter  to  the  fundamental  assumptions  of  the  received 
theology.  The  philosophers  therefore  came  to  be  regarded  as  a  godless  crew :  cp. 
Plato,  ApoL  18  B  C,  19  B,  23  D  j  Xen.  Mem,  i.  2,  31 ;  Plut.  Pericle*,  c.  82  (law  of 
Diopithcs,  482  B.  o.). 


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HEIDEL.  —  n«pl  ^Cfnm.  91 

Epicurus)  and  prejudice  (ScartScu/ima),*^  luid  endeavors  to  explain 
natural  phenomena  on  the  basis  of  well  considered  facts  and  analo- 
gies,^ assuming  the  constancy  of  nature  and  the  universal  reign  of 
law.*«  Aristotle  says  that  the  early  philosophers  did  not  believe  in 
chance,**  and  we  find  objection  raised  even  to  the  conception  of  spon- 
taneity,'^ which  is  made  relative  to  human  ignorance. 

If  one  would  catch  the  spirit  of  that  age  one  must  read  the  priceless 
repository  of  fifth  century  thought  contained  in  the  Hippocratean  cor- 
pus and  the  fragments  of  the  Sophists.    So  little  remains  to  us  of  the 

**  Rohde,  Payehe  ii.  p.  90  draws  attention  to  the  conscioos  opposition  of  philos- 
ophers to  the  magicians,  etc.  The  same  opposition  developed  among  the  philosophical 
and  practical  physicians,  whence  they  also  have  been  traditionally  denounced  as  a 
godless  crew.  An  interesting  document  in  this  regard  is  Hippocrates  n.  Uprjs  wo^ov, 
quoted  below,  n.  133.  See  also  II.  irapi^cWcav  (8,468  Littr^)  :  rj  *Afyr4/uSi  al  yvmiKes 
dXXa  re  roXXd,  dXXd  8}j  koI  rd  TovXtrreX^ffrara  tQv  liMrloav  Kadiepovffi  twv  yvpaiKciujVf 
K€\€v6pTiMt¥  TiOf  fidrrewiff  ^(airarec^Moui.  II.  €^xVI^<^^St  5  (9,  234,  Littr^) :  The 
author  says  one  must  carry  philosophy  into  medicine,  and  vice  versa.  The  difference 
between  the  two  disciplines  is  slight :  among  other  things  they  have  in  common  is 
dd€undcufu»flrj ;  but  medicine  is  not  disposed  to  try  to  dethrone  the  gods — each  in 
its  own  sphere  ! 

*•  See  Rohde,  PsyeJie,  ii.  137.  The  pre-Socratic  literature  (including  Hijipo- 
crates)  is  a  remarkable  repository  of  interesting  observations  and  analogies,  including 
a  few  carefully  considered  experiments. 

*•  See  Rohde,  Pgyche,  ii.  138  ;  Milhaud,  Lemons  sur  les  Origins  de  la  ScUnce 
Oreeqtte,  p.  11  folL  Aristotle  says  Phys.  261^  25 :  4>v<rtKbp  ydp  r6  6fLoiu>s  ^etv  ip 
&vd<raxt.  Hippocr.  II.  0(><rtof  &p$pi^ov,  6  (6,  42  Littr^)  in  order  to  prove  that  some- 
thing is  #fOT4  ^^ip  says :  icai  ravra  roti^et  <roi  wdma  xatrav  iifiiprip  kcU  v^ficra  koL 
Xetftw^*  foi  9ip€0t,  fUxPts  ttp  dwarbs  j  t6  vyevfia  HXkcip  is  iofvrbw  Kal  rdXtv  fudUvai, 
dvparbs  di  (<rrai  f<rr  (Lp  rivoi  rovriwp  <rrepri$i  rCw  ^vyyeyov&rwp.  Who  could  give  a 
better  statement  of  the  constancy  of  natural  law  applied  to  a  given  case  ?  n.  dialTrjt 
I.  10  (6,  486  Littr^)  tO/d,  Sxep  rdm-unf  iTiKparieratf  diivov  Atram-a  jcord  <pCfftP.  Leu- 
cippus  (fr.  2  Diels)  :  oitdh  xpVfJ^  fJLdrnjp  yiyrrcu,  dXXd  rdyra  ix  \&yov  re  xal  inr  dtfdyKijs, 
Hippocr.  n.  d^/Kaf,  22  (1,  66  Kiihlewein) :  ylverai  di  /cord  <f>ii(rtp  Uatrra,  Epicurus 
and  Lucretius  (1, 150)  regard  the  dictum  "  nuUam  rem  e  nilo  gigni  divinitus  umquam  " 
as  the  cornerstone  of  a  rational  view  of  the  world  :  Aristotle  repeatedly  affii-ms  that  it 
was  the  common  postulate  of  the  early  philosophers.  Once  {de  Gen,  et  Corr.  317  »>  29) 
he  hints  that  the  intervention  of  the  gods  was  to  be  thereby  excluded  :  &  fidXurra 
<l>o^o6fuvoi  SieriXeffop  ol  wpQroi  ^i.Xo<ro<f>-fiaain€%  rb  ix  firiSevos  ylyeffOai  Tpovirdpxovros, 

»•  Arist.,  Phys,  196  •  5-11.  This  means,  of  course,  that  the  philosophers  believed 
their  principles  suflBcient  to  account  for  things.  When  later  writers  charge  the 
Atomista,  for  example,  with  having  recourse  to  chance,  this  is  said  from  the  point  of 
view  of  teleology :  a  purely  physical  cause  was  thought  to  be  no  cause  at  all.  On  the 
practical  side,  chance  is  luck.  The  physicians  thought  they  could  dispense  with  it ; 
see  below,  n.  152  and  153. 

•^  Hippocr.  n.  T^KiTf,  6  (6,  10  Littr^)  rb  a^bfiarw  o6  tfxilyercu  oMtjp  Ix<w  oitdefUjjp^ 
dXX'  ^  oCpofUL  fioupop,  Cp.  n.  Tpo<f>r}s,  14  (9,  102  Littr^)  avrbfiaTot  xal  ovk  adrbfAaroi, 
iffup  fih  ai/ToiAaroi,  alrl-Q  5'  o(Jk  ainbimroi.  In  the  popular  sense  rb  avr^fxarw  is 
allowed,  H.  poOjup,  A,  7  (6,  152  Litire),  H.  x^f^^,  ^  (5»  486  Littr^). 


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92  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

authentic  utterances  of  the  philosophers  of  the  sixth  and  fifth  centu- 
ries B.C.,  thai  we  should  study  with  especial  interest  the  body  of  liter- 
ature emanating  in  great  part  firom  the  pamphleteers  who  assimilated 
and  disseminated  the  teachings  of  the  great  masters.  The  latter  were, 
as  is  the  wont  of  true  men  of  science,  more  reserved  than  the  motley 
crowd  of  pseudo-scientists  who  caught  up  their  half-expressed  conclu- 
sions and  published  them  in  the  market  places  to  eager  laymen,  for 
whom  the  scientists  entertained  only  an  ill-concealed  contempt** 
No  opinion  was  so  well  established  that  they  would  not  sap  its  roots ; 
no  question  was  too  obscure  to  baffle  explanation.  A  certain  decorous 
respect  was  still  shown  for  the  gods ;  but  they  had  in  &ct  become  su- 
pernumeraries so  &r  as  concerned  the  explanation  of  the  world.  Thus 
Hippocrates  ''  says: "  In  matters  human  the  divine  is  the  chief  cause ; 
thereafter  the  constitutions  and  complexions  of  women  " ;  but  while  the 
divine  is  then  dismissed,  the  constitutions  and  complexions  of  women 
are  considered  at  length  and  made  to  account  for  everything.  In  other 
cases,  as,  e.  g.,  in  the  treatise  n.  l^^  vowrov,  the  gods  are  definitely 
ruled  out  as  a  particular  cause,  and  only  the  elemental  substances,  which 
rule  in  the  human  frame,  are  recognized  as  divine.'^  Thus  the  divine 
working  becomes  another  name  for  the  operation  of  Nature. 

A  good  illustration  of  this  procedure  is  found  in  Hippocrates,  n.  difxay 
vSarcDv  roinav.  After  remarking  that  the  Scjrthians  worship  the  eunuchs 
because  they  attribute  their  estate  to  a  god  and  fear  a  like  fate  for 
themselves,  the  author  says:**  ''I  myself  regard  this  as  divine,  as 
well  as  everything  else.  One  is  not  more  divine  nor  human  **  than 
another ;  but  all  are  on  the  same  level,  and  all  are  divina  Yet  every 
one  of  these  things  has  its  natural  cause,  and  none  occurs  without  a 
natural  cause.  I  will  now  explain  how  in  my  opinion  this  comes  about" 
Whereupon  the  author  proceeds  to  give  a  purely  naturalistic  explana- 
tion. You  will  note  here  the  words  Ikootov  .  .  .  c^ct  <l>wnv  t^v  cavrov  •^ 

**  See  above,  n.  87.  For  the  physicians,  see  Hippocr.  II.  dpdpioy,  67  (4,  280 
Littr^),  UpoppjrriKbv,  2  (9,  10  Littr^),  II.  Wx^f,  1  (6,  2  Littr^). 

»»  n.  ywauceliit  <f>tMTios,  1  (7,  812  Littr^).  Similarly  UpoyvwrrtK^tf,  1  (2, 112  Littr^) 
it  is  required  that  the  physician  stady  the  nature  of  the  disease  to  see  whether  it  is 
too  powerful  for  the  strength  of  the  body,  Apu  di  Kod  etn  BtTov  iyeffrt  h  r^t  poi^ouri, 
Kal  Tovriov  r^v  rp^yotar  iKfuu^dweuf,  Yet,  the  main  business  of  the  physician  is  with 
the  disease  and  its  natural  causes,  which  he  must  combat. 

•*  Hippocr.  n.  Upijs  ro^ovt  18  (6,  394  Littr^) :  raOro  5*  i^rl  BtuLt  &aT€  firfiip 
UtaKfAvwrra  r6  voOcJiiia  deiArtpof  rcoc  \oiirCap  lOVfffifMiTW  ropdi^etp,  dXXd  Tdirra  $€ia  Kal 
ivOpunrtpa  wdrra  *  0i^(y  6i  (x^i  tKOffrov  Kcd  5ijvafWf  i^*  itavrou.  For  the  last  phrase 
see  n.  57. 

w  Ch.  22,  p.  64  Kuhlewein.  ••  Cp.  n.  64. 

'^  Natorp,  Philos.  Monatshefte,  21,  581  detects  in  these  words  a  protest  against 
teleology.     I  think  he  is  in  error :  it  is  rather  a  protest  against  the  supposition  of 


A 


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HEIBEL.  —  n^l  ^^owt.  93 

fcoi  ovScv  oi^cv  ^ixrios  ytvcrcu.  —  "  Every  thing  has  its  natural  caase  and 
nothing  oocors  without  a  natural  cause.''  Natare  has  usurped  the 
power  of  deity.  Lest  any  should  &il  to  catch  his  meaning,  the  writer, 
after  detailing  his  naturalistic  explanation,  repeats:  "but  as  I  said 
above,  diis  is  equally  divine  with  other  things ;  but  everything  occurs 
in  accordance  with  natural  law."  Elsewhere  '*  Hippocrates  suggests 
tliat  it  is  ignorance  alone  which  inclines  the  vulgar  to  regard  epilepsy 
as  a  divine  visitation.  It  is  in  keeping  with  this  view  that  teleol- 
ogy is  excluded ;  even  where  a  modem  scientist  would  involuntarily 
slip  into  modes  of  expression  which  imply  final  causes,  the  pre-Socra- 
tics,  though  at  a  loss  for  a  satisfisu)tory  explanation,  offer  no  such  sug- 
gestion.** To  the  Socratics  it  was  a  scandal  that  Anaxagoras  made  no 
teleological  use  of  his  Novs.*<^ 

When  nature  was  thus  interpreted,  it  is  dear  that  the  gods  must 
suffer.  One  recourse  was  to  attribute  the  organization  of  the  world  to 
them,  and  then  to  have  done  with  theuL    This  is  suggested  by  Hip- 

a  direct  intervention  of  the  gods  in  the  regnlar  course  of  nature.  The  scientific 
assumption  of  proximate,  special  causes  is  perhaps  an  outgrowth  of  the  suppositions 
of  magic,  for  which  see  Ed.  Meyer,  Oesch.  des  Alterturtxs,  i.  (a)  p.  97.  Heraclitus, 
fr.  1  (Diels)  btaipiiav  fKCurroi'  «rard  0i^tv  Kal  ^pd^  Skus  ^ei  appears  to  mean  that 
the  philosopher  proposes  to  give  in  his  philosophical  Xiyos  both  the  general  law  or 
cause  (for  0iJ<rtj  includes  both ;  cp.  11.  lepijs  po^ov,  1  (6,  352  Littr^)  ^i^criv  /xiv  ^et 
(epilepsy)  Ifp  xal  rdi  Xoixd  pova-j^fiaray  Wev  yiverai '  4>^<ruf  8i  airrj  xal  Tp6<f>aauf  ktX.) 
and  the  proximate,  particular  cause.  This  latter  promise  he  failed,  of  course,  to 
keep  ;  but  that  is  true  of  every  philosophy  that  has  been,  or  ever  will  be,  devised. 

••  n.  UpTjs  Poi^oVf  I  (6,  352  Littre)  icard.  fUp  rrp  iwoplrpr  ainoiai  tov  fi^  yiyiinrKew 
t6  B€io¥  avrj  diaff<»>^€rai.  The  similarity  of  this  case  with  that  of  tiJxi?  and  t6  airrb- 
fiaTO¥  (see  above,  n.  50  and  51)  is  at  once  apfmreut.  Science  can  dispense  with 
chance  and  God,  in  proportion  as  it  apprehends  the  proximate  causes  of  things. 
The  religious  bearings  of  this  position  need  not  be  developed. 

••  Cp.  Hippocrates,  11.  <p(i(nos  waiSlov,  19,  21  (7,  606  and  510  foil.  Littr^)  in 
regard  to  the  nails  on  fingers  and  toes,  and  in  regard  to  the  rising  of  milk  to  the 
breasts  of  the  mother  at  parturition.  Almost  countless  other  examples  might  be 
citiMl.  The  significance  of  thi»  fact  is  made  clear  when  one  thinks  of  the  constant 
opposition  of  t6  o5  heica  to  t6  dj^ayKoiop  by  Aristotle  (Hist.  Animal.,  Partt.  Animal., 
etc. )  and  Galen  {De  Usu  Partt. ),  the  latter  being  the  point  of  view  of  the  pre-Socrat- 
ics,  the  former  that  of  the  Socratic.  Plato,  Tim,  46  C  foil,  regards  physical  causes 
as  mere  avwalTta,  off  0€6t  imjpeTovffiP  XAT^**  ''^  "^^^  dplffrov  irord  tA  hvvarbv  lb4ap 

••  See  Diels,  Vor9okratiker,  Anaxagoras,  §  47.  Rohde,  Psyche  ii.  192,  n.  1  gives 
the  impression  that  Anaxagoras  employed  teleology.  Such  a  statement  would  be 
absurd.  Our  sources  are  explicit  on  this  head.  Proclus  ad  Tim,  (ed.  Diehl.  i.  1) 
says  :  *Aw|.,  tti^  doKei  Kad€v66yT<i>v  rwp  dXXbw  rbw  vovv  atriov  itrra  rCiv  yiyrofi^vup 
tdtiv,  o^Sip  iv  rats  dvoS6^€(rt  ir^ocrxp^Tat  t$  vf.  I  add  the  passage  because 
y  it  is  omitted  by  Diels.    Cp.  Gilbert,  AristoteUs  mid  die  ForsokrcUiker,  Philol.,  68, 

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94  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

pocrates,*^  and  was,  apparently,  the  r61e  assigned  by  Anaxagoras  to  his 
NoOs.  Disguise  it  as  he  might,  Aristotle  could  find  no  better  solution 
of  the  problem.  Plato  **  puts  the  question  sharply  as  between  Gk>d 
and  Nature,  and  says  that  the  majority  iavor  the  latter.  Such,  indeed, 
was  for  the  moment  the  logical  outcome  of  the  pre-Socratic  movement 
of  thought.  It  might  be  allowed  that  the  idea  of  God  was  innate ;  •• 
but,  like  all  other  ideas,  it  was  more  likely  to  be  regarded  as  haying  a 
history,  and  as  requiring  explanation  along  with  the  other  immediate 
(<^vcris)  or  mediate  (vdfto?)  products  of  nature.  Thus,  among  others, 
Critias  *^  explained  belief  in  the  gods  as  a  deliberate  fiction  concocted 
by  a  clever  statesman  to  enforce  morality  beyond  the  reach  of  the  law, 
supporting  it  with  the  natural  fears  inspired  in  man  by  ra  ficrectf/Hz.  It 
is  not  necessary  here  to  rehearse  the  fiamiliar  story  of  rationalism  as 
applied  to  religion  in  the  fifth  century,  B.C.;  *'  but  it  is  not  too  much 
to  say  that  philosophy  had  deliberately  enthroned  Nature  in  the  place 
of  God. 

But  nature,  thus  completely  depersonalized,  could  not  so  remain 
indefinitely.  Conceived  as  the  power  that  brings  to  pass  all  the  events 
constituting  the  sum  of  experience,  nature  became  in  fact  a  Creator 
and  Governor,  only  deprived  of  reason  and  purpose,  and  identified 
with  the  sum  of  existence.**  The  Greek  mind,  with  its  plastic  imagin- 
ation, was  not  likely,  however,  permanently  to  acquiesce  in  this  imper- 
sonal view  of  nature,  although  ^wri^  was  extremely  late  in  attaining 
personification  as  a  deity. *^  Yet,  as  we  shall  see,**  a  good  beginning 
was  made  in  the  pre-Socratic  period.  The  transfer  of  the  functions 
and  attributes  of  the  ancient  gods  to  ^wri^  by  the  philosophers  of  the 

*^  n.  SialrriSj  I.  11  (6,  486  Littr^)  4>^uf  B^  rdm-wp  0€oi  SuKdfffittffOP. 

**  Soph,  265  C  i^ijn  d^  wdirra  Omfrii  xal  S^i  kclI  ^vrd  .  .  .  fiuv  dWov  rufbt  ^  Otov 
drffuoupyoDirros  if>i^otiep  IkrTepop  ylyvtaSai  xp&rtpw  oi>K  /Jrro ;  ff  rf  tCjp  roXXuw  dSyfiaTi 
Kol  ^'^fJMTt  xp^fJ^^oi  .  .  .  r^  ^ifiTtp  aitrd  ycwoM  dir6  rivot  atrlas  airrofidTrfi  koX  Am(V 
diayolas  ^voiarit,  1j  /ierA  \6yov  re  xal  iTiffufffifis  Betas  dwb  d€ov  yiyvofi^mis ; 

••  Hippocrates,  n.  €^<Txvt^i'0<r6yrjt,  6  (9,  284  Littre)  koX  ydp  fidXurra  ^  wtpl  d(Q¥ 
tVhtais  h  wdtp  a^j)  ifiTXiKcrai, 

•*  In  the  Satyr  drama  Sisyphus^  fr.  25  (Diels). 

••  See  Decharme,  La  Critique  des  Traditions  Religieuaes  ehez  les  Orecs^l^i, 

••  Cp.  XL  62.  With  the  necessary  additions  drawn  from  that  passage  the  follow- 
ing definition  of  ^icn  by  lamblichus  (Stobaens,  i.  80,  9  Wachsinuth)  well  expresses 
the  conception  of  the  pre-Socratics :  ^6auf  8i  Xiyta  t^  dx(6/ot<rroy  cUrlaw  roO  k6<thov 
KoX  dx<apl<mat  xcpUxovffOP  rd%  SKat  alrlas  Trjs  ycp^ffeun,  Cp.  also  Hermes  (Stobaens 
I.  289,  26  Wachsmuth)  ^  0(^is  rdprw,  ^^vaa  rd  yiyvSiupo^  <pu'qv  {^  ^i^iv)  rap^xd 
Tois  ^vofiipois. 

w  See  K.  Preisendanz,  Philologus,  XLViix.  (1908)  pp.  474-5.  *«J<rtf  is  worshipped 
in  the  tenth  Orphic  Hymn. 

M  See  below,  notes  106  folL 


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HEiDEL.  —  n^l  ^^vtm.  95 

sixth  and  fifth  oentaries  eventaally  bo  charged  Nature  with  personal- 
ity that  the  Socratio  teleology  was  a  foregone  conclusion.  From  Plato 
onwards,  with  few  exceptions,  philosophers  proceed  with  the  Sjmthesis: 
the  gods  act  according  to  the  laws  of  nature,  and  Nature  assumes  the 
divinity  of  the  gods. 

11. 

After  thus  sketching  the  setting  of  those  works  which  by  common 
consent  bore  the  title  n^l  <^v(r€<i)9,  it  is  proposed  in  this  section  to  con- 
sider the  use  of  the  term  <^u(rts  among  the  Greeks  of  the  pre-Socratic 
period.  Although  this  study  is  based  upon  a  collection  of  passages 
nearly  if  not  quite  complete,  it  is  not  intended  to  treat  the  subject  ex- 
haustively, classifying  each  occurrence  of  the  term.  Such  an  exhibit^ 
if  carefully  and  intelligently  made,  would  serve  a  valuable  purpose  ;  its 
main  uses  would,  however,  be  lexicographical  rather  tham  historical 
and  philosophical  The  purpose  of  this  section  is  the  more  modest  one 
of  determining  somewhat  roughly  the  range  of  the  term  ^ixrts,  in  the 
period  under  discussion,  as  an  index  of  the  scope  of  the  conception  of 
Nature.  While  the  chief  emphasis  will  properly  fiJl  on  works  to  be 
dated  before  400  b.c.,  we  shall  have  occasion  to  use,  with  proper  pre- 
cautions, also  certain  writings  of  later  date,  such  as  those  of  Plato  and 
Aristotle.  Indeed,  the  careful  student  is  not  likely  to  be  greatly  mis- 
led in  this  matter  by  any  text  of  ancient  Greek  literature.  The  reason 
is  already  clear.  The  philosophy  of  the  Greeks  prior  to  400  b.c.,  with 
the  sole  exception  of  that  of  Socrates,  may  all  be  properly  described  as 
concerning  itself  Tr€pl  <^vo-€a>9.  As  such  it  is  sharply  contrasted  with 
the  later  systems,  the  main  interest  of  which,  with  few  and  relatively 
nnimportiuit  exceptions,  lies  elsewhere  :  to  wit,  in  the  spheres  of  logic, 
ethics,  and  metaphysics.  This  new  interest  did  not  date  from  Socra- 
tes, but  had,  like  all  conceptions,  an  interesting  history.  If  we  were 
here  concerned  with  this  history  we  should  have  to  retrace  our  steps, 
'beginning  once  more  with  Homer  and  the  popular  notions  of  the 
Greeks  embodied  in  religion,  mjrthology,  and  moral  precepts.  But  all 
this  would  yield  at  most  a  Vorgeschichte ;  for  the  method,  which  alone 
is  of  importance  in  philosophy  proper,  was  created  by  Socrates. 

There  are,  strictly  speaking,  only  two  periods  in  the  history  of  occi- 
dental philosophy,  the  pre-Socratic  and  the  Socratic.  The  first  took 
ei^temal  Nature  as  its  point  of  departure,  and  fixed  for  all  time  the 
fundamental  conceptions  of  physical  processes.  Even  where  it  con- 
sidered biological  and  intellectual  processes,  it  started  with  mechanical 
notions  and  arrived  in  the  end  at  materialistic  conclusions.  We  may, 
if  we  choose,  speak  of  the  ethics  or  metaphysics  of  the  pre-Socratics ; 


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96  PROCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 

bat  every  careful  student  will  be  conscious  of  a  fundamental  difference. 
Socrates,  by  introducing  the  logical  method  of  definition,  based  upon 
induction  and  employed  in  the  interest  of  deduction,  discovered  a 
new  order  of  existence,  which  was  subject  not  to  mechanical,  but  to 
teleological  laws.  Teleological  facts  were  known  from  the  beginning  of 
time,  and,  as  we  have  seen,  Nature  herself  became,  in  the  latter  part 
of  the  pre-Socratic  period,  charged  with  personality  in  a  measure 
which  made  a  new  interpretation  of  her  operations  a  foregone  conclu- 
sion ;  but  teleology,  considered  as  a  method  qf  eaplaTuUion,  was  a  dis- 
covery of  the  Socratics, 

The  significance  of  this  tact  can  hardly  be  measured ;  certainly  it 
has  not  been  appreciated  hitherto  by  historians  of  philosophy.  Among 
the  pre-Socratics  conceptions  have  been  found  which  were  certainly 
alien  to  their  range  of  thought ;  and  the  fundamental  significance  of 
the  revolution  wrought  by  Socrates  still  awaits  the  appreciation  which 
is  its  due.  Henceforth  the  world  is  definitively  divided  into  two  spheres, 
one  subject  to  mechanical,  the  other  subject  to  final,  causes.  The 
latter  alone  is  really  "  intelligible  " ;  of  the  other  we  may  say  ore,  not 
Siori.  The  later  Greek  systems  owe  their  basic  physical  concepts  ulti- 
mately, and  almost  exclusively,  to  the  pre-Socratics:  where  these  con- 
ceptions were  in  any  way  modified,  the  reasons  for  the  change  are 
commonly  to  be  sought  in  obviously  logical  or  metaphysical  considera- 
tions traceable  to  the  Socratics.  Hence  the  two  discrete  streams  of 
philosophical  thought,  though  externally  united,  flow  in  the  main 
peacefully  side  by  side,  clear  and  transparent  everywhere  save  at  the 
line  of  contact,  where  they  become  a  trifle  turbid.  Plato  and  Aristotle 
constantly  betray  their  dependence  upon  the  predecessors  of  Socrates 
for  their  physical  concepts ;  and  where  the  post- Aristotelians  departed 
from  the  specifically  Platonic- Aristotelian  doctrines^  they  harked  back 
firankly  to  one  or  another  of  the  pre-Socratics  for  their  physical  theories. 

In  the  following  sjmopsis  the  attempt  has  been  made  to  classify  the 
uses  of  the  word  ^vo-ts  in  such  sort  as  to  suggest  their  relations  one  to 
another  and  to  the  root-meaning,  which  is  assumed  to  be  "growth." 
The  scheme  makes  no  claim  to  finality  or  completeness,  being  intended 
primarily  as  a  means  of  displaying  in  a  more  or  less  logical  order  the 
chief  connotations  of  the  term.  The  inner  history  of  the  semasiology 
may  be  left  to  others  whose  interests  incline  them  to  such  studies.** 

••  I  regret  to  say  that  I  hiTC  not  been  able  to  obtain  Der  Begriffder  Physia  in  der 
gruchiaehen  Philosophies  I  Tbeil,  von  K  Hardy,  Berlin,  1884.  I  know  it  only  at  second 
hand,  chiefly  through  the  reviews  of  Natorp  (in  Philosophische  Monatshefte,  21  (1885), 
pp.  672-598)  and  of  Lorteing  (in  Bursian's  Jahresbericht,  96  (1899),  pp.  228-225). 
There  is  a  brief  study  of  ^6cis  in  Ch.  Huit,  La  Philosophie  de  la  Nature  chez  U» 


Digitized  by 


Gor" 


HEIDEL.  —  n^l  ^io^Mt. 


97 


)»rimary 
meaning,  "^ 
growth. 


I.  ^6<nt  as  a 
process. 


II.  <p6(nt  as 
the  be^D- 
uing  (»  a 
process. 


Synapsii  of  the  U$e$  of  4>6<nt, 

tA.  in  the  concrete :  growth  as  a  phenomenon  or  fact 
B.  in  the  abstract :  growth  as  a  law,  principle  or  *  force  * 
of  nature. 

'A.  the  starting  point  of  the  process  considered  imperson- 
ally as  phynical  element,  original  condition,  or  place 
of  origin.     (Aristotle's  **  material  cause.") 

NcUura  crcalrix, 
'  e&cient  cause.' 


B.  regarded  as  a  person  or  originator. 
(Aristotle's  "efficient  cause.") 


III.  0<^it  as 
the  end  or 
result  of  a 
process. 
(Aristotle's 
"final 
cause," 
which,  in 
the  com- 
plete circle 
is  identified 
with  the 
"efficient 
cause.") 


A.  regarded  from 


/'I.  individual,  —  0ui^,   (U/xi),    (Aris- 


B.  regarded  from 
within,  as  char- ^ 
acter  or  consti- 
tution. 


totle'a  hncKix^ia). 
:±"al  1JZ\  2-X''''=  -  generic.  -/««.  yi^. 
or  constitution.         ^ 

v8.  uniyersal,  —  KSafi^i. 

1.  physical:  'chemically*  define<l 
or  analyzed  into  its  constituent 
elements  in  pre-Socratic  times, 
regarded  with  reference  to  its 
origin  ;  (by  the  Socratics  defined 
teleologically,  with  reference  to 
its  meaning  or  end). 

^a.  regarded  positively, 
as  power,  talent,  in- 
stinct, native  endow- 

2.  mental -<      ""^o*- 
.  regarded  negatively, 

as     natural     limita- 
tions. 

Let  US  now  tarn  to  the  uses  of  ^vo-cs,  following  the  order  of  the  syn- 
opsis and  noting  the  implications  involved  in  them.  Etymologically 
^ixrts  means  "growth  : "  as  an  abstract  verbal  its  first  suggestion  (I.) 
is  that  of  a  process.    The  process  of  growth  may  be  regarded  concretely 

AncienSt  Paris,  1901,  pp.  65-69.  Somewhat  fuller  is  Woodbridge,  The  Dominant 
Conception,  of  the  Earliest  Greek  Philosophy,  Philas.  Rev.,  1901,  pp.  369-374,  which 
was  brought  to  my  attention,  after  this  article  was  in  the  hands  of  the  printer,  by 
Lovejoy,  The  Meaning  of  4>6<ns  in  the  Oreek  Physiologera,  Philos.  Rev.  (July), 
1909,  pp.  369-383.  Professor  W.  A.  Merrill's  study  of  The  SignifiecUion  and  Vm 
of  the  Word  Natura  hy  Lttcretius  (Proceedings  of  the  American  Philol.  Ass'n, 
July,  1891,  vol.  22,  pp.  xxxii-xxxiv)  will  serve  as  an  interesting  illustration  of  the 
influence  of  pre-Socratic  usac^e.  The  same  may  be  said  of  the  articles  nature^  kind, 
and  kin,  in  the  Oxford  English  Dictionary.  One  cannot  overlook  the  lexicographical 
stadies  of  ^t^tf  found  in  Aristotle's  Phys,  B,  1  (and  in  briefer  form.  Met.  A,  4). 
Reference  will  be  made  to  his  distinctions  at  the  proper  points  in  the  survey.  There 
are  several  wonls  of  similar  origin  and  meaning  which  should  be  studied  in  connex- 
ion with  ^(kth  if  a  really  exhaustive  account  of  the  word  is  to  be  given  from  a  lexi- 
cographical point  of  view.  Among  them  may  be  mentioned  ^vii  and  y4iva.  Of 
cnuree  ^iJfU'  in  all  its  uses  is  of  the  utmost  importance  ;  but,  for  our  present  purpose, 
these  may  be  disregarded,  except  for  occasional  illustration. 
VOL.  XLV. —  7 


Digitized  by  VjOOQIC 


98  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

(I.  A)  as  a  tact  or  phenomenon.  This  conception  was  to  the  Qreeks 
so  obyioQS  ^^  that  the  £sbct  of  natural  growth  lay  at  the  foundation  of 
their  thought  Growth  implies  life,  and  life  implies  motion.  This  is 
true  of  Greek  thought  always.  The  growth  denoted  by  ^ixrts  refers  to 
animal  as  well  as  to  vegetable  life ;  wherefore  <I>vt6v  appears  originally 
to  have  applied  to  the  former  as  well  as  to  the  latter.  It  is  noteworthy 
that  ^vo-is,  as  implying  motion,  seems  always  to  denote  a  process  or  a 
phase  of  such  process ;  that  is  to  say,  specifically  the  process  itself, 
taken  as  a  whole,^^  or  its  beginning,  progress,  or  end.  It  does  not  lend 
itself,  therefore,  to  use  as  an  absolute  0^x17 :  it  is  consequently  always 
opposed',  or  subordinated  to,  creative  force  as  such.^*  These  ideas 
clearly  hark  back  to  the  pre-Socratic  period.  In  Empedocles  we  find 
<^i^i9,  in  the  sense  of  absolute  origination,  denied  ;^'  in  Aristophanes  ^^ 
we  find  ^vo-ts  in  the  sense  of  origin.  It  is  difficult  to  classify  certain 
uses  of  f^vo-ts,  where  it  may  be  rendered  birth,  descent,  age,  lineage, 
etc.,  but  they  may  be  set  down  here  for  convenience.^' 
But  ^v(ri9,  as  a  process,  may  be  viewed  abstractly  (I.  B)  as  natural 

^*  Arist.  Phys,  193*  3  ws  5'  icriv  if  ^d<ns  T€ipcUr$at  dccici^at  yeXaiiop,  These  words 
apply  to  <t>C<ns  as  a  whole,  which,  according  to  Aristotle,  is  a  process. 

^  There  is  an  interesting  passage  in  Plato's  Phaedo  71  E  foil.,  where  he  is  apply- 
ing to  the  soul  the  principles  of  the  pre-Socratica  :  ovk  drrairodd>aofxep  t^p  ivojrriop 
y4y€ffiM,  dXXA  Ta&rjj  x^^h  ^(frat  ij  4>6<ns ;  1j  dvdyxrf  dvodoOtm  r^  iiirodrQ<rK€w  ivayriop 
TUfik  y4y€ffip; ,  .  ,  t6  dyapubffK€(T$ai.     Here  0i^(f  is  the  circular  process  as  a.  whole. 

^*  Thus  Arist.  can  say  if  biffuovp/y-fiaaaa  0i^if,  De  Parti,  Anim,  645*9,  but  that  is 
said  metaphorically ;  habitually  ^i/<rcf  is  opposed  to  diVa/tus  and  r^io;,  in  that  they 
operate  from  without,  whereas  ^tArcf  resides  within  :  De  Cael.  301^  17  iwcl  8i  tp^an 
lUv  iffTW  ij  hf  oi)r#  hwdpxovaa  KUfifaetai  i^x^»  S^tufus  i^  ij  ip  &\\(i>  -f  &\\o,  Cp.  Met. 
1049*8.  Met.  1070*  7  if  fihf  odv  rix^  ^PXh  ^  ^XXy,  if  6i  if>6<ns  dpxh  ^  ai>rf?.  As 
the  Stoics  regarded  God  as  immanent,  they  could  speak  of  Zeds  Tcxf^lrris.  In  Plato, 
Tim.  41  C  even  the  $€ol  0€wp  are  bidden :  rpireffdc  icard  ^iaip  OneTs  iirl  tV  tup 
^t^  drifuovpylop.  Without  discussing  whether  Plato's  Siffuovpryis  was  regarded  as  a 
creator  me^rly  icar*  iwlpoiop  or  not,  it  is  clear  that  nature  is  supposed  to  proceed 
according  to  her  own  laws,  and  *  creation  *  is  not  drX^  ^A^o-tf. 

^*  Fr.  8  (Diels) ;  <p6<ns  oiievds  iaruf  inrdjmav  \  Ovrp-Qv^  oif54  ris  oitXofx^ov  OapaToio 
TfX«in-iJ,  I  dXXd  fi6pop  fd^is  re  SidWa^ls  re  fuyirrufp  \  i<rrlf  0i^cf  3*  ixl  rotf  dpofidf^erai 
dpOpunrouriM,  Aristotle,  Met.  1014*35  curiously  misinterprets  ^i^ts  here,  equating  it 
with  TpiifTfi  <riJi^€<rtf,  possibly  because  he  misquoted  Uwrtav  for  drdirraw,  quoting  (as 
usual)  from  memory.  The  slavish  commentators  do  not  correct  him.  Empedocles 
implies  that  laymen  understand  ^tVcr  as  dTkri  7^0-it,  which  the  philosophers  one 
and  all  denied.  Aristotle  recognizes  0i^cf  «  yive<n%  Phys.  193*  12  #r(  b*  ij  ^Otris  ij 
\eyotUvri  lin  yimrts  Ms  4<rriP  els  4>6aiy  («-  els  oiMriav^  cp.  Met.  1003*  7).  Met.  1014*  16 
fpvffis  Xtferoi  .  ,  .  if  Twr  ^^vofUnap  yiveffts. 

^*  Ao.  691  ^lATU'  olu)i^  yivevip  re  deiop.  This  occurs  in  the  so-called  *Oi-phic 
cosmogony.' 

^'  Op.  Soph.  Ant,  726  ol  Ti?Xtifo/5e  koX  8t8a^Sfie<r$a  8/)  I  ^pw€iv  (nr*  d^dpbs  Tri\tKou9€ 
t)p  ^Offiu;  0.  C,  1295  dr  ^^ei  nJrrepot*    Track,  379  fj  Kipra  Xafixpd  koI  rar  ti^ofM 


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HEIDEL.  —  nipl  ^Ca-M9.  99 

law,  principle,  or  force.  As  we  have  seen,  ^vo-ts  and  ff>v€w  seemed  to 
imply  a  growth  from  within,  directed  not  by  an  external  force  or  power, 
bat  obedient  to  its  own  laws.  The  importance  of  this  conception  can- 
not easily  be  measared.  It  expresses  succinctly  the  opposition  of  urropta 
ir€fH  if>v<r€m  and  fiv$<K  ircpl  0€Qiv.  As  Aristotle  well  puts  it^  Phys,  192*" 
8  :  TCI  ftcK  C0T4  <fiva'€if  Ta  8c  St'  aXXjos  cuTw.  That  which  is  ^wrci  is  auto- 
nomous, or,  as  the  Socratics  would  say,  avroftarov.  The  pre-Socratics, 
when  they  use  to  avrofiarov  strictly,  deny  its  existence  in  nature,  since 
every  thing  has  its  cause,  though  we  may  be  ignorant  of  it  The  law 
of  nature  is  an  inner  constraint  or  dvaym^J*  Hence  ^vo-t?,  besides  be- 
ing the  embodiment  of  all  natural  laws,  is  also  tbe  mode  ^^  of  operation, 
or  Tp<nro9,  and  so  comes  to  mean  the  customary.  ^^  Indeed  habit  becomes 
a  "  second-nature,"  ^*  and  thus  approaches  vd/io9.*<>   It  was  apparently 

Kcd  ^{fffof.  Probably  the  last  («  lineage)  should  be  classed  under  III.  A,  2,  but 
many  cases  present  difficulties. 

^*  Eurip.  Troad,  886  ZeiJt,  cfr'  difdyicTf  0i5<reof  efrf  wDf  Pporuif,  Here,  as  often, 
it  is  difficult  to  distinguish  whethei  it  is  the  mode  or  the  force  which  predominates  in 
the  conception  of  law.  The  conception  of  0i5<rtj  as  comparable  to  ivdyKii  is  neatly 
shown  in  Hippocr.  II.  dudrrjSf  A,  28  (6,  502  Littr^)  i/vx^  M^  odv  aUl  d/xolrf  ical  iv  fU^ovi 
Koi  i¥  iXdiraovi '  o^  yhp  iWoiovrai  o(iT€  did  <f>Cffiv  oUrt  bC  di,vdyK7iv  autfui  Si  oifS^- 
KOT€  Tiah-b  oiht  «rard  <p6fftif  odd*  hx*  dpdyKr)S.  As  has  been  already  said,  the 
Socratics  did  not  really  understand  what  the  pre-Socratics  meant  by  saying  that  a 
phenomenon  occurs  d^dyiq) ;  as  it  was  opposed  to  what  occurs  according  to  design,  it 
was  rashly  described  almost  indifferently  as  due  to  no- cause  at  all,  to  tuxv*  or  to 
r6  a^S/mroif.     Cp.  such  popular  phrases  as  ij  dyayKoia  r{rx,%  Soph.,  Ai.  485. 

^  Hippocrates,  n.  dcriutv  ^iJ<rtoj,  18  (9, 194  Littre)  ^  ik  ix  tQv  dpLtmpGw  <p\4\f/ .  .  . 
rV  a^ifp  i>tuciP  ippli^iorai  rj  iv  rotai  Se^idiffu'.  If  one  compares  the  analogous  use  of 
dt^pafjuM,  e.g.  Hippocrates,  H.  5ta/Ti?j,  A,  10  (6,  484  Littr^)  6a\dfffffis  SOmfitv,  and  the 
common  adverbial  use  of  dlicrfy,  one  is  naturally  struck  by  the  circle  of  ideas  from 
which  the  usage  springs.  The  comparison  shows  the  need  of  caution  in  inferring 
etymology  from  particular  senses  of  a  word.  Cp.  Soph.,  PhiL^  164  f.  piorrji  <P\lktip 
(—  rp^w), 

^*  The  association  of  ^^is  with  t6  eluBSs  is  common  ;  see,  e.g.  Hippocrates,  II.  leprjs 
poOffov,  14  (6,  888  Littre)  ff  rt  dWo  ir€ir6p$rj  wddos  wapd  t^  ^^ip  6  fiij  iibdti.  Hpo- 
ywtaartK6pf  2  (2, 112  ff.  Littr^).  It  is  the  best  sign  in  regard  to  the  symptom,  €l  6px>i.b» 
itm  Tcliffi  rOtf  {rfuuvbvTtaVy  fidXiirra  8i  el  airrb  iu>vTi<t>,  oOna  ydp  Ay  efrj  dpivroVy  rh  hk 
ipamiinarop  rod  bpjotov^  dew&raToy,  (For  t6  <f>6(r€i  in  relation  to  likeness,  see  Proclus 
in  Platon,  CrcU,^  pp.  7,  18  ff.,  Pasquali.)  Ibid,  passim  rb  ^^pri$€t  is  regarded  as  /card 
^>^uf.  [Arist.]  Ftobl.  949»31  tA  rdXtp  e/s  rd  tlwdimi  iXOcuf  Ciarripia  yivrrai  avrois 
Cxnrep  c/f  ^Cffews  Kardaraaaf,  Thueyd,  II.  45,  2  (advice  to  women)  ttjs  re  ydp  inrap- 
Xo^ijt  4>^etas  fiij  x^^P^^^  y€v4<r0ai  ifup  fieydXri  ij  d6|a. 

^  Democritus,  fr.  33  ^  <f>6(ns  kcU  ij  Sidax^  xapaxXijirUiv  iffru  koI  ydp  ii  Stdaxh 
fternpwrfUH  rbv  ^jfOpwrov,  firrapvfffiowra  8i  4>v<noToui.  [Arist.]  Prohl,  949*  27  Ai^a 
lUv  Ti  xal  t6  fOos  iarlv  iKdarois  •  ^6ini  ydp  Ifiri  yivcrat.  Theophrastus,  C  P,  il.  5,  5 
t6  ydp  fOos  (referring  to  plant  life)  ClxTTep  ^o-ls  y4yope.  Cp.  Nauck,  Poet.  Trcig.  Fr, 
Adespota,  516 ;  Xen.  Lacon,  8,  4. 

**  The  fact  that  the  pre-Socratics  contrasted  ^i^is  and  v6tMt  is  instructive.    They 


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100  PROCEEDINGS  OP  THE  AMEBICAN  ACADEMY. 

on  the  analogy  of  such  words  as  ivaymy,*!  voftos,  airto,  84107,  ^<>ro«i  etc^ 

that  the  ubiquitous  constructions  #caTa  ^wiv,  irapa  ^wriv,  ^tKTCi,  <l>v(riv 

Ix^iVi*'  were  built  Though  they  often  connote  other  notions,  such  as 
cause,  their  fundamental  reference  seems  to  be  to  what  we  call  law. 
The  fi^uency  of  such  phrases  is  significant  of  the  prevailing  suggestion 
which  ^v(rt9  had  for  ^e  investigators  ircpl  <^v(re(09.  There  is  here  a 
marked  contrast  between  the  implicit  and  explicit  signification  of  terms. 
S^ch  phrases  as  vapa  ^vo-iv  have  no  proper  sense  except  in  relation  to 
a  teleological  interpretation  of  nature ;  *'  but  it  is  obvious  that  the 
pre-Socratics  were  not  aware  of  this  implication.  They  built  up  a 
structure  of  conceptions  which  of  necessity  led  to  teleology,  but  |t  was 

felt  instinctively  the  i>arallelism  of  human  and  physical  law,  hut  the  latter  was  con- 
sciously their  point  of  departure.  Yet  in  trying  to  interpret  physical  law,  they 
necessarily  imported  conceptions  derived  from  human  law,  as,  e.g.  the  dlxri  of  Anax- 
imauder  and  Heraclitus.  When  Simonides  said  d^dyKgi  d'  o{fS^  Otol  fidxom-ai  he 
meant  much  the  same  as  the  (intermittent)  tyranny  of  Motpa  in  Homer.  I  can- 
not but  think  that  Pindar  (Plato,  Gorg,  488  C,  484  B)  p6fios  6  vdtnrcw  paaiXeifs  Bparwif 
T€  Kcd  ddcLydrufp  —  d7€t  dtKoiiOf  t6  ^tai'jrarov  vTeprdrgL  x^^P^  meant  the  same  thing  : 
cp.  also  the  overruling  God  of  Heraclitus,  who  is  also  A/in;.  So,  at  any  rate,  Plato 
interpreted  the  saying  {Oorg.  483  C,  Legg.  THE),  as  did  Hippocrates,  H.  701^^,  1 
(7,  470  Littr^)  vSfios  /Up  wdvra  Kpar^i,  and  the  Anonymus  lamblichi  (Diels, 
Forsokr.^  6S2y  31  foil.).  Of  course,  in  an  age  when  4>6(ns  and  wofjLOi  were  contrasted, 
the  opposite  interpretation  would  also  be  found  ;  cp.  Plato,  Protag.  387  C  foil.,  Hdt., 
III.  38,  V  I.  104,  Critias,  fr.  25  (Diels).  Cp.  Galen,  i>«  Usu  Partium,  xi.  14  (in. 
905  f.  Kiihn),  and  Nestle,  Neue  Jahrb.  fiird.  klass.  Altert.,  1909,  p.  10  foil.  Zeller, 
Ueber  Bcgriff  u.  BegrUndang  der  sittlichen  Gesetze,  Abh,  d.  Berl.  Akad.,  1882,  cites 
some  interesting  phrases  characteristic  of  the  blending  of  ^(nrit  and  pb/un.  Cp.  Arist. 
Ciiel  268*  13,  Ariua  Did.  (Diels  Lhx,  464,24  if.).  The  latter,  siieakiug  of  the  Stoics, 
says  Kounapiav  J*  inrdpxfu^  rphs  dWi/jXovs  Sid  t6  Xiryov  furix^ip^  6%  itrri  4>(f<r€i  p6/ios. 
The  common  possession  of  reason  is  here  the  basis  of  law  :  conversely  in  Hippocrates, 
n.  hrrafxiivovy  9  (7,  460  Littr^)  the  possession  of  a  common  physical  composition  is 
the  foundation  of  the  inexorable  law  that  all  must  die :  Kal  ye  6  Odvaroi  5td  rijp 
fioiprip  fXax^f''  ^&tfTe  vapdSeiyfUL  toTj  ircUriP  elpoif  ^t  irdrro  <f>v<Tty  ix^ii  ^k  tCjp  aMwp 
ijvTo^  fiera^oXdt  fx^^  ^^  XP^"^"  ^<^  Upov/Upiop,  Here  iiolpa  has  become  expressly 
a  physical  law  inhering  in  matter. 

•^  Cp.  Thucyd.  v.  105  rfyo^neOa  ydp  t6  re  $€iop  86^-(f  t6  dy6pdnr€i6p  re  aa^tws  iid 
xaprbs  vir6  0(^(rewf  dpayKcUrfSy  oC  dy /cparj,  d/)x««' •  Kal  iifuU oCre  Ohrti  t6p  p6fiop 
kt\.  Cp.  Plato,  Gorg.  483  E ;  Eurip.,  Troad.  886  ;  Hipjiocrates,  H.  <rap<cwr,  19 
(8,  614  Littr^)  ttjs  di  4)6<nos  rijp  dpdyKTjp^  ^iirt  ip  hrrd  ro&reujp  fKaara  dioiKeirai,  iyC» 
<f>pd<r(i)  ip  dWoifftP.  U.  5ta/7^j,  A,  6  (6,  476  foil.  Littre)  wdvra  ylprrai  fit*  dpdy/cTfp  Oelrjp 
is  said  from  the  point  of  view  of  Heraclitus. 

**  With  ^6<rtp  (x^ip  one  should  class  such  uses  as  ^0i/,  Soph.  Elect,  860,  where  it 
stntes  a  natural  law.     One  also  meets  dpdyicrpf  ix^tp  Cxn-e  c.  inf. 

••  Natorp,  Philos.  Monatsh.  21,  p.  575  rightly  refers  to  this  fact ;  but  he  fails  to 
observe  that  the  pre-Socratics  did  not  draw  the  obvious  inference.  In  Aristotle,  of 
course,  the  thought  is  clearly  expressed,  e.g.  Phys,  193*  32  {i<rT€p  rixp^i  Xfyrrat  rh 
Kard  rix^nfPf  oOrw  koX  0i^ts  t6  Kard  p^tP  Xiyerau 


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HEIDEL.  —  IIipl  ^^KTiMf.  101 

the  Socratics  who  seized  the  import  of  their  labors,  and,  by  introducing 
the  teleological  method,  reconstituted  philosophy.  Even  in  the  post- 
Socratic  period  teleology,  because  seen  essentially  from  the  pre-Socratio 
point  of  view,  became,  for  example  among  the  Stoics,  an  idle  play-thing, 
being  purely  external** 

The  step  is  short  and  easy  from  <^ixrw,  regarded  as  a  process  eventu- 
ating in  a  result,  to  ^vo-t?  considered  as  the  author  or  source  of  that 
which  so  results  (II.).  The  distinction  must  lie  in  the  degree  of  em- 
phasis laid  upon  the  beginning  of  the  process  as  distinguished  from  its 
end,  and,  by  consequence,  in  the  degree  of  disruption  visited  upon  the 
process  as  a  whola  Such  a  separation  is  the  result  of  analysis,  and 
the  relative  prominence  of  the  members  into  which  the  unitary  process 
£bi11a  may  reasonably  be  supposed  to  indicate  the  direction  of  interest 
of  those  who  used  the  terms.  This  is,  however,  a  point  extraordinarily 
difficult  to  determine  in  a  satisfactory  way.  It  is  safe  to  say  that  the 
layman  is  chiefly  interested  in  ^vo-t^,  the  result  of  the  nature-process  : 
he  takes  it  for  granted  —  his  not  to  question  why.  It  must^  therefore, 
occasion  no  surprise  that  by  far  the  most  numerous  uses  of  <^v(7i9  belong 
to  this  class  (III.).  The  philosopher,  also,  must  begin  with  the  finished 
product  and  from  it  reason  back  to  ita  source.  In  a  peculiar  way  ^vo-t9 
in  this  sense  (II.)  will  occupy  his  attention ;  but  it  is  obvious  that  the 
distinction  between  cause  and  law  must  be  difficult  to  draw.  Even  in 
the  philosophical  and  scientific  literature  of  our  day  it  is  almost  im- 
possible to  maintain  a  sharp  distinction  between  them.  We  *may  be 
inclined  to  lay  this  to  the  charge  of  the  Aristotelian  usage ;  but  this 
solution  would  fiJl  short  of  historical  truth.  As  we  shall  see,  the  four- 
fold causation  of  Aristotle,  united  in  <f>va-K,  is  rooted  in  pre-Socratic 
usage,  though  Aristotle  reinterpreted  the  pre-Socratic  X0709  fttifcws,  or 
chemical  definition,  converting  it  into  a  Xdyo?  oia-w  as  the  result  of 
logical  definition,  and  at  the  same  time  made  explicit  the  unconscious 
teleology  of  the  pre-Socratics  by  recognizing  in  the  logical  definition 
the  final  cause. 

Touching  the  beginning  of  the  process,  the  philosophers  were  chiefly 
interested  in  what  Aristotle  styled  the  "material  cause"  (II.  A). 
There  is  no  reason  to  doubt  that  the  pre-Socratics  used  ^wris  in  this 
sense.*'    Aristotle  speaks  of  Thales  as  the  founder  of  the  philosophy 

•*  From  certain  points  of  view  modern  philosophy,  from  Kant  onwards,  may 
be  said  to  be  the  attempt  to  interpret  the  world  in  terms  of  teleology  consciously 
conceived  as  the  method  of  human  thought.  At  bottom  Pragmatism  is  hardly  any- 
thin;;  more  than  an  effort  to  do  this  consistently,  leaving  no  Absolute  outside  the 
teleological  process. 

*'  It  is  one  of  the  many  services  of  Baruet  (see  above,  n.  8)  that  he  directed 


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102  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

which  deals  with  the  material  cause,**  and  says  thai  the  majority  of 
the  first  philosophers  regarded  material  causes  as  the  sole  causes  of  all 
things.*^  Empedocles  **  uses  ^vo-ts  of  the  substance  contributed  by 
the  parents  to  the  birth  of  their  oflFspring,  and  Hippocrates  ••  does  so 
likewise  in  the  same  connexion.  In  another  passage  Hippocrates  well 
illustrates  this  force  of  <^v(ri9.  He  is  engaged  in  a  polemic  against  the 
monists,  who  assert  that  all  is  one,  and  makes  the  point  that  a  living 
being  does  not  arise  from  even  a  multiplicity  of  substances  unless  they 
are  mixed  in  the  right  proportions,**  and  hence  d  fortiori^  could  not 
arise  from  a  single  substance.    He  then  proceeds  :  *^  "  Such  being  the 

attention  to  this  usage,  though  I  cannot  but  differ  from  him  in  the  interpretation  of 
individual  texts.  It  would  serve  no  useful  purpose  to  specify  further  instances.  But 
it  should  be  noted  that  0iJ<rts  in  this  sense  means  *  natural  kind,*  and  hence  is  proba- 
bly denved  from  iii.  A,  2.     Op.  IS^ai^  n.  89,  and  ef5co,  n.  113. 

»•  Met.  983»»  20,  interpreted  by  983*  7  foil. 

•^  Met,  988*  7  :  tQv  5  J)  vpthnap  <^i\o<ro<prf<TdPT09w  ol  irXetOTO*  rdf  iw  CXrit  €{3ci  fiAi^s 
ifi-fldr^oM  ipx^f  ^^"ox  wimav,  Proclus  in  Tim,  (Diehl,  I.  p.  1)  says  to  the  same  effect 
cl  fih  ToXXoi  rw  vp6  ToO  HXdruvos  ^wriKtop  vepl  rffv  CXrpf  bUrpiyj/w,  Cp.  Gilbert, 
Aristoteles  und  die  Vorsokratiker,  Philol.  68,  368  foil. 

••  Fr.  63  dXXA  SUffTatrrai  fuX^ufP  0i^(f  •  ■^  ftiv  iv  dydp6s.  Diels  renders  :  **der 
Ursprung  der  Glieder  liegt  auseinander  ;"  Burnet :  **the  substance  of  (the  child's) 
limbs  is  divided  between  them,  part  of  it  in  the  man's  and  part  in  the  woman's 
(body).'*  Here  I  agree  in  the  main  with  Burnet.  The  phrase  fieXiufp  ff>6ffit  occurs 
also  in  Farm.,  fr.  16,  8,  where  Burnet  gives  it  the  same  sense,  whereas  Diels  renders  : 
"die  Beschaffenheit  seiner  Organe."     In  this  case  I  agree  with  Diels. 

••  n.  7or^t,  11  (7,  484  Littre)  iTr)tf  Si  rl  oi  p6<r7}fia  Tpoa-iri<rg  kuI  toO  iiypoO  a&roOf 
d0'  o5  t6  (rxipfia  yliKTaif  ricnrapes  ISiai  ioOffat,  6K6<rai  iv  tp^ati.  inrrjp^^  tV  yov^iv  oOx 
SXtpf  irapixovauff  ktX, 

••  IT.  <pOfftot  dy0p(^ov,  3  (6,  38  Littr^).  There  is  much  in  this  discussion  which 
applies  the  reasoning  of  Empedocles,  for  the  interpretation  of  whose  thought  it  is  of 
extreme  importance.  It  clearly  presupposes  and  combats  the  theory  of  Diogenes 
of  Apollonia  (cp.  espec.  fr.  3,  beginning).  For  the  interpretation  of  Empedocles  the 
statements  regarding  fit  conditions  of  mixture  for  yip€<ns  are  of  especial  interest, 
since  they  imply  definite  proportions  and  the  admixture  of  all  four  elements.  The 
intimate  relation  of  Empedocles  to  the  medical  schools  should  be  constantly  borne  in 
mind.  Medicine,  so  far  as  it  consisted  in  the  ministration  of  medicaments,  was 
essentially  the  art  of  interfering  in  the  roicrocosmic  ir6X6juos,  which  reproduced  in 
miniature  the  cosmic  ir6XefU)j,  and  of  preventing  irucpdrcia  of  the  several  elements  by 
combatting  the  overbearing  and  assisting  those  which  were  in  danger  of  succumbing. 
One  might  be  misled  into  supposing  that  Greek  prescriptions  were  not  precise,  because 
few  such  are  found  in  Hippocrates.  The  reason,  I  believe,  is  that  Hippocrates 
insisted  on  a  minute  study  of  the  individual  case,  for  which  precise  prescriptions  for 
general  distribution  would  be  unsuitable.  That  prescriptions  were  given  by  formula 
we  know  :  cp.  Hippocrates,  11.  tifCxniMc^t^  10  (9,  238  Littr^)  xpoKaroffKcvdcdta  64 
<roi ,  , .  woT-^fULTa  TifiM€iP  SwdfJLeva  i^  dvaypct^^s  iffxtvafffiiwa  wpbt  rd  yiP€a, 
These  are  classified  prescriptions. 

*^  n.  4>6(rtot  dy$piJ^ov,  3  (6,  88  Littr^). 


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HEIDEL.  —  n^l  ^Ca%m.  103 

constitation  (4^wni)  of  the  universe  and  of  man,  it  follows  of  necessity 
that  man  is  not  one  substance,  but  each  ingredient  contributed  to  his 
birth  keeps  the  self-same  force  (3vva/us)  in  the  body  that  it  had  when 
contributed.**  And  each  must  return  again  to  its  natural  kind  (eh  r^ 
iujvTov  <l>wny),  when  man's  body  ceases  to  be,  —  the  moist  to  the  moist, 
the  dry  to  the  dry,  the  hot  to  the  hot,  and  the  cold  to  the  oold.  Such 
is  the  constitution  (^vo-ts**)  of  animals  and  of  all  things  else ;  all  things 
originate  in  the  same  way,  and  all  end  in  the  same  way ;  for  their  con- 
stitution is  composed  of  the  aforesaid  substances  and  terminates  in  the 
same  in  ihe  aforesaid  manner, — whence  it  sprung  into  existence, 
tiiither  also  does  it  return.''  ^ 

Here  we  find  peacefully  side  by  side  two  uses  of  <^u(ri9,  (1)  that  of 
elemental  constituent  and  (2)  that  of  the  resultant  constitution.  Among 
the  strict  monists  there  would  be  no  real  distinction,  and  thus  there 
would  be  a  show  of  reason  for  Professor  Burnet's  main  contention  if 
one  limited  its  application  to  the  lonians  and  insisted  on  a  strictly 
monistic  interpretation  of  their  thought  ;*^  but  where  a  multiplicity  of 
elemental  constituents  are  recognized,  the  two  uses  must  differ  at  least 


**  This  is  interesting  and  important  in  view  of  its  evident  dependence  upon 
Empedocles.  Those  who  incline  to  regard  Empedocles  as  a  shifty  and  inaccurate 
pseudo-philosopher  and  decline  to  take  seriously  his  doctrine  of  /li^tt,  as  does  Profes- 
sor Millerd,  Chn  the  Interpretation  of  Empedocles,  p.  89  foil.,  should  reckon  with 
Hippocrstefl  instead  of  relying  entirely  on  scraps  of  his  philosophical  poem,  espe- 
cially when  Aristotle  agrees  with  Hippocrates.  The  fact  that  Aristotle  found  Em- 
pedocles' doctrine  of  the  elements  inconsistent  with  Aristotle's  own  misinterpretation 
of  Empedocles'  **  union  into  one  "  (Millerd,  p.  40)  means  absolutely  nothing  to  those 
who  know  how  prone  the  Stagirite  was  to  find  his  own  "indeterminate  matter"  in 
his  predecessors.  (See  my  essay  Qualitative  Change^  etc. ,  and  Burnet,  2d  ed.  p.  57.) 
The  fact  is,  and  it  ought  to  be  emphasized,  that  the  significance  for  the  pre-Socrat- 
ics  of  a  knowledge  of  Hippocrates  has  been  too  much  neglected  even  by  scholars 
otherwise  competent.  The  study  of  Qualitative  Change  which  I  published  in  1906 
would  have  gained  immensely  in  value  if  I  had  then  realized  the  evidential  value  of 
the  Hippocratean  corpus  and  of  general  Greek  literature  for  these  subjects  and  had 
incorporated  the  materials  drawn  from  these  sources  which  were  then  at  my  command. 
This  is  not,  however,  the  proper  occasion  for  a  rehandling  of  that  whole  question, 
and  it  must  therefore  be  postponed. 

**  This  [lassage  well  illustrates  the  fact  that,  while  the  philosopher  does  speak  of 
the  elemental  substance  as  0i^ts,  when  he  uses  the  term  in  a  general  way,  as,  e.g. 
the  0i$(rtt  of  a  man  or  the  0i^it  of  the  universe,  he  means  the  ''constitution"  of 
things.  This  agrees  well  with  the  conclusion  of  Professor  Millerd,  On  ihe  InUrpre* 
UUion  of  Empedocles,  p.  20. 

^  Such  an  interpretation  I  cannot  accept  for  the  lonians  (see  my  QuaJitaHve 
Change,  etc.),  since  strict  monism  implies  the  interpretation  of  r6  li'  as  t6  S/juhop, 
which  appears  distinctly  first  in  the  Eleatios.  Even  Diogenes  is  not  to  be  regarded 
as  a  consistent  mooist,  since  he  admitted  distinctions  in  his  One. 


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104  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

in  this,  that  in  the  second  sense  (fiva-K  is  a  collective  comprising  the 
individual  ^vo-as  ••  of  which  it  is  the  sum.** 

It  is  probable  that  Democritus  also  spoke  of  the  atoms  as  <^v(ri9  in 
the  sense  of  elemental  constituents  of  things,  though  this  is  not  alto- 
gether certain.*^  Burnet  likewise  discovers  this  meaning  in  a  frag- 
ment ••  of  Diogenes  of  Apollonia,  though  as  a  would-be  consistent 
monist  Diogenes  could  ill  distinguish.  Closely  allied  to  this  force  of 
<l>v<n^  is  that  in  which  ^vVts  appears  as  the  natural  or  original  place 
or  condition  of  a  thing.  Thus  Hippocrates**  speaks  of  a  joint,  in 
dislocation,  as  leaving,  and  on  being  replaced,  as  returning  to,  its 
4>v(ns.  It  will  be  recalled  that^  according  to  Aristotle,  each  element 
has  its  ouccios  roTTos  to  which  it  betakes  itself  as  naturally  as  a  cat 
returns  home.  Thus  we  find  ^  Apxaia  <f>v(n^  denoting  the  original  form 
or  condition  in  Plato, ^**  and  <l>v<nq  coupled  with  apxaCa  icaToorcurt? ; 
but  these  turns  lead  naturally,  if  indeed  they  do  not  belong,  to  the  use 
of  <^v<n^  as  constitution. 


••  The  plural  0i5(rcif,  in  this  sense,  is  rare,  cp.  Arist,  Met.  987*17  ;  [Arist.],  De 
Mnndo,  896M4  ;  Philodem.,  De  Morte  (Diels,  ForsoAr..^  385,  17).  [PlatoJ  Epm, 
981  D,  uses  the  singular,  not  the  plural,  as  one  might  gather  from  Diels,  Elementiim^ 
p.  22. 

••  The  recognition  of  this  is  common  ;  e.g.  Hippocrates,  II.  <ff6<nos  ij^Bpilncovy  4 
(6,  38  foil.  Littre)  rb  di  (rufixi  roO  difdpii)wov  ix^i  iv  itaxrr^  aXfM  Kal  ff>\4yfia  xai  x<>^V*' 
^avB^  T€  KcU  fiiXaiyatff  Kal  ravr'  icrrlp  aM<fi  ij  <f>i&ait  tov  atbiMTOS,  kqX  5td  ravra  dX^^et 
Koi  Oyiaiv€u     Cp.  also  Plato,  Phil.  29  A. 

•'  Democr.  fr.  168.  But  the  words  of  Simplicius  are  a  comment  on  Arist.,  Phys, 
265^  24  5tA  Si  rb  K€Pbv  KivcTaBaL  ipaa^ip  •  Kal  ydLp  oCroi  (the  Atoraists)  tt^v  Karik  totov 
Klpr}(ruf  Ktyelcrdai  rqv  <f>Ociv  \4yovaiy  and  may  have  no  other  warrant.  But  rJ^r  ^0<raf 
in  the  Aristotelian  passage  means,  alnwst  certainly,  **  Nature,"  as  Prantl  renders  it. 
On  the  other  hand,  Epicurus  calls  rb-  k€v6p  (which  differe  fi-om  rb  vaarbv^  acconling 
to  Democritus,  only  as  (i-qSh  from  Siv)  by  the  name  of  dw^?;s  0t^tt,  though  this 
may  only  be  a  periphrasis  for  rb  dva^s.     But  see  Arist.,  i/e^.,  985*  4  foil. 

••  Fr.  2  frepof  dv  rj  Ibiqi  4nj<r€i,  This  Burnet  renders  :  "by  having  a  substance 
peculiar  to  itself ; "  Diels  says  "anderes  in  seinem  eigenen  Wesen,"  which  is  probably 
the  true  meaning,  implying  constitution  (composition  ?). 

••  n.  &p0puv,  30  (4,  144  Littre) ;  ibid.  61  (4,  262  Littr^). 

^^  Syinp.  191  A.  ii  (pfjcit  Slxa  irpL-ffit} ;  191  C  ^<rrt ...  6  ^p«f  ffupvTos  dXXi^Xov 
Tois  dpdpunroit  Kal  rrjt  dpxa^os  <f>va€(as  <rvvay(ay€i>s  Kal  iirix^ipQp  Toiij<rai  fr  iK  dvoif  xal 
IdLffacrBai  rijv  <p6<TUf  tjjp  dpOpoyirlprjp  ;  192  E  ^  dpx^^^  ^t^ais  ;  198  C  elsT)jp  Apxalajf  dreX- 
$ufp  <p6<np.  Cp.  Repub.  547  B  ivl  t^p  Apxaiajf  KardaraffiP.  In  Democritus,  fr.  278  we 
find  dxb  <p6(nos  Kal  KaraffTdffios  dpxairft.  Protagoras  (Diels,  Vorsokr,  ii.  627,  1)  is 
reported  to  have  written  a  work  II.  rrjt  ip  dpxv  KaTaardaetas  (perhaps  a  sort  rif 
n.  <p{f(r€U)s  dpdpunrov)  from  which  Nestle,  Neue  Jahrb.  fiir  klass.  Altert.,  1909,  p.  8, 
thinks  Plato  freely  transcribed  the  myth  in  the  Protag.  320  C,  foil.  Hdt.  viii.  83 
says  ip  dvdpu)7rov  ipOai  Kal  KaTdffa(ri.  Here  belongs  also  Aristotle's  Trpun-n  ff^pStffis 
(see  n.  73)  and  Hippocrates*  ^  i^  dpx^s  ajjcTociSj  U,  buUrTitf  A,  2  (6,  468  Littr^). 


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HEIDEL.  —  n<p\  ^«<r«M«.  105 

We  have  seen  that  in  the  world  of  Homeric  thought  every  event  was 
regarded  as  due  to  the  activity  of  the  gods,  and  that,  as  the  conception 
of  Nature  replaced  that  of  the  gods  as  a  basis  of  explanation,  ff>v(n<: 
was  conceived  as  the  source  of  the  manifold  activities  of  the  world. 
The  phenomena  of  life,  cosmic  and  ifiicrocosmic,  seeming  to  occur 
spontaneously  and  without  external  cause  ^^^  and  direction,  naturally 
engrossed  the  attention  of  ^  the  philosopher  and  might  well  make  it 
appear  possible  to  dispense  with  a  special  cause  of  motion.  Aris- 
totle ^^^  complains  that  the  first  philosophers  did  not  concern  them- 
selves with  this  question,  confining  themselves  to  the  investigation  of 
the  material  cause ;  and  such  anticipations  of  his  efficient  cause  as  he 
finds  in  the  early  cosmogonists  and  cosmologists  bear  the  stamp  of 
vital  and  psychic  agencies,  hardly  distinguishable  firom  the  personifica- 
tions of  mythology.  From  these  facts  divergent  conclusions  have  been 
drawn,  some  assuming  that  the  m}thical  conceptions  continued  essen- 
tially unchanged,  others  finding  a  refined  animism  to  which  they  give 
the  name  of  hylozoism  or  hylopsychism.  The  first  conclusion  is  shown 
to  be  false  by  the  mechanical  interpretation  put  upon  the  activities  of 
the  mythically  named  agencies ;  ^®'  the  second  presupposes  distinc- 
tions which  developed  only  at  a  later  period.  ^^^  In  general  the  phil- 
osophers appear  to  have  contented  themselves  with  the  recognition  of 
the  autonomy  of  nature,  assigning  no  ground  for  her  activity,  since  she 
seemed  herself  to  be  the  sufficient  explanation  of  events.  The  strict 
exclusion  of  divine  agency  not  unnaturally  suggests  a  conscious  effort 
to  eliminate  such  interference,  though  this  inference  might  be  wrong  ; 
on  the  other  hand  the  habit  of  saying  that  certain  phenomena  occur 
"  of  themselves  "  or  "  of  necessity  "  or  "  by  chance ''  gave,  as  we  have 
seen,  great  offense  to  the  teleological  Socratics.  A  modem  philoso- 
pher, conscious  of  the  difficulties  presented  by  an  attempt  to  define 
causality  and  necessity,  would  judge  these  early  thinkers  with  less 
severity.  But  the  constant  criticism  of  pre-Socratic  philosophers 
by  their  Socratic  successors,  due  to  the  teleological  prepossessions  of 


"*  Spontaneous  generation  of  animal  life,  for  exani]ile,  seems  to  have  been  gener- 
ally accepted  for  lower  forms.  As  philo80|)hy  advanced  the  higher  forms  of  life  were 
iiicladed,  at  least  at  the  beginning  of  the  worUl. 

*••  Aristotle,  Met.  984»  18-985*  22.  Cp.  Gilbert,  Aristotcles  unddie  VorsokraWcer, 
Philol.,  68,  878  foU. 

*•*  In  Empedoclea  this  is  obvious  to  all  who  regard  him  as  a  philosopher  and 
consider  the  evidence  ;  it  is  equally  clear  in  regard  to  Parmenides.  Cp.  my  Quali- 
iative  Change^  n.  89,  and  see  also  ibid.  un.  55  and  65. 

!•*  For  thja  see  Burnet,  ed.  2,  p.  15  folL 


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106  PROCEEDINGS  OF  TEffi  AMERICAN  ACADEBfT. 

the  latter,  ^<^*   is  suggestive  of  the  tardiness  with  which  they  came  to 
ooDsider  the  implications  of  causality  and  the  laws  of  nature. 

The  use  of  <^u(ri9,  with  more  or  less  personification,  as  the  author  of  a 
process  (11.  B),  appears  relatively  late,  as  we  should  expect.^^^  Hip- 
pocrates speaks  of  Nature  as  arranging  the  vitals  in  the  inner 
parts ;  ^^^  says  of  the  auricles  of  the  heart  that  they  are  instruments 
by  which  she  takes  in  the  air,  adding  that  they  seem  to  be  the  handi- 
work of  a  good  craftsman ;  i®*  refers  to  the  vis  medicatrix  natwras^ 
Nature  having  discovered  tiie  methods  without  understanding  and  un- 
taught ;  ^0*  she  makes  glands  and  hair ;  ^^®  she  can  prepare  the  way 
for  and  ofiier  resistance  to  instruction  '^^}  she  is  all-sufficient ;  ^^^  she 

*••  It  is  perhaps  unnecessaiy  to  cite  passages,  but  the  intrinsic  interest  of  the 
following  may  justify  one  in  quoting  it  Arist.  De  Partt,  Animal.  641^  20  :  ol  di  tu» 
flip  r<JK^  ^icaoTOP  <l>C<T€i  ipturlp  elmt  koI  y€v4a$aij  rhp  di  oitpophp  drd  t&x.'H^  f*^  ''o*'  o.\rrO' 
fidrov  ToiovTOP  ffwrrrjpoi,  h  ^  dwb  ti/x'T*  «f«i  ira^Lat  oW*  6tioGp  ^xUprrai.  Topraxov  Si 
T^e  TOvd€  Ivc/ca,  6tov  Bm  tpalprjrat  riXos  ri  irpbs  i  if  Klprfffit  irfpalvti  /xrjdf-pbt  ifiroSt^op- 
roi.  &aT€  €lpai  <paP€p6p  6ti  iari  ri  ToiovroPf  i  d)}  xal  KaXovficp  <f>6(rLP,  o^  ydp  S))  5ti 
tnrx!^  i^  iKdiTTov  ylpercu  airipfMTOt,  dXXd  t6B€  iK  toD56,  oirdi  trwipfui  t6  tvx6p  iic  rod 
Tvx^os  (TtbfMTos,  ^PX^  ^^  '^  roiTfTiKitP  ToO  i^  avToO  rb  awipfM,  ^i^ei  ydip  ravra 
<f>tkrat  yovp  iK  to&tou.  dXXd  fiffp  (ri  ro&rov  wp&repop  t6  o5  rb  awipfia  •  yip€ffis  fUp  yh.p 
t5  aripfia,  ovela  8i  t6  tAoj.  Op.  Ed.  Meyer,  OeschichU  des  Altert.  I.  (a),  p.  106  : 
**  Vielleicht  noch  verbreiteter  (than  the  belief  that  divinities  reside  in  inanimate  ob- 
jects, such  as  stocks  and  stones)  ist  der  Glaube,  dass  die  Gotter  in  Tieren  ihi*en 
Wohnsitz  haben.  Die  Tiere  sind  lebendige  Wcsen,  die  eine  willenstarke  Secle  haben 
wie  der  Mensch  ;  nur  sind  sie  nicht  nnr  an  Kraft  dem  Menschen  vielfach  iiberlegen, 
sondern  vor  allem  viel  geheimnisvoUer,  unberecheubarer  und  dabei  zugleich  durch 
ihren  Instinkt  viel  sicherer  und  zielbewusster  in  ihi-em  Auftreten  als  der  Mensch  : 
sie  wissen  vieles,  was  der  Mensch  nicht  weiss.  Daher  sind  sie  fur  die  primitive 
Anschauung  recht  eigentlich  der  Sitz  geheimnisvoUer  gottlicher  Machte."  Tliese 
same  qualities  of  animals,  as  we  shall  see,  shared  in  the  development  of  the  idea  of 
0i;(rtf  which  took  the  place  of  that  of  the  go^Js  for  purposes  of  explanation. 

*••  Not  all  the  passages  cited  emphasize  the  agency  of  Nature,  and  the  degrees  of 
personification  differ  ;  but  personification  in  any  degree  implies  or  suggests  agency, 
and  for  convenience,  if  for  no  other  reason,  the  uses  should  be  considered  together. 

*W  n.  6»aTOfi7i%  1  (8,  538  Littrd)  rd  /it^  i^  d^d  pAcoP  irrbs  ^lArtt  iKoapL-ffiri,  Cp. 
Bonitz,  Index  Arist.  836»  26. 

*••  n.  Kopdi-ns,  8  (9,  84  Littre)  i<m  di  Spyat^  rotai  ii  4>^is  d/nrd^ci  rbp  ijipa,  xal- 
Toi  boKiio  rb  TolrjpLa  xftp^»««fTOj  dyaOoO. 

lot  *Eri8ripi.  VI.  5,  1  (5,  814  Littre)  poj^up  <f>6ffi€t  IrfrpoL  dpevpl<rK€i  ^  ^6<Tit  a^ij 
iuvrS  rdf  i<f>6bovSy  oCk  ix  diapolrftf  clop  rb  ffKapdapLinrffeiPf  Kcd  if  y\(a<r<ra  inrovpyiei,  Kal 
6<ra  dXXa  rotoDra  •  diredbevTos  ^  tpinris  iovca  Kal  oi>  fiaOovaa  rd  Siopra  TOii€i.  H, 
rpo<pn%  39  (9,  112  Littre)  (f>{Hrus  wdprutp  dblbaKTOi.  II.  bialrrjs,  A,  15  (6,  490  Littr^) 
rj  <pvjit  airropLdrrf  ravra  itrltrrarai,     Cp.  n.  117. 

"•  11.  dbipuiP^  4  (8,  558  Litti-^  ^  ydp  <f>v(Tis  roUfi  dbipas  koI  rplxat. 

^*  N6/iOT,  2  (4,  638  Littr^)  rrpCrrop  fUp  ofnr  rdpTUfp  bei  ^{htios  (talent,  natural  apti- 
tude) •  ^ijffiot  ybip  dpriTprfffffOJ^ffrjt,  K€P€b.  irdvra  •  ipOaios  bi  it  rb  dpurrop  bbrjfy€oOffris^ 
bidaffKaXlrf  rix*^t  yLptrai. 

1"  n.  rpwprjs,  15  (9,  102  Littr^  <t>^is  i^pKiei  Tdvra  reurti'. 


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HEIBEL.  —  n«p\  <^^rf«f .  107 

produces  nataral  species  and  legislates  language;  ^^'  in  disease  she 
may  withhold  signs^  but  may  be  constrained  by  art  to  yield  them  ;  ^^^ 
the  means  employed  by  her  are  likened  to  the  means  m  use  in  the 
arts.^1'  Such  is  the  picture  we  find  drawn  of  </>v(rt?  at  the  close  of  the 
pre-Socratic  period.  In  the  earlier  writers  such  expressions  are  rare. 
Heraclitus  ^^^  says  that  "nature  loves  to  play  at  hide-and-seek,"  and 
Epicharmhs  ^*^  says  "  Eumaeus,  wisdom  is  not  confined  to  one  place, 
but  all  living  things  have  intelligence.  The  tribe  of  hens,  if  you  will 
note  sharply,  does  not  bring  forth  living  ofiTspring  but  hatches  eggs  and 
causes  them  to  acquire  a  living  souL  This  bit  of  wisdom  —  how  this 
comes  about —  Nature  alone  doth  know ;  she  was  self-taught" 

Aside  firom  such  utterances  as  these  ^^®  we  are  reduced  to  inferences 
from  the  general  doctrines  of  philosophers,  but  it  is  not  our  plan  to 
pursue  this  subject  here.  It  may  not  be  amiss,  however,  to  remark 
that  the  type  of  pantheism  found  in  Xenophanes,  ^^*  vaguely  anticipat- 

*^  n.  T^inp,  2  (6,  4  Littr^  ol/iat  5*  fy&ryc  «o2  rd  drSfiara  ai^rdt  (sc.  rAt  T^vas) 
did  rd  etdea  Xa/Seir  •  dXcyop  yikp  d.vb  tQp  dpofidrow  rd  eWea  iiy€i<r$ai  /SXatrrdi^ty,  koI 
iMforw  •  rdL  fikv  ydip  Mfmra  <f>6<not  vofjLoOeHifjiaTd  ieri,  rd  ^k  cfdco  ou  wofiJoBcT))tMra^ 
iWh.  fiXaun-^fMTa.  Cp.  Plato's  Cratylus,  It  is  noteworthy  that  p6fios  is  here  de- 
rived from  0(^ts,  its  products  as  only  in  n  secondary  degree  accounted  the  result  of 
Nature.  Alongside  this  view  ran  the  other  which  distinguished  sharply  between 
0i^(f  and  p6fiott  though  here  ahio  p6fios  is  secondaiy.  Hippocrates,  II.  dialTrjs,  A,  11 
(6,  4S6  Littrd)  says  :  ydfu>$  yiip  Kai  <f>ij(riSt  otei  rdrra  Siaxprffftrdfudaj  oirx,  6fAo\oy4€Tai 
6fio\ciy€6fi€Pa  *  rdfjutp  ydip  i0t<ray  Ib^piaxoi  avrol  iuvroiaaf,  ov  yuKtXTKoyres  xepl  &v  i0€<rav  ■ 
^6fftp  di  irdrrurp  (doubtless  including  man)  Oeol  di€K6<rfirf<Tav  •  d  fUv  otfv  AvSpwroi  ideaap, 
ot/d^Tore  (card  rdurb  ^ci  oCre  6pdCn  oUrt  p.ij  dpOCoi  •  dxixTa  Si  Oeol  (Bcfrav^  del  dpOCis  ^x^*» 

***  n.  T^x^h  12  (6,  24  Littr^)  tfroi'  Si  ravra  fi^  firi»i6tayrai,  fxifS'  airrrj  ij  ^Cffts 
iKoOaa  d^jf,  d^dyicat  eOprjKev  (sc.  ij  t4x^),  ^w  ^  ^6aii  di^/uos  ^laffOetaa  fuSlrjaiv. 

^^  n.  T^xi^f  S  (6,  14  Littr<0  &f  ydp  iartp  ^fuv  roial  re  tw  rrxyiujv  6pydvoi% 
ixLKparkuf.  11.  Swirrii  is  full  of  comparisons  between  the  operations  of  nature  and 
those  of  the  arts. 

**•  Fr.  123  ^tJtf-tf  Kp&irT€<r$ai  ^tXet.  I  interpret  this  sapng  as  referring  to  the 
game  called  KpvTTipSaj  and  regard  it  as  parallel  to  fr.  52  a/Jir  irait  i<m  iral^wvy  irer- 
reiuv^'  waiSbs  if  paaiXrilvi,  Bemays  (Abh.  der  Akad.  Berl.,  1882,  p.  43)  said  of  the 
latter:  **H.  hatte  seinen  Zeus,  insofem  er  unablassig  Welten  baut  und  Welten 
zerstort,  ein  'spielendes  Rind'  genannt ;  der  tiefsinnige  Naturphilosoph  wablte 
dieses  Bild,  um  das  Wirken  der  Naturkrafte  alien  menschlichen  Fragen  nach  dem 
Zwecke  zu  entriicken."  Heraclitus  probably  had  little  reason  to  fear  teleological 
interpretation  of  nature.  Perhaps  the  altSjp  is  playing  a  game  of  solitaire  or  playing 
against  a  dummy,  now  winning  {KSpos),  now  losing  (Kifidt),  Cp.  Stein  on  Hdt.  ii. 
122,  3.     On  similar  lines  one  might  explain  the  game  of  Kpinrrlfda, 

^\  Fr.  4  (Biels).  Cp.  n.  109,  above,  and  Ar.,  Fesp,,  1282.  The  genuineness  of 
the  fragment  is  not  above  suspicion. 

*"  Cp.  Eurip.  fr.  920  ^  0i5<rit  i^oCXeO*,  j  y6fiw  oifSh  fU\€i, 

"•  Cp.  Burnet,  2d  ed.,  p.  141  and  Adam,  Tfie  Edigioua  Teachers  of  Oreece,  p. 
209  foil.    I  incline  to  think  that  Adam  somewhat  overemphasized  the  degree  of 


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108  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

ing  that  of  the  Stoics,  iDevitably  contributed  indirectly  to  the  develop- 
ment of  the  conception  of  Nature  as  of  a  power  more  or  less  personally 
conceived  but  devoid  of  definite  anthropomorphic  attributes.  This 
view  of  Nature  was  henceforth  to  prevail  in  ever-widening  circles. 

We  now  turn  to  consider  ^vo-i?  regarded  as  the  end  of  the  process 
(III.).  As  has  ahready  been  said  the  number  and  variety  of  cases  which 
fall  under  this  head  are  very  great  compared  with  the  foregoing.  In 
most  respects  there  is  little  occasion  for  special  remark  in  this  connex- 
ion, since  the  usage  of  the  pre-Socratic  period  coincides  in  the  main 
with  that  of  later  times.  Yet  there  are  implications  involved  in 
this  same  usage  which  were  drawn  out  and  made  explicit  only  in  the 
Socratic  age.  Most  interesting  of  all,  perhaps,  is  the  complete  inver- 
sion of  the  conclusions  of  homely  common  sense  and  common  usage  in- 
troduced by  the  doctrine  of  Aristotle.  Thus,  e.  g.,  he  says  :  ^*®  "  From 
what  has  been  said,  then,  it  is  plain  that  <^vo-t9,  in  the  primary  and 
strict  sense,  is  the  substantial  entity  (ova-ia  =  c^wri?  III.)  of  things  which 
have  in  themselves,  as  such,  a  source  of  movement ;  for  the  matter  is 
called  ifivaiq  (11.  A)  by  reason  of  having  a  capacity  to  take  this  on,  and 
the  processes  of  becoming  and  growing  (<^u<ri9  I.),  by  reason  of  being 
derived  firom  it."  In  the  circular  process  of  the  Socratic  the  end  has 
become  the  beginning ;  that  which  the  pre-Socratic  called  the  reality 
has  become  a  bare  potentiality.  Neither  premise  nor  conclusion  of 
this  view  would  have  been  acceptable  or  even  intelligible  to  the  pre- 
Socratic,  although,  with  one  exception,  the  conceptions  upon  which  the 
new  view  rests  were  common  property.  Yet  that  one  exception  is  the 
comer-stone  of  Socratic  philosophy. 

When  the  pre-Socratic  asked  what  a  thing  was,  the  answer  he  desired, 
if  given  with  ideal  completeness,  would  have  presented  its  chemical 
formula.  Now  a  formula  is,  I  suppose,  in  origin  and  intention,  a  pre- 
scription. In  the  pre-Socratic  schools,  closely  associated  as  they  were 
with  the  schools  of  medicine,  this  procedure  was  natural :  furthermore 
it  was  adequate,  since  the  "  things  "  they  sought  to  define  were  ma- 
terial. But,  as  we  have  already  seen,  the  Nature  which  the  philosopher 
studied  became  at  the  end  of  the  pre-Socratic  period  so  charged  with 
spiritual  meaning,  and  in  particular  in  the  kingdom  of  vofioq,  the  son 
of  <^vo-i9,  there  was  so  much,  non-material  in  character,  which  called 
for  analysis,  that  a  method  of  definition  suited  to  the  new  objects  of 
study  became  an  urgent  necessity.     If  the  old  method  sought  a  defini- 

personality  with  which  the  0€6s  of  Xenophanes  is  invested,  especially  as  the  negation 
of  the  popular  view  of  the  gods  is  so  pronounced.     What  remains  after  the  denials, 
while  containing  elements  of  personality,  appears  shadowy. 
"•  Met  1015*  13  foil.,  transl.  of  Ross,  modified. 


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HEIDEL.  —  n^X  ^^mm.  109 

tion  of  the  material  thing,  jdelding,  as  its  final  result,  the  fonnula  of 
its  production  or  origin  with  a  view  to  its  possible  reproduction,  the  new 
method  proposed  to  define  the  idea  of  the  thing.  Henceforth  it  mat- 
tered little  whether  the  thing  was  material  or  not ;  nor  did  it  matter 
whether  it  was  actually  or  only  "  potentially  "  existent  These  distinc- 
tions did  not  and  could  not  arise  until  the  new  method  supplanted  that 
of  the  pre-Socratics.^*^  The  thing  itself  has  a  beginning,  a  source,  and 
a  history  :  it  is  transient  The  idea  of  the  thing  (for  the  Socratic)  had 
no  relation  to  beginnings  or  history  :  it  is  eternal  The  idea  of  a  key, 
for  example,  is  totally  different  firom  the  key  itself.  The  key  is  of  brass 
or  of  iron :  that  is  to  say,  it  is  defined  with  reference  to  its  material 
source :  the  definition  of  the  idea  of  a  key,  however,  looks  inevitably 
to  its  purpose,  or  end.  Thus  the  limits  of  the  process  of  <^v(ri9,  erected 
by  this  two-fold  method  of  definition,  are  polar  opposites.  In  either 
direction  the  quest  was  for  the  truly  existent,  and,  the  human  mind 
being  constituted  as  it  is,  the  ultimate  existence  must  be  the  first  cause. 
To  the  Socratic  the  first  cause  must  be  the  end  or  purpose ;  but,  since 
historically  this  conception  was  a  cadet  and  could  not  wholly  supplant 
the  first-bom,  the  end  must  be  in  the  beginning,  even  if  it  be  only 
"  potentially ''  present  there.  Like  most  Socratic  ideas,  the  conception 
of  the  causality  of  </>wri9,  as  the  end  of  a  process,  was  involved  in  many 
pre-Socratic  expressions,  though  their  significance  was  not  realized. 
Attention  was  directed  above  to  instances  of  personification  (involving 
agency)  of  ^vcns  in  the  sense  of  constitution,  talent,  etc.,  falling  under 
III.  The  same  implication  belongs  to  ttcc^vkc  and  <f>v(ri.v  ^ci  with  the 
infinitive.  Nature  thus  becomes,  as  it  is  by  Aristotle  expressly  re- 
garded, a  circular  process,  in  which  the  end  of  one  cycle  is  the  begin- 
ning of  another  :  SvOpum-o^  avOpwirov  yevv^  The  kvkXo^  yevco-cco^  thuS 
established  is,  however,  for  the  pre-Socratic  a  real  process,  with  a  clear 
history,  comparable  to  the  Orphic  cycle,  in  which  the  immortal  soul 
experiences  the  vicissitudes  incident  to  sin.  In  Aristotle,  where  the 
process  as  a  whole  is  all  in  all,  the  single  moment  tends  to  assume  the 
guise  of  something  having  a  reality  only  for  the  theorist,  — a  kind  of 
psychologists'  fallscy. 

***  Hippocrates,  11.  rixinp,  2  (6,  2  foil.  Littr^)  is  an  iuteresting  discussion  of  the 
** existence"  of  arts,  which  could  not  have  taken  the  form  it  actually  takes  if  the 
Aristotelian  distinction?*  had  been  current.  "Potentiality"  and  ** actuality"  have 
DO  significance  in  relation  to  things  which  have  a  real  history ;  the  temis  acquire 
meaning  only  in  relation  to  an  ideal  construction,  such  as  we  find  in  the  Aristotelian 
system,  where  the  definition  of  the  oi/<r(o  of  a  thing  has  reference  to  its  realization  of 
an  end  as  seen  from  without.  Teichmiiller,  strangely  enough,  imported  these  con- 
ceptions into  the  pre-Socratics. 


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110  PROCEEDINGS  OF  THE  AMERICAN  ACADEMT. 

It  has  already  been  said  that  the  practical  man  is  concerned  chiefly 
with  the  product,  which  he  takes  roughly  for  granted  without  too  much 
curiosity  as  to  its  origin ;  but  he  is  intensely  interested  in  its  uses,  what- 
ever they  may  be.  He  does  not  reflect  upon  even  this  circumstance, 
however,  proceeding  in  his  pragmatic  way  to  do  the  work  in  hand. 
When  therefore  he  speaks  of  ^vons  it  is  generally  some  aspect  of  nature 
as  it  is  that  he  has  in  view.  From  this  attitude  springs  the  common 
usage  of  philosophical  and  quasi-philosophical  circles,  which  regards 
chiefly  things  as  things,  without  too  much  implication  of  further  ques- 
tionings. In  so  £9ir  as  there  is  a  suggestion  of  further  questions,  they 
concern  the  "constitution"  of  the  thing  —  that  is,  "what  it  is"  ex- 
pressed in  terms  of  "what  it  is  made  of."  This  is  the  regular  sense 
of  the  phrase  Trcpl  ^ixrccus  as  applied  in  titles  of  the  works  of  Hippo- 
crates,^'*  and  there  is  no  reason  to  think  that  it  bore  a  difierent  sense 
when  used  as  a  title  of  distinctively  philosophical  Avritings. 

If  it  were  our  purpose  to  treat  fully  of  the  uses  of  i*^'^^  we  should 
have  to  gather  and  discuss  here  the  multitudinous  meanings  of  the  term 
which  fell  under  the  third  head.  This  we  could  not  do,  however,  with- 
out unduly  and  unprofitably  increasing  the  bulk  of  this  study ;  for  most 
developments  of  <^v(rt9,  regarded  as  the  end  of  the  process  (III.)>  &fe  of 
slight  interest  for  the  particular  purposes  of  our  inquiry.  We  may 
therefore  here  content  ourselves  with  a  summary  glance  at  the  ramifica- 
tions of  this  main  branch,  adding  such  observations  as  may  serve  to 
throw  light  on  philosophical  and  scientific  conceptions. 

We  may  then  regard  <^v(ri9,  as  the  end  of  thef  process,  firom. without 
or  from  within.  As  seen  from  without  it  is  the  outward  constitution 
or  frame  of  a  thing  (III.  A) ;  viewed  from  within,  it  is  its  inner  consti- 
tution or  character.  Under  the  former  head  we  may  distinguish  (1) 
the  individual  frame,^*'  (2)  the  specific  or  generic,***  (3)  the  uni- 

"*  See  above,  n.  10  and  n.  93.  The  titles  of  Hippocrates  are  probably  not  origi- 
nal, since  in  many  instances  they  are  in  doubt,  some  works  that  bear  specific  titles 
being  clearly  parts  of  larger  wholes.  This  is  in  keeping  with  the  facts  mentioned 
below,  n.  204,  relative  to  philosophical  works.  But  in  the  case  of  Hippocrates  the 
title  in  most  cases  merely  repi-oduces  in  abbreviated  form  the  subject  as  stated  in  the 
body  of  the  work ;  and  the  invariable  meaning  of  0i^tf,  when  used  by  Hippocrates 
in  reference  to  the  subject-matter  of  discourse,  is  "constitution." 

**•  In  the  individual,  <f^O<ns  denotes  primarily  the  (perfect)  stature  attained,  e/j 
A^dpa  TActov,  e/f  fUrpw  ifXuclas,  as  Paul  says,  Eph.  4,  18.  This  is  Aristotle's 
/rrcX^eia,  for  which  the  whole  creation  groaneth.  Aesch.,  Pers.  441  dicfiouoi  <f>ij(rtp 
shows  that  this  association  of  ideas  was  popular. 

*■*  This  head  includes  0jJ(rtf  in  the  sense  of  *  birth,'  *  lineage,'  'family,*  and 
0iJ<rtt  as  sex  ;  for  sex  is  a  ydvoi.  It  also  embraces  0infr^  0i^t$,  Democritns,  fr.  297, 
Soph.,  0.  T.  869,  fr.  516,  and  Aesch.,  Ag,  6ZZ  x^ovbs  <t>^(ruft  •  earth's  brood. '  As 
(a)  under  this  head  should  be  classed  <f^6cis  denoting  not  the  yivos  itself  but  the 


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HETDEL.  —  n^l  <^^rf«f .  Ill 

versal  ^'*  frame  of  things.  Difficult,  and  in  some  cases  impossible,  it 
is  to  distinguish  clearly  between  the  outward  frame  or  constitution  and 
the  inner  constitution  or  character  of  things  (III.  B).  Each  <t>wn^  or 
frame  has  its  inner  constitution  corresponding  to  it,  which  will  of  course 
vary  according  as  the  (f^va-L^  in  question  is  individual,  generic,  or  uni- 
versal. Description  or  definition  of  the  fftvcri^  relates  the  individual  or 
generic  to  the  universal.  Of  course  the  crude  methods  of  description 
and  definition  in  use  in  the  pre-Socratic  period  were  not  consciously 
generalized ;  but  there  was  an  evident  desire,  manifested  most  clearly 
in  the  parallel  drawn  between  the  microcosm  and  the  cosmos,  to  find 
the  universal  in  the  particular.  In  accordance  with  the  chemical  mode 
of  definitioYi  in  vogue  this  desire  assumed  the  form  of  the  postulate 
that  the  constitution  of  individual  things  was  the  same  as  that  of  the 
world  as  a  whole.  We  may,  if  we  choose,  denounce  this  procedure  as 
crude  logic,  but  it  was  instinctive  logic,  or  logic  in  the  making,  for 
all  that.  The  differentiae  specificae  were  found  chiefly  in  the  propor- 
tions of  the  \oyo9  fu^c(i>9,  although  this  method  was  to  a  limited  extent 
supplemented,  though  perhaps  nowhere  wholly  supplanted,  by  the 
differentiation  introduced  in  the  universal  through  rare&ction  and  con- 
densation, or  —  what  practically  amounts  to  the  same  thing  —  through 
heat  and  cold.  As  to  the  universal,  the  wide-spread  conviction  that 
each  thing  shares  the  attributes,  or  rather  the  constituents,  of  the  world 
one  and  all  in  varying  proportions,  served  as  a  bond  of  union,  making 
things,  on  the  physical  side,  capable  of  interaction,  and,  on  the  intel- 
lectual side,  capable  of  being  comprehended.  The  motive  that  inspired 
the  postulation  of  a  common  principle  for  the  explanation  of  the  mani- 
fold data  of  sense  is  particularly  evident  in  the  case  of  the  Pjrthagor- 
eans,  whose  postulate  that  all  is  at  bottom  number  or  numerical  relation 
has  no  meaning  except  that  of  rendering  phenomena  intelligible.  This 
is  clear  even  without  accepting  the  so-called  fragments  of  Philolaus,  in 
which  it  is  expressly  stated.  To  Aristotle  this  principle  descended  in 
two  forms.     For  physical  theory,  it  provided  a  basis  of  interaction, 

spei*i6c  differentiae,  of  which  we  have  an  early  example  in  Horn.  Od.  10,  303,  the 
4^ati  of  the  plant  /twXu  pointed  out  to  0«lysseu8  by  Hermes ;  later  we  find,  in  the 
same  class,  <f>i<ni  denoting  the  characteristic  differentiae  of  Rex.  Under  (2)  we  might 
likewise  include  many  uses  in  which  0t^(f  —  dt/ra/Lut,  since  the  fih-pa  of  <ft{nTii  and 
9(fwatui  are  specific  differentiae.  Gp.  n.  85  above  and  n.  118,  where  natural  kinds  are 
called  ^6<no%  pXaxn-fntaTa. 

^^  In  this  sense  ^{mth  practically  ^  KSfffios.  For  the  uses  of  K6fffu>s  see  Bemays, 
Abb.  der  Akad.  Berlin,  1882,  p.  6  foil.  In  this  universal  sense  0t^(s  «  rd  0u6/Aem, 
0iJfftt  Tuw  SXtM^t  etc.  For  instances  see  Archytas,  fr.  1;  Eurip.  fr.  910;  Critias,  fr. 
19  (Diels);  Auraol  Aiyoi  {Bialexeis),  Diels,  Vorsokr,  II.  647,  15;  Hippocrates, 
n.  dpxctlrft  Irp-ptxris,  20  (p.  24  foil.,  Eiihleweiu). 


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112  PROCEEDINGS  OF  THE  AMERICAN  ACADEBIT. 

since,  in  order  to  interact,  things  must,  according  to  his  theory,  be 
generically  alike,  though  specifically  they  may  be  opposite  or  neutral 
in  character.  For  logical  theory,  again,  the  universal  is  the  foundation 
of  the  intelligible  world. 

It  was  said  above  that  while  the  inquiry  ircpi  </>wr€o)?  regarded  pri- 
marily the  constitution  of  the  world,  viewed  as  a  given  fact,  it  did 
naturally  imply  a  question  as  to  its  constituents  and  hence  as  to  its 
origin.  To  this  we  have  now  added  that  this  implied  question  in- 
volved for  nearly  all  philosophers  of  early  Greece  the  conception  of  <^i;o-i9 
as  a  Xoyo9  fu^cws.^**  In  effect  we  had  already  adverted  to  this  fisuct  in 
referring  to  the  chemical  definition  of  things  as  a  congener  of  the  med- 
ical prescription.  In  a  curious  passage  **^  Aristotle  dimly  perceives 
that  the  Xoyo?  ^i^ccds,  which  he  appears  to  recognize  only  in  Empedo- 
cles,  is  intimately  related  to  logical  definition,  though  he  seems  more 
fully  aware  of  their  differences  than  of  their  fundamental  likeness. 
Chemical  definition  seeks  to  determine  what  matter  entered  into  the 
making  of  the  thing.  Whether  this  matter  is  of  one  or  more  kinds 
makes  little  difference ;  since  even  the  monist  must  somehow  give 
variety  to  his  unitary  substance,  and  the  Greek  monists  in  particular 
appear  to  have  conceived  of  concrete  things  as  '  blends '  of  the  deriva- 
tive forms  of  matter.  Logical  definition,  on  the  other  hand,  aims  to 
discover  what  meanings  or  marks  (teleologically  interpreted)  constitute 
the  idea  of  the  thing.  Each  method  arrives  at  a  \6yos  :  the  first  at  a 
Aoyos  ftt^cws ;  the  second,  at  a  Aoyos  ovo-ias.^**  In  the  Aristotelian 
scheme  </>u<rt9,  as  the  Aoyo?  ovo-ias,  is  the  "  formal  cause."  Among  the 
pre-Socrati«s,  the  Aoyo?  /iiifcw?  of  the  cosmos  was  the  object  of  scienti- 
fic inquiry ;  and  it  was  <t>v<n^  in  this  sense  which,  as  we  have  seen, 
appears  in  the  titular  IIcpi  ^vo-ccds. 

Thus  far  we  have  considered  chiefly  the  physical  ^^uVt?  or  constitu- 
tion (III.  B,  1)  ;  but  we  must  not  overlook  the  feet  that  with  the 

"•  Cp.  n.  90  above.  For  <f^6(Tis  involving  \6ryos  /a/^cws  see  Pamienides,  fr.  16  and 
E[)icharmus,  fr.  2.  The  latter  fragment,  whether  rightly  or  wrongly  attributed  to 
Epieharmus,  clearly  reflects  the  thought  of  Heraclitus,  a  siipposed  monist.  On  this 
subject  see  my  study  of  QualUalive  Change. 

**^  J)e  Partt.  Ayiimal.  642  •  2-31.  The  passage  is  too  long  to  transcribe,  but 
will  well  repay  study. 

**•  I  cannot  help  feeling  that  the  periphrastic  use  of  0iJ<r«f  is  a  by-product  of 
logical  definition  and  hence  essentially  peculiar  to  the  Socratic  period.  The  presence 
of  such  phrases  as  d  ru)  dpiO/xCj  ^t^crif,  ras  rd  dwelpu)  koL  dyoi^ta  Kal  dX^yta  <f>ij<rios 
alongside  dpiOfibs  Kal  d  toOtoj  ovala  and  rgi  tw  dpiOfxta  ycvegi  (fr.  11),  in  Philolaus 
casts  grave  suspicion  on  the  supposed  fragments ;  for  ovaia  in  the  pre-Socratics 
means  not  *  essence,'  but  *  reality.'  Natorp,  to  be  sure,  in  Philos.  Monatshefte, 
21,  pp.  577,  582,  finds  a  deep  significance  in  these  same  phrases. 


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HEIDEL.  —  ncp\  ^^(TiMt.  1 1 3 

growth  of  interest  in  the  microcosm  <^v(rt9  as  the  mental  constitution 
(III.  B,  2)  assumed  considerable  importance.  Now  <^wri9  (like  its  great 
rival,  vofioi)  opt^ci ;  and  every  delimitation  implies  a  positive  claim  as 
well  as  a  restrictive  limitation.  Thus  ^uW  positively  regarded  (III. 
B,  2  a),  is  as  (native)  endowment,  talent,  instinct,  power,  etc.,  opposed 
to  (acquired)  virtue,  art,  experience,  wisdom ;  i**  negatively  con- 
ceived (III.  B,  2  b),  4>v<n^  marks  the  bounds  set  by  nature  to  every 
creature,  beyond  which  it  may  not  pass.^'® 

III. 
A  glance  at  the  survey  just  given  of  the  uses  of  <^ro-t9  will  satisfy 
anyone  that  the  conception  of  Nature  in  the  pre-Socratic  period  was 
developed  to  a  point  at  which  little  remained  to  be  added.  Certainly 
little  was  added  in  the  course  of  subsequent  Greek  thought.  Already 
our  conclusion  as  to  the  connotation  of  <t>v<n^  when  used  as  a  compre- 
hensive term  has  been  stated  ;  but  it  is  desirable  that  this  conclusion 
be  confirmed  by  a  consideration  of  the  questions  raised  by  those  who 
wrote  Ucpl  <f>wT€m.  Many  a  word  having  a  wide  range  of  meanings  in 
the  course  of  its  development  receives  at  different  times  an  emphasis 

**•  Examples  of  native  endowment,  talent,  or  power,  are  exceedingly  common  ;  cp. 
Protagoras,  fr.  3  ;  Epicharmus,  fr.  40  ;  Critias,  fr.  9  ;  Deniocritus,  fr.  21,  33,  176, 
183,  242,  etc.  Of  <l>v<rit  =»  instinct  we  have  an  instance  in  Democritus,  fr.  278.  In 
Democntns,  fr.  267  (t>v<Tis  means  *  birthnght.* 

MO  <*Xhe  metes  and  bounds  of  providence"  furnish  a  fdvorite  theme  to  singers 
and  sages  of  all  ages  and  peoples.  Cp.  for  example,  Psalm  104.  Greek  mythology 
foand  a  text  in  the  extravagance  of  the  elemental  water  and  fire  respectively  in  the 
flood  and  in  the  conflagration  of  the  worhl  due  to  the  escapade  of  Phaethon.  Anaxi- 
mander  and  Heraclitus  called  in  the  cosmic  dUri  to  curb  such  transgression. 
Xenophanes  also  recognized  this  principle  in  the  ]>eriodicity  of  cosmic  processes. 
With  later  philosophers  it  was  a  common  theme.  Democritus,  fr.  3,  couples  SOva^s 
and  <t>6<ns;  cp.  also  Archytas,  fr.  1,  and  Herodotus,  8,  83.  In  Herodotus,  7,  16  o, 
it  is  said  that  the  winds  do  not  suffer  the  sea  ipOci  ry  iuivrijs  xP^<^^^h  which  is 
explained  afterwards  by  reference  to  Uppn.  On  this  see  ray  review  of  Hii*zel,  Themis^ 
Dike,  und  VerwaiidUs,  in  A.  J.  P.,  xxix,  p.  216  foil.  In  Thucydides,  2,  35,  2 
inrkp  ryip  4>6<riv  is  set  definitely  in  relation  to  <f^06vost  which  opens  up  the  kindred 
subject  of  the  jealousy  of  the  gods  visited  upon  all  who  transgress  their  proper  fi^rpa, 
as  we  find  it  developed  in  the  tragedians  and  Herodotus.  In  fact  all  things  have 
their  limitations,  even  God,  according  to  the  Greeks.  There  is  an  interesting  pass- 
age in  Hippocrates,  II.  rixvrit,  8  (6,  12  Littre),  where,  after  rebuking  unreasonable 
critics  of  the  art  of  medicine,  the  author  says  :  cl  ydp  m  ij  rixvriv^  it  A  p.^  r^trri, 
^  4>6fftM,  is  A  fi^i  <p(Hn%  wi<f>VK€P,  d^nixreu  S^voffOaif  dyvo€t  Ayvoiav  dpMovffav  /xavi-fi 
/taWov  1j  dfJM0i-g.  d>y  ydp  iarip  ripXv  rdtai  re  rOtv  <l>v<ri<ap  Toiffl  re  rtav  rtx^iiJiv  6pyd»oii 
irucparieiPy  rovriujp  iarbf  ijfjuv  iri^ovprfoh  flwit,  6XK(av  8i  oCk  iarir.  As  limitation 
and  definition  are  the  basis  of  intelligence  and  the  guaranty  of  sanity,  the  Greeks  had 
an  antipathy  to  all  extraragance.  This  appears  most  clearly  in  their  aversion  to  the 
dreipop  in  all  forms. 
VOL.   XLV.  —  8 


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114  PROCEEDINGS   OF   THE   AMERICAN   ACADEMY. 

felling  now  on  one  meaning,  now  on  another,  cwcording  to  the  direction 
of  interest  from  time  to  time.  We  have  had  occasion  to  note  this 
tendency  in  regard  to  <^var4$  and  have  seen,  for  example,  that  the  per- 
sonification of  Nature  has  a  clear  history,  arriving  at  the  close  of  the 
pre-Socratic  period  at  a  stage  that  rendered  the  subsequent  teleologi- 
cal  interpretation  of  the  world  a  foregone  conclusion.  It  behooves  us, 
therefore,  to  inquire  what  were  the  principal  questions  asked  concern- 
ing Nature  in  the  pre-Socratic  period,  in  order,  if  possible,  to  deter- 
mine the  direction  of  interest  upon  which  depends  the  selection  of 
meanings  attached  to  the  term  ^v<ri$. 

We  may  prosecute  this  inquiry  in  either  of  two  ways.  First,  we 
may  study  the  fragmentary  remains  of  the  literature  of  pre-Socratic 
philosophy  and  extract  ficom  its  implicit  logic  the  answer  to  our  ques- 
tion. Or  we  may  approach  the  matter  indirectly,  asking  what  were 
the  ideals  of  science  in  that  age  as  we  find  them  reflected  in  the  non- 
philosophical  or  only  quasi-philosophical  literature  of  the  time  and 
of  the  following  period  which  received  its  inspiration  from  the  pre- 
Socratics.  Strictly  both  methods  should  be  followed  conjointly  ;  for 
only  thus  could  we  arrive  at  a  conclusion  that  might  be  justly  regarded 
as  definitive.  But  a  moment's  thought  will  convince  any  reader  that 
the  limits  of  such  a  study  as  this  could  not  possibly  be  made  to  yield 
to  a  detailed  examination  of  the  individual  systems  with  a  view  to 
deducing  firom  them  the  interests  of  their  propounders.  So  compre- 
hensive a  review  must  be  undertaken  in  connexion  with  a  history  of 
•early  Greek  philosophy,  which  is  not,  and  cannot  be,  the  scope  of  this 
study.  Our  attention  shall,  therefore,  be  directed  to  the  second 
means  of  approach,  with  only  an  occasional  glance  at  the  systems  of 
the  pre-Socratic  philosophers  themselves.  We  may  pursue  this  course 
with  the  better  conscience  because  it  is  self-evident  that  the  scientific 
ideals  of  the  age  were,  or  soon  became,  common  property,  to  the  defini- 
tion and  development  of  which  every  man  of  science  contributed  what 
he  had  to  ofier.  Nowhere  does  the  unity  of  pre-Socratic  thought 
more  clearly  appear  than  in  this  field,  where  philosophers  and  medical 
theorists  cooperated  in  \a,jing  broad  and  sure  foundations. 

Hippocrates  gives  us  the  best  glimpse  of  the  scientific  ideals  of  the 
age ;  and  it  will  prove  worth  our  while  to  pause  for  a  moment  to  learn 
what  he  has  to  teach  us.  The  true  physician  is  called  the  child  of  his 
art ;  m  he  is  disinterested  in  his  devotion  to  it,  since  the  love  of  one  s 
art  involves  necessarily  a  love  of  mankind.^*'    The  charlatan  was 

"*  IIopo77eX/at,  7  (9,  260  Littr^)  Irjrpdi  iya$6t .  .  .  6fjUtT€xvos  KoXeSfuPos, 
^*  Among  the  virtues  which  the  physician  is  said  to  )>ossess  in  common  with 
the  philosopher  in  n.  €(f<rx,'nyioc^%  5  (9,  232  Littre)  is  d^Xapyvplrf,  U,  Irp-pov,  1  (9, 


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HEIDEL.  —  IIcpl  ^^<rf««.  115 

particularly  despised,  and  his  histrionic  deportment  decried. *'•  The 
physician  who  desires  to  appear  in  public  and  address  the  people,  should 
refrain  from  quoting  the  poets  :  such  a  procedure  merely  argues  inca- 
pacity for  honest  work.^'*  In  public  speech  or  writing,  however,  one 
must  begin  by  lajdng  down  a  proposition  to  which  all  may  assent  ^^* 

204  Littre)  the  physician  is  bidden  r6  di  fjOos  ehat  KaXbf  Kal  dyaOdv^  roioOrov  d*  dvra 
xfluri  Kcd  eeiu^bv  koX  (piXdySponrw.  Uapayy^Xlaij  6  (9,  258  Littre)  rls  ydp  &  wpbi  At6f 
ifSeX^fUpot  (called  brother,  because  belonging  to  the  fraternity:  cp.  Isocr.  19,  80) 
IrfTpbs  IrjTpci^tM  r€tff0€lri  drepanMlij ;  The  brotherhood  of  the  fraternity  leads  to  the 
fraternity  of  man  !  Ibid.  6^  Ijy  di  Kaipbs  €trj  x^PVy^V^  ^^V  t^  ^^*  f^oX  djcopiovri^ 
ftdXicrTa  hrapKieip  rdiffi  ToiovrdouriP,  Ijy  ybip  irapi  (f^iXavOputTLrj  wdp€<rri  Kal  ^iXorexc^i?. 
Xen.  Mem.  I.  2,  60  refers  to  Socrates*  refusal  to  receive  remuneration  for  his  informal 
instmction  as  evidence  that  he  was  <f^iXdyOp<aTot  and  SiifioriKbt.  In  like  manner  Plato, 
Evihyph.  8  D,  explains  hia  lavish  expenditure  of  wisdom  as  due  to  ^iXavBpioirla^  which 
would  not  only  refuse  to  accept  remuneration  but  would  even  display  itself  in  paying 
the  listener  to  boot.  It  seems  evident  that  the  exalted  and  even  extravagant  disinter- 
estedness of  Socrates  reflects,  though  it  doubtless  carried  beyond  the  common  practice, 
the  teaching  of  the  medical  schools,  and  possibly  also  of  the  early  philosophical 
schools.  In  the  medical  "OpKOi  (4,  628  foil.,  Littre)  the  physician  swears  to  regard 
his  teacher  as  a  father,  sharing  with  him  his  substance,  and  his  teacher's  sons  as  his 
brothers  ;  if  they  desire  to  learn  medicine,  he  swears  dtdd^civ  tJji'  T^x^nv  raOrrfv .  .  . 
df€v  lucOov  KoX  ^uYypcupTJs.  Socrates,  like  Paul,  was  a  debtor  to  all  men :  he  could 
receive  pay  from  none ;  for  Socrates  is  the  first  great  cosmopolitan.  That  the 
Sophists  departed  from  this  custom  was  one  of  Plato's  severest  charges  against  them. 
They  were  like  the  men  of  whom  Xen.  Afem.  I.  2,  60  complains,  who  departed  from 
the  philanthropic  and  demotic  way :  oOddya  Tdnrort  fu<r$^  rrjs  ffwov^las  irpd^To^ 
dXXd  TcuTiif  &<f>06i^s  iiriipKu  tQv  iavrod  •  t&v  tu^j  fiiKpii  fUpri  Tap  ^Kelvov  (Socrates) 
Tpolica  Xa^furret  voXXov  roh  dXXots  ^irtiXow,  ifoi  ohx  ^<ray  CMTwep  iKCivos  di^fioriKol.  Cp. 
Hippocrates,  11.  e^irxrjfJ^off^irriSf  2  (9,  226  Littr^)  irdaai  ydp  al  fifj  fur  al<rxpoK€pd€lrjs 
KoX  dffxrifitxrivTii  (sc.  r^wt)  KaXal.    These  are  the  truly  **  liberal  "  arts. 

"»  n.  Irrrpov,  4  (9,  210  Littr^)  ;  H.  lep^s  voiJcrov,  1  (6,  864  Littr^)  iixoi  W  ioKiovffUf 
cl  wpuTOt  TovTo  rd  p6arifia  dtp'.epdxrayTes  toiovtoi  e&at  Aydpcrroi  otoi  koI  vv¥  clai  fxayoi  re 
Kol  KaOdprai  Kal  dy(/prax  koI  dXa^^ves,  6x6901  SP;  irpocrwoiiovTai.  <r<f>68pa  Oeocepiet  elvai 
KoX  xXiw  Tt  €lSipai  *  oOtoi  roivvv  •irapaiiTex6pxvoi  koX  Tpo^XX6fi£Poi  t6  Seiov  rrjs  dfirjxa- 
pirit  rod  fii}  tffx^iP  8  ri  wpoffevdyKoyret  (lxp€Xiff<roviTi»,  (hs  /x^  KaTddrjXoi  iwffof  ovdh  iriard' 
ficiHX,  Up6p  Mfuaav  tovto  r6  xddos  elwt,  Kal  X6yovs  iwiX4^asrr€s  iiriTrflklovt  r^v  trf<rip 
Kar€(rHiaaPTO  is  rb  d<r<f>aXis  ff<f>lffiv  a&rot<ri,  KaOappain  irpo<r<t>ipoPT€s  koI  iiraoidds,  ktX, 
(With  this  passage  cp.  Plato,  Repub.  364  B  foil.).  Ibid.,  18  (6,  896  Littr^).  Cp. 
also  the  portrait  of  the  spurious  philosopher,  H.  €i;<rx'?/Ao<riVi7f,  2  (9,  226  foil.,  Littr^). 
Cp.  n.  47,  above. 

"*  UapayyeXlai,  12  (9,  266  foil.,  Littr^).  I  read  <pi\oropirjs  with  the  vulgate ; 
Littr^  reads  ^tXoxw'fiy. 

*••  n.  ffapKWP,  1  (8,  584  Littr^)  iyCb  rd  fUxP*^  '''^^  Xiyov  ro&rov  KOipy<rt  yp(!)fii[i(n 
Xfiiofuu  Mptop  T€  t{jp  ifiTpocOep,  drdp  koI  ifieufvrov.  (Littr^  misinterprets  this;  it 
means  that  he  shares  the  common  assumption  of  his  predecessors  !)  dpayKolus  ydp  (x^i 
KOUf^pf  dpxh^  vToOiaOat  ryffi  ypthfi'Qffi  povX6fi€POP  ^vpOeiPoi  t6p  X&yop  t6v8€  wepl  riji  rix^Vi 
TTJs  Irp-piKrjs,  ktX,  Cp.  n.  0iVcos  dpOpiiwoVy  1  (6,  82  Littro)  for  the  common  assump- 
tion of  the  predecessors  of  whom  he  speaks  at  length  in  what  follows.  II.  t^kt;?,  4 
(6,  6  Littr^)  iarl  fUp  oirp  fioi  dpxh  f'oO  \670v,  Ij  koI  6/*o\o7i7^^cr8u  wctpd  vdatp,     Cp. 


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116  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

The  physician  will  not  indulge  in  useless  dialectics, ^'^  but  if  he 
knows  bis  art  he  will  prefer  to  show  it  by  deeds  rather  than 
words.  ^'^  Life  is  fleeting,  art  is  long,  ^'*  and  a  cure  may  depend 
upon  the  moment.^**  Hence  the  physician  must  not  restrict  his 
attention  to  rational  inference  but  must  resort  to  the  rule  of  rote  to- 
gether with  reason  ;  i*®  he  must  therefore  have  a  knowledge  of  prac- 
tice as  well  as  of  theory.**^  The  main  object  of  medicine  is  to  eflFect 
a  cure;  ^^'  above  all  the  physician  should  avoid  making  much  ado  and 
accomplishing  nothing.**'  The  art  of  medicine  is  not,  however,  a 
mere  routine ;  a  good  share  of  the  ability  of  the  physician  is  shown  in 
his  capacity  to  judge  correctly  touching  what  has  been  written ;  ***  for 
science  is  constituted  by  observations  drawn  from  every  quarter  and 
brought  into  a  unity.**'  An  art  or  science  attests  its  reality  by  what 
it  accomplishes.***  The  art  of  medicine  cannot  always  arrive  at 
absolute  certainty ;  but  far  from  disputing  the  reality  of  medicine  as 
an  art  or  science  because  it  does  not  attain  strict  accuracy  in  all  things, 
one  ought  to  praise  it  because  of  its  desire  to  approximate  it  and  to 
admire  it  because  from  extreme  ignorance  it  has  proceeded  to  great 
discoveries  well  and  rightly  made,  and  not  by  chance.**^ 

Diog,  of  Apollonia,  fr.  1 :  Xiryov  Tcan-bs  ipx^fJi^f^v  doKei  fioi  xP^w"  «^'  "^^^  ^^PX^ 
6»at^ia§-fjfrrrrw  ira/)^x«<^^«*>  "^h^  ^^  ipfiriyelatf  &T\rju  ical  ffefju^.  The  latter  ideal  com- 
ports with  the  portrait  of  the  true  philosopher,  II.  ei/a-xiyAwwiJi^t,  3  (9,  22S  Littr^) 

"•  n.  ei5(rx'?Mo<"Ji^t,  1  (9,  226  Littr^). 

w»  n.  Wx»"^.  18  (6,  26  Littr^). 

"•  'Aipopi<rfjLol,  1  (4,  458  Littre). 

"•  napary€\iai,  1  (9,  250  Littr^). 

1*^  UapaYyeXlaif  1  (9,  250  Littr^)  5et  ye  /xijv  ravra  ttS&ra  fi}j  \oyurfif  wpSrepov 
Ti^oKW  Tpoffixoyra  l-qrpivtiv^  dXXA  rpi^y  fi€T6.  \&yov.  Plato  and  Aristotle  oppose 
rpi^ifl  to  Wx*"? ;  but  this  rpi^iff  is  not  Arexifoi  (Plato,  Phaedr.  260  E),  but  firrA  \byov, 
.  ***  n.  ApOpccVy  10  (4,  102  Littr^)  ovk  dpK^ci  fiouvov  X47v  «^3A^t  t'^jp  r^n/r  roiJrip, 
dXXd  Kal  6fu\l-j^  dpuX^eip, 

i«  n.  ApOpufp,  78  (4,  312  Littr^). 

***  n.  ApSpuv^  44  (4,  188  Littrd)  alrxP^^  fUvroi  koX  iv  irdtry  t/x*T7  *<^^  ^^  liKurra  iw 
IriTpiK^  vovK^v  6xX^i  **i  toXXt)!'  ^^tv,  Koi  vovKbv  \irfov  xapa<rx^i^o-i  firtira  firfdiw 
tlnfteXtjirai, 

***  II.  KpurlfxufP,  1  (9,  298  Littr6).     Cp.  n.  dtalrris.  A,  1  (6,  466  Littr^). 

**•  UapaYY^Xlaif  2  (9,  254  Littre)  oDru;  7^^  doxita  r^^y  ^vfiiracrap  t^x*^  dpadttx^^frai^ 
iJiA  tA  i^  CKdiTTOv  ToO  riXovt  rrjpriOTp^i  Kal  els  rairrb  ^vvaXurdrivai, 

**•  n.  T^x^h  5  and  6  (6,  8  foil.  Littr^).  We  even  find  a  suggestion  of  definition 
in  terms  of  the  purpose  of  an  art,  II.  r^x^^^i  3  (6,  4  Littr^)  Kal  rrpCrrbv  ye  diopuOfiai 
i  vofil((a  IrfTpiK^jp  eXvaiy  t6  d)j  wdfixap  draXXdaaeiy  tup  voaebimaw  roi>%  KOfidrovif  ktX, 
Tliis  and  several  other  matters  incline  me  to  the  opinion  that  11.  t4x^^  belongs  to 
the  fcui-th  century,  though  its  general  value  for  our  purposes  is  not  thereby  appreci- 
ably affected. 

"^  n.  dpxalrjt  IrjTpiKiit,  12  (1,  696  Littr^)  oi  ^ttX  5Jy  bid  toOto  3e2p  tV  f^f^  ^ 


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GooQh 


HEIDEL.  —  ncp\  +wr€«s.  117 

"  There  be,"  we  read,***  "  who  have  reduced  vilifying  the  sciences  to 
a  science,  as  those  who  engage  in  this  pursuit  opine.  I  think  not  so ; 
but  they  are  giving  an  exhibition  of  their  own  learning.  To  me  it  ap- 
pears that  to  make  a  discovery,  that  were  better  made  than  left  undis- 
covered, is  the  desire  and  function  of  understanding,  and  to  advance 
to  completion  that  which  is  half  finished,  likewise ;  but  to  essay  with 
ungentle  words  to  shame  the  discoveries  of  others,  oneself  bettering 
nothing,  but  casting  reproach  upon  the  discoveries  of  those  who  know 
before  those  who  do  not  know,  this  appears  to  me  not  the  desire  and 
function  of  understanding,  but  argues  natural  depravity  even  **•  more 
than  want  of  science."  Another  interesting  passage  is  the  following :  i'® 
"  Medicine  has  long  had  an  established  principle  and  a  method  ***  of 
its  own  invention,  in  accordance  with  which  the  many  excellent  discov- 
eries were  made  in  the  long  lapse  of  time  and  in  accordance  with  which 
also  the  rest  will  be  made,  if  one,  having  proper  capacity  and  a  knowl- 
edge of  past  discoveries,  shall  take  these  as  the  point  of  departure  for 
his  quest.  But  whoso,  casting  these  aside  and  rejecting  all,  shall  essay 
to  investigate  after  another  method  and  in  other  fashion,  and  shall  say 
that  he  has  discovered  aught,  is  deceived  and  deceives  others ;  for  that 
is  impossible."  Elsewhere  we  are  assured  *'*  that  the  science  of  medi- 
cine has  nothing  left  it  to  discover,  since  it  now  teaches  ever3i;hing, 
characters  as  well  as  proper  seasons.  He  who  has  learned  its  teachings 
will  succeed  with  or  without  the  favor  of  fortune.*'* 

From  this  it  will  be  seen  that  the  ancient  art  or  science  of  medicine 
had  not  only  developed  the  spirit  of  science  and  formulated  in  general 
its  ideals,  but  that  in  some  minds  it  had  attained  to  a  position  of  such  in- 
dependence that  it  might  lay  claim  to  finality.     The  fact  that  the  claim 

oy#c  iov<ray  oi/5^  xaXQs  ^to^vriv  Tqv  d.pxai'n*'  diro^aXiffdai,  €l  y.))  ^x^i  wepi  rrdtn-a  &Kpi' 
/Ki/y,  dWd  ToXd  /xaXXov,  did  t6  iyyv^,  ol:iaL,  tov  drpeKecTTdTou  6/xov  dvvaadai  iJK€iv 
Xo7«r/i^  Tpoffieffdaif  xal  ix  iroXX^s  dyv<afflTji  Oavudj^ctM  rd  i^€vpr)fiivaf  <bs  koXws  koI 
6p$un  i^€6prfTatt  Kcd  oifK  drb  rixv^' 

"•  n.  T^x»"7»,  1  (6,  2  Littr^. 

**•  I  read  in  /uaXXov,  and  drcxWiyf. 

"•  n.  dpxodrjs  IrrrpiKTJs,  2  (1,  672  Littr^. 

W*  Cp.  n.  €V(Txvf^<rvvrit,  2  (9,  226  Litti^),  and  above,  n.  147,  Kal  oIk  dxb  rijxrjt. 

^"  n.  T&irufy  Twv  Kard  dvdptaxoVy  46  (6,  342  Littr^)  lr}TpiKij  StJ  /mi  Sox^ei  ijdrj  dy€V' 
pTjcdai  5X17,  ffrtt  oOrfjis  ^X"»  ^*^  dt8d(TK€i  ^Kaffra  Kal  rd  i$€a  Kal  toj>s  Kaipotjs.  6s  ydp 
oCtwj  IrfTpiK^  hrioTaraif  i\dxt<Tra  rqv  T^r)v  iirifjjp€i,  dWd  Kal  dveu  tijxv^  'f^'i  ^^ 
T&XV  €^Tfonj6€Lr)  &k  ^i^i)K€  ydp  IrfrpiK)  irSuTa,  Kal  ^a/yrrat  twv  <ro<pt<rfidT(t)y  rd  /rdXXi- 
era  ip  aini  <rvyK€ifX€va  iXdx^ffra  T^rjt  ScTffdai '  ij  ydp  r^x't  avroKpartji  Kal  ovk  Apx^raif 
oifd'  iw*  eCxv  i<fTiv  ain-)i»  (an  avrrit  ?)  iXBily '  ij  5^  iviffrififirj  dpxeral  re  Kcd  eurvx'^t 
icrrip,  6ir!rray  /3oi/Xi7rat  6  ixiardfievos  xfiV^^^'-h  f^^- 

"»  Cp.  n.  T^ioyf,  4  and  6  (6,  6  and  10  Littr^.  II.  eCurxvP^^f,  7  (9,  258 
Li^tr^  the  charlatans  are  said  to  depend  on  lack. 


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118  PROCEEDINGS   OF  THE   AMERICAN    ACADEMT. 

was  preposterous  must  not  be  allowed  to  obscure  the  significance  of  its 
being  made ;  for  at  any  time,  past^  present,  or  future,  such  assurance 
must  be  essentially  subjective,  based  upon  the  sense  of  inner  congruity 
or  harmony  of  the  world  of  thought  organized  and  interpreted  by  the 
system.  It  was  just  this  feeling  of  independence  to  which  we  attributed 
the  growing  sense  of  the  autonomy  of  Nature  that  made  it  possible  for 
philosophers  to  dispense  with  the  intervention  of  the  gods.  The  scien- 
tific movement  in  philosophy  and  medicine  runs  parallel  courses  with 
constant  interaction.  How  constant  and  important  this  reaction  of  one 
npon  the  other  really  was  we  can  never  know.  In  the  present  state  of 
our  knowledge  it  would  be  foolish  even  to  attempt  to  say ;  but  that  it  is 
a  fact,  and  a  fact  of  large  significance,  none  will  deny.  The  physicians 
could  not  overlook  the  relation  of  the  individual  human  organism  to 
the  world.  They  devoted  themselves  with  keen  intelligence  to  the  study 
of  atmospheric  and  climatic  conditions  ^'^  affecting  the  health  of  man, 
and  in  so  doing  could  not  avoid  trenching  on  the  domain  of  the  physi- 
cal philosopher.  In  countless  other  ways  subjects  of  prime  importance 
to  the  philosopher  came  within  the  purview  of  the  writer  on  medicine. 
For  all  these  questions  the  works  of  Hippocrates  are  for  us  an  inex- 
haustible source  of  information,  though  they  rarely  enable  ,us  to  refer 
an  opinion  to  its  responsible  author.  It  is  therefore  a  matter  of  interest 
to  see  the  intimacy  of  the  relation  between  these  kindred  disciplines 
recognized  by  the  physicians. 

The  Hippocratean  treatise  On  Decorum  ^^^  sketches  in  ideal  por- 
traiture the  man  of  science  (especially  the  physician)  and  the  philoso- 
pher and  contrasts  with  them  the  charlatan,  who  appears  in  the  colors 
familiar  to  all  in  the  Platonic  portraits  of  the  Sophists.  There  the 
physician  is  called  a  god-like  philosopher,*'®  since  he  combines  theory 
and  practice  of  all  that  is  true  and  beautiful.  Philosopher  and  physi- 
cian have  the  same  virtues ;  their  differences  are  slight  ^'^  Elsewhere, 
however,  a  distinction  is  drawn  between  the  physician  and  the  physical 
philosopher  in  respect  to  method.  "  There  are  those,"  we  are  told,*'* 
"  who  have  essayed  to  speak  or  write  concerning  medicine,  basing  their 
argument  on  the  hot  or  the  cold,  on  the  moist  or  the  dry  or  any  thing 


W4  Cp.  especially  the  treatise  II.  &4pw,  itddrwi^,  t6twp  (2,  12  foil.  Littrtf ;  I,  38 
foil.  Klihlewein). 

"•  n.  eiJcrxiy/tMxrtJriTf  (9,  226  foil.  Littr^. 

^•^  Ibid,    c.  6  (9,  232  Littr€)  dib  Set ,  .  .  fierAyttP  r^w  ffOi^lrpf  h  tV  IrrrpiKiiP  ical 

TTJP  IrfTpLK^P  is  T^  ffO^TfW,       ItfTpbt  7*^  ^iXScO^S  lff6$€0S. 

"^  Ibid.   oO  ToW^  yh.p  5ia<f^op^  hrl  rd  frepa  '  Kal  ydip  hi  Td  Tp6s  ao^rp^  h  lirrpuc^ 
Tdtn-a,  d<f>i\apyvplrff  etc. 

"•  n.  dpxalris  Inrpucijs,  1  (1,  570  foil.  Littrtf ;  1,  1  foil.  Kiihlewein). 


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HEIDEL.  —  Iltpl  ^tfircox.  1 19 

else  they  choose,  reducing  the  causes  of  human  diseases  and  death  to  a 
minimum,  one  and  the  same  for  all,  basing  their  argument  on  one  or 
two ;  but  in  many  of  the  novelties  they  utter  they  are  clearly  in  the 
wrong.  This  is  the  more  blameworthy,  because  they  err  touching  an 
actual  art  which  all  men  employ  in  tiie  greatest  emergencies  and  in 
which  they  honor  most  the  skillful  practitioners.  Now  there  are  prac- 
titioners, some  bad,  some  excellent ;  which  would  not  be  true  if  medi- 
cine were  not  actually  an  art,  and  no  observations  or  discoveries  had 
been  made  in  it  All  would  be  equally  unskilled  and  ignorant  of  it, 
and  the  cure  of  diseases  would  be  wholly  subject  to  chance.  As  a  matter 
of  fSiCt,  it  is  not  so ;  but,  as  artisans  in  all  other  arts  excel  one  the  other 
in  handicraft  and  knowledge,  so  also  in  medicine.  Therefore  I  main- 
tained that  it  had  no  need  of  vain  hypotheses,  as  is  the  case  in  matters 
inaccessible  to  sense  and  open  to  doubt.  Concerning  these,  if  one  es- 
say to  speak,  one  must  resort  to  hypothesis.  If,  for  example,  one  should 
speak  and  entertain  an  opinion  touching  things  in  the  heavens  or  under 
the  earth,  it  would  be  clear  neither  to  the  speaker  nor  to  those  who 
heard  him  whether  his  opinion  was  true  or  &lse ;  for  there  is  no  appeal 
to  aught  that  can  establish  the  truth."  While  tlie  resort  to  hypothesis 
in  medicine  is  here  denounced  there  are  instances  of  such  use  in  the 
works  of  Hippocrates,  notably  in  IIcpl  <f>va-uivA^^ 

One  more  passage  *••  relating  to  philosophy  we  may  properly  quote 
here.  "  Whoso  is  wont  to  hear  men  speak  concerning  the  human  con- 
stitution beyond  the  range  of  its  bearing  upon  medicine,  will  find  the 
following  discourse  unprofitable ;  for  I  do  not  say  that  man  is  wholly 
air,  nor  fire,  nor  water,  nor  earth,  nor  any  thing  dae  that  is  not  clearly 
present  in  man.  This  I  leave  for  whoso  wills  to  say.  Yet  I  think  that 
those  who  say  this  are  in  error ;  for  they  agree  in  point  of  view,  but 
not  in  statement.  Nevertheless  the  argument  in  support  of  their 
point  of  view  is  the  same ;  for  they  say  that  all  that  exists  is  ona  This 
is  tiie  One  and  All ;  but  they  give  it  different  names.  One  calls  the 
One  and  All  air ;  another,  fire ;  a  third,  water;  still  another,  earth.  And 
each  supports  his  argument  with  proof  and  evidence,  which  amounts  to 
nothing.  For,  seeing  that  they  are  all  of  one  mind,  but  say,  one  man 
this  thing,  another  that,  it  is  clear  that  they  have  no  knowledge  of  the 

*••  Littr^  6,  90  foil.  The  treatise  is  a  Sophistic  exercise,  intended  to  prove  that 
air,  particularly  the  air  in  tlie  body,  is  the  cause  of  all  diseas^ps,  and  employs  hypoth- 
esis avowedly.  Cp.  c.  15  (p.  114  Littr^.  The  treatises  11.  ^iViot  &r&p(&rov  and 
n.  ipxf^V^  lijrpuciit  aim  their  polemic  at  such  exercises,  as  Littr^  justly  obtterves, 
6,  88. 

^•0  n.  i>^iot  dr^pc^ov,  1  (6,  32  foil.  Littr^.  Littr^,  6,  88,  thinks  the  author  of 
this  treatise  had  definitely  in  mind,  among  others,  the  essay  II.  i»wm. 


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120  PROCEEDINGS   OF   THE   AMERICAN   ACADEMY. 

matter.  Of  this  one  would  be  most  thoroughly  convinced  if  one  at- 
tended their  disputations ;  for  when  the  self-same  men  dispute  with 
one  another  in  the  presence  of  the  self-same  auditors,  the  same  man 
never  thrice  in  succession  prevails  in  argument ;  but  now  one  prevails, 
now  another,  and  again  he  who  has  the  most  flowing  speech  before  the 
mob.  Surely  it  is  fair  to  demand  that  he  who  claims  to  have  the 
right  opinion  about  things  should  cause  his  argument  always  to  pre- 
vail, assuming  that  his  opinion  is  true  and  that  he  properly  sets  it 
fortL  As  for  me,  I  think  that  such  men  for  want  of  understanding 
refute  one  another  by  the  terms  of  their  very  argument  and  establish 
the  contention  of  Melissus." 

If,  now,  we  recall  to  mind  those  ideals  and  conceptions  anticipated 
above  in  the  first  section  of  this  study,  we  shall  have  a  feir  notion  of 
science  as  it  was  conceived  among  the  Greeks  of  the  fifth  century  b.  c. 
But  we  have  still  to  inquire  just  what  questions  the  scientist  addressed 
to  nature ;  and  to  this  quest  we  may  now  turn. 

Science  essays  to  determine  the  facts  and  to  explain  them.  The  one 
thing  depends  upon  the  other.  If  you  find  a  rock  and  ask  what  it  is, 
it  becomes  necessary  to  discover  whether  it  is  in  position  or  not  It 
proves  to  be  a  boulder,  and  examination  shows  that  it  is  metamoi;phic 
in  character :  finally  it  is  identified  as  Laurentian,  and  its  presence 
here  is  explained  by  reference  to  glacial  action.  The  definition  of  the 
fact  involves  the  explanation ;  but  explanation  is  the  motive  of  the  sci- 
entific study  of  the  fistct,  in  contrast  to  the  practical  interest  which  leads 
merely  to  classification.  The  curious  child,  no  less  than  the  philoso- 
pher, asks  the  question.  Why?  £ut^  while  almost  any  answer,  judi- 
ciously framed,  will  satisfy  the  child,  the  philosopher  knows  that  the 
question  may  receive  very  different  answers  according  to  its  specific 
intention.  To  ask  why  is  to  demand  an  explanation ;  and  '  cause '  is 
our  generic  name  for  explanation.  Different  as  individual  attempts  at 
explanation  may  be,  they  are  reducible  to  a  few  kinds.  We  are  &mil- 
iar  with  the  four-fold  causal  principle  of  Aristotle,  and  with  the  £sM;t 
that,  while  recognizing  four  kinds  of  causation  and  insisting  that  in  ex- 
planation one  should  adduce  all  causes,  he  did  not  find  it  possible  to 
reduce  all  to  one,  but  was  compelled  to  content  himself  in  the  ultimate 
analysis  with  two.^®^ 

This  is,  of  course,  not  the  place  to  discuss  matters  of  metaphysics 
except  so  far  as  they  pertain  or  contribute  to  our  purpose ;  but  there 
is  here  a  point  of  some  interest  for  us.  We  have  noted  that  of  Aris- 
totle's causes,  the  material  points  to  the  past     It  is  that  which  is 

1"  Cp.  Ritter-PreUer,  §§  395-896. 


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HEtDEL.  —  UcpX  <|>v(rco>s.  121 

there  to  begin  with.  "In  the  beginning,"  sajrs  the  materialist,  "was 
matter."  "  No,"  replies  the  theist^  "  in  the  beginning  God  created 
matter  ; "  and  thus  a  pre&ce  is  placed  before  the  beginning.  The  tele- 
ologist  and  the  pragmatic  explain  all  with  reference  to  the  end,  which 
justifies  the  means.  All  alike  endeavor  to  define  the  fact  in  the  hope 
of  explaining  it ;  but  it  remained  for  a  Socratic  to  detect  the  teleologi- 
cal  import  of  logical  definition  and  hence  practically  to  identify  it  with 
the  final  cause.  We  have  referred  to  the  principal  classes  of  philoso- 
phers with  tiie  exception  of  the  positivist.  If  the  materialist  defines 
things  with  reference,  so  to  speak,  to  the  past,  and  the  teleologist,  with 
reference  to  the  future,  the  positivist  asks  neither  whence  nor  whither, 
but  how.  Definition  for  him  becomes  description,  and  description  in 
universal,  timeless  terms.  Such  at  least  is  the  logic  of  his  position. 
The  reason  why  Aristotle  did  not  find  it  possible  to  reconcile  his  ulti- 
mately two-fold  causation  in  his  '  formal '  cause  is  that  historically  he 
was  the  heir  of  the  pre-Socratic  and  the  Socratic  methods,  of  which 
the  former  deified  the  material,  the  latter  the  final,  cause.  ^^*  The 
degree  of  advancement  in  the  formulation  of  the  positivist  attitude 
was  not  such  as  to  compel  a  recognition  in  logic  and  metaphysics, 
although  it  would  not  be  unfii.ir  to  say  that  there  was  much  of  the  pos- 
itivist spirit  in  the  scientific  thought  of  the  fifth  century.  Apparently 
it  was  the  concreteness  of  Greek  thinking,  more  than  anything  else, 
that  obscured  the  significance  of  the  scientific  impulse  as  such.  Every 
process,  as  we  have  seen,  no  matter  how  abstract,  assumed  in  the 
thought  of  the  Greeks  the  form  of  a  series  in  time,  or  of  a  history  with 
a  proper  beginning.  How  much  of  this  was  conscious  device,  how 
much  instinctive  procedure,  we  shall  never  know.  Even  the  ideal  con- 
struction of  the  world  in  Plato's  Timaeus  was,  however,  taken  as  an 
intended  vera  historia  by  the  literal-minded  Aristotle. 

Accordingly  we  are  not  surprised  to  find  that  Aristotle  sets  down  the 
pre-Socratics  as  mentioning  only  the  material  causes  of  things.  This 
means,  however,  as  we  may  now  see,  that  they  did  not  bring  forward 
efficient  causes — that  is,  chiefly,  (Jod  —  nor  formal  causes  —  that  is, 
definitions  or  descriptions  —  nor  final  causes,  as  sufficient  principles  of 
explanation.  It  does  not  mean  that  they  were  not  interested  in  the 
processes  of  nature  as  such  or  in  their  precise  methods  and  laws. 
This  no  one  would  deny ;  but  it  is  a  point  of  prime  importance,  whose 
significance  is  firequently  overlooked.  What  Hippocrates  says  of  the 
monists  is  true  of  them  all.  "  They  agree  in  point  of  view,  but  not  in 
statement."    Why  the  difference  in  language  1    Because  one  kind  of 

^*  The  logical  aspect  of  this  situation  I  sought  to  set  forth  in  luy  essay  on  The 
Neceuary  and  the  Contingent  in  the  Aristotelian  System, 


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122  PBOCEEDINQ8  OF  THE  AMEBICAN  ACADElfT. 

primal  matter  seemed  to  lend  itself  better  than  another  to  the  explan- 
ation of  phenomena.  The  elements  were  interesting  only  as  means  to 
an  end.  It  was  the  regularities  of  phenomena  more  than  anything 
else  that  drew  the  attention  of  the  philosopher ;  presumably  it  was  this 
aspect  of  nature  which  counted*  most  strongly  in  fii.yor  of  a  single  pri- 
mary substance.  But  the  tendency  to  simpUiy  was  indulged  too  &x 
and  led  ultimately  to  the  opposite  extreme. 

Science,  then,  in  attempting  to  explain  things,  assigns  the  cause 
and  interprets  the  &ct8  in  accordance  with  analogies  drawn  from  expe- 
rience. In  Hippocrates,  n.  ^wcuv,  c.  15  we  read  :  "Airs,  tiien,  have 
been  shown  to  be  most  mischievous  in  all  diseases  :  other  causes  are 
only  accessory  and  ancillary,  but  this  has  been  shown  to  be  the  real 
cause  of  diseases.  I  promised  to  declare  the  cause  of  diseases,  and  I 
have  shown  that  wind  (iivcvfia)  lords  it  over  otiier  things  and  particu- 
larly over  the  bodies  of  living  beings.  I  have  applied  the  reasoning 
to  known  maladies,  and  in  them  the  hypothesis  has  been  shown  to  be 
true."  "  It  is  the  function  of  the  same  intelligence  to  know  the  causes 
of  diseases  and  to  know  how  to  treat  them  with  all  the  resources  of  the 
art  of  healing. "^'^  What  applies  to  the  microcosm,^**  is  equally 
true  of  the  cosmos.  The  causes  must  be  sought  everywhere ;  for  as 
Plato  says,^*'  citing  Hippocrates  as  his  authority,  one  cannot  know 
the  nature  of  man  without  knowing  the  nature  of  the  whola  We  are 
accustomed  to  think  that  strict  science,  based  upon  the  knowledge  of 
causes,  dates  from  the  age  of  Plato  and  Aristotle,  but  such  is  not  the 
case.^**    In  the  Republic  i*^  Plato  suggests  that  in  the  eflFort  to  read 

"»  Hippocrates,  H.  Wx»^.  H  (6,  20  Litti^). 

^^  The  comparison  is  old  (cp.  Auaximeues,  fr.  2),  though  the  expression  only 
occurs  later ;  cp.  Democritus,  fr.  84. 

"»  Phatdr,  270  B  foil. 

"•  Cp.  Arist.  De  PartU  Animal,  640*4  foil.  ;  De  Sensu,  486»15  <ca2  M  loi  ^<^- 
Tos  '  wept  iDv  dftaptfriov  rl  re  ^icatrroy  ai^runr,  koI  Sid  rlwit  alrlat  trvfJifkUifti,  4*vauco0  6i 
Kul  Tepl  iryulai  xal  vixrov  rAj  wpurrai  IStuf  dpxdt  (cp.  Hippocrates,  11.  dpxcUrft  Itirpitc^, 
r^v  dpxV  T"^*  alri-qf  .  .  .  voinnav  t€  Kal  Baydrov) '  oOt€  ydp  irfUuuf  odrt  vbaw  OU0  re 
yly€<r0ai  roXt  iffTtprifUrois  fW^f.  Sib  ox^^^  "^^^  '''*  ""'P^  0i5<r€trff  ol  x\«t<rTOi  xal  tuw; 
larpCtv  ol  ^i\o<Toif>(tn4p<t)t  r^v  rix^ifv  fieri&vrts,  ol  fUv  TeXcvruHrc  c/f  rd  irtpl  larpiKfjs,  ol 
^i  ix  tQv  wtpl  0iVf(tft  d/>x<»^A(  ^^P^  T^  larpiKrjs.  J)e  Oener.  Animal.  769*  6  €lpiiKa<n 
Si  TUf€t  Ttair  if>v<rio\6rY(av  Koi  h-tpoi  (the  medical  writers)  ircpi  to6to9p,  did  rip*  cUtIop  Sptoia 
Kai  6»6pLOia  ylyv^rai  roit  7oi«0<rt.  Cp.  De  ParU,  Animal,  641*  7  ;  Met,  1069*  25  fMp* 
Tvpodai  Si  Kal  ol  dpxatoi  tpytfi  '  rrjt  ydp  otV/af  if^ow  dpxdt  koX  vroix^'ia  kqX  afrm; 
P)id,  988*  22  Scoi  fikv  otp  h  rt  rb  waif  koI  fdaif  riyd  0i^tv  wt  CXriP  rt^/cwi,  koI  ra&rrfp 
ffUfxariKfjif  Kal  fUy^Bot  ^oiway,  SrjKwr  Sri  iroWaxC^  dfMprdPOwnp  .  .  .  xcU  irepi  y€v4vt(a% 
Kal  <f>0opdit  iirix€ipowT€i  rd%  alrlat  X^etv  Kr\.  It  is  evident  that  Aristotle  is  here 
enlarging  upon  the  criticism  of  the  monists  contained  in  Hippocrates,  U.  ^iciot 
drOpdnrov,  c.  1,  quoted  above,  p.  119  folL 

1"  368  D  foil. 


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HEIDEL.  —  H^l  ^^(TCMf .  1 23 

the  character  of  justice  one  may  perhaps  gain  some  advantage  from 
contemplating  it  as  writ  large  in  the  history  and  constitution  of  the 
state  and  noting  how  it  originated.  ^'^  There  were  others  who  pre- 
ferred to  reverse  the  procedure,  hoping  to  throw  light  on  general  nature 
by  stadjring  the  nature  of  man.  Of  these  we  have  an  example  in  Hip- 
pocrates, Ilept  (Spx^V  ^TP**^-  "  Certain  physicians  and  philosophers, " 
he  says,***  "assert  that  one  cannot  know  the  science  of  medicine 
without  knowing  what  man  is,  how  he  originally  came  into  existence, 
and  of  what  substances  he  was  compounded  in  the  beginning  ;  and  this 
he  who  would  properly  treat  men  must  be  thoroughly  cognizant  of. 
Now  the  contention  of  these  men  really  looks  to  phUosopby,  as  do 
Empedocles  and  others  who  have  written  IJcpi  <f>wr€m.  As  for  me,  I 
consider  that  what  a  philosopher  or  physician  has  said  or  written  ITcpi 
^vo-ccd?  has  less  relevancy  to  medicine  than  to  painting ;  and  I  am  of 
opinion  that,  so  &r  as  concerns  knowledge  ll€pi  <^vcr€(i>9,  one  can  know 
nothing  definite  about  it  except  from  medicine ;  but  this  may  be  thor- 
oughly learned  when  men  go  about  it  rightly.  Hitherto,  it  seems  to 
me,  we  are  far  from  it :  &r,  that  is  to  say,  from  having  a  scientific 
knowledge  of  what  man  is  (that  is  to  say,  what  his  constitution  is), 
and  to  what  causes  he  owes  his  origin  and  the  rest,  in  any  exact  sensa 
Now  so  much  at  least  it  is  indispensable  that  the  physician  should 
know  Utpl  ^v<re<D9  and  should  greatly  concern  himself  to  know,  if  he  is 
to  do  any  part  of  his  duty ;  to  wit,  what  a  man  is  (i.  e.  what  his  con- 
stitution is)  relative  to  meat  and  drink,  and  what  he  is  relative  to  the 
rest  of  his  mode  of  life,  and  what  results  follow  for  the  indmdual  from 
particular  things,  and  all  this  not  merely  in  general  terms,  as  a  g., 
'  cheese  is  unwholesome  food,  for  it  distresses  one  who  eats  plentifully 
of  it ' ;  but  what  particular  distress  it  causes,  and  for  what  reason,  and 
to  what  ingredient  of  the  man's  constitution  it  is  unsuitable."    The 

^•*  Cp.  nlao  the  myth  in  Plato's  ProtcigoraSf  320  C  foil.,  where  the  virtues  are 
illustrated  by  the  story  of  their  origin.  An  interesting  contrast  is  presented  by 
Aristotle,  Be  Oener,  Animal,  778^  16  foil.,  where  he  discusses  the  cases  in  which 
biological  phenomena  are  to  be  interpreted  teleologically  or  physically  ;  yh^aa  is  for 
the  sake  of  o^ta,  and  oinrla  is  the  cause  of  y^<rtt.  The  ancient  physiologers  thought 
otherwise  ;  hence  they  recognized  only  material  and  efficient  causes,  not  even  discrim- 
inating between  them.  He  states  his  own  view  thus  :  o&  did  t5  yLyv€<Tdai  fKaarov 
ir<M6r  Ti,  dih  rovro  iroibv  n  iffTlv^  8<ra  rcraytUva  xal  (hpur/i^va  fpya  rrji  <p6(r€ci)t  ivriVy 
dXXA  /btaXXor  iiA  rb  cimi  roiaSi  ylyvrrai  roiavra.  The  opposite  argument  is  presented 
in  Plato,  Euthyphro,  10  A  foil.  The  latter  clearly  represents  the  common  logical 
procedure,  based  upon  the  common  usage  of  the  Greeks  as  established  in  the  pre- 
Socratic  period,  though,  strictly  speaking,  the  former  conforms  perfectly  to  the  teleo- 
logical  logic  of  the  Socratics.  This  is  another  illostration  of  the  inner  contradiction 
of  the  Aristotelian  logic. 

"•  C.  20  (1,  p.  24  Kiihlewein). 


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124  PROCEEDIXGS  OF  THE  AMERICAN  ACADEMY. 

writer  then  proceeds  to  say  that  the  physician  must  study  the  particu- 
lar food-stuflf  and  its  physiological  action  as  well  as  the  individual  con- 
stitution, determining  which  of  the  humors  is  TrXctwK  cvcwv  koL  fxakkov 
cvSuvao-Tcvoij'  iv  tw  crco/xaTt,  and  then  knowing  which  humor  is  inimical  ^^^ 
to  the  particular  food-stufif  and  is  roused  to  hostility  by  it,  he  can  pre- 
scribe a  suitable  diet. 

Here  we  find  set  up  an  id6^1  that  science  is  still  &r  from  realizing. 
Only  a  year  or  two  ago  an  eminent  physician  stated  that  the  specific 
physiological  action  of  drugs  still  remained  undiscovered,  with  the 
possible  exception  of  two  or  three.  Even  for  foods  a  bare  beginning 
has  been  made.  We  may  recall  that  Hippocrates  elsewhere  ^^^  insists 
that  each  phenomenon  has  its  own  <^vcri9  or  natural  cause  (law  ?)  and 
that  Heraclitus  likewise  proposed  to  explain  each  thing  according  to 
its  own  law,  thus  aspiring  to  meet  the  two-fold  requirement  of  science 
which  aims  to  discover  both  the  proximate  causes  of  events  and  the 
ultimate  statement  of  universal  law.  There  is,  moreover,  a  further 
interest  attaching  to  the  passage  just  quoted  at  length.  It  formulates 
three  questions  raised  by  philosophers  and  by  physicians  philosophi- 
cally inclined:  (1)  what  man  is;  (2)  how  he  originated;  and  (3)  of 
what  he  is  composed.  The  first  and  third  questions,  as  we  have  seen, 
practically  coincide ;  the  second  agrees  with  its  fellows,  except  that  it 
regards  the  process  rather  than  the  result,  which  is,  however,  only  an 
analysis  read  backward  and  cast  into  the  time-form.  Hippocrates  does 
not  object  to  the  questions,  as  such ;  he  merely  regards  them  as  too 
general  and,  therefore,  as  premature,  considering  the  stage  of  advance- 
ment attained  by  positive  science  in  his  time.  His  attitude  is  instruc- 
tive, however,  since  it  is  obviously  that  of  a  scientist  of  knowledge  and 
discernment  looking  with  critical  eye  upon  the  venturesome  undertak- 
ings of  less  mature  minds ;  for  science  naturally  proceeds  from  the  gen- 
eral to  the  particular.  ^^* 

The  same  position  is  taken  in  the  essay  Ilcpt  Biairrj^i  i^'  "  I  say  that  one 

*^®  In  the  microcosm  we  thus  have  a  picture  in  miniature  of  the  cosmic  ir6\€fios 
of  elemental  forces,  in  which  one  element  prevails  (iiriKpaTeT)  at  one  time,  a  second 
at  another.  It  ia  the  function  of  the  physician  to  support  (^oridciy)  the  losing  ele- 
ment and  so  to  restore  the  harmony  of  a  ])roper  balance  of  powers.  Op.,  for  example, 
11.  lepijs  voijffovt  18  (6,  394  foil.  Littr^)  xph  ^^  ^'<»i  ^»'  TaOT-Q  rrj  vovui^  Kal  ivr^ffi  &\\o<ny 
dird(Trj<n  fir]  aC^eiv  xA  voutr^/xara,  dXXd  (nrevSeiv  Tp^x^it^  trpoJip^povTa  t J  voOaff  t6  roXe- 
puJ^arov  iKdffTT^y  koX  fi^  rb  <pi\ov  Kal  (rOvrjdes. 

^'^  See  above,  n.  57,  and  Plato,  Phacdr,  270  B  quoted  below,  n.  175. 

*^'*  There  is  an  interesting  parallel  to  the  procedure  of  Hippocrates  in  Aristotle's 
discussion  of  the  winds,  Meteor.  360*  27  and  the  comments  of  Olympiodorus.  See 
Gilbert,  DU  meteorologischen  Theorien  des  gricchischen  AlUrtums^  p.  624,  n.  2. 

"»  A, 2  (6,  468  Littre). 


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HEIDEL.  —  UtfX  ^vmm.  125 

who  is  to  write  a  proper  treatise  on  human  dietetics  must  first  of  all  know 
the  constitution  of  man,  —  know  and  distinguish  :  he  must  know  of 
what  he  was  constituted  in  the  beginning  and  distinguish  (in  the  in- 
dividual case)  by  what  constituents  he  is  ruled.  Unless  he  knows  his 
original  composition,  he  wilt  not  be  able  to  know  the  results  that  flow 
from  it ;  unless  he  distinguish  ^^*  the  ruling  constituent  in  the  body, 
he  will  not  be  capable  of  administering  what  is  beneficial  to  the  man. 
This,  then,  the  writer  must  know ;  but  he  must  have  learned,  in  addi- 
tion, the  action  —  whether  due  to  nature  or  to  human  constraint  and 
art — that  each  kind  of  meat  and  drink  has  which  we  employ  by  way 
of  diet."  To  these,  or  similar,  words  of  Hippocrates  Plato  refers  in 
the  Pkaedrus  ^^'  with  cordial  approval.  It  thus  becomes  a  common- 
place that  distinction  and,  above  all,  analysis  of  a  complex  whole  into 
its  parts,  are  necessary  to  clear  ))hilosophical  thought ;  ^^*  and  that,  in 
order  to  make  clear  the  nature  of  anjrthing,  it  is  desirable  by  an  act  of 
imaginative  synthesis  to  reconstitute  the  fact  thus  analyzed. 

The  boy  who  takes  his  watch  to  pieces  and  tries  to  put  it  together 
again, — usually  witU  scant  success,  because  synthesis  lags  far  be- 
hind analysis, — indulges  an  ideal,  rather  than  a  practical,  instinct. 
He  has  no  thought  of  making  watches,  but  wants  to  understand  his 
time-piece.  At  the  beginning  of  the  Politics  ^^^  Aristotle  puts  the 
matter  clearly  :  "As  in  other  departments  of  science,  so  in  politics, 
the  compound  should  always  be  resolved  into  the  simple  elements  or 
least  parts  of  the  whole.  We  must  therefore  look  at  the  elements  of 
which  the  state  is  composed.  ...  He  who  thus  considers  things  in 
their  first  growth  and  origin,  whether  a  state  or  anything  else,  will 

*^*  I  read  Suiyv(iHrerai  for  yvtbaerai, 

WB  270  B  ip  dfjufxnipais  (sc.  medicine  and  rhetoric)  Set  SitXMai  ^jJcrw,  (rt^/Mtrof 
fUvivri  h-ifH^  f^^f  ^  ^^  fy  ^^P9t  ^^  AiAXftf,  ytx^  rpipy  fi6yov  Kal  i/Mxeiplq.  dXXA  T^i^y, 
r{  f/iiv  iffdpfiOKa  Kai  rpo<pf)p  'irpoc<f>ip(jav  iryUiap  Kal  (ni)fJLrjp  ip.iroiifi<T€tv  .  .  .  ^f^vxvs  6tp 
^itovp  Hiiin  XA70W  Korovo^fiai  ofri  hwarhv  eZiwi  Avev  ry\%  rod  5\ov  <pv<r€U)S ;  El  fxh  'Iiriro- 
Kpdrei  yt  ry  tQp  'A<TK\rpria5ufP  dci  rt  xiB^ffOai,  oifdi  wept  (rthpuoLTOt  &p€v  t^  fu66dov 
ra^ijs  .  .  .  T6  toIpvp  ircpl^  0i;(r€Wf  (TKinrei  rl  irore  X^ei  ^liriroicpdTris  rt  koX  6  iXrfO^t 
Xiryos  '  &p  o^x  &de  Set  diapoeiaSau.  w€pl  drovovv  <p6ff€(as  '  irpujrop  fjjp,  dirXovc  fj  iro\v€id4s 
i<m  o5  T4pi  pov\rfa6fJL€$a  tlpai  aOrol  rcxwifol  Kal  dXXoi'  dwarol  iroieiPf  tirtira  3^,  fty  fih 
iLxXovp  5,  (FKoreTp  ri)p  SOpafUP  airoO,  riva  xp6x  rl  ir^^uice  tls  rb  dpay  txpy  ^  rlpa  eli  rb 
TaStip  (nrb  roO,  Olp  8i  wXtlu  ttdij  ixVt  f^^o.  dpiB/HTjcdfUvoPf  5irep  i<p*  ivbiy  roOr  Ibeip  i<f) 
ixdffrov,  Ty  rl  'toicip  a^b  x44>vk€p  fj  rf  rl  vaBcip  inrb  rod  ;  Kipdvpfi^i. 

^'*  Cp.  Plato,  Tim.  67  D  8ib  d^  avfjifxeiypip^a  airrd  re  rpbt  airrd  Kal  xpbt  dXXi/Xa 
tV  ToiKiXlop  icrlv  &v€ipa  '  tJj  8^  Set  Oeupobt  ylypcffOai  ro^  fUXXorras  xtpl  f^itrtuit 
eUbri  Xiryip  x/>V«^^«w.  But  to  study  the  roiKikla  of  things  requires  that  the  crazy- 
patchwork  be  set  in  order  by  analysis. 

ITT  1252*  24  foil.,  transl.  Jowett.  Aristophanes,  Thesmoph.  11  foil,  affords  a 
good  example  of  ^i^tt  —  '  constitution,'  which  at  once  suggests  '  origin.' 


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126  PROCEEDINCa  OF   THE   AMERICAN   ACADEMY. 

obtain  the  clearest  view  of  them.''  Qaite  apart  from  the  obvious  debt 
of  Aristotle  in  this  matter  to  Plato  ^^*  and  Hippocrates,  it  must  be 
clear  that  this  method  of  procedure  has  no  relevancy  to  the  distinct- 
ively Socratic  doctrine  of  definition  in  terms  of  the  end  or  purpose ;  it 
is  a  survival  from  the  naturalistic  or  mechanical  mode  of  thought,  de- 
veloped in  the  pre-Socratic  age,  which  explains  things  in  terms  of  their 
origin  and  physical  constituents. 

Socrates,  the  originator  of  the  teleological  method,  could  not  under- 
stand this  procedure.  To  his  mind  it  belonged  not  to  theory,  but  to 
the  sphere  of  the  practical  arts.  There  is  an  extremely  interesting 
passage  touching  tiiis  matter  in  Xenophon's  MemorabiliaA'^^  "Nor 
did  he  (Socrates)  converse,"  we  are  told,  "about  the  constitution  of 
the  world  (Trcpl  t^  twv  irdvnav  ^ucrcws),  as  the  majority  of  the  philoso- 
phers do,  inquiring  how  that  which  the  philosophers  call  the  cosmos 
originated  *••  and  by  what  mechanical  forces  ^®^  (dvdyiceu?)  the  phe- 
nomena of  the  heavens  are  brought  about,  but  he  even  declared  that 
they  who  worry  their  heads  about  such  matters  are  fools."  ...  "He 
inquired  also  concerning  the  philosophers,  asking  whether,  in  like  man- 
ner as  they  who  learn  the  human  arts  ^**  think  that  tiiey  shall  be  able 
to  make  what  they  may  learn  either  for  themselves  or  for  whomsoever 
they  please,  so  also  they  who  study  things  divine  think  that  when  they 
have  learned  by  what  mechanical  forces  they  severally  come  about,  they 
shall  at  their  pleasure  make  winds  and  rains  ^*'  and  whatever  of  the 

^T*  Especially  Repub,  868  D  foil.,  Pfuudr,  270  C  folL  Cp.  Plato's  summary  of 
tbe  Republic  in  Tim.  17  0  x^^J  «■<>''  ^^  ^*  ^MoC  ^O^m-tap  Xiryup  repl  ToAtrekif  ^  r6 
ice^dXatov  ota  re  Kal  i^  otup  dpSpQv  dpl<mi  Kartipaiper'  dp  fioi  y€p4(r6ai.  For  the 
thought  that  to  understand  a  thing  one  should  see  it  put  together,  cp.  Tim.  27  C, 
28  B,  90  E,  etc. 

"»  L  1,  11  and  15. 

^w  The  MSS  vary  between  f^v  and  ix^i.  The  fonner  emphasizes  the  process  of 
origination ;  the  latter  implies  it  in  the  question  as  to  the  truth  about  phenomena 
(rCjs  ^€i).  Cp.  Parmen.  fr.  10.  In  Hippocrates  u)s  ^et  is  often  used  in  relation  to 
^i^if  -•  constitution. 

^•*  Where  the  physical  philosopher  inquired  rlffip  {ipwriicdis)  dpdyicais  yiyptrai^ 
Socrates  asked,  if  at  all,  i  fKoara  6  Btbs  fitfxaMarai,  Xen.  Mem.  iv.  7,  6.  Cp.  ibid. 
I.  4,  14  where  ^6ff(t  —  BtoO  rpopolq.:  <p^it  has  become  the  mechanism  of  God's 
providence. 

^M  Cp.  Aristoxenus,  fr.  81  (MuUer,  F.  H.  O.,  Ii.  281)  4>rjirl  d*  'A.  6  ftowrucht 
JpdMf  €&ai  rbp  \6yop  rbpSt  *  *A$'tprriai  ydp  hrrvxtuf  IQuKpdrti  tQp  djfdpCjp  iicttpiop  hfa 
Ttyd,  K&v€iTa  a^ov  rvp0dpt(r$aif  tI  troitap  ^i\oao4>olrf  •  rod  5*  tlxbPTOS,  5rt  f^cSi'  wepl  roO 
dp0p<awlyov  ptov,  KarayeXdffcu  rbp  *lpbbp,  X^opra  fi^  Sj^PourOal  tipo,  rd  dpBpilnripa  KariditP 
dypooGprd  yc  rd  Bua.  Compare  the  opinion  of  those  who  held  that  one  cannot  know 
the  0(^(r<t  of  man  without  knowing  the  ^i^tt  toO  SXov. 

^M  One  is  tempted  to  regard  this  as  a  hit  at  Empedocles ;  cp.  fr.  111.  Because 
of  this  expression  Empedocles  has  been  set  down  as  a  charlatan ;  bat  in  the  present 


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HEIDEL.  —  Ilipl  ^C<rm%.  1 27 

sort  they  may  desire,  or  whether  they  do  not  even  conceive  such  a  hope, 
bat  are  content  merely  to  know  how  these  phenomena  occur."  The 
di£ference  between  the  physical  and  the  teleological  points  of  view  is 
beautifully  illustrated  by  the  story  told  by  Plutarch  in  his  Life  qf  Per- 
icles :  ^**  "  It  is  related  that  on  a  certain  occasion  the  head  of  a  goat 
with  a  single  horn  was  brought  from  the  country  to  Pericles,  and  that 
Lampon,  the  seer,  when  he  saw  the  strong,  solid  horn  growing  out  of 
the  middle  of  the  forehead,  said  that,  there  being  in  the  city  two  rivals 
for  power,  Thucydides  and  Pericles,  the  power  would  come  to  the  one 
to  whom  the  sign  was  given.  Anaxagoras,  however,  cutting  open  the 
skull,  showed  that  the  brain  was  not  fully  developed  at  the  base,  but 
shrunken  from  its  integument  and  coming  somewhat  to  a  point,  egg- 
like, at  the  spot  where  the  horn  sprouted.  At  the  time  Anaxagoras 
was  applauded  by  those  who  were  present ;  but  Lampon's  turn  came 
shortly  afterwards,  when  the  power  of  Thucydides  was  broken  and  the 
affairs  of  the  people  came  steadily  under  the  direction  of  Pericles. 
There  was  nothing,  however,  so  fer  as  I  can  see,  in  the  way  of  the  phy- 
sical philosopher  and  the  seer  ^*'  being  equally  in  the  right,  the  one 

state  of  his  poem  we  are  not  in  position  to  judge.  The  promise  of  fr.  2  is  sufficiently 
modest  (cp.  Parmenides,  fr.  10  and  11).  I  incline  to  think  that  fr.  Ill  belongs  to 
the  concluding  passage  of  his  philosophical  poem,  and  voices  the  high  hopes  of  the 
author  that  the  secrets  of  nature  will  soon  be  laid  bare.  The  age  of  Empedocles 
was  intoxicated  with  the  new  wine  of  science  and  regarded  nothing  as  too  difficult 
to  explain.  Once  the  principles  were  fully  understood,  as  in  certain  sciences  (e.g. 
medicine,  as  we  have  seen)  they  were  by  some  even  then  thought  to  be,  it  was  not 
strange  that  men  should  hope  to  perform  wonders  of  science  equal  to  the  most 
ambitious  miracles  of  magic. 

"•0.6. 

"•  It  is  certain  that  the  Socratic  teleology,  whether  suggested  by  Socrates* 
reyerence  for  fuun-uc/j  or  not,  came  to  the  rescue  of  divination  at  a  time  when  it  wss 
in  a  bad  way,  as  we  may  see  from  Thucydides.  The  identity  of  the  two  points  of 
view  is  apparent:  the  question  remains  whether  teleology  is  immanent  in  the  process 
of  nature  or  imposed  on  it  from  without.  In  a  way  fiwnuc/f  differs  from  Urropiii 
chiefly  in  this  that  the  latter  attempts  to  know  the  present  by  reconstructing  the 
past,  while  the  former  seeks  to  infer  the  future  from  the  present.  Hence  the  words 
of  Pindar,  Pyth,  9,  48  ff.  are  interesting :  K^^piw  t%  wdm-aw  r Aot  |  otcrOa  (Apollo)  koI 
rdaas  K€\€^0out  .  .  .  x^  ''*  MAXei,  x^^^  (ffacrai,  e5  KaBopft.  Knowledge  of  the 
endj  implies  teleology  :  8  rt  ^Xet  is  5  rt  l^ari  thrown  into  the  future,  and  6ir6$€v 
iffffCTfu  refers  to  the  jcAev^oi,  as  Gildersleeve  rightly  says.  Compare  the  praise  of 
(Anaxagorean  ?)  physical  philosophy  in  Eurip.  fr.  910  (the  text  of  Diels,  Vorsokr, 
299,  28)  Skpiot  8<ms  riji  Iffroplas  \  ((TX€  fidBrftrtP  \  /n-fp-t  woXitCjp  ivl  irrifioaiipriv  \  fn/fr* 
th  ddlKOvt  vpdids  hpiMPf  \  dXV  iBoMdrov  xaBopw  ^^€(os  \  xSafiw  iyfiptav,  ^J  tc 
avi>4ffrfj  I  x^^\v  X**""*-  WTuU  and  how  are  the  main  questions ;  the  latter 
includes  liie  story,  and  hence  the  beginnings.  Ck)mpare  Plato,  P?iaed,  97  0  e/  otv 
Tif  fioiffXoiTo  T^  alrlav  eifpeU  rcpl  iKdarov  Strg  ylyyrrai  1j  dirdWirrai  ^)  fffTi  with  96  A 
(rw€pii^a9Qt  ydp  fioi  iddxtt  (sc.  ^  <ro0/a,  i^  8ii  KoXowri  ftpL  ^^ews  lffToplav\  kuI 
€l94^tu  rdt  eUrlas  iKdarov,  8iit  rl  ylyprrai  fxaarw  koX  SUl  ri  dx^XXvrac  koX  dtd  tI  fffrt. 


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128  PROCEEDINGS   OF   THE   AMERICAN    ACADEMY. 

well  singling  ont  the  physical  cause  (rrjv  alrlav)  the  other  the  purpose 
(to  tcXos)  ;  for  the  former  was,  by  hjrpothesis,  inquiring  from  what  phy- 
sical conditions  it  sprung  and  how  it  came  about  in  the  course  of  nature 
(cic  TtVwv  ycyovc  koL  tto)?  ttc^vicc),  whereas  the  latter  was  predicting  to 
what  purpose  it  came  about  and  what  it  signified  "  (vfm  ri  yeyovc  koI  tI 

Democritus  is  reported  to  have  said  that  he  would  rather  make  one 
contribution  to  the  causal  explanation  of  things  than  be  made  King  of 
the  Persians. ^^*  Surely  this  does  not  mean  that  he  wanted  to  discover 
an  atom ;  he  was  in  search  of  the  causal  nexus  in  whatever  form,  and 
his  atoms  and  void  were  only  the  last  link  in  the  chain.  Men  knew 
what  it  meant  to  explain  :  tiiey  did  not  confuse  explanation  with  de- 
scription, although  they  might  content  themselves  with  the  latter,  in 
default  of  the  former.  This  was  often  the  attitude  of  the  physician, 
aware  of  his  ignorance  of  the  real  cause.  The  words  of  Thucydides 
about  the  great  plague  well  illustrate  this  point  "  As  to  its  probable 
origin,"  he  says,^®^  "or  the  caused  which  might  or  could  have  produced 
such  a  disturbance  of  nature,  every  man,  whether  a  ph3rsician  or  not, 
may  give  his  own  opinion.  But  I  shall  describe  its  actual  course,  and 
the  symptoms  by  which  any  one  who  knows  them  beforehand  may 
recognize  the  disorder  should  it  ever  reappear.'' 

It  would  be  easy  to  multiply  witnesses  proving  that  the  pre-Socratio 
philosophers  aimed  at  nothing  short  of  a  complete  understanding  of  the 
world  in  terms  of  its  physical  causes ;  but  enough  has  been  said.  There 
is,  however,  one  passage  in  Plato  to  which  reference  should  be  made. 
In  the  Pkaedo  i®®  Socrates  sets  forth,  as  only  Plato  could  do  it,  the 
difference  in  point  of  view  between  the  Socratic  and  the  pre-Socratic 
philosophies.  No  contrast  could  be  more  clearly  or  sharply  drawn  :  on 
the  one  hand  we  find  an  explanation  of  things  beginning  with  matter 
and  operating  with  mechanical  causes,  for  which  Socrates  declares  him- 
self by  nature  unfitted ;  on  the  other  stands  the  teleological  conception 
of  the  world  for  which  Socrates  is  sponsor.  Socrates  tells  how  eagerly 
he  took  up  the  book  of  Anaxagoras  in  the  hope  of  finding  a  real  antici- 
pation of  his  view,  but  only  to  meet  with  utter  disappointment.  Plato 
does  not  often  touch  directly  upon  the  earlier  philosophies,  but  here  he 
has  drawn  a  picture  of  their  aims  and  methods  which  leaves  nothing 
to  be  desired.     Perhaps  its  full  significance  is  hardly  realized. 

*••  Fr.  118. 

*•'  n.  48,  3,  transl.  Jowett.  In  Hippocrates,  especially  in  the  works  which  may 
be  classed  as  note-books,  explanation  commonly  yieKls  to  descriptloii  of  the  disease 
and  its  symptoms. 

w»  96  A  foU. 


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HEIDEL.  —  Ilipl  ^^mtn.  129 

It  may  be  assomed,  then,  that  in  the  conception  of  Nature  developed 
by  the  pie-Socratics  all  the  main* senses  of  the  term  tf)v<nq  were  com- 
bined; that  is  to  say,  Nature  meant  to  them  not  only  that  out  of 
which  things  grew  or  of  which,  in  the  last  analysis,  they  are  consti- 
tuted ;  this  was  one  of  its  meanings,  but  only  one,  and  that  not  the 
most  important  Certainly  it  would  not  be  true  to  say  even  of  the  loni- 
ans  that  they  restricted  themselves  to  the  question  as  to  the  primary 
substance  of  the  world.  Nature  (and  ^vo-t?)  meant  more  than  this  :  it 
included  the  law  or  process  of  growth  exemplified  in  all  things.  Aris- 
totle and  Theophrastus  suggest  that  Thales  was  led  to  the  assumption 
that  water  was  the  primary  substance  by  observations  connected  with 
evaporation  and  precipitation ;  be  that  as  it  may,  it  is  certain  that  his 
successor  Anaximander  was  more  interested  in  the  cosmic  process  of  seg- 
regation than  in  his  colorless  Infinite,  and  thenceforward  cosmic  pro- 
cesses and  laws  occupy  the  attention  of  philosophers  more  and  more. 
The  main  sense  of  Nature  was,  however,  the  sum  of  things  as  consti- 
tuted by  the  elements  and  the  cosmic  laws  and  processes.  This  it  was, 
the  Natura  Rerum,  to  the  understanding  of  wtuch  the  philosopher  im- 
mediately addressed  himself ;  and  it  was  in  this  sense  that  the  term  t^vcri? 
occurs  in  the  titular  phrase  Ilepl  t^vo-co)?.  Yet,  as  we  have  seen,  while 
the  inquiry  or  loroptiy  ircpl  <^ca)9  concerned  the  question  *  what  is  it ' 
(oTt  ^oTt),  the  answer  at  once  carried  the  inquirer  to  the  further  ques- 
tions 'of  what  is  it  constituted'  and  'how  did  it  come  about'  There 
is  nothing  startling  in  this  conclusion.  It  is  just  what  we  might  have 
expected,  knowing  the  operations  of  the  human  mind.  It  is,  however, 
not  without  a  certain  interest  that  we  thus  discover  the  ideals  of  pres- 
ent-day science  informing  and  impelling  the  fathers  of  all  science. 

Science,  however,  merely  formulates  in  the  hierarchy  of  its  ideals  the 
interests  of  the  plain  man  who  goes  about  his  daily  business  with  no 
particular  predilection  for  matters  theoretical  The  common  mind  is 
chiefly  concerned  with  results,  neither  asking  nor  greatly  caring  how 
they  were  obtained.  As  for  the  underlying  causes,  material  or  efficient, 
which  produced  the  results,  they  are  relatively  unimportant,  except  for 
the  purpose  of  attaining  the  same  object  either  actually  or  by  way  of 
ideal  construction  or  verification.  Thus  every  one  has  heard  of  the 
latest  invention,  say  the  aeroplane,  and  accepts  it  as  a  &ct  of  interest 
Many,  though  by  no  means  all,  know  the  names  of  the  inventors ;  the 
human  interest  in  personalities  of  distinction  contributes  not  a  little  to 
the  attitude  of  mind  which  fixes  attention  upon  the  author.  Even 
smaller  is  the  number  of  those  who  know  of  what  materials  the  machine 
is  constructed.  That  is  a  question  of  importance  chiefly  to  tiie  practical 
experimenter.    Fewest  of  all  are  those  who  concern  tiiemselves  about 

VOL.  XLV. — 9 


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130  PBOCEEDINQS  OF  THE  AMERICAN  ACADElfT. 

the  natural  laws  involyed  in  the  attempt  to  navigate  the  air,  of  which 
the  inventor  must  take  advantage  in  the  deft  adjustment  of  his  me- 
chanical contrivance  to  the  attainment  of  his  cherished  object  Many 
an  experimenter  even  will  be  found  to  be  lacking  in  a  Imowledge  of 
these  principles  which  absorb  the  attention  of  the  theorist  The  natural 
philosopher,  however,  will  devote  himself  to  tiie  determination  and  for- 
mulation of  the  laws  involved ;  from  his  point  of  view  the  inventor  is 
of  no  consequence,  and  in  his  calculations  the  materials  used  in  the 
contrivance  will  figure  as  a  plus  or  minus  quantity. 

It  remains  for  us  to  speak  briefly  of  Professor  Burnet's  dictum  ^** 
concerning  the  scope  of  the  early  Greek  researches  IIcpl  (^vo-ccof.  Since 
he  himself  holds  that  the  title  is  not  original  and  finds  it  first  men- 
tioned in  Euripides,^*^  it  is  fii.ir  to  judge  it  by  the  conceptions  of  the 
fifth  century.  But  we  may  reasonably  go  &rtlier  and  assert  that  the 
usage  of  the  fifth  and  fourth  centuries  b.o.  merely  reflects  the  ideals  of 
Greek  science  as  they  were  gradually  developed  from  the  beginning. 
In  the  Metaphysics  ^*^  Aristotle  says  :  '  It  is  owing  to  their  wonder 
that  men  both  now  begin  and  at  first  began  to  philosophize ;  they  won- 
dered originally  at  the  obvious  difficulties,  then  advanced  little  by  little 
and  stated  difficulties  about  the  greater  matters,  a  g.  about  the  phe- 
nomena of  the  moon  and  those  of  the  sun,  and  about  the  stars  and 
about  the  genesis  of  the  universe."  It  is  clear  that  the  "  obvious  diffi- 
culties,''  which  are  said  to  have  originally  excited  the  wonder  of  men, 
belong  rather  to  the  stages  of  preparation  for  technical  philosophy,  and 
that  philosophy  proper  begins  for  Aristotle  with  the  investigation  of  the 
phenomena  of  the  heavens  and  of  the  origin  of  the  universe.  Accord- 
ing to  Plato  *•*  also  it  was  the  observed  regularities  of  heavenly  phe- 
nomena that  begot  the  research  into  the  nature  of  the  universe.  They 
were  the  ^cid  /wtr  ewcellence,^^*  and  wonder  bom  of  the  observation  of 
them  was  supposed  to  have  produced  the  belief  in  the  existence  of 
gods.***  It  can  hardly  be  doubted  that  in  the  early  stages  of  philoso- 
phy the  researches  of  investigators  might  have  been  abnost  indifferently 
characterized  as  Trcpl  fiernofnav  or  ^cpl  ^vo-ccus  iaropirj.  Speaking  of  the 
distinction  and  elevation  in  oratory  conferred  upon  Pericles  by  his  &• 
miliarity  with  the  lofty  speculations  of  Anaxagoras,  Plato  says  **'  iroo-ot 

6<rai  /xeyoAai  ra>v  T€)(ytav  wpoaSiovrai  6So\€(r\w  kox  ficrcoipoXoyuis  <^v(r€cu9 

^•»  Quoted  above,  p.  80. 

"®  See  above,  n.  7. 

»^  Ma.  982^  12-17,  transl.  Ross. 

w«  Tim.  47  A.     Cp.  Epin,  990  A  and  JUpub.  680  A-681  A. 

»»»  Cp.  n.  182  above. 

^•*  By  Democritus,  cp.  Diels,  Vorsokr,  865,  22  (olL 

"»  Fhacdr.  209  B. 


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HEIDEL.  —  n^l  ^C<rm%.  131 

v€pi ;  and  even  AriBtotle  comprehended  in  the  term  /tcrcopoAoyia  his 
philosophy  of  nature  as  a  whole.  *••  His  Physics  is  rather  the  metaphy- 
sical consideration  of  the  principles  involved  in  the  explanation  of 
Nature.  In  the  Hippocratean  treatise  Utpl  aapKutv  occurs  an  instruc- 
tive passaga  "Concerning  ra  fieriwpa,"  we  read,^*^  " I  do  not  want 
to  speak  except  to  show,  in  regard  to  man  and  the  other  animals,  how 
they  came  about  in  the  course  of  nature,  and  what  the  soul  is,  what  is 
health  and  disease,  what  it  is  that  produces  health  and  disease  in  man, 
and  from  what  cause  he  dies."  The  author,  while  professing  to  speak 
ircpl  Twv  ii€r€^ptavy  proceeds  to  sketch  the  origin  of  things,  giving  in  fiu^t 
a  miniature  discourse  XIcpl  (^vo-eo)?  after  tiie  manner  of  the  philosophers, 
in  the  course  of  which  he  describes  the  segregation  of  the  cosmic  ele- 
ments and  tiien  turns  abruptly  to  tell  of  the  origin  of  the  various  parts 
of  the  human  organism.  Each  subject  is  introduced  with  the  laconic 
but  significant  phrase,  oiSc  iyci/cro.^** 

We  are  thus  brought  £bu^  to  &ce  with  the  second  sphere  of  interest 
included  in  the  researches  of  early  philosophy ;  for,  however  much  the 
cosmos  engaged  the  attention  of  the  investigator,  the  microcosm  soon, 
if  not  immediately,  made  good  its  claims.  We  have  repeatedly  re- 
marked upon  the  intimate  connexion  of  medicine,  so  £m*  as  it  con- 
cerned physiology,  witii  inquiries  Trepi  t^vcrccos.  We  need  not  now 
enlarge  upon  this  thema  It  is  sufficient  to  call  attention  to  the  fact 
that  it  was  recognized  by  Aristotle  ^•^  as  well  as  by  the  pre-Socratics. 

But  while  the  philosopher  may  have  devoted  tiie  greater  part  of  his 
attention  to  these  two  fields,  noUiing  lay  outside  the  sphere  of  his  in- 
terest Thus  it  is  not  improbable  that  the  study  of  mathematics  was 
associated  with  philosophy  from  the  beginning  and  included  in  the 
scope  of  Ucpt  ^v(rc(D9  UrropCrf.  Aristotle,  whose  empirical  method  of 
determining  what  does  and  what  does  not  belong  to  the  subject  matter 
of  the  several  sciences  is  well  known,  says  in  the  Metaphysics :  ^^^ 

^*  See  Gilbert,  Die  meteorol.  Theorien  des  grieehischen  AUertums,  p.  14. 

^•^  n.  (r<ipKii¥,  1  (8,  684  Littr^)  wepl  di  rwp  /ureibfxaif  oidi  (read  oiJ5^  !)  S4ofjLat 
X^ecy,  fjp  M^  TwrovToif  is  ApBponrop  dwodtl^  koI  rd  dXXa  ^{)a,  iieSaa  (read  ^jrwf  !) 
l0vKoU  iy4p€T0,  Kcd  5ti  rfn/x^  irriy,  Kal  6ti  rb  ^iafvew,  «al  dn  t6  Kdfwtw,  Kcd  6ti 
Td  ip  dM0piinr<if  xaKbp  xal  dyaBinf^  koX  6$(p  ixo6¥^K€i,  This  little  treatise  has  been 
unduly  neglected  and  deeenres  especial  attention  because  of  its  intimate  relation  to 
pre-Soeratic  philosophy.  Its  date  is  hard  to  determine.  Diels,  EUmenium,  p.  17, 
n.  2,  would  assign  it  to  the  first  half  of  the  fourth  century,  B.C. 

MS  Compare  Arist.,  De  Parti.  Animal,  641»7  oihtat  yip  koI  o2  ^wyio\6yoi  rAf  7eW- 
C€it  Koi  rdf  alrlat  tov  ffx^/iarof  \4yowrtM '  inrb  rlvtap  ydp  idrffuovpry^rfaay  dwdfuiop. 
Ibid,  647»9  foil. ;  [Arist]  Probl,  892»23  foil. 

^  Cp.  Arist.,  Ik  Langev,  464^33  ff. ;  De  FartL  Animal.  653*8  folL  ;  De  Sensu^ 
486»  17  foil.  ;  De  JUspir,,  480*22  foU. 

«^  1006»19  foil.,  tranal.  Ross. 


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132  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

"  We  must  state  whether  it  belongs  to  one  or  to  different  sciences  to 
inquire  into  the  truths  which  are  in  mathematics  called  axioms,  and 
into  substance.  Evidently  the  inquiry  into  these  also  belongs  to  one 
science,  and  that  the  science  of  the  philosopher  .  .  .  And  for  this  rea- 
son no  one  who  is  conducting  a  special  bquiry  tries  to  say  anjrthing 
about  their  truth  or  falsehood,  —  neither  the  geometer  nor  the  arithme- 
tician. Some  natural  philosophers  (<^t;(rifcoi)  indeed  have  done  so,  and 
their  procedure  teas  intelligible  enough  ;  for  they  thotight  that  they  alone 
were  inquiring  about  the  whole  of  nature  and  of  being  "  (ircpi  tc  t^  okrj^ 
^vo-ccDs  Kol  ir€pl  Tov  ovTos),  lu  llko  matmor  Plato*®*  refers  to  the 
•philosophers  as  those  "who  discourse  and  write  about  nature  and  the 

universe  "  (  oi  ircpl  ^vo-ccos  tc  koI  tov  oXov  SioXcyo/Acvoi  koX  ypd(f>ovT€si). 
Again  *•*  he  pictures  Hippias  enthroned  in  the  chair  of  philosophy  at 
the  home  of  Gallias  with  a  crowd  of  admiring  students  at  his  feet,  who 
"  appeared  to  be  plying  him  with  certain  astronomical  questions  about 
nature  and  the  phenomena  of  the  heavens  *'  (ci^Vovro  Sc  irepl  (^va-ea>9  re 

icai  ra>v  fieretapitsv  axTTpovofiuca  arra  Stcpoirav).  Here  fr€pl  <^v(rco>9  gives 
the  general  subject,  which  includes  ra  /Acreaipa,  and  this  in  turn  com- 
prehends darpovofUKa  aTTo.*®'  We  may,  therefore,  safely  say  that 
IIcpi  <^v(re(i)9  was  the  general  title  *®*  by  which  the  comprehensive  philo- 
sophical works  of  the  early  philosophers  were  called  because  they  were 
devoted  to  the  universal  Berum  NaturaJ^^^    For  this  reason  also  Titpi 

wi  Lysis,  214  B.  «w  Prolog.,  815  C. 

SOS  xhig  geenis  also  to  be  the  interpretation  put  upon  the  passage  by  Gilbert,  DU 
meieorol.  Theorien  des  griechischen  Allertums,  p.  3,  n.  8,  although  he  emphasizes  the 
(undoubted)  fact  that  in  many  cases  wepl  fji€Te(JI)p<inf  and  repl  0u<refa^  were  used  inter- 
changeably. 

*•♦  See  Gilbert,  0.  c,  p.  6,  n.  1 :  **Es  haben  deshalb  Anaximenes  und  Anaxi- 
mander,  Xenophanes  und  Parmenides,  Empedokles  und  Anaxagoras  jeder  in  einem 
Werke  die  Metaphysik,  Physik,  und  Meteorologie  gleichmassig  behandelt.  Auch  des 
Diogenes  von  ApoUonia  angefuhrte  Schriften  tieT€(apo\oyla  und  irepi  i^epibrw  4>^€U)s 
waren  wohl  nur  Teile  seines  Werkes  x.  0iJ<rewt.  Erst  Demokrit,  der  auch  hierin 
epocheroachend  erscheint,  hat  —  neben  der  Darstellung  seines  Gesamtsystems  —  in 
einer  Menge  von  Specialschriften  seine  Forschungen  niedergelegt."  Diels,  Vorsokr, 
p.  833,  is  of  the  same  opinion  regarding  the  titles  attributed  to  Diogenes.  It  was 
the  common  tradition  in  after  times  that  11.  ^t^ewf  was  the  general  title  ;  cp.  D.  L. 
IX.  5  (of  Heraclitus)  rh  6i  <f>€p6tuvw  airroO  /St/SXioy  itrrl  fih  dir6  rov  <rtWxo»^of  Hipi 
^6ff€<as,  Snjprfrai  Si  els  rpcU  Xiryovs,  eft  re  t6i'  repl  tov  irai^6»  Kcd  ToXirixby  iral  $eo\o- 
yiKbv,  Hippolytus,  Philos.  2  (Diels,  Dox.  555,  17)  says  of  Pythagoras  :  koL  oSrot  W 
xcpl  0v(riKc^  (—  xepi  0i5<rc«t)  ^^rnj<raf  (ni^ev  d<rrpwofdtiM  koX  yeotfieTpltuf  <cai  fiova'iK}pf 
Kal  dpt6fi.7rriKiiv.  Cp.  ibid.  1.  24 :  clra  ^TctiAy  .  .  .  ircpi  Aarpiap  Kal  tpi^eut  <f>i\oa<h 
tp-fyrwri,  rrX.  Philolaus,  fr.  6,  TcpH  <p{MTeiot  koI  ipfiovlas  tWe  ^x^**  To  the  Pythago- 
reans, we  are  told,  Urropla  meant  ytbtfierpla  ;  cp.  Kichomachus,  apnd  lamblichus, 
Fita  Pythag.  89. 

•w  It  is  therefore  not  surprising  to  find  in  Plato  uses  of  ^tkrtf  corresponding  to 


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HEIDEL.  —  n^\  ^^<rcc»f .  133 

^i^cci>9  laropia  was  set  in  sharp  contrast  ^^^  to  the  ethical  and  method- 
ological studies  of  Socrates  which  resulted  in  the  logic  and  metaphysics 
of  Plato  and  Aristotle. 

It  is  not  surprising  that  science,  sprung  from  the  bosom  of  religion, 
and  fostered  by  a  spirit  of  reverence  for  truth  in  an  age  when  the 
crumbling  ruins  of  ancient  beliefis  testified  to  a  loss  of  respect  for  the 
traditional  gods,  should  have  become  in  a  measure  itself  a  religion. 
Attention  was  called  above  to  the  fact  that  the  philosophical  system 
became  in  time  invested  with  sanctity  and  was  handed  down  as  a  icpos 
Xoyo5.  In  the  Greek  mysteries,  even  in  the  fifth  century,  and  possibly 
in  the  sixth,  cvourctia,  the  final  stage  of  initiation,  included  a  vision  of 
that  most  divine  spectacle,  the  stellar  universe.  In  Orphic  and  Py- 
thagorean conventicles  there  was  undoubtedly  some  consideration  of 
its  meaning,  though  one  cannot  say  how  much.  Much  nonsense  is 
reported  of  the  secrets  of  the  Pythagoreans,  but  it  probably  had  some 
basis  in  iajct  The  religion  of  the  time  tended  more  and  more  to  be- 
come a  matter  of  the  individual,  though  the  public  forms  were  ob- 
served. Science,  competing  with  religion  and  in  educated  circles  to  a 
considerable  extent  supplanting  it»  naturally  appropriated  its  forms. 
The  "  Law  "  of  Hippocrates  *®^  ends  thus  :  "  Things  holy  are  revealed 
to  holy  men  ;  to  the  pro&ne  it  is  forbidden,  before  they  are  initiated 
into  the  Mysteries  of  science."  We  are  familiar  with  the  beatitude 
pronounced  by  the  poets  upon  those  who  were  initiated  in  the  Myste- 
ries of  Eleusis,*®®  for  they  should  see  the  gods  and  dwell  with  them, 
released  from  the  distressing  cycle  of  birth  and  death.  Not  unlike  it  is 
the  inspired  utterance  of  Euripides  *o*  in  praise  of  the  philosopher  of 
nature  :  "  Blessed  is  he  who  hath  got  knowledge  of  science,  bent 
neither  on  harm  to  his  neighbors  nor  on  ways  of  injustice  ;  but,  con- 
templating the  ageless  order  of  undying  nature,  knoweth  what  it 
is  and  how.  To  such  men  there  never  cleaves  desire  for  deeds  of 
shame." 

Wesletan  University, 
MiDDLETOWN,  CoNN.,  July  10,  1909. 

the  Lucretian  phrases  in  rerum  natura  and  in  rebiia  ;  thus,  Phaedo  103  B  o<h-€  rb  iv 
ilfjuv  oih-e  t6  iv  ry  if>6(T€t,  and  Pai'vi.  132  D  rd  fih'  ctdrj  ravra  Cxrvcp  irapadelyfiATa 
iffrdyai  hf  t j  ^6ff€i. 

«of  Arist.,  Met.  987*1  foil.     Cp.  n.  7,  above. 

*^  Hippocrates,  4,  642  Littr^.     Cp.  also  the'O/xrot  (4,  628  foil.  Littr^).    . 

*••  Cp.  especially  Pindar,  fr.  114  (Bergk)  dX/3(oj  dcrru  Wwv  |  kHv  tla'  inrb  x^^*' 
oI5c  fikif  pLov  rcXevrdi',  |  oldev  5i  diSadorov  dpxdu. 

*••  Fr.  910.     The  text  is  quoted  above,  n.  185. 


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Proceedings  of  the  American  Academy  of  Arts  and  Sciences. 
Vol.  XLV.  No.  6.  — January,  1910. 


CONTRIBUTIONS  FROM  THE  CHEMICAL  LABORATORY  OF 
HARVARD  COLLEGE. 


A  REVISION  OF   THE  ATOMIC  WEIGHT  OF 
PHOSPHORUS. 

FIRST  FAPER.^THE  ANALYSIS  OF  SILVER  PHOSPHATE. 
Bt  Gregobt  Paul  Baxter  and  Grinnell  Jones. 


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CONTRIBUTIONS  FROM  THE  CHEMICAL  LABORATORY  OF 
HARVARD  COLLEGE. 

A  REVISION  OF  THE  ATOMIC  WEIGHT  OF  PHOSPHORUS. 

FIRST  PAPER.— THE  ANALYSIS  OF  SILVER  PHOSPHATE. 

Bt  Gregory  Paul  Baxter  and  Grinnell  Jones. 
Presented  September  28,  1009.    Received  November  12,  1909. 

Although  phosphorus  is  one  of  the  best  known  and  most  important 
elements,  present  knowledge  concerning  its  atomic  weight  is  somewhat 
inadequate.  The  early  determinations  of  this  constant  by  Dulong,^ 
Pelouze,^  Berzelius,^  and  Jacquelain  *  are  widely  discrepant  and  have 
no  particular  significance.  Those  by  Schrotter,  Dumas,  van  der  Platts, 
and  Berthelot,  on  the  other  hand,  all  give  values  not  far  from  31.0,  and 
this  value  has  been  selected  by  the  International  Committee  on  Atomic 
Weights.  Although  these  investigations  have  already  been  critically 
discussed  by  Clarke,^  Brauner,^  and  others,  a  few  of  the  more  important 
sources  of  error  are  briefly  pointed  out  here. 

Schrotter,^  the  discoverer  of  red  phosphorus,  converted  weighed 
quantities  of  this  substance  into  phosphorus  pentoxide  by  combustion 
in  a  stream  of  oxygen.  As  the  mean  of  ten  determinations  which 
varied  from  30.94  to  31.06,  he  obtained  31.03  for  the  atomic  weight  of 
phosphorus.  The  oxygen  used  was  slightly  moist,  as  Brauner  has 
pointed  out,  since,  although  it  was  dried  by  phosphorus  pentoxide,  it 
was  finally  passed  through  a  tube  containing  calcium  chloride !  •  The 
phosphorus  pentoxide  formed  during  the  combustion  must  have  re- 
tained this  small  amount  of  water,  which  would  make  the  atomic 
weight  of  phosphorus  appear  too  low.  Schrotter  admits  that  the  com- 
bustion was  incomplete,  and  since  this  error  would  tend  to  raise  the 
atomic  weight  of  phosphorus,  he  concludes  that  the  true  value  is 
31.00. 

»  Ann.  Chim.  Phys.  1816,  2,  149.  «  C.  R.,  1845,  20,  1053. 

»  Lehrbuch,  5th  Ed.,  1845,  3,  1188.  *  C.  R.,  1851,  33,  693. 

•  A  Recalculation  of  the  Atomic  Weights,  Smith.  Misc.  Coll.,  1897. 

•  Abegp.  Handb.  der  anorg.  Chem.,  1907,  vol.  3,  part  3,  p.  366. 
T  Ann.  Chim.  Phys.,  (3).  1853.  38,  131. 


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138  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

Damas®  titrated  the  trichloride  of  phosphorus  against  silver  after 
decompoHing  the  trichloride  with  water.  Since  the  sample  used  did 
not  boil  at  constant  temperature,  but  distilled  between  76°  and  78^,  it 
must  have  been  impure.  K  it  contained  oxychloride,  as  Clarke  has 
suggested,  the  atomic  weight  of  phosphorus  would  be  found  too  high. 
Dumas  overlooked  the  solubility  of  silver  chloride  and  therefore  used 
the  wrong  end-point  in  these  titrations.  Furthermore  no  precautions 
are  mentioned  either  for  preventing  access  of  water  to  the  material 
before  weighing  or  for  preventing  the  reduction  of  the  silver  salt  by 
the  phosphorous  acid  formed  in  the  decomposition  of  the  trichloride 
with  water.  Recalculated  on  the  basis  of  the  atomic  weight  of  silver 
as  107.88,  his  five  analyses  give  results  which  vary  between  30.99  and 
31.08.    The  average  is  31.03. 

Van  der  Platts  ®  made  two  determinations  by  each  of  three  different 
methods.  He  obtained  the  values  30.90  and  30.97  by  the  precipitation 
of  silver  firom  silver  sulphate  solution  with  phosphorus.  His  results 
fi'om  the  analysis  of  silver  phosphate  were  31.08  and  30.95.  He  gives 
no  details  of  the  method  of  preparing  and  analyzing  this  substance, 
merely  making  the  statement^  "  It  \a  difficult  to  be  sure  of  the  purity 
of  this  salt"  Finally,  by  the  combustion  of  yellow  phosphorus  in 
oxygen  he  obtained  the  results  30.99  and  30.96.  The  very  meagre 
descriptions  of  these  experiments  preclude  criticism. 

Using  Leduc's  data  for  the  densities  and  compressibilities  of  phos- 
phine  and  oxygen,  Daniel  Berthelot  ^^  has  calculated,  by  the  method  of 
limiting  densities,  the  molecular  weight  of  phosphine  to  be  34.00  and 
the  atomic  weight  of  phosphorus  to  be  30.98. 

Very  recently  Gazarian  ^^  has  obtained  a  considerably  lower  value  for 
the  molecular  weight  of  phosphine,  33.93.  This  value  was  calculated 
from  the  experimentally  determined  weight  of  the  standard  liter  by  the 
four  methods  of  molecular  volumes  (Leduc),  limiting  densities  (Berthe- 
lot), critical  constants  (Guyo),  and  "indirect"  limiting  densities 
(Berthelot).  The  different  methods  give  essentially  identical  results, 
except  in  the  case  of  the  direct  method  of  limiting  densities.  By  the 
latter  method  a  value  six-hundredths  of  a  unit  higher  is  obtained,  but 
Gazarian  rejects  the  result  on  the  basis  of  inaccurate  knowledge  of  the 
compressibility  of  phosphine.  It  is  highly  desirable  to  obtain  more 
certain   knowledge  of   the  compressibility  of  phosphine,   since  the 


»  Ann.  Chem.  Pharm.,  1860, 113,  28. 

•  C.  R.,  1885, 100,  52. 
^«  C.  R.,  1898,  126.  1415. 
"  Jour,  de  Chim.  Phys.,  1909,  7,  337. 


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BAXTER    AND   JONES.  —  ATOMIC   WEIGHT   OF   PHOSPHORUS.      139 

method  of  limiting  densities  is  the  most  reliable  of  all  the  methods  for 

appljdng  the  correction  to  the  densities  made  necessary  by  deviations 

from  the  laws  of  a  perfect  gas. 

The  other  methods  are  bnrdened  with  arbitrary  assumptions  and 

empirical  constants,  and  furthermore  Baume^'  has  shown  that  both 

the  method  of  molecular  volumes  and  the  method  of  critical  constants 

T 
give  correct  results  only  with  gases  for  which  the  ratio  j^  is  nearly  1, 

whereas  for  phosphinQ  this  ratio  is  1.26.  V 

If  the  molecular  weight  of  phosphine  be  ^sumed  to  be  33.93,  the 
atomic  weight  of  phosphorus  is  30.91.  In  the  light  of  this  low  result 
it  is  unfortunate  that  Gazarian  prepared  phosphine  by  only  one 
method,  and  that  he  did  not  determine  the  purity  of  the  gas,  i.  e.  by 
absorption.  Gazarian  used  the  method  of  Matignon  and  Trannoy  ^^ 
which  consists  in  heating  calcium  phosphate  and  aluminum  together 
until  they  react,  and  then  treating  the  product  of  this  reaction  without 
Airther  purification  with  water  in  a  gas  generator.  Matignon  and 
Trannoy  show  that  the  gas  prepared  in  this  way  by  them  contained 
about  three  per  cent  of  hydrogen,  probably  derived  from  calcium  con- 
tained by  the  phosphide.  In  this  case  some  calcium  nitride  would  be 
formed,  since  the  phosphide  was  made  in  air ;  and  this  would  produce 
ammonia  as  an  impurity  in  the  phosphine.  Although  the  gas  was 
purified  by  firactional  distillation,  according  to  Gazarian's  statements 
hydrogen  is  diflScult  to  eliminate,  and  a  proportion  of  only  four-tenths 
of  one  per  cent  would  be  sufficient  to  lower  the  atomic  weight  of  phos- 
phorus one-tenth  of  a  unit  Ammonia  would  be  even  more  difficult  to 
remove,  since  its  boiling  point  is  only  50°  higher  than  that  of  phos- 
phine. The  effect  of  a  given  percentage  of  impurity  is,  however,  much 
less  with  ammonia  than  with  hydrogen,  although  in  the  same  direction. 

From  the  preceding  brief  summary  it  is  evident  that  the  uncertainty 
in  the  atomic  weight  of  phosphorus  is  as  great  as  one  tenth  of  a  unit, 
and  that^  as  Brauner  remarks  at  the  conclusion  of  his  review  of  the 
subject^  "a  revision  of  the  atomic  weight  of  phosphorus  with  modem 
means  is  urgently  necessary." 

The  analysis  of  silver  phosphate  was  selected  as  one  of  the  most 
promising  methods  of  attacking  the  problem,  since  the  percent  of  silver 
can  be  determined  exactly  by  a  method  which  has  been  carefully 
studied,  especially  in  this  laboratory.  The  accuracy  of  the  result  will 
therefore  depend  primarily  upon  the  success  attained  in  preparing 

"  Baume,  J.  Chim.  Phys.  1908,  6,  76  and  86. 
"  C.  R.,  1909,  148,  167. 


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140  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

silver  phosphate  in  a  perfectly  definite  and  pure  state.  The  greater 
part  of  the  following  research  was  devoted  to  the  solution  of  this  prob- 
lem which  van  der  Platts  found  so  difficult 

The  analysis  of  the  halogen  compounds  of  phosphorus  ofiers  certain 
difficulties  owing  to  the  ease  with  which  these  substances  are  decom- 
posed by  water,  and  to  the  necessity  for  oxydizing  the  phosphorous  acid 
resulting  from  the  decomposition  of  the  halogen  compounds  with  water 
before  the  addition  of  silver  nitrate.  An  investigation  upon  the  tri- 
bromide  of  phosphorus  is  now  in  progress  in  this  laboratory.  Phospho- 
nium  compounds  were  found  utterly  unsuited  for  exact  analysis  on 
account  of  their  instability. 

Purification  of  Materials. 

Water,  All  the  water  used  in  this  research  was  made  firom  the 
laboratory  supply  of  distilled  water  by  distillation,  first  firom  an  alka- 
line permanganate  solution,  and  then,  after  the  addition  of  a  trace  of 
sulphuric  acid,  through  a  block  tin  condenser. 

Ammonia.  The  best  commercial  ammonia  was  distilled  into  the 
purest  water. 

Nitric  Acid,  The  best  commercial  concentrated  acid  was  twice 
firactionally  distilled  through  a  platinum  condenser,  with  the  rejection 
of  the  first  third  of  the  distillate.  Every  sample  was  shown  to  be  firee 
firom  chloride  by  careful  nephelometric  tests. 

Hydrochloric  Acid.  The  best  commercial  C.  P.  acid,  diluted  with  an 
equal  volume  of  water,  was  distilled  through  a  platinum  condenser. 

Ili/drobromic  Acid,  This  substance  was  prepared  in  conjunction 
with  Mr.  F.  B.  Coffin,  who  was  engaged  in  a  parallel  research  upon  the 
atomic  weight  of  arsenic^*  Commercial  bromine  was  converted  into 
potassium  bromide  by  addition  to  recrystallized  potassium  oxalata 
In  a  concentrated  solution  of  this  bromide,  in  a  distilling  flask  cooled 
with  ice,  bromine  was  dissolved,  and  distilled  ft*om  the  solution  into  a 
flask  cooled  with  ice.  A  portion  of  the  purified  bromine  was  then  con- 
verted into  potassium  bromide  with  pure  potassium  oxalate  as  before, 
and  the  remainder  of  the  bromine  was  distilled  firom  solution  in  this 
pure  potassium  bromide.  The  product  obtained  was  thus  twice  dis- 
tilled from  a  bromide,  the  bromide  in  the  second  distillation  being 
essentially  free  from  chlorine.  This  treatment  has  already  been  proved 
sufficient  to  free  bromine  from  chlorine.^^ 

"  Baxter  and  Coffin,  These  Proceedings,  1909,  44,  179. 
"  Baxter,  These  Proceedings,  1906,  42,  201. 


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BAXTER  AND   JONES.  —  ATOMIC  WEIGHT   OF  PHOSPHORUS.      141 

Hydrobromic  acid  was  sjmthesized  from  the  pure  bromine  by  bub- 
bling hydrogen  gas  (made  by  the  action  of  water  on  "  hydrone " ) 
through  the  bromine  warmed  to  40''-44°  and  passing  the  mixed  gases 
over  hot  platinized  asbestos  in  a  glass  tube.  The  apparatus  was  con- 
structed wholly  of  glass.  The  hydrogen  was  cleansed  by  being  passed 
through  two  wash  bottles  containing  dilute  sulphuric  acid,  and  through 
a  tower  filled  with  beads  also  moistened  with  dilute  sulphuric  acid. 
The  hydrobromic  acid  gas  was  absorbed  in  pure  water  contained  in  a 
cooled  flask.  In  order  to  remove  iodine  the  solution  of  hydrobromic 
acid  was  diluted  with  water  and  twice  boiled  with  a  small  quantity  of 
free  bromine.  Then  a  small  quantity  of  recrystallized  potassium  per- 
manganate was  added  to  the  hydrobromic  acid  solution,  and  the  bro- 
mine set  free  was  expelled  by  boiling.  Finally  the  acid  was  distilled 
with  the  use  of  a  quartz  condenser,  the  first  third  being  rejected.  It 
was  preserved  in  a  bottle  of  Nonsol  glass  provided  with  a  ground- 
glass  stopper. 

The  purity  of  the  hydrobromic  acid  was  tested  by  a  quantitative 
synthesis  of  silver  bromide.  The  silver  used,  which  was  kindly  fur- 
nished by  Mr.  G.  S.  Tilley,  had  been  prepared  with  all  the  necessary 
precautions  for  work  on  the  atomic  weights  of  silver  and  iodine.^® 
The  procedure  used  by  Baxter  ^^  for  the  synthesis  of  silver  bromide 
from  a  weighed  amount  of  silver  was  followed  in  detail.  In  this  experi- 
ment 6.02386  grams  of  silver  jdelded  10.48627  grams  of  silver  bromide ; 
hence,  silver  bromide  contains  57.4452  per  cent  of  silver,  while  Baxter 
found  as  the  mean  of  18  determinations  57.4453  per  cent  The  hydro- 
bromic acid  was  evidently  pure. 

Silver  Nitrate.  Crude  silver  nitrate  was  reduced  with  ammonium 
formate,  made  by  passing  ammonia  gas  into  redistilled  formic  acid. 
The  reduced  silver  was  washed  with  the  purest  water,  until  the  wash 
waters  no  longer  gave  a  test  for  ammonia  with  Nessler's  reagent,  and 
was  fused  on  sugar  charcoal.  The  buttons  were  then  scrubbed  with 
sea-sand  and  thoroughly  cleansed  with  ammonia  and  nitric  acid. 
They  were  then  dissolved  in  redistilled  nitric  acid,  in  a  platinum  dish. 
After  the  silver  nitrate  solution  had  been  evaporated  on  a  steam  bath 
until  saturated,  an  equal  volume  of  redistilled  nitric  acid  was  added 
and  the  solution  was  cooled.  The  precipitated  silver  nitrate  was  very 
completely  drained  in  a  centrifugal  machine,  provided  with  platinum 
Goocfa  crucibles  to  retain  the  salt.^®    A  similar  recrystallization  fol- 


"  Baxter  and  Tilley,  Jour.  Amer.  Chem.  Soc.,  1909.  31,  201. 

^T  Baxter,  These  Proceedings,  1906,  42,  208. 

"  Baxter,  Jour.  Amer.  Chem.  Soc.,  1908,  30,  286. 


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142  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

lowed.  The  final  product  was  preserved  in  Jena  glass  vessels  under  a 
bell-jar. 

Disodium  Phosphate.  One  kilogram  of  Merck's  best  disodium  phos- 
phate was  dissolved  in  hot  water  in  a  porcelain  dish  and  hydrogen 
sulphide  passed  into  the  solution  for  several  hours.  After  standing 
for  twenty-four  hours,  the  solution  was  again  heated,  saturated  with 
hydrogen  sulphide  and  filtered.  The  filtrate  was  slightly  green,  owing 
to  the  presence  of  iron.  The  solution  was  boiled  to  exx>el  the  hydro- 
gen sulphide  and  a  small  amount  of  green  precipitate  filtered  out 
The  filtrate  was  still  distinctly  green.  The  sodium  phosphate  was 
then  crystallized  fifteen  times,  five  times  in  porcelain  with  centrifugal 
drainage  of  the  crystals  in  a  large  porcelain  centrifugal  machine,  ten 
times  in  platinum  vessels  with  centrifugal  drainage  of  the  crystals  in 
platinum  Gooch  crucibles.  The  green  color  concentrated  in  the  first 
mother  liquor. 

When  tested  by  means  of  the  Marsh  test,  this  material  was  found  to 
contain  only  a  mere  trace  of  arsenic,  which  was  estimated  to  be  0.01 
mg.  in  ten  grams  of  the  salt.  This  small  amount  could  have  no  effect 
on  the  analytical  results,  especially  since  the  percentage  of  silver  in 
silver  arsenate  is  nearly  the  same  as  in  silver  phosphate.  By  means  of 
the  nephelometer  it  was  proved  that  this  material  contained  no  chlo- 
ride or  other  substances  which  could  be  precipitated  by  silver  nitrate 
in  the  presence  of  dilute  nitric  acid. 

Sodium  Ammonium  Hydrogen  Phosphate.  The  best  commercial 
microcosmic  salt  was  recrystallized  four  times  in  platinum  vessels.  It 
was  tested  for  arsenic  by  Marsh's  method  with  negative  results  and 
gave  no  opalescence  visible  in  the  nephelometer  when  tested  with  silver 
nitrate  and  dilute  nitric  acid. 

Preparation  of  Trisilver  Phosphate. 

Silver  phosphate  was  prepared  by  mixing  dilute  solutions  of  silver 
nitrate  with  solutions  of  sodium  and  ammonium  phosphates.  Since  it 
is  not  feasible  to  purify  silver  phosphate  by  recrystallization,  the  con- 
ditions of  precipitation  must  be  so  chosen  that  a  pure  product  will  be 
obtained  at  once. 

In  order  to  avoid  inclusion  and  occlusion  of  silver  nitrate,  sodium 
nitrate,  sodium  phosphate,  or  mono-  or  disilver  phosphate,  all  of  the 
solutions  for  precipitation  were  made  about  0.03  N.  All  samples  after 
precipitation  were  thoroughly  washed  and  allowed  to  stand  in  water  for 
at  least  twenty-four  hours,  in  order  to  convert  occluded  acid  phos- 
phates into  trisilver  phosphate.      Qualitative  tests  for  nitrate  with 


J 


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diphenylamine  and  for  sodium  by  the  spectroscope  showed  that  all  of 
the  first  three  substances  named  could  be  completely  washed  out 

Joly^^  states  that  disilver  phosphate  is  stable  in  the  presence  of 
phosphoric  acid  containing  40  per  cent  (11.8  N)  of  phosphoric  anhy- 
dride, but  is  transformed  into  trisilver  phosphate  if  the  acid  contains 
38  per  cent  (1 1.0  N)  or  less  of  phosphoric  anhydride.  Since  all  the  solu- 
tions used  for  the  preparation  of  silver  phosphate  were  nearly  neutral, 
it  is  evident  that  the  precipitation  of  disilver  phosphate  as  a  distinct 
phase  in  equilibrium  with  the  solution  is  not  to  be  feared. 

It  is,  however,  not  such  a  simple  matter  to  prove  the  absence  of 
occluded  disilver  hydrogen  phosphate  or  monosilver  hydrogen  phos- 
phate. Much  light  is  thrown  on  this  point  in  a  recent  paper  by 
Abbott  and  Bray  20  upon  the  dissociation  constants  of  the  three  hydro- 
gens of  phosphoric  acid,  which  were  found  to  be  1.1  X  10"*,  1.95  X  10"^ 
and  3.6  X  10""  respectively.  Since  the  phosphate  ion  (P04=)  is  ahnost 
completely  hydrolyzed  to  lie  monohydrophosphate  ion  (HP04=),  even 
in  slightly  alkaline  solutions,  and  since  in  slightly  acid  solutions  the 
dihydrophosphate  ion  (HaPOr)  acquires  an  appreciable  concentration, 
the  possibility  of  occlusion  must  be  examined  with  especial  care. 

The  concentrations  in  the  following  table  are  either  taken  directly 
from  a  table  given  by  Abbott  and  Bray  or  calculated  from  these  num- 
bers with  the  help  of  the  values  of  the  dissociation  constants  of  phos- 
phoric acid.  The  values  are  expressed  in  formular  weights  per  liter, 
the  total  concentration  of  the  salt  being  in  each  case  0.05. 


NaNH«HP04 

Na,NH«P04 

H,POr 

0.00118421 

0.00000222 

HP04= 

0.03265  21 

0.03219  21 

PO«H 

0.0000016  22 

0.00112321 

OH- 

0.0000007921 

0.000502  21 

H+ 

0.000000007522 

0.000000000012 

It  will  be  noted  that  the  replacement  of  the  remaining  hydrogen  in 
sodium  ammonium  hydrogen  phosphate  by  sodium  decreases  the  concen- 

w  C.  R.,  1886, 103,  1071. 
«•  Jour.  Amer.  Chem.  Soc.,  1909,  31,  755. 

**  These  values  are  taken  directly  from  the  table  of  Abbott  and  Bray. 
•*  These  values  are  calculated  from  the  others  in  the  above  table  by  the 
aid  of  the  following  equations: 

(H+)(OH-)  -  0.59  X  10-»* 
(HPOr)     -  3  6  X  10-«  -  1.95  X  10-7 


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144  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

tration  of  the  hydrogen  ion  to  0. 16  percent  of  its  value  in  the  microcosmic 
salt  solution  and  decreases  the  conoenta:ation  of  the  dihydrophosphate 
ion  to  0.2  percent  of  its  former  value.  The  concentration  of  the  mono- 
hydrophosphate  ion  remains  essentially  unchanged,  while  the  concen- 
tration of  the  phosphate  ion  is  increased  seven  hundred  times. 
Bisodium  phosphate  doubtless  takes  a  position  intermediate  between 
the  other  two  solutions  in  this  regard,  since  it  is  more  alkaline  than 
microcosmic  salt  and  less  so  than  disodium  ammonium  phosphate. 
The  numbers  given  above  refer  to  solutions  which  are  five  times  as 
strong  as  those  used  in  this  research,  but  the  conditions  in  the  more 
dilute  solutions  must  be  very  similar.  Furthermore,  the  exact  values 
have  no  great  importance,  as  die  concentrations  of  the  various  ions  change 
continuously  during  precipitation.  It  is  evident  from  the  figures  given 
above  and  from  the  value  of  the  dissociation  constant  of  the  second 
hydrogen  of  phosphoric  acid  that  if  the  concentration  of  hydrogen  ion 
increases  above  its  value  in  a  microcosmic  salt  solution,  the  concentra- 
tion of  the  dihydrophosphate  ion  must  increase  greatly  at  the  expense 
of  the  monohydrophosphate  ion.  If  there  is  any  tendency  for  the 
occlusion  of  disilver  hydrogen  phosphate  or  monosilver  hydrogen  phos- 
phate, the  amounts  of  these  salts  occluded  would  be  expected  to  depend 
on  the  concentration  of  the  undissociated  molecules  of  these  salts  in 
the  solution,  and  therefore  on  the  concentration  of  the  silver  ion  and 
on  the  concentration  of  the  monohydrophosphate  or  dihydrophosphate 
ion  respectively. 

The  exact  concentrations  of  the  ions  during  the  precipitation  cannot 
be  calculated,  since  the  solubility  of  silver  phosphate  in  slightly  acid 
solutions  and  the  solubility-product  of  silver  phosphate  are  not  known. 
It  is,  however,  easy  to  understand  from  a  study  of  the  conditions  under 
which  the  various  samples  of  silver  phosphate  were  precipitated,  that 
these  concentrations  must  have  varied  greatly  in  the  preparation  of  the 
different  samples  and  therefore  constancy  of  composition  gives  a  strong 
presumption  that  there  is  very  little  or  no  tendency  for  the  occlusion 
of  the  undesired  acid  salts. 

Samples  N  and  0.  A  0.03  normal  solution  of  silver  nitrate  was 
slowly  poured  into  a  0.03  normal  solution  of  disodium  hydrogen  phos- 
phate with  frequent  shaking.  This  reaction  may  be  roughly  consid- 
ered to  take  place  in  two  stages  represented  by  the  equations 

3  AgNOs  +  2  Na^HPO*  =  AgjPO*  +  NaHjPO*  +  3  NaNO, 
3  AgNOs  +    NaH,P04  =  AgsPO*  +  NaNO,  +  HNO, 

At  the  beginning  of  the  precipitation  the  solution  is  very  slightly 
alkaline  and  remains  very  nearly  neutral  during  the  addition  of  the 


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BAXTER   AND   JONES.  —  ATOMIC  WEIGHT  OF   PHOSPHORUS.       145 

first  half  of  the  silver  nitrate.  The  concentration  of  the  silver  ion  is 
kept  very  low  by  the  excess  of  phosphate  and,  therefore,  little  occlu- 
sion of  the  acid  salts  is  to  be  expected  in  spite  of  the  tajct  that  the 
solution  contains  appreciable  concentrations  of  the  monohydrophos- 
phate  and  dihydrophosphate  ions.  The  precipitate  during  this  stage 
is  very  finely  divided  and  does  not  settle  well  and,  therefore,  no 
attempt  was  made  to  collect  it  separately. 

During  the  addition  of  the  second  half  of  the  silver  nitrate  the 
solution  becomes  slightly  acid  and  the  solubility  of  the  silver  phos- 
phate increases  rapidly.  The  precipitate  settles  readily.  During  the 
second  stage  the  conditions  are  more  fiivorable  for  the  occlusion  of 
the  acid  phosphate,  but  only  a  small  amount  of  silver  phosphate  is 
precipitated  during  this  staga 

After  standing  a  short  time  the  mother  liquor  was  decanted  firom 
the  precipitate,  and  exactly  the  calculated  amount  of  redistilled 
ammonia,  diluted  to  one  liter,  was  added  to  neutralize  the  excess 
of  acid  and  complete  the  precipitation.  Since  this  sample  was  evi- 
dently produced  from  a  solution  which  was  slightly  acid  at  the  be- 
ginning of  the  precipitation,  although  very  nearly  neutral  at  the  end, 
and  since  it  contained  a  considerable  amount  of  silver,  the  conditions 
were  fiekvorable  for  the  formation  of  acid  salts. 

Both  precipitates  were  transferred  to  a  large  platinum  dish  and 
washed  many  times  by  decantation  with  the  purest  water.  This 
washing  was  prolonged  over  more  than  twenty-four  hours  in  order 
to  give  time  for  all  soluble  matter  to  be  leached  out.  When  the 
precipitates  were  tested  for  nitrate  with  diphenylamine,  negative 
results  were  obtained.  Sodium  was  found  to  be  absent  by  spectro- 
scopic tests.  The  precipitates  were  drained  as  far  as  possible  in  a 
platinum  centrifugal  machine,  and  the  drying  was  completed  by  heat- 
ing in  platinum  crucibles  in  an  electric  air  bath  for  several  hours,  first 
at  90°  and  finally  at  about  130°.  The  dried  lumps  of  silver  phosphate 
were  then  gently  ground  in  an  agate  mortar.  The  samples  were  pre- 
served in  platinum  crucibles  over  sulphuric  acid  in  the  dark.  All  of 
the  operations  were  performed  in  a  dark  room. 

The  sample  prepared  by  pouring  silver  nitrate  into  disodium  phos- 
phate is  designated  Sample  N,  and  the  sample  prepared  by  adding 
ammonia  to  the  mother  liquors  is  designated  Sample  0. 

Samph  P.    A  0.03  normal  solution  of  disodium  ammonium  phos- 
phate was  prepared  by  dissolving  a  weighed  amount  of  disodium  hy- ' 
drogen  phosphate  and  then  adding  the  calculated  amount  of  redistilled 
ammonia.    The  solution  was  then  slowly  poured  into  a  0.03  normal 
solution  of  silver  nita:ate.     By  this  method  of  precipitation  the  solu- 

VOL.  XLV. — 10 


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146  PBOCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

tion  is  maintained  as  nearly  neatral  as  is  possible,  because  the  excess 
of  silver  prevents  the  concentration  of  phosphate  in  solution  from 
exceeding  a  very  small  value,  so  that  neither  can  the  solution  become 
alkaline  by  hydrolysis  nor  can  the  concentration  of  hydrophosphate 
attain  an  appreciable  value.  The  absence  of  the  hydrophosphate 
ions  would  be  expected  to  prevent  the  formation  and  occlusion  of 
acid  silver  phosphate  in  this  sample,  whereas  in  Sample  N  the  same 
result  is  probably  brought  about  by  the  absence  of  the  silver  ion. 
Unfortunately  both  of  these  £sivorable  conditions  cannot  be  combined 
in  one  precipitation,  as  will  be  shown  later.  This  precipitate  settled 
readily.  The  washing,  testing,  and  drying  were  carried  out  as  al- 
ready described  for  Samples  N  and  0.  This  sample  is  designated 
Sample  P. 

Sample  R,  A  0.03  normal  solution  of  sodium  ammonium  hydrogen 
phosphate  was  slowly  poured  into  a  similar  solution  of  an  equivalent 
amount  of  silver  nitrate.  Under  these  conditions  the  solution  con- 
tains an  excess  of  silver,  which  tends  to  produce  occlusion  of  acid 
phosphates,  since  the  solution  becomes  more  and  more  acid  as  the  pre- 
cipitation proceeds,  and  as  the  precipitation  is  therefore  £a.r  from 
complete,  the  concentrations  of  the  two  hydrophosphate  ions  gradually 
approach  a  very  considerable  value.  At  no  stage  could  the  solution 
become  alkaline  by  hydrolysis.  It  should  be  noticed  that  the  pro- 
cedure differs  from  that  used  in  preparing  Sample  N  in  that  the 
precipitate  is  formed  in  the  presence  of  an  excess  of  silver  nitrate 
instead  of  an  excess  of  phosphate,  and  that  this  difference  in  the 
method  of  mixing  greatly  changes  the  conditions  of  precipitation. 

The  precipitate,  which  was  designated  Sample  R,  coagulated  and 
settled  quite  readily.  The  washing  and  drying  were  completed  as 
usual 

It  will  be  shown  that  samples  of  silver  phosphate  prepared  under 
these  various  conditions  have  nearly,  if  not  exactly,  the  same  composi- 
tion. Further  proof  of  the  absence  of  acid  phosphate  in  these  samples 
is  given  by  experiments  to  be  described  later  which  show  that  no 
water  is  given  off  when  this  material  is  fi^d. 

An  attempt  to  prepare  a  sample  by  pounng  silver  nitrate  into  di- 
sodium  ammonium  phosphate  3delded  unsatis&ctory  results.  Since 
the  disodium  ammonium  phosphate  solution  was  fidkaline,  owing  to 
hydrolysis,  it  contained  free  ammonia,  which  prevented  the  precipita- 
tion of  silver  phosphate  at  first  Nearly  one-quarter  of  the  silver 
nitrate  was  added  before  a  permanent  precipitate  was  produced.  At 
the  end  of  the  precipitation  the  solution  was  of  course  essentially 
neutral    Even  after  standing  for  four  days  the  precipitate  bad  not 


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BAXTER  AND   JONES.  —  ATOMIC   WEIGHT   OF   PHOSPHORUS.       147 

appreciably  settled.  Since  the  coagulation  of  the  precipitate  seems 
to  occur  much  more  readily  in  the  presence  of  excess  of  silver,  a 
considerable  amount  of  silver  nitrate  in  solution  was  added.  The 
precipitate  coagulated  and  settled  immediately.  It  was  washed  and 
dried  as  usual  This  sample  was  somewhat  darker  in  color  than  the 
other  samples  and  gave  a  large  amount  of  insoluble  residue  when 
treated  with  dilute  nitric  acid.  The  analysis  showed  that  it  contained 
about  two  hundredths  per  cent  too  much  silver.  This  method  of 
preparation  is  evidently  unsatisfiaictory. 

Three  unsuccessful  attempts  were  made  to  prepare  silver  phosphate 
from  trisodium  phosphate.  The  samples  obtained  in  this  way  did  not 
appear  homogeneous  after  being  dried  and  contained  considerable 
sodium  in  spite  of  protracted  washing.  Two  of  these  samples  were 
found  by  analysis  to  contain,  respectively,  4.4  and  4.1  per  cent  less 
silver  than  pure  trisilver  phosphate.  The  third  of  these  samples 
was  so  unsatisfactory  in  appearance  and  in  its  behavior  during  its 
preparation  that  it  was  not  analyzed.  This  method  of  preparing 
silver  phosphate  is  evidently  not  suitable  for  our  purpose.  Time  was 
lacking  to  investigate  further  this  anomalous  behavior. 

Method  of  Analysis. 

Unfortunately,  owing  to  the  high  melting  point  of  silver  phosphate, 
it  was  not  feasible  to  fuse  the  silver  phosphate  before  its  analysis  in 
order  completely  to  eliminate  all  water.  Instead  it  was  heated  in  a 
platinum  boat,  in  a  current  of  pure  dry  air,  at  a  temperature  of  about 
400°  for  seven  hours,  and  then  by  means  of  bottling  apparatus  ^  it 
was  inclosed  in  its  weighing  bottle  without  coming  in  contact  with  the 
moist  air  of  the  laboratory.  During  this  heating  the  access  of  light  to 
the  sample  was  prevented.  The  continuous  current  of  air  which  passed 
over  the  silver  phosphate  during  the  heating  was  driven  by  a  water 
pump  successively  through  an  Emmerling  tower  containing  beads 
moistened  with  silver  nitrate  solution,  through  a  tower  containing 
small  pieces  of  fused  caustic  potash,  then  through  three  towers  con- 
taining beads  drenched  with  concentrated  sulphuric  acid,  and  finally 
through  a  long  tube  containing  phosphorus  pentoxide  which  had  been 
resublimed  in  a  current  of  air.  The  hard  glass  tube  containing  the 
platinum  boat  was  surrounded  by  blocks  of  aluminum  ^  which  were 
jacketed  with  asbestos  on  the  top  and  sides  and  heated  directly  from 

«*  Richards  and  Parker,  These  Proceedings,  1896,  32,  59. 
**  Baxter  and  Coffin,  These  Proceedings,  1909,  44,  184. 


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14S  PROCEEDINGS  OF  THE  AilERICAN  ACADEMY. 

below  by  a  large  burner.  The  platinum  boat  was  not  attacked  in  the 
least,  as  was  shown  by  the  fact  that  its  weight  remained  constant 

It  was  feared  that  in  spite  of  this  prolonged  heating  the  silver 
phosphate  still  retained  a  trace  of  water,  but  by  making  the  conditions 
in  the  different  experiments  as  nearly  uniform  as  possible  it  was  hoped 
that  the  amount  of  water  retained  would  be  constant  Proof  will  be 
given  later  that  the  drying  was  highly  efficient 

The  salt  thus  prepared  for  analysis  was  allowed  to  stand  over  night 
in  a  desiccator  covered  with  a  black  cloth  in  the  balance  room,  and 
was  then  weighed  in  its  glass-stoppered  bottle  by  substitution,  with  the 
use  of  another  weighing  bottle  of  very  similar  surface  and  volume  as  a 
counterpoise. 

The  balance  was  a  nearly  new  No.  10  Troemner  balance.  It  was 
easily  sensitive  to  0.02  mg.  The  weights  had  already  been  used 
in  an  investigation  of  the  atomic  weight  of  sulphur, ^^  and  were  re- 
standardized  with  a  very  gratifying  result  None  of  the  corrections 
found  differed  by  as  much  as  0.02  mg.  from  those  found  a  year  before, 
and  only  a  few  by  0.01  mg.  The  balance  was  provided  with  a  few 
milligrams  of  radium  bromide  of  radioactivity  10000  to  dispel  electri- 
cal charges  generated  during  the  handling  of  the  weighing  bottles 
with  cork-tipped  pincers. 

The  platinum  boat  containing  the  silver  phosphate  was  transferred 
to  an  Erlenmeyer  flask  of  "  non-sol "  glass  of  one  liter  capacity  and 
treated  with  about  30  cubic  centimeters  of  5  normal  nitric  acid. 
Solution  took  place  rapidly.  The  solution  was  not  perfectly  clear, 
however,  owing  to  a  very  slight  insoluble  residue  which  sometimes 
settled  out  on  standing.  The  solution  was  then  heated  on  a  steam 
bath  until  the  residue  dissolved  completely.  Upon  the  addition  of 
about  one  liter  of  cold  water  a  very  slight  opalescence  was  produced, 
which  was  visible  only  when  the  solution  was  carefully  examined  in  a 
very  fisivorable  light.  The  solution  was  again  warmed  until  it  became 
perfectly  clear.  The  water  and  nitric  acid  used  in  these  processes  did 
not  give  an  opalescence  visible  in  the  nephelometer  when  treated 
with  silver  nitrate.  The  nature  of  this  residue  will  be  discussed  more 
in  detail  after  describing  the  remainder  of  the  analytical  process. 

About  eight  hundred  cubic  centimeters  of  water  was  placed  in  a 
large  glass-stoppered  precipitating  flask  and  a  very  slight  excess  of 
hydrobromic  acid  was  added  from  a  burette.  The  silver  phosphate  solu- 
tion was  then  very  carefully  poured  into  the  hydrobromic  acid  solution. 
This  method  of  precipitation  gives  less  opportunity  for  the  occlusion 

»  Richards  and  Jones,  Pub.  Car.  Inst.,  1907,  No.  69,  69. 


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BAXTER   AND   JONES.  —  ATOMIC    WEIGHT   OF    PHOSPHORUS.       149 

of  silver  phosphate  or  nitrate  than  the  reverse  method.  The  occlusion 
of  hydrobromic  acid  can  do  no  harm.  The  flask  was  shaken  for  twenty 
minutes  and  was  allowed  to  stand  for  several  days  until  the  precipitate 
had  completely  settled.  Then  the  precipitate  was  collected  upon  a 
weighed  (jooch  crucible  after  many  rinsings  with  pure  water.  In  order 
to  protect  the  mat  of  the  Gooch  crucible  from  disintegration,  it  was 
covered  by  a  circular  disk  of  thin  platinum  foil,  perforated  with  many 
small  holes.  The  precipitate  was  dried  in  an  electrically  heated  air 
bath  for  several  hours  at  90°,  then  for  some  time  at  130°,  and  finally 
for  at  least  eight  hours  at  180°.  After  the  crucible  containing  the 
precipitate  had  been  weighed,  the  silver  bromide  was  transferred 
to  a  porcelain  crucible  and  the  loss  on  fusion  determined.  The 
presence  of  the  platinum  disk  covering  the  mat  makes  it  possible 
to  transfer  very  nearly  all  the  silver  bromide  to  the  porcelain  crucible 
without  contamination  with  asbestos  and  therefore  it  is  unnecessary  to 
correct  the  loss  on  fusion  for  the  small  amount  of  silver  bromide  which 
is  not  fused.  The  loss  on  fusion,  which  represents  water  remaining 
in  the  silver  bromide,  was  subtracted  from  the  weight  of  the  silver 
bromide.  The  asbestos  shreds  carried  away  by  the  wash  waters  and 
any  silver  bromide  which  may  have  escaped  the  Gooch  crucible  were 
collected  by  passing  the  filtrate  through  a  very  small  filter  paper. 
The  paper  was  then  burned  and  the  residue,  after  treatment  with  a 
drcp  of  nitric  and  hydrobromic  acids  to  convert  any  reduced  silver 
into  silver  bromide,  was  again  gently  heated  and  finally  was  weighed. 
The  weight  of  the  asbestos,  corrected  for  the  ash  of  the  paper,  was 
added  to  the  weight  of  the  silver  bromide.  In  order  to  determine  the 
soluble  silver  bromide,  the  filtrate  was  evaporated  until  most  of  the 
excess  of  nitric  acid  was  driven  off.  The  precipitating  flask  and  all 
the  flasks  which  had  held  the  filtrate  were  rinsed  with  strong  ammonia 
and  the  rinsings  added  to  the  evaporated  wash  water.  Enough 
ammonia  was  added  to  make  the  solution  alkaline  and  it  was  then 
diluted  to  one  hundred  cubic  centimeters  in  a  graduated  flask.  The 
amount  of  silver  bromide  present  was  determined  by  comparison  in 
the  nephelometer  with  a  very  similar  solution  containing  a  known 
amount  of  silver  bromide.  Both  precipitates  were  dissolved  in  ammo- 
nia and  reprecipitated  at  the  same  time  and  under  precisely  similar 
conditions  ^6  in  the  nephelometer  tubes  by  a  slight  excess  of  nitric 
acid.  The  amount  found  in  this  way  was  added  to  the  weight  of  the 
silver  bromide. 

In  order  to  determine  whether  silver  phosphate  is  occluded  by  silver 

*•  See  Richards  and  Staehler,  Pub.  Carnegie  Institute,  No.  76,  p.  20. 


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150  PROCEEDINGS  OF  THE  A2tfERICAN  ACADEMT. 

chloride,  about  six  grams  of  silver  phosphate  were  dissolved  in  nitric 
acid  and  the  solution  was  diluted  and  poured  into  an  excess  of  hydro- 
chloric acid.  After  standing  until  the  supernatant  liquid  was  clear, 
the  precipitate  was  washed  very  thoroughly  with  water  and  then  dis- 
solved in  redistilled  ammonia.  The  solution  wa^  diluted  to  one  liter 
and  the  silver  chloride  was  reprecipitated  with  nitric  acid.  The 
precipitate  was  filtered  out  and  the  filtrate  evaporated  in  a  platinum 
dish  until  concentrated.  A  little  sodium  carbonate  was  added  and 
the  dish  was  heated  to  expel  all  volatile  ammonium  salts.  The  residue 
was  dissolved  in  about  three  cubic  centimeters  of  water  and  treated 
with  an  excess  of  ammonium  molybdate  reagent  with  gentle  warming. 
After  standing  for  three  days,  not  the  slightest  precipitate  or  yellow 
color  had  appeared,  showing  that  no  phosphate  had  been  occluded  by 
the  silver  chloride.  Although  not  tested  experimentally,  it  is  reason- 
able to  suppose  that  silver  bromide  also  does  not  possess  the  property 
of  occluding  appreciable  quantities  of  silver  phosphate  or  phosphoric 
acid. 

Insoluble  EEsmuE. 

The  presence  of  a  slight  residue  or  opalescence,  after  dissolving  the 
dried  silver  phosphate  in  dilute  nitric  acid,  proved  the  most  perplexing 
difficulty  which  was  encountered.  The  eflfort  to  discover  the  nature 
of  this  insoluble  matter  and  eliminate  it  consumed  a  large  part  of  the 
time  devoted  to  this  research.  In  an  effort  to  make  sure  that  it  was 
not  due  to  some  unknown  impurity,  nineteen  different  samples  of 
silver  phosphate  were  prepared,  the  source  of  material,  method  of 
purification,  and  precipitation  being  varied.  Disodium  phosphate, 
trisodium  phosphate,  and  sodium  ammonium  phosphate  were  carefuUy 
purified  and  converted  into  silver  phosphate  under  varying  conditions 
without  appreciable  effect  upon  the  Amount  of  the  residue.  Phospho- 
rus oxychloride  was  twice  firactionally  distilled,  converted  into  phos- 
phoric acid,  and  then  into  disodium  phosphate  by  means  of  sodium 
hydroxide  made  fix>m  sodium  amalgam.  The  product  was  crystallized 
three  times.  Silver  phosphate  made  fix>m  this  material  gave  a  slight 
residue,  very  similar  to  that  obtained  from  the  best  samples  made  in 
other  ways..  Unfortunately,  it  was  necessary  to  reject  the  analjrtical 
results  obtained  with  this  specimen  because  it  was  found  to  contain  a 
small  amount  of  metaphosphate.  We  did  not  succeed  in  preparing 
a  sample  of  silver  phosphate  entirely  free  from  the  residue. 

In  the  meantime  attention  bad  been  devoted  to  the  residue  itself. 
The  small  amount  of  material  available  rendered  this  part  of  the  inves- 


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BAXTER   AND   JONES.  —  ATOMIC    TTEIGHT    OF   PHOSPHORUS.       151 

tigation  diffioult.  The  silver  phosphate,  after  its  precipitation  and 
washing,  bat  andried,  dissolves  in  dilute  nitric  acid,  giving  a  solution 
which  is  perfectly  clear  to  the  naked  eye,  although  some  samples  gave 
a  barely  visible  opalescence  in  the  nephelometer.  The  opalescence 
was  much  too  small  to  have  any  effect  on  the  analytical  results.  The 
dried  samples  invariably  gave  an  opalescence. 

Dry  silver  phosphate  is  very  slowly  darkened  in  color  by  the  action 
of  light.  This  effect  is  even  more  pronounced  when  silver  phosphate 
is  exposed  to  the  light  in  thQ  presence  of  water.  These  darkened  sam- 
ples gave  a  much  greater  residue  than  tJie  undarkened  material  The 
residue  was  insoluble  in  ammonia,  slowly  soluble  in  dilute  nitric  acid, 
especially  when  heated,  and  readily  soluble  in  strong  nitric  acid.  The 
addition  of  hydrochloric  acid  to  these  nitric  acid  solutions  gave  a  pre- 
cipitate of  sUver  chloride,  while  ammonium  molybdate  indicated  the 
presence  of  phosphate. 

In  order  to  determine  whether  or  not  a  loss  of  weight  occurs  during 
ihe  darkening  by  lights  a  sample  of  silver  phosphate  was  dried  and 
weighed  as  usual  and  found  to  weigh  3.01901  grams.  It  was  then 
exposed  to  the  direct  action  of  bright  sunlight  for  a  day,  while  con- 
tained in  a  weighing  bottle  which  was  placed  in  a  desiccator  over  sul- 
phuric acid.  It  was  found  to  have  darkened  slightly  in  color  and  to 
weigh  3.01903.  The  gain  of  0*02  milligram  is  within  the  limit  of  error 
in  the  weighing.  This  sample,  when  treated  with  dilute  nitric  acid, 
gave  a  much  larger  residue  than  usual,  which  weighed  1.8  milligrams. 
This  is  much  more  residue  than  was  usually  found  in  samples  contain- 
ing from  four  to  eight  grams  of  silver  phosphate.  It  is  estimated  that 
the  samples  which  had  been  protected  from  the  action  of  light  as 
much  as  possible,  except  when  unavoidably  exposed  to  diffused  day- 
light while  being  weighed  or  transferred  to  the  furnace  and  solution 
flask,  contained  about  one  one-hundredth  of  a  per  cent  of  this  residue. 

Two  analyses  were  made  of  the  residue  obtained  by  exposing  silver 
phosphate  under  water  to  the  action  of  light  for  several  days,  then 
dissolving  the  excess  of  silver  phosphate  in  dilute  nitric  acid  and  thor- 
oughly washing  and  drying  the  residue.  0.02674  gram  of  this  residue 
yielded  0.03551  gram  of  silver  chloride,  which  indicates  that  the  res- 
idue contained  99.9  per  cent  of  silver.  In  the  case  of  another  sample 
of  the  residue  prepared  and  analyzed  in  the  same  way,  0.04320  gram 
of  residue  pelded  0.05747  gram  of  silver  chloride,  which  indicates  that 
the  residue  contained  100.1  per  cent  of  silver.  The  mean  of  the  two 
analyses  is  100.0  per  cent  of  silver.  These  analyses  prove  conclusively 
that  when  silver  phosphate  is  acted  on  by  light  in  the  presence  of 
water,  it  is  so  altered  (perhaps  by  the  formation  of  a  subphosphate 


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152  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

similar  to  subchloride),  that  when  treated  with  very  dilate  nitric  acid 
metallic  silver  remains. 

It  does  not  follow,  however,  that  it  would  be  a  correct  procedure  to 
determine  the  per  cent  of  this  residue  obtained  from  the  samples  used 
for  analysis  and  apply  a  correction  on  the  assumption  that  the  material 
consisted  of  pure  silver  phosphate  and  a  small  amount  of  pure  silver. 
This  procedure  would  assume  that  the  other  product  of  decomposition 
is  eliminated  and  not  weighed.  There  are  two  facts  which  show  that 
this  assumption  would  be  incorrect  In  nearly  every  analysis,  when 
the  solution  was  diluted,  after  bringing  the  residue  into  solution  by 
heating  on  the  steam  bath,  a  slight  opalescence  was  produced.  Care- 
ful tests  of  the  water  used  showed  that  this  opalescence  was  not  due 
to  impurity  in  the  water.  It  seems  probable  that  the  substance  which 
caused  this  opalescence  was  derived  in  part  from  the  phosphate  radical 
during  the  decomposition  which  produced  the  residue.  The  other  fact 
is  that  dry  silver  phosphate  does  not  lose  weight  when  darkened  by 
exposure  to  sunlight^  although  this  treatment  increases  the  amount  of 
residue.  The  conclusion  in  regard  to  this  residue  may  be  summarized 
as  follows  :  The  washed  moist  silver  phosphate  was  free  from  residue 
and  contained  silver  and  phosphoric  acid  combined  in  atomic  propor- 
tions. During  the  drying  and  weighing  a  slight  decomposition  took 
place,  undoubtedly  owing  in  part  at  least  to  the  action  of  light  It 
seems  probable  that  during  this  decomposition  no  loss  in  weight  took 
place,  and  therefore  the  sample  contained  the  proper  percentage*  of 
silver.  When  this  slightly  darkened  silver  phosphate  is  treated  with 
cold  dilute  nitric  acid,  the  unchanged  silver  phosphate  and  perhaps 
also  a  portion  of  the  altered  material  dissolve,  leaving  a  slight  opales- 
cence, which  in  some  cases  is  deposited  as  a  very  slight  residue  on 
standing.  This  residue  is  estimated  to  be  about  0.01  per  cent  of  the 
weight  of  the  silver  phosphate.  When  the  solution  is  warmed  until 
perfectly  clear,  and  then  diluted,  a  very  slight  opalescence  is  usually 
produced  which  could  be  again  cleared  up  by  warming  the  solution. 
This  opalescence  is  probably  caused  by  the  presence  of  the  altered 
phosphate  anion.  If  this  explanation  is  correct,  the  presence  of  the 
residue  cannot  influence  the  result^  and  no  correction  need  be  applied. 
Until  the  exact  nature  of  the  decomposition  products  can  be  deter- 
mined, there  must  remain  some  uncertainty  in  regard  to  whether  or 
not  any  correction  is  necessary. 

The  uncertainty  from  this  cause  is,  however,  not  very  great  Even 
if  all  the  phosphorus  and  oxygen  corresponding  to  the  residue  of  silver 
is  removed  before  the  weighing,  the  correction  would  be  only  twenty- 
three  per  cent  of  the  weight  of  the  residue.    If  the  residue  amounts  to 


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BAXTER   AND   JONES.  —  ATOMIC  WEIGHT    OF    PHOSPHORUS.       153 

0.01  per  cent,  as  has  been  estimated,  the  maximum  correction  would 
be  0.002  per  cent.  If  part  of  the  oxygen  is  lost,  but  the  phosphorus 
remains,  the  correction  would  of  course  be  smaller.  If  there  is  no  loss 
in  weight  by  the  action  of  light  on  the  dry  silver  phosphate,  no  correc- 
tion need  be  applied.  From  the  evidence  so  far  obtained  the  latter 
assumption  seems  rather  more  probable  than  any  of  the  others,  and 
therefore  no  correction  has  been  applied. 

Thb  Determination  of  Water  in  the  Dried  Silver  Phosphate. 

In  order  to  find  out  how  efficient  the  drjdng  of  the  silver  phosphate 
had  been,  experiments  were  made  to  determine  the  amount  of  water 
retained  by  silver  phosphate  which  had  been  dried  for  analysis  as 
described  above.  (See  page  147.)  The  water  was  determined  by 
fusing  the  dried  phosphate  in  a  current  of  dry  air  and  collecting  the 
moisture  set  free  in  a  weighed  phosphorus  pentoxide  tube.  Since  the 
melting  point  of  pure  silver  phosphate  is  considerably  above  the  soft-, 
ening  point  of  hard  glass,  it  was  found  advantageous  to  lower  the 
melting  point  of  the  phosphate  by  the  use  of  silver  chloride  as  a  flux. 

About  fifteen  grams  of  silver  phosphate  were  placed  in  one  end  of  a 
large  silver  boat  and  in  the  other  end  about  twelve  grams  of  previously 
fused  silver  chloride.  The  boat  was  then  inserted  in  a  hard  glass  tube 
and  dried  under  the  same  conditions  as  prevailed  in  preparing  the 
samples  for  the  determination  of  the  silver  content  After  the  silver 
phosphate  had  been  heated  for  seven  hours  in  a  current  of  purified  air 
dried  by  phosphorus  pentoxide,  the  air  passing  over  the  boat  in  the 
furnace  was  conducted  through  a  weighed  U-tube  containing  resub- 
limed  phosphorus  pentoxide  for  one  half  hour.  This  was  done  to  make 
sure  that  all  the  water  which  had  been  liberated  from  the  silver  phos- 
phate without  fusion  had  been  swept  out  of  the  apparatus.  In  no  case 
was  there  a  gain  in  weight  during  this  process  of  more  than  0.05  mg., 
which  is  about  the  limit  of  error  in  weighing  the  phosphorus  pentoxide 
tubes.  The  backward  diffusion  of  moisture  was  prevented  by  a  second 
tube  containing  pentoxide. 

The  carefully  weighed  phosphorus  pentoxide  tube  was  again  attached 
to  the  tube  containing  the  silver  boat  with  its  charge  of  silver  phosphate 
and  silver  chloride.  The  latter  tube  was  then  heated  hot  enough  to 
fuse  the  silver  chloride,  which  flowed  down  to  the  silver  phosphate  and 
readily  caused  the  entire  charge  to  fuse  completely.  The  liberated 
water  was  swept  into  the  phosphorus  pentoxide  tube  by  a  current  of 
dry  air  for  about  thirty  minutes.  The  tube  was  then  reweighed  to 
determine  the  water  evolved  by  the  fusion  of  silver  phosphate.  The 
pentoxide  tube  was  weighed  by  substitution  for  a  very  similar  counter- 


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154 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


poise  tube,  one  stop-cock  of  each  tube  being  open  during  the  weighing. 
Before  being  weighed  both  tubes  were  wiped  with  a  damp  cloth  and 
allowed  to  stand  near  the  balance  for  at  least  thirty  minutes. 
The  following  table  gives  the  results  of  these  experiments  : 


Sample. 

Weight  of  Sil- 
ver Phosphate. 

Weight  of 
Water. 

Per  Cent 
of  Water. 

P 

13.50 

0.00012 

0.0009 

P 

15.64 

0.00007 

0.0004 

0 

15.66 

0.00005 

0.0003 

0 

16.62 

0.00003      . 

0.0002 

Average    .    .    .    . 

.    0.0005 

The  amount  of  water  evolved  is  hardly  greater  than  the  probable 
error  in  weighing  the  phosphorus  pentoxide  tubes,  and  is  less  than  the 
probable  error  in  determining  the  amount  of  silver  in  the  salt  We 
are  therefore  justified  in  concluding  that  the  material  which  was  used 
for  the  determination  of  silver  was  essentially  free  from  water  and  that 
no  correction  need  be  applied  to  the  results  for  ineflScient  dr3ring. 

This  result  also  furnishes  evidence  that  the  samples  are  free  from 
acid  phosphates,  which,  owing  to  conversion  into  pyro-  or  metaphos- 
phate,  would  evolve  water  when  ftised,  although  it  is  possible  that 
occluded  acid  phosphates  might  have  been  converted  into  pyro-  or 
metaphosphates  during  the  drying.  Sample  0,  which  was  prepared 
under  conditions  most  favorable  for  the  formation  of  the  acid  silver 
phosphate,  does  not  appear  to  contain  more  water  than  Sample  P, 
which  was  prepared  under  conditions  which  were  unfavorable  to  the 
formation  of  acid  phosphate.  Since  these  two  samples,  which  differed 
most  widely  in  their  method  of  preparation,  showed  no  difference  in 
the  amount  of  water  retained,  it  seemed  unnecessary  to  test  the  other 
samples  also.  Unfortunately  this  method  of  detecting  acid  phosphate 
is  not  very  sensitive,  owing  to  the  unfavorable  relation  of  the  atomic 
weights  involved,  —  one  molecule  of  water  corresponding  to  a  deficiency 
of  two  atoms  of  silver. 


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baxter  and  jones.  —  atomic  weight  of  phosphorus.     155 

The  Specific  Gravity  of  Silver  Phosphate. 

In  order  that  the  apparent  weight  of  the  silver  phosphate  might  he 
corrected  to  the  vacuum  standard,  the  specific  gravity  of  this  salt  was 
found  by  determining  the  weight  of  toluol  displaced  by  a  known  quan- 
tity of  salt  The  specific  gravity  of  the  toluol  at  25°  referred  to  water 
at  4°  was  0.8633.  Great  care  was  taken  to  remove  air  from  the  salt 
when  covered  with  the  toluol  by  warming  the  pycnometer,  then  placing 
it  in  a  vacuum  desiccator  and  boiling  the  toluol  under  reduced  pres- 
sure. The  salt  and  toluol  were  mechanically  stirred  to  assist  the 
escape  of  air  bubbles.    This  process  was  repeated  several  times. 


Weight  of 

Silver  Phosphate 

in  Vacuum. 

Weight  of 

Displaced  Toluol 

in  Vacuum. 

Volume  of 
Silver  Phosphate. 

Density  of 
Silver  Phosphate. 

grains 
22.955 

16.942 

grams. 
3.113 

2.295 

c.c. 
3.606 

2.658 

25V  4<>. 
6.366 

6.374 

Mean 6.37 

Therefore  the  apparent  weight  of  silver  phosphate  was  corrected  to  the 
vacuum  standard  by  adding  0.000044  gram  per  gram  of  salt  Similarly 
^.000041  gram  was  added  for  every  gram  of  silver  bromide. 

The  Adsorption  of  Air  by  Silver  Phosphate. 

Since  the  silver  phosphate  was  in  a  very  finely  divided  condition 
and  since  many  fine  powders  have  the  power  of  adsorbing  appreciable 
quantities  of  air  or  other  gases,  the  possibility  of  the  adsorption  of  air 
by  silver  phosphate  was  investigated.  The  method  of  experimenting 
and  the  apparatus  were  very  similar  to  that  used  by  Baxter  and  Tilley 
for  investigating  the  behavior  of  iodine  pentoxide. 

"  Two  weighing  bottles  were  constructed  with  long,  very  well  ground 
stoppers  which  terminated  in  stop-cocks  through  which  the  tubes  could 
be  exhausted.  These  tubes  were  very  closely  of  the  same  weight  and 
very  nearly  the  same  internal  capacity.  The  tubes  were  first  exhausted 
and  compared  in  weight  by  substitution.  Next  they  were  filled  with 
dry  air  and  again  weighed,  the  weighing  being  carried  out  with  stop- 
cocks open.  Both  steps  were  then  repeated  with  essentially  the  same 
results."  27 

^  Baxter  and  Tilley,  Jour.  Amer.  Chem.  Soc.,  1909,  31,  214. 


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156  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

In  these  two  experiments,  when  air  was  admitted,  the  counterpoise 
gained  0.00028  and  0.00021  gram  respectively  (average  0.00025)  more 
than  the  tube  which  was  later  to  contain  the  silver  phosphate.  After 
22.69  grams  of  pure  dry  silver  phosphate  had  been  placed  in  the  tube, 
the  tube  and  its  counterpoise  were  exhausted  and  the  difference  in 
weight  determined.  When  dry  air  at  25°  C.  and  766  mm.  was  admitted 
to  both  the  tube  containing  the  silver  phosphate  and  the  counterpoise, 
the  counterpoise  gained  0.00443  gram  more  than  the  tube.  Therefore 
the  air  displaced  by  the  silver  phosphate  was  0.00443  —  0.00025  = 
0.00418  gram.  Since  22.69  grams  of  silver  phosphate  of  density  6.37 
have  a  volume  of  3.56  cc,  the  volume  of  pure  air  displaced  at  25°  C. 
and  766  mm.  should  weigh  0.00425  gram.28 

The  experiment  was  then  repeated.  After  the  air  had  been  ex- 
hausted from  the  tube  and  its  counterpoise,  the  tube  containing  the 
silver  phosphate  was  heated  gently.  No  gas  was  evolved.  The  tube 
and  its  counterpoise  were  then  weighed  by  substitution.  When  dry 
air  at  24.5°  and  767  mm.  was  admitted  to  both,  the  counterpoise 
gained  0.00445  grams  more  than  the  tube  containing  the  silver  phos- 
phate*  Therefore  the  air  displaced  by  the  silver  phosphate  was 
0.00445  —  0.00025  =  0.00420  grams,  whereas  the  weight  of  air  dis- 
placed, calculated  from  the  density  of  the  salt,  is  0.00426  gram. 

The  agreement  between  the  experimental  results  and  those  calcu- 
lated from  the  density  of  silver  phosphate  on  the  assumption  that  no 
adsorption  takes  place  is  close  enough  to  show  that  no  significant 
amount  of  adsorption  occurs. 

Discussion  of  the  Results. 

The  following  table  contains  all  of  the  analyses  not  vitiated  by  a 
known  impurity  in  the  sample  or  by  an  accident  during  the  analysis. 
One  feature  of  this  table  requires  further  explanation.  In  Analysis  5 
the  silver  was  determined  by  precipitation  as  chloride  instead  of 
bromide.  For  every  gram  of  silver  phosphate  there  was  obtained 
1.02707  grams  of  silver  chloride.  Since  Baxter  found  AgBr  :  Ag  Cl  = 
1.31017  :  1.00000,2®  this  analysis  indicates  that  one  gram  of  sample  N 
is  equivalent  to  1.02704  X  1.31017  =  1.34560  grams  of  silver  bromide. 
This  result  is  placed  in  the  table  for  comparison  with  the  other  analyses 
and  is  used  in  the  computation  of  the  mean. 

*•  Rayleigh's  value  for  the  density  of  air  at  0*^  and  760  mm.,  1.293  grams 
per  liter,  is  used.     Proc.  Roy.  Soc.,  63,  147. 
"  These  Proceedings,  1906,  42,  213. 


Digitized  by 


Goot 


BAXTER   AND   JONES.  —  ATOMIC  WEIGHT    OF    PHOSPHORUS.       157 


Series  I. 
3AgBr:  AgjPO* 


Number     1 

of 
Analysis.    1 

M 

Weight 
Vacuum. 

A^Br 

m 

Vacuum. 

Weight 
Asbestos. 

Loss 

on 

Fusion. 

Dissolved 
AgBr. 

Corrected 
Weight 

AgBr. 

Ratio 
SAgBr 
AgsPO«' 

1 

0 

grams 
6.20166 

grams 
8.34427 

gram 
0.00036 

gram 
0.00034 

gram 
0.00007 

grams 
8.34490 

1.34558 

2 

0 

6.35722 

8.55386 

0.00041 

0.00003 

0.00011 

8.55419 

1.34559 

3 

N 

5.80244 

7.80792 

0.00029 

0.00005 

0.00007 

7.80819 

1.34567 

4 

N 

5.05845 

6.80658 

0.00019 

0.00020 

0.00012 

6.80685 

1.34564 

5 

N 

3.34498 

(AgCI) 
3.43514 

0.00029 

0.00009 

0.00008 

(AgCl) 
3.43544 

1.34560 

6 

P 

7.15386 

9.62648 

0.00046 

0.00013 

0.00013 

9.62694 

1.34570 

7 

P 

7.20085 

9.68929 

0.00023 

0.00005 

0.00010 

9.68947 

1.34560 

8 

R 

6.20182 

8.34466 

0.00041 

0.00027 

0.00012 

8.34522 

1.34561 

9 

R 

5.20683 

7.00543 

6.00029 

0.00040 

0.00007 

7.00605 

1.34555 

Average 1.34562 

Per  cent  of  Ag  in  AggPO*    ....  77.300 

A  carefbl  study  of  these  results  shows  that  the  composition  of  silver 
phosphate  is  very  nearly,  if  not  quite,  independent  of  the  changes  in 
the  acidity  of  the  solutions  from  which  it  is  precipitated.  Samples  0 
and  R  were  prepared  under  slightly  more  acid  conditions  than  Sam- 
ples N  and  P.  The  average  amount  of  silver  bromide  obtained  from 
one  gram  of  Samples  0  and  R  is  1.34558  (77.297  per  cent  of  silver), 
whereas  the  average  from  Samples  N  and  P  is  1.34564  (77.301  per 
cent  of  silver).  This  difiference,  if  real  and  significant,  is  probably  due 
to  a  very  slight  occlusion  of  disilver  hydrogen  phosphate.  It  does  not 
seem  probable  that  any  basic  salt  was  present  in  Samples  N  and  P, 
because  silver  shows  little  tendency  to  form  basic  salts  and  the  condi- 
tions of  precipitation  were  not  &vorable  for  the  formation  of  basic 
salts. 

The  difference  between  composition  of  the  samples  is  so  slight,  both 
in  absolute  amount  and  by  comparison  with  the  differences  between 


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158  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

different  analyses  of  the  same  sample,  that  in  the  present  state  of  onr 
knowledge  it  does  not  seem  justifiable  to  reject  the  analyses  of  Samples 
N  and  0.  This  conclusion  is  supported  by  the  &ct  that  the  water 
determinations  failed  to  show  a  difference  between  these  samples. 
The  results,  however,  indicate  that  the  average  ratio  1.34562  (77.300 
per  cent  of  silver)  may  be  very  slightly  too  low,  owing  to  the  presence 
of  disilver  hydrogen  phosphate.  The  ratio  1.34562,  assuming  the 
atomic  weight  of  silver  to  be  107.88,  and  assuming  that  silver  bromide 
contains  57.4453  per  cent  of  silver,  leads  to  an  atomic  weight  of 
31.043  for  phosphorus,  whereas  the  ratio  1.34564  derived  from  Sam- 
ples N  and  P  gives  the  value  31.037.  The  rounded-off  value,  31.04, 
may  be  considered  to  be  essentially  ftw  from  error  from  this  source. 

We  are  greatly  indebted  to  the  Carnegie  Institution  of  Washington 
for  generous  pecuniary  assistance  in  pursuing  this  investigation ;  also 
to  the  Cyrus  M.  Warren  Fund  for  Research  in  Harvard  University  for 
many  pieces  of  platinum  apparatus. 

Summary. 

1.  A  careful  study  has  been  made  of  the  conditions  necessary  for 
the  preparation  of  pure  trisilver  phosphate. 

2.  It  is  found  that  silver  phosphate  can  be  almost  completely  dried 
without  fusion  by  heating  in  a  current  of  dry  air. 

3.  The  density  of  silver  phosphate  is  found  to  be  6.37.  ^ 

4.  It  is  found  that  silver  phosphate  does  not  adsorb  a  significant 
amount  of  air. 

5.  Nine  analyses,  made  with  four  different  samples,  show  that  one 
gram  of  silver  phosphate  yields  1.34562  grams  of  silver  bromide,  Whence 
the  per  cent  of  silver  in  silver  phosphate  is  77.300. 

Therefore, 

If  Ag=  107.88  P  =  31.04 

If  Ag=  107.87  P  =  31.03 

If  Ag=  107.86  P  =  31.02 

Cambridoe,  Mass.,  November  12,  1909. 


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Prooeedings  of  the  Ammican  Academy  of  Arti  and  Sdenoea. 
Vol.  XLV.  No.  6.  — January,  1910. 


CONTRIBUTIONS  FROM  THE  ZOOLOGICAL  LABORATORY  OF 
THE  MUSEUM  OF  COMPARATIVE  ZOOLOGY  AT  HARVARD 
COLLEGE,  E.  L.  MARK,  DIRECTOR.  —  No.  206. 


THE  REACTIONS  OF  AMPHIBIANS   TO  LIGHT. 


Bt  A.  S.  Peabsb. 


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Digitized  by  VjOOQIC 


CONTRIBUTIONS  FROM  THE  ZOOLOGICAL  LABORATORY  OF 
THE  MUSEUM  OF  COMPARATIVE  ZOOLOGY  AT  HARVARD 
COLLEGE.    E.  L.  MARK,  DIRECTOR.    NO.  206. 

THE   REACTIONS   OF  AMPHIBIANS  TO   LIGHT. 

Bt  a.  S.  Pearse. 

Presented  by  E.  L.  Mark.  December  8,  1900.    Received  November  24.  1009. 

TABLE  OF  CONTENTS. 

PAOB 

I.  INTRODUCTION 162 

A.  Historical 162 

B.  Methods 167 

II.  OBSERVATIONS       168 

A.  The   Photic  Reactions   op   Normal  Amphibians  compared 

WITH  THOSE  FROM  WHICH  THE    EyES   HAVE  BEEN    REMOVED  168 

(a)   Necturua  maculoaua 168 

(6)    Cryptobranchus  allegheniensis 170 

(c)  AmUystoma  pundatum 173 

(d)  Plethodon  cinereua  eryUironotua 173 

(c)    Diemyctylus  virideacens 174 

(/)    Rana  damata     175 

(g)   Rana  sylvatica 175 

(h)   Bufo  americanus  and  B.fowleri 176 

(t)    Condusians 177 

B.  The  Influence  of  Mechanical  Stimulation  on  the  Photic 

Reactions  of  the  Toad 177 

C.  The  Reactions  of  the  Toad  to  Photic  Stimulation  through 

THE  Eyes  alone      178 

D.  The  Reactions  of  Eyeless  Toads  to  Unilateral  Stimula- 

tion BY  Light  from  above 182 

E.  TffE  Effects  of  Illuminating  Small  Areas  of  Skin  on  Eye- 

less Toads       183 

F.  The  Effect  of  Previous  Conditions  of  Light  Stimulation 

ON  Photic  Reactions 184 

G.  The   Reactions   of  Amphibians   to   Lights   of   Different 

Colors 187 

(a)  Normal  individudla 188 

(b)  Eydess  individitdU 189 

(c)  Summary 191 

vol.  xlv.  — 11 


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162  PBOCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

H.  Comparison  op  the  Reactions  op  Eyeless  Toads  to  Heat 

AND  to  Light 192 

I.    EIxperiments  to  determine  the  Inpluencb  op  the  Central 

Nervous  Organs  on  the  Photic  Reactions  op  Amphibians  195 

III.  DISCUSSION  and  conclusions      199 

IV.  SUMMARY       205 

V.  BIBLIOGRAPHY       206 

I.  INTRODUCTION. 

A.    Historical. 

Considerable  interest  has  lately  centred  itself  in  the  study  of  the 
behavior  of  animals  under  the  influence  of  lights  and  the  results  of 
such  studies  have  been  largely  used  in  formulating  the  various  theories 
which  attempt  to  account  for  the  reactions  of  organisms  after  they 
have  been  subjected  to  external  stimulation.  Among  vertebrates  the 
amphibians  offer  particularly  fieivorable  material  for  such  study,  as 
the  various  species  may  be  used  for  experimentation  in  or  out  of  the 
water ;  they  are,  as  a  rule,  very  responsive  to  photic  stimulation  and 
are  able  to  withstand  severe  operations  without  serious  interference 
with  their  reactions.  A  large  amount  of  work  by  a  number  of  observers 
has  already  been  done  in  the  study  of  light  responsiveness,  and  in  the 
next  few  pages  an  attempt  is  made  to  summarize  the  results  of  those 
studies,  so  £bu:  as  they  apply  to  amphibians.  For  the  sake  of  clearness 
this  material  will  be  considered  from  a  comparative  standpoint  rather 
than  in  an  historical  order. 

Amphibians  react  to  light  by  giving  motor  responses.  This  motor 
reaction  to  illumination  was  first  recorded  by  Configliachi  and  Rusconi 
('I9).i  They  observed  that  Porteus  anguinus,  the  blind  cave  sala- 
mander of  Europe,  became  restless  when  exposed  to  lights  and  this 
observation  has  been  confirmed  by  later  observers  (Semper,  '81 ; 
Dubois,  'SO ;  Beer,  K)l).i  Since  that  time  responsiveness  to  light  has 
been  noted  in  the  following  genera:  Triturus,  or  Triton  (Graber,  '83,  '84 ; 
Willem,  *91),  Necturus  (Cope,  '89,  Eeese,  .-06),  Cr3rptobranchus  (Reese, 
:06,  B.  G.  Smith,  :07),  Diemyctylus  (Jordan,  '93),  Spelerpes  (Banta  and 
McAtee,  :06),  Rana  (Kiihne,  '70»;  Loeb,  '90;  Parker,  :03*;  Torelle, 
:03,  Yerkes,  K)3,  06 ;  Dickerson,  K)6 ;  Holmes,  :06 ;  Cole,  07),  Acris 

*  The  numbers  in  parentheses  indicate  the  year  of  publication  of  th^^ 
article  referred  to,  the  title  of  which  is  given  in  full  in  the  "Bibliography  " 
at  the  end  of  the  paper.  An  apostrophe  indicates  an  omitted  18;  a  colon,  an 
omitted  19. 


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PEARSE. — THE    REACTIONS   OF    AMPfflBIANS   TO  LIGHT.         163 

(Cole,  :07),  Bnfo  (Graber,  *B4).  As  these  are  representatiye  genera^  it 
seems  evident  that  photic  stimulation  exerts  an  influence  of  wide  range 
among  the  amphibians. 

Many  amphibians  show  a  marked  tendency  to  orient  the  body  and  to 
move  toward  or  away  from  the  source  of  light.  Gonfigliachi  and  Rus- 
coni  ('19)  observed  that  Proteus  tended  to  go  to  the  side  of  an  enclosure 
fiEurther  from  the  light  and  remain  thera  Since  then  a  number  of  ob- 
servations have  been  made  concerning  the  phototropism  of  amphibians. 
Thus,  the  following  have  been  claimed  to  be  positively  phototropic: 
Rana  sp.  1  (Hobnes,  :06 ;  Dickerson,  :06),  R.  temporaria  (Plateau,  '89), 
R.  clamata  (Torelle,  :03;  Yerkes,  :03,  :06;  Cole,  :07),  R.  pipiens 
(Parker,  03*;  Torelle,  .-03),  Acris  gryllus  (Cole,  .07),  Bufo  clamita 
(Plateau,  '89) ;  and  the  five  following  negatively  phototropic:  Proteus 
anguinus  (Configliachi  and  Rusconi,  19;  Dubois,  '90),  Necturus  (Cope, 
'89 ;  Reese,  .06 ;  R  0.  Smith,  :07),  Spelerpes  maculicaudus  (Bsmta  and 
McAtee,  06),  Rana  (Loeb,  '90).  It  will  be  seen  from  this  list  that  the 
photic  reactions  of  the  Caudata  are  negative,  while  those  of  the  Sali- 
entia  are  positive,  with  the  exception  of  the  observations  by  Loeb  ('90), 
which  do  not  agree  with  those  of  other  writers. 

Some  amphibians  show  a  tendency  to  come  to  rest  in  the  shade.  We 
would  perhaps  expect  such  a  reaction  in  species  which  are  normally 
negative  in  their  phototropism,  but  Torelle  (03)  has  shown  that  the 
frog,  which  is  strongly  positive,  will  also  go  toward  a  shaded  area  and 
come  to  rest  in  it,  though  the  animal  then  faces  toward  the  light. 
Graber  ('83,  '84)  had  previously  found  that'Triturus,  Raoa,  and  fiufo 
tended  to  come  to  rest  in  shadow. 

The  eyes  are  not  essential  for  the  light  reactions,  that  is,  such  reactions 
maybe  brought  about  by  stimulation  through  ths  skin.  Configliachi  and 
Rusconi  (19)  ascribed  the  photic  reactions  of  Proteus  to  the  pain- 
ful effect  of  light  upon  the  sKh,  but  Kohl  ('95)  showed  that,  while  the 
eyes  of  this  species  are  rudimentary,  they  might  nevertheless  be  effec- 
tive photoreceptors.  It  remained  for  Dubois  ('90)  to  show  that  the 
reactions  of  Proteus  might  take  place  through  the  skin  alone.  He 
blackened  the  eyes  and  obtained  a  reaction  from  an  individual  in 
which  only  the  tip  of  the  tail  was  illuminated.  Graber  ('83,  '84)  ob- 
served reactions  in  Triturus,  which  were  like  those  of  normal  indi- 
viduals, after  the  eyes  had  been  removed  and  the  orbits  filled  with 
black  wax.  More  recently  Parker  (:03*)  has  shown  that  Rana  is 
positively  phototropic  with  and  without  the  eyes;  and  Cole  (K)7), 
besides  corroborating  Parker's  observations,  has  obtained  like  results 
from  Acris.  Eor^yi  ('93)  observed  reflex  leg  movements  in  a  frog, 
which  had  been  rendered  particularly  sensitive  by  treatmg  the  brain 


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164  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

with  meat  extract,  when  he  threw  a  strong  beam  of  light  on  its  back. 
Reese  (:06)  found  that  when  only  the  tip  of  the  tail  was  illaminated  in 
Cryptobranchus  or  Nectaros,  the  individuals  thus  stimulated  moved 
out  of  the  lighted  area. 

The  reactions  brought  about  by  stimulating  the  eye  alone  agree,  in 
kind,  with  those  brought  about  through  the  skin.  Parker  (-OS^)  found 
that  frogs  in  which  the  skin  was  covered  but  the  eyes  were  exposed,  were 
positively  phototropic,  like  individuals  in  which  the  eyes  had  been  re- 
moved Torelle  (-03)  made  an  observation  which  bears  indirectly  on 
the  same  point  She  found  that  frogs  which  had  one  eye  covered  with 
black  cambric  went  toward  the  light  at  an  angle  or  made  circus  move- 
ments with  the  uncovered  eye  towards  the  centre. 

The  positive  phototropism  qf  amphibians  is  apparently  a  reaction  to- 
ward a  greater  intensity  of  illumination;  or,  with  the  eyes,  toward  a 
greater  illuminated  area.  Plateau  ('89,  p.  88)  observed  that  Rana 
and  Bufo,  when  placed  in  a  box  having  two  openings,  went  toward  the 
larger  aperture  even  though  it  was  covered  with  a  grating.  Cole  (07) 
showed  that  when  Acris  was  placed  between  two  lights  of  the  same 
quality  and  intensity  but  of  different  areas,  it  went  toward  the  larger 
area,  but  when  individuals  in  which  the  optic  nerves  had  been  cut 
were  placed  in  the  same  situation,  they  went  toward  either  light  an 
approximately  equal  number  of  times.  Rana  also  showed  the  same 
reaction  toward  the  larger  area  when  it  was  in  normal  condition. 
Torelle  (:03)  found  that  the  direction  of  the  illumination  made  no 
difference  in  photic  respond  as  frogs  went  toward  the  lighter  end  of 
a  box  when  the  illumination  was  from  below,  and  Reese  (:06)  has 
made  similar  observations  on  Crj^tobranchus  and  Necturus.  Dicker- 
son  (:06,  p.  32)  says,  "  Frogs  do  not  distinguish  between  a  lighted 
space  and  a  white  solid.  They  will  turn  toward  a  white  card  or 
paper  and  try  to  jump  through  it,  and  they  may  struggle  at  the  im- 
possible task  of  working  their  way  into  the  solid  white  surfsice  made 
by  the  leaf  edges  of  a  closed  book" 

Torelle(03)  noted  that  frogs,  when  they  were  confined  in  a  small 
space  with  an  opening  above,  pointed  the  head  upward  toward  the 
opening,  and  she  supposed  this  to  be  evidence  for  the  directive  action 
of  the  ra)rs.  Objection  may  be  made  to  this  view  on  the  ground  that 
the  opening  offers  the  only  opportunity  for  escape,  and  the  animal, 
seeing  the  opening  with  its  eyes,  points  its  head  toward  it.  If  she  had 
shown  the  same  reaction  with  eyeless  individuals,  the  evidence  would 
have  been  more  conclusiva 

The  rays  toward  the  violet  end  of  the  spectrum  are  apparently  most 
2X>tent  in  producing  photic  reactions,  and  the  rays  toward  the  opposite 


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PEAHSE.  —  THE   REACTIONS   OF   AMPHIBIANS   TO    LIGHT.         165 

end'  approach  in  their  effects  the  conditions  brought  about  by  dark, 
Graber  ('83,  ^84)  foand  that  Tritarus  did  not  come  to  rest  in  the  colors 
toward  the  violet  end  of  the  spectrum  when  tliere  was  equal  oppor- 
tunity to  remain  in  those  nearer  the  opposite  end.  This  was  true  of 
blinded  as  well  as  normal  animals.  He  also  ('84)  found  that  Rana 
and  Bufo  reacted  in  much  the  same  way.  He  states  that  his  results 
could  not  have  been  due  to  the  effect  of  temperature,  as  he  performed 
experiments  in  which  he  used  a  heat  screen  for  the  blue  and  none  for 
the  red  light,  and  the  results  were  the  sama  Eiitme  ('78»)  had  pre- 
viously observed  that  normal  frogs  went  from  green  toward  blue  light, 
while  blinded  individuals  did  not  Loeb  ('SO)  states  that  the  less  re- 
frangible rajTS  do  not  affect  light  reactions  to  such  an  extent  as  those 
of  greater  refrangibility,  and  in  this  connection  he  remarks  that  a  frog 
will  jump  towards  a  red  cloth.  (He  found  Rana  to  be  negatively  pho- 
totropic.)  Torelle  (»3)  in  speaking  of  the  frog  recorded  in  a  stronger 
positive  phototropism  for  blue  light  than  for  red,  yellow,  or  green ;  and 
this  was  the  same  when  the  light  was  reflected,  transmitted,  or  both. 
The  individuals  she  used  were  indifferent  to  red  light  Reese  (:06) 
found  blue  to  be  most  potent  in  causing  reactions  in  Necturus  and 
Cryptobranchus.  Yerkes  (:03,  p.  586)  suggested  that  the  frog  might 
be  able  to  distinguish  between  red  and  white  backgrounds,  but,  as  he 
says  (:06,  p.  548),  there  is  nothing  to  show  that  these  reactions  might 
not  have  been  due  to  intensity  differences.  Holmes  (:06,  p.  350)  in 
speaking  of  frogs  sums  up  the  whole  matter  by  stating  that  "  in  general 
it  may  be  said  that  where  they  are  able  to  go  toward  one  of  two  colors, 
of  equal  intensity,  they  move  to  the  color  lying  nearest  the  violet  end 
of  the  spectrum." 

The  phototropic  reactions  of  amphibia  are  apparently  not  due  to  the 
direct  stimulation  of  the  central  nervous  system  by  light.  Parker  (:03*) 
found  that  eyeless  frogs  responded  positively  when  only  the  lower  part  of 
the  body  was  illuminated  from  the  side  in  such  a  manner  that  the  central 
nervous  organs  were  in  shadow.  The  experiments  of  Dubois  (:90)  on 
blinded  Proteus,-  and  Reese  (:06)  on  Cryptobranchus  and  Necturus 
offer  additional  evidence  on  this  point  These  animals  reacted  to  a 
beam  of  light  thrown  on  the  tail,  and  hence  beyond  the  limits  of  the 
central  nervous  organs. 

Various  internal  and  external  factors  may  influence  the  resp<mses  qf 
amphibians  to  light.  It  is  probable  that  there  are  many  factors  which 
exert  such  a  modifying  influence.  Those  which  are  enumerated  in  the 
following  paragraphs  are  known  to  alter  the  photic  responses  of  certain 
amphibians  by  producing  changes  in  their  physiological  states. 

Breeding  season.    Jordan  (:93,  p.  271),  in  speaking  of  Diemyctylus, 


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166  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

sajTS  they  "asaally  conceal  themselves  under  fallen  leaves  and  among 
the  tangle  of  water  weeds.  On  warm,  sunny  days  in  early  spring, 
however,  they  bask  openly  in  the  sunshine  along  the  shore."  Another 
instance  is  given  by  B.  G.  Smith,  (:07,  p.  6),  who  remarks  that  "  Cryp- 
tobronchns  comes  forth  but  seldom  in  the  daytime  except  during  the 
breeding  season,"  and  (p.  32)  "  with  the  close  of  the  breeding  season, 
becomes  more  shy,  avoids  the  light  and  is  seldom  seen  in  the  open." 

Temperature.  ToreUe  (.03,  p.  475)  stated  that  the  positive  photo- 
tropism  of  the  irog  increased  as  the  temperature  was  raised.  If,  how- 
over,  the  temperature  rose  above  30°  C,  these  animals  were  indifferent 
to  light,  and  if  it  fell  below  8°  C,  they  became  negative.  Cole  (07, 
p.  401)  has  shown  conclusively  that  conditions  of  temperature  influ- 
ence the  photic  responses  in  Rana.  As  has  been  stated,  his  method 
was  to  place  the  animals  between  two  lights  of  equal  intensities  but 
different  areas.  When  a  frog  has  been  cooled  to  from  6°  to  10°  C,  it 
went  toward  the  smaller  illuminated  area,  but  after  it  became  warm  its 
reactions  were  uniformly  toward  the  larger  area. 

Previous  photic  stimulation.  Configliachi  and  Rusooni  (:19)  noticed 
that  after  Proteus  had  been  exposed  to  light  for  some  time,  its  reac- 
tiveness  to  that  stimulus  decreased.  Reese  (.-06,  p.  94),  in  experi- 
menting with  Cryptobranchus  and  Necturus,  found  that "  the  responses 
to  light  were  much  more  marked  for  the  first  ten  or  a  dozen  stimula- 
tions." Torelle  (:03,  p.  47),  on  the  other  hand,  observed  that,  after 
five  to  eight  hours'  exposure  to  light,  frogs  exhibited  the  same  positive 
phototropism  as  before. 

Stereotropism.  Eigenmann  and  Denny  (OO,  p.  34)  in  st)eaking  of 
Typhlotriton,  say  that  "  it  seems  probable  that  sterotropism  rather  than 
negative  heliotropism  accounts  for  the  presence  of  this  species  in  caves. 
Torelle  (:03,  p.  477)  found  that  Rana  was  strongly  stereotropio  below 
8°  C.  This  stereotropism  was  associated  with  a  change  from  positive 
to  negative  phototropism,  and,  as  Holmes  (.06,  p.  349)  has  pointed 
out,  may  have  been  responsible  for  such  changa 

Age.  Banta  and  McAtee  (K)6,  p.  71)  in  their  experiments  with  the 
cave  salamander  found  that  "  all  larvae  are  very  much  more  responsive 
to  light  stimulus  than  the  adults,  the  young  larvae  more  so  than  the 
older." 

Surrounding  medium.  Torelle  (03,  p.  473)  has  shown  that  frogs 
will  go  toward  the  light  under  water  as  well  as  in  air.  The  change  in 
surrounding  medium,  and  from  walking  to  swimming,  apparentiy  does 
not  alter  the  reactions* 


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PEABSE.  —  THE   REACTIONS   OP   AMPHIBIANS    TO    LIGHT.        167 

B.  Methods. 

The  experiments  described  in  the  present  paper  have  been  devoted 
(1)  to  extending  the  range  of  oar  knowledge  of  photic  reactions  among 
the  amphibians,  (2)  to  ascertaining  more  fully  the  nature  of  the  photo- 
receptors involyed,  and  (3)  to  determining  how  great  a  part  the  central 
nervous  system  takes  in  these  reactions.  It  gives  me  great  satisfsiction 
to  express  my  indebtedness  to  Professor  6.  H.  Parker,  under  whose 
direction  the  work  was  accomplished. 

All  the  experiments  which  are  described  in  the  succeeding  pages  were 
carried  on  in  a  dark  room,  the  temperature  of  which  usually  varied 
between  17^  G.  and  21^  C.  The  source  of  the  light  was  a  six-glower 
Nemst  lamp,  and  as  the  amount  of  light  it  gave  out  varied  under  dif- 
ferent conditions,  the  intensity  used  is  given  under  the  descriptions  of 
the  various  experiments.  All  the  amphibians  used  were  collected  in  the 
vicmity  of  Cambridge,  Massachusetts,  with  the  exception  of  Necturus, 
which  came  from  Venice,  Ohio ;  Cryptobranchus  from  Oil  City,  Penn- 
sylvania, and,  through  the  kindness  of  Professor  A.  M.  Banta,  from 
Marietta,  Ohio ;  and  Diemyctylus  from  Jafirey,  New  Hampshire.  Th^ 
aquatic  species  were  kept  in  a  large  aquarium  tan^  four  meters  long 
by  one  and  a  half  wide,  in  a  cool  basement  room.  The  terrestrid 
forms  were  kept  in  cages,  the  floors  of  which  were  covered  with  earth 
and  dead  leaves,  and  individuals  upon  which  operations  had  been  per- 
formed were  placed  on  a  bed  of  moist  excelsior  in  glass  jars.  Little 
trouble  was  experienced  in  keeping  the  animals  in  good  condition. 
The  frogs  and  toads  were  fed  with  meal  worms,  which  they  ate  readily 
throughout  the  winter.  The  other  species  were  not  fed,  though  Cryp- 
tobranchus may  have  eaten  frogs,  which  were  kept  for  other  purposes 
in  the  aquarium  with  it ;  and  as  one  of  those  animals  lived  for  two 
years,  it  is  not  improbable  that  it  obtained  such  food  from  time  to 
tima  The  experiments  were  carried  out  in  the  autumn  and  winter 
months  (October  1  to  April  1)  of  two  different  years. 

Of  the  aquatic  species  used,  Cryptobranchus  was  the  most  reactive. 
For  experimental  purposes  Bufo  was  the  most  satisfactory  of  the  land 
forms,  both  on  account  of  its  extreme  activity  and  its  greater  ability  to 
withstand  dryness.  Both  Bufo  fowleri  and  B.  americanus  were  used, 
but  the  experiments  on  the  two  species  were  not  kept  separate.  Dr. 
L.  J.  Cole  informs  me  that  Acris  is  much  better  than  Bufo  for  work 
of  this  nature,  but  I  have  not  had  an  opportunity  to  try  it.  The  term 
"amphibians"  in  this  paper  does  not  include  caeoiliws,  whose  reac- 
tions to  light  are,  so  &r  as  I  know,  unstudied. 


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168 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


IL  OBSERVATIONS. 
A.  The  Photic  Reactions  op  Normal  Amphibians  compared 

WITH  THOSE  FROM  WHICH  THE  EyBS  HAVE  BEEN  REMOVED. 

In  order  to  compare  the  reactions  of  amphibians  in  which  both  the 
skin  and  eyes  acted  as  photoreceptors  with  those  in  which  only  the 
skin  was  open  to  stimulation,  individuals  were  tested  both  in  normal 
condition  and  after  the  eyes  had  been  excised.  The  eyes  were  usually 
removed  by  making  a  single  transverse  cut  as  near  the  anterior  edge 
of  the  ear  drums  as  possible.    The  whole  front  of  the  head,  including 

the  ol&ctory  lobes  and  a 
part  of  the  cerebral  hemi- 
spheres, was  removed  by 
this  method  of  procedure 
(Figure  1).  In  Necturus 
and  Cryptobranchus,  how- 
ever, only  the  eyes  were 
excised.  All  the  species 
stood  the  operation  well 
and  subsequently  gave  typ- 
ical reactions,  except  Pleth- 
odon  and  Diemyctylus, 
which  were  apparently  much 
weakened  by  it  and  were 
indifferent  to  light  after  the 
eyes  had  been  removed.  As 
a  rule  individuals  were  not 
used  for  experimentation 
until  the  day  after  the  oper- 
ation. 

The  species  studied  fall  naturally  into  two  groups,  aquatic  and 
terrestrial.  The  former  group  included  Necturus  maculosus  and  Cryp- 
tobranchus allegheniensis,  and  the  terrestrial  species  studied  were 
Amblystoma  punctatum,  Plethodon  cinereus,  Diemyctylus  viridescens, 
Rana  clamata,  R.  sylvatica,  Bufo  fowleri,  'and  B.  americanus.  The 
reactions  of  each  species  will  be  considered  separately. 

(a)  Necturus  maculosus. 

The  first  experiments  with  this  species  were  intended  to  show  what 
influence  light  had  upon  its  movements.  Four  individuals  were 
placed  successively  in  the  centre  of  a  large  aquarium,  which  was  illu- 


FiGURE  1.  Dorsal  view  of  toad's  head 
showing  the  position  of  the  brain.  The  dotted 
line  indicates  the  plane  of  the  cut  used  in 
removing  the  eyes,    e,  eye;  r,  ear. 


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PEABSE.  —  THE   REACTIONS   OF   AMPHIBIANS  TO   LIGHT.        169 

minated  from  one  end  in  sooh  a  way  that  tbe  light  had  an  intensity 
of  about  220  candle-meters  at  its  centre.  Under  these  conditions  an 
individual  asnally  went  at  once  to  the  end  of  the  aqaarium  farther 
from  the  light  It  then  wandered  about  from  one  end  to  the  other  for 
some  time,  but  finally  came  to  rest  as  fistr  as  possible  from  the  light 
If  the  lamp  was  then  changed  to  the  opposite  end  of  the  aquarium,  the 
animal  again  moved  to  the  end  which  was  fsurther  from  the  light  and 
came  to  rest 

In  order  to  test  the  reactions  of  Necturus  to  light  and  shadow,  the 
lamp  was  moved  to  the  iside  of  the  aquarium  and  a  movable  screen 
interposed  in  such  a  way  that  one  half  of  the  aquarium  was  in  shadow 
and  the  other  half  in  light  (220  candle-meters  at  the  centre  of  the 
aquarium).  Two  animals  were  successively  introduced.  One  of 
these,  after  wandering  back  and  forth  frx)m  one  end  to  the  other, 
came  to  rest  in  the  shaded  end  of  the  aquarium.  When  the  screen 
was  changed  to  the  opposite  half,  the  animal  moved  again  into  the 
shaded  area^  and  this  action  was  repeated  for  five  successive  trials  on 
two  different  occasions.  The  other  individual  remained  at  the  side 
of  the  aquarium  nearer  the  light,  and  in  two  experiments  it  kept  going 
back  and  forth  from  light  to  shadow  for  more  than  one  hour.  It  i^- 
parently  did  not  avoid  the  light,  but,  by  comparing  the  time  it  spent 
in  the  light  with  that  spent  in  shadow  during  ]^  an  hour,  it  was 
found  that  three-fifths  of  that  period  had  been  passed  in  the  shaded 
part  of  the  aquarium.  The  first  individual,  then,  invariaBly  came  to 
rest  in  the  shadow,  and  the  second  one,  while  it  continued  to  move 
actively,  spent  somewhat  less  time  in  the  light  than  in  the  shadow. 

The  most  decisive  reactions  shown  by  Necturus  were  brought  about 
by  illuminating  a  small  area  at  its  anterior  or  posterior  end.  The 
apparatus  was  in  the  same  position  as  for  the  experiments  just  de- 
scribed, wBxcept  that  a  screen  was  arranged  in  such  a  manner  that  a 
vertical  band  of  light  about  five  centimeters  wide  could  be  suddenly 
thrown  on  different  regions  of  the  body.  Four  individuals  were  used 
for  these  experiments  and  all  of  them  behaved  in  essentially  the  same 
manner.  Aft^er  an  animal  had  remained  quiet  in  the  dark  for  five 
minutes,  it  was  suddenly  illuminated,  and  a  reaction  usually  took  , 
place  within  a  few  seconds.  When  the  light  fell  on  the  tail,  the 
animal  moved  forward,  but  when  it  was  allowed  to  fiJl  on  the  head, 
the  movement  was  usually  backward.  Since  the  animals  were  never 
tested  with  the  light  until  they  had  been  quiet  in  the  dark  for  five 
minutes,  these  reactions  were  without  doubt  due  to  the  illumination, 
for  they  took  place  within  a  few  seconds  of  the  time  when  the  light 
was  thrown  on*the  animals. 


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170  PBOCEEDINOS  OF  THE  AMEBICAN  ACADEBfT. 

In  order  to  discover  whether  the  skin  of  Neotams  was  sensitive  to 
light  or  not,  the  eyes  were  removed  from  two  individuals  and  they 
were  then  tested  by  local  stimulation  as  described  in  the  last  para- 
graph. Their  reactions  were  similar  to  those  of  animals  with  eyes 
except  in  one  particular.  The  average  time  which  elapsed  before  the 
individuals  with  eyes  moved  out  of  the  lighted  area  was  shorter  when 
the  head  was  stimulated  than  when  the  light  fell  upon  the  tail,  but 
the  eyeless  animals,  on  the  contrary,  reacted  more  quickly  when  the 
tail  was  stimulated.  The  results  with  normal  animals  agree  with 
those  of  Reese  ( :  06,  p.  96)  in  his  experiments  on  Necturus.  He 
ascribed  the  shorter  reaction  time  for  the  head  to  greater  sensitiveness 
in  that  region,  and  he  believed  it  to  be  due  to  stimulation  received 
through  the  eyes.  The  present  experiments  with  eyeless  «.niTnft|ff 
give  support  to  his  views,  as  the  posterior  end  of  the  individuals 
tested  was  apparently  more  sensitive  to  photic  stimulation  after  the 
eyes  had  been  excised.  The  decreased  sensitiveness  of  the  head 
region  may,  however,  have  been  due  to  the  injury  incident  to  the 
removal  of  the  eyes,  instead  of  the  mere  loss  of  the  eyes  themselves. 

From  the  experiments  described  it  is  evident  that  Necturus  is  nega- 
tively phototropic  and  that  it  comes  to  rest  in  shaded  areas.  Both 
the  skin  and  eyes  act  as  photoreceptors,  and  the  stimulation  of  either 
brings  about  negative  reactions. 

(b)  Cryptobranchus  allegheniensis. 

The  arrangement  of  the  apparatus  for  the  experiments  with  Crypto- 
branchus  was  the  same  as  for  those  with  Necturus.  The  reactiveness 
of  this  .species  to  light  was  very  marked.  Seven  individuals  were 
placed  successively  in  the  middle  of  the  aquarium,  the  illumination 
being  from  one  end,  whereupon  they  moved  immediately  to  the  end  £ur- 
ther  from  the  light.  When  the  lamp  was  carried  to  the  opposite  end 
of  the  aquarium,  they  usually  changed  their  position  at  once  and  again 
came  to  rest  in  the  end  further  from  the  light.  In  these  reactions  they 
were  much  more  responsive  than  Necturus,  though,  as  Reese  ( :  06, 
p.  94)  has  observed,  tiiey  often  £sdled  to  respond  readily  after  the  first 
few  reactions. 

The  reactions  of  Gryptobranchus  to  conditions  of  light  and  shadow 
were  also  pronounced.  In  testing  these,  half  the  aquarium  was  shaded 
by  a  screen  which  was  changed  from  one  end  to  the  other  at  five 
minute  intervals.  An  individual  was  placed  in  the  aquarium  and  the 
screen  changed  ten  times.  It  never  frkiled  to  move  at  once  to  the 
shaded  part  of  the  aquarium,  and  furthermore  it  rested  quietly  in 
the  shadow  in  the  intervab  between  the  changes. 


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PEARSE. — THE   BEACTIONS   OF    AMPHIBIANS   TO   LIGHT.         171 

The  illumination  of  a  small  area  at  the  anterior  or  posterior  end  of 
an  individual  produced  the  same  reactions  as  in  Nectarus,  bat  in 
Crjrptobranchus  they  took  place  more  quickly. 

To  test  the  sensitiveness  of  the  skin  to  light,  the  eyes  were  removed 
from  one  individual  and  it  was  stimulated  alternately  on  the  head  and 
tail  by  the  same  method  as  that  used  for  Necturus.  This  animal 
usually  responded  within  a  few  seconds  to  such  illumination.  In  a 
.  series  of  fifty  reactions  it  was  found  that  the  average  time  required 
for  the  animal  to  move  out  of  the  illuminated  area  was  more  than 
twice  as  great  when  the  light  fell  upon  the  head  as  when  the  tail  was 
illuminated  in  the  same  manner.  The  skin  of  Gryptobranchus  is,  then, 
a  photoreceptor  and  the  sensitiveness  seems  to  be  greater  at  the  pos- 
terior than  at  the  anterior  end.  Beese  (^06,  p.  94)  has  stated  that, 
even  with  the  eyes  present^  this  species  shows  the  greatest  sensitive- 
ness to  light  in  the  caudal  region. 

This  eyeless  individual  was  strongly  photokinetic.  It  was  placed  in 
a  flat  porcelain  dish  about  a  meter  below  an  ordinary  gas  burner,  and 
after  it  had  been  allowed  to  remain  in  the  dark  for  about  an  hour,  the 
gas  was  suddenly  lighted.  There  was  an  un&iling  response  to  this 
illumination  within  a  few  seconds,  the  animal  moving  restlessly  about 
in  the  dish.  As  the  light  was  non-directive,  and  the  animsJ  often 
remained  quiet  for  hours  in  the  dark,  this  uniform  response  to  sudden 
illumination  showed  this  species  to  be  strongly  photokinetia  In  this 
respect  it  was  quite  different  from  Necturus,  which  often  did  not  re- 
spond to  such  stimulation  for  some  time,  even  when  the  light  intensity 
was  220  candle-meters. 

In  summarizing  the  results  of  the  experiments  upon  Cr3rptobranchus, 
it  may  be  said  that  it  is  negatively  phototropic,  that  it  comes  to  rest  in 
shaded  areas  and  is  strongly  photokinetic.  These  reactions  apparently 
take  place  as  readily  when  only  the  skin  is  stimulated  by  light  as  when 
the  eyes  are  also  affected. 

The  terrestrial  amphibians  were  found  to  be  much  more  satis&ctory 
subjects  for  experimental  work  than  the  aquatic  species.  Not  only 
was  it  easier  to  arrange  the  apparatus  for  the  land  forms,  but  more 
accurate  results  were  obtained,  as  it  was  possible  to  orient  the  animab 
with  a  perfectly  uniform  relation  to  the  light  before  each  reaction.  In 
all  the  experiments  with  terrestrial  forms  the  apparatus  shown  in  Fig- 
ure 2  was  used.  After  this  apparatus  had  once  been  arranged,  it  was 
a  simple  matter  to  test  one  species  after  another,  and  to  compare  the 
reactions  of  normal  animals  with  those  of  individuals  without  eyes.  It 
will  be  seen  from  the  figure  that  the  two  side  screens  (/)  were  placed 


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172 


PROCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 


at  the  edge  of  the  shadow  made  by  the  light  that  passed  through  the 
heat  screen  (a).  Thus  the  greatest  open  space  was  away  from  the 
light,  and,  as  far  as  the  animal  was  able  to  see,  the  best  chance  for 
escape  lay  in  that  direction.  An  individual  was  not,  then,  subjected  to 
the  same  conditions  as  one  placed  in  a  small  box  having  a  single 
opening.  It  does  not  seem  improbable  that  any  animal  with  eyes, 
after  being  handled  and  shut  up  in  a  small  enclosure,  would  endeavor 
to  escape  by  the  most  apparent  opening ;  and  the  reactions  could  not  • 
in  that  case  be  interpreted  as  being  due  to  the  influence  of  light  alona 
The  apparatus  shown  in  Figure  2  is  not  open  to  such  an  objection. 


Figure  2.  Plan  of  apparatus  in  which  the  reactions  of  terrestrial  amphib- 
ians to  light  were  tested,  a,  heat  screen  filled  with  water;  6,  screen  for 
head  of  observer;  c,  lamp;  h,  screen  extending  to  ceiling;  «,  «',  screen  25  cm. 
high. 

The  method  of  experimentation  was  to  place  an  individual  at  a 
distance  of  seventy  centimeters  from  the  light  (where  the  intensity 
was  225  candle-meters)  and  watch  it  through  a  small  hole  in  the  screen 
6,  until  a  definite  movement  had  taken  place.  After  a  reaction  of  this 
kind,  the  animal  was  held  for  a  few  seconds  outside  the  screen  8,  where 
it  could  not  see  the  light,  in  order  to  eliminate  any  directive  effect 
produced  by  that  stimulus,  and  it  was  then  replaced  ready  for  another 
reaction.  To  counteract  the  effects  of  compensatory  movements,  the 
animals  were  always  turned  in  a  clockwise  direction  between  the  re- 
actions, and  were  placed  with  the  right  and  left  sides  alternately  to- 
ward the  light,  the  long  axis  of  the  body  being  at  right  angles  to  the 
direction  of  the  rays.    To  avoid  effects  due  to  fatigue,  no  more  than 


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173 


twenty  reactions  were,  as  a  role,  recorded  from  an  individual  on  any 
one  day.  As  the  method  of  procedure  was  the  same  in  all  cases,  and, 
as  the  only  object  in  view  was  to  compare  the  reactions  of  eyeless  and 
normal  animals,  the  discussion  under  each  species  will  be  limited 
mostly  to  the  results  obtained. 

(c)   Amblystoma  punctatum. 

Four  individuals  were  used  in  the  experiments  upon  this  species. 
After  the  eyes  had  been  excised,  the  two  smaller  animals,  which 
measured  about  seven  centimeters  in  length,  did  not  survive  more 
than  a  day  or  two.  The  two  adult  individuals,  however,  were  ap- 
parently little  affected  by  the  operation,  and  one  of  them  lived  for 
forty-seven  days  after  it  The  results  of  the  experiments  are  given 
in  Table  I.    This  species  is  shown  to  be  negatively  phototropic,  both 

TABLE  I.« 

Photic  Reactions  op  Amblystoma  punctatum,  with  and 
WITHOUT  Eyes. 


Coadition  of  individuals 

Normal 

Eyeless 

Direction  of  movement 

r  Number 
Reactions 

[Fer  cent 

+ 
6 
6 

88 
84 

0 
10 
10 

19 
16 

71 
58 

0 
32 
26 

in  the  normal  and  eyeless  condition.  As  might  be  expected,  there  were 
more  movements  withoat  reference  to  the  light  after  the  eyes  had  been 
excised,  bat  this  may  have  been  dae  to  the  effects  of  the  operation. 
Whether  this  is  true  or  not,  the  fact  remains  that  the  animals  were 
able  to  respond  negatively  to  light  received  throagh  the  skin. 

(d)  Plethodan  cinereus  erythranatUB. 

This  species  manifested  the  same  negative  phototropism  as  the  last, 
when  in  normal  condition,  but  it  did  not  stand  the  operations  well. 

'  In  the  tables  which  appear  throughout  this  paper  the  following  signs 
are  used:  ''  -f  "  indicates  a  decided  movement  towiuxl  the  light,  **  —  **  is 
used  for  a  similar  movement  away  from  the  li^t,  and  "  0  "  signifies  that  the 
individual  remained  still  for  fifteen  minutes  or  made  a  movement  without 
apparent  reference  to  the  light. 


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174 


'PROCEEDINGS   OF   THE   AMERICAN   ACADEMY. 


This  may  have  been  dae  to  the  small  size  of  the  animal,  which  ren- 
dered it  less  able  to  withstand  the  unfiskvorable  conditions  in  its  en- 
vironment after  the  eyes  had  been  excised.  The  reactions  summarized 
in  Table  II.  show  that  the  species  was  n^gatiyely  phototropic  when  in 

TABLE  II. 
Photic  Reactions  of  Plbthodon  ctnereub  ertthronotus, 

WITH  AND  without  EyES. 


Condition  of  individuals 

Normal 

Eyeless 

Direction  of  movement 

Number 
Reactions 

Per  cent 

+ 

4 

12 

30 

88 

0 
0 
0 

12 
29 

9 

22 

0 
20 
49 

normal  condition.  After  the  eyes  had  been  excised,  however,  the  move- 
ments were  without  apparent  reference  to  the  light  This  indifference 
may,  nevertheless,  have  been  due  to  the  effects  of  the  operation  rather 
than  to  lack  of  photic  sensitiveness  in  the  skin. 

(e)  Diemyctylus  viridescens. 

Like  Plethodon,  this  species  did  not  stand  the  operation  well  and 
gave  no  reactions  which  were  manifestly  due  to  light  after  the  eyes  had 
been  removed.  Ten  individuals  were  used,  and  the  eyes  were  excised 
from  eight  of  them.  None  of  the  latter  lived  more  than  twelve  days 
after  the  operation.    The  results  given  in  Table  III.  bring  out  the  fact 

TABLE  III. 

Photic  Reactions  of  Diemyctylus  vikidesceks,  with  and 
without  Eyes. 


Condition  of  individuals 

Normal 

Eyelesa 

Direction  of  movement 

/  Number 
Reactions 

^Percent 

242 
71 

88 
26 

0 

10 

3 

+            - 
30           29 
26           25 

0 
57 
49 

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175 


that  this  species  is  positively  phototropic ;  a  condition  which  is  not, 
80  &r  as  I  know,  found  in  any  other  caudate  amphibian.  All  the  in- 
dividuals used  were  of  the  orange  type  of  coloration,  and  it  is  possible 
that  animals  of  this  species  having  die  green  phase  might  give  different 
results. 

(/)  Bana  clamata. 

Although  the  eyes  were  not  excised  from  any  individual  of  this  spe- 
cies, the  reactions  observed  are  given  in  Table  IV.  for  comparison  with 

TABLE  IV. 
pHonc  Reactions  of  Rana  clamata. 


Direction  of  movement 

C  Number 
Reactions  •{ 

IPercent 

104 
67 

37 
23 

0 
15 
10 

the  next  form.  They  agree  essentially  with  those  described  by  Parker 
(:03^)  and  Torelle  (^03)  for  R.  pipiens  and  R.  viridescens.  Five  indi- 
viduals were  tested,  and  they  sJl  proved  to  be  positively  phototropic. 

{g)  Bana  sylvatica. 

This  frog  was  more  active  than  the  last  species,  and  some  individuals 
gave  more  decided  phototropic  reactions  than  did  any  member  of  the 

TABLE  V. 

Photic  Reactions  op  Rana  sylvatica,  with  and  without  Etes. 


Condition  of  individuals 

Normal 

Eyeless 

Direction  of  movement 

+ 

- 

0 

+ 

— 

0 

Individual  No.  1 

20 

0 

0 

20 

0 

0 

Individual  No.  2 

17 

2 

1 

10 

5 

5 

Individual  No.  3 

7 

11 

12 

Individual  No.  4 

6 

7 

1 

Total            f  ^^^^ 

60 

20 

14 

30 

5 

5 

Reactions    \  pe^  cent 

60 

24 

16 

75 

12 

12 

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176 


PROCEEDINGS   OF  THE   AMERICAN   ACADEMY. 


preceding  species.  There  were,  however,  such  differences  in  the  re- 
actions of  the  four  animals  used  that  they  are  tabulated  separately. 
Individual  No.  1  never  fisdled  to  move  straight  toward  the  light  No.  2 
was  not  as  persistently  positive  after  the  eyes  had  been  excised  as  be- 
fore this  operatiout  though  it  continued  to  give  a  majority  of  positive 
reactions.  As  individuals  3  and  4  were  apparently  indifferent  to  the 
light  in  their  normal  conditions,  their  eyes  were  not  removed.  The 
reactions  of  animals  1  and  2  were,  however,  strongly  positive,  and  this 
condition  remained  even  after  the  eyes  had  been  excised ;  hence  their 
skins  served  as  photoreceptors  as  wdl  as  their  eyes. 

(h)  Bi^fo  americanus  and  B.  fawleri. 

Both  these  species  were  used  for  experimentation,  but,  as  the  records 
were  not  kept  separate,  their  reactions  cannot  be  distinguished  and 
are  given  together  in  Table  VI.    The  results  include  experiments  with 

TABLE  VI. 
Photic  Reactionb  op  Normal  and  Eyeless  Toads, 


Condition  of  individnaln 

Normal 

Eyeless               1 

Direction  of  movement 

(  Ninnber 
Reactions     { 

(  Per  cent 

802 
74 

265 
25 

0 
11 

1 

126 
66 

47 
25 

0 

17 

9 

twenty  normal  animals  and  six  in  which  the  eyes  had  been  excised.  In 
removing  the  eyes  from  another  individual,  the  head  was  cut  diagonally 
so  that  the  left  ear  was  injured.  This  animal  turned  continually  to  the 
right,  regardless  of  the  direction  of  the  light,  and  its  reactions  were 
therefore  not  included  in  the  tabla  Although  most  of  the  individuals 
were  adults,  a  few  were  immature,  but  none  of  them  measured  less  than 
two  centimeters  in  length.  The  results  show  the  species  to  be  positively 
phototropic  in  response  to  stimulation  received  through  the  slan  as  well 
as  through  the  eyes. 

It  was  also  possible  to  show  that  the  phototropic  reactions  of  eyeless 
toads  were  not  due  to  the  effect  of  light  upon  the  exposed  ends  of  the 
optic  nerves.  On  two  occasions,  after  an  individual  had  given  ten 
successive  positive  responses,  it  was  immediately  oriented  in  such  a 
manner  that  the  anterior  end  of  the  body  pointed  away  from  the  light. 
In  both  instances  the  animals  turned  at  once  and  went  directly  toward 


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PEABSE. — THE   REACTIONS   OP   AMPHIBIANS  TO    LIGHT.         177 

the  light,  and  this  reaction  was  repeated  on  five  saccessive  trials. 
These  reactions  could  not  have  been  due  to  the  direct  stimolation  of 
the  optic  nerves  by  light,  as  they  were  not  exposed  to  such  stimulation. 
The  results  are  in  agreement  with  those  of  Graber  ('83),  who  filled  the 
orbits  of  Triturus  with  black  wax,  and  of  Dubois  ('90),  who  covered 
the  eyes  of  Proteus  with  a  mixture  of  gelatine  and  lampblack.  Both 
these  observers  obtained  phototropic  reactions  by  stimulating  the  skin. 

(0   Conclusions. 

From  the  experiments  described  it  may  be  said  that  photic  sensi- 
tiveness is  general  in  the  skin  of  amphibians.  While  there  is  consid- 
erable variation  in  the  phototropism  of  different  species,  and  even 
of  individuals  of  the  same  species,  the  reactions  brought  about  by 
stimulation  through  the  skin  alone  are  like  those  produced  when  both 
the  skin  and  eyes  act  as  photoreceptors. 

R   The  Influence  op  Mechanical  Stimulation  on  the  Photic 
Reactions  op  the  Toad. 

In  the  experiments  with  terrestrial  amphibians  and  light  the  obser- 
vations were  always  made  after  the  animals  had  been  handled  by  the 
experimenter,  and,  though  the  response  was  decided  in  most  cases  and 
of  such  a  nature  as  to  attribute  it  to  lights  it  is  not  impossible  that 
mechanical  stimulation  through  handling  may  have  been  responsible 
for  more  or  less  of  it.  In  order  to  test  this  matter  five  toads  which 
were  known  to  be  positively  phototropic  were  placed  successively  in  a 
box,  the  floor  of  which  measured  thirty-eight  by  ninety  centimeters. 
The  sides  and  floor  of  this  box  were  of  slate,  and  the  ends  were  closed 
by  glass  heat-screens  containing  a  layer  of  water  3.75  centimeters 
thick.  The  roof  consisted  of  a  coarsely  woven  black  cloth  stretched 
on  a  wooden  fi^me,  and  the  observations  were  made  through  the  meshes 
of  this  clotL  A  lamp  giving  a  light  intensity  of  220  candle-meters 
was  changed  firom  one  end  to  the  other  at  five-minute  intervals  for  a 
period  of  fifteen  minutes.  Four  of  the  individuals  when  first  placed  in 
the  apparatus  went  toward  the  light,  and  then  wandered  back  and 
forth  without  evident  reference  to  it^  and  apparently  tried  to  escape 
firom  the  enclosure.  The  fifth  animal  sat  in  the  centre  of  the  box, 
turning  firom  one  side  to  the  other  for  three  minutes,  and  then  went 
away  firom  the  light  When  the  lamp  was  changed  firom  one  end  of 
the  apparatus  to  the  other,  only  one  of  the  individuals  turned  imme- 
diately and  went  toward  it ;  the  other  four  were  apparentiy  indifferent. 
In  a  later  experiment,  however,  two  toads  were  observed  to  be  persist- 
VOL.  xlv.  — 12 


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178  PBOCEEDINOS  OF  THE  AlfERICAN  ACADEMY. 

ently  positive,  and  they  tried  for  as  much  as  five  minutes  to  move 
through  a  heat  screen  to  the  light. 

Six  toads  were  next  placed  together  in  a  rectangular  glass  vessel 
(the  floor  of  which  measured  twelve  by  twenty  centimeters)  and  were 
subjected  to  approximately  the  same  light  conditions  as  in  the  last 
experiment  In  jumping  about  they  stimulated  each  other  in  a  me- 
chanical way.  During  fifteen  minutes  all  the  individuals  remained 
mostly  &cing  the  light  and  making  vain  attempts  to  reach  it^  and  only 
occasionally  did  one  of  them  try  to  escape  on  the  opposite  side  of 
the  jar. 

It  is  evident  firom  these  two  experiments  that  mechanical  stimulation 
exerts  an  influence  on  the  phototropism  of  the  toad  by  enforcing  the 
effect  of  light,  or,  it  could  perhaps  better  be  said,  that  the  mechanical 
stimulation  furnishes  the  impuhe  to  locomotion,  while  the  light  is 
efiective  in  determining  the  direction  of  the  movement  after  locomotion 
has  been  established.  For  the  purpose  of  the  present  paper,  however, 
it  makes  no  difiierence  whether  the  responses  obtained  were  due  solely 
to  the  influence  of  light  or  whether  they  were  reactions  to  light  after 
mechanical  stimulation.  In  either  case  the  fietct  remains  that  both  the 
skin  and  eyes  of  amphibians  act  as  photoreceptors,  and  that  definite 
reactions  take  place  as  a  result  of  stimulation  through  either. 

C.  The  Reactions  op  the  Toad  to  Photic  Stimulation 

THROUGH  THE  EyBS  ALONE. 

Experiments  have  been  described  in  this  paper  which  show  that 
various  amphibians  react  in  the  same  way  when  either  the  skin  alone 
is  stimulated  or  when  both  the  skin  and  eyes  are  affected.  The  next 
question  which  naturally  arises  is  whether  animals  will  react  in  the 
same  way  when  the  stimulation  is  received  through  the  eyes  alona 
That  such  responses  take  place  in  Rana  pipiens  has  been  shown  by 
Parker  (:03^  p.  33),  who  found  this  species  to  be  positively  photo  tro- 
pic when  its  entire  surfisice  was  covered,  with  the  exception  of  the  eyes. 
In  order  to  test  the  toad  in  a  similar  manner  the  apparatus  shown  in 
Figure  3  was  used.  Light  was  allowed  to  pass  through  a  small  open- 
ing (e)  in  a  screen,  which  could  be  adjusted  so  that  only  a  small  area 
around  the  eye  of  the  animal  was  illuminated.  As  an  additional  pre- 
caution against  light  reception  through  the  skin,  the  individuals  used 
were  covered,  except  the  eyes  and  feet,  by  a  tight-fitting  suit  of  soft 
leather.  As  might  be  expected,  the  movements  of  the  two  animals 
used  in  the  experiments  were  slow.  Each  of  these  individuals  was 
placed  with  its  right  and  left  side  alternately  toward  the  lights  the 


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179 


long  axis  of  the  body  being  at  right  angles  to  the  direction  of  the  ra3rs. 
The  movements  which  resulted  from  Qiis  method  of  stimulation  are 
summarized  in  Table  VIL    The  results  show  that  the  toad  gives  the 


.fiL. 


FiGtJRE  3.  A^  section  of  apparatus  to  test  reactions  of  toads  to  stimu- 
lation through  the  eyes  alone;  B,  ground  plan,  a,  screen;  c,  lamp;  d,  heat 
screen;  e,  aperture  for  light;  /,  chimney  for  carrying  away  heat;  y,  slate 
upon  which  the  animals  were  placed;  2,  source  of  light;  8,  screen. 


same  sort  of  positive  reactions  when  the  eyes  are  stimulated  as  when 
the  skin  is  illuminated. 

If  the  reactions  of  the  two  individuals  just  described  were  due  to 
unequal  stimulation  of  the  eyes,  it  ought  to  be  possible  to  produce 


^ 


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180 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


circus  movements  by  stimulating  only  one  eye.    In  order  to  obtain 
such  unilateral  stimulation,  a  flap  was  fastened  in  the  leather  suit  used 

TABLE  Vn. 

Photic  Reactions  op  Toads  Stimulated  through  the 
Eyes  alone. 


Direction  of  movement 

+ 

— 

0 

Individual  No.  1 

73 

14 

13 

Individual  No.  2 

72 

22 

6 

['Number 
Reactions    - 

iPer  cent 

145 
72 

36 
18 

16 
10 

in  previous  experiments  so  that  it  could  be  made  to  cover  either  eya 
The  individuals  were  placed  so  that  they  &ced  the  light  with  only  the 
area  about  the  uncovered  eye  illuminated.  Under  these  circumstances 
seventy  per  cent  of  the  movements  (Table  VIII.)  were  not  toward  the 
light  but  toward  the  side  bearing  the  uncovered  eya     These  reac- 

TABLE  Vm. 

Photic  Reactions  op  Two  Toads  Facing  toward  the  Light 
AND  Stimulated  thbouoh  only  one  Ete. 


Condition  of  individuals 

Right  eye  covered 

Left  eye  covered 

Direction  of  movement 

Right 

Left 

t 

Right 

Left 

-f 

Individual  No.  3 

33 

45 

22 

63 

21 

16 

Individual  No.  4 

0 

97 

3 

66 

5 

29 

rNumber 
Reactions    • 

I  Per  cent 

33 
17 

142 
71 

25 
12 

139 
69 

26 
13 

35 
18 

tions  are  what  might  be  expected  from  a  positively  phototropio  species 
like  the  toad,  as  similar  responses  have  been  observed  in  many  other 
animals.  For  example,  circus  movements  have  been  noted  in  several 
arthropods  after  one  eye  had  been  blackened  over  or  excised,  by 
Hohnes  (:0l,  :05),  Parker  0O3'),  and  RMl  (:03).    No  observations 


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PEABSE.  —  THE   BEACTIONS   OF   AMPHIBIANS  TO   LIGHT. 


181 


of  exactly  this  kind  have  been  made  on  amphibians,  although  Torelle 
(:03,  p.  474)  found  that  a  frog  went  toward  the  light  with  the  long 
axis  of  the  body  oblique  to  the  direction  of  the  rays,  or  made  circus 
movements,  after  one  eye  had  been  covered.  She  made  no  attempt^ 
however,  to  stimulate  the  eye  without  also  affecting  the  skin. 


A 


jH^ 


' 


FiGUBB  4.  Af  front  sectional  view  through  the  middle  of  the  apparatus 
for  testing  eyeless  frogs  under  unilateral  stimulation;  B,  sectional  view  from 
the  side,  a,  wooden  support  for  heat  screen,  which  contained  an  oblong 
opening;  c,  adjustable  screen  of  blackened  sheet  iron;  I,  source  of  light; 
8,  black  cardboard  screen;  tp,  glass  dish  containing  water. 


From  these  experiments  it  is  apparent  that  the  photic  reactions  of  the 
toad,  which  are  brought  about  by  stimulation  through  the  eyes,  are  due 
to  intensity  differences  in  the  illumination  of  the  two  eyes,  and  the 
direction  of  the  light  rays  is  apparently  of  no  significance. 


Digitized  by 


GOOQ^ 


182  PROCEEDINGS   OF   THE    AMERICAN   ACADEMY. 

D.  The  Reactions  of  Eyeless  Toads  to  Unilateral  Stimulation 
BY  Light  from  abovk 

The  last  experiments  described  showed  that  a  toad  would  turn  toward 
the  illuminated  side  when  only  one  eye  was  stimulated,  even  when  such 
a  movement  did  not  take  it  into  a  region  of  greater  light  intensity. 
The  next  question  which  suggested  itself  was  whether  eyeless  indi- 
viduals would  make  similar  movements  when  only  one  side  was  stimu- 
lated. In  solving  this  problem,  the  apparatus  shown  in  Figure  4  was 
used.  It  consisted  of  a  wooden  box  (sixty  centimeters  high,  forty-five 
wide,  and  twenty-eight  deep)  which  was  lined  throughout  with  two 
layers  of  black  cloth,  except  the  floor,  which  was  of  slate.  Light  com- 
ing from  above  (J)  passed  through  oblong  openings  in  two  screens  (a,  s) 
so  that  an  area  a  little  larger  than  a  toad  was  illuminated  on  the  floor 
of  the  apparatus,  where  the  light  intensity  was  413  candle-meters. 
Each  toad  was  so  placed  that  the  right  and  left  sides  were  alternately 
illuminated,  and  an  accurate  unilateral  division  of  light  and  shadow  was 
secured  by  using  a  small  movable  screen  (c)  of  blackened  sheet  iron. 

In  preparing  individuals  for  these  and  subsequent  experiments,  a 
different  method  was  used  for  excising  the  eyes  from  that  followed 
heretofore.  Instead  of  removing  the  whole  upper  jaw,  a  horizontal  cut 
was  made  just  above  the  nostrils,  which  met  a  vertical  cut  behind  the 
eyes.  The  roof  of  the  mouth  was  thus  lefb  intact,  and  there  was  conse- 
quently no  interference  with  the  respiratory  movements.  The  plan 
followed  in  experimenting  was  to  orient  the  individual  facing  the  ob- 
server before  each  of  the  first  ten  reactions,  while  for  the  last  ten  it  was 
&ced  in  the  opposite  direction.  Before  and  after  the  tests  with  light 
from  above,  each  toad  was  tested  ten  times  with  light  of  the  same  in- 
tensity (413  candle-meters)  from  the  side.  The  results  of  the  reactions 
(Table  IX.)  with  the  light  from  above  show  a  turning  toward  the  side 
illuminated  in  seventy  per  cent  of  the  cases,  and,  while  the  positive 
phototropism  of  the  same  individuals  was  slightly  greater  when  they 
were  illuminated  from  one  side,  the  difference  does  not  amount  to 
enough  to  be  significant.  It  may  therefore  be  said  that  the  positive 
phototropism  of  eyeless  toads  is  due  to  intensity  differences  on  the  two 
sides  of  ^e  body. 

Pa3me  (•'07)  has  performed  experiments  of  the  same  kind  with  the 
blind  fish,  Amblyopsis  spelaeus,  after  the  eyes  had  been  excised,  and 
obtained  similar  results.  Apparently  the  direction  of  the  light  rays,  as 
distinguished  fix)m  intensity  differences,  has  no  influence  on  the  reac- 
tions of  either  of  these  species. 


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PEABSE.  —  THE    REACTIONS    OF    AIUPHIBIANS  TO    UGHT. 


183 


TABLE  IX. 

Reactions  op  Six  Eyeless  Toads  to  .Vertical  and 

Horizontal  Light. 


Direction  of  light 

Light 
from  side 

Light  from  above 

Light 
from  side 

Regions  illuminated 

Light  on  right 
side 

Light  on  left 
side 

Direction  of  movement 

C  Number 
Reactions    ] 

I  Per  cent 

54 
90 

1 
2 

0 
5 

8 

+ 
42 
70 

10 
17 

0 

8 

13 

48 
80 

5 

8 

0 

7 

12 

38 
62 

9 
15 

0 
13 
23 

K  The  Effbcts  of  Illuminating  Small  Areas  of  Skin  on 
Eyeless  Toads. 

In  order  to  test  the  reactions  of  eyeless  toads  to  local  stimulation  by 
light  in  various  regions  of  the  skin,  individuals  were  placed  two  centi- 
meters behind  a  screen  containing  a  circular  opening  3.2  millimeters  in 
diameter,  through  which  a  horizontal  beam  of  light  passed.  To  render 
the  rays  of  light  as  nearly  parallel  as  possible  a  large  condensing  lens 


Figure  5.  Toad,  viewed  from  right  side.    The  dotted  areas  indicate  the 
regions  illuminated. 

was  interposed  between  the  screen  and  the  light.  A  small  area  of  skin 
could  thus  be  strongly  stimulated  by  light ;  the  light  used  had  an  in- 
tensity of  474  candle-meters.  The  three  regions  shown  by  the  dotted 
areas  in  Figure  5  were  stimulated,  and  they  may  be  designated  as  the 
regions  of  the  front  leg,  the  hind  leg,  and  the  back.     Before  each  of 


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184 


PROCEEDINGS  OF  THE  AlfEBICAN  ACADEMT. 


the  tests  the  individaals  were  tried  in  light  of  lesser  intensity,  but  ap- 
plied to  the  whole  surfisice  of  the  body,  to  see  that  they  were  positively 
phototropia 

TABLE  X. 


IiOCAL  Son  Ttj^uionation 

OP 

Eight  Eyeless  Toads. 

' 

Regions  illuminated 

Whole  body 

Front  leg 

Hind  leg 

Back 

Direction  of  movement 

(  Number 
Reactions    < 

{  Percent 

104 
73 

18 
13 

0 
20 
14 

+ 
15 
57 

6 
23 

0 

5 

20 

+ 
74 
64 

21 
18 

0 
21 
18 

18 
56 

10 
31 

0 

4 

13 

The  experiments  (Table  X)  showed  the  toad  to  be  positively  photo- 
tropic  in  response  to  stimulation  received  through  each  of  the  regions 
l^ed,  and  there  was  no  reason  to  assume  that  one  region  was  more 
sensitive  to  such  stimulation  than  another. 

TABLE  XI. 

SuMMABT  OP  Daily  Series  op  Twenty  Reactions  by  Eleven  Toads 
APTEB  Previous  Exposure  in  the  Ijght  or  in  the  Dark. 


Previously  in 

dark 

Previously  in  light 

Direction  of  reaction   ..... 

+ 

- 

0 

+ 

— 

0 

First  reaction 

Number 
Percent 

29 
53 

20 
36 

6 
11 

33 
59 

10 
17 

3 
23 

First  5  reactions 

/Number 
^Percent 

188 
69 

73 
27 

11 
4 

174 
64 

58 
21 

42 
15 

Last  15  reactions 

t  Number 
'percent 

668 
84 

116 
15 

5 

1 

589 

88 

65 
10 

9 

1 

Total  reactions 

t  Number 
'percent 

851 
81.3 

179 
17.1 

16 
1.5 

763 
81.6 

121 
12.9 

51 
5.5 

Pajme  (:07)  has  shown  a  similar  condition  in  Amblyopsis.    He  states 
(p.  323)  that  these  fishes  "seem  to  be  equally  sensitive  on  all  parts  of 


r 


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PEARSE. — THE   REACTIONS    OF    AMPHIBIANS    TO    LIGHT.         185 

the  body,"  after  the  eyes  have  been  excised.  Parker  (lOS*',  p.  419)  and 
Reese  (.06,  p.  94)  have,  on  the  other  hand,  found  the  tail  to  be  the  most 
sensitive  region  in  Ammoccetes  and  Cryptobranchus  respectively.  These 
few  observations  indicate  that  the  comparative  sensitiveness  of  the  skin 
to  photic  stimulation  varies  in  diflferent  species  of  vertebrates. 


R    The  Effect  of  Previous  Conditions  of  Light  Stimulation  on 
Photic  REACTiONa 

It  had  been  noticed  in  a  general  way  during  the  preceding  experi- 
ments that  when  a  toad  was  placed  near  a  strong  light  the  first  reac- 
tion was  more  often  away  from  the  light  than  any  of  the  subsequent 
responses  were,  and  that  the  first  reaction  was  usually  slower  than 
those  which  followed.  G.  Smith  (:05)  has  shown  that,  when  Gam- 
marus  is  exposed  to  light,  a  pigment  migration  takes  place  toward 
the  proximal  ends  of  the  retinula  cells,  and  that  as  this  migration  pro- 
gresses the  animal  changes  its  reactions  firom  indifferent  to  strongly 
positive.  As  a  pigment  migration,  as  well  as  other  changes,  takes 
place  when  the  eyes  of  amphibians  are  exposed  to  light,  it  was  thought 
that  there  might  be  a  similar  influence  on  the  reactions  in  this  case, 
and  experiments  were  accordingly  carried  out  to  test  this  question. 

In  these  experiments  toads  were  placed  in  the  centre  of  a  box  which 
was  ninety  centimeters  long  and  thirty-eight  wide.  The  floor  and 
sides  were  of  slate,  and  both  ends  were  closed  by  glass  heat-screens 
which  contained  a  layer  of  water  3.75  centimeters  thick.  Light,  which 
had  an  intensity  of  220  candle-meters  at  the  spot  where  the  toads  were 
exposed  to  it,  was  admitted  from  one  end,  and  before  each  reaction  the 
individuals  were  placed  with  the  right  and  left  sides  alternately  toward 
the  source  of  light.  Eleven  toads  were  kept  first  in  the  dark  for  five 
days  and  then  in  the  light  (three  candle-meters)  of  a  gas  jet  for  an 
equal  period  of  time.  The  eyes  were  thus  exposed  continuously  to 
uniform  light  or  dark,  except  when  the  animals  were  removed  for  the 
experiments,  which  occupied  about  half  an  hour  daily.  By  taking 
twenty  records  from  each  individual  each  day,  an  attempt  was  made 
to  get  a  series  of  a  hundred  reactions  from  each  individual  under  the 
two  conditions  of  previous  exposure  to  light  and  to  dark  In  all  but 
three  cases  these  attempts  were  successful 

The  results  in  Table  XI.  show  that  the  first  reaction  in  a  series  of 
twenty  has  the  least  tendency  to  be  positively  phototropic  and  that 
subsequent  reactions  are  increasingly  positive.  There  is,  however,  no 
great  diff'erence  between  the  responses  of  individuals  previously  exposed 
to  light  and  those  previously  in  the  dark.    In  Table  XII.  the  reactions 


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186 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


of  each  animal  are  shown,  and  it  will  be  seen  that  the  individuals  often 
vary  widely  in  their  different  reactions.  For  example,  toad  No.  13 
was  negatively  phototropio  after  being  in  the  dark,  but  strongly  posi- 
tive after  exposure  to  light    Although  the  effect  of  previous  stimula- 

TABLE  XII. 

Reactions  of  Individual  Toads  previouslt  in  the  Light 
OB  in  the  Dark. 


Condition 

Previously  in 

dark 

Previously  in 

Ught 

Direction  of  movement 

+ 

- 

0 

+ 

— 

0 

Individual  No.  11 

94 

6 

0 

100 

0 

0 

Individual  No.  12 

89 

11 

0 

76 

6 

3 

Individual  No.  13 

26 

74 

0 

95 

5 

0 

Individual  No.  15 

89 

10 

1 

74 

9 

1 

Individual  No.  22 

94 

5 

1 

82 

14 

4 

Individual  No.  23 

88 

9 

3 

64 

25 

7 

Individual  No.  24 

72 

8 

2 

83 

14 

4 

Individual  No.  25 

97 

:    9 

0 

64 

34 

2 

Individual  No.  26 

76 

22 

2 

10 

1 

18 

Individual  No.  27 

59 

8 

7 

26 

3 

12 

Individual  No.  28 

73 

27 

0 

89 

10 

1 

Total            /Number 
reactions       ^  Per  cent 

851 

179 

16 

763 

121 

51 

81.3 

17.1 

1.5 

81.6 

12.9 

5.5 

tion  is  marked  in  some  individuals,  yet  when  we  consider  the  total 
number  of  reactions,  almost  the  same  percentage  of  positive  photo- 
tropism  is  shown  aftier  prolonged  exposure  to  the  light  as  aft;era  similar 
period  in  the  dark  These  results  agree  with  those  of  Torelle  (:03),  who 
found  that  eight  hours  of  exposure  to  light  did  not  change  the  positive 
phototropism  of  the  frog. 

Table  XIII.  shows  the  times  which  elapsed  before  the  reactions 
recorded  in  Table  XII.  took  place.    No  records  were  included  which 


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PEABSE. — THE   REACTIONS   OF   AMPHIBIANS  TO   LIGHT.        187 

did  not  show  twenty  successive  reactions  on  the  day  considered 
Under  (a)  sixty  sach  sets  of  daily  records  are  included,  and  under  (6), 
forty-three  sets.  The  toads  reacted  more  slowly  after  having  been 
kept  in  the  dark  than  after  they  had  been  exposed  to  light  The 
difference  is  not  great  and  cannot  be  considered  very  significant  in 
showing  optic  influence.  The  results  may,  however,  be  interpreted  as 
indicating  that  prolonged  exposure  to  light  renders  the  toad  more 
photokinetic 


G.  The  Reactions  of  Amphibians  to  Lights  of  Different 

Colors. 

In  testing  the  reactions  of  animals  to  lights  of  different  wave  lengths 
the  apparatus  shown  in  Figure  6  was  used.  Animals  were  placed  in 
the  position  shown  in  the  figure,  and  after  each  reaction  they  were 
rotated  clockwise  through  180°.  The  right  and  left  sides  were  thus 
brought  alternately  toward  the  light,  which  had  an  intensity  of  612 
candle-meters  (for  white  light)  at  the  point  where  the  animals  were 
placed.  The  different  colors  were  obtained  by  passing  the  white  light 
of  a  Nemst  lamp  through  colored  screens.  These  screens  were 
solutions  of  various  substances  held  in  rectangular  glass  jars  which 
could  be  easily  interchanged.^  The  colors  used  were  r^  yellow,  green, 
and  blue,  and,  though  they  were  not  perfectly  monochromatic,  they 
did  not  overlap  significantly  in  the  spectrum. 


*  The  substances  used  in  making  the  solutions  and  the  ranges  of  the 
colors  obtained  from  them,  as  determined  by  an  Engehnann  spectroscope, 
were  as  follows: 


Colon. 

Substances. 

Amount 
in  grama. 

c.c.  of 
water. 

Wave- 
length in  11. 

Red 

Fuchsin 

0.10 

750 

0.605-0.608 

YeUow 

Potassium  bichromate 

and 
Copper  sulphate 

es.oO'j 

15.00' 

750 

0.540-0.606 

Green 

/"LichtgrOn" 

and 
i  Copper  sulphate 

1.50% 
5.00^ 

750 

0.460-0.530 

Blue 

" Bleu  de  Lyon" 

0.15 

760 

0.430^.485 

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188  PBOCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 

TABLE  XIII. 

AvBRAGB  Reaction  Times  in  BIinutes  of  Toads  fbeyiouslt 
IN  THE  Light  ob  in  the  Dabk. 


Number  of  the  reacticm 

1 

2 

3 

4 

6 

6 

7 

8 

9 

10 

(a)   Previously  in  dark 

8.3 

3.5 

2.2 

2.0 

1.8 

1.4 

1.3 

1.1 

1.1 

1.1 

(6)   Previously  in  light 

5.9 

3.5 

3.4 

1.6 

1.8 

1.4 

0.8 

0.8 

0.9 

0.8 

Number  of  the  reaction 

11 

12 

13 

14 

15 

16 

17 

18 

19 

20 

(a)   Previously  in  dark 

1.1 

1.0 

1.0 

0.9 

0.9 

1.0 

0.8 

1.0 

0.7 

0.8 

(6)   Previously  in  light 

0.7 

0.7 

0.6 

0.7 

0.6 

0.7 

0.7 

0.6 

0.6 

0.5 

(a)  Normal  Individuak. 

For  the  experiments  with  animals  in  normal  oondition,  Bana 
palustris  was  used.  Six  individuals  were  successively  tested  with  the 
colors  in  the  following  order,  blue,  green,  yellow,  red,  and  then  this 


$ 

f 

.^^-— 

i 

/C 

CL    ^ 

t 

f 

1 

A 

9 

Figxtre  6.  Plan  of  apparatus  for  testing  the  reactions  of  toads  to  colored 
lights.  Af  position  of  observer;  a,  heat  and  color  screen;  6,  screen  25  cm. 
high;  I,  light;  a,  a,  a,  a,  screen  extending  to  ceiling;  t,  t,  t,  t,  table. 


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PEABSE.  —  THE   REACTIONS   OP   AMPHIBIANS  TO   LIGHT.        189 

order  was  reyersed.  The  plan  followed  was  to  test  all  the  individaals 
in  one  oolor  and  then  to  change  the  screen  and  test  them  again  in  the 
same  order  bat  with  the  next  color ;  ten  reactions  being  taken  from 
each  individoal  in  every  color.  Each  animal  was  thus  actoally  subject 
to  experiment  for  about  one  hour  out  of  the  six  which  were  required  to 
complete  the  series.  A  second  half-dozen  of  frogs  was  tested  in  the 
same  maimer,  except  that  the  colors  were  used  in  the  order  red,  yellow, 
green,  blue,  and  then  the  order  was  reversed. 

TABLE  XIV. 
Reactions  of  Rana  palubtbis  to  Ck>LOBED  Lights. 


Color  of  lights 

Blue 

Qreen 

YeUow 

Red 

Direction  of  movement 

+ 

- 

0 

+ 

- 

0 

-f 

- 

0 

+ 

- 

0 

Reactions 

First  six 
individuals 

Second  six 
individuals 

(Number 
Total 

(  Per  cent 

96 

81 

177 

74 

13 

26 
38 
16 

11 

14 
25 
10 

80 

68 

148 

62 

14 

38 
52 
22 

26 

14 
40 
16 

69 

55 

124 

52 

20 

39 
59 
24 

33 

26 
59 
24 

66 

45 

111 

46 

16 

29 
45 
19 

39 

46 
85 
35 

Ave.  reaction  time  in  minutes 

2.83 

3.09 

3.60 

3.75 

The  results  (Table  XIV.)  show  that  blue  is  apparently  the  most 
effective  in  the  production  of  positively  phototropic  reactions,  and  that 
there  is  a  reguliur  graduation  from  blue  to  red,  both  in  the  percentage 
of  positive  reactions  and  in  the  rapidity  with  which  the  movements 
took  place.  Other  observers  (p.  165)  have  obtained  similar  results  in 
experiments  with  other  species  of  amphibians.  It  is  probable  that 
these  differences  in  the  reactions  are  due  to  differences  of  the  wave 
lengths,  but  they  may  be  due  to  intensity  differences. 

(b)  Eyeless  IndividucUs. 

The  blue  end  of  the  spectrum  is  known  to  be  more  potent  in  affect- 
ing changes  in  the  eyes  of  many  animals,  and  in  some  species  the 
sensitiveness  to  red  is  apparently  lacking  altogether.  For  example, 
Abelsdorff  (:00,  p.  562)  observed  that  the  pnpil  of  the  owl's  eye 


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190 


PROCEEDINGS  OF  THE  AlfEBICAN  ACADEMY. 


enlarged  in  red  light  but  oontraoted  rapidly  when  it  was  exposed  to 
blue  light  of  low  intensity.  It  therefore  seemed  not  improbable  that 
the  differences  in  the  frog's  reactions  to  lights  of  different  colors  might 
have  been  due  to  stimulation  received  through  the  eyes ;  therefore 
another  set  of  experiments  was  undertaken  to  ascertain  if  like  results 
could  be  obtained  through  the  stimulation  of  the  skin  alone. 

As  toads  had  been  found  to  be  more  responsive  than  frogs  after  the 
eyes  had  been  excised,  they  were  used  in  testing  the  light  reactions 
through  the  skin.  The  same  apparatus  (Figure  6)  was  used  as  in  the 
experiments  with  normal  animsJs,  except  that  the  light  was  passed 
through  a  square  aperture,  2.7  centimeters  on  a  side,  and  had  an 
intensity  of  874.  candle-meters  for  white  light  at  the  point  where  the 
animals  were  placed.    The  method  used  for  removing  the  eyes  was  the 

TABLE  XV. 
Reactions  of  Thbeb  Eyeless  Toads  to  Colored  Lights. 


Color  of  lighte 

White 

Red 

YeUow 

Green 

Blue 

Direction  of  movement 

(  Number 
Reactions    < 

(Percent 

+ 
48 
96 

1 
2 

0 

1 
2 

+ 
38 
76 

2 
4 

0 
10 
20 

37 
74 

2 
4 

0 
11 
22 

+ 
38 
76 

5 
10 

0 

7 

14 

+ 
37 
74 

3 
6 

0 
10 
20 

same  as  in  previous  experiments  (p.  182).  Three  individuals  were 
tested  successively  with  white,  red,  yellow,  green,  and  blue  light  in  the 
order  given.  The  next  day  two  of  the  animals  were  tested  again  with 
the  same  colors  but  in  the  inverse  order. 

It  will  be  seen  (Table  XV.)  that  these  toads  gave  about  seventy-five 
per  cent  of  positively  phototropic  reactions  with  every  color.  Appar- 
ently all  the  colors  were  equally  effective  in  inducing  photic  responses. 
This  &ct  is  the  more  striking  when  we  remember  that  the  same  color 
screens  were  used  as  in  the  experiments  with  normal  amphibians 
(Table  XIV.),  in  which  case  the  blue  was  most  potent  The  reactions 
to  white  light)  in  the  present  instance,  showed  an  almost  perfect  posi- 
tive phototropism,  and  it  seemed  possible  that  the  lesser  d^ree  of 
reactiveness  diown  in  the  responses  to  colored  lights  might  have  been 
due  to  differences  in  intensity,  as  the  color-screens  undoubtedly  cut 
off  much  light.  To  ascertain  if  any  difference  would  be  manifest  in 
the  responses  if  the  intensity  were  lowered,  a  diaphragm,  having  a 
circular  aperture  2.8  millimeters  in  diameter,  was  interposed  and 


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PEABSE.  —  THE   REACTIONS   OP   AMPHIBIANS   TO    LIGHT.        191 

experiments  performed  in  which  eyeless  toads  were  placed  at  a  distance 

of  275  centimeters  from  the  lamp,  where  the  intensity  was  1.44  candle 

meters  for  white  light    The  colored  screens  cut  the  light  down  to 

what  must  have  been  considerably  less  than  a  candle-meter.    The 

results  obtained  from  seven  toads  not  previously  tested  are  shown  in 

Table  XVI. 

TABLE  XVI. 


Reactions  of  Seven  Eyeless  Toads  to 
OP  Low  Intensity. 

Ck>LORED  Lights 

Color  of  lighte 

White 

Red 

Yellow 

Green 

Blue 

Direction  of  movement 

Number 
Reactions 

Per  cent 

84 
84 

6 
6 

0 
10 
10 

+ 
56 
50 

26 
23 

0 

28 

27 

76 
68 

18 
17 

0 
16 
15 

65 

58 

21 
19 

0 
24 
23 

59 
53 

28 
25 

0 
25 

22 

Althongh  the  "  positive  percentages  "  in  every  color  were  lower  than 
when  light  of  greater  intensity  was  used  (Table  XV.),  the  eyeless  toads 
again  showed  positive  phototropism  in  all  the  colors.  There  was  also, 
in  this  case,  a  greater  number  of  positive  reactions  when  white  light 
was  used  than  when  any  of  the  colors  were  substituted  for  it  It  is, 
then,  apparent  that  in  a  decreased  light  intensity  the  number  of 
positive  reactions  decreased,  but  no  especial  potency  was  shown  by  one 
color  as  compared  with  another  as  a  means  of  inducing  such  reactions. 
The  slight  differences  between  the  number  of  positive  reactions 
produced  by  lights  of  different  colors,  as  shown  in  the  table,  may  be 
accounted  for  as  being  due  to  intensity  differences.  The  colors,  as 
judged  by  the  human  eye,  could  be  arranged  from  more  to  less  intense 
in  the  following  order,  yellow,  green,  red,  blue ;  and  it  will  be  seen  that 
the  largest  number  of  positive  reactions  was  brought  about  by  the  most 
intense  lights  thus  judged. 

(c)  Summartf. 

The  results  of  the  reactions  of  amphibians  to  colored  lights  may  be 
briefly  summarized  as  follows  :  normal  animals  were  positively  photo- 
tropic  in  all  the  colors  tried,  but  there  were  more  positive  reactions 
toward  the  violet  end  of  the  spectrum  than  toward  the  red  end ;  eyeless 
individuals  were  also  positively  phototropio  in  all  the  colors,  but  there 
was  no  difference  in  number  between  the  positive  reactions  to  the  several 
colors.    These  results  do  not  agree  with  those  of  most  other  observers. 


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192  PBOOEEDINOS   OF   THE   AMERICAN   ACADEMY. 

In  &ct»  Loeb  ('88)  has  stated  as  a  general  law,  that  the  more  primitive 
the  photoreoeptor,  the  greater  is  its  sensitiveness  to  the  rays  toward  the 
violet  end  of  the  spectrum,  as  compared  to  those  toward  the  opposite 
end.  Graber  ('83,  p.  225)  stated  that  in  the  phototropio  responses  of 
Tritnms  the  rays  became  more  and  more  like  darkness  in  their  effects 
as  the  red  end  of  the  spectrum  was  approached ;  and  that  this  was  true 
of  eyeless  individuals  as  well  as  those  in  normal  condition.  Dubois 
('90,  p.  358)  observed  that  blue  was  more  effective  than  red  in  produc- 
ing responses  from  a  blinded  Proteus  when  only  the  tail  was  illumi- 
nated. Opposed  to  these  observations  are  those  of  Euhne  ('78^, 
p.  119),  who  found  that,  while  normal  frogs  rested  in  green  when  there 
was  equal  opportunity  to  rest  in  blue,  blinded  individuals  showed  no 
such  reactions.  The  results  described  in  the  present  paper  agree  with 
those  of  Eiihne,  and  it  seems  to  be  evident  that  the  photoreceptors  in 
the  skin  of  the  frog  and  toad  have  little  or  no  sensitiveness  to  color 
differences,  as  sucL 


H.  Comparison  op  the  Reactions  of  Eyeless  Toads  to  Heat 
AND  TO  Light. 

It  has  long  been  known  that  the  skin  of  amphibians  could  be  stimu- 
lated by  heat^  and  the  opinion  has  been  expressed  that  there  are  recep- 
tors which  are  open  to  stimulation  by  either  heat  or  light  Kor^n}ri 
(^93)  showed  that  heat,  as  well  as  ligh^  might  produce  motor  reactions 
when  it  was  applied  to  the  skin  of  a  frog.  Parker  (K)3*,  p.  34)  says  : 
"  It  is  conceivable  that  in  the  lower  vertebrates,  like  the  frog,  the  end 
organs  of  the  skin  are  stimulated  by  radiant  energy  of  a  wide  range, 
including  what  is  for  us  both  radiant  heat  and  ligh^  and  that  the  de- 
scendants of  these  organs  in  the  skins  of  higher  vertebrates  are  more 
restricted  in  function  and  are  ordinarily  sensitive  to  radiant  heat  and 
its  effects."  Washburn  (:08,  p.  142)  also  says,  "  While,  then,  the  nerve 
endings  in  the  human  skin  are  sensitive  only  to  the  slowest  of  these 
vibrations,  the  heat  rays,  those  in  the  skin  of  the  frog,  may  respond  to 
the  whole  series." 

During  the  experiments  with  eyeless  toads  the  question  arose  as  to 
whether  the  supposed  photic  reactions  might  not,  after  all,  be  due  to 
the  influence  of  heat  And,  although  a  heat  screen  containing  water 
was  used  in  all  experiments,  there  was  a  possibility  that  the  light  was 
converted  into  heat  as  it  was  absorbed  by  the  skin,  and  that  the  sensi- 
tiveness was  to  heat  rather  than  light  Furthermore,  the  part  of  the 
apparatus  containing  the  lamp  was  warmed  somewhat  during  a  series 
of  experiments  and  gave  off  a  small  amount  of  heat    A  crude  test  as 


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PEABSE. — THE   REACTIONS    OF   AMPHIBIANS   TO   LIGHT.        193 

to  the  e£fect  of  this  heat  from  the  apparatus  was  made  in  the  following 
way :  On  two  occasions  when  a  toad  had  gone  successively  ten  times 
toward  the  light,  an  opaque  screen  was  interposed  in  such  a  way 
that  the  light  was  cut  off  but  the  radiating  heat  from  the  apparatus 
was  allowed  to  reach  the  toad.  In  both  instances  the  individuals 
gave  ten  reactions  without  apparent  reference  to  the  heated  appa- 
ratus, thus  showing  that  the  reactions  had  not  been  brought  about 
by  heat 

In  order  to  test  the  sensitiveness  of  the  toad  to  increased  tempera- 
ture, two  eyeless  individuals  were  suspended  in  such  a  way  that  the 
hind  legs  could  be  dipped  into  water.  Neither  of  these  animals  made 
any  movement  under  this  method  of  treatment  when  the  water  was  at 
room  temperature  (20^  C).  The  temperature  of  the  water  was  then 
raised  five  degrees  at  a  time,  and  there  was  no  response  until  a  temper- 
ature of  40°  G.  to  45°  G.  had  been  reached,  when  the  animals  quickly 
withdrew  their  legs  from  the  hot  water.  It  was  evident^  from  these 
results,  that  the  toad  did  not  respond  readily  to  increase  in  tempera- 
ture. Reese  (:06)  found  that  Gryptobranchus  also  was  comparatively 
insensitive  to  changes  in  the  temperature  of  the  surrounding  medium, 
but,  if  the  temperature  was  raised  above  40°  G^  violent  motor  reactions 
occurred. 

While  these  observations  showed  that  amphibians  might  not  be 
very  sensitive  to  thermic  stimulation,  the  possibility  was  not  excluded 
that  the  assumed  photic  reactions  might  in  reality  be  due  to  stimula- 
tion of  the  skin  receptors  by  heat  If  the  positively  phototropio 
.  reactions  of  blinded  toads  were  due  to  the  stimulation  of  such  recep- 
tors, it  ought  to  be  possible  to  obtain  similar  reactions  through  the 
use  of  radiant  heat  instead  of  light  To  ascertain  if  this  were  possible, 
an  apparatus  was  arranged  in  which  steam  was  passed  through  a  verti- 
cal brass  pipe  which  measured  seven  millimeters  in  diameter.  The 
eyeless  toads  were  placed  near  this  pipe,  and  their  reactions  tested  in 
the  same  manner  as  had  previously  been  done  with  light  All  these 
experiments  were  performed  in  the  dark,  but  before  and  after  the  heat 
experiments  each  individual  was  tested  with  light  (1.24  candle-meters) 
to  ascertain  whether  it  was  positively  phototropio  or  not  The 
method  of  experimenting  in  the  dark  was  to  orient  the  toad  by  using 
a  mark  at  a  known  distance  from  the  source  of  heat ;  then  to  listen 
until  a  movement  was  heard ;  after  which  the  position  of  the  animal 
was  ascertained  by  feeling  for  it  with  the  hand.  In  Table  XVII.  the 
signs  +}  — }  and  0  are  used  to  indicate  movements  in  relation  to  the 
steam  pipe  as  a  source  of  heat,  as  they  have  previously  been  used  for 
sources  of  light    As  this  table  shows,  toads  placed  near  (10  to  20  cm.) 

VOL.  XLV.  — 13 


Digitized  by  LjOOQIC 


194 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


the  heated  pipe  showed  a  slight  tendency  to  move  away  from  it^  hut 
heyond  twenty  centimeters  they  were  apparently  indifferent 

The  amount  of  heat  given  off  by  the  steam  pipe  as  compared  to  that 
given  off  by  the  light  apparatus  was  determined  by  means  of  a  pair  of 
thermometers.  These  thermometers  were  mounted  in  a  wooden  box 
(Figure  7),  blackened  inside  and  out  and  divided  into  two  freely  com- 

TABLE  XVII. 
Reactions  op  Four  Eyeless  Toads  to  Light  and  to  Radiant  Heat. 


Nature  of 
stimulation 

Light 

Distances  from  a  hot  pipe,  in  centimeters 

10 

20 

30 

40 

50 

Direction  of 
movement 

+ 

- 

0 

+ 

- 

0 

+ 

- 

0 

+ 

- 

0 

+ 

- 

0 

+ 

- 

0 

<\  «  (  No. 

OS   O 

108 

6 

16 

16 

29 

5 

17 

25 

8 

64 

59 

27 

16 

34 

10 

25 

21 

14 

tf-^  (Perot. 

83 

6 

12 

32 

58 

10 

34 

50 

16 

44 

40 

16 

30 

54 

16 

40 

34 

26 

Nature  of 
stimulation 

Distances  from  a  hot  pipe,  in  centimeters 

Light 

60 

70 

80 

90 

100 

Direction  of 
movement 

+ 

- 

0 

+ 

- 

0 

+ 

- 

0 

+ 

0 

+ 

- 

0 

+ 

- 

0 

Reac- 
tions 

13 
42 

9 
30 

8 
28 

15 

38 

14 
35 

11 

27 

15 
50 

13 

42 

2 
8 

15 
50 

11 
37 

4 
13 

14 
34 

18 
43 

10 
23 

131 

77 

21 
13 

18 
10 

municating  compartments  in  each  of  which  the  blackened  bulb  of  one 
of  the  thermometers  {A,  E)  was  enclosed.  One  of  these  compart- 
ments was  permanently  dosed,  while  the  other  could  be  opened  or 
closed  at  will  by  a  slide  {d).  This  apparatus  was  placed  in  such  a 
position  that  the  radiant  heat  to  be  measured  fell  directly  upon  the 
bulb  of  the  thermometer  B  when  the  slide  was  out  After  reading 
the  thermometers  at  intervals  and  allowing  the  apparatus  to  become 
adjusted  to  the  surroundings  for  two  hours,  the  difference  between  the 
two  thermometers  was  observed  at  one-minute  intervals  for  twenty 
minutes  while  the  compartment  was  open  to  receive  the  light  or  heat 
to  be  tested,  and  then  for  a  like  period  of  time  with  it  closed.    The 


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PEARSE.  —  THE   BEACTIONS   OF    AMPHIBIAKS  TO    UGHT. 


195 


average  di£ferenoe  between  the  two  thermometers,  when  placed  before 
the  steam  pipe  was  0.064°  G.  while  that  for  the  light  apparatus  was 
0.025°  G.  The  amount  of  heat  received  by  a  thermometer  at  a  distance 
of  thirty  centimeters  from  the  heated  pipe  was  therefore  more  than 
twice  that  received  when  the  light  apparatus  was  tested.  As  the 
toads  were  strongly  positively  phototropic  to  this  light,  and  as  the 
same  individuals  were  indifferent  when  placed  near  the  steam  pipe,  it 
is  safe  to  conclude  that  thermo-  and  photo-reception  are  distinct 
processes  in  the  toad's  skin,  and  that,  in  this  animal  at  leasts  heat 
does  not  give  rise  to  tropic  reactions  unless  there  is  very  strong 
stimulation. 


FiouBE  7.  Plan  of  thermometer  box.  A  and  B,  thermometers;  c,  c, 
positions  of  two  of  the  ten  circular  openings  between  the  two  compartments; 
d,  slide. 

I.  Experiments  to  deterbiinb  the  Influence  of  the  Central  Ner- 
vous Organs  on  the  Photic  Reactions  of  AMPHiBiANa 

Parker  (:05^)  succeeded  in  obtaining  photic  responses  from  one  of  the 
lower  fishes  (Ammocoetes)  after  the  entire  brain  had  been  removed,  and 
he  believed  that  such  reactions  were  brought  about  by  stimulation  re- 
ceived through  skin  receptors  and  transmitted  through  the  spinal  nerves. 
To  ascertain  if  similar  reactions  could  be  obtained  from  amphibians, 
experiments  were  undertaken  with  four  species.  The  first  to  be  tested 
was  Rana  pipiens.  A  sharp  scalpel  was  inserted  through  the  dorsal 
wall  of  the  cranium  and  a  transverse  cut  was  made  through  the  dien- 
cephalon ;  this  was  followed  by  another  cut  behind  the  second  vertebra 
which  separated  the  cord  from  the  myelencephalon.  After  such  indi- 
viduals had  been  tested,  they  were  killed  and  hardened  in  alcohol. 
Subsequent  dissection  showed  that  the  cuts  had  been  successfully 
made  in  ten  of  the  twelve  individuals  upon  which  operations  had 


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sLm.^ 


196  PROCEEDINGS  OF   THE   AMERICAN   ACADEMY. 

been  performed.  This  method  of  procedure  separated  the  cord  from 
the  brain,  but  did  not  interfere  with  the  vital  centres  in  the  latter  nor 
with  the  sympathetic  system.  These  frogs  were  tested  several  times, 
for  the  two  or  three  days  during  which  they  livedo  by  suspending 
them  at  the  anterior  end  in  such  a  way  that  the  hind  legs  could  be 
subjected  to  various  stimuli  All  of  these  individuals  flexed  the  legs 
when  they  were  touched  with  a  brush  which  had  been  moistened 
in  ten  per  cent  acetic  acid,  and  four  of  them  reacted  in  the  same 
manner  when  the  light  and  heat  from  a  Nemst  lamp  was  thrown  on 
the  skin,  a  lens  being  used  to  bring  the  light  to  a  focus ;  but  not  a 
single  individual  reacted  to  light  from  this  lamp  when  the  heat  rays 
were  cut  off  by  interposing  a  flat-sided  jar  filled  with  water. 

Ten  toads  were  tested  by  the  same  methods  as  those  used  for  the 
frogs,  and,  though  they  reacted  to  acid  and  the  light  with  heat,  no 
reactions  were  obtained  when  light  alone  was  used. 

As  no  photic  reactions  had  been  obtained  from  spinal  frogs  or  toads, 
it  was  thought  that  such  responses  might  be  induced  if  the  animals 
were  rendered  more  sensitive;  and  experiments  were  accordingly 
undertaken  in  which  the  diencephalon  and  cord  were  transected  in 
nine  toads  and  0.001  grain  of  strychnine  inserted  into  the  dorsal  Ijrmph 
space  through  a  small  slit  in  the  skin.  The  individuals  which  had  been 
treated  in  this  manner  were  extremely  sensitive  to  tactual  stimuli,  and 
the  slightest  jar  of  the  table  on  which  they  were  supported  sufficed  to 
throw  their  limbs  into  a  state  of  spasmodic  extension.  When,  however, 
a  beam  of  light  was  focussed  on  the  hind  leg  of  such  an  individual,  no 
indubitable  responses  were  obtained. 

Since  the  attempts  to  induce  photic  reactions  in  terrestrial  am- 
phibians had  met  with  no  success  after  the  brain  had  been  separated 
from  the  cord,  I  next  turned  my  attention  to  the  available  aquatic 
species.  The  eyes  were  removed  from  a  single  Grjrptobranchus,  and 
its  cord  was  cut  behind  the  first  vertebra.  This  individual  was  then 
placed  in  an  aquarium,  and  light  firom  a  Nemst  lamp  was  focussed 
upon  its  skin  in  various  regions ;  and,  although  it  had  been  found 
to  be  extremely  responsive  to  light  after  the  eyes  had  been  removed, 
no  such  responses  were  obtained  fiK)m  it  after  the  cord  had  been  cut 
It  nevertheless  continued  to  respond  to  tactual  stimulation,  and  when 
the  side  was  stroked  gently  with  the  finger,  it  jerked  its  legs  and  drew 
its  tail  away  fix)m  the  stimulated  region.  Chemical  stimulation  was 
also  effective  after  the  cord  had  been  cut,  for  when  a  pellet  of  cotton 
moistened  with  ten  per  cent  acetic  acid  was  placed  so  that  it  touched 
the  tail,  the  body  was  bent  away  firom  the  stimulated  area. 

As  the  experiments  with  Gryptobranchus  had  given  only  negative 


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PEARSE. — THE   REACTIONS   OP   AMPHIBIANS   TO    UGHT.        197 

results,  it  was  dotermined  to  make  cuts  in  various  regions  of  the  cord 
in  different  animals  and  determine  whether  the  individuals  thus  treated 
would  show  differences  in  their  behavior.  The  eyes  were  accordingly 
removed  from  four  specimens  of  Necturus,  and  the  cord  was  cut  behind 
the  fourth,  ninth,  eleventh,  and  twentieth  vertebrse  in  the  respective 
individuals.  All  these  animals  gave  marked  reactions  to  light  when 
the  illumination  was  anterior  to  the  cut  in  the  cord,  but  no  responses 
were  obtained  from  the  region  posterior  to  this  cut,  even  when  a  strong 
beam  of  light  was  focussed  on  the  skin.  The  regions  posterior  to  the 
cut  were,  however,  influenced  by  certain  forms  of  stimulation,  and  re- 
sponded by  making  withdrawing  movements  when  they  were  stroked 
with  a  brush,  or  when  cotton  saturated  with  ten  per  cent  acetic  acid 
was  placed  in  the  water  near  them.  All  the  individuals  seemed  to  stand 
the  operation  well ;  the  gill  movements  continued  in  a  normal  manner, 
and  walking  was  carried  on  by  the  front  legs,  while  the  posterior  part 
of  the  body  dragged  behind.  All  these  animals  lived  more  than  five 
days,  and  one  of  them  (with  its  cord  cut  behind  the  eleventh  vertebra) 
lived  thirty-six.  This  particular  individual  was  extremely  active,  and 
when  the  front  part  of  the  body  was  in  motion  the  hind  legs  also  made 
walking  movements,  though  they  had  a  slower  rate  than  that  of  the 
front  legs.  Furthermore,  by  gently  pinching  the  tail  the  hind  legs 
could  be  induced  to  walk  when  the  front  legs  were  quiet.  In  swim- 
ming, however,  the  trunk  muscles  of  the  whole  body  moved  together. 
Loeb  (:03)  noted  similar  correlated  swimming  movements  in  Ambly- 
stoma  larv»  after  the  cord  had  been  transected.  Notwithstanding 
such  correlated  movements,  it  may  be  said  of  the  four  specimens  of 
Necturus  that  the  parts  of  the  body  in  front  of  and  behind  the  cut 
in  the  cord  carried  on  reactions  more  or  less  independently,  and  that 
the  regions  anterior  to  this  cut  responded  to  a  greater  range  of 
stimuli 

As  none  of  the  spinal  amphibians  tested  showed  sensitiveness  to 
light,  even  when  reactions  were  easily  induced  by  other  forms  of 
stimulation,  it  seems  reasonable  to  conclude  that  their  lack  of  sensi- 
tiveness to  photic  stimulation  was  not  due  to  the  absence  of  receptive 
or  motor  power,  but  to  the  fiict  that  the  ultimate  control  (centres  or 
essential  portioBS  of  reflex  arcs)  of  these  reactions  lies  in  the  brain  and 
therefore  anterior  to  the  spinal  cord. 

In  order  to  discover  what  parts  of  the  brain  were  essential  for  the 
photic  responses,  experiments  were  carried  out  in  which  certain  regions 
were  excised  and  observations  made  of  the  deficiency  phenomena  thus 
brought  about  The  method  followed  was  to  excise  all  parts  of  the 
brain  anterior  to  a  certain  region,  and  to  carry  the  regions  excised 


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198  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

progressively  backward  in  successive  operations;  the  light  reactions 
being  tested  at  each  step.  On  account  of  the  large  size  of  their 
brains,  Necturus  and  Cryptobranchus  were  used  for  these  experiments. 
The  individuals  were  wrapped  in  a  damp  cloth,  the  head  being  allowed 
to  protrude ;  and  a  T-shaped  incision  was  then  made  in  the  skin  on  the 
dorsal  side  of  the  head,  the  stem  of  the  T  being  toward  the  anterior 
end ;  after  this  the  muscles  were  cut  away  and  the  bony  roof  of  the 
cranial  cavity  carefully  picked  away  with  a  pair  of  strong  forceps. 
The  brain  was  then  cut  across  with  a  pair  of  scissors  or  a  sharp 
scalpel  and  the  parts  anterior  to  the  cut  removed.  The  flaps  of  skin 
were  drawn  over  the  wound  and  stitched  together  with  silk  thread. 
The  success  of  such  operations  was  verified  by  subsequent  dissection. 
The  method  used  in  testing  photic  reactions  was  to  throw  a  vertical 
band  of  light  (which  had  an  intensity  of  about  220  candle-meters  at  the 
point  where  the  animals  were  placed)  upon  the  anterior  or  posterior  end 
of  an  individual,  and  to  observe  the  responses  which  took  place.  As 
such  responses  were  like  those  previously  described  (p.  169),  they  need 
not  be  discussed  in  detail 

For  a  preliminary  test  as  to  the  effect  of  such  an  operation  as  has 
just  been  described,  aside  from  the  actual  cutting  of  the  brain  itself, 
the  roof  of  the  cranial  cavities  was  removed  from  four  individuals  and 
the  brain  was  left  exposed  to  the  water  in  which  they  were  kept.  These 
individuals  seemed  to  be  little  affected  by  the  operation,  as  they  swam 
and  walked  in  a  normal  manner ;  and  when  (twenty-four  hours  later) 
light  was  thrown  on  the  anterior  or  posterior  end  of  any  one  of  them, 
it  reacted  in  the  same  manner  as  an  individual  in  which  only  the  eyes 
had  been  excised*  The  exposure  of  the  brain  had,  then,  no  obvious 
effect  on  the  photic  reactions  of  Necturus. 

The  eyes  and  telencephalon  were  next  removed  fiK)m  six  individuals, 
and  five  of  them  gave  marked  responses  to  light  on  the  day  after  the 
operation.  The  other  individual,  which  lived  for  fifteen  days,  gave  no 
photic  responses  until  the  third  day  after  the  cerebral  lobes  had  been 
excised,  though  it  had  apparently  recovered  from  the  operation  before 
that  time.  These  animals  could  doubtless  have  been  kept  alive  for  a 
long  time  if  it  had  not  been  for  the  Saprolegnia  which  grew  abundantly 
around  the  cut  sur&ces,  and,  even  with  this  handicap,  one  of  them 
lived  for  fifty  days.  The  cerebral  lobes  are  not^  then,  essential  for 
the  photic  reactions  of  Necturus. 

Owing  to  the  scarcity  of  material,  the  number  of  operations  had  to 
be  limited  in  the  remaining  experiments.  The  portions  of  the  brain 
anterior  to  the  mesencephalon  were,  therefore,  excised  in  only  one 
Necturus.    This  individual  lived  for  twelve  days  and  gave  character- 


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PEABSE. — THE   REACTIONS   OF    AMPHIBIANS   TO    UGHT.         199 

istic  reactions  when  it  was  touched  gently  on  the  foot  or  tail,  or  when 
cotton  which  had  been  moistened  in  ten  per  cent  acetic  acid  was  placed 
in  the  water  near  it.  When  it  was  turned  on  its  back,  the  righting 
reaction  occurred,  though  this  was  accomplished  with  some  difficulty. 
Light,  however,  caUed  forth  no  response,  even  when  a  condensing  lens 
was  used  to  bring  the  rays  to  a  focus  on  the  skin.  The  investigations 
of  Schrader  ('87)  and  Looser  ('05)  have  demonstrated  the  teuct  that  the 
mesencephalon  exerts  an  inhibitory  influence  on  those  reflex  actions, 
that  take  place  through  the  spinal  nerves.  These  observers  found 
that  frogs  were  more  responsive  to  external  stimulation  after  the  brain 
had  been  excised  so  as  to  leave  only  the  myelencephalon  than  when 
such  an  operation  did  not  include  the  mesencephalon.  In  other  words, 
the  midbrain  had  an  inhibitory  action  on  the  reflexes  controlled  by  the 
portions  of  the  brain  posterior  to  it,  and  when  the  more  anterior  brain 
regions  (which  originate  the  "spontaneous"  reflexes)  had  been  re- 
moved it  rendered  the  frogs  unusually  sluggish.  It  is  probable  that 
the  mesencephalon  exerts  a  similar  influence  in  other  amphibians, 
and  that  the  lack  of  responsiveness  in  Necturus  was  due  to  inhibition 
rather  than  lack  of  abiUty  to  respond  to  light.  The  following  experi- 
ments support  this  view. 

The  portions  of  the  brain  anterior  to  the  metencephalon  were  re- 
moved in  two  specimens  of  Gryptobranchus.  Both  t^ese  individuals 
were  restless  and  usually  continued  to  move  about  slowly  for  some  time 
after  locomotion  had  once  been  induced  by  any  form  of  stimulation. 
When  either  of  them  was  kept  in  dim  light  for  an  hour  or  two,  however, 
it  became  quiet,  and,  if  it  was  afterwards  suddenly  illuminated  (with 
light  having  an  intensity  of  about  a  thousand  candle-meters),  there 
was  in  most  cases  an  active  locomotor  response  and  the  movement 
continued  for  some  time,  even  after  the  light  had  been  shut  off*. 

As  the  metenoephalon  is  poorly  developed  in  all  amphibians,  and  as 
it  has  been  shown  to  exert  little,  if  any,  influence  on  their  ability  to 
perform  locomotor  reactions,  it  is  safe  to  conclude  that  the  myelenceph- 
alon and  the  cord  are  the  only  portions  of  the  central  nervous  system 
which  are  essential  for  the  photic  responses. 

III.    DISCUSSION  AND  CONCLUSIONS. 

Photic  responsiveness  is  a  quality  which  is  probably  present  in  all 
amphibians,  for  the  sixteen  species  which  have  been  found  to  give  re- 
actions to  light  include  representatives  of  most  of  the  families  of  the 
class.  Light  has  an  orienting  influence  on  all  the  species  which  have 
been  studied ;  the  Caudata  are  mostly  negative  in  their  phototropism, 


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200  PROCEEDINGS   OF  THE   AMERICAN   ACADElffY. 

while  the  Salientia  are  positive.  Such  reactions  are  easily  conceived 
to  be  of  benefit  to  the  different  species  under  their  ordinary  conditions 
of  environment,  but  whether  the  different  types  of  reactions  have 
arisen  as  the  result  of  natural  selection  in  the  development  of  each 
species,  or  whether  they  are  due  to  structural  peculiarities  which  limit 
each  species  to  certain  stereotyped  reactions  and  have  hence  caused 
it  to  frequent  a  particular  habitat,  or  whether  they  have  been  brought 
about  by  other  factors,  are  open  questions.  The  negatively  photo- 
tropic  r^&ctions  of  the  nocturnfd  species  would  serve  to  bring  Uiem  into 
places  of  concealment  during  the  day.  The  positive  reactions  of  the 
more  diurnal  forms  would  lead  them  toward  the  water  (a  large  illum- 
inated area)  and  thus  £Msilitate  their  escape  from  pursuing  enemies,  or 
would  take  them  into  the  bright  sunlight^  where  inserts  were  abun- 
dant and  their  hunger  would  be  satisfied. 

Under  artificial  conditions  light  has  been  shown  to  have  a  directive 
influence  on  the  movements  of  all  the  amphibians  which  have  been 
made  the  subject  of  experiment,  but  it  does  not  foUow  that  the  pres- 
ence of  light  will  induce  motor  reactions  in  all  these  species,  and  there 
is,  in  fiict,  great  variation  between  the  different  forms  in  this  respect 
For  example,  Gryptobranchus  is  strongly  photokinetic  and  becomes 
restless  when  suddenly  illuminated,  while  Necturus  is  comparatively 
indifferent  to  such  stimulation.  This  photokinetic  quality  is  appar- 
ently little  developed  in  frogs  and  toads,  though  they  are  strongly 
phototropic.  Generally  speaking,  there  seems  to  be  no  correlation 
between  the  photokinesis  and  the  phototropism  of  amphibians. 

A  given  individual  of  any  species  is  seldom  consistently  positive  or 
negative  in  its  phototropism,  even  when  the  conditions  of  light  stimu- 
lation are  uniform.  This  may  be  due  to  the  influence  of  internal 
factors  which  bring  about  changes  in  the  physiological  state  of  the 
animal,  or  to  external  stimuli  other  than  light  which  exert  a  modifying 
influence.  Some  of  these  modifying  factors  will  be  briefly  considered, 
as  far  as  they  apply  to  the  amphibians.  Broadly  speaking,  the  habits 
of  the  different  forms  are  correlated  with  their  phototropic  responses 
and  the  species  which  are  most  truly  terrestrial  (Bufo  americanus  and 
Bana  sylvatica)  are  most  strongly  positive,  while  the  typical  aquatic 
forms  (Gryptobranchus  allegheniensis  and  Necturus  maculosus)  are  as 
decidedly  negative.  Therefore  any  variation  from  the  conditions 
found  in  the  normal  habitat  of  a  species  might  involve  changes  which 
would  alter  its  ordinary  phototropic  responses.  Previous  exposure  in 
light  or  dark  does  not  usually  exert  a  marked  influence  on  the  photic 
reactions  of  the  toad,  but  some  individuals  were  found  to  be  positive 
after  having  been  in  the  light,  though  they  were  negative  after  passing 


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PEARSE.  —  THE   REACTIONS   OF   AMPHIBIANS  TO    UGHT.        201 

a  similar  period  in  the  dark  Mechanical  stimulation  serves  to  initiate 
reactions  which  'are  directed  by  light,  but  it  produces  no  marked 
changes  in  phototropism.  Fatigue  makes  the  photic  responses  more 
difficult  to  induce  in  some  cases  (e.  g.  Cryptobranchus),  but  does  not 
alter  their  character.  These  few  examples  are  typical  and  will  serve 
to  illustrate  the  influence  of  many  fistctors  on  the  photic  reactions  of 
amphibians.  In  general  it  may  be  said  that,  while  various  &ctors  may 
give  rise  to  changed  phototropic  responses  in  some  individuals,  the 
same  factors  may  be  without  apparent  influence  in  others.  No  stimu- 
lus, with  the  possible  exception  of  decreased  temperature  (Torelle, 
:03)  has  been  demonstrated  to  produce  uniform  changes  in  the  light 
responses  of  amphibians.  The  internal  causes  which  produce  negative 
reactions  in  one  species,  or  even  in  one  individual  of  a  species,  while 
the  same  external  conditions  call  forth  positive  reactions  in  other 
species  or  individuals,  is  practically  an  untouched  field  as  £sur  as  the 
amphibians  are  concerned.  The  careful  study  of  such  a  form  as  Die- 
myctylus,  which  undergoes  marked  changes  in  habitat  during  its  life, 
ought  to  throw  light  on  at  least  one  aspect  of  this  matter. 

The  next  subject  that  deserves  consideration  is  the  nature  of  the 
photoreceptors  upon  which  the  sensitiveness  of  amphibians  to  light 
depends.  There  are  at  least  two  sets  of  nerve  terminations  which  are 
open  to  photic  stimulation,  those  of  the  retina  and  those  of  the  skin. 
The  investigation  of  the  responses  produced  by  light  received  through 
these  two  sets  of  endings  is  involved  in  considerable  difficulty,  for  we 
are  obliged  to  refer  constantly  to  judgments  formed  through  the 
human  eye.  We  are  able  to  form  opinions  as  to  the  direction,  inten- 
sity and  color  of  light,  and  to  judge  the  form,  size,  color,  position,  and 
movement  of  illuminated  objects  as  they  appear  through  our  own  eyes, 
but  we  have  no  conception  of  how  these  things  appear  when  they  are 
seen  through  the  eyes  of  an  amphibian,  except  as  we  can  interpret  its 
actions,  and  the  problem  becomes  even  more  difficult  when  we  attempt 
to  consider  the  reception  of  light  through  the  skin.  There  is  some 
evidence  that  nervous  connections  exist  in  amphibians  between  these 
two  kinds  of  photoreceptors  and  this  complicates  the  matter  still 
farther.  Englemann  QBS)  observed  that  retinal  changes  were  induced 
in  the  eyes  of  frogs  by  illuminating  the  skin.  Furthermore,  Fick  ('90) 
found  that  the  same  changes  took  place  after  the  optic  nerves  had  been 
cut,  and  connections,  if  they  exist,  must  therefore  take  some  other 
course,  in  part  at  least,  than  that  through  the  second  nerve. 

The  eyes  of  amphibians  are  adapted  for  use  in  both  air  and  water, 
and  are  hence  not  finely  adjusted  for  visual  discrimination  in  either 
medium.    Binocular  vision  cannot  be  present,  as  the  eyes  are  placed 


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202  PROCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 

laterally,  so  that  there  is  probably  no  overlapping  in  the  fields.  Nor  is 
any  definite  image  formed,  as  Beer  ('96)  has  shown  that  the  eye  cannot 
be  accommodated  to  any  extent,  and  amphibians  therefore  depend 
npon  motion  rather  than  the  form  of  objects  to  warn  them  of  danger  or 
to  enable  them  to  captare  food.  A  frog  or  toad  will  allow  a  worm  to 
lie  in  foil  view  as  long  as  it  is  qniet,  but  as  soon  as  the  worm  moves 
it  is  devoured.  The  vision  of  amphibians  is  therefore  limited  to  rather 
ill-defined  outlines  of  the  surrounding  objects,  and  the  comparative 
brightness  or  dulness,  or  possibly  the  colors,  of  objects  will  have  con- 
siderable importance  in  determining  the  nature  of  the  responses  of  an 
individual  The  reactions  brought  about  when  the  eyes  alone  are 
illuminated  are  similar  to  those  which  take  place  when  such  stimula- 
tion affects  both  the  skin  and  eyes.  When  only  one  eye  is  stimulated, 
by  light  coming  ttom  in  front  of  a  toad,  the  individual  usually  does 
not  go  toward  the  light  but  turns  toward  the  stimulated  side.  These 
beta  indicate  that  the  eyes  in  their  relations  to  objects  in  the  field  of 
vision  serve  more  as  direction  eyes  than  as  camera  eyes.  Cole  has 
recently  given  additional  support  to  this  view  by  showing  that  am- 
phibians placed  between  two  lights  of  equal  intensity  but  of  different 
areas  go  toward  the  larger  area ;  thus  demonstrating  that  the  size  of 
the  area  illuminated  is  of  importance  in  the  visual  processes.  Kiibne 
C78*)  has  shown  that  the  eye  of  the  frog  is  sensitive  to  light  rays  firom 
the  whole  range  of  the  visible  spectrum,  and  the  results  described  in 
the  present  paper,  as  well  as  those  of  other  observers  (p.  165),  indicate 
that  the  rays  toward  the  violet  end  are  most  effective  in  producing 
photic  responses.  These  apparent  differences  in  sensitiveness  to  what 
appear  to  the  human  eye  as  colors  may,  however,  be  only  differences  in 
intensity  when  received  by  the  frog's  eya 

The  skin  is  known  to  act  as  a  photoreceptor  in  ten  representative 
species  of  amphibians,  and  individuals  show  tropic  reactions  which  are 
like  those  of  animals  in  normal  condition  after  their  eyes  have  been 
excised.  There  is  no  great  differentiation  shown  in  the  structure  of 
the  qerve  endings  in  amphibians'  skins,  and  Parker  (K)3^>  p.  34)  has  al- 
ready  been  quoted  as  saying,  "  it  is  conceivable  that  in  the  lower  verte- 
brates, like  the  frog,  the  dnd  organs  of  the  skin  are  stimulated  by 
radiant  energy  of  wide  range,  including  what  is  for  us  both  heat  and 
light"  There  seems  to  be  no  doubt^  however,  that  the  amphibian 
sUn  is  sensitive  to  light  as  such,  and  no  tropic  responses  are  induced 
by  radiant  heat  having  the  same  energy  value  as  the  light  which  does 
induce  marked  tropic  reactions.  Our  knowledge  of  the  comparative 
sensitiveness  of  the  skin  in  different  regions  of  the  body  is  rather 
limited,  but  it  shows  that  there  is  no  uniformity  among  different  am- 


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PEABSE.  —  THE    REACTIONS   OF    AMPHIBIANS  TO    LIGHT.        203 

phibians  in  this  respect  Gryptobianchas  is  most  responsive  when  the 
tail  region  is  illuminated,  but  the  skin  of  the  toad  is  equally  sensitive 
on  all  parts  of  the  body. 

The  fiiot  that  both  the  skin  and  eyes  act  as  photoreceptors  in  fishes 
as  well  as  amphibians  has  led  to  considerable  speculation  concerning 
the  origin  of  the  retina  in  higher  vertebrates.  Various  theories  have 
been  put  forward,  but  only  two  of  them  have  direct  relation  to  the 
field  included  in  the  present  paper.  Willem  ('91)  advanced  the  view 
that  in  its  primitive  condition  light  sensitiveness  was  distributed  over 
the  whole  skin  and  that  it  had  become  gradually  localized  in  the  eyes 
of  higher  forms.  Parker  (.-06)  has  pointed  out  an  objection  to  this 
view  in  the  fact  that  photic  sensitiveness  is  lacking  in  the  skin  of  the 
most  primitive  member  of  the  vertebrate  series  (Amphioxus),  though 
it  possesses  direction  eyes  which  are  closely  connected  with  the  central 
nervous  organs.  He  believes  that  the  development  of  photoreceptive 
power  in  the  skins  of  vertebrates  has  been  a  separate  process  firom  that 
of  the  development  of  the  retinas,  which  first  arose  in  intimate  connec- 
tion with  the  central  nervous  system.  This  question  cannot  be  re- 
garded as  definitely  settled,  and  the  results  of  the  experiments 
described  in  the  present  paper  throw  little  light  upon  it  The  fact 
that  photic  sensitiveness  is  present  in  such  a  wide  range  of  amphib* 
ians  seems  to  support  Willem's  view,  as  the  different  forms  have 
developed  along  extremely  diverse  lines. 

Not  only  do  the  photoreceptive  organs  constitute  important  factors 
in  a  consideration  of  the  photic  reactions  of  amphibians,  but  variations 
in  the  light  itself  are  important  Differences  in  intensity  are  signifi- 
cant in  the  reactions  of  the  toad,  for  the  percentage  of  positively  pho- 
totropic  responses  decreases  and  the  number  of  indifferent  reactions 
increases  when  the  light  intensity  is  decreased.  The  direction  of  the 
incident  rays  of  light  which  impinge  on  the  photoreceptor  is,  however, 
of  no  apparent  consequence.  A  toad  in  which  only  one  eye  is  illumi- 
nated by  light  firom  in  firont  turns  toward  the  stimulated  side  instead 
of  going  toward  the  light,  and  ai^  eyeless  toad  subjected  to  unilateral 
stimulation  by  light  from  above  turns  toward  the  illuminated  side 
without  regard  to  the  direction  of  the  rays.  In  general,  then,  the 
photic  reactions  of  amphibians  are  brought  about  by  intensity  differ- 
ences on  the  two  sides  of  the  body.  Concerning  the  influence  of  the 
quality  of  the  light,  it  may  be  said  that  both  the  skin  and  eyes  of  am- 
phibians are  open  to  stimulation  by  light  rays  which  include  the  whole 
range  of  the  visible  spectrum.  When  the  light  is  received  through 
both  the  eye  and  skin  receptors,  the  rays  toward  the  violet  end  of  the 
spectrum  are  most  effective  in  producing  tropic  responses,  but  when 


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204  PROCEEDINGS    OF   THE   AMERICAN   ACADEMY. 

the  light  is  received  through  the  skin  alone,  no  such  potency  is  shown 
by  the  more  refrangible  rays.  The  differences  observed  in  the  first 
case  may  therefore  be  interpreted  as  being  due  to  stimalation  received 
through  the  eyes,  and  we  may  conclude  that  the  power  of  color  per- 
ception, as  distinct  firom  light  perception,  is  present  in  the  eyes  but 
alj^nt  in  the  skin.  It  is  not  certain,  however,  that  these  differences, 
which  are  supposedly  due  to  differences  in  wave  length,  are  not^  after 
all,  brought  about  by  intensity  differences. 

Generally  speaking,  the  parts  of  the  central  nervous  system  are 
segmentaUy  arranged  throughout  the  vertebrate  series.  Each  neural 
segment  is,  however,  capable  of  carrying  on  only  the  comparatively 
simple  reflex  actions  which  are  concerned  with  the  somatic  segment 
which  it  controls.  The  complex  reactions  which  involve  correlated 
movements  in  different  regions  of  the  body  depend  upon  correlation 
centres,  and,  the  higher  we  go  in  the  vertebrate  scale,  the  more  these 
centres  become  localized  toward  the  anterior  end  of  the  nervous  tube. 
A  spinal  eel  is  able  to  swim  in  a  normal  manner  (Bickell,  '97),  but  in 
the  higher  vertebrates  spinal  reactions  show  less  correlative  power,  and 
there  is  a  correspondingly  greater  importance  attached  to  those  reac- 
tions which  are  controlled  through  Uie  brain.  The  buot  that  spinal 
fishes  react  to  light  (Parker,  :03>>),  while  spinal  amphibians  do  not,  is 
therefore  perhaps  to  be  expected  and  may  be  interpreted  as  new  evi- 
dence of  the  progressive  anterior  localization  of  functions  in  the  nervous 
system  of  vertebrates.  However,  Sherrington  (:06,  p.  9)  has  called 
attention  to  the  &ct  that  only  stimuli  of  a  particular  kind  will  evoke 
certain  reflexes.  He  was  easily  able  to  induce  the  croak  reflex  in  a 
spinal  frog  by  certain  forms  of  stimulation,  but  he  could  not  evoke  it  by 
others,  and  he^  also  found  that  the  scratch  reflex  could  be  called  forth 
in  spinal  dogs  by  certain  forms  of  tactual  stimulation  only.  It  is 
therefore  possible  that  spinal  amphibians  may  yet  be  induced  to  give 
photic  reactions  under  some  new  method  of  stimulation.  As  far  as 
the  present  evidence  goes,  however,  the  myelencephalon,  as  well  as 
the  cord,  is  essential  for  photic  responses  in  which  the  skin  is  the 
receptor. 

In  the  reactions  of  many  organisms  the  ultimate  direction  of 
locomotion  is  determined  by  making  many  random  movements  and 
following  such  of  them  as  lead  away  from  conditions  un&vorable  to 
the  organism  or  into  conditions  better  adapted  to  its  existence.  Other 
organisms  do  not  make  great  use  of  this  method,  but  usually  move 
directly  toward  or  away  from  the  source  of  stimulation,  and  Loeb  ('90) 
has  given  the  name  of  tropism  to  such  responses.  The  light  reactions 
of  amphibians  are  characteristicaUy  tropic  in  nature,  and,  as  has  been 


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PEABSE. — THE   REACTIONS   OF    AMPHIBIANS  TO    UGHT.        205 

stated,  they  are  apparently  broaght  about  by  unequal  stimulation  on 
the  two  sides  of  the  body.  This  tropic  character  applies  to  the  reac- 
tions whether  they  are  induced  by  stimulation  through  the  skin  or 
eyes  or  through  the  simultaneous  stimulation  of  both.  In  general,  it 
may  be  said  that  the  photic  responses  are  of  a  typically  reflex  character 
and  show  little  evidence  of  powers  of  association. 

IV.  SUMMARY. 

(1)  The  following  amphibians  were  found  to  be  positively  photo- 
tropic:  Diemyctylus  viridesoens,  Rana  clamata,  R.  palustris,  Bufo 
fowleri,  B.  americanus ;  and  the  negatively  phototropic  species  studied 
were :  Necturus  maculosus,  Cryptobranchus  allegheniensis,  Ambly- 
stoma  punctatum,  Plethodon  cinereus  er3rthronotu8. 

(2)  Most  of  the  species  mentioned  under  (1),  after  the  removal  of 
their  eyes,  gave  photic  responses  which  were  like  those  of  normal 
individuals. 

(3)  The  photic  reactions  of  eyeless  amphibians  are  not  due  to  the 
direct  stimidation  of  the  central  nervous  system  or  the  exposed  ends 
of  the  optic  nerves  by  lights  but  to  the. action  of  the  skin  as  a 
photoreceptor. 

(4)  Mechanical  stimulation  (handling)  does  not  change  the  charac- 
ter of  the  photic  reactions,  though  it  makes  them  more  evident  by 
inducing  locomotion. 

(5)  Toads  which  are  stimulated  by  light  through  the  eyes  alone 
react  in  the  same  manner  as  individuals  stimulated  through  the  skin 
or  through  both  the  skin  and  the  eyes. 

(6)  The  movements  of  eyeless  toads  stimulated  unilaterally  by  light 
from  above  are  toward  the  illuminated  side;  and  toads  stimulated 
through  one  eye  only  by  light  from  in  front  do  not  go  toward  the  light 
but  turn  toward  the  illuminated  side.  The  photic  reactions  are  there- 
fore due  to  differences  in  light  intensity  on  the  two  sides  of  the  body 
and  the  direction  of  the  rays  is  ineffective. 

(7)  After  the  eyes  have  been  removed,  Cryptobranchus  and  Nec- 
turus are  most  responsive  when  the  tail  is  illuminated,  but  the  skin  of 
the  toad  is  apparently  of  equal  sensitiveness  on  all  parts  of  the  body. 

(8)  A  prolonged  period  of  time  passed  in  light  or  dark  had  no 
effect  on  the  nature  of  the  phototropic  responses  of  the  toad. 

(9)  Cryptobranchus  is  strongly  photokinetic,  but  in  the  other  am- 
phibians tested  this  quality  was  not  strongly  developed. 

(10)  When  normal  amphibians  were  used,  blue  light  was  the  most 
effective  in  the  production  of  tropic  responses,  but  when  eyeless  indi- 


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206  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

viduals  were  tested  with  the  same  oolored  lights,  the  rays  toward  the 
blue  end  of  the  spectrum  showed  no  such  potency  as  compared  with 
those  nearer  the  opposite  end.  It  may  be  said  that,  while  both  the 
skin  and  eyes  are  sensitive  to  the  whole  range  of  the  visible  spectrum, 
color  sensitiveness  is  present  only  in  the  latter.  It  is  possible,  how- 
ever, that  the  supposed  color  sensitiveness  is  due  to  the  efiects  of  what 
are  intensity  differences  to  the  amphibian  eye. 

(11)  A  decrease  in  the  intensity  of  the  light  brings  about  a  corre- 
spondingly smaller  number  of  positively  phototropic  responses  and  an 
increase  in  the  number  of  indifferent  reactions. 

(12)  The  phototropic  responses  of  eyeless  toads  are  not  due  to 
the  stimulation  of  heat-receiving  organs  in  the  skin.  Thermo-  and 
photo-reception  are  separate  processes,  and  the  former  does  not  readily 
give  rise  to  tropic  reactions. 

(13)  Spinal  amphibians  gave  no  photic  responses,  but  such  reactions 
were  induced  in  animals  in  which  the  brain  anterior  to  the  meten- 
cephalon  had  been  excised. 


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Thiere.    Prag,  Leipzig,  viii  +  322  pp. 
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Psychol.,  Vol.  15,  No.  4,  pp.  305-349. 
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'93.  The   Habits  and  Development  of  the  Newt  (Diemyctylus  viri- 
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Prooeedings  of  fhe  Amerioan  Academy  of  Arte  and  Sdenoes. 
Vol.  XLV.  No.  7.  — January,  1910. 


AVERAGE  CHEMICAL  COMPOSITIONS  OF 
lONEOUS-ROCK   TYPES. 


Bt  Reginaij)  Aldwobth  Dalt. 


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AVERAGE  CHEMICAL  COMPOSITIONS  OP  laNEOUS-ROCK 

TYPES. 

By  Reginald  Aldwobth  Daly. 
Praseated  December  8, 1000;  Reoehred  Deoember  4, 1000. 

CONTBKTa 

Introduction:  Purpose  of  the  Paper 211 

Method  of  Calculation 213 

Sources  of  Information 214 

Average  Specific  Gravities  of  Certain  Types 235 

Some  Applications    •   .   . 235 

Iktboduction:  Pueposb  of  the  Paper. 

The  study  of  the  igneous  rocks  has  hitherto  largely  consisted  in  an 
analj^is  of  their  mineralogical  and  chemical  composition,  with  the 
special  intent  to  produce  a  satis&otory  nomenclature  and  classification 
of  the  rocks  as  they  occur  throughout  the  world.  This  systematic  ' 
petrography,  though  still  pursued  by  a  great  number  of  workers,  is 
now  rivaled  in  interest  and  excelled  in  importance  by  its  own  ofishoot, 
petrogeny.  The  science  of  the  origm  and  history  of  the  igneous 
rocks  is  reacting  on  the  more  purely  descriptive  subject^  and  at  present 
petrologists  are  feeling  their  way  toward  a  genetic  classification  of 
this  great  series  of  rock-types.  Meantime,  the  much  more  numerous 
dass  of  workers  engaged  on  the  problems  of  economic  and  general 
geology,  of  geochemistry  and  cosmogony,  are  raising  highly  important 
questions  which  belong  to  the  field  of  petrogenesis.  The  problems 
thus  raised  are  as  fundamental  as  they  are  complex  and  difficult  For 
many  of  their  solutions  recourse  must  be  had  to  the  more  modern 
geological  reports  and  maps.  With  ever  increasing  skill  and  accuracy 
the  distribution  and  relations  of  the  rodcs  composing  the  earth's  crust 
are  being  recorded  by  government  officers  and  by  geologists  working  in 
private  capacity.  For  some  thirty  years  past^  as  at  present,  the  great 
body  of  geologists  have  mi^ped  and  deiBoribed  the  igneous  rocks  in* 
terms  of  what  may  be  called  the  Qerman  system  of  nomenclature  and 
definition.    In  particular,  Boaenbasoh's  monumental  treatises  on  the 


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212  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

eruptive  rocks  have  been,  for  a  generation,  the  osaal  guide  to  the  many 
authors  who  have  described  their  findings  among  the  igneous  terranes 
of  the  world. 

In  view  of  these  &ct6  it  is  clear  that  a  student  in  petrology  who 
wishes  to  use  the  maps  and  memoirs  should  have  a  good  conception  of 
the  rock-types  recognized  by  Rosenbusch  and  by  his  hundreds  of  dis- 
ciples among  the  field-geologists.  It  is  true  that  in  some  details  the 
usages  of  master  and  followers  as  regards  names  and  classification  have 
varied,  but  in  a  broad  way  Roeenbusch's  definitions  of  the  principal 
&milies  and  species  of  massive  rocks  have  been  used  for  maps  and 
reports  in  all  regions  where  modem  work  on  igneous  geology  has  been 
dona  Just  as  the  general  sequence  of  the  stratified  rocks  as  first  de- 
scribed in  England,  France,  and  Germany  has  been  found  to  be  closely 
paralleled  in  the  rest  of  Europe  and  in  the  other  continents,  so  the 
sjTstem  of  igneous  rocks  as  at  first  developed  from  material  largely 
collected  in  Europe  has  been  nearly  sufficient  for  the  mapping  of  those 
rocks  elsewhere.  In  the  field  as  in  the  library  the  geologist  soon 
learns  that  there  is  a  persistent  recurrence  of  types  in  the  larger  divi- 
sions of  the  earth's  surfiice.  The  usefulness  and  objective  character 
of  Rosenbusch's  classification  are,  therefore,  proved  by  its  adaptability 
in  all  the  continents  and  islands. 

Rosenbusch  and  his  followers  recognize  some  latitude  of  variation  in 
the  composition  of  each  rock-typa  The  variation  is  both  mineralog- 
ical  and  chemical,  two  rock  specimens  referred  to  a  type  showing 
differences  in  the  proportions  of  the  chemical  elements  found  by  analy- 
sis of  the  two  rocks.  In  &ct,  no  two  analyses  of  granite,  andesite,  or 
any  other  one  type  have  ever  given  precisely  the  same  proportions  of 
the  dozen  or  more  oxides  which  regularly  make  up  an  igneous  rock. 
It  is  obvious  that  the  student  of  map  and  memoir  should,  for  many 
problems,  have  at  hand  the  actual  figures  showing  the  most  typical 
chemical  composition  of  the  rock-types  to  which  his  study  is  directed. 
In  numerous  cases  an  analysis  of  a  single  specimen  is  not  so  useful  as 
that  which  could  be  made  from  a  thorough  mixture  of  specimens  of  the 
same  rock-variety  fix)m  all  places  on  the  globe  where  that  variety 
occurs. 

For  obvious  reasons  such  ideal  analjrses  have  never  been  made.  In 
their  stead  the  writer  believes  that  the  investigator  of  petrogenic  and 
other  world-problems  may  well  use  the  averages  calculated  fix)m  the 
many  excellent  chemical  analjrses  of  rocks  made  since  Rosenbusch's 
system  of  naming  and  classification  has  been  in  general  use.  It  may, 
indeed,  be  argued  that  such  averages  would  more  nearly  represent  the 
chemistry  of  Rosenbusch's  types  than  any  of  the  respective  single 


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DALY.  —  COMPOSITIONS   OF    IGNEOUS-ROCK  TYPES.  213 

analysis  which  he  has  published  in  his  treatise.  These  averages  would 
be  chemical  "  center-points  "  in  his  system  of  classification  as  actvaliy 
appUed  to  the  terranes  of  the  world. 

So  &r  as  the  writer  is  aware,  the  preparation  of  these  averages  has 
not  hitherto  been  attempted  to  such  an  extent  as  to  cover  the  chief 
&milies  and  species  of  igneous  rocks.  An  approximation  to  the 
desired  results  is  offered  in  the  following  tables. 

The  work  of  computing  the  averages  has  been  lessened  very  greatly 
by  the  publication  of  Osann's  "  Beitrage  zur  chemischen  Petrographie  " 
(2nd  part,  Stuttgart^  1905).  This  remarkable  book  contains,  in  con- 
venient arrangement,  the  statement  of  most  of  the  eruptive-rock 
analyses  (over  2400  in  number)  puUished  in  the  interval  between 
1883  and  1901.  The  period  of  seventeen  years  lies  within  that  during 
which  systematic  petrography  has  been  dominated  by  Rosenbusch's 
names  and  definitions.  In  general,  the  number  of  analyses  for  each 
rock-species  is  so  large  that  their  average  would  be  but  slightly  modi- 
fied by  the  inclusion  of  the  analyses  made  since  1900.  In  many  cases, 
therefore,  the  extended  labor  required  to  search  out  firom  the  literature 
the  additional  analyses,  has  not  been  considered  necessary  for  the 
preparation  of  useful  averages.  For  other  averages  it  was  necessary 
to  include  analjrses  published  since  1900.  The  sources  of  such  infor- 
mation are  indicated  below.  Fortunately  for  the  purpose,  nearly  the 
entire  period  since  1884  has  seen  the  application  of  more  or  less  re- 
fined methods  of  analysis ;  so  that  errors  of  observation  for  the  leading 
oxidee  are  relatively  small 

Method  op  Calculation. 

The  method  of  computation  used  is  essentially  like  that  employed 
by  Washington  and  Clarke  in  their  respective  calculations  of  the 
"average  composition"  of  all  igneous  rocks.  In  general,  only  the 
twelve  more  important  oxides  (including  MnO)  are  recognized  in 
the  following  tables.  Distinctly  "  inferior  "  analyses  were  not  consid- 
ered. In  each  case  the  average  was  computed  according  to  the  actual 
numbers  of  determinations  made  by  the  analysts.  Table  L  shows 
these  numbers  for  the  respective  rock-types,  each  column  being  headed 
by  a  key-number  which  corresponds  with  the  named  types  of  Table  II. 
For  some  of  the  rocks  BaO  and  SrO  were  computed.  Their  sum 
appears  in  the  averages  for  CaO,  as  indicated  in  the  tables.  Similarly 
COs  and  CrsOg  were  sometimes  averaged  and  entered  with  HsO  and 
FcsOt  respectively.  As  expected  firom  the  method  employed,  the 
average  totals  nearly  always  ran  well  over  one  hundred  per  cent    All 


Digitized  by  LjOOQIC 


214  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

averages  were  reduced  to  100.00  per  cent  and  entered  in  Table  II. 
Each  average  analysis  was  then  recalcolated  to  100.00  per  cent  after 
HgO  (and  GOg)  had  been  subtracted.  The  results  are  also  given  in 
Table  IL,  in  which  platonics  and  corresponding  effasives  are  grouped 
together.  Magmatic  relationships  are  often  less  obscured  if  these 
volatile  oxides,  which  may  be  wholly  or  in  part  of  exotic  nature,  are 
excluded.  Finally,  in  order  to  facilitate  reference  to  the  tables,  an 
index  to  the  different  rock-types  was  prepared  and  may  be  found 
below  Table  II. 

It  will  be  observed  that  certain  rock-types  have  be^  omitted  from 
the  tables.  The  large  class  of  "  aschistic  "  dike-rocks  is  not  rq>reeented 
because  of  their  chemical  similarity  to  the  corresponding  plutonio 
species.  Other  named  varieties  are  omitted  since  their  analyses  are 
too  few  to  give  useful  averages.  In  a  few  cases  the  mineralogical  and 
chemical  variations  within  each  variety  are  so  great  that  it  has  not 
seemed  advisable  to  regard  their  averages  as  worthy  of  entry.  Many 
other  subordinate  varieties  of  rock,  though  given  special  names,  are 
chemically  ahnost  identical  with  the  more  important  typed  entered  in 
the  tables  and  therefore  have  been  excluded. 

Sources  of  Information. 

The  immediate  sources  of  the  analytical  statements  used  in  the 
computations  are  as  follows  :  — 

1.  Beitrage  zur  chemischen  Petrographie,  zweiter  Teil,  by  A.  Osann. 

Stuttgart^  1905. 

2.  Chemical  Analyses  of  Igneous  Rocks  published  from  1884  to  1900, 

by  a  S.  Washington.    Pro£  Paper,  Na  14,  U.  a  Geological 
Survey,  1903. 

3.  Elemente   der  Gesteinslehre,  2nd  edition,   by  H.   BosenbuscL 

Stuttgart,  1901. 

4.  Lehrbuch  der  Petrographie,  2nd  edition,  by  F.  ZarkeL    Leipzig, 

1893. 

5.  Studien  liber  die  Oranite  von  Schweden,  by  P.  J.  Holmquist.    BulL 

Geol.  Institution,  University  of  Upsala,  VoL  7, 1906,  p.  76. 

6.  Some  Lava  Flows  of  the  Western  Slope  of  the  Sierra  Nevada,  Cal- 

ifornia, by  F.  L.  Ransome.    Amer.  Jour.  Science,  VoL  5,  1898, 
p.  355. 

7.  Mat^riaux  pour  la  Min^ralogie  de  Madagascar.     Nouv.  Archives 

du  Museum,  (4),  VoL  -5,  Paris,  1903. 
a  Geology  of  the  Yellowstone  National  Park,  by  A.  Hague  and 
others.    Petrography  by  J.  P.  Iddings.    Monograj^  No.  32, 
Part  2,  U.  S.  Geological  Survey,  1899. 


Digitized  by 


G( 


DALT.  —  COMPOSITIONS   OF   lONEOUS-ROCK  TYPES.  215 

9.  Analyses  of  Rooks  from  the  Laboratory  of  the  United  States  (Geo- 
logical Survey,  1880  to  1903,  by  F.  W.  Clarke.  Bulletin  228 
of  the  Survey,  1904. 

10.  Geological  and  Petrographical  Studies  of  the  Sudbury  Nickel  Dis- 

trict, by  T.  L  Walker,  Quart  Jour.  GeoL  Soc,  Vol.  53,  1897, 
p.  40. 

11.  Petrography  and  Geology  of  the  Igneous  Rocks  of  the  Highwood 

Mountains,  Montana,  by  L  V.  Pirsson.     Bull  237,  U.  S.  Geo- 
lo^cal  Survey,  1905. 

12.  (Geology  of  the  North  American  Cordillera  at  the  Forty-ninth 

Parallel,  by  R.  A.  Daly  (forthcoming ;  analyses  by  M.  F.  Con- 
nor and  M.  Dittrich  used  in  calculating  some  averages). 
The  sources  of  the  analjrses  used  in  each  average  are  indicated  by  the 
authors'  names  at  the  head  of  the  corresponding  colunms  in  Table  II. 


Digitized  by  VjOOQIC 


216 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMT. 


TABLE  I. 

Showino  the  Number  of  Separate  Determinations  used  in  computing 
THE  Average  Quantity  of  each  Oxide  in  each  Rock-ttpe. 


1 

2 

8 

4 

6 

6 

7 

■^H 

9 

10 

U 

12 

18 

14 

16 

16 

SiO, 

47 

114 

184 

236 

64 

24 

40 

50 

7 

5 

8 

23 

50 

48 

7 

13 

TiO, 

22 

74 

60 

87 

40 

10 

30 

20 

6 

4 

6 

14 

36 

26 

6 

6 

A1.0, 

47 

114 

180 

232 

63 

23 

40 

49 

7 

6 

8 

23 

49 

48 

13 

Fe.0. 

36 

101 

118 

168 

61 

22 

39 

32 

4 

6 

3 

16 

43 

38 

10 

FeO 

36 

101 

118 

168 

42 

6 

36 

32 

4 

6 

3 

14 

43 

38 

10 

BInO 

24 

86 

64 

93 

32 

4 

28 

20 

4 

6 

6 

14 

38 

34 

6 

MgO 

47 

114 

184 

236 

63 

24 

39 

49 

6 

6 

8 

22 

60 

48 

13 

CaO 

47 

114 

184 

236 

64 

24 

40 

49 

6 

6 

8 

22 

50 

48 

13 

Na,0 

47 

108 

182 

234 

63 

24 

39 

49 

6 

6 

8 

22 

50 

48 

13 

K,0 

47 

108 

182 

234 

63 

24 

39 

49 

6 

6 

8 

21 

50 

48 

13 

H,0 

38 

40 

41 

41 

17 

16 

17 

39 

7 

3 

8 

21 

41 

44 

10 

PA 

16 

34 

73 

81 

27 

4 

23 

17 

3 

3 

7 

34 

26 

4 

BaO 

8 

36 

36 

SrO 

5 

•• 

21 

21 

•• 

•• 

•• 

•• 

•• 

•• 

•• 

•• 

17 

18 

19 

ao 

21 

22 

28 

24 

26 

26 

27 

28 

29 

80 

81 

82 

SiO, 

T 

7 

12 

10 

10 

3 

3 

43 

26 

4 

8 

12 

30 

20 

89 

"to 

TiO, 

10 

10 

4 

3 

30 

16 

3 

12 

16 

16 

71 

67 

A1.0. 

3 

7 

12 

10 

10 

3 

3 

43 

26 

4 

8 

12 

30 

20 

89 

70 

Fe,0. 

3 

!' 

(12 

10 

6 

3 

3 

30 

18 

2 

2 

12 

24 

18 

86 

69 

FeO 

2 

^2 

10 

6 

3 

2 

30 

18 

2 

2 

12 

24 

18 

86 

69 

BInO 

10 

10 

4 

3 

2 

30 

16 

1 

3 

12 

14 

11 

66 

63 

MgO 

3 

7 

12 

10 

10 

3 

3 

41 

26 

4 

8 

12 

30 

20 

89 

70 

CaO 

3 

7 

12 

10 

10 

3 

3 

43 

26 

4 

8 

12 

30 

20 

89 

70 

Na,0 

3 

7 

12 

10 

10 

3 

3 

43 

25 

4 

8 

12 

30 

20 

86 

67 

K.0 

3 

7 

12 

10 

10 

3 

3 

43 

26 

4 

8 

12 

30 

20 

86 

67 

H,0 

3 

7 

9 

10 

10 

3 

1 

26 

23 

4 

6 

12 

30 

17 

47 

36 

PA 

1 

•• 

12 

10 

4 

3 

14 

16 

•• 

1 

12 

16 

^ 

71 

67 

Digitized  by  LjOOQIC 


DALT.  —  COMPOSITIONS   OF   IGNEOUS-ROCK  TYPES. 


217 


TABLE  l,^  Continued, 


33 

34 

36 

36 

37 

38 

39 

40 

41 

42 

Is 

44 

46 

46 

47 

48 

SiO, 

87 

33 

20 

24 

10 

7 

41 

198 

161 

20 

17 

11 

9 

24 

17 

5 

TiO, 

51 

16 

13 

13 

9 

6 

26 

132 

113 

13 

6 

5 

8 

16 

10 

4 

A1.0, 

87 

33 

20 

24 

10 

6 

41 

197 

160 

20 

17 

11 

9 

24 

17 

4 

FeiO, 

71 

25 

18 

18 

10 

7 

36 

174 

146 

18 

14 

5 

9 

21 

15 

5 

FeO 

71 

25 

18 

18 

10 

7 

36 

173 

146 

18 

14 

5 

8 

21 

15 

5 

BInO 

44 

16 

14 

8 

6 

6 

28 

108 

96 

13 

6 

2 

4 

15 

13 

4 

MgO 

87 

33 

20 

24 

10 

7 

40 

197 

160 

20 

17 

11 

9 

24 

16 

5 

CaO 

87 

33 

20 

24 

10 

7 

41 

198 

161 

20 

17 

11 

9 

24 

17 

5 

Na,0 

84 

32 

20 

22 

10 

7 

40 

190 

154 

20 

16 

11 

9 

24 

16 

5 

K,0 

84 

32 

20 

22 

10 

7 

39 

190 

154 

20 

16 

11 

9 

23 

16 

5 

H,0 

67 

5 

18 

24 

10 

6 

17 

55 

27 

16 

1 

5 

2 

12 

5 

4 

PA 

47 

14 

13 

11 

9 

6 

27 

135 

116 

14 

6 

4 

9 

16 

11 

4 

48 

60 

61 

62 

63 

64 

66 

66 

67 

68 

69 

60 

61 

62 

63 

64 

SiO, 

2 

12 

4 

3 

4 

3 

4 

49 

3 

11 

4 

7 

6 

6 

6 

TiO, 

2 

4 

1 

3 

2 

27 

11 

2 

3 

3 

2 

6 

A1.0. 

2 

12 

4 

3 

2 

4 

49 

3 

11 

4 

7 

6 

6 

6 

Fe,0. 

2 

10 

4 

3 

2 

4 

40 

3 

10 

2 

2 

5 

6 

6 

FeO 

2 

10 

4 

3 

3 

4 

40 

3 

10 

4 

2 

5 

6 

6 

MnO 

2 

3 

4 

3 

1 

3 

32 

6 

4 

4 

MgO 

2 

12 

4 

3 

3 

4 

47 

3 

11 

4 

7 

6 

6 

6 

CaO 

2 

12 

4 

3 

1 

4 

49 

3 

11 

4 

7 

6 

6 

6 

Na,0 

2 

12 

3 

3 

1 

4 

31 

3 

11 

4 

7 

6 

6 

6 

K,0 

2 

12 

2 

3 

4 

31 

3 

11 

4 

7 

6 

6 

6 

H,0 

2 

7 

4 

3 

4 

3 

3 

47 

3 

10 

2 

7 

4 

6 

6 

PaO, 

2 

1 

1 

3 

..  1 

2 

25 

3 

11 

2 

2 

2 

2 

6 

Digitized  by 


Goo 


^' 


218 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


TABLE  1.^  Continued. 


66 

66 

67 

68 

68 

70 

71 

72 

78 

76 

76 

77 

78 

79 

80 

81 

SiO, 

24 

20 

4 

20 

16 

4 

2 

7 

6 

9 

26 

3 

10 

4 

10 

•no. 

8 

14 

4 

4 

11 

3 

2 

2 

5 

3 

23 

3 

10 

4 

9 

A1.0, 

24 

20 

4 

20 

16 

4 

2 

6 

9 

26 

3 

10 

4 

10 

Fe.0. 

22 

19 

3 

19 

16 

4 

2 

5 

3 

25 

3 

10 

4 

10 

FeO 

22 

19 

3 

19 

16 

4 

2 

6 

3 

25 

3 

10 

4 

10 

MnO 

14 

7 

1 

13 

6 

2 

2 

6 

4 

16 

3 

10 

1 

10 

MgO 

24 

20 

4 

20 

16 

4 

2 

6 

9 

26 

3 

10 

4 

10 

CaO 

24 

20 

4 

20 

16 

4 

2 

6 

9 

26 

3 

10 

4 

10 

Na,0 

24 

20 

4 

20 

16 

4 

2 

6 

9 

26 

3 

10 

4 

10 

K.0 

24 

20 

4 

20 

16 

4 

2 

5 

9 

26 

3 

10 

4 

10 

H,0 

9 

18 

3 

6 

16 

3 

2 

3 

4 

5 

25 

3 

10 

4 

10 

PA 

19 

9 

3 

16 

8 

1 

2 

6 

2 

4 

6 

23 

3 

10 

4 

9 

82 

83 

84 

86 

86 

87 

88 

89 

90 

91 

92 

93 

94 

96 

96 

97 

98 

SiO, 

8 

5 

2 

6 

15 

5 

5 

8 

16 

10 

20 

15 

16 

6 

TiO, 

8 

5 

2 

6 

9 

2 

3 

7 

9 

8 

16 

10 

12 

5 

A1.0. 

8 

5 

2 

6 

16 

5 

6 

8 

16 

10 

19 

16 

16 

6 

Fe.0, 

8 

5 

2 

6 

11 

2 

4 

8 

10 

8 

16 

10 

14 

5 

FeO 

8 

6 

2 

6 

10 

2 

3 

8 

9 

8 

16 

10 

14 

5 

MnO 

8 

5 

2 

8 

1 

4 

8 

9 

7 

17 

8 

9 

2 

MgO 

8 

5 

2 

6 

16 

4 

6 

8 

16 

10 

20 

15 

16 

6 

CaO 

8 

5 

2 

6 

16 

5 

6 

8 

16 

10 

20 

15 

16 

6 

Na,0 

8 

5 

2 

6 

16 

6 

5 

8 

15 

10 

20 

15 

16 

5 

K,0 

8 

5 

2 

6 

15 

5 

6 

8 

16 

10 

20 

15 

15 

5 

H,0 

6 

8 

6 

2 

6 

11 

2 

3 

7 

10 

10 

19 

10 

16 

3 

P.O. 

8 

8 

5 

2 

6 

7 

•• 

7 

5 

7 

18 

6 

11 

3 

Digitized  by  VjOOQIC 


DALY.  —  COMPOSITIONS   OF   IGNEOUS-EOCK  TYPES. 


219 


TABLE   n. 
Showinq   thb  Avesaqb  Compositions  calculated  fob  the  PRiNaPAL 

lONEOUft-BOCK  TyFES. 

GROUP  I. 


No.  of 
Analyses. 


Pldtonicb. 


47 


114 


184 


236 


ErFDuvss. 


64 


24 


•8 

y 

■'I 


i- 


40 


50 


SiO, 

TiO, 

A1.0, 

Fe.0, 

FeO 

MnO 

MgO 

CaO 

Na,0 

K,0 

H,0 

PA 


71.06 

.48 

14.10 

1.46 

1.63 

.18 

.59 

1.97  > 

3.24 

4.50 

.69 

.10 


69.81 

.54 

13.76 

2.17 

1.87 

.26 

.84 

2.20 

3.17 

4.38 

.74 

.26 


69.73 

.34 

14.98 

1.62 

1.66 

.11 

1.08 

2.20* 

3.28 

3.95 

.78 

.27 


69.92 

.39 

14.78 

1.62 

1.67 

.13 

.97 

2.15 

3.28 

4.07 

.78 

.24 


72.60 

.30 

13.88 

1.43 

.82 

.12 

.38 

1.32 

3.54 

4.03 

1.52 

.06 


72.90 

.48 

14.18 

1.65 

.31 

.13 

.40 

1.13 

3.54 

3.94 

1.33 

.01 


72.62 

.25 

13.77 

1.29 

.90 

.12 

.38 

1.43 

3.55 

4.09 

1.63 

.07 


72.36 

.33 

14.17 

1.55 

1.01 

.09 

.52 

1.38 

2.85 

4.56 

1.09 

.09 


Calculated  as  Water-free. 


SiO, 

71.66 

70.33 

70.28 

•no. 

.48 

.64 

.34 

A1.0, 

14.20 

13.86 

16.10 

FeiO. 

1.47 

2.19 

1.63 

FeO 

1.65 

1.89 

1.67 

BinO 

.18 

.26 

.11 

MgO 

.59 

.86 

1.09 

CaO 

1.98' 

2.22 

2.22 

Na,0 

3.26 

3.19 

3.31 

K,0 

4.53 

4.41 

3.98 

PA 

.10 

.26 

.27 

70.47 

.39 

14.90 

1.63 

1.68 

.13 

.98 

2.17 

3.31 

4.10 

.24 


73.72 

.30 

14.10 

1.45 

.83 

.12 

.40 

1.34 

3.69 

4.09 

.06 


73.89 

.49 

14.37 

1.67 

.31 

.13 

.41 

1.14 

3.59 

3.99 

.01 


73.75 

.25 

13.99 

1.31 

.91 

.12 

.39 

1.45 

3.60 

4.16 

.07 


73.16 

.33 

14.33 

1.57 

1.02 

.09 

.63 

1.39 

2.88 

4.61 

.09 


Each  sum  -  100.00. 


Includes  .08%  BaO  and  .01%  SrO. 
Includes  .06%  BaO  and  .02%  SrO. 
Includes  .06%  BaO  and  .02%  SrO. 


Digitized  by  LjOOQIC 


220 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


GROUP   II. 


No.  of 
Analyses. 

Plctonics. 

Effusives.             I 

9 

10 

11 

12 

13 

14 

16 

16 

i| 

11 

1 

a 

1 

.  "ill 

Iff 

1 

k 

Ji 

1] 

7 

5 

8 

23 

50 

48 

7 

13 

SiO, 

64.36 

61.86 

61.96 

61.99 

60.19 

60.68 

61.51 

75.45 

TiO, 

.46 

.16 

.99 

.56 

.67 

.38 

.45 

.17 

AlaO, 

16.81 

19.07 

17.07 

17.93 

16.28 

17.74 

17.37 

13.11 

Fe,0, 

1.08 

2.66 

2.36 

2.22 

2.74 

2.64 

1.92 

1.14 

FeO 

2.71 

1.49 

3.37 

2.29 

3.28 

2.62 

3.35 

.66 

MnO 

.15 

.01 

.09 

.08 

.14 

.06 

.01 

.29 

MgO 

.72 

.66 

1.38 

.96 

2.49 

1.12 

1.26 

34 

CaO 

1.65 

1.47 

3.41 

2.65 

4.30 

3.09 

1.08 

.83 

Na^O 

5.76 

6.46 

4.65 

6.54 

3.98 

4.43 

5.23 

5.88 

K,0 

6.62 

6.76 

3.80 

4.98 

4.49 

6.74 

5.29 

1.26 

H,0 

.70 

.47 

.93 

.76 

1.16 

1.26 

2.45 

.69 

PA 

09 

.08 

.14 

.28 

.24 

.08 

.18 

Calculat 

edasWati 

jr-free. 

SiO, 

64.81 

62.15 

62.55 

62.46 

60.90 

61.46 

63.06 

75.98 

TiO, 

.46 

.15 

1.00 

.56 

.68 

.38 

.46 

.17 

AlaO, 

16.93 

19.16 

17.23 

18.07 

16.47 

17.97 

17.81 

13.20 

Fe,0, 

1.09 

2.66 

2.37 

2.24 

2.77 

2.67 

1.97 

1.16 

FeO 

2.73 

1.60 

3.40 

2.31 

3.32 

2.66 

3.43 

.66 

MnO 

.15 

.01 

.09 

.08 

.14 

.06 

.01 

.29 

MgO 

.73 

.55 

1.39 

.97 

2.52 

1.13 

1.29 

.34 

CaO 

1.56 

1.48 

3.44 

2.57 

4.35 

3.13 

1.11 

.84 

Na,0 

5.80 

6.48 

4.69 

5.68 

4.03 

4.49 

6.36 

5.92 

K,0 

5.66 

5.78 

3.84 

5.02 

4.64 

6.81 

6.42 

1.27 

PaO. 

.09 

.08 

.... 

.14 

.28 

.24 

.08 

.18 

Each 

sum  =  10( 

).00. 

Digitized  by  LjOOQIC 


DALT. 


-COMPOSITIONS   OF   IGNEOUS-BOCK  TYPES. 


221 


GROUP  ra. 


No.  of  Analyses. 

Plutonic. 

ErruBivs. 

Plutonic. 

ErruaivB. 

17 

18 

19 

20 

Laurvikite 
(Osann). 

• 

Rhomb-porphyiy 

Monsonite 
(Osann  and 
Washington). 

Latite  (Ran- 
someand 
Daly). 

3 

7 

12 

10 

SiO, 

57.46 

57.46 

55.25 

67.66 

TiO, 

.... 

.... 

.60 

1.00 

A1.0. 

21.11 

19.53 

16.53 

16.68 

Fe.0. 
FeO 

2.89 
2.39 

6.47      j 

3.03 
4.37 

2.29 
4.07 

BinO 

.... 

.... 

.15 

.10 

MgO 

1.06 

1.28 

4.20 

3.22 

CaO 

4.10 

3.11 

7.19 

5.74 » 

Na,0 

5.89 

6.35 

3.48 

3.59 

K,0 

3.87 

4.46 

4.11 

4.39 

H,0 

.70 

1.35 

.66 

.91 » 

PsO, 

.54 



.43 

.36 

Calculated  as  Water-free.                                          1 

SiO, 

57.86 

58.24 

65.62 

68.18 

TiO, 

.... 

.60 

1.01 

A1,0, 

21.26 

19.79 

16.64 

16.84 

Fe.0, 
FeO 

2.91 
2.41 

6.56      j 

3.05 
4.40 

2.31 
4.11 

MnO 

.15 

.10 

MgO 

1.07 

1.30 

4.23 

3.25 

CaO 

4.13 

3.15 

7.24 

5.79 » 

Na,0 

5.93 

6.44 

3.60 

3.62 

K,0 

3.90 

4.52 

4.14 

4.43 

PaO. 

.54 

.43 

.36 

Each  sum  -  100.00. 

»  Includes  .16%  BaO  and  .07%  SrO. 
«  Includes  .14%  CO,. 

Digitized  by  LjOOQIC 


222 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


GROUP   IV. 


No.  of 
Analyses. 


SiO, 

TiO, 

A1.0. 

Fe.0. 

FeO 

BinO 

MgO 

CaO 

Na,0 

K,0 

H,0 

PsO. 


Plutonics. 


21 


10 


56.11 

.45 

21.33 

1.87 

1.47 

.05 

.55 

1.72 

8.48 

6.46 

1.50 

.01 


22 


45.61 

27.76 

3.67 

.50 

.15 

.19 

1.73 

16.25 

3.72 

.42 


28 


3 


54.36 

1.30 

19.99 

2.79 

2.58 

.18 

1.72 

2.96 

8.28 

4.98 

.22 

.64 


24 


•*-N 


43 


54.63 

.86 

19.89 

3.37 

2.20 

.35 

.87 

2.51 

8.26 

6.46 

1.35 

.25 


EFFUSrVSB. 


26 


25 


57.45 

.41 

20.60 

2.35 

1.03 

.13 

.30 

1.50 

8.84 

5.23 

2.04 

.12 


26 


1 


54.89 

21.28 
3.04 
1.49 
.01 
.66 
2.31 
5.62 
8.39 
2.31 


27 


H 


t- 


n 

J5 


8 


49.83 

.71 

19.00 

3.17 

3.59 

.17 

1.79 

5.69 

7.19 

6.15 

1.93 

.78 


Calculated  as  Water-free. 


SiO, 

56.96 

TiO, 

.46 

A1.0. 

21.65 

Fe.0. 

1.90 

FeO 

1.49 

BinO 

.05 

MgO 

.56 

CaO 

1.75 

Na,0 

8.61 

K,0 

6.56 

P.O. 

.01 

45.80 

27.88 

3.68 

.50 

.15 

.19 

1.74 

16.32 

3.74 


54.48 
1.30 

20.03 
2.80 
2.59 
.18 
1.72 
2.97 
8.30 
4.99 
.64 


55.38 

.87 

20.16 

3.42 

2.23 

.35 

.88 

2.54 

8.38 

5.54 

.25 


58.65 

.42 

21.03 

2.40 

1.05 

.13 

.31 

1.53 

9.02 

5.34 

.12 


56.19 

50.82 

.... 

.72 

2^.78 

19.38 

3.11 

3.23 

1.53 

3.66 

.01 

.17 

.68 

1.83 

2.36 

5.80 

5.75 

7.33 

8.59 

6.27 

«... 

.79 

Each  sum  -  100.00. 


Digitized  by 


Goc 


DALT.  —  COMPOSITIONS   OF    IGNEOUS-BOCK  TYPES. 


223 


GROUP  V 

No.  of 
Analyses. 

PL. 

Er. 

Plutonigb 

28 

29 

30 

31 

32 

33 

34 

36 

36 

37 

1 

1 

li 

'Co 
•S3 

N 

u 

i 

1 

1 
5 

5 

i 

h 

lit 

p«  a 

1 

12 

30 

20 

89 

70 

87 

33 

20 

24 

10 

SiO, 

65.10 

66.91 

59.47 

58.38 

56.77 

59.59 

57.50 

59.48 

61.12 

62.25 

TiO, 

.54 

.33 

.64 

.80 

.84 

.77 

.79 

.48 

.42 

1.65 

AlaO. 

15.82 

16.62 

16.52 

16.28 

16.67 

17.31 

17,33 

17.38 

17.65 

16.10 

Fe,0. 

1.64 

2.44 

2.63 

2.98 

3.16 

3.33 

3.78 

2.96 

2.89 

3,62 

FeO 

2.66 

1.33 

4.11 

4.11 

4.40 

3.13 

3.62 

3.67 

2.40 

2,20 

MnO 

.05 

.04 

.08 

.13 

.13 

.18 

.22 

.15 

.15 

.21 

MgO 

2.17 

1.22 

3.75 

3.88 

4.17 

2.75 

2.86 

3.28 

2.44 

2.03 

CaO 

4.66 

3.27 

6.24 

6.38 

6.74 

5.80 

5.83 

6.61 

5.80 

4.05 

Na,0 

3.82 

4.13 

2.98 

3.34 

3.39 

3.58 

3.53 

3.41 

3.83 

3.55 

K,0 

2,29 

2.50 

1.93 

2.09 

2.12 

2.04 

2.36 

1.64 

1.72 

2.44 

H,0 

1.09 

1.13 

1.39 

1,37 

1.36 

1.26 

1.88 

.74 

1,43 

1.50 

PaOs 

.16 

.08 

.26 

.26 

.25 

.26 

.30 

.20 

.15 

.40 

Calculated  as  Wat 

er-free 

SiO, 

65.82 

67.67 

60.31 

59.19 

57.56 

60.35 

58.65 

59.92 

62.01 

63.20 

TiO, 

.55 

.33 

.65 

.81 

.85 

.78 

.80 

,48 

.43 

1.67 

A1,0. 

15,99 

16.81 

16.75 

16.51 

16.90 

17.54 

17.67 

17.51 

17.91 

16.35 

Fe,03 

1.66 

2.47 

2.67 

3.02 

3.20 

3.37 

3.85 

2.98 

2.93 

3.67 

FeO 

2.69 

1.35 

4.17 

4.17 

4.46 

3.17 

3.69 

3.70 

2.44 

2.23 

MnO 

.05 

.04 

.08 

.13 

.13 

.18 

.22 

.15 

.15 

.21 

MgO 

2.19 

1.23 

3.80 

3.93 

4.23 

2.78 

2,90 

3.31 

2.48 

2.06 

CaO 

4.71 

3.31 

6.33 

6.47 

6.83 

5.87 

5.92 

6.66 

5.88 

4.11 

Na,0 

3.86 

4.18 

3.02 

3.39 

3.44 

3.63 

3.60 

3.44 

3.88 

3.61 

K,0 

2.32 

2.53 

1.96 

2.12 

2.15 

2.07 

2.40 

1.65 

1,74 

2.48 

P,0, 

.16 

.08 

.26 

.26 

.25 

.26 

,30 

.20 

.15 

.41 

Each  sum  =  10< 

).00. 

1 

r 


Digitized  by  VjOOQIC 


224 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY 


GROUP   VI. 


No.  of 
Anal3rse8. 

Plutonigb. 

ErruBivxs.                                       1 

38 

39 

40 

41 

42 

43 

44 

46 

1 

1 

3 

111 

Basalt,  as  named  by 

Authors  {inrludinp:  also 
Anamesite.  Tachyliic, 
etc.)  (Osann). 

1 

J 
o 

^ 

g 
1 

7 

41 

198 

161 

20 

17 

11 

9 

SiO, 

50.16 

48.24 

49.06 

48.78 

50.12 

50.10 

50.60 

49.50 

TiO, 

1.64 

.97 

1.36 

1.39 

1.41 

1.25 

.68 

1.42 

A1.0, 

18.61 

17.88 

15.70 

15.85 

15.68 

14.43 

17.40 

14.37 

Fe.0. 

1.88 

3.16 

5.38 

5.37 

4.55 

5.06 

4.57 

6.55 

FeO 

9.29 

5.95 

6.37 

6.34 

6.73 

6.31 

6.29 

5.84 

BinO 

.14 

.13 

.31 

.29 

.23 

.25 

.46 

.17 

MgO 

5.97 

7.51 

6.17 

6.03 

5.85 

7.32 

4.89 

7.75 

CaO 

7.90 

10.99 

8.95 

8.91 

8.80 

9.53 

8.09 

9.96 

Na,0 

2.72 

2.55 

3.11 

3.18 

2.95 

2.75 

3.23 

2.50 

K,0 

.80 

.89 

1.52 

1.63 

1.38 

.73 

1.76 

.84 

H,0 

.76 

1.45 

1.62 

1.76 

1.93 

2.00 

1.83 

.66 

P,Os 

.23 

.28 

.45 

.47 

.37 

.27 

.20 

.44 

Calculated 

as  Water-f  1 

nee. 

SiO, 

50.54 

48.95 

49»87 

49.65 

51.11 

51.12 

51.54 

49.83 

TiO, 

1.65 

.98 

1.38 

1.41 

1.44 

1.27 

.69 

1.43 

A1,0. 

18.65 

18.15 

15.96 

16.13 

15.99 

14.73 

17.73 

14.47 

Fe.0, 

1.90 

3.21 

5.47 

5.47 

4.64 

5.16 

4.66 

6.59 

FeO 

9.36 

6.04 

6.47 

6.45 

6.86 

6.44 

6.41 

5.88 

MnO 

.14 

.13 

.32 

.30 

.23 

.25 

.47 

.17 

MgO 

6.02 

7.62 

6.27 

6.14 

5.96 

7.47 

4.99 

7.80 

CaO 

7.96 

11.15 

9.09 

9.07 

8.97 

9.73 

8.24 

10.02 

Na^O 

2.74 

2.59 

3.16 

3.24 

3.01 

2.81 

3.29 

2.52 

K,0 

.81 

.90 

1.55 

1.66 

1.41 

.74 

1.78 

.85 

PA 

.23 

.28 

.46 

.48 

.38 

.28 

.20 

.44 

Each  8U1 

m  -  100.0C 

). 

Digitized  by  LjOOQIC 


DALT.  —  COMPOSITIONS   OF   IGNEOUS-ROCK  TYPES, 


225 


GROUP  vn. 


No.  of 

Analyses. 

PUITONICS.                                                                       1 

48 

47 

48 

49 

60 

5 

g 
o 

Norite,  excludinc 
Olivine  Norite 
(psannand 
Walker). 

5 

5^ 

24 

17 

5 

2 

12 

SiO, 

49.50 

46.49 

50.08 

50.38 

50.40 

TiO, 

.84 

1.17 

1.44 

2.04 

.15 

A1.0. 

18.00 

17.73 

18.62 

18.27 

28.30 

Fe.0. 

2.80 

3.66 

2.35 

.73 

1.06 

FeO 

5.80 

6.17 

8.87 

10.35 

1.12 

MnO 

.12 

.17 

.11 

.20 

.05 

MgO 

6.62 

8.86 

6.22 

5.32 

1.25 

CaO 

10.64 

11.48 

7.89 

7.91 

12.46 

Na,0 

2.82 

2.16 

2.53 

3.18 

3.67 

K,0 

^98 

.78 

.71 

1.02 

.74 

H,0 

1.60 

1.04 

1.01 

.26 

.75 

P.O. 

.28 

.29 

.17 

.34 

.05 

Calculated  a 

LS  Water-free. 

SiO, 

50.31 

46.97 

50.60 

50.51 

50.78 

TiO, 

.85 

1.18 

1.45 

2.05 

.15 

A1,0. 

18.30 

17.92 

18.81 

18.32 

28.61 

Fe,0. 

2.85 

3.70 

2.37 

.73 

1.07 

FeO 

5.89 

6.24 

8.96 

10.38 

1.13 

BinO 

.12 

.17 

.11 

.20 

.05 

MgO 

6.73 

8.96 

6.28 

5.33 

1.26 

CaO 

10.81 

11.60 

7.97 

7.93 

12.55 

Na,0 

2.86 

2.18 

2.56 

3.19 

3.70 

K,0 

1.00 

.79 

.72 

1.02 

.75 

P.O. 

.28 

.29 

.17 

.34 

.05 

Each  sum 

I  -  100.00. 

VOL.   XLV.  —  15 


Digitized  by  VjOOQIC 


226 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


GROUP   VIII. 


No  of 

Analyses. 

Plutonics. 

EfTD- 
BIVB. 

61 

62 

63 

64 

66 

66 

67 

68 

« 

1 
1 

i 

i 

|l3 

1 

.i 

5 

ll 

< 

4 

4 

3 

4 

3 

4 

49 

3 

SiO, 

42.09 

63.65 

48.13 

43.86 

40.06 

49.82 

44.39 

43.24 

TiO, 

.12 

.14 

.87 

.... 

.... 

1.46 

.88 

.... 

A1,0. 

4.83 

1.66 

6.60 

6.00 

.67 

5.12 

6.14 

16.19 

Fe,0. 

4.98 

1.90 

2.01 

2.64 

2.29 

1.83 

3.88 

8.62 

FeO 

4.68 

5.36 

11.73 

6.30 

7.32 

7.44 

6.70 

7.89 

MnO 

.06 

.17 

.08 

.12 

.24 

.09 

.19 

MgO 

31.80 

22.67 

21.01 

36.96 

46.62 

19.56 

29.17 

8.56 

CaO 

6.37 

13.37 

6.17 

2.70 

.35 

13.00 

6.31 

13.78 

Na,0 

1.02 

.20 

1.15 

.... 

.01 

.37 

.64 

.54 

K,0 

.29 

.07 

.68 

.... 

.... 

.21 

.76 

.48 

H,0 

3.85 

.85 

1.62 

2.53 » 

2.63 

1.06 

1.80 

1.21 

PsOs 

.01 

.07 

.15 



.01 

.05 

.14 

.49 

( 

[Calculated 

as  Water-f  1 

■ee. 

1 

SiO, 

43.78 

64.11 

48.93 

44.99 

41.10 

60.36 

45.20 

43.77 

TiO, 

.12 

.14 

.88 

• . .  • 

.... 

1.48 

.90 

AI3O. 

5.02 

1.67 

6.61 

6.13 

.68 

6.17 

6.26 

16.37 

Fe,0. 

6.18 

1.92 

2.04 

2.61 

2.35 

1.86 

3.95 

8.72 

FeO 

4.77 

6.40 

11.92 

6.46 

7.61 

7.52 

6.82 

7.99 

MnO 

.06 

.17 

.08 

.12 

.26 

.09 

.19 

.... 

MgO 

33.08 

22.76 

21.36 

37.92 

47.83 

19.76 

29.70 

8.66 

CaO 

6.62 

13.49 

6.27 

2.77 

.36 

13.14 

6.43 

13.95 

Na,0 

1.06 

.20 

1.17 

• .  •  • 

.01 

.37 

.66 

.65 

K,0 

.30 

.07 

.69 

•  • .  • 

.... 

.21 

.77 

.49 

PsO, 

.01 

.07 

.16 

.... 

.01 

.06 

.14 

.60 

Each  sun 

a  -  100.00 

'  L068O 

n  ignition. 

Digitized  by  ^ 


DALT.  —  COBfPOSrnONS  OP  IGNEOUS-ROCK  TYPES. 


227 


GROUP  EX. 


No.  of 
Analyses. 


SiO, 

TiO, 

AI3O. 

Fe.0. 

FeO 

MnO 

MgO 

CaO 

Na,0 

K,0 

H,0 

PA 


SiO, 

TiO, 

AlaO. 

Fe.0. 

FeO 

MnO 

MgO 

CaO 

Na,0 

K,0 

P,0. 


Plutonic. 


59 


11 


48.40 

1.71 

16.67 

5.31 

6.03 

.15 

4.48 

9.05 

4.45 

2.13 

.95 

.67 


EFrUBXVBS. 


60 


^ 


54.81 
.42 

20.01 
3.98 
1.93 

2.32 
5.60 
5.86 
3.13 
1.46 
.48 


61 


41.69 

.67 

14.80 

I     15.04     I 


8.64 
11.98 
3.52 
1.17 
2.36 
.13 


Calculated  as  Water-free. 


48.86 
1.73 

16.83 
5.36 
6.09 
.15 
4.52 
9.14 
4.49 
2.15 
.68 


55.62 
.43 

20.31 
4.04 
1.96 

2.35 
5.68 
5.94 
3.18 
.49 


42.69 

.68 

15.18 

I     15.43     I 


8.85 

12.27 

3.58 

1.19 

.13 


Each  sum  -  100.00. 


6 


42.25 
2.52 

16.26 
8.43 
5.46 

5.49 
9.75 
4.45 
1.92 
2.43 
1.04 


43.30 
2.58 

16.67 
8.64 
5.59 

5.63 
9.99 
4.56 
1.97 
1.07 


Digitized  by  LjOOQIC 


228 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


GROUP   X. 


No.  of 
Analyses. 

Plutonics. 

EFrusxvBS.                                      1 

63 

64 

66 

66 

67 

68 

68 

70 

•-§ 

S^ 

% 

1 

3 

1^ 

h 

fi 

6 

6 

24 

20 

4 

20 

16 

4 

SiO, 

45.61 

48.66 

49.14 

44.41 

46.91 

49.90 

44.20 

45.34 

TiO, 

1.96 

.97 

1.00 

1.56 

1.81 

.16 

1.64 

1.30 

A1,0. 

14.35 

12.36 

16.57 

15.81 

15.25 

16.94 

15.64 

16.59 

Fe,0. 

6.17 

3.08 

3.65 

4.66 

7.70 

3.02 

4.35 

6.83 

FeO 

4.03 

5.86 

6.68 

5.85 

4.06 

7.15 

6.14 

4.76 

MnO 

.19 

.13 

.30 

.14 

1.43 

.23 

.19 

.01 

/MgO 

6.05 

8.09 

3.98 

8.20 

2.95 

4.22 

8.89 

6.43 

CaO 

9.49 

10.46 » 

9.88 

10.12 

9.36 

10.04 

9.74 

11.64 

Na,0 

5.12 

2.71 

2.57 

3.81 

4.25 

2.24 

4.03 

2.93 

K,0 

3.69 

6.15 

3.39 

2.37 

2.63 

3.67 

1.83 

4.65 

H,0 

2.60 

1.46 

2.00 

2.42 

2.51 

1.74 

2.67 

1.12 

P,0, 

.74 

1.07 

.84 

.65 

1.14 

.79 

.68 

.50 

Calculated  as  Water-free.                                          | 

SiO, 

46.83 

49.38 

50.15 

45.51 

48.12 

50.79 

45.41 

45.86 

TiO, 

1.98 

.98 

1.02 

1.60 

1.86 

.16 

1.68 

1.31 

A1.0. 

14.73 

12.55 

16.90 

16.20 

15.65 

17.24 

16.07 

16.78 

Fe.0. 

6.34 

3.12 

3.72 

4.78 

7.89 

3.07 

4.47 

6.90 

FeO 

4.14 

5.95 

6.82 

5.99 

4.16 

7.28 

6.31 

4.81 

MnO 

.19 

.13 

.31 

.14 

1.47 

.23 

.20 

.01 

MgO 

6.22 

8.21 

4.06 

8.41 

3.02 

4.30 

9.13 

6.49 

CaO 

9.75 

ld.6i» 

10.08 

10.37 

9.60 

10.22 

10.01 

11.77 

Na,0 

6.27 

2.75 

2.62 

3.90 

4.36 

2.28 

4.14 

2.96 

K,0 

3.79 

5.23 

3.46 

2.43 

2.70 

3.63 

1.88 

4.60 

PA 

.76 

1.08 

.86 

.67 

1.17 

.80 

.70 

.61 

Each  sum  -  100.00.                                               | 

*  Includ< 

58  .40%  BaO  and  .09%  SrO^ 

»  Include 

BS  .41%  BaO  and  .09%  SrO. 

Digitized 


DALT.  —  COMPOSITIONS   OF   IGNEOUS-ROCK  TYPES. 


229 


GROUP  XI. 


No.  of 
Analyses. 

Plutonicb. 

E1TDSIVK8. 

Plutonic. 

E1TDSXVX8.       1 

71 

72 

73 

74 

76 

76 

77 

1 

h 

Is 

1 

5 

1 

11 

1 

2 

7 

7 

6 

9 

26 

SiO, 

51.70 

44.27 

46.47 

47.72 

43.51 

41.17 

39.87 

TiO, 

.23 

1.37 

1.33 

.52 

1.07 

1.35 

1.50 

AI3O, 

14.60 

10.73 

15.97 

18.19 

19.54 

16.83 

13.58 

Fe.0. 

5.07 

3.63 

5.97 

4.74 

3.77 

7.61 

6.71 

FeO 

3.58 

5.87 

4.27 

3.90 

3.88 

6.64 

6.43 

MnO 

.01 

.06 

.01 

.06 

.16 

.16 

.21 

MgO 

4.55 

13.05 

6.87 

3.46 

2.94 

3.72 

10.46 

CaO 

7.40 » 

11.46  » 

10.54 

7.27 

9.89 

10.12 

12.36 

Na,0 

2.93 

1.07 

1.69 

4.51 

10.68 

6.45 

3.86 

K3O 

7.60 

4.43 

4.83 

7.66 

2.26 

2.49 

1.87 

H,0 

2.25 

3.23 

2.32 

1.51 

.86 

2.42 

2.22 » 

PsO. 

.18 

.83 

.73 

.47 

1.54 

1.04 

94. 

Calculated  as 

Water-free. 

1 

SiO, 

52.89 

45.75 

47.58 

48.45 

43.89 

42.19 

40.77 

TiO, 

.24 

1.41 

1.36 

.53 

1.08 

1.38 

1.53 

AI3O, 

14.83 

11.09 

16.35 

18.47 

19.71 

17.25 

13.88 

Fe.0, 

5.18 

•     3.75 

6.11 

4.81 

3.80 

7.79 

6.86 

FeO 

3.66 

6.07 

4.37 

3.96 

3.91 

6.81 

6.57 

BinO 

.01 

.06 

.01 

.06 

.16 

.17 

.21 

MgO 

4.65 

13.49 

6.01 

3.60 

2.97 

3.81 

10.73 

CaO 

7.57* 

11.85 » 

10.79 

7.38 

9.98 

10.37 

12.65 

Na,0 

3.00 

1.10 

1.73 

4.68 

10.67 

6.61 

3.94 

K,0 

7.79 

4.57 

4.94 

7.78 

2.28 

2.55 

1.90 

P.O. 

.18 

.86 

.75 

.48 

1.55 

1.07 

.96 

Each  sum 

-  100.00. 

*  Includes 

•  Includes 

.30%BaC 
.29%  CO, 

>and.07%SrO. 
•Includes  .60%  B 

•Includes  .48% Ba 
*  Includes  .31  %Ba 
aOand.l9%SrO. 

Oand.l8%SrO. 
Oand.07%SrO. 

Digitized  by  LjOOQIC 


230 


PBOCEEDINGS  OF  THE  AMERICAN  ACADEBIT. 


GROUP  xn. 


No.  of  Analyses. 

Plutonicb.                                             I 

78 

79 

80 

Alaaldte 
(Osann). 

Diorit©  of 
Electric  Peak 
(Roeenbuach). 

Malignite 

(Osann  and 

Daly). 

3 

10 

4 

SiO, 

76.47 

62.21 

50.34 

TiO, 

.07 

.60 

.34 

AlaO, 

13.03 

16.45 

14.76 

Fe.0. 
FeO 

1.04 

2.53 
2.89 

4.18 
2.76 

MnO 

.01 

.02 

.11 

MgO 

.06 

3.32 

4.23 

CaO 

.45 

4.96 

10.43 

Na,0 

3.53 

3.88 » 

6.27 

K,0 

4.81 

2.21 

5.21 

H,0 

.62 

.80 » 

1.20 

P3O. 

.01 

.13 

1.19 

Calculated  as  Water-free.                                             | 

SiO, 

76.87 

62.71 

50.95 

TiO, 

.07 

.60 

.35 

A1.0, 

13.10 

16.58 

14.93 

Fe,0. 
FeO 

1.05         1 

2.55 
2.92 

4.23 
2.78 

MnO 

.01 

.02 

.11 

MgO 

.06 

3.35 

4.28 

CaO 

.45 

5.00 

10.56 

Na,0 

3.55 

3.91 » 

5.33 

K,0 

4.83 

2.23 

5.27 

P3O, 

.01 

.13 

1.21 

Each  sum  -  100.00.                                               | 

»  Includes  .07%  Li,0. 

»  Includes  .05%  CI  and  .05%  SO,. 

Digitized  by  LjOOQIC 


DALY.  —  COMPOSITIONS   OF    IGNEOUS-ROCK   TYPES. 


231 


GROUP 

XIII. 

No.  of 
Analyses. 

Effubivbs.                                                       I 

81 

82 

83 

84 

86 

86 

87 

it 

1. 

2? 

l| 

ll 

5"^ 

'<'^ 

^1 

5i 

TS  5 

1^ 

10 

'' 

4 

8 

5 

2 

6 

SiO, 

74.04 

48.36 

52.04 

53.56 

60.11 

47.45 

36.19 

TiO, 

.18 

.66 

.76 

.82 

.96 

.81 

.    7.11 

A1,0, 

13.19 

15.40 

17.65 

17.88 

13.04 

11.43 

10.62 

Fe,0, 

1.35 

6.48 

4.66 

4.51 

4.68 

3.22 

8.48  » 

FeO 

1.01 

10.07 

2.75 

3.05 

3.94 

6.78 

5.97 

MnO 

.04 

.80 

.13 

.07 

.11 

.12 

MgO 

.32 

4.19 

3.33 

3.62 

9.27 

14.60 

14.59 

CaO 

1.19 

8.69 

5.11 

6.45 

7.63 

8.18 

9.88 

Na,0 

3.88 

3.34 

4.10 

3.41 

1.94 

2.32 

3.28 

K,0 

3.75 

1.30 

6.03 

3.76 

4.16 

2.99 

2.03 

H,0 

1.02' 

.43 

3.74 

2.32 

3.68 

2.60 

1.94' 

PaO, 

.03 

.28 

.70 

.55 

.69 

.60 

.01 

Calc 

ulated  as 

Water-free. 

8iO, 

74.80 

48.57 

54.06 

54.84 

61.97 

48.67 

36.90 

TiO, 

.18 

.66 

.79 

.84 

1.00 

.83 

7.25 

A1,0. 

13.33 

15.47 

18.34 

18.31 

13.52 

11.73 

10.73 

Fe,0. 

1.37 

6.51 

4.84 

4.62 

4.74 

3.30 

8.66^ 

FeO 

1.02 

10.11 

2.85 

3.12 

4.08 

6.93 

6.09 

MnO 

.04 

.80 

.14 

.07 

.12 

.12 

.... 

MgO 

.32 

4.21 

3.46 

3.70 

9.62 

14.97 

14.88 

CaO 

1.20 

8.73 

5.31 

6.60 

7.91 

8.39 

10.08 

Na,0 

3.92 

3.35 

4.26 

3.49 

2.01 

2.38 

3.34 

K,0 

3.79 

1.31 

5.22 

3.85 

4.31 

3.06 

2.07 

PsO, 

.03 

.28 

.73 

.56 

.72 

.62 

.01 

£ 

lach  sum 

-  100.00 

'  Include 
'  Loss  01 

is  2.85  %  ( 
1  ignition. 

>«o,. 

t 

4 

Includes  .02  %  Li,0  and  .23 
Includes  2.47  %  OjO,. 

%so,. 

Digitized  by  LjOOQIC 


232  PROCEEDINGS  OF  THE  AMERICAN  ACADEMT. 

GROUP  XIV. 


DIKS-ROCK8. 


No.  of 
Analyses. 


SiO, 

TiO, 

AlaO. 

Fe.0, 

FeO 

MnO 

MgO 

CaO 

Na,0 

K,0 

H,0 

P.O. 


88 


hi 


15 


75.00 

.30 

13.14 

.58 

.40 

.07 

.30 

1.13 

3.54 

4.80 

.71 

.03 


61.32 

.89 

18.43 

3.84 

1.60 

.01 

.46 

1.45 

6.75 

4.94 

1.31 


90 


28 

|S5 


70.91 

.48 

11.50 

4.68 

1.88 

.39 

.11 

.39 

6.43 

4.08 

.25 


91 


8 


62.16 

.31 

17.68 

3.06 

1.80 

.18 

.48 

1.11 

7.30 

4.96 

1.04 

.04 


92 


hi 


16 


65.02 

.36 

20.42 

3.06 

1.82 

.22 

.69 

1.67 

8.63 

6.38 

2.77 

.06 


Calculated  as  Water-free. 


SiO, 

TiO, 

A1,0, 

Fe,0, 

FeO 

MnO 

MgO 

CaO 

Na,0 

K,0 

P.O. 


76.64 

.30 

13.23 

.68 

.40 

.07 

.30 

1.14 

3.67 

4.84 

.03 


62.14 

.90 

18.67 

3.89 

1.62 

.01 

.47 

1.47 

6.82 

6.01 


71.09 

.48 

11.63 

4.69 

1.89 

.39 

.11 

.39 

6.44 

4.09 


62.82 

.31 

17.77 

3.08 

1.82 

.18 

.49 

1.12 

7.37 

6.00 

.04 


66.69 

.37 

21.00 

3.16 

1.87 

.23 

.61 

1.72 

8.87 

6.63 

.06 


Each  sum  -  100.00. 


Digitized  by  LjOOQIC 


DALT.  —  COMPOSITIONS   OF   IGNEOUS-ROCK  TYPES. 


233 


GROUP  XV. 


No.  of 
Analyses. 


SiO, 

TiO, 

A1,0, 

Fe.0, 

FeO 

MnO 

MgO 

CaO 

Na^O 

K,0 

H,0 

PaO, 


8iO, 

TiO, 

AlaO, 

Fe,0, 

FeO 

MnO 

MgO 

CaO 

Na^O 

K,0 

P,0, 


DiKE-BOCXS. 


93 


I- 


10 


49.45 
1.23 

14.41 
3.39 
5.01 
.13 
8.26 
6.73 
2.54 
4.69 
3.04 » 
1.12 


94 


j^-ff 


20 


60.79 
1.02 

15.26 
3.29 
5.54 
.07 
6.33 
5.73 
3.12 
2.79 
5.71 « 
.35 


95 


5e 


52.62 

.54 

14.86 

3.60 

4.18 

.84 

8.55 

5.86 

3.21 

2.83 

2.70 

.21 


96 


-I 


15 


40.70 
3.86 

16.02 
5.43 
7.84 
.16 
5.43 
9.36 
3.23 
1.76 
5.59* 
.62 


97 


H 


oO 


16 


45.17 
1.90 

14.78 

5.10 

5.05 

.35 

6.26 

11.06 

3.69 

2.73 

3.40 

.51 


Calculated  as  Water-free. 


50.99 
1.27 

14.86 
3.50 
5.17 
.13 
8.53 
6.95 
2.62 
4.84 
1.14 


53.87 
1.08 

16.18 
3.48 
5.88 
.07 
6.71 
6.09 
3.31 
2.96 
.37 


Each  sum  -  100.00. 


98 


^1 


6 


32.31 

1.41 

9.50 

5.42 

6.34 

.01 

17.43 

13.58 

1.42 

2.70 

7.50* 

2.38 


54.08 

43.10 

46.76 

.56 

4.09 

1.96 

15.28 

16.97 

15.30 

3.70 

5.76 

5.28 

4.29 

8.30 

5.23 

.86 

.16 

.36 

8.79 

5.76 

6.48 

6.02 

9.92 

11.45 

3.30 

3.42 

3.82 

2.90 

1.86 

2.83 

.22 

.66 

.53 

34.93 
1.52 

10.27 

5.86 

6.85 

.01 

18.84 

14.68 
1.53 
2.92 
2.59 


»  Includes  .61%  CO,. 
»  Includes  2.97%  CO,. 


«  Includes  2.61%  CO,. 
*  Includes  4.35%  CO,. 


Digitized  by  LjOOQIC 


234 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


Index  to  Table  II. 


Absarokite 86 

Akerite 11 

Alaskite 78 

Alnoite 98 

Amphibole  andesite 36 

Andesite  (all)      33 

Anorthoeite 60 

Augite  andesite 34 

Augitite 62 

Banakite 83 

Basalt  (aU) 40 

Basalt  as  named  by  authors    .   .  41 

Basalt  of  Hawaiian  Islands  ...  82 

Basanite  (aU) 66 

Bostonite 89 

Camptonite 96 

Dacite 29 

Diabase 42 

Diorite,  including  quartz  diorite  .  31 

Diorite,  excluding  quartz  diorite .  32 

Diorite  of  Electric  Peak    ....  79 

Dolerite 45 

Dunite 66 

Eleolite  syenite 24 

Essexite i   .   .   .  69 

Fergusite 71 

Foyaite 21 

Gabbro(aU) 39 

Gabbro,  excluding  olivine  gabbro  46 

Granite  of  all  periods 4 

Granite  younger  than  the  Pre- 

Cambrian 3 

Granites   (Pre-Cambrian,  includ- 
ing   16    analyses    of   Swedish 

types) 1 

Granites       (Pre-Cambrian,       of 

Sweden) 2 

Granite-aplite 88 

Granodiorite 28 

Grorudite 90 

Harzburgite 64 

Hornblende  andesite 36 

Hypersthene  andesite 36 

Ijolite 76 

Keratophyre 16 

Kersantite 94 

Latite 20 

Laurdalite 23 

Laurvikite 17 


Leucite  absarokite 86 

Leucite  basalt 73 

Leucite  basanite 70 

Leucite  phonolite 26 

Leucite  tephrite 68 

Leucitite 74 

Leucitophyre 27 

Lherzolite 61 

Limburgite 61 

Liparite  (all) 6 

Liparite,  as  named  by  authors  6 

Malignite 80 

Melaphyre 44 

Melilite  basalt 87 

Mica  andesite     37 

Minette 93 

Missourite 72 

idonchiquite 97 

Monzonite 19 

Nephelite  basalt 77 

Nephelite  basanite 69 

Nephelite  syenite 24 

Nephdite  tephrite 67 

Nephelinite 76 

Nordmarkite 9 

Norite(aU)                 38 

Norite,  excluding  olivine  norite  .  48 

Olivine  diabase 43 

Olivine  gabbro 47 

Olivine  norite 49 

Peridotite  (all) 67 

Phonolite 26 

Picrite 68 

Pulaskite 10 

Pyroxenite 66 

Quartz  diorite SO 

Quartz  keratoph3rre 16 

Quartz  porphyry 8 

Rhomb-porphyry 18 

Rhyolite,  as  named  by  authors   .  7 

Rhyolite  of  Yellowstone  Park  81 

Saxonite 64 

Shonkinite 64 

Shoshonite 84 

S51vsbergite 91 

Syenite  (all) 13 

Syenite  (alkaline) 12 

Tephrite  (all) 66 

Theralite     63 


Digitized  by 


Gor. 


DALT.  —  COBIPOSITIONS    OP   IGNEOUS-ROCK  TYPES. 


235 


Tinguaite     .  \ 92 

Trachydolerite 60 

Trachyte      14 

unite 22 


Vogesite 95 

Websterite 62 

Wehrlite 63 


AvEBAQE  Specific  Gbavities  of  Ceetain  Types. 

The  average  specific  gravities  of  holoorystalline  tyx>es  have  been 
calculated,  with  result  shown  in  the  following  accessory  table.  Most 
of  the  determinations  were  taken  firom  Osann's  book. 


• 

Number  of  Speci- 
mena  averaged. 

Average  Specific 
Gravity. 

Granite 

Granodiorite 

Syenite 

Monzonite 

Nephelite  syenite     .... 

Diorite 

Gabbro 

Olivine  gabbro 

Anorthosite 

Peridotite 

Essexite 

58 

5 

11 

2 

13 

17 

19 

4 

6 

21 

2 

3 

4 

2.660 
2.740 
2.773 

2.805 
2.600 
2,861 
2.933 
2.948 
2.715 
3.176 
2.862 
2.917 
2.884 

Theraiite 

Malignite 

Some  Applications. 

The  uses  to  which  the  averages  may  be  put  are  diverse  and,  in  cer- 
tain instances,  direct  and  important.  A  brief  note  in  this  place  will 
indicate  something  of  the  range  of  the  considerations  affected. 

1.  The  writer  has  found  from  personal  experience  that  the  averages 
have  been  of  decided  benefit  in  showing  the  chemical  individuality  and 
true  nature  of  the  igneous-rock  types  as  actually  mapped.  To  student 
and  investigator  alike  such  averages  are,  for  many  purposes,  more 
valuable  than  single  analyses.     They  help  to  show  that  eruptive  rocks 


';::itized  by 


Google 


236  PB0CEEDIN6S  OF  THE  AMERICAN  ACADEMY. 

do  not  fonn  an  infinite  series,  but  that  the  yari0tie9  duster  about 
''center-points."  Osann's  great  compilation  proves  that  Rosenbasch's 
classification  is  an  objective  and  "natural"  one  to  a  highly  useful 
degrea 

2.  The  obvious  error  involved  in  computing  "  the  average  composi- 
tion of  the  primitive  crust  of  the  earth,"  or  "the  average  igneous 
rock/'  or  "the  mean  composition  of  the  accessible  parts  of  the  earth's 
crust,"  by  averaging  a  large  number  of  analyses  compiled  at  random,  has 
not  deterred  a  goodly  number  of  authors  from  using  such  results  as 
those  deduced  by  Clarke,  Washington,  and  Harker.  These  averages 
are  bound  to  bre^  further  errors  when  used  as  a  basis  for  quantitative 
studies  in  geology  or  oceanography.  The  discovery  of  "  the  average 
igneous  rock  "  is  of  the  highest  importance  for  many  problems  such  as 
the  chemical  denudation  of  the  lands  and  iiie  chemical  evolution  of 
the  ocean.  The  mean  composition  of  the  accessible  crystalline  rocks 
of  the  globe  must  ultimately  be  obtained  by  taking  account  of  the 
relative  volumes  of  the  different  rock-t3r{jes.  In  computing  the  mean 
the  average  analyses  for  the  principal  individual  species  must  be  em- 
ployed. Since  the  only  approach  to  success  is  through  the  quantita- 
tive study  of  geological  maps  and  memoirs,  it  is  clear  that  for  many 
years  to  come  the  averages  for  the  types  recognized  in  Rosenbusch's 
system  are  to  be  basal  to  the  calculation. 

A  glance  at  Table  11.  shows,  however,  that  this  new  world-average 
will  differ  little  from  the  earlier  world-averages  with  respect  to  one 
oxide,  namely,  soda.  For  each  of  the  areally  and  volumetrically  im- 
portant rock-types  the  average  soda  never  departs  £Bir  from  a  mean 
of  about  three  and  one  half  per  cent  The  soda  in  the  averages  of 
Clarke,  Washington,  and  Harker  (calculated  as  water-free)  is,  respec- 
tively, 3.63  per  cent,  3.34  per  cent,  and  3.90  per  cent.^  The  agree- 
ment is  fortunate,  since,  for  example,  the  quantitative  problem  relative 
to  the  sodium  in  the  ocean  can  be  pursued  without  waiting  for  the 
close  determination  of  "the  average  igneous  rock."  Incidentally,  it 
may  be  remarked  that  the  estimates  of  Joly^  and  Sollas^  regarding 
the  age  of  the  ocean,  as  determined  by  the  sodium  content,  need  revis- 
ion, since  neither  author  has  allowed  for  the  great  variations  in  the 
area  of  the  lands  during  geological  time. 

3.  The  recurrence  of  the  main  types  of  igneous  rock  in  every  conti- 
nent shows  that  general  processes  of  differentiation  have  been  at  work 

»  F.  W.  Clarke,  Bull.  228,  U.  S.  Geol.  Survey,  1904,  p.  16. 
«  J.  Joly,  Sci.  Trans.  Roy.  Dublin  Society,  7.  23  (1899). 
*  W.  J.  SoUas,  Quart.  Join*.  Geol.  Soc.,  Presidential  Address,  66,  p.  Ixxix 
(1909). 


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DALT.  —  COMPOSITIONS   OP   IGNEOUS-BOCK  TYPEa 


237 


from  the  earliest  recorded  time.  There  is  no  reason  to  doubt  that  the 
diorite  or  the  nephelite  syenite  of  the  pre-Cambrian  periods  have 
generally  owed  their  origin  to  the  same  physico-chemical  reactions  as 
those  responsible  for  the  Mesozoic  or  Tertiary  diorite  or  nephelite 
syenite.  If  this  be  true,  the  world-averages  for  the  different  principal 
types  should  be  so  many  tests  of  theoretical  conclusions  as  to  the  causes 
of  the  differentiation  of  those  tjrpes.  The  question  as  to  the  derivation 
of  augite  andesite  from  basalt  through  fractional  crystallization  has 
been  thus  tested,  with,  so  £str  as  this  test  goes,  an  affirmative  answer.^ 
Sometimes  the  averages  themselves  suggest  lines  of  thought  For 
example,  the  average  granite  analysis  (calculated  water-free ;  236  analy- 
ses) is  close  to  the  average  of  four  analyses  of  the  glassy  base  of 
augite  andesite  (calculated  as  water-free).  The  comparison  may  be 
made  from  the  following  table : 


Oxanite  of  all 
Periods. 

Ground-mass  (base) 
of  Augite  andesite. 

No.  of  Analyses 

236 

4 

SiO, 

per  cent. 
70.47 

per  cent. 
69.31 

TiO, 

.39 

.... 

AI3O. 

14.90 

17.11 

Fe,0. 

1.63 

2.15 

FeO 

1.68 

.60 

MnO 

.13 

.... 

MgO 

.98 

.70 

CaO  (BaO  and  SrO) 

2.17 

2.63 

Na,0 

3.31 

3.20 

K,0 

4.10 

4.30 

PA 

.24 

.... 

100.00 

100.00 

The  exact  meaning  of  the  correspondence  between  the  two  averages 
may  not  be  discussed  here ;  but  it  does  suggest  an  explanation  of  the 

*  Journal  of  Geology,  16,  401  (1908). 


r- 


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238 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


common  association  of  granites  (and  liparites)  with  andesites  (and 
diorites)  in  nature.  The  qaestion  is  open  as  to  whether  the  primitive 
granite-liparite  magma  was  not  a  polar  differentiate  of  an  andesitic 
magma,  preferably  by  a  settling-out  of  the  phenocrjrstic  constituents 
(in  solid  or  liquid  phases)from  the  andesitic  magma. 

Other  related  questions  are  raised  by  the  comparison  of  the  mean  of 
average  granite  and  average  basalt  with  average  diorite  (including 
qaartE  diorite). 


1. 
Average 
Granite. 

2. 
Average 
Basalt. 

3. 

Mean  of  1 

and  2. 

4. 
Average 
Dionte. 

No.  of  Analyses 

236 

161 



89 

SiO, 

•no, 

A1,0. 

Fe,0. 

FeO 

MnO 

MgO 

CaO 

Na,0 

K,0 

PaO, 

per  cent. 
70.47 

.39 

14.90 

1.63 

1.68 

.13 

.98 
2.17 » 
3.31 
4.10 

.24 

percent. 
49.65 

1.41 

16.13 

5.47 

6.45 

.30 
6.14 
9.07 
3.24 
1.66 

.48 

per  cent. 
60.06 

.90 

15.52 

3.55 

4.06 

.21 
3.56 
5.62 
3.28 
2.88 

.36 

per  cent. 
59.19 

.81 

16.51 

3.02 

4.17 

.13 
3.93 
6.47 
3.39 
2.12 

.26 
100.00 

100.00 

100.00 

100.00 

»  Includes  .06%  BaO  and  .02%  SrO. 

Is  basalt  the  basic  pole,  granite  the  acid  pole,  of  a  primitive  differ- 
entiation of  diorite  magma  t  Is  diorite  the  product  of  mixture  of 
primitive,  granitic  crust  and  primary  basalt  still  molten  beneath  t 
Though  the  averages  give  no  answer,  they  tend  to  keep  these  funda- 
mental queww  before  the  eye  of  the  petrologist 

4  The  Averagefl  have  been  arranged  so  aa  generally  to  place 


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DALY.  —  COMPOSITIONS  OF   IGNEOUS-ROCK  TYPES.  239 

together  those  of  plutonics  and  the  corresponding  effusive  rooks.  The 
comparisons  show  the  truth  of  Rosenbusch's  statement  that  the 
effusives  are,  on  the  whole,  somewhat  higher  in  silica  and  alkalies 
and  lower  in  iron  oxides,  lime,  magnesia,  etc.,  than  the  respective 
plutonics. 

The  importance  of  this  rule  is  at  least  two-fold.  It  proves  the 
value  of  Rosenbusch's  primary  division  into  the  deep-seated  types  and 
the  surface  lavas.  It  shows  therewith  one  of  the  reasons  why  the 
Norm  B  Classification  of  igneous  rocks  is  largely  a  failure  so  £Bir  as  either 
the  field-geologist  or  the  student  of  petrogeny  is  concerned. 

Secondly,  the  rule  suggests  clearly  that  at  volcanic  vents  there  is  a 
general  cause  for  the  removal  of  iron,  magnesium,  and  calcium  oxides 
fix)m  the  magmatic  columns  and  that  the  cause  is  more  effective  in  vol- 
canic vents  than  in  the  average  plutonic  body.  The  cause  is  most 
probably  to  be  found  in  the  gravitative  settlement  of  part  of  the  ferro- 
magnesian  and  other  constituents  of  early  cr3rstallization.  These  con- 
stituents may  settle  out  either  as  solid  crystals  or  as  liquid  firactions 
immiscible  near  the  consolidation  point  of  the  magma.  Since,  on  the 
average,  the  column  of  fluid  magma  is  taller  in  an  active  volcanic 
vent  than  in  a  plutonic  mass,  the  overlying  phase  of  the  splitting 
magma  should  be,  in  general,  slightly  more  acid  and  alkaline  than  the 
corresponding  pole  of  differentiation  in  a  deep-seated  mass.  In  the 
nature  of  the  case  the  more  acid-alkaline  pole  is  the  one  most  liable  to 
flow  out  at  the  sur£M^  Though  volcanic  vents  are  much  narrower 
than  plutonic  chambers  and  therefore  subject  to  quicker  chilling,  with 
a  resulting  check  to  differentiation,  this  tendency  is  largely  counter- 
balanced by  the  passage  of  very  hot  gases  through  vents.  The  mere 
agitation  in  the  vents  £9M3ilitates  the  separation.  Whatever  additional 
considerations  are  necessary  to  complete  the  comparison,  it  must  here 
suffice  to  note  that,  as  a  rule,  the  laws  of  solution  as  applied  to 
magmas  seem  to  demand  a  differentiation  with  slow  cooling,  whereby 
a  surface  lava  is  less  basic  and  ferromagnesian  than  the  plutonic  body 
feeding  the  vent  of  that  lava.  The  corroboration  of  Rosenbusch's 
above-mentioned  rule  through  the  world-averages  appears,  therefore,  to 
be  of  use  in  illustrating  one  of  the  world-wide  influences  controlling 
the  origin  of  igneous  rocks. 

Some  special  conclusions  regarding  classification  may  be  noted. 
From  the  averages  it  is  evident  that  dacite  is  the  effusive  correspond- 
ent of  granodiorite  and  not  of  quartz  diorite.    The  contention  of 

'  Quantitative  Classification  of  Igneous  Rooks,  by  W.  Cross,  J.  P.  Idd- 
ings,  L.  V.  Firsson,  and  H.  S.  Washington,  Chicago  and  London,  1903. 


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240  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

American  geologists  that  the  vast  development  of  granodiorite  in  the 
Cordilleras  of  North  and  South  America  should  alone  give  the  name  a 
primary  place  in  rock  classification,  is  again  justified.  The  many 
occurrences  of  dacite  throughout  the  world  represent  just  so  many 
additional  masses  of  cooled  magma  which  were  chemically  identical 
with,  or  closely  related  to  granodiorite.  In  volumetric  importance,  as 
in  mineralogical  and  chemical  individuality,  the  granodiorite  t3rpe 
should  rank  as  of  the  same  order  as  granite  itself. 

Quart?  porphjrry,  liparite,  and  rhyolite  show  that  essential  identity 
of  composition  which  has  long  been  apparent  firom  more  qualitative 
comparison. 

5.  There  is  little  noteworthy  chemical  difference  between  the  aver- 
age pre-Cambrian  granite  and  the  average  granite  of  later  periods. 
How  £5u:  the  differences  in  alumina  and  potash  (columns  1,  2,  and  3) 
are  due  to  the  relative  fewness  of  anal3r8es  of  pre-Cambrian  types 
cannot  be  stated.  In  spite  of  any  such  uneertainties  the  stabili^  of 
the  chemical  type  represented  by  granite  throughout  geological  time 
is  manifest  The  explanation  of  the  fact  may  wdl  be  found  in  Vogt's 
idea  that  granite  is  an  "anchi-eutectic,"  a  crystallized  mother-liquor, 
a  nearly  extreme  product  of  magmatic  differentiation.  It  is  possible 
that  some  of  the  older  pre-Cambrian  granite  represents  the  differentia- 
tion of  primeval  magna.  For  many  reasons  it  seems  probable  that 
most,  if  not  all,  post-Cambrian  granites  are  differentiates  from  syntec- 
tio  magma,  chiefly  composed  of  primary  basaltic  magma  which  has 
locally  redissolved  the  ancient,  acid  shell  overlying.  In  such  case  the 
splitting  of  the  sjmtectic  would  ultimately  give  an  acid  differentiate 
similar  to  that  formed  in  the  primitive  tima  In  general,  differentia- 
tion in  batholiths,  when  well  advanced,  restores  the  condition  tempo- 
rarily disturbed  by  magmatic  assimilation.  On  this  (confessedly 
hjrpothetical)  view  one  may  feel  no  surprise  in  noting  a  &irly  steady 
composition  in  the  granites  from  the  average  oldest  type  to  the 
average  youngest 

Massachusetts  Institutb  of  Technoloqt, 
Boston,  January,  1910. 


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Proceedings  of  the  Ainericftii  Academy  of  Arts  and  Sciences. 
Vol.  XLV.  No.  8.  — Mabch,  1910. 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 


ON  THE  APPLICABILITY  OF  THE  LAW  OF  CORRE- 
SPONDING STATES  TO  THE  JOULE-THOMSON 
EFFECT  IN    WATER   AND   CARBON   DIOXIDE. 


By  Habybt  N.  Davis. 


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Digitized  by 


G( 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 

ON  THE  APPLICABILITY  OF  THE  LAW  OF  CORRESPOND- 
ING  STATES  TO  THE  JOULE-THOMSON  EFFECT  IN 
WATER  AND  CARBON  DIOXIDR 

By  Harvey  N.  Davis. 
Presented  by  John  Trowbridge,  December  8,  1909;  Received  December  30,  1909. 

In  the  classical  plug  experiments  of  Joule  and  Kelvin  certain  gases 
were  forced  by  pressure  through  a  porous  plug  under  circumstances 
which  permitted  the  accurate  measurement  of  any  small  resulting 
change  in  their  temperature.  It  can  easily  be  shown  that  a  perfect 
gas  would  show  no  such  change.  As  a  matter  of  &ct,  hydrogen  was 
found  to  be  slightly  warmer  on  the  low  pressure  side  of  such  a  plug 
than  on  the  high  pressure  side,  while  air,  oxygen,  nitrogen  and  carbon 
dioxide  were  slightly  cooler.  The  ratio  of  the  observed  drop  in  tem- 
perature to  the  drop  in  pressure  in  such  a  plug  has  ever  since  been 
called  the  Joule-Thomson  coefficient 

The  results  of  such  experiments  afford  the  best  known  means  of 
computing  corrections  for  reducing  the  temperature  scale  of  a  gas 
thermometer  to  Kelvin's  absolute  thermodynamic  scala  For  this  pur- 
pose one  must  know  the  Joule-Thomson  coefficient  of  the  gas  in  the 
thermometer  at  all  temperatures  between  0^  C.  and  the  t""  C.  at  which 
the  correction  is  desired.  Unfortunately,  none  of  the  experiments 
either  of  Joule  and  Kelvin  or  of  any  of  their  successors  are  at  temper- 
atures other  than  between  0°  C.  and  100**  C,  except  for  certain  inver- 
sion points  of  Olschewsky  obtained  under  circumstances  not  yet  fully 
understood.  These  are  not  enough  to  give  a  direct  determination  of 
the  absolute  thermodynamic  scale  above  100^.  In  order  to  get  one 
indirectly,  it  has  been  customary  to  assume  that,  at  least  in  the  five 
gases,  hydrogen,  oxygen,  nitrogen,  carbon  dioxide  and  air,  the  Joule- 
Thomson  effect  obeys  the  law  of  corresponding  states.  That  is,  it  is 
assumed  that  if  the  coefficient  for  each  gas  is  expressed  in  terms  of  the 
critical  pressure  and  temperature  of  that  gas  as  units,  and  if  the 
results  are  plotted  against  the  temperature  expressed  in  the  same 


i 


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244 


PROCEEDINGS  OF  THE  AMERICAN  ACADEBfY. 


"reduced*'  units,  the  resulting  curves  will  be  identical  for  all  five 
gases.  The  observations  at  ordinary  temperatures  on  hydrogen,  whose 
critical  temperature  is  very  low,  will  then  correspond  to  observations 
at  very  high  temperatures  on  other  gases,  and  will  afford  a  useful 
though  precarious  extrapolation  of  their  curves  to  above  1000°  C. 


i 

A-  tm. 

■  -M, 
F.N. 

% 

%\ 

V" 

\ 

■ 

\ 

\ 

V. 

Vfc 

^ 

^ 

^ 

\ 

^ 

"— 

•*- 

__ 

.     < 

, 

.^ 

«_ 

«_ 

H 

_ 

... 

.. 

^i— 

^ 

> 

H 

; 

1 

\ 

r 

Figure  1.  Reduced  Joule-Tliomson  coefficient,  fi',  plotted  against  reduced 
temperature.  From  Buckingham's  paper  in  the  Bulletin  of  the  Bureau  of 
Standards,  May,  1908.    (See  the  note  at  the  end  of  this  paper.) 

The  experimental  justification  of  this  use  of  the  law  of  correspond- 
ing states  is,  as  yet,  meager.  Figure  1,  which  is  taken  firom  a  recent 
paper  by  Buckingham,  represents  the  available  data.  It  will  be  seen 
that  neither  the  hydrogen  nor  the  carbon  dioxide  observations  overlap 
those  on  the  other  tiiree  gases,  and  that  the  points  for  each  of  these 


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DAVIS.  —  THE  LAW  OP   COHHESPONDINO  fiTTATES.  245 

three  gases  show  sach  disorepanoies  among  themselves  as  to  make  un- 
certain any  judgment  as  to  their  agreement  with  each  other.  What 
evidence  there  is,  is  in  &vor  of  the  validity  of  the  law  of  corresponding 
states ;  but  an  accurate  verification  of  it,  especially  for  two  substances 
with  very  different  critical  temperatures,  would  put  the  whole  subject 
on  a  much  more  satis&ctory  basis. 

In  this  paper  it  will  be  shown  that  this  law  is  verified  for  carbon 
dioxide  and  water  within  the  limit  of  error  of  the  available  observa- 
tions on  water!  This  limit  of  error  is  unfortunately  quite  as  great  as 
that  of  the  oxygen,  nitrogen  and  air  observations  plotted  in  Figure  1. 
Nevertheless,  a  multiplication  of  evidence,  even  of  an  inferior  sort,  is 
often  valuable,  and  in  this  case  there  is  an  added  interest  because,  if 
water,  which  is  known  to  be  anomalous  in  many  ways  through  associa- 
tion, is  found  to  obey  the  law  of  corresponding  states  as  to  its  Joule- 
Thomson  effect^  it  is  probable  that  the  permanent  gases  will  also  obey 
l^tlaw. 

There  are  four  sets  of  experiments  on  water  which  can  be  used.  They 
were  all  undertaken  for  the  purpose  of  determining  the  variation  of 
the  specific  heat  of  superheated  steam  with  pressure  and  temperature, 
an  investigation  which  has  since  been  more  satisfiu^torily  accomplished 
in  other  ways.  Of  the  four  observers,  Griessmann^  used  a  porous 
plug  very  much  like  that  of  Joule  and  Thomson,  while  the  other  three, 
Grindley,  ^  Peake^  and  Dodge,^  used  what  engineers  call  a  throttiing 
or  wiredrawing  calorimeter.  The  essential  part  of  this  instrument  is  a 
small  orifice  through  which  the  steam  flows  tumultuously  firom  one 
chamber  into  another,  the  high  velocity  of  the  steam  being  subse- 
quently destroyed  by  firiction  at  the  sur&ces  of  the  walls  of  the  second 
chamber  and  within  the  steam  itself.  During  this  process  the  kinetic 
energy  of  the  steam  is  transformed  into  heat,  all  of  which,  if  the 
thermal  insulation  is  perfect,  goes  back  into  the  steam.  If  this  trans- 
formation is  complete,  the  throttiing  calorimeter  is  exactly  equivalent 
to  a  porous  plug.  To  ensure  this  completeness,  one  of  the  three  ob- 
servers (Peake)  put  a  quantity  of  wire  gauze  in  the  path  of  the 
steam  firom  the  orifiee,  and  another  (Dodge)  used  at  times  four  small 
orifices  instead  of  one  larger  one  witliout  noticeable  change  in  the 
results.    Grindley  took  no  especial  precautions  of  this  sort,  but  the 


^  Zeitsch.  Ver.  d.  Ing.,  1903,  47,  1852  and  1880;  also  ForBchungBaib.,  Ver. 

Ing.,  1904,  13,  1. 

«  Phil.  Trans.,  1900-1,  194A,  1. 

»  Proc.  Roy.  Soc.,  1905,  A,  76,  185. 

«  Jour.  Am.  Soc.  Mech.  Engs.,  1907,  28,  1265;  and  1908,  80,  1227. 


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246  PROCEEDINGS  OF  THE  AMEBICAN  ACADEBfT. 

fieict  that  his  results  agree  with  those  of  Peake  and  of  Oriessmann 
shows  that  none  were  necessary  in  his  apparatus. 

This  agreement  is  in  many  other  ways  a  significant  one,  for  it  is 
inconceivable  in  view  of  the  great  differences  in  almost  every  respect 
between  the  details  of  the  three  sets  of  apparatus,  that  any  serious 
systematic  errors  should  have  been  present  in  any  one  of  the  sets  of 
results  without  completely  destroying  the  agreement  between  them. 
This  is  particularly  true  in  the  matter  of  heat  insolation,  where  the 
precautions  taken  by  the  three  observers  had  almost  nothing  in  com- 
mon except  effectivenesa  In  Dodge's  work  also  this  point  was  care- 
fully considered  but  the  results  are  not  so  satisfactory.  They  will  be 
discussed  and  a  correction  computed  on  page  262. 

In  all  four  cases  the  thermometry  is  the  weakest  part  of  the  work. 
It  is  especially  unfortunate  for  the  present  purpose  that  the  original 
aim  of  the  experiments  did  not  require  or  suggest  that  the  difference 
between  the  temperatures  before  and  after  the  expansion  be  measured 
as  such,  as  by  a  thermocouple  or  a  differential  resistance  thermometer. 
The  subtraction  which  must  now  be  made  of  one  reading  on  a  mercury 
thermometer  from  another  reading  on  another  thermometer,  to  give 
a  small  difference,  is  not  a  particularly  accurate  method  of  getting 
that  differenca  The  same  is  true  of  the  determination  of  the  pressure 
drop.  The  individual  measurements  were  comparatively  good,  being 
made  in  three  of  the  cases  with  carefully  calibrated  Bourdon  or  spring 
gauges,  and  in  the  fourth  case  by  an  extra  measurement  of  the  temper- 
ature of  resaturation  of  the  low  side  steam,  but  the  differences  needed 
in  this  paper  must  inevitably  be  subject  to  comparatively  large  errors. 
The  reader  must  therefore  be  prepared  for  much  lack  of  self-consistency 
in  the  results.  It  is  hoped  that  the  errors  are  largely  incidental  errors 
such  as  can  be  eliminated  by  averaging. 

Grindley's  experiments  were  performed  in  England  during  the  winter 
of  1897-8.  His  data  are  given  in  full  in  his  paper  and  are  plotted  in 
his  Diagram  5  reproduced  here  as  Figure  2.  It  will  be  observed  that  in 
every  case  his  steam  drops  several  pounds  in  pressure  before  it  leaves 
the  saturation  line.  This  he  explained  by  means  of  a  curious  and  now 
discredited  "heat  of  gasification."  A  better  explanation  is  that  his 
steam  was  initially  slightly  wet  Since  this  source  of  error  affects 
the  high  side  data  of  every  one  of  his  experiments,  it  might  seem  that 
all  of  his  work  must  be  rejected.  It  will  be  noticed,  however,  that  his 
experiments  are  grouped  into  runs ;  that  is,  if  in  a  certain  experiment 
steam  in  a  certain  initial  condition  has  been  throttled  to  a  certain  low 
side  pressure  and  temperature,  then  in  later  experiments  of  the  same 
group,  steam  in  the  same  initial  condition  is  more  and  more  throttled 


Digitized  by  LjOOQIC 


DAVIS. -^  THE   LAW   OF   CORRESPONDING   STATES. 


247 


to  lower  low  side  pressares  and  temperatures,  which  when  plotted 
together  form  the  tlurottling  carves  of  Figure  2.  Since  it  is  character- 
istic of  throttling  l^t  the  total  heat,  J7,  of  the  steam  is  the  same  on 
the  high  and  low  sides,  it  foUows  that  H  is  constant  along  the  whole 
of  any  throttling  curve,  and  that  any  two  low  side  points  of  a  run  may 
be  ts^en,  one  as  describing  the  high  side  conditions  and  the  other  as 
describing  the  low  side  conditions  of  a  possible  throttling  experiment 


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Figure  2.  Grindley's  throttling  curves.  Abscissae  are  pressures  in  lbs. 
per  sq.  in.  Ordinates  are  Fahrenheit  temperatures.  From  his  paper  in  the 
Philosophical  Transactions. 

In  other  words,  the  slope  of  a  throttling  curve  at  any  point  is  a  value 
of  the  Joule-Thomson  coefficient  under  corresponding  conditions.  It 
is  therefore  possible,  even  while  rejecting  all  of  Grindley's  high  side 
points  together  with  that  one  of  the  low  side  points  which  is  obviously 
affected  by  the  same  error,  to  use  the  remaining  low  side  points  in 
pairs.  There  were  101  of  them  in  all,  Ijring  on  seven  throttling  curves. 
They  were  first  grouped  so  as  to  give  29  average  points,  the  averaging 
being  justified  by  the  fieict  that  for  a  range  of  not  more  than  5^,  a 
throttling  curve  can  be  considered  straight  These  means  were  then 
taken  two  by  two  consecutively  to  give  22  values  of  the  Joule-Thomson 


Digitized  by  LjOOQIC 


248 


FBOCESDINGS  OF  THE  AMERICAN  AOADEUT* 


coefficient,  each  of  idiioh  is  assximed  to  oonespo&d  to  the  mean  of  the 
high  and  low  side  tempemtmes  firom  which  it  was  obtained.  The 
yalaes  of  the  coefficient  have  been  '*  ledaced  "  by  mohiplying  by  2.56, 

TABLE  I. 

StTiaCABT  OF  GtUNDLBT's  ThBOTTLINO  ExFBBIMBNTS. 


Curve. 

No.  of 
Points. 

Avenge  Preaaure 

Avenge  Tempenture 

Reduced 

Joule- 
Thomson 
CkMfficieot. 

Ibe.per 
•q.m. 

Redueed. 

Fahr. 

Reduced. 

A 

B 

C 

D 

E 

Pfl 
F6 

1-1 
1-2 
2-1 
1-2 
2-2 
2-1 
1-1 

2-1 
1-3 

a-1 

1-2 
2-3 

3-6 

4-8 
8-4 

4-3 
5-1 

8-5 
5-4 

6-7 
6-5 

141.6 
121.7 
101.6 
81.7 
61.0 
40.3 
22.7 

87.5 
74.7 
58.2* 
40.3 
*     25.5 

50.7 
37.5 
24.3 
12.4 

26.3 
12.4 

24.2 
12.8 

12.2 
11.5 

0.0480 
0.0412 
0.0344 
0.0277 
0.0207 
0.0137 
0.0077 

0.0296 
0.0253 
0.0197 
0.0137 
0.0086 

0.0172 
0.0127 
0.0082 
0.0042 

0.0089 
0.0042 

0.0082 
0.0043 

0.0041 
0.0030 

360.2 
353.9 
347.4 
340.5 
832.3 
322.9 
315.0 

326.3 
321.0 
313.6 
306.1 
299.9 

288.0 
281.4 
274.7 
268.4 

,     267.2 
259.5 

251.7 
245.1 

229.3 
228.7 

0.714 
0.708 
0.703 
0.697 
0.600 
0.682 
0.675 

0.685 
0.680 
0.673 
0.667 
0.662 

0.651 
0.645 
0.640 
0.634 

0.633 
0.626 

0.620 
0.613 

0.600 
0.600 

0.82 
0.79 
0.86 
0.92 
1.12 
1.20 
1.11 

1.00 
1.13 
1.15 
1.00 
1.14 

1.27 
1.29 
1.31 
1.39 

1.40 
1.47 

1.39 
1.57 

1.74 
1.69 

Column  2  indioates  tiie  nmnbor  of  obs^rvatiops  invdved  in  eseh 

used  as  the  hi^  side  point  of  the  pair  included  6  of  the.  points  plotted 
in  figure  2,  while  that  used  as  the  low  side  point  involved  7. 

a  £EM^r  which  is  the  ratio  of  the  critical  prcBSure  of  water  expressed  in 
ponnds  per  square  inch  (2947  lbs.  per  sq.  in.  or  200  atmospheres  ^)  to 
its  critical  temperature  in  Fahrenheit  degrees  absolute  (1149^  F.  abe. 
or  365^  C.  ord.^.    The  results  are  summiuized  in  Table  I,  which  gives 

i  Qkilletet  and  Colaideau,  Jour,  de  Fhys.,  1891, 10, 333. 


Digitized  by  LjOOQIC 


DATIS.  —  THE   LAW   OF   CORRESPONDING   STATES. 


249 


also  the  corresponding  "  reduced  "  pressures  and  temperatures.    These 
values  of  the  coefficient  are  plotted  as  open  circles  in  Figure  6. 

The  experiments  of  Griessmann  were  performed  in  the  mechanical 
engineering  laboratory  of  the  "  Technische  Hochschule  "  in  Dresden, 
and  were  published  in  1903.  They  were  primarily  undertaken  to  test 
the  heat  of  gasification  hypothesis  already  mentioned,  and  are  a  critical 


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FioiTRB  3.  Griessmann's  throttling  curves.  Abscissae  are  pressures  in  kg. 
per  sq.  cm.  Ordinates  are  Centigrade  temperatures.  From  his  paper  in  the 
Forschungsarbeiten. 

repetition  of  Ghindley's  work  The  data  are  given  in  full  in  the  paper 
in  the  Forschungsarbeiten,  and  are  plotted  in  his  Figure  7,  which  is 
reproduced  here  as  Figure  3*  He  records  13  runs  with  87  sets  of  low 
side  observations,  which  with  the  13  high  side  observations  give  100 
points  on  his  diagram.  Of  these,  three  points  on  curve  2,  one  point 
on  curve  7,  three  points  on  curve  8,  and  three  points  on  curve  9  lie  so 
&r  off  the  smooth  curves  determined  by  the  neighboring  points  that 
diey  have  arbitrarily  been  omitted  from  these  caJculations.  The  re- 
maining 90  points,  lying  on  11  curves,  have  been  grouped  in  44  means 


Digitized  by  LjOOQIC 


250 


PROCEEDINGS   OF  THE   AMERICAN   ACADEBfT. 


TABLE  n. 

SUMMABT  OF  GRIESSMANN's  OBSERVATIONS. 


Curve. 

No.  of 
PointB. 

Average  Pressure 

Average  Temperature 

Reduced 

Joule- 
Thomson 
Coefl&cient. 

kgs./sq.  cm. 

Reduced. 

Cent. 

Reduced. 

1 

2-2 
2-1 

2.19 
1.37 

0.0106 
0.0066 

129.8 
126.1 

0.632 
0.625 

1.33 
1.64 

2 

1-1 
1-1 

2.86 
1.42 

0.0138 
0.0069 

137.6 
131.4 

0.644 
0.634 

1.34 
1.56 

3 

2-2 
2-2 

2.97 
1.81 

0.0144 
0.0088 

139.2 
134.4 

0.646 
0.639 

1.26 
1.44 

4 

2-5 
5-4 
4-2 

4.35 

2.85 
1.46 

0.0210 
0.0138 
0.0071 

148.2 
142.3 
136.5 

0.660 
0.651 
0.642 

1.19 
1.30 
1.47 

5 

1-1 
1-1 
1-1 

4.11 
2.53 
1.52 

0.0199 
0.0122 
0.0074 

149.2 
142.3 
138.2 

0.662 
0.651 
0.644 

1.27 
1.23 
1.44 

6 

2-2 
2-3 
3-4 
4-2 

5.36 
4.18 
2.98 
1.64 

0.0260 
0.0202 
0.0144 
0.0079 

156.1 
152.2 
147.9 
142.5 

0.673 
0.667 
0.660 
0.651 

1.07 
1.06 
1.22 
1.42 

7 

2-2 
2-3 

5.56 
3.64 

0.0219 
0.0176 

160.3 
154.1 

0.679 
0.670 

0.93 
1.18 

8 

3-2 
2-1 

6.37 
4.90 

0.0308 
0.0237 

165.4 
161.0 

0.687 
0.680 

0.88 
1.08 

9 

1-2 
2-1 
1-1 

6.46 
3.73 
1.46 

0.0313 
0.0180 
0.0071 

166.9 
158.2 
150.2 

0.690 
0.676 
0.663 

0.84 
1.13 
1.25 

10 

2-2 
2-1 
1-1 
1-1 

8.22 
5.02 
2.55 
1.55 

0.0398 
0.0243 
0.0123 
0.0075 

174.1 
164.7 
156.8 
152.8 

0.701 
0.686 
0.673 
0.668 

0.88 
0.99 
1.23 
1.29 

11 

1-2 
2-2 
2-1 
1-1 
1-1 
1-1 

9.05 
7.17 
5.53 
3.89 
2.48 
1.52 

0.0438 
0.0347 
0.0268 
0.0188 
0.0120 
0.0074 

176.6 
171.9 
167.3 
162.2 
157.4 
153.8 

0.705 
0.698 
0.690 
0.682 
0.675 
0.669 

0.75 
0.88 
0.96 
1.01 
1.19 
1.25 

Digitized  by  LjOOQIC 


DAVIS.  —  THE   LAW   OF   CORRESPONDING   STATES. 


251 


which  have  been  used  as  above  to  give  the  33  values  of  the  Joale- 
Thomson  coefficient  which  are  presented  in  the  following  table.  They 
are  plotted  as  circles  with  diagonal  crossbars  in  Figure  6.  The  re- 
duction fiM^tor  in  this  case  is  0.324,  Oriessmann's  pressures  being  in 
kilograms  per  square  centimeter  and  his  tQmperatures  in  Centigrade 


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FiouRB  4.  Peake's  throttling  curves.  From  his  paper  in  the  Proceedings 
of  the  Royal  Society. 

Peake's  experiments  were  carried  out  in  the  engineering  laboratory 
of  Cambridge  University  in  England  and  were  begun  in  the  &11  of 
1898.  The  appearance  in  1900  of  Grindley's  work  along  almost  iden- 
tical lines  at  first  inclined  Peake  to  discontinue  his  investigation,  but 
a  careful  examination  of  Orindley's  data  as  compared  with  his  own, 
led  him  to  the  discovery  in  both  of  the  heat  of  gasification  error  already 
mentioned  and  to  its  true  explanation,  and  his  experiments  were  con- 
tinued with  this  particular  point  in  view.  His  apparatus  was  there- 
fore redesigned  so  as  to  bring  the  steam  as  quickly  as  possible  firom  the 
boiler  to  the  orifice  to  avoid  condensation  on  the  way,  and  he,  like 


Digitized  by  LjOOQIC 


252 


'PBOCEEDINGS   OF  THE  AHEBICAN  ACADEMY. 


TABLE  ni. 
SmcMART  OF  Peakb's  Thbottlino  Expebimentb. 


Avermge  PreBsure 

Average  Temperature 

Reduced 

Curve. 

No.  of 
Pointa. 

Joule- 
Thomson 

mm.  of  Ha.1 

Reduced. 

Cent. 

Reduced. 

Coefficient. 

A 

3-3 

9724 

0.0639 

192.3 

0.730 

0.86 

3-3 

8503 

0.0569 

187.8 

0.722 

0.94 

3-2 

7632 

0.0502 

184.4 

0.716 

0.90 

2-3 

6282 

0.0413 

179.4 

0.709 

0.87 

3-2 

4617 

0.0304 

173.1 

0.699 

0.94 

2-4 

3239 

0.0213 

167.8 

0.690 

0.87 

4-4 

1925 

0.0127 

162.5 

0.683 

1.05 

B 

4-9 

7594 

0.0499 

181.6 

0.712 

0.97 

9-3 

6128 

0.0403 

175.6 

0.703 

0.97 

a-2 

4735 

0.0312 

170.0 

0.695 

0.95 

2-2 

3359 

0.0221 

164.3 

0.686 

1.01 

2r-2 

1914 

0.0126 

158.2 

0.675 

1.00 

C 

2-2 

6162 

0.0405 

171.8 

0.697 

1.09 

2-2 

5762 

0.0379 

170.0 

0.694 

1.10 

2-1 

5017 

0.0337 

166.6 

0.689 

1.05 

1-1 

4163 

0.0274 

162.8 

0.683 

1.13 

1-1 

3030 

0.0199 

157.4 

0.675 

1.11 

1-1 

1513 

0.0100 

150.6 

0.665 

1.06 

D 

1-1 

4212 

0.0277 

156.6 

0.674 

1.05 

1-1 

3960 

0.0260 

155.3 

0.671 

1.14 

1-1 

3547 

0.0233 

153.4 

0.668 

1.11 

1-1 

3035 

0.0200 

151.0 

0.665 

1.17 

1-1 

2502 

0.0165 

148.3 

0.661 

1.17 

1-2 

1984 

0.0131 

145.6 

0.656 

1.36 

2r-\ 

1460 

0.0096 

142.7 

0.652 

1.29 

1-1 

986 

0.0065 

140.0 

0.648 

1.53 

E 

2-1 

2045 

0.0135 

135.4 

0.640 

1.41 

1-1 

1468 

0.0096 

132.1 

0.635 

1.35 

1-1 

1050 

0.0069 

129.6 

0.631 

1.44 

F 

1-1 

1404 

0.0092 

122.2 

0.619 

1.66 

1-1 

1044 

0.0069 

119.7 

0.615 

1.63 

1 

All  of  Peake's  pressures  were  computed  from  suitable  temperature 

meai 

mrements  by  means  of  Regnault's  steam  table.    As  a  special  pre- 

caut 

ion  they  have  been  recomputed  with  the  new  table  of  Holbom  and 
[ling,  and  are  therefore  left  in  the  metric  units  in  which  they  were 

Hen] 

thus 

found.    The  "  reduction  factor  "  to  give  /  is  238. 

Digitized  by  LjOOQlf 


DAVIS.  —  THE  lAW  OP   COBBSSPONDINO  STATES. 


253 


Orieesmann,  practioally  elimiiuited  the  effect  whioh  OrincUey  had  found. 
His  results  are  plotted  as  his  Figure  4  which  is  reproduoed  as  Figure  4 
of  this  paper.  He  records  10  runs  with  68  low  side  observations, 
making  78  points  in  alL  Two  of  the  high  side  points  and  two  of 
the  low  side  points  still  show  traces  of  the  wet  steam  effect  and  have 
therefore  been  rejected.    The  other  low  side  points  are  much  more 


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.  FiouBB  5.  Dodge's  throttling  curves.  Plotted  from  the  original  data 
sheets. 

self-consistent  than  Griessmann's.  The  ten  runs  correspond  to  only 
six  throttling  curves.  The  74  satis&ctory  points  were  grouped  into 
83  means,  giving  the  27  values  of  die  Joule-Thomson  coefficient  which 
are  presented  in  TaUe  UI  and  Ure  plotted  as  circles  with  horizontal 
crosdi)ar8  in  Figure  6. 

Dodge  worked  in  the  laboratories  of  the  O^aeral  Electric  Company 
at  Schenectady,  N.  T.,  from  1901  to  1906.  His  data  were  not  given 
at  all  in  his  first  p^>er  and  were  publisbed  <»ily  in  part  in  his  second 


iigitized  by 


Google 


254  PROCEEDINGS  OF  THE  AMERICAN  ACADEHT. 

paper.  What  follows  is  based  on  a  study  of  the  original  records,  the 
generous  loan  of  which  for  this  purpose  is  very  gratefully  acknowledged. 
On  his  advice,  the  first  26  of  his  92  runs  were  disregarded  as  prelimin- 
ary, and  9  other  runs  were  rejected,  either  because  of  experimental 
mishaps,  or  because  the  log  did  not  show  satisfiu^torily  steady  condi- 
tions. The  data  selected  were  corrected  for  probable  radiation  and 
conduction  losses  in  the  way  explained  in  the  appendix  of  this  paper 
(page  262). 

Of  the  47  selected  tests,  14  were  like  those  already  discussed,  except 
that  the  temperatures  were  much  higher,  the  high  side  steam  being 
superheated  instead  of  saturated.  The  results  of  these  14  tests  are 
plotted  in  Figure  5.  It  wiU  be  noticed  that  in  every  case  a  smooth  curve 
through  the  low  side  points  runs  considerably  below  the  corresponding 
high  side  pointy  just  as  did  Grindley's  curves.  In  Orindley's  case  this 
was  because  the  entering  steam  carried  water  in  suspension,  the  pres- 
ence of  which  made.the  true  total  heat  of  the  incoming  mixture  less 
than  its  apparent  total  heat  regarded  as  homogeneous  saturated  steam, 
and  dropped  all  the  low  side  points  onto  throttling  curves  lower  than 
those  on  which  they  apparently  belonged.  A  similar  phenomenon  may 
be  in  evidence  in  Dodge's  case,  for  although  the  incoming  steam  was 
superheated,  it  may  still  have  been  canying  in  suspension  a  part  of  the 
water  which  had  been  sprayed  into  it  for  temperature  regulation  just 
before  it  reached  the  high  side  chamber.^  It  must,  however,  be  ad- 
mitted that  if  this  explanation  is  to  account  for  the  whole  of  tiie  dis- 
crepancy in  Dodge's  results,  an  extraordinarily  large  amount  of  water 
in  suspension  must  have  reached  the  high  side  chamber  —  fix)m  one  to 
one  and  a  half  per  cent  of  the  whole  weight  present.  It  is  therefore 
probable  that  there  is  another  source  of  error  not  yet  discovered. 
Nevertheless,  if  the  high  side  points  are  disregarded  and  the  low  side 
points  are  taken  together  in  pairs  as  in  Orindley's  case,  it  is  probable 
that  tiie  resulting  values  of  the  Joule-Thomson  coefficient  will  be 
trustworthy. 

Each  of  the  14  runs  was  handled  separately.  It  did  not  seem  best 
to  take  consecutive  points  together  as  in  the  other  cases,  because,  at  the 
very  high  temperatures  here  dealt  with,  the  temperature  difference  be- 
tween consecutive  points  is  much  smaller  than  at  lower  temperatures, 
and  so  an  error  in  either  observation  would  make  much  more  difference 
in  the  coefficient.  Furthermore,  the  throttling  curves  are  more  nearly 
straight  in  this  range  than  at  lower  temperatures.  The  lowest  point 
of  a  run  has  therefore  been  taken  ¥rith  the  point  just  beyond  the  middle 

*  See  the  work  of  Knoblauch  and  Jakob,  Forschungsaib.,  1006,  84,  109. 


Digitized  by  V^OOQlf 


DAVIS.  —  THE   LAW  OP   COBRESPONDING   STATES. 


255 


TABLE  IV. 

SUMMABT  OF  DoDGE's  ThBOTTUNO  CuRVB  TeSTS. 


Test. 

Average  Pressure 

Avermge  Temperature 

Reduced 

Joule- 
Thomson 
CJoefficient. 

lbs.  per  sq.  in. 

Reduced. 

Fahr. 

Reduced. 

70  o 

36.5 
67.6 
85.2 

0.0124 
0.0196 
0.0289 

663 
569 
672 

0.892 
0.895 
0.899 

0.52 
0.39 
0.36 

706 

64.2 
73.0 

0.0184 
0.0248 

476 
479 

0.816 
0.818 

0.38 
0.46 

71 

36.5 
67.5 
84.9 

0.0124 
0.0195 
0.0288 

356 
362 
369 

0.711 
0.716 
0.722 

0.72 
0.62 
0.75 

72 

36.5 
67.4 

0.0124 
0.0195 

621 
523 

0.855 
0.857 

0.30 
0.20 

73 

36.7 
52.4 
84.8 

0.0125 
0.0178 
0.0288 

418 
424 
248 

0.765 
0.770 
0.774 

0.55 
0.48 
0.44 

74 

64.0 

72.6 

102.2 

0.0183 
0.0246 
0.0347 

522 
627 
630 

0.856 
0.860 
0.863 

0.32 
0.27 
0.32 

76 

84.3 
114.6 

0.0286 
0.0389 

373 
381 

0.726 
0.733 

0.58 
0.52 

76 

127.3 
101.0 

0.0432 
0.0343 

534 
627 

0.866 
0.860 

0.32 
0.24 

77 

200.6 
225.6 

0.0681 
0.0765 

547 
651 

0.877 
0.881 

0.50 
0.44 

78 

67.5 
105.0 
142.0 

0.0195 
0.0356 
0.0482 

668 
576 
680 

0.895 
0.902 
0.906 

0.35 
0.32 
0.36 

79 

57.9 
105.0 
.142.0 

0.0196 
0.0356 
0.0482 

627 
635 
648 

0.860 
0.867 
0.878 

0.50 
0.49 
0.67 

80 

90.7 
120.4 
152.0 
184.4 

0.0308 
0.0409 
0.0516 
0.0626 

636 
639 
643 
648 

0.867 
0.870 
0.874 
0.878 

0.43 
0.39 
0.34 
0.35 

81 

90.3 
120.3 
152.0 
184.0 

0.0306 
0.0409 
0.0516 
0.0625 

484 
489 
495 
601 

0.822 
0.826 
0.832 
0.837 

0.54 
0.49 
0.48 
0.47 

82 

90.3 
120.3 
152.0 
184.0 
213.5 

0.0306 
0.0409 
0.0516 
0.0625 
0.0724 

434 
441 
447 
452 
458    " 

0.779 
0.785 
0.790 
0.795 
0.800 

0.57 
0.62 
0.54 
0.52 
0.42 

Digitized  by  LjOOQIC 


256 


PBOCBSDINOfl  OF  THX  AMEBICAN  ACADBlfT. 


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Digitized  by  VjOOQIC 


DAVIS.  —  THE    LAW   OF   CORRESPONDING   STATES.  257 

of  that  run,  and  so  on,  no  point  being  used  more  than  once.  The  41 
valaes  of  the  coefficient  obtained  in  this  way  are  summarized  in  Table 
IV,  and  are  plotted  as  small  open  circles  in  Figure  6.  They  lie  in  the 
range  between  0.8  and  0.9  reduced  temperature,  filling  a  gap  of  con- 
siderable importance  in  that  figure. 

The  remaining  33  of  the  selected  runs  cannot  be  handled  in  the  same 
simple  way,  because  the  experiments  which  make  up  each  of  these  runs 
are  not  so  related  as  to  give  throttling  curves,  but  are  related  in  an- 
other way  much  better  suited  to  the  original  purpose  of  the  work,  but 
much  less  suited  to  the  present  purpose.  Nevertheless  the  gap  be- 
tween 0.7  and  0.9  in  Figure  6  is  so  important  that  it  is  desirable  to 
use  every  bit  of  information  about  it  that  can  be  obtained.  These  33 
additional  runs  have  therefore  been  discussed  at  some  length  in  the 
'  appendix  of  this  paper,  and,  suitable  corrections  for  the  high  side  tem- 
peratures having  been  applied,  the  more  &vorable  of  them  have  been 
used  to  get  the  77  values  of  the  Joule-Thomson  coefficient  which  are 
presented  in  Table  IV.  These  values  are  plotted  in  Figure  6  as  small 
black  dots.  They  are  more  self-consistent  than  the  values  in  Table  IV 
above,  but  their  trustworthiness  is  more  uncertain  as  each  involves  two 
uncertain  corrections  of  the  original  data  instead  of  one.  They  are 
nevertheless  valuable  corroborative  evidenca  , 

Figure  6  is  now  complete.  The  82  values  of  the  coefficient  which  are 
summarized  in  Tables  I.,  II.,  and  III.,  lie  in  the  range  between  0.6  and 
0.7  units  of  reduced  temperature,  and  form  a  broad  but  reasonably  well 
defined  band,  within  which  there  is  no  evident  tendency  for  either  of 
the  three  sets  of  points  to  separate  themselves  from  the  others.  The 
118  values  of  the  coefficient  which  were  computed  from  Dodge's  data, 
and  which  are  presented  in  Tables  IV.  and  V.,  lie  between  0.7  and  0.9  and 
form  a  satisfisu^tory  continuation  of  the  band.  Above  0.9  are  five  large 
circles  with  diagonal  crossbars  representing  on  the  same  scale  the  origi- 
nal observations  of  Joule  and  Thomson  on  carbon  dioxide,  six  large 
circles  without  crossbars  representing  Kester's  ^  experiments,  and  one 
large  circle  with  a  horizontal  crossbar  representing  Natanson's  *  result. 
These  circles  form  a  surprisingly  good  continuation  of  the  curve  sug- 
gested by  the  band  of  steam  points.  The  law  of  corresponding  states  is 
therefore  verified  for  carbon  dioxide  and  water  within  the  limits  of  error 
of  the  observations  on  the  two  substances. 

The  various  values  in  Tables  I  to  V  have  been  grouped  according  to 
temperature  and  averaged.     For  this  purpose  a  number  was  assigned 

'  Phys.  Zeitsch.,  1905,  6,  44;  repeated  and  revised  in  Phys.  Rev.,  1905,  21, 
260. 

•  Wied.  Ann.,  1887,  31,  502. 

VOL.   XLV.  —  17 


Digitized  by  VjOOQIC 


258 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


TABLE  V. 
Summary  of  Dodge's  Main  Series  op  Tests  (Corrected  as  Described). 


Average  Pressure 

Average  Temperature 

Reduced 

Teat. 

Joule- 
Thomson 

lbs.  per  sq.  in. 

Reduced. 

Fahr. 

Reduced. 

Coefficient. 

2S 

328 

0.112 

558 

0.886 

0.48 

n 

tt 

534  • 

0.865 

'  0.50 

11 

tt 

503 

0.839 

0.52 

n 

tt 

430 

0.775 

0.55 

« 

tt 

463 

0.804 

0.56 

<( 

tt 

574 

0.901 

0.49 

29 

380 

0.129 

568 

0.895 

0.42 

<< 

tt 

544 

0.875 

0.42 

ft 

tt 

520 

0.853 

0.45 

it 

tt 

483 

0.821 

0.49 

n 

It 

460 

0.803 

0.54 

It 

tt 

504 

0.839 

0.51 

it 

it 

538 

0.869 

0.45 

31 

330 

0.112 

511 

0.846 

0.41 

tt 

tt 

474 

0.813 

0.48 

•    tt 

tt 

441 

0.785 

0.47 

32 

379 

0.129 

558 

0.886 

0.38 

**       • 

tt 

540 

0.871 

0.40 

tt 

tt 

524 

0.857 

0.42 

tt 

tt 

507 

0.842 

0.45 

tt 

ft 

493 

0.830 

0.48 

tt 

tt 

469 

0.809 

0.54 

tt 

tt 

444 

0.787 

0.58 

36 

385 

0.131 

563 

0.891 

0.39 

(( 

tt 

539 

0.870 

0.41 

It 

tt 

516 

0.850 

0.44 

tt 

tt 

491 

0.829 

0.48 

it 

tt 

460 

0.801 

0.54 

37 

338 

0.115 

571 

0.898 

0.39 

tt 

tt 

545 

0.875 

0.40 

ft 

tt 

516 

0.850 

0.43 

tt 

tt 

480 

0.819 

0.50 

tt 

tt 

456 

0.798 

0.54 

41 

205 

0.070 

562 

0.890 

0.36 

tt 

tt 

527 

0.860 

0.40 

tt 

tt 

462 

0.803 

0.50 

t* 

It 

432 

0.777 

0.59 

42 

255 

0.087 

565 

0.893 

0.37 

It 

It 

540 

0.871 

0.40 

tt 

tt 

515 

0.850 

0.43 

tt 

It 

492 

0.829 

0.46 

tt 

tt 

459 

0.800 

0.53 

tt 

tt 

437 

0.781 

0.55 

Digitized  by  LjOOQIC 


DAVIS.  —  THE    LAW    OF   CORRESPONDING   STATES. 


259 


TABLE   y ^(continued). 


Average  Preaaure 

Average  Temperature 

Reduced 

T«t. 

Joule- 
Thomson 

lbs.  peraq.in. 

Reduced. 

Fahr. 

Reduced. 

Coefficient. 

43 

302 

0.103 

550 

0.880 

0.41 

« 

it 

533 

0.865 

0.43 

it 

if 

514 

0.847 

0.46 

i< 

it 

495 

0.832 

0.47 

tt 

it 

468 

0.808 

0.54 

11 

it 

444 

0.786 

0.56 

56 

256 

0.087 

513 

0.848 

0.38 

(< 

it 

475 

0.815 

0.46 

it 

ti 

435 

0.780 

0.55 

59 

252 

0.086 

560 

0.888 

0.38 

<( 

tt 

531 

0.863 

0.41 

ti 

ti 

488 

0.826 

0.48 

n 

it 

441 

0.785 

0.59 

n 

it 

463 

0.804 

0.53 

60 

204 

0.069 

500 

0.837 

0.46 

li 

it 

470 

0.810 

0.52 

ti 

a 

431 

0.776 

0.62 

61 

168 

0.057 

493 

0.830 

0.43 

it 

it 

464 

0.805 

0.48 

a 

ti 

432 

0.777 

0.58 

a 

it 

400 

0.749 

0.69 

62 

200 

0.068 

569 

0,896 

0.36 

ti 

tt 

513 

0.848 

0.42 

64 

302 

0.103 

550 

0.880 

0.41 

it 

ft 

526 

0.859 

0.44 

a 

it 

493 

0.830 

0.49 

it 

it 

467 

0.807 

0.54 

it 

it 

436 

0.780 

0.54 

68 

166 

0.056 

485 

0.823 

0.46 

tt 

tt 

449 

0.791 

0.53 

it 

it 

409 

0.756 

0.66 

69 

162 

0.055 

483 

0.821 

0.47 

'  it 

(( 

446 

0.790 

0.56 

It 

tt 

406 

0.754 

0.67 

to  each  of  the  values  in  Tables  I,  II,  and  III  equal  to  the  product  of  the 
total  number  of  observations  involved  at  both  ends  of  the  determina- 
tion of  the  coefficient  and  the  corresponding  temperature  drop  meas- 


Digitized  by  LjOOQIC 


2(50 


PROCEEDINGS   OF    THE   AMERICAN    ACADEMY. 


ured  in  Centigrade  degrees;  proportional  integral  weights  from  1  to 
6  were  then  used  in  forming  the  weighted  means  in  Table  VI.  The 
relative  weights  of  the  means  themselves  which  are  given  in  the  last 
column  of  Table  VI  are  proportional  to  the  square  roots  of  the  sums  of 
the  above  products  which  entered  into  each  mean;  they  are  given 

TABLE  VI. 
Summary  op  Weighted  Means  prom  Tables  I  to  V. 


Observer. 

Temperature 

Reduced 

Weight. 

Cent. 

Reduced. 

Grindley 

Peake    

Dodge 
Table  IV 

Table  V 

109.4 

122.3     . 

131.0 

138.6 

158.4 

176.2 

128.3 
134.7 
152.7 
167.0 

120.6 
137.9 
160.1 
179.0 

0.600 
0.620 
0.633 
0.645 
0.676 
0.705 

0.628 
0.646 
0.667 
0.690 

0.616 
0.644 
0.679 
0.708 

0.770 
0.870 

0.794 
0.861 

1.719 
1.475 
1.399 
1.290 
1.121 
0.850 

1.454 
1.377 
1.140 
0.923 

1.641 
1.400 
1.075 
0.927 

0.549 
0.389 

0.543 
0.432 

4 
4 
3 
3 
4 
2 

2 
5 
5 
4 

1 
2 
4 
6 

(16)  » 
(25)  » 

(34)  » 
(43)  » 

*  These  are  not  weights  comparable  with  those  above.     They  give 
simply  the  number  of  observations  involved  in  the  corresponding  means. 

merely  as  a  rough  guide  for  anyone  who  may  wish  to  use  these  means 
for  other  purposes.  If  weights  had  been  assigned  to  Dodge's  means  on 
the  same  basis,  they  would  have  been  misleadingly  large  because  all 
the  temperature  diflferences  retained  were  large  (see  the  Appendix). 
The  numbers  in  parentheses  in  the  last  column  of  Table  VI  are  the 
number  of  separate  coefficients  involved  in  each  of  the  means. 

The  small  figure  in  the  upper  corner  of  Figure  6  is  Buckingham's 
figure  (Figure  1  of  this  paper)  replotted  on  a  different  scale  with  the 


Digitized  by 


GooQle 


DAVIS.  —  THE    LAW   OF    CORRESPONDING   OTATE8.  261 

500*  600^ 


— 1—  — 1 j.7 

V 

\ 

^ 

\ 

V 

-^                                                                                                                                       — 

\-                                                       .                    ....                               _        _    ft 

A 

V 

^ 

^ 

S 

N, 

^                                                                     it 

^s.                                                                                                      . 

^ 

A                             -^^ 

^               ^^      i 

^                  ■^=v                i 

"*--^ 

\                                                     "^'^■^— -^ 

!^           -                                    ±"* 

i^ 

3 

S 

\ 

\ 

\ 

s 

'^^^ 

^^^ 

=:=>^__i_____ 

200" 


800" 


Figure  7.  Joule-Thomson  coefficient  in  ordinary  units.  In  the  lower  j)art 
of  the  figure  these  are  Centigrade  degrees  for  a  pressure  drop  of  1  kg.  per  sq. 
cm.  (scale  at  left).  In  the  upper  part  they  are  Fahrenheit  degrees  for  a  pres- 
sure drop  of  1  lb.  per  sq.  in.  (scale  at  right). 

18  means  of  Table  VI  added  as  large  circles.  The  six  small  circles  near 
^1  are  Eester's  carbon  dioxide  points,  the  other  carbon  dioxide  points 
being  omitted  for  cleamcHs.  The  other  points  in  the  figure  are  easily 
recognizable  on  comparison  with  Figure  1. 


Digitized  by  VjOOQIC 


262  PROCEEDINGS  OF  THE  AAfERICAN  ACADEMY. 

Figure  7  shows  the  smooth  curve  that  best  represents  the  band  of 
Figure  6,  translated  back  from  "reduced"  to  ordinary  units,  both 
Centigrade  and  Fahrenheit.  This  curve  has  proved  useful  in  several 
unexpected  ways.  For  example,  it  will  be  made  the  basis  of  a  dis- 
cussion of  the  specific  heat  of  very  highly  superheated  steam  in  a 
later  paper  (see  page  292  of  these  proceedings).  It  has  also  made 
certain  cumbersome  and  uncertain  computations  in  continuous  flow 
calorimetry  unnecessary  (see  "  Power,"  June  2,  1908,  page  871).  It 
is  hoped  that  the  various  scales  of  Figure  7  are  open  enough  to  make 
the  curve  useful  to  others. 

All  of  the  observations  discussed  in  this  paper  have  been  examined 
with  considerable  care,  both  arithmetically  and  graphically,  for  traces  of 
a  systematic  variation  of  the  Joule-Thomson  coeflicient  with  pressure 
at  constant  temperature,  without  success.  If  such  a  variation  exists 
even  close  to  the  saturation  line,  it  is  within  the  limit  of  error  of 
the  data. 

Appendices. 

Discussion  of  Dodge's  Data. 

In  Dodge's  apparatus  the  low  side  chamber  was  protected  against 
loss  of  heat  to  its  surroundings  chiefly  (although  not  wholly)  by  an 
independently  heated  steam  jacket  made  in  one  piece  with  the  wall  of 
the  chamber,  smd  kept  as  nearly  as  possible  at  the  same  temperature 
as  the  low  side  steam.  Thermometers  were  placed  in  this  jacket  and 
their  temperatures  recorded  with  the  other  routine  data  of  each  run. 
As  a  matter  of  fiu^t,  the  jacket  temperatures  usually  ran  somewhat 
lower  than  the  low  side  steam  temperatures,  so  that  some  loss  of  heat 
by  conduction  through  the  chamber  wall  was  to  be  expected.  The 
high  temperatares  employed  would  also  tend  to  make  probable  some 
loss  of  heat  by  radiation.  The  possibilities  were  tested  in  six  special 
runs  numbered  83  to  88,  in  which  the  partition  between  the  high  and 
the  low  side  chambers,  with  its  orifice,  was  completely  removed.  It 
was  found  that  the  low  side  thermometers  in  these  tests  did  read 
somewhat  lower  than  the  high  side  thermometers  although  there  was 
no  throttling.  The  27  observed  difiierences  can  be  fidrly  well  repre- 
sented by  the  empirical  equation 

_  12  (low  side  temp,  —jacket  temp.)  +  ^  (high  side  temp.) 
~  flow  in  lbs.  per  hour 

The  forms  of  the  two  terms  in  the  numerator  were  intended  to  cor- 
respond to  the  two  sorts  of  heat  loss  mentioned  above.  Corrections 
corresponding  to  this  formula  were  accordingly  applied  to  the  main 


Digitized  by  LjOOQIC 


J 


DAVIS.  —  THE   LAW    OF   CORRESPONDING    STATES.  263 

tests.  The  corrections  in  the  tests  sammarized  in  Table  IV  averaged 
2.4°  F.,  and  only  occasionally  amounted  to  4**.  Those  in  the  tests 
summarized  in  Table  V  averaged  2.9"^  F.  and  only  occasionally 
amounted  to  5°, 

The  second  set  of  corrections  which  are  involved  in  Table  V  but  not 
in  Table  IV  are  much  more  uncertain.  As  has  been  stated,  the  ex- 
periments of  the  runs  of  Table  V  could  not  be  grouped  into  throttling 
curves  whose  various  low  side  points  could  be  combined  with  each 
other,  all  the  high  side  observations  being  ignored  except  as  indicatmg 
constancy  of  initial  conditions,  as  was  done  in  preparing  Table  IV.  If 
the  data  were  to  be  used  at  all,  each  low  side  point  had  to  be  taken 
with  its  own  high  side  point  When  this  was  done  with  only  the 
radiation  and  conduction  corrections  made,  the  resulting  values  of  the 
Joule-Thomson  coefficient  were  not  at  all  self-consistent>  the  values  in 
each  run  which  corresponded  to  small  temperature  drops  and  therefore 
to  high  mean  temperatures  being  abnormally  high.  This  tendency  of 
the  points  near  0.9  in  Figure  6  to  swoop  upward  was  unmistakable,  and 
indicated  clearly  the  presence  in  the  tests  of  Table  V  of  the  same  "  wet 
steam  "  error  shown  in  Figure  5  for  the  tests  of  Table  IV. 

The  necessary  corrections  were  obtained  from  the  tests  of  Table  IV. 
It  seemed  that  they  alone  gave  enough  of  a  verification  of  the  law 
of  corresponding  states  to  justify  the  drawing  of  a  tentative  curve  like 
those  of  Figure  7,  and  this  curve  was  then  used  to  compute  what 
correction  would  have  to  be  applied  to  each  of  the  high  side  tempera- 
tures of  the  tests  of  Table  IV  to  make  them  self-consistent  These 
corrections  were  surprisingly  constant  They  were  examined  for 
systematic  variations  with  mean  pressure,  with  pressure  drop  and  with 
quantity  of  steam  discharged,  without  success.  There  seemed,  how- 
ever, to  be  a  slight  variation  with  the  mean  temperature  and  the 
following  scheme  was  adopted  : 

If  the  mean  reduced  decrease  the  high 

temperature  is  side  temperature  by 

0.9  14** 

0.85  13° 

0.8  12° 

0.75  11° 

It  should  be  noticed  that  these  corrections  were  deduced  wholly 
from  the  14  throttling  curve  tests  of  Table  IV.  When  they  were 
applied  to  the  tests  of  Table  V,  the  resulting  values  of  the  coefficient 
showed  none  of  their  previous  tendency  to  run  high  near  0.9,  and  were 


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264  PROCEEDINGS  OP  THE  AMERICAN  ACADEMY. 

in  general  much  more  self-consistent  Further,  they  now  agreed  very 
definitely  with  the  tests  of  Table  IV  in  verifjring  the  law  of  correspond- 
ing states  and  lay  close  along  the  tentative  curve  previously  drawn. 
These  fiu^ts,  particularly  the  disappearance  of  the  tendency  to  swoop 
near  0.9,  seem  to  show  that  this  reasoning  is  not  a  '*  circular  blhucy" 
and  that  the  values  in  Table  V  are  a  real  corroboration  of  those  in 
Table  IV. 

As  a  precaution  against  using  these  corrections  too  freely  in  cases 
where  they  might,  perhaps,  not  apply,  it  seemed  best  to  include  in 
Table  V  only  such  of  the  33  selected  tests  of  the  t3rpe  in  question  as 
resembled  the  tests  firom  which  the  corrections  were  determined  in 
having  comparatively  large  steam  flow  (more  than  80  lbs.  per  hour). 
Furthermore,  all  tests  or  parts  of  tests  were  rejected  for  which  the 
observed  temperature  drop  was  not  as  great  as  five  times  the  correc- 
tion, as  the  application  of  any  correction  amounting  to  more  than  20 
per  cent  of  the  quantity  involved  seemed  unsafe.  The  33  tests  were 
thus  reduced  to  19,  and  these,  corrected  as  above,  gave  the  77  values 
of  the  coefficient  in  Table  V. 

Note  an  the  Vertical  Scale  of  Figure  1. 

The  numerical  values  of  the  ordinates  in  Figure  1  are  not  the 
"reduced  "  Joule-Thomson  effect  in  the  ordinary  sense,  because  Buck- 
ingham, in  computing  them,  used  100  in.  of  mercury  as  his  unit  of 
pressure,  but  nevertheless  expressed  his  critical  pressures  in  atmos- 
pheres. The  true  reduced  values  of  fi  are  ,those  indicated  in  the 
upper  comer  of  Figure  6. 

Jefferson  Physical  Laboratory,  ^ 

Cambridge,  Mass., 
December,  1909. 


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Proceedings  of  the  American  Academy  of  Arts  and  Sciences. 
Vol.  XLV.  No.  9.  — March,  1910. 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 


NOTES  ON  CERTAIN   THERMAL  PROPERTIES 
OF  STEAM. 


By  Habvet  N.  Davis. 


Digitized  by  VjOOQIC 


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GoogLf jj^ 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,   HARVARD  UNIVERSITY. 

NOTES  ON  CERTAIN  THERMAL  PROPERTIES  OF  STEAM. 

By  Hakvby  N.  Davis. 

PreBonted  by  John  Trowbridge,  December  8, 1009;  Received  December  30, 1009. 

§  1.   Introduction 267 

§  2.   On  the  Cp  values  available  for  the  present  purpose 269 

§  3.  On  the  total  heat  of  saturated  steam 

A.  The  determination  of  H  —  H^^ 272 

B.  The  value  of  Hioo 280 

C.  Extrapolation  formulae  for  H  and  h 281 

§  4.  Discussion  of  the  specific  heat  of  superheated  steam,  including 

A  recomputation  of  Regnault's  values 286 

Computations  based  on  the  Joule-Thomson  efifect 289 

Computations  with  Planck's  equation 295 

§5.  Clausius' "Specific  heat  of  saturated  steam  " 303 

§  6.  The  critical  volume  of  water 305 

Summary  of  the  results  in  this  paper 310 

1.    Introduction. 

It  is  the  purpose  of  this  paper  to  coUeot  and  correlate  certain 
material  on  the  thermal  properties  of  steam.  A  part  of  this  material 
was  published  in  a  technical  journal  a  year  ago.^  Other  parts  of  it 
have  been  contributed  as  discussion  of  papers  by  others  in  that  journal 
and  elsewhere.  Still  other  parts  of  it  have  been  used  in  a  recent  book.^ 
The  rest  appears  here  for  the  first  time.  It  all  centers  around  a  new 
determination  of  the  total  heat  of  saturated  steam. 

The  previous  determinations  of  the  total  heat  of  steam  {n\  and  of 
the  closely  related  latent  heat  of  evaporation  (X),  will  first  be  summa- 
rized. The  most  &mous  of  them  was  published  by  Regnault  in  1847. 
His  experiments  were  so  numerous,  covered  such  a  wide  temperature 
range,  and  were  characterized  by  such  perfection  of  detail  as  to  be 
accepted  as  the  foundation  of  the  engineering  practise  of  the  world, 

1  Jour.  Am.  Soc.  of  Mech.  Engs.,  1908,  30,  1419. 
*  Marks  and  Davis,  Steam  Tables  and  Diagrams. 


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268  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

and  to  remain  standard  for  sixty  years.  He  himself  deduced  from 
them  the  well-known  linear  formula 

ir=  606.5  +  0.305  t  calories. 

Others  have  represented  them  by  second  degree  formulsB  with  negative 
second  degree  terms. 

The  more  modem  experimental  work  began  in  1889  with  a  measure- 
ment of  L  at  O''  C.  by  Dieterici.^  He  was  followed  by  Griffiths,*  Joly  ^ 
and  Smith,^  working  at  various  temperatures  between  O*'  and  100**  C, 
and  finally  in  1906  by  Henning,^  of  the  Reichsanstalt,  who  published 
an  excellent  series  of  values  covering  the  range  from  30^  to  100**  C. 
The  results  of  all  these  observers  are  in  excellent  agreement  and  show 
that  Regnault's  formula  for  H  gives  values  which  are  much  too  high 
near  0**  and  somewhat  too  low  near  100**. 

In  1908  the  formula  which  is  the  basis  of  this  paper  was  presented 
to  the  American  Physical  Society  ®  and  to  the  American  Society  of 
Mechanical  Engineers.^  It  was  based  on  the  results  of  certain  throttling 
experiments  by  Grindley,^^  Griessmann  ^^  and  Peake.^^  These  experi- 
ments were  originally  undertaken  for  the  purpose  of  computing,  with 
the  help  of  Regnault's  total  heats,  the  variation  with  pressure  and 
temperature  of  the  specific  heat,  C^  of  superheated  steam.  This 
attempt  was  unsuccessful,  because  the  total  heats  entered  into  the 
computations  in  such  a  way  as  to  cause  the  errors  in  them  to  be 
tremendously  magnified  in  the  results.  The  desired  information  about 
C>  has  since  been  obtained  in  other  more  direct  ways,  and  the  throt- 
tling experiments  have  been  ignored.  It  is,  however,  possible,  by 
reversing  the  computation  processes  of  Grindley,  Griessmann  and 
Peake,  to  proceed  from  the  recently  determined  values  of  C>  which 
were  to  have  been  their  goal,  back  to  d  new  determination  of  the 
values  of  H  which  were  their  starting  point.  The  very  sensitiveness 
of  their  procedure  to  errors  in  H  ensures  the  insensitiveness  of  the 

•  Wied.  Ann.,  1889,  37,  494. 

•  PhU.  Trans.,  1895,  186  A,  261. 

■  In  an  appendix  to  Griffiths'  paper,  page  322. 

•  Phys.  Rev.,  1907,  26,  145. 
»  Wied.  Ann.,  1906,  21,  849. 

•  Phys.  Rev.,  1908,  26,  407. 

•  Journal,  loc.  cit. 

w  PhU.  Trans.,  1900,  194  A,  1. 

"  Zeit.  Ver.  d.  Ing.,  1903,  47,  1852,  and  1880;  also  Forschungsarb.,  1904, 
13.1. 

"  Proc.  Roy.  Soc.,  1905,  76  A,  185. 


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DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OP  STEAM.  269 

present  prooednre  to  errors  in  Cp,  The  result  of  such  a  reversal  of  their 
reasoning  is  the  formula  which  was  suggested  two  years  ago,  namely, 

J5r=  ^100  +  0.3745  {t  -  100)  -  0.000990  (t  -  100)^. 

This  formula  belongs  only  to  the  range  between  100°  and  190°  C. 
Within  this  range  its  accuracy  is  believed  to  be  of  the  order  of  one 
tenth  of  one  per  cent 

When  the  new  formula  was  announced,  there  were  no  direct  experi- 
mental determinations  oi  H  or  L  above  100°  by  which  it  could  be 
checked  except  Regnault's,  but  more  recently  Henning  ^^  has  published 
a  continuation  of  his  admirable  research  to  180°.  The  extent  of  the 
agreement  of  this  with  the  formula  will  be  discussed  later. 

As  has  been  indicated,  the  computations  leading  to  the  new  formula 
involve  two  diflFerent  sorts  of  experimental  data.  The  first  of  these, 
namely,  the  throttling  e±periments  of  Grindley,  Griessmann  and  Peake, 
have  been  sufficiently  discussed  in  a  previous  paper. ^^  The  second, 
the  direct  determinations  of  C,  mentioned  above,  will  be  discussed  in 
the  next  section. 

2.  On  the  Cp  Values  Available  for  the  Present  Purpose. 

There  are  three  direct  calorimetrio  determinations  of  the  variation  of 
C^  with  pressure  and  temperature,  namely,  those  of  Lorenz,^*  of  Knob- 
lauch and  Jakob  ^^  and  of  Thomas. ^^  That  of  Lorenz  was  the  earliest 
of  the  three  and  was,  as  he  himself  says,  a  preliminary  survey  for  the 
sake  of  those  engineers  who  could  not  afford  to  wait  for  more  accurate 
work.    It  is  not  ordinarily  considered  comparable  with  Knoblauch's. 

Both  Knoblauch's  and  Thomas'  results  were  obtained  by  determin- 
ing the  electrical  energy  necessary  to  increase  by  a  known  amount  the 
temperature  of  previously  superheated  steam.  In  Knoblauch's  appa- 
ratus the  original  superheating  took  place  in  an  electrical  preheater. 
The  steam  was  then  still  further  heated  in  a  separate  calorimeter,  the 
energy  added  being  the  object  of  a  direct  measurement  In  Thomas' 
case  the  separate  preheating  and  calorimetrio  coils  of  Knoblauch's 
apparatus  were  replaced  by  a  single  coil,  by  means  of  which  initially 
wet  steam  was  brought,  first  just  to  dr3mess,  and  in  a  later  experiment 

"  Wied.  Ann.,  1909,  29,  441. 
"  These  Proceedings,  page  241. 

w  Zeitsch.  Ver.  d.  Ing.,  1904,  48,  698;  Phys.  Zeitsch.,  1904,  5,  383;  and 
Forschungsarfo.,  1905,  21,  93. 

"  Zeitsch.  Ver.  d.  Ing.,  1907, 51, 81  and  124;  Forschungsarb.,  1906, 35, 109. 
^v  Proc.  Am.  Soc.  Mech.  Engs.,  1907,  29,  633. 


:'  . 


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270 


PBOCEEDINQS  OF  THE  AMERICAN  ACADEMT. 


to  a  high  superheat.  The  amount  of  energy  necessary  for  the  super- 
heating was  then  found  by  a  subtraction.  It  is,  therefore,  liable  to  a 
percentage  error  much  greater  than  that  in  either  of  the  observed 
components.  Knoblauch's  method  is  obviously  preferable  to  Thomas' 
in  this  respect. 

His  experimental  arrangements  also  seem  superior  to  Thomas'.  In 
his  separate  calorimeter  there  were  only  small  temperature  differences 
between  the  inlet  and  outlet  pipes ;  in  Thomas'  combination  calori- 
meter there  were  very  large  diffierences.  In  Knoblauch's  case  the  heat 
losses  through  these  pipes  were  determined ;  in  Thomas'  case  they 


Figure  1.    Knoblauch's  Cp.  diagram. 

were  ignored.  Furthermore,  although  both  calorimeters  were  very 
carefully  lagged,  Knoblauch  determined  his  radiation  losses  in  each 
experiment,  while  Thomas,  in  the  final  form  of  his  apparatus,  relied  on 
eliminating  them,  a  difi&cult  thing  to  be  sure  of.  Finally,  Knoblauch's 
thermometry  is  apparently  more  refined  than  Thomas'.  It  is  there- 
fore probable  that  wherever  the  two  sets  of  results  disagree,  Knob- 
lauch's are  to  be  preferred. 

As  a  matter  of  &ct,  the  two  sets  of  results  agree  fi&irly  well  in  the 
region  of  moderate  superheats,  as  will  be  seen  in  Figures  1  and  2,  but 
disagree  fundamentally  in  exactly  that  part  of  the  diagram  which  will 
be  most  used  in  what  follows,  namely,  the  region  of  moderate  pressures 
and  very  low  superheats  (the  lower  left-hand  comer  of  Figure  1).    The 


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DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OF  STEAM. 


271 


sudden  rise  in  Thomas'  carves  near  satnration  indicates,  according  to 
his  interpretation,  that  a  comparatively  large  amonnt  of  heat  is  re- 
qaired  to  change  dry  steam  into  slightly  8u|)erheated  steam.  But  it 
may  also  indicate  that  what  he  believed  to  be  dry  steam  really  carried 
a  small  amount  of  water  floating  as  a  mist  This  would  have  to  be 
evaporated  at  the  expense  of  some  extra  heat  in  addition  to  that  re- 
quired for  the  actual  superheating,  and  C,  would  come  out  too  large. 


.200"  .2W 

FiaxTRB  2, 


That  this  explamation  is  a  reasonable  one  is  shown  by  a  comparison  of 
his  apparatus  with  Knoblauch's.  The  latter's  prebeater,  mentioned 
above,  was  a  pipe  made  up  of  15  sections  each  20  cms.  in  diameter  and 
20  cms.  long,  each  filled  with  a  dense  grid  of  constantan  ribbons  which 
ensured  thorough  mixing  of  the  passing  steam.  All  of  the  heat  neces- 
sary for  the  desired  saperheating  was  ordinarily  put  in  in  the  first  one  or 
two  sections,  and  the  sole  purpose  of  the  rest  of  the  prebeater  was  to 
bring  the  resulting  mixture  of  highly  superheated  steam  and  floating 


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272 


PROCEEDINGS  OP  THE  AMERICAN  ACADEMY. 


mist  into  a  homogeneous  state.  Knoblauch  and  Jakob  say  that  traces 
of  moisture  were  observable  through  several  of  the  mixing  sections, 
and  it  is  easy  to  show  thAt  even  if  "  several "  means  as  few  as  two,  and 
even  if  the  steam  in  these  sections  had  always  had  the  greatest  specific 
volume  which  it  ever  had,  the  floating  mist  must  have  persisted  for  a 
time  which  was  never  less  than  a  second  and  averaged  more  than  two 
seconds,  and  this  after  cUl  of  the  heat  necessary  for  the  high  superheat 
had  been  put  in.  In  Thomas'  apparatus,  on  the  other  hand,  the  evapora- 
tion and  superheating  had  to  take  place  in  24  quarter-inch  holes  in  a 
soapstone  block  something  like  5  inches  long,  and  in  a  small  chamber 
just  above  it,  and  a  similar  computation  shows  that  even  if  the  specific 
volume  of  the  steam  had  never  been  greater  than  that  of  the  original 
saturated  steam,  it  must  have  passed  the  thermocouple,  always  within 
nine  tenths  of  a  second,  sometimes  within  a  thirtieth  of  a  second,  and 
on  the  average  within  less  than  half  a  second  of  the  time  when  the 
first  of  the  superheating  heat  was  put  in.  It  is,  therefore,  very  proba- 
ble that  Thomas'  "saturated  steam"  was  slightly  wet,  and  that  the 
percentage  of  moisture  passing  the  thermocouple  decreased  from  ex- 
periment to  experiment  as  the  final  superheat  was  increased,  giving 
too  high  values  of  C>  near  saturation.  Knoblauch's  values  have  there- 
fore been  used  in  preference  to  Thomas'  in  this  work.  Confirmations 
of  this  decision  will  be  found  on  pages  287,  298  and  302. 


8.  The  Total  Heat  of  Saturated  Steam. 

A.  The  determination  of 
H  —  ^100. "—  A  part  of  the  fol- 
lowing account  of  the  method 
by  which  the  total  heat  of  satu- 
rated steam  has  been  computed 
is  reprinted  with  minor  changes 
firom  the  Proceedings  of  the 
American  Society  of  Mechan- 
ical Engineers. 

Let  Figure  3  represent  a 
throttling  curve  of  the  sort 
published  by  Grindley,  Griess- 
man  or  Peake.  Supposedly 
dry  and  saturated  steam  at 
the  pressure  and  temperature 
corresponding  to  the  point  A  is  first  throttled  to  lower  pressure  and 
temperature  corresponding  to  the  point  B ;  then  in  a  later  experiment 


Showing  how  the  Total  Heat  Curve 
ob^cfd*  is  obtained  from  a  Throttling 
Curve  ABCD. 


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DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OF   STEAM.  273 

in  the  same  ran,  it  is  throttled  from  exactly  the  same  initial  condition 
A  to  the  condition  C ;  then  to  D  and  so  on.  The  well-known  law  of 
throttling  is  that  the  total  heat  in  the  condition  B,  or  G,  or  D,  is  eqaal 
to  that  in  the  initial  condition  A. 

The  point  B  represents  superheated  steam  at  the  pressure  ps ;  the 
point  B'  represents  saturated  steam  at  the  same  pressure;  and  the 
amount  of  superheat  at  B  is  the  measured  temperature  there  minus 
the  temperature  at  B',  which  can  be  taken  from  a  steam  table.  Also, 
by  definition,  the  total  heat  at  B  equals  that  of  saturated  steam  at  the 
same  pressure  (point  B')  plus  the  amount  of  heat  required  to  superheat 
it  at  constant  pressure  from  B'  to  B.  This  is  the  integral  of  C^  from 
B'  to  B,  or  simply  the  mean  C^  from  saturation  multiplied  by  the 
known  superheat  If  C^  is  known,  this  integral,  or  increment  in  the 
total  heat  between  B'  and  B,  is  easily  evaluated. 

This  integral  is  not  only  the  difference  between  the  total  heat  of 
saturated  steam  at  B'  and  that  of  superheated  steam  at  B ;  it  is  also 
the  difference  between  the  total  heat  of  saturated  steam  at  B'  and  that 
of  saturated  steam  at  A ;  that  is,  between  the  two  corresponding  ordi- 
nates  of  the  curve  that  gives  the  total  heat  of  saturated  steam  as  a  func- 
tion of  the  temperature,  the  curve  sought  in  this  paper.  To  draw  a 
piece  of  this  curve,  one  chooses  arbitrarily  some  horizontal  line  such  as 
a:if  in  Figure  4,  and  lays  off  below  it,  at  the  proper  temperatures,  the 
distances  &6',  cc\  dd\  etc.,  which  represent  on  the  desired  ^-scale  the 
integrals  or  total  heat  differences  between  B'  and  B,  C  and  G,  D'  and 
D,  eta  The  curve  aVc^df  is  an  isolated  piece  of  the  trae  curve  of  total 
heat  against  temperature.  The  relative  height  of  its  points,  that  is,  its 
shape,  is  accurately  determined ;  the  absolute  height  above  the  usual 
zero  of  total  heats,  namely,  that  of  water  at  0°C.,  is  as  yet  wholly  un- 
known. The  experiments  of  Grindley  gave  seven  independent  sample 
pieces  of  this  sort^  one  for  each  throttling  curve,  their  temperature 
ranges  being  known  and  greatly  overlapping ;  similarly  Griessmann's 
data  gave  eleven  such  sample  pieces,  and  Peake's  six. 

As  was  explained  in  the  preceding  paper  on  the  Joule-Thomson 
effect,  Grindley's  incoming  steam  (point  A),  and  occasionally  Peake'js, 
was  not  quite  dry,  so  that  its  total  heat  was  not  determined  by  its 
pressure  and  temperature.  Whenever  this  seemed  to  be  the  case,  the 
points  A  and  a  of  Figures  3  and  4  were  left  out  of  consideration  alto- 
gether. BGD  would  still  be  a  curve  of  constant  total  heat,  provided 
only  that  the  quality  of  the  incoming  steam  at  A  remained  constant 
during  a  ran,  and  Vc^df  would  still  be  a  useful  piece  of  the  desired 
total  heat  curva 

All  sample  pieces  of  any  one  observer  were  then  plotted  carefully  on 

VOL.  XLV.  — 18 


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274  PROCEEDINGS   OF  THE   AMERICAN  ACADEBiT. 

very  thin  transparent  rice  paper,  with  vertical  guide-lines  at  certain 
standard  temperatures,  which  enaUed  these  plots  to  be  accurately  ori- 
ented as  far  as  rotation  and  horizontal  displacement  were  concerned, 
but  left  them  free  to  slide  up  and  down  over  each  other.  The  sheets 
were  then  piled  on  top  of  one  another  on  a  transparent  table  lighted 
from  below,  each  one  placed  so  as  to  make  its  piece  of  curve  coincide 
most  satis&ctorily  with  the  overlapping  pieces  already  laid  down.  The 
exact  relative  displacements  of  the  sheets  were  then  carefully  measured. 
This  process  was  repeated  for  each  of  the  three  observers'  sets  of  sheets 
independently,  four  different  times  for  each  set,  in  two  very  different 
orders  and  in  those  orders  reversed,  on  different  days,  all  with  the  ob- 
ject of  avoiding  as  far  as  possible  any  routinizing  effects  of  memory  or 
habit  which  might  disturb  the  real  independence  of  the  four  determina- 
tions. The  means  of  the  measured  displacements  were  then  used  to 
reduce  each  of  the  pieces  of  curve  in  any  one  of  the  sets  to  a  zero  com- 
mon to  all  the  curves  of  that  set  The  results  are  marked  Gy^  Gs,  and 
P  in  Figure  5.  They  are  plotted  separately  for  clearness,  but  they 
are  simply  different  experimental  determinations  of  exactly  the  same 
real  curva  The  vertical  scale  of  each  is  that  indicated  at  the  side  of 
the  diagram,  but  the  height  of  each  above  its  true  zero  is  still  unknown. 
Each  of  the  circles  represents  at  least  one  independent  throttling  ob- 
servation, and  some  of 'them  two  or  three  independent  observations 
that  happened  to  coincide.  It  will  be  noticed  that  no  one  of  the  curves 
is  more  than  a  fifth  of  a  scale  division,  or  four  tenths  of  a  calorie,  wide 
between  centers.  Each  is,  therefore^  a  self-consistent  determination  of 
the  true  curve  within  two  tenths  of  a  calorie,  or  about  three  hundredths 
of  one  per  cent. 

The  next  step  was  to  establish  a  comparison  between  the  three 
curves.  The  points  of  each  were  first  divided  into  groups,  each  includ- 
ing some  20^  of  temperature  range,  and  the  mean  point  of  each  group 
was  used  to  represent  the  group.  This  procedure  is  justified  by  the 
£a^t  that  so  short  a  section  of  the  total  heat  curve  can  be  considered 
straight  without  serious  error.  There  were  eighteen  such  means,  seven 
representing  Grindley's  points,  five  Griessmann's  and  six  Peake*a 
These  means  were  then  plotted  on  three  more  sheets  of  rice  paper,  the 
resulting  curves  were  superposed  in  the  way  already  described,  and  a 
determination  was  made  of  the  corrections  necessary  to  reduce  all  three 
sets  of  means  to  a  common  but  still  arbitrary  zero. 

In  the  meantime  successive  means  from  each  of  the  three  curves 
taken  separately  were  used  to  compute  the  values  of  the  derivative 
dll/dt  which  are  plotted  with  large  circles  in  Figure  6.  It  is  evident 
that  the  results  from  the  three  sources  agree  with  each  other  in  deter- 


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DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OF  STEAM. 


275 


mining  a  straight  line  as  the  graph  of  dH/dt  against  t.  The  total  heat 
curve  itself  can  therefore  be  represented  in  the  range  between  100*^  and 
190°  by  an  equation  of  the  second  degree  in  ^,  within  the  limit  of  error 
of  the  available  data.    The  form  selected  is 

H-Hxt»  +  a  (^  -  100)  -  6  (^-  100)1 

The  eighteen  means,  reduced  to  a  common  but  still  arbitrary  zero,  were 


FiGUKB  6.     dH/dt  plotted  against  t, 
authorities  as  in  Figure  5. 


150  i  200 

The  symbols  refer  to  the  same 


nsed  to  give  a  least  squares  determination  of  the  constants  JTioo,  cl  and 
b  and  of  their  probable  errors,  with  the  following  results; 

Hiwi  =  arbitrary  ±  0.03, 
a      =  0.3745      ±  0.0014, 
b       =  0.000990  ±  0.000020. 

The  agreement  of  the  eighteen  individual  means  with  this  formula  is 
shown  in  the  upper  part  of  Figure  5,  the  curve  being  drawn  to  represent 
the  formula  as  accurately  as  possible.  It  is  also  shown  by  the  smallness 
of  the  three  probable  errors.  Even  if  these  errors  are  combined  in  the 
most  unfavorable  way,  the  change  in  the  computed  value  of  H  at  200°C. 
is  only  0.37  calories,  or  about  one  eighteenth  of  one  per  cent  of  H  itself; 
at  lower  temperatures  the  change  would  be  still  less. 


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276 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


The  value  of  ^loo  which  was  obtained  from  the  least  squares  process 
is  entered  in  the  above  table  as  "arbitrary"  because  it  is  measured 
from  an  arbitrary  zero.  This  value  of  ^loo  was  next  subtracted  from 
each  of  the  eighteen  means,  giving  new  values  for  these  means  on  a  new 
scale  whose  zero  is  Hwy  In  other  words,  these  means  now  represent 
the  true  values  of  iST  —  iSTioo.  The  resulting  values  are  given  in  Table 
I,  and  are  represented  within  their  limit  of  error  by  the  formula 

H  -  ^100  =  0.3745  {t  -  100)  -  0.000990  {t  -  100)*. 

TABLE  I. 

Values  op  Ht  —  H^^  and  of  ^^ 


/ 

^/— ^i» 

Ht* 

Grindley      .... 

67.56 

-13.23 

625.88 

82.70 

-  6.80 

632.31 

101.80 

+  0.71 

639.82 

109.27 

+  3.31 

642.42 

123.82 

+  8.36 

647.47 

139.92 

+  13.46 

652.57 

161.65 

-1-19.26 

658.37 

Gricssixi&iin    ... 

99.61 

+  0.03 

639.14 

119.80 

+  6.89 

646.00 

139.18 

-1-12.94 

652.05 

156.01 

-1-17.98 

657.09 

172.60 

+22.28 

661.39 

Peake 

102.88 

+   1.15 

640.26 

120.22 

+  7.16 

646.27 

138.41 

+  12.87 

651.98 

157.56 

+  18.36 

657.47 

173.60 

+22.22 

661.33 

186.33 

+  24.77 

663.88 

♦  These  values  of  Ht  are  computed  from  Ht  —  H,«  on  the  assump- 
tion that  //|oo  =  639.11  mean  calories  (see  page  281).    They  are  inserted 
here  for  the  convenience  of  the  reader,  but  the  values  of  Hf  —  H^^^  are 

the  significant  part  of  this  table  and  indeed  of  the  whole  paper. 

This  formula  gives,  in  mean  calories,  the  total  heat  of  saturated  steam 
at  any  temperature  between  100®  and  190®  C.  in  terms  qf  that  at 
\0(f  G.  A  value  for  the  fundamental  constant  ^loo  will  presently  be 
chosen  from  those  available  in  the  literature  of  the  subject,  but  it  should 
be  remembered  that  even  if  this  choice  is  wrong,  or  if  new  and  different 
data  near  100^  are  hereafter  published,  whatever  merit  the  above  equa- 


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DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OF  STEAM. 


277 


tion  may  have  will  be  wholly  unaffected  by  the  necessary  change  in 

ijTioo- 

It  is  interesting  to  compare  the  self-consistency  of  this  work,  as 
represented  by  the  narrowness  of  the  bands  of  plotted  points,  with 
that  of  Regnault's  observations^  which  are  plotted  at  the  bottom  of 
Figure  5.^^    His  band  is  at  least  eight  or  ten  times  as  wide  as  any  of 

TABLE  II. 
Henning's  Measurements  of  H, 


Temp. 

Value  of  L. 

Heat 
of  the 
liquid. 

H. 

HyarH. 

Hm. 

VariatioD  from     1 

Aa 
reported. 

Reduced. 

First 
mean. 

Second 
mean. 

30.12 
49.14 
64.85 
77.34 
89.29 
100.59 

102.34 
120.78 
140.97 
160.56 
180.72 

(579.0) 
569.55 
559.47 
552.47 
545.76 
538.25 

536.93 
525.32 
509.60 
495.95 
481.99 

(579.5) 
570.07 
559.98 
552.97 
546.26 
538.74 

537.42 
525.90 
510.06 
496.40 
482.43 

30.1 

49.09 

64.77 

77.27 

89.24 

100.59 

102.35 
121.02 
141.62 
161.80 
182.78 

(609.6) 
619.16 
624.75 
630.24 
635.50 
639.33 

639.77 
646.92 
651.68 
658.20 
665.21 

+  14.39 
+  8.99 
+  4.13 

-  0.22 

-  0.87 

-  7.36 
-13.79 
-19.06 
-23.79 

639;i4 
639.23 
639.63 
639.11 

638.90 
639.56 
637.89 
639.14 
641.42 

-()!l9 
-0.10 
+  0.30 
-0.22 

-0.43 
+0.23 
-1.44 
-0.19 
+2.09 

-6;i2 

-0.03 
+0.37 
-0.15 

-0.36 
+0.30 

Mean  of 

all 

.  639.33    ±0.49      ..    . 

Mean  of 

firstsix 

.  639.26     . . : .       ±0.19 

The  values  of  L  in  the  second  column  are  in  terms  of  Henning's 
"  15°  Calorie  "  of  4.188  international  Joules;  those  in  the  third  column 
are  reduced  to  mean  calories  of  4.1842  Joules.    The  heat  of  the  liquid 
in  the  fourth  column  is  from  the  steam  tables  of  Marks  and  Davis.    The 
probable  error  of  each  mean  is  0.845  times  the  corresponding  average 
error. 

those  above  it  It  should  also  be  noticed  that  something  evidently 
happened  to  his  apparatus  at  178°  C,  and  that  allowing  for  this,  his 
band  shows  anmistakably  the  s^e  curvature  as  those  above  it  The 
observations  above  178°  C.  were,  as  a  matter  of  febct,  the  last  he  made, 
and  he  speaks  definitely  of  serious  trouble  with  his  apparatus  at  the 

^*  The  large  circle  at  the  boiling  point,  100^  C,  represents  the  mean  of  38 
points,  of  which  only  the  highest  and  lowest  are  plotted. 


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278  PBOCEEDINQS  OF  THE  AMEBICAN  ACADEMY. 

very  point  at  which  the  jump  occurs ;  in  feet,  he  had  to  renew  many  of 
its  parts,  and  to  watch  it  continually  thereafter,  so  that  his  conditions 
may  well  have  been  somewhat  changed.  This  discontinuity  in  his 
curve  has  been  noticed  by  many  writers,  one  of  whom  attributes  it.  to 
a  leak  in  his  distributing  valve,  remedied  at  this  point ;  but  this  is  not 
definitely  mentioned  in  the  memoir. 

The  recent  publication  by  Henning  of  his  measurements  of  L  between 
100''  and  180°  gives  a  valuable  test  of  the  new  formula.  All  his 
values  in  both  papers  are  collected  in  the  second  column  of  Table  II. 
They  are  expressed  in  terms  of  a  calorie  of  4.188^®  international 
Wattseconds.  It  is  probable  that  the  mean  calorie  (0°  to  100°)  is 
about  4.184(2)  international  Wattseconds,  for  the  fine  work  of  Rey- 
nolds and  Moorby  ^^  by  a  mechanical  method,  leads,  according  to 
Smith,2i  to  the  value  4.1836,  while  the  equally  good  work  of  Barnes  ^2 
by  an  electrical  method  must  now  23  be  regarded  as  leading  to  the 
value  4.1849.  Each  of  Henning's  numbers  should  therefore  be  multi- 
plied by  4.188  /  4.1842  =  1.00091.  The  results  are  given  in  the  third 
column  of  Table  II.  They  lead  to  the  values  of  i7  in  the  fifth  column. 
In  the  sixth  and  seventh  columns  are  given  the  values  at  the  cor- 
responding temperatures  of 

H  "11x00  =  0.3745  {t  -  100)  -  0.000990  (t  -  100)^ 

and  of  ^100  itself  The  latter  is  practically  constant  as  it  should  be  if 
the  new  formula  is  true.  It  will  be  noticed  that  the  probable  error  of 
the  mean  value  of  H  is  only  one  thirteenth  of  one  per  cent  of  that 
mean,  and  that  this  agreement  is  within  the  one  tenth  of  one  per  cent 
which  Henning  claims  for  his  observations.  It  will  further  be  noticed 
that  practically  all  of  the  discrepancy  is  in  two  of  the  last  three  values. 
If  all  three  of  these  values  are  omitted,  so  that  the  range  of  the  test  is 
cut  down  to  that  between  65°  and  121°,  the  probable  error  of  the  new 
mean  is  only  ±0.19  calories,  or  one  thirty-fourth  of  one  per  cent 

In  estimating  the  significance  of  the  comparatively  great  disagree- 
ment between  Henning's  value  at  180°  and  the  new  formula  it  should 
be  remembered  that  Henning  himself  says,  "  Bei  der  hochsten  Tem- 
peratur  von  180°  konnten  nur  an  zwei  tagen  Versuchen  angestellt 
werden  "  (instead  of  on  four  days  as  at  most  of  the  other  temperatures). 

*•  This  is  Jager  and  von  Steinwehr's  value  for  the  15®  calorie.    The  justi- 
fication for  it  has  not  yet  been  published. 
«•  PhU.  Trans.,  1897,  190  A,  301. 
«i  Monthly  Weather  Review,  1907,  36,  458. 
M  Phil.  Trans.,  1902, 199  A,  149. 
»  Proc.  Roy.  Soc.,  1909,  82  A,  390. 


^7. 


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DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OF  STEAM.  279 

"  Za  B^inn  des  dritten  Tages  y^rsagte  der  Apparat  seinen  Dienst  und 
es  war  infolge  der  durch  die  starke  Hitze  eintretenden  allmahlichen 
Veranderungen  des  Materials  and  inbesondere  infolge  der  Abnutzung 
des  Hahnes  H  nicht  wieder  der  erforderliche  Grad  der  Dichtheit  za 
erreichen."  If  a  small  leak  of  die  same  sort  had  been  present  without 
being  noticed  on  the  two  days  on  which  observations  were  made,  its 
effect  woald  have  been  to  make  tiie  observed  L  too  large,  jast  as  it 
seems  to  be.  At  any  rate,  the  point  at  180^  is  not  entitled  to  nearly 
as  mach  weight  as  the  others.  The  x)oint  at  140°  was,  however,  as  £ur 
as  Henning  coald  judge,  as  good  as  any  of  the  rest 

One  other  aspect  of  Henning's  paper  tends  to  minimize  the  signifi- 
cance of  the  disagreement  at  the  two  high  temperatures.  He  is  led  by 
his  points  at  140°  and  180°  to  tie  conclusion  that  the  curve  L  =/{t) 
is  a  straight  line  between  120°  and  180°.  Now,  of  course,  it  is  pos- 
sible that  he  and  Regnault  are  both  right  in  finding  unexpectedly 
high  values  near  180°,  and  that,  because  of  changing  polymerization 
or  some  other  disturbing  condition,  the  character  of  the  curve  L  =f(t) 
between  120°  and  180°  is  very  different  firom  that  which  it  is  known 
to  have  below  120°  and  fix)m  that  which  it  must  begin  again  to  have 
somewhere  above  180°,  if  it  is  to  come  vertically  to  zero  at  the  critical 
temperature  as  is  commonly  supposed.  This  is,  however,  not  probable, 
and  until  Henning's  180°  point  is  definitely  verified  by  observations 
with  unquestionable  apparatus,  the  writer  will  still  believe  that  the 
formula  proposed  in  this  paper  is  nearer  the  trutii  than  is  Henning's 
straight  line.  The  excellence  of  the  confirmation  between  65°  and 
121°  and  also  at  160°  seems  more  significant  than  the  disagreements 
at  140°  and  180°. 

Another  check  of  the  new  H  formula  can  be  obtained  by  computing 
fi'om  it  the  specific  volume  of  saturated  steam  by  means  of  Glapyron's 
equation 

This  check  has  been  carried  through  independently  by  Peabody^  and 
by  the  writer.  26  In  both  cases  the  necessary  values  of  dp/dt  were  taken 
firom  the  recent  paper  of  Holbom  and  Henning  on  the  saturation  pres- 
sures of  steam,^  and  the  values  of  X  were  based  on  the  formula  pro- 
posed in  this  paper.  The  choice  of  a  suitable  value  for  JTioo  and  of 
suitable  values  for  the  heat  of  the  liquid  which  has  to  be  subtracted 

«*  Proc.  Am.  Soc.  Mech.  Engs.,  1909,  31,  695. 
»•  Marks  and  Davis,  Steam  Tables. 
«•  Wied.  Ann.,  1908,  26,  833. 


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280  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

from  H  to  give  Z,  was  in  each  case  aooomplished  independently  o^  and 
to  a  minor  extent  in  disagreement  with,  the  judgment  of  the  other, 
but  in  each  case  the  greatest  difference  between  thid  computed  values 
and  those  actually  observed  by  Knoblauch,  Linde,  and  Klebe27  was 
under  two  tenths  of  one  per  6ent»  and  in  each  case  the  average  of  the 
deviations  was  about  one  tenth  of  one  per  cent  and  they  were  nearly 
equally  divided  between  plus  and  minus.  It  is  probable  that  some  of 
these  deviations  may  properly  be  attributed  to  errors  in  the  observed 
values. 

The  accuracy  of  the  new  H  formula  can  now  be  estimated.  It  has 
been  pointed  out  that  the  self-consistency  of  the  computed  i)oints  indi- 
cates a  precision  of  the  order  of  a  twentieth  of  one  per  cent.  The 
actual  error  is  probably  larger  than  this  because  of  systematic  errors 
in  Knoblauch's  specific  heats.  It  is  possible  that  these  will  ultimately 
be  raised  enough  to  make  ^im  a  tenth  or  even  a  sixth  of  one  per  cent 
larger.  Inasmuch,  however,  as  the  other  two  tests  which  have  been 
applied,  based  on  Henning's  direct  nieasurements  of  H  and  on  Knob- 
lauch, Linde,  and  Klebe's  volume  measurements,  have  both  led  to  an 
estimated  accuracy  of  a  tenth  of  one  per  cent  or  better,  a  part  of  the 
outstanding  disagreement  in  each  case  being  furthermore  reasonably 
attributable  to  possible  errors  on  the  observed  as  well  as  on  the  com- 
puted side  of  the  comparison,  it  would  seem  that  a  claim  of  a  tenth  of 
one  per  cent  for  the  accuracy  of  the  new  H  formula  between  100°  and 
190°  is  justified. 

B.  The  valm  of  ffioo-  —  In  what  is  to  follow  a  suitable  value  for  Hioo 
will  be  necessary.  Henning's  work  has  already  been  shown  to  lead  to 
the  value 

^100  =  639.26  mean  calories  (Henning). 

Another  available  value  is  that  of  Joly  ^8  who  compared  the  latent 
heat  of  steam  at  99.96°  with  the  mean  specific  heat  of  water  between 
11.89°  and  99.96°.  The  latter  number  is  0.99949  according  to  the 
curve  used  in  the  steam  tables  already  mentioned.  The  resulting  value 
of  i/ioo  is 

i/ioo  =  638.82  mean  calories  (Joly). 

In  this  determination  of  ZTioo  Begnault's  measurements  wiU  not  be 
considered  at  all.  They  show  unmistakable  evidence  of  running 
lower  than  they  should,  probably  for  the  same  reason  that  makes 

«  Forschungsarb.,  1905,  21,  33. 
>•  Loc,  cU,f  on  page  268. 


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DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OF  STEAM.  281 

Thomas'  values  of  C>  at  saturation  correspondingly  too  high.  Only 
recently  has  it  become  evident  how  difficult  it  is  to  remove  the  last 
traces  of  moisture  from  apparently  dry  steam,  and  if  any  remained  in 
Regnault's  steam,  it  would  have  made  his  results  too  low,  just  as  they 
seem  to  be. 

The  mean  of  Henning's  and  Joly's  values  of  iJioo  is  639.04  if  both 
are  weighted  alike,  or  639.11  if  Henning's  has  (as  it  seems  to  deserve) 
twice  the  weight  of  Joly's.    The  final  formula  for  H  is,  therefore, 

H  =  639.11  +  0.3745  {t  -  100)  -  0.000990  (t  ~  100)*  mean  calories. 

The  steam  table  of  Marks  and  Davis,  which  was  computed  before 
the  appearance  either  of  Henning's  second  paper  or  of  Barnes'  revision 
of  his  value  of «/,  was  based  on  ZT^o  =  639.08,  which,  as  it  happens,  is 
between  the  two  means  just  found,  and  nearer  to  either  of  them  than 
the  limit  of  error  of  the  work  demands.  The  values  of  H^  L  and  L/T 
in  that  table  will  be  used  in  the  rest  of  this  paper  as  representing  the 
best  available  dataw 

C.  Extrapolation  formulm  for  H  arid  L,  —  The  range  within  which 
the  new  H  formula  holds  has  been  set  as  from  100^  to  190°.  Above 
the  latter  temperature  no  observations  are  available.  It  is  often 
important,  however,  both  in  scientific  and  in  technical  work,  to  have  at 
least  reasonably  accurate  steam  tables  at  considerably  higher  tempera- 
tures. It  is,  therefore,  desirable  to  develop  as  safe  an  extrapolation 
formula  as  possible  for  either  H  or  L. 

For  this  purpose  the  second  degree  H  formula  proi)osed  above  is 
wholly  unsuited.  Within  the  range  for  which  it  is  proposed,  it  happens 
to  be  an  unusually  good  three  term  Taylor's  series  development  of  the 
true  function  but  it  cannot  be  extrapolated  safely  either  up  or  down. 

Thali  it  cannot  be  used  near  0°,  is  seen  from  Figure  6,  where  the 
small  circles,  not  previously  mentioned,  represent  values  of  the  deriva- 
tive of  H  with  respect  to  t,  obtained  from  the  five  sets  of  experimental 
values  mentioned  on  page  268.  It  is  evident  that  the  graph  of  dHjdt 
against  t  is  not  a  straight  line  over  the  whole  range  from  0°  to  200^. 
No  second  degree  formula  that  fitted  the  observations  above  100*^ 
could  be  expected  to  reproduce  those  near  0°  also. 

That  a  second  degree  formula  is  no  less  unsatisfiu^ry  for  a  extrapo- 
lation to  high  temperatures  can  be  shown  as  follows.  Let  it  be  as- 
sumed that  the  top  of  the  steam  dome  on  either  the  pv  or  the  T  N 
(temper»ture-entropy)  plane  is  round  like  Figure  la  and  not  pointed 
like  Figure  Ib,^    This  is  the  usual  assumption,  and  it  is  corroborated 

>*  It  follows  from  the  Clapyron  equation  that  if  the  dome  is  round  on 
either  plane,  it  will  be  on  botL 


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282 


PROCEEDINGS    OF    THE   AMERICAN   ACADEMY. 


by  the  work  of  a  number  of  observers.^  Now  according  to  a  familiar 
equation  of  thermodynamics 

dff=TdN+vdp 

for  any  transformation,  and  in  particular  for  one  along  the  saturation 
line.  Dividing  by  dt  and  passing  along  that  line  to  the  critical  temper- 
ature as  a  limit,  gives 

=  —  00  +  constant 


4oor 


FiouKE  7  a. 


Figure  76. 


The  steam  dome  on  the  temperature-entropy  plane.  The  full  lines  are 
drawn  to  scale;  the  dotted  lines  show  two  possible  shapes  near  the  critical 
point,  of  which  the  first  is  almost  certainly  right. 

• 
That  is,  H  must  not  only  pass  a  maximum  below  the  critical  tempera- 
ture, but  must  approach  that  temperature  with  so  sharp  a  turn  down- 
ward as  to  reach  it  with  a  vertical  tangent  The  H  curve  is  throughout 
a  curve  not  only  of  constantly  changing  slope  but  also  of  constantly 
increasing  curvature  as  is  shown  in  the  upper  part  of  Figure  8,  and  it  is 
only  in  very  limited  regions  that  the  first  three  terms  of  a  Taylor's 
development  can  be  expected  to  represent  it  with  sufiicient  exactness. 
It  might  be  possible  to  invent  a  function  having  the  general  properties 
indicated  by  Figure  8,  if  one  knew  the  value  of  H  at  the  critical 

»•  See  for  example  papers  by  Cailletet  and  Mathias,  C.  R.,  1886, 102,  1202, 
and  1887,  104,  1663;  by  Amagat,  C.  R.,  1892,  114,  1093;  and  by  Young, 
Phil.  Mag.,  1900,  60,  291.  See  also  the  diagrams  for  normal  pentane  on  pages 
166  and  167  of  Young's  book  on  Stoichiometry,  Longman's  (1908). 


Digitized  by 


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DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OF  STEAM. 


283 


temperature.    Inasmuch  as  nothing  is  known  about  that  final  value 
of  H^ui  such  an  empirical  treatment  gives  no  promise  of  significance. 

In  the  case  of  X,  on  the  other  hand,  one  learns  from  an  inspection  of 
figure  8,  not  only  that  dLfdt  ==  —  od  at  the  critical  i)oint,  but  also  that 
Z  =  0  there.    This  led  Thiesen  in  1897,^^  to  the  fortunate  suggestion 


400 


Figure  8.  The  steam  dome  on  the  Hi  plane,  showing  the  relationship 
between  the  graphs  representing  the  "total  heat  of  saturated  steam"  and 
the  *'  heat  of  the  liquid."  The  former  (the  upper  boundary  of  the  steam 
dome)  is  the  cur/e  that  Regnault  beUeved  to  be  a  straight  line.  It  obviously 
passes  a  maximimi  and  reaches  the  critical  point  with  a  negatively  infinite 
derivative. 

that  if  the  known  values  of  L  at  ordinary  temperatures  can  be  repre- 
sented by  a  formula  of  the  form 

L-A  (t,  —  0^        n<l, 

one  could  also  be  sure  that  it  gave  correct  values  both  for  L  and  for 
dL/dt  at  tiie  critical  point,  so  that  the  use  of  the  formula  for  other  high 
temperatures  would  be,  in  a  sense,  an  interpolation  rather  than  an 
extrapolation.  The  constants  can  be  determined  and  the  formula 
tested  in  the  range  of  the  known  X's  by  writting  it  in  the  logarithmic 
form 

»i  Verb.  Phys.  Gesch.,  Berlin,  1897, 16,  80. 


gedbyGoOgle 


284 


PB0CEEDING8  OF  THE  AMERICAN  ACADEMY. 


log  X  =  n  log  (tc  —  0  +  log  A. 

That  is,  if  log  L  is  plotted  against  log  (t^  —  t)  one  should  get  a  straight 
line.  This  turns  out  to  be  remarkably  near  the  truth.  Thiesen  origi- 
nally suggested  n  =  1/3 ;  Henning  ^^  showed  that  his  observations 
below  100°  could  be  represented  by  putting  n  =  0.31249  and  A  = 
94.21 ;  a  careful  plot^  a  year  ago,  of  the  values  available  before  the 
appearance  of  Henning's  work  above  100°,  but  including  the  values  in 
Table  I.  in  this  paper,  led  to  n  =  0.3150  and  A  =  92.93.  The  work 
has  been  carefully  repeated  this  £edl.  Including  Henning's  new  work 
and  the  values  in  this  paper,  37  values  of  L  are  available.    They  were 

TABLE  III. 


Range. 

No.  of  deviations. 

Ali^ebraic  average  of 

deviations  in  fractions 

of  one  per  cent. 

+ 

- 

O**-   70'' 

70''- 130** 

130«-190«» 

2 

14 

4 

9 
0 

8 

-0.027% 
+0.023% 
-0.003%  ♦ 

37-20  +  17 

*  This  includes  Henning's  point  at  181°  with  a  deviation 
of  +0.167%  (see  page  278) ;  if  this  one  point  is  omitted,  the 
last  value  in  the  above  table  would  be  —0.018%. 

plotted  logarithmically  on  a  large  scale,  and  the  slope  of  the  line  that 
best  represented  them  was  determined  graphically  by  stretching  a  thread 
among  the  points.  This  was  done  several  times  by  each  of  two 
different  people,  their  results  being  closely  accordant  The  average 
of  their  values  of  n  was  then  used  to  compute  A  arithmetically.  The 
result  is  exactly  the  same  as  that  of  a  year  ago,  namely, 

L  =  92.93  (365  -  0^*"" 

The  average  of  the  numerical  values  of  the  differences  between  the  37 
observed  values  of  L  and  the  numbers  computed  by  means  of  the 
above  formula  is  one  fourteenth  of  one  per  cent,  which  is  less  than  the 
probable  accuracy  of  the  measurements.  It  is  true  that  there  is  some 
evidence  of  regularity  among  the  deviations  as  the  above  table  shows. 

M  Wied.  Ann.,  1906,  21,  870. 


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DAVIS.  —  CERTAIN  THERBiAL  PROPERTIES  OF  STEAM.  285 

These  average  deviations  are,  of  course,  very  small,  but  the  larger 
deviations  in  eaoh  group  tend  to  cluster  and  to  approach  the  limit 
of  accuracy  of  die  measurements,  so  that  the  S3rstematic  variation  may 
be  real  In  any  case,  its  amplitude  is  so  small  that  it  deserves  but 
little  consideration  at  this  time. 

4.    Discussion  op  the  Specific  Heat  of  Sttperhbated  Steam. 

It  is  the  purpose  of  the  rest  of  this  paper  to  collect  and  revise  such 
useful  computations  of  other  thermal  properties  of  steam  as  are 
affected  by  a  change  in  the  accepted  values  of  the  total  heat  of 
saturated  steam,  together  with  such  other  results  as  are  valuable  for 
comparison  with  them.  Section  4  will  be  concerned  with  the  specific 
heat  of  superheated  steam.  Many  papers  on  this  subject  have  been 
published  during  the  last  ten  years,  especially  in  the  technical  press. 
They  can  be  roaghly  classified  under  the  following  heads. 

A.  Direct  experimental  determinations. 

B.  Indirect  experimental  determinations  and  computations  from 
other  data. 

a.  Throttling  experiments. 

b.  Gompatations  based  on  characteristic  equations  or  on  volume 

measurements. 

c.  Computations  based  on  the  Joule-Thomson  effect. 

d.  Computations  along  the  saturaticm .  line  based  on  Planck's 

equation. 

e.  Other  computations. 

C.  Resumes  and  discussions. 

Each  of  these  possible  sources  of  information  will  be  discussed  in  turn, 
with  the  object,  not  so  much  of  reviewing  previous  papers,  as  of  getting 
by  each  method  the  best  information  that  the  new  material  in  this  and 
in  the  preceding  paper  makes  possibla 

A.  Direct  experimental  determinations.  —  Three  of  the  papers  that 
belong  in  this  subsection  have  already  been  discussed  in  Section  2. 
The  conclusion  there  reached  was  that  of  the  three,  that  of  Knoblauch, 
Linde  and  Elebe  was  the  most  reliable.  Their  results  will  therefore 
be  used  as  the  point  of  departure  of  this  section,  it  being  the  object 
of  each  subsection,  either  to  test  the  justice  of  the  decision  that  their 
work  is  preferable  to  Thomas  \  or  to  determine  what  changes  should 
be  made  in  their  curves  to  bring  them  nearer  to  the  truth. 

The  most  fiunous  of  all  contributions  to  this  subject  is  Begnault's 
direct  experimental  determination  of  C,  in  1862.^    It  seems  not  to  be 

M  Mem.  Inst,  de  France,  1862,  26,  167. 


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286 


PROCEEDINGS   OF   THE   AMERICAN.  ACADEMY. 


generally  known  that  his  compatatibns  involve  one  step  which  modem 
work  has  shown  to  be  erroneous.  He  made  four  sets  of  experiments, 
all  at  atmospheric  pressure,  and  all  covering  about  die  same  range  of 
superheat.  In  each  experiment,  first  slightly  superheated  steam,  and 
later  highly  superheated  steam  at  the  same  pressure,  was  condensed  in 
a  water  calorimeter.  The  heat  released  per  gram  of  steam  in  the  first 
process  was  then  subtracted  fi*om  that  released  per  gram  of  steam  in 
the  second  process  and  the  difference  divided  by  the  difference  in 
superheat  to  give  Cp.  The  results  which  he  deduced  irom  his  experi- 
ments will  be  found  in  the  third  column  of  Table  IV.  below. 
The  error  which  he  made  was  in  the  determination  of  the  quantity 

TABLE  rv. 
A  Recomputation  op  Regnault's  Values  op  Cp, 


Temp,  range 

R's  value 
ofC,. 

New  value 
ofCp. 

Kn'a  value 
ofC,». 

Series  1 
Series  2 
Series  3 
Series  4 

127.7-231.1 
137.7-225.9 
124.3-210.4 
122.8-216.0 

(0.46881)  ♦ 
0.48111 
0.48080 
0.47963 

(0.4655)  ♦ 
0.4769 
0.4736 
0.4780 

0.462 
0.462 
0.462 
0.462 

Mean  of  last  three    .   .   .          0.48051                0.4762 

*  " .  .  .  les  r^sultats  de  la  premiere  s^rie,  qui  m'inspirent  moins  de 
confiance  que  les  autres.  .  .  .       Regnault,  p.  178. 

of  water  in  his  calorimeter.  This  he  accomplished,  not  by  weighing, 
but  by  a  volumetric  measurement  in  a  sheet  iron  tank  filled  each  time 
to  a  scratch  on  the  glass  tube  that  formed  its  neck.  Regnault  knew 
that  the  coefficients  of  expansion  of  the  water  and  of  the  tank  were 
such  that  the  tank  would  hold  fewer  grams  of  water  at  the  room 
temperatures  at  which  he  worked  than  at  0°,  the  temperatare  at 
which  he  had  calibrated  the  tank.  But  he  supposed  that  he  also  knew 
the  specific  heat  of  water  to  be  an  increasing  function  of  the  tempera- 
ture at  room  temperatares  as  well  as  above  100°  where  he  had  care- 
fully studied  it  He  therefore  neglected  both  temperature  changes, 
thinking  that  they  neutralized  each  other,  and  used  at  all  room 
temperatures  the  weight  that  would  have  filled  the  tank  at  0°,  and 
the  specific  heat  1. 


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DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OP  STEAM.  287 

We  now  know  that  the  specific  heat  of  water  decreases  with  in- 
creasing temperature  from  0°  to  above  25°.  There  is  some  difference 
of  opinion  between  Barnes  and  Dieterioi,  the  two  leading  investigators 
of  the  subject,  as  to  the  exact  shape  of  the  curve  of  variation,  but  it 
is  near  enough  to  the  truth  to  take,  as  in  the  steam  tables  already 
mentioned,  a  mean  curve  between  that  of  Barnes  and  that  of  Dieterici, 
giving  the  former  twice  the  weight  of  the  latter. 

Regnault's  values  of  C,  have  been  recomputed  from  the  data  in  his 
memoir,  using  his  own  value  for  the  coefficient  of  expansion  of  sheet 
iron,  modem  data  for  the  density  of  water,  and  the  mean  curve  just 
mentioned  for  the  specific  heat  of  water.  The  new  results  are  given  in 
the  fourth  column  of  Table  IV.  They  are  somewhat  lower  than  his 
original  values  and  are  thereby  brought  nearer  to  the  corresponding 
values  obtained  by  Knoblauch  and  Jakob,  which  are  given  in  the  fifth 
column  of  the  table. 

In  the  present  unsettled  state  of  our  knowledge  of  C,^  Regnault's 
work  should  have  considerable  weight 

The  only  other  important  direct  experimental  determination  of  G^  is 
that  of  Holborn  and  Henning.^  Their  work,  like  Regnault's,  was  only 
at  atmospheric  pressure,  but^  unlike  his,  it  covered  a  very  wide  temper- 
ature range,  reaching  1400^  G.  It  is  certainly  to  be  regarded  as  standard 
in  the  region  of  high  superheats.  It  shows  that  in  that  region  C^  in- 
creases with  increasing  temperature,  but  not  as  rapidly  as  Eoioblauch's 
curves  would  indicate. 

In  a  "  Memorandum  by  the  Chief  Engineer  for  the  year  1906  to  the 
Executive  Committee  of  the  Manchester  Steam  Users  Association,"  ^5 
the  National  Physical  Laboratory  at  Teddington,  England,  is  said  to 
have  found  Cp  =  0.532  at  saturation  at  4.3  atmospheres  (147°  C). 
This  value  lies  remarkably  close  to  Knoblauch's  saturation  curve. 

Ba.  Throttling  experiments.  —  The  failure  of  even  the  best  throt- 
tling experiments  to  give  satisfactory  values  of  C^  by  the  ordinary 
methods  has  already  been  mentioned.  A  new  method  elaborated  by 
Dodge  ^  is  much  more  promising,  but  no  thoroughly  reliable  results 
have  yet  been  obtained  by  it. 

Bb.  Characteristic  equations :  —  If  a  sufficiently  accurate  character- 
istic equation, /(p,  v,  t)=0,  were  known  for  superheated  steam,  much 
useful  information  about  C>  could  be  obtained  from  Clausius's  equation 


(Wr"""'K^v; 


»•  Ann.,  1907,  23,  809.  »  Manchester,  June  4,  1907. 

»•  Proc.  Am.  Soc.  Mech.  Engs.,  1907,  28,  1266  and  1908,  30, 1227. 


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288 


PROCEEDINGS   OF  THE    AMERICAN   ACADEMY. 


At  the  present  time  this  is  not  a  good  way  to  get  information  about 
Cp  for  two  reasons.  In  the  first  place,  all  of  the  most  reliable  set  of 
volume  measurements  yet  made  (Knoblauch,  Linde  and  Elebe)  lie 
close  to  the  saturation  line,  not  one  of  them  reaching  either  50°  of 
superheat  or  190*^  of  temperature.  No  characteristic  equation  based 
on  them  can  be  depended  on  at  i)oint8  £aur  out  in  the  superheated 
region.  And  in  the  second  place,  Glausius'  equation  inyolyes  a  second 
derivative  of  the  observed  quantity  v^  and  even  the  first  derivative  of 
an  empirically  determined  function  is  liable  to  relative  errors  much 


100  200  800  t    400 

Figure  9.  Knoblauch  and  Jakob's  measurements  of  Cp^  reduced  to  a 
pressure  of  1  kg.  per  sq.  cm.  by  means  of  Clausius'  equation,  using  the  char- 
acteristic equation  developed  by  Linde  to  represent  the  volume  measurements 
of  Knoblauch,  Linde,  and  Klebe.  The  smallest  circles  correspond  to  the 
highest  original  pressure  (8  kg.)>  the  next  smallest  to  6  kg.,  and  so  on.  The 
progressive  departure  from  a  single  curve  with  increasing  pressure  is 
marked. 

larger  than  any  in  the  observed  quantity  itself,  while  a  second  deriva- 
tive is  still  more  uncertain.  This  is  illustrated  by  the  fact  that  a 
characteristic  equation  of  Tumlirz's  form,  which  was  shown  by  Linde 
to  represent  Knoblauch's  volume  measurements  within  four  fifths  of 
one  per  cent  throughout  their  range,  leads  through  Clausius'  equation 
to  the  startling  result  that  C,  does  not  vary  at  all  with  pressure  at 
constant  temperature,  whereas  it  is  known  to  vary  within  that  same 
range  by  something  like  60  per  cent  of  its  initial  value. 

The  contention  that  even  the  best  i)0S8ible  representation  of  Knob- 
lauch's volume  measurements  is  still  too  inaccurate  to  give  reliable 
values  of  C>,  through  Clausius'  equation,  can  be  further  substantiated 
by  an  examination  of  the  experimental  data  already  described.  Knob- 
lauch and  Jakob  made  observations  on  C^  at  four  pressures,  all  greater 


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DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OF  STEAM.  289 

than  one  atmosphere.  If  these  are  all  "redaced  "  to  one  atmosphere 
hy  means  of  Glausias'  equation,  using  Linde's  best  characteristic  equa- 
tion to  represent  the  volume  measurements,  the  results,  plotted  in 
Figure  9,  show  deviations  from  a  common  curve  that  increase  with  the 
pressure.  The  same  is  more  strikingly  true  in  Thomas'  case.  If  his 
results,  so  recomputed  ^7  as  to  partly  eliminate  the  wet  steam  error 
already  mentioned  (see  page  271),  are  similarly  reduced  to  one  atmos- 
phere by  means  of  Clausius'  thermodynamic  equation  and  Linde's 
best  characteristic  equation,  the  progressive  departure  with  increasing 
pressure  from  the  probable  curve"  for  one  atmosphere  is  very  marked, 
the  500  lb.  and  600  lb.  values  disappearing  beyond  the  bottom  of  the 
diagram  altogether.  That  is,  although  Linde's  second  best  equation 
gave  no  variation  of  C^  with  pressure  at  all,  his  best  one  gives  alto- 
gether too  much.  The  experimental  evidence  is  thus  wholly  against 
die  reliability  of  any  C^  values  obtained  by  means  of  Glausius'  equation 
from  any  volume  measurements  as  yet  available 

Be.  The  Joule-Thomson  ^ect.  —  There  are  three  ways  in  which 
C^  can  be  connected  with  the  Joule-Thomson  coefficient  fu  The  first  of 
these  was  suggested  almost  simultaneously  by  Linde  and  by  Planck.^ 
It  is  thermodjmamically  rigorous,  except  for  the  assumption  of  the 
form  of  an  analytical  expression  for  /a  as  a  function  of  t  The  one 
they  used,  namely, 

_  Const. 

was  proposed  by  Joule  and  Thomson  in  their  original  memoir  on  air, 
and  is  not  at  all  accurate,  especially  for  steam.  If  it  is  replaced  by  a 
more  complicated  expression,  the  integration  of  the  partial  differential 
equation,  to  which  the  reasoning  of  Linde  and  Planck  leads,  is 
impossible. 

A  second  equation  connecting  Cp  with  fi  is  used  by  Griessmann  ^ 
in  the  discussion  of  his  throttling  experiments.  It  is  not  a  thermody- 
namic equation  in  the  true  sense  because  it  does  not  involve  either 
of  the  two  laws  of  thermodynamics ;  it  is  merely  a  manipulative 
identity  that  can  be  proved  by  the  laws  of  partial  differentiation  — 
that  is  a  truism.  It  says  that  at  any  point  in  any  thermodynamic 
plane 

«  Davis  Proc.  Am.  Soc.  Mech.  Engs.,  1908,  30,  1433. 
»•  Linde,  Sitzimgsber,  bays.  Akad.,  Math.  Kl.,  1897;  Planck,  "Vorlesungen 
Qber  Thermodynamik,"  1897,  117;  Eng.  ed.,  1903,  124. 
»»  Forechungsarb.,  1904, 18,  7  and  46. 
VOL.  XLV.  — 19 


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PBOCKEDINQS   OF   THE    AMERICAN    ACADEMY. 


provided  only  that  both  derivatives  are  taken  in  the  same  direction 
from  the  point  Griessmann  uses  the  equation  over  the  whole  plane, 
but  makes  certain  experimentally  deduced  assumptions  which  do  not 
now  seem  to  be  j  ustified. 

The  equation  is  likely  to  be  most  useful  along  the  saturation  line 
where  dH/dt  and  dp/dt  are  both  well  known.  Unfortunately  n  is  not 
as  yet  well  known  at  such  low  temperatures,  and  it  will  be  interesting 
to  see  whether,  in  the  development  of  the  subject^  Griessmann's  truism 
turns  out  to  be  more  useful  for  the  computation  of  C,  at  saturation 
from  fi  or  of  fi  from  C^ 

The  only  use  that  will  be  made  of  the  equation  in  this  paper  is  to 
deduce  from  it  the  well-known  theorem,  usually  attributed  to  Bankine, 
that  at  ordinary  temperatures  Cp  at  saturation  must  be  numerically 
greater  than  dH^at/dt^  At  most  temperatures  this  condition  is  so 
overwhelmingly  fulfilled  as  to  be  of  no  value.  At  0**C.  it  requires 
that  Cp  at  saturation  be  as  great  as  0.44.  Now  if  Knoblauch's  satura- 
tion curve  is  continued  to  temperatures  below  100°  C,  this  condition 
will  be  found  to  require,  either  that  the  curve  passes  a  minimum 
between  100°  and  0°,  or  that  it  must  lie  somewhat  higher  between 
100°  and  150°  so  as  to  approach  smoothly  the  right  value  at  0°.  The 
existence  of  such  a  minimum  has  several  times  been  suspected  as  a 
result  of  other  indirect  computations,  and  its  experimental  verification 
would  be  a  matter  of  some  interest ;  in  the  mean  time  the  other  alter- 
native seems  more  probable,  especially  as 
it  brings  Knoblauch's  values  of  Cp  at 
atmospheric  pressure  into  better  agree- 
ment with  Regnault's.  Additional  con- 
firmation of  this  decision  will  be  found  on 
pages  293  and  300. 

The  third  of  the  methods  referred  to 
above  for  connecting  Cp  with  fi  is  appar- 
ently new.  It  involves  an  equation  which, 
like  Griessmann's,  is  merely  a  manipula- 
tive identity  or  truism.  It  can  be  devel- 
oped as  follows.  In  Figure  10,  let  ab  and 
cd  be  parts  of  two  throttling  curves  on  the  usual  tp  diagram,  the  corre- 
sponding values  of  the  total  heat  being  If  and  H  +  AH,  Then  at 
the  pressures  p  and  j9  -h  Ap  we  have 

^  This  follows  at  once  from  the  fact  that  both  /a  and  C/  are  known  to  be 
positive. 


Figure  10. 


Digitized  by  ^ 


DAVIS.  —  CEBTAIN  THEBMAL  PBOPEBTIES  OF  STEAM. 


291 


C>  lim 


from  which 


and        (^p+^p-^i.o^^—f. 


Now,  except  for  tenns  of  higher  order  than  AZT  and  Ap, 


Substitating  this  above  gives 

^p+^p  —  Q>  lim 


and  the  limit  sign  is  no  longer  necessary.    Dropping  it,  dividing  by 
A/>,  and  then  letting  Ap  approach  zero,  gives 

Integrating  this  at  constant  H  gives  as  the  final  equation  *i 

^  The  differential  form  of  this  equation  can  also  be  proved  analytically  as 
follows:  For  any  three  related  quantities  p,  tj  and  H,  one  has  the  identity 


But 


and  therefore 


\dt)H\dH)Adv)i  "       ^' 


18  C/  which  can  be 
one  has  a  second  i< 
(dCj,\         (dCA   /dp\         (dCA    (dt\ 


(1) 

But  for  any  function  such  as  C/  which  can  be  expressed  in  terms  of  any  two 
of  the  variables  p,  (,  and  H,  one  has  a  second  identity 


Digitized  byLaOOQlC 


292  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

This  fonniila  has  the  disadvantage,  as  compared  with  Griessmann's, 
of  involving  the  derivative  of  the  inaccurately  known  function  /*. 
This  prohibits  its  use  at  the  low  temperatures  close  to  saturation  where 
fi  is  scarcely  known  at  all,  but  makes  much  less  difference  at  very  high 
temperatures  where  the  CO2  jwints  of  Figure  5  of  the  preceding  paper 
help  to  place  the  fi  =/(0  curve  with  great  definiteness.  This  method 
of  computation  is  therefore  at  its  best  where  many  others  tail  completely. 

The  use  of  the  new  equation  at  ordinary  temperatures  is  a  matter 
requiring  patience  and  much  labor.  First  one  computes  and  plots 
against  t  the  derivative  of  the  fi=/(t)  curve  of  the  preceding  paper. 
Next  one  computes  from  the  curve  of  fi  itself  the  progress  of  some 
curve  of  constant  ff  across  the  p  t  plane ;  this  is  necessary  so  as  to  be 
able  to  express  dfi/dt  as  a  function  of  p  in  the  int^fral.  Then  the 
integral  has  to  be  evaluated,  either  by  replotting  dfA,/dt  against  p  for 
the  particular  H  curve  in  question  and  using  an  int^fraph,  or  by  a 
step  by  step  numerical  process.  The  results  are  the  Naperian  loga- 
rithms of  the  desired  ratios. 

This  process  has  been  carried  through  for  four  curves  in  the  region 
of  moderate  superheats.  The  results,  which  are  presented  in  the  first 
part  of  Table  V.,  are  in  general  in  substantial  agreement  with  the  corre- 
sponding ratios  computed  from  Eoioblauch's  curves,  which  are  given  in 

"-    (t).-(t).-'(fi-  ^ 

Now  from  the  definition  of  C/ 

(V//  "  \d^)r  \dth  'dvdt'  ^^^ 

and  from  (1) 

Substituting  (3)  and  (4)  in  (2)  and  using  (1)  gives  the  desired  equation. 
Neither  of  the  Laws  of  thermodynamics  has  been  used. 

The  differential  form  of  the  equation  can  also  be  deduced  immediately 
from  the  equation 


which  Grindley  proves  on  pages  31  and  32  of  his  paper  in  the  PhUosophieal 
Transactions.  His  proof  depends  twice  over  on  each  of  the  two  laws  of 
thermodynamics,  but  it  need  not  have,  as  the  above  derivations  show.  The 
use  which  he  makes  of  his  form  of  the  equation  is  quite  different  from  that 
here  proposed. 


Digitized  by 


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DAVIS.  —  CEBTAIN  THERMAL  PROPERTIES  OF  STEAM. 


293 


the  last  of  ea<5h  set  of  columns.  The  chief  disagreement  is  along 
carve  1  where  Knoblauch's  carves  are  too  condensed.  This  means 
either  that  his  carve  at  atmospheric  pressure  should  be  lower,  or  that 
the  lower  part  of  his  saturation  curve,  with  the  constant  pressure 
curves  near  it»  should  be.  higher.  The  first  of  these  possibilities  would 
mean  even  less  agreement  between  Knoblauch  and  Regnault  than  at 
present,  and  may  therefore  be  rejected.  The  remaining  possibility  has 
already  been  suggeste^l  by  the  result  obtained  firom  Griessmann's 
truism  (see  page  290).  Furthermore,  it  will  be  corroborated  again  in 
the  next  section  (see  page  300).  It  may  therefore  be  accepted  the 
more  readily  here. 
At  veiy  high  superheats,  where  the  method  is  most  valuable,  the 

TABLE  V. 
Cp  Ratios  obtainbd  from  the  Joulb-Thomson  Effect. 


Press 

{ 

[hirvel. 

{ 

[hirve2. 

Curves.             1 

kgysq. 

" 

1 

1 

cm. 

Temp. 

Cp/C,^. 

Kn. 

Temp. 

c,lc,^. 

Kn. 

Temp. 

C,/Cp^.     Kn.  1 

0.1 

121.3 

0.946 

0.97 

149.0 

0.960 

0.98 

204.5 

0.984 

0.98 

0.5 

123.3 

0.970 

0.98 

150.5 

0.979 

0.99 

205.4 

0.991 

0.99 

1.0 

125.8 

1.000 

1.00 

152.3 

1.000 

1.00 

206.4 

1.000 

1.00 

1.5 

128.2 

1.030 

1.02 

154.0 

1.020 

1.02 

207.5 

1.009 

1.01 

2.0 

130.6 

1.060 

1.03 

155.8 

1.041 

1.03 

208.5 

1.018 

1.02 

2.5 

132.9 

1.090 

157.5 

1.062 

209.5 

1.026 

3.0 

135.1 

1.120 

1.07 

159.1 

1.082 

1.06 

210.5 

1.034 

1.04 

3.5 

137.2 

1.150 

160.7 

1.102 

211.5 

1.043 

4.0 

... 

... 

... 

162.3 

1.122 

i.io 

212.5 

1.051 

1.06 

5.0 

165.5 

1.161 

214.5 

1.067 

6.0 

168.5 

1.200 

1.17 

216.5 

1.084 

1.09 

7.0 

171.4 

1.237 

218.4 

1.101 

8.0 

174.3 

1.264 

1.25 

220.2 

1.118 

1.12 

9.0 

... 

... 

177.0 

1.309 

... 

222.1 

1.135 

10.0 

179.7 

1.344 

1.34 

223.9 

1.151 

1.15 

12.0 

227.5 

1.183 

14.0 

... 

... 

... 

230.9 

1.215 

16.0 

... 

... 

. . . 

... 

... 

234.3 

1.246 

18.0 

... 

... 

... 

237.6 

1.277 

... 

20.0 

240.9 

1.307 

22.0 

... 

244.1 

1.337 

24.0 

... 

... 

... 

. . . 

247.2 

1.367 

26.0 

250.3 

1.396 

28.0 

253.4 

1.424 

... 

Digitized  by  LjOOQIC 


294 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


TABLE  y^  continued. 


PrMm 

Curve  4. 

Curves, 

Curve  6, 

Curve?, 

Curves, 

kg./8q. 

near 
486°  C. 

near 
600°  C. 

near 
926°  C. 

near 
1480°  C. 

cm. 

Temp. 

C,/Cp^. 

Kn. 

Cp/C,^. 

Cp/Cp^. 

Cp/Cp^, 

Cp/Cp^ 

0.1 

287.8 

0.994 

0.99 

1.0 

288.9 

1.000 

1.00 

i.booo 

1.6660 

1.6660 

1.6660 

2.0 

290.1 

1.007 

1.01 

1.0025 

1.0016 

1.0009 

1.0004 

4.0 

292.4 

1.020 

1.025 

1.0053 

1.0036 

1.0020 

1.0010 

6.0 

294.7 

1.032 

1.035 

1.0082 

1.0055 

1.0031 

1.0015 

8.0 

297.0 

1.044 

1.045 

1.0106 

1.0072 

1.0041 

1.0019 

10.0 

299.2 

1.057 

1.055 

1.014 

1.009 

1.005 

1.002 

12.0 

301.4 

1.069 

•  •  • 

1.016 

1.011 

1.006 

1.003 

14.0 

303.6 

1.081 

1.019 

1.013 

1.007 

1.003 

16.0 

305.8 

1.093 

•  •  • 

1.022 

1.015 

1.008 

1.004 

18.0 

308.0 

1.105 

1.025 

1.017 

1.009 

1.004 

20.0 

310.1 

1.117 

1.028 

1.019 

1.011 

1.005 

22.0 

313.3 

1.128 

• . . 

1.030 

1.020 

1.012 

1.005 

24.0 

314.4 

1.140 

•  •  • 

1.033 

1.022 

1.013 

1.006 

26.0 

316.4 

1.151 

• . . 

1.036 

1.024 

1.014 

1.006 

28.0 

318.5 

1.163 

1.039 

1.026 

1.015 

1.007 

computation  is  simpler  for  two  reasons.  In  the  first  place,  ft.  and 
dfi/dt  are  both  so  small  that  the  temperature  can  be  assumed  constant 
iJong  a  curve  of  constant  ff.  dfi/dt  is  then  constant  in  the  integra- 
tion. And  in  the  second  place  dfi/dt  can  be  compnted  firom  Bucking- 
ham's  ^  equation  for  ftf  against  f,  both  in  reduced  units,  namely, 


,  _    0.209 
^  ^  i!  -  0.32 


-  0.0368. 


This  is  corrected  for  the  £eu)t  that  although,  in  his  paper,  100  inches  of 
mercury  is  taken  as  the  unit  of  pressure,  his  critical  pressures  are  ex- 
pressed in  atmospheres.  It  was  shown  in  the  preceding  paper  that 
this  equation  can  safely  be  assumed  to  hold  for  steam  at  very  high 
superheats,  since  it  is  known  to  hold  for  the  other  gases  which  Buck- 
ingham discusses,  and  they  are  known  to  be  connected  with  steam  by 
a  law  of  corresponding  states. 

This  simpler  process  has  been  carried  through  for  the  four  very  high 
temperatures  mentioned  in  the  last  part  of  Table  V,  with  the  results 
there  presented.  These  results  are  the  basis  of  the  high  superheat 
part  of  the  Steam  Tables  of  Marks  and  Davis. 

^  Bui.  Bureau  of  Standards,  1907, 3, 263. 


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DAV18.  —  CEKTAIN  THERMAL  PROPEBTIES  OP  STEAM. 


295 


B<L  Planck's  equation :  —  There  remains  the  most  interesting  of  all 
the  indirect  attacks  on  C,  at  ordinary  temperatures.  In  1897  Planck 
published  in  his  thermodynamics  the  equation 


_dH_LL 
^~  dt       T^  u 


L\^*  )"<«-.      V»*A«.J 


This  equation  holds  only  along  the  saturation  curve.  For  its  deriva- 
tion the  reader  is  referred  to  the  English  translation  of  Planck's 
book*3  or  to  Griessmann's  paper.**  The  two  partial  derivatives  must 
be  such  as  to  describe  the  behavior  of  superheated  steam  and  of  water, 
both  close  to  the  steam  dome,  not  of  steam  within  the  steam  dome. 
In  practise,  the  second  of  these  derivatives  is  always  negligible  in 
comparison  with  the  first 

Two  sorts  of  experimental  material  are  necessary  for  computations 
with  this  equation,  a  set  of  total  heat  values  (those  proposed  in  this 
paper  will  be  used),  and  a  set  of  values  of  (dv/dt)p  for  superheated 
steam  close  to  saturation.  The  latter  can  be  based  on  the  volume 
measurements  of  Knoblauch,  Linde  and  Elebe,*^  or  on  those  on  Ram- 
say and  Young,*®  or  on  those  of  Battelli.*^ 
These  three  sources  will  be  considered  in 
turn. 

In  the  experiments  of  Knoblauch,  Linde, 
and  Klebe,  the  volume  was  held  constant 
while  tiie  pressure  and  temperature  were 
varied.  Their  results,  when  plotted  on  the 
p  t  plane,  gave  isochors  or  lines  of  constant 
volume.  These  turned  out  to  be  straight 
lines  within  the  limit  of  error  of  the  meas- 
urements. Their  slopes  are  entered  with 
other  data  in  the  main  table  of  the  original 
paper.  These  slopes  are  values  of  (dp/dt)p 
and  some  manipulation  is  necessary  to  get 
from  them  the  desired  values  of  {dv/dt)^ 
Let  Figure  II  represent  a  portion  of  the 

p  t  plane  drawn,  like  an  analytical  geometry  figure,  with  the  same  unit 
of  length  along  each  axis.    Then 


Figure  11 


*»  Treatise  on  Thermodynamics,  1903,  147. 

**  Forschungsarb.,  1904,  13,  8. 

*»  Forschungsarb.,  1905,  21,  33.  ♦•  Phil.  Trans.,  1893, 183  A,  107. 

*»  Mem.  di  Torino,  1893,  43,  63;  condensed  in  Ann.  Chim.  et  Phys.,  1894, 

408. 


Digitized  by  VjOOQIC 


296  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


'"(«+«=(l). 


This  derivative  is  well  known  from  the  work  of  Holbom  and  Henning.*® 
Also 

tan  p  =  (dp/dt\. 

This  is  the  derivative  given  by  Enoblanch,  Linde,  and  Elebe,  as  just 
explained.  Along  OB,  v  is  constant ;  along  OD,  which  is  perpendicular 
to  OBy  V  increases  most  rapidly.  The  following  equations  can  then 
be  verified,  "  Grad.  v  "  being  the  space  rate  of  v'a  increase  along  OD. 

n    J  1     «?4  —  % 

Orad.  t?  =  —  ^       " 


sma     03 

UV'QTBA,vsmp 


At 


sin  pTJU    „„   v^-vo 


A/^O  ' 


sin  a  03 -^-^      At 
sin  P 


;-<•+«©. 


sm  a 
The  last  term  of  Planck's  equation  can  then  be  written  in  the  fonn 

^\^^  /P(ste«n)  \^^  /«t.  \^^  Jp  Vi  /sat.  Sm  a 

In  this  transformation  use  has  been  made  of  the  familiar  Clap3rron 
equation  and  of  the  definition  of  tan  (a  +  ^).  The  computations  are 
carried  through  by  determining  (a  +  fi)  and  /3  from  their  tangents  and 
getting  a  by  subtraction.  The  necessary  values  of  the  differential 
coefficient  (dv/dt),^:,t  were  formed  from  the  values  of  v  in  the  Steam 
Tables  of  Marks  and  Davis  by  the  usual  finite  difference  formula 


dv  =  Av—  i  A^v  -h 


The  results  of  the  computation  are  summarized  in  the  first  part  of 
Table  VI.,  and  are  plotted  as  black  dots  in  Figure  12. 

*•  Wied.  Ann.,  1908,  26,  836. 


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DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OF  STEAM. 


297 


The  necessary  values  of  (pv/dt)p  can  also  be  obtained  by  differentiat- 
ing the  complicated  characteristic  equation  which  Linde  has  developed 

TABLE  VI. 

Values  of  Cp  at  Saturation  from  Planck's  Equation,  using: 
a.  Knoblauch,  Linde,  and  Klebe's  6.  Linde 'a  Characteristig 

EXPEBIMENTAL  DaTA.  EQUATION. 


Temp. 

c^ 

Temp. 

Cp. 

Temp. 

.    1 

Knoblauch.* 

Thomaa.* 

101.4 
102.4 
108.1 
110.7 
112.4 
114.8 
115.3 
119.1 
119.3 
122.1 
122.6 
126.3 
131.5 
131.9 
133.0 
139.1 

0.46 
0.55 
0.44 
0.56 
0.49 
0.40 
0.36 
0.50 
0.52 
0.49 
0.53 
0.49 
0.53 
0.51 
0.47 
0.53 

140.9 
143.0 
143.2 
144.1 
149.8 
150.2 
153.7 
154.2 
157.6 
159.6 
163.7 
166.0 
170.0 
174.6 
180.8 
183.0 

0.54 
0.65 
0.52 
0.52 
0.58 
0.54 
0.56 
0.60 
0.56 
0.58 
0.64 
0.59 
0.58 
0.62 
0.64 
0.66 

100.6 
126.3 
153.1 
170.1 
193.2 
205.1 
215.8 
225.1 
235.8 
245.2 
253.5 

0.484 
0.506 
0.560 
0.615 
0.722 
0.794 
0.875 
0.956 
1.067 
1.179 
1.293 

0.519 
0.533 
0.585 
0.634 
0.737 
0.808 
0.885 
0.966 
1.075 
1.184 
1.298 

♦  The  column  headed  "  Knoblauch  "  is  based  on  the  H  formula  of 
this  paper.    That  headed  "Thomas  "is  based  on  a  modified  H  formula 
derived  from  his  values  of  Cp.    It  is  inserted  only  for  comparison  with 
the  preceding  one  (see  page  299).    In  both  columns  values  above  200** 
involve  a  doubtful  extrapolation  of  Linde's  equation  beyond  its  proper 
range.    All  temperatures  are  on  the  centigrade  scale. 

Digitized  by  LjOOQIC 


298 


PROCEEDINGS  OF  THE  AMERICAN  ACADEBfY. 


TABLE   YL  —  continued. 

Values  op  Cp  at  Saturation  from  Planck's  Equation,  using: 

c.  Ramsay  and  Young's  ,    Ti*„«*,Tr,'o  <<t*»t«  iwr  » 

Experimental  Data.  d.  Battellis     Table  M. 


Temp. 

Cp. 

Temp. 

Cp. 

130.3 

0.69 

99.5 

0.46 

133.2 

0.69 

129.9 

0.42 

136.9 

0.60 

133.9 

0.48 

144.3 

0.72 

140.6 

0.49 

154.1 

0.74 

143.8 

0.50 

168.2 

0.64 

149.2 

0.50 

180.4 

1.04 

160.9 

0.49 

191.3 

0.80 

178.5 

0.48 

180.9 

0.54 

192.0 

0.55 

199.0 

0.59 

to  represent  the  same  data.  This  alternative  compntation  seems 
worth  while,  partly  because  of  the  automatic  smoothing  effect  which 
the  use  of  an  equation  based  on  all  the  observations  necessarily  has, 
but  more  because  it  means  a  redistribution  of  the  dependence  of  the 
computed  values  of  Cp  on  the  volume  measurements  on  the  one  hand 
and  the  new  11  formula  on  the  other.  The  results  of  eleven  computa- 
tions of  this  kind  are  summarized  in  the  second  part  of  Table  VI.,  and 
five  of  them  are  plotted  as  circles  in  Figure  12. 

Two  conclusions  can  be  drawn  from  Figure  12.  In  the  first  place, 
both  sets  of  points  agree  in  confirming  the  conclusion  reached  on 
page  272,  that  Knoblauch's  saturation  curve  is  nearer  the  truth  than 
Thomas'.  It  will  probably  be  argued  this  confirmation  is  simply  a 
circular  fallacy,  inasmuch  as  the  ff  formula  of  this  paper  was  based 
on  Knoblauch's  values  of  Cp  and  might  therefore  be  expected  to  lead 
back  to  them  in  the  end.  This  is  true  only  in  a  very  small  measure. 
The  dependence  of  H  on  Cp  is  such  that  comparatively  large  changes 
in  the  Cp  curves  used  at  the  beginning  of  this  paper  would  have  made 


Digitized  I 


DAVIS.  —  CERTAIN  THEBMAL  PBOPEBTIES  OF  STEAM. 


299 


only  small  changes  in  the  H  fonnula,  Cp  being  a  factor,  not  of  H  itself 
but  only  of  ^H,  And  in  the  second  part  of  the  computation,  the  re- 
dependence  of  Cp  on  H  is  again  insensitive  to  errors  in  the  assumed 
function,  which  this  time  is  H,  All  this  can  be  strikingly  illustrated 
as  follows.  It  is  easy  to  compute  approximately  by  the  method  of 
Section  3  of  this  paper  a  value  of  AJST  near  140**  and  one  near  180"^ 
using  Thomas'  values  of  C,  instead  of  Knoblauch's.     These,  with 


F200 


Figure  12.  Values  of  Cp  computed  by  Planck's  method.  The  dots  are 
based  on  the  original  volume  measurements  of  Knoblauch,  Linde  and  Klebe; 
the  circles  are  based  on  Linde's  characteristic  equation.  The  lower  curve  is 
Knoblauch's  saturation  line;  the  upper  one  is  Thomas'. 

^H  =  0  at  100°,  give  a  new  second  degree  equation  for  II=/(t)  based 
wholly  on  Thomas'  values.  Finally  this  new  H  equation  can  be  used 
with  Linde's  characteristic  equation  to  compute,  by  means  of  Planck's 
equation,  a  set  of  values  of  Cp  at  saturation  which  are  exactly  com- 
parable with  those  in  the  second  part  qf  Table  VL,  except  that  Knob- 
lauch's C,  work  is  wholly  replaced  by  Thomas'.  If  there  is  a  circular 
fallacy  in  the  confirmation  mentioned  at  the  beginning  of  this  para- 
graph, the  new  results  ought  to  confirm  Thomas'  C,  values  at  satura- 
tion just  as  definitely  as  the  old  ones  did  Knoblauch's.  As  a  matter 
of  tsyot,  this  is  not  at  all  the  case.  The  new  results  are  compared  with 
the  old  in  Figure  13,  and  agree  strikingly  in  confirming  Knoblauch's 
saturation  curve.    In  other  words,  no  matter  which  set  of  C,  values 


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300 


PROCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 


one  starts  with,  one  is  led  by  this  method  of  successive  approximations 
to  something  much  like  Knoblauch's  curve  in  the  end. 

The  second  conclusion  that  can  be  drawn  from  Figure  12  is  that 
the  true  saturation  curve,  although  close  to  Knoblauch's  curve,  prob- 
ably runs  somewhat  higher  in  the  range  covered  by  these  computations. 


Figure  13.  Values  of  Cp  computed  by  Planck's  method  from  Linde's 
characteristic  equation.  The  circles  come  from  an  H  formula  based  wholly 
on  Knoblauch's  Cp  measurements,  the  crosses  from  a  similar  H  formula 
based  wholly  on  'Thomas'  Cp  measurements.  Both  confirm  Knoblauch's 
saturation  curve  {K)  rather  than  Thomas'  (T). 

It  will  be  remembered  that  the  same  conclusion  was  reached  in  two 
different  wajrs  in  the  last  subsection  (pages  290  and  293),  and  that  it 
is  further  confirmed  by  the  fsfit  that  Regnault's  values  near  saturation 
at  atmospheric  pressure  are  higher  than  Knoblauch's. 

The  volume  measurements  of  Ramsay  and  Toung  and  of  Battelli  are 
not  so  conveniently  arranged  for  the  purposes  of  this  particular  compu- 
tation. In  both  cases  the  temperature  was  held  constant  while  the 
pressure  and  volume  were  varied.  In  the  case  of  Ramsay  and  Toung 
it  is  possible  to  rearrange  the  data  so  as  to  give  i^pnmmate  isochors 


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DAVIS.  —  CEBTAIN  THERMAL  PROPEBTIES  OP  STEAM. 


301 


which  can  then  be  reduced  to  suitable  absolutely  constant  yolumes  by 
interpolation.  The  curves  thus  obtained  are,  however,  irregular,  and 
furthermore  they  show  unmistakable  evidences  of  a  phenomenon  ex- 
actly analogous  to  the  wet  steam  error  into  which  Thomas  is  believed 
to  have  fiaJlen.  The  presence  of  this  error,  which  took  the  form  of 
surfishce  condensation  in  the  experimental  bulb  as  saturation  was 
approached,  is  specifically  mentioned  by  the  authors,  but  no  attempt 
was  made  to  eliminate  it  on  the  ground  that,  "however  interesting 


FiGUHE  14.  Values  of  Cp  computed  by  Planck's  method  from  the  volume 
measurements  of  Ramsay  and  Young  (circles)  and  of  Battelli  (dots). 

from  a  theoretical  point  of  view  the  absolute  expansion  of  water-gas 
may  be,  in  practise  it  is  always  in  contact  with  a  surface;  and  an 
indication  of  the  behavior  of  steam  in  contact  with  glass  cannot  &il  to 
be  of  use  in  considering  the  practical  case  of  steam  in  contact  with 
iron."  It  is  therefore  interesting  to  find  that  the  values  of  Cp  which 
have  been  computed  from  the  data  of  Ramsay  and  Toung  and  which 
are  plotted  as  circles  in  Figure  14,  run  dose  to  Thomas'  saturation 
curve.  This  agreement  is  an  indication  that  both  are  subject  to  the 
same  error. 

Battelli  was  also  troubled  by  surfiu^e  condensation,  but  was  at  great 
pains,  in  discussing  his  results,  to  eliminate  its  effects.  It  has  there- 
fore seemed  best  to  work  not  from  his  data,  but  firom  a  table  near  the 


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302  PROCEEDINGS   OP   THE   AMERICAN   ACADEBffT. 

end  of  his  memoir  ("  Table  M  ")»  ^  which  are  given  certain  graphically 
detennined  values  of  the  coefficients  in  the  fonnula 

p=zb  t  +  a, 
which  he,  like  Knoblauch,  Linde,  and  Elebe,  uses  to  represent  his 
isochoTs.  The  coefficient  b  in  this  formula  is  the  same  as  the  {dp/dt)^ 
in  the  main  table  of  Knoblauch's  paper,  and  can  be  used  in  the  same 
way.  The  values  of  C^  computed  from  Battelli's  table  M  with  con- 
densation effects  eliminated,  run  even  lower  than  Knoblauch's  satura- 
tion curve  throughout  the  range  of  Figure  14.  This  indicates  that 
Battelli  rather  more  than  eliminated  the  condensation  errors  in  his 
discussion  of  his  data. 

The  contrast  between  the  values  obtained  from  Ramsay  and  Young's 
work,  where  the  wet  steam  error  is  known  to  exist,  and  those  obtained 
from  Battelli's  work,  where  it  is  known  to  have  been  consciously 
eliminated,  is  so  much  like  the  contrast  between  Thomas'  saturation 
curve  and  Knoblauch's  as  to  be  a  striking  verification  of  the  conclusion 
reached  on  page  272. 

It  is  not  probable  that  either  of  the  three  sets  of  volume  measure- 
ments are  reliable  enough  to  make  the  results  computed  in  this  section 
worthy  of  much  consideration  as  new  determinations  of  C^  Their 
value  is  chiefly  as  corroborative  evidence  on  one  side  or  the  other  of 
the  various  doubtful  points  that  have  been  mentioned. 

Be.    Other  indirect  computations,  — )  -•  -  ,,  , .  , 

C.     Reswmes  and  discussions.-        [None    of  the   papers  which 

might  be  listed  under  Be  or  C  are  such  as  to  be  improvable  by  the  use 
of  the  new  material  in  this  and  in  the  preceding  paper,  or  to  be  of  im- 
portance in  the  present  connection.  They  will  not  be  discussed  in 
detail. 

Summary  of  this  Cp  discussion :  — 

1.  Knoblauch's  curves  in  general,  and  his  saturation  curve  in 
particular,  are  much  nearer  the  truth  than  Thomas'.  The  evidence  for 
this  is  to  be  found  on  pages  287  and  298  to  302. 

2.  Knoblauch's  saturation  curve  runs  somewhat  too  low  at  low 
temperatures  (see  pages  290,  293  and  300). 

3.  The  low  temperature  end  of  Knoblauch's  1  kg.  curve  should  be 
somewhat  raised,  not  only  because  of  conclusion  2  above,  but  also  so 
as  to  agree  better  with  Regnault's  recomputed  results  (see  page  286). 

4.  Knoblauch's  1  kg.  curve  should  be  relocated  at  high  superheats 
so  as  to  agree  with  that  of  Holbom  and  Henning. 

5.  The  spacing  at  high  superheats  of  the  curves  corresponding  to 
pressures  higher  than  1  kg.  is  best  determined  by  a  new  method 
involving  the  Joule-Thomson  coefficient  (see  pages  290  to  294). 


^^^  ^  Digitized  by  LjOOQIC 


DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OF  STEAM.  303 

6.  The  reconcfliation,  tiirough  Clausius'  thermodynamic  relation,  of 
the  accepted  volume  and  specific  heat  measurements  in  the  superheated 
region  is  impossible.  This  is  probably  the  most  important  of  the  out- 
standing problems  in  this  field. 

All  these  conclusions  have  been  embodied  in  the  C>  diagram  which  is 
the  basis  of  the  Steam  Tables  already  mentioned,^  and  it  is  partly  for 
the  purpose  of  gathering  in  one  place  all  of  the  underlying  evidence 
that  justifies  those  tables,  much  of  it  unsuitable  for  presentation  there, 
that  this  section  of  the  present  paper  has  been  written.  The  Cp  curves 
which  were  used  were  as  faithful  a  translation  and  extrapolation  of 
Knoblauch's  curves  as  possible,  except  for  the  differences  stated  abova 
In  particular  they  reproduced  the  tremendous  rise  of  his  saturation 
curve  at  even  moderately  high  pressures  and  temperatures.  It  is 
probable  that  this  feature  of  Knoblauch's  curves,  although  near  enough 
to  the  truth  to  satisfy  the  present  needs  of  engineering  practise,  will 
have  to  be  revised  later.  It  is,  however,  the  only  rational  guess  yet 
published,  and  it  is  not  worth  while  to  cumber  the  literature  with  any 
more  "  harmonized  "  sets  of  C>  values  at  high  pressures  until  there  is 
something  definite  to  build  on.  The  problem  of  determining  the  true 
course  of  the  high  pressure  end  of  the  saturation  curve  on  the  Cp  dia- 
gram is  second  in  importance  only  to  that  mentioned  at  the  end  of 
the  summary  just  above. 

5.    Clausius'  "Specific  Heat  of  Saturated  Steam." 

This  section  will  be  devoted  to  a  revision  of  a  computation  first 
made  by  Clausius,  which,  although  no  longer  of  especial  importance, 
is  usually  of  considerable  interest  to  students  of  thermodynamics.  In 
the  sixth  chapter  of  the  first  volume  of  his  "  Mechanical  Theory  of 
Heat "  he  defines  the  specific  heat  of  saturated  steam  as  the  quantity 
of  heat  that  must  be  added  to  saturated  steam  at  any  temperature  U) 
turn  it  into  saturated  steam  one  degree  hotter,  account  being  taken  of 
the  fact  that  it  will  have  to  be  compressed  to  keep  it  saturated.  For 
steam  and  for  most  other  substances  it  is  negative  at  ordinary  tempera- 
tures, because  the  work  of  compression  is  more  than  enough  to  provide 
the  corresponding  increase  in  the  internal  energy.  But  in  the  case  of 
most  substances  including  steam  it  is  at  ordinary  temperatures  an 
increasing  function  of  the  temperature  and  may,  therefore,  pass 
through  zero  and  become  positive  if  the  temperature  is  sufficiently 
raised.  This  Clausius  found  to  be  actually  the  case  for  ether  at 
ordinary  temperatures  and  for  chloroform  above  130°,  and  the  ex- 

*•  See  page  97  of  the  Tables. 


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304 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


periments  of  Cazin  and  of  Him  confinned  this  result  For  snch 
sabstanoes,  the  top  of  the  temperature-entropy  diagram  must  have 
the  curious  shape  shown  in  Figures  15a  and  15& 


J 

/ 

/ 

/ 

f 

% 
% 

IM 

/ 

/ 

,1 

A 

^ 

X 

J 

«■  J 

Figure  15  a.    Temperature-en- 
tropy diagram  for  ether. 


Figure  156.  Temperature- 
entropy  diagram  for  chloroform. 


The  extrapolation  formula  for  L  in  sub-seotion  3C  enables  one  to 
compute  this  specific  heat  of  saturated  steam  from  Glausius'  equation. 

with  the  following  results. 

TABLE  VII. 
The  Specific  Heat  op  Saturated  Steam. 


Temp. 

C^. 

Same  ace.  to 
ClausiuB. 

0** 

-1.69 

-1.916 

60<» 

-1.33 

-1.465 

100*» 

-1.08 

-1.133 

150« 

-0.90 

-0.879 

200« 

-0.80 

-0.676 

260<» 

-0.82 

300*» 

-1.13 

DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OF  STEAM.  305 

The  neoessary  values  of  the  specific  heat  of  water,  c,  are  taken  from 
Marks  and  Davis'  Steam  Tables.  Above  100"^  they  are  based  on  the 
experiments  of  Dieterici  which  ran  to  303"^.  The  Table  shows  that 
C^t.  passes  its  maximum  below  250°  without  becoming  zero  or  positive, 
and  that  at  300"^  it  is  already  well  on  its  way  toward  the  value  minus 
infinity  which  it  has  at  the  critical  point  The  temperature-entropy 
diagram  for  steam  (see  Figure  la)  is,  therefore,  fundamentally  difier- 
ent  in  shape  firom  that  of  ether  or  chloroform. 

6.    The  Critioal  Volume  op  Water. 

The  extrapolation  fommla  for  L  also  makes  possible  a  computation 
of  the  critical  volume  of  water  by  the  method  of  Cailletet  and  Mathias. 
These  investigators  announced  in  1886^  their  well-known  "law  of 
the  straight  diameter,"  according  to  which,  if  the  densities  of  a  liquid 
and  its  saturated  vapor  are  plotted  against  the  corresponding  tem- 
peratures to  form  a  steam  dome,  the  mid-points  of  the  horizontal 
chords  of  the  dome  lie  in  a  straight  line.  This  law  has  been  tested  by 
a  number  of  observers,*^  but  particularly  by  Young,  who  proved  that 
the  diameter  is  accurately  straight  only  in  the  case  of  a  few  "normal " 
substances  of  which  normal  pentane  is  the  best  known  example,  but 
that  it  is  always  nearly  straight  and  can  almost  always  be  represented 
within  the  limit  of  error  of  the  observations  by  a  second  degree 
equation  in  t.  In  certain  cases,  notably  acetic  acid  and  the  alcohols, 
a  third  degree  equation  is  necessaiy.  All  departures  of  the  diameter 
firom  perfect  straightness  are  oommonl^  attributed  to  association  in 
the  liquid. 

If  the  equation  of  the  diameter  is  known,  the  substitution  in  it  of  the 
critical  temperature  gives  the  critical  density  with  an  accuracy  far 
surpassing  that  of  any  known  method  of  direct  measurement.  This 
accuracy  is  greatly  increased  by  the  fact  that  the  diameter  is  always 
so  nearly  parallel  to  the  t  axis  that  even  a  considerable  error  in  the 
critical  temperature  makes  very  little  difference  in  the  critical  volume. 

In  applying  this  method  to  the  determination  of  the  critical  density 
of  water,  one  finds  available  in  the  third  (1905)  edition  of  Landolt 
and  Bernstein's  "  Physikalische  Tabellen  "  a  satisfiwjtory  set  of  values 

»•  C.  R.,  1886,  102,  1202. 

w  Mathias,  Ann.  de  la  Fac.  des  Sci.  Toulouse,  1892,  6,  Ml;  C.  R.,  1892, 
116, 35;  M6m.  Soc.  Roy.  des  Sci.,  Liege,  1899, 2;  Joum.  de  Phys.,  1899, 8, 407; 
and  1905, 4,  77 ;  Young,  Joum.  Chem.  Soc.,  trans.,  1893, 63, 1237 ;  Phil.  Mag., 
1892,  34,  503;  and  1900,  60,  291 ;  Guye,  Archives  des  Sci.  Phys.  et  Nat.,  1894, 
31,  43;  Tsuruta,  Phys.  Rev.,  1900, 10, 116.  See  also  Young's  "Stoichiome- 
try,"  1908,  165. 

VOL.   XLV.— 20 


Digitized  by  LjOOQIC 


306 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


of  the  density  of  water  up  to  320°C.  Furthennore,  the  pressure  of 
saturated  steam  has  heen  observed  up  to  the  critical  point  itself  by 
a  number  of  observers,  of  whom  Cailletet  and  Colardeau  *2  seem  the 
most  trustworthy.  From  their  values  and  the  extrapolation  formula 
for  Zr,  one  can  compute  the  change  of  volume  during  vaporization  up 


400 


"1 — r 


800 


200 


lOOj 


T 


.00--0 — o-^ 


N- 


/ 
o 
o 
-o 
o 
o 
o 
o 
o 
o 
o 


o 
o 


o 
o 
o 


o 

o 


o 
o 
o 

o 

o 

o 

o 

o 

o 

o 

o 

o 

o 

OH 

o 

o 

o 

o 

o 

c 

c 


LO 


Figure  16.  The  steam  dome  on  the  temperature-density  plane,  with 
the  ''straight  diameter"  of  Cailletet  and  Mathias,  and  the  critical  point 
according  to  Nadejdine  (N),  Battelli  (B),  Dieterici  (D),  and  the  present  writer. 

to  320°  and  indeed  up  to  the  critical  point  itself.  The  sum  of  these 
values  and  the  volumes  of  the  liquid  mentioned  above  are  the  volumes 
of  saturated  steam  up  to  320°.  The  results  are  tabulated  below  and 
are  plotted  in  Figure  16.  The  diameter  is  seen  to  be,  as  usual,  nearly 
but  not  quite  straight  It  is  not  possible  to  represent  the  whole  of  it 
even  by  a  third  degree  formula  in  t,  because  of  the  peculiar  behaviour 
of  the  density  of  water  at  low  temperatures.    The  20  points  above 

w  Journ.  de  Phys.,  1891,  10,  333;  also  Ann.  Chem.  et  Phys.,  1892,  25, 
619;  also  Physik.  Rev.,  1892,  1,  14;  also  a  short  note  in  C.  R.,  1891,  112, 
563;  see  also  Risteen,  The  Locomotive,  1907,  26,  219. 


Digitized  by  ^ 


DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OF  STEAM. 


307 


TABLE  VIII. 
The  Law  of  the  Straight  Diameter  for  Steam. 


Temp. 

Density  of 

Density  of 

Mean 

ITrti  ii'tiilii 

Diflf. 

C. 

Water. 

Steam. 

Density. 

f  onuuia* 

O*' 

0.9999 

0.000005 

0.5000 

10« 

0.9997 

0.4999 

... 

... 

20*> 

0.9982 

0.4991 

•  •  • 

30*^ 

0.9957 

0.4978 

•  • « 

40<> 

0.9922 

0.06605 

0.4961 

... 

... 

60° 

0.9881 

0.00008 

0.4941 

... 

60° 

0.9832 

0.00013 

0.4917 

.  .  . 

... 

70° 

0.9778 

0.0002 

0.4890 

, , , 

80° 

0.9718 

0.0003 

0.4860 

•  •  • 

... 

90° 

0.9653 

0.0004 

0.4828 

... 

... 

100° 

0.9584 

0.0006 

0.4796 

... 

110° 

0.9510 

0.0008 

0.4759 

. . . 

120° 

0.9434 

0.0011 

0.4722 

.  .  . 

130° 

0.9352 

0.0015 

0.4684 

0.4688 

+  6.6604 

140° 

0.9264 

0.0020 

0.4642 

0.4644  ^ 

+0.0002 

150° 

0.9173 

0.0026 

.  0.4699 

0.4599 

0.0000 

160° 

0.9075 

0.0033 

0.4554 

0.4552 

-0.0002 

170° 

0.8973 

0.0041 

0J507 

0.4504 

-0.0003 

180° 

0.8866 

0.0052 

0.4459 

0.4454 

-0.0005 

190° 

0.8750 

0.0064 

0.4407 

0.4403 

-0.0004 

200° 

0.8628 

0.0079 

0.4354 

0.4351 

-0.0003 

210° 

0.850 

0.010 

0.430 

0.431 

+0.001 

220° 

0.837 

0.012 

0.424 

0.424 

0.000 

230° 

0.823 

0.014 

0.419 

0.419 

0.000 

240° 

0.809 

0.017 

0.413 

0.413 

0.000 

250° 

0.794 

0.020 

0.407 

0.407 

0.000 

260° 

0.779 

0.024 

0.402 

0.401 

-0.001 

270° 

0.765 

0.029 

0.397 

0.395 

-0.002 

280° 

0.75 

0.03(4) 

0.39(2) 
0.38(0) 

0.388 

-0.00(4) 

290° 

0.72 

0.03(9) 

0.382 

+0.00(2) 

300° 

0.70 

0.04(6) 

0.37(3) 

0.375 

+0.00(2) 

310° 

0.68 

0.05(5) 

0.36(8) 

0.368 

0.00(0) 

320° 

0.66 

0^06(5) 

0.36(2) 

0.362 

0.00(0) 

120°  can,  however,  be  represented  with  an  average  deviation  of  about 
one  ninth  of  one  per  cent  by  the  formula 

s  =  0.4552-0.0004757  (^-160)-0.0000(X)685  (^-160)  ^  gr,/cm.* 
It  should  be  noticed,  in  judging  of  the  reliability  of  the  formula,  that 
comparatively  large  relative  errors  in  the  density  of  steam  make  only 


Digitized  by  LjOOQIC 


308  PBOCEEDINOS  OF  THE  AMEBICAN  ACADEMY. 

very  small  relative  errors  in  the  mean  of  the  densities.  Thus  in  the 
most  unfevorable  case,  at  320°,  if  an  error  in  either  dpjdt  or  in  the 
extrapolated  yalae  of  L  made  the  computed  change  of  volume  wrong 
by  five  per  cent^  the  resulting  error  in  the  mean  of  the  densities  would 
be  less  than  half  of  one  per  cent 

The  substitution  of  Cailletet  and  Colardeau's  value  for  the  critical 
temperature  of  water,  tc  =  365°G.,  in  the  equation  of  the  diameter  gives 

B^  =  i/vc  =  0.329  gr./cm.*, 

from  which  it  follows  that  the  critical  volume  is 

Vc  =  3.04  cm.Vgr. 

There  are  three  previous  determinations  with  which  this  can  be  com- 
pared, two  of  which  are  direct  measurements.    These  are 

Vc  =  2.33  cmVgr.  (Nad.), 
found  by  Nadfejdine^  in  1885,  and 

Vc  =  4.812  om.Vgr.  (Batt), 

found  by  Battelli  ^  in  1890.  In  both  cases  a  known  weight  of  water 
was  enclosed  in  a  steel  tube  and  heated  at  constant  volume  until  the 
contents  became  homogeneous.  If  there  was  too  little  liquid,  this  oc- 
curred when  it  was  all  evaporated ;  if  too  much,  when  it  had  so  ex- 
panded as  to  fill  the  tube ;  if  just  enough,  at  the  critical  point.  The 
last  case  they  hoped  to  recognize  because  of  its  corresponding  to  a 
higher  temperature  than  either  of  the  others.  Such  a  method  gives  an 
excellent  determination  of  the  critical  temperature,  but  it  can  hardly 
be  expected  to  give  an  accurate  determination  of  the  critical  volume. 
It  amounts  to  tr3ring  to  find  the  highest  point  of  the  steam  dome  by 
selecting  experimentally  its  longest  ordinate  on  the  v  t  plane.  The  ex- 
tremely flat  top  of  the  steam  dome  makes  this  almost  impossible,  and 
it  is  interesting  to  notice  that  both  Nadejdine  and  Battelli  fell  within 
the  nearly  flat  region,  one  at  one  end  and  one  at  the  other.  The  present 
determination  lies  between  theirs  and  should  be  much  more  accurate 
than  either. 

•»  Univerdtatftkija  Investia  Kiew.,  1885,  6,  32;  Mel.  Phys.  et  Chim.  tir^s 
du  Bull,  de  TAc.  de  St.  P^tersb.,  1885, 12,  299;  Chem.  CBL,  1885,  17,  401. 
M  Mem.  deU.  Ac.  di  Torino,  1891,  41,  76;  Physikal.  Rev.,  1892,  2,  1. 


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DAVIS.  —  CERTAIN  THERMAL  PROPERTIES  OP  STEAM.  309 

The  third  published  valae  of  the  critical  volume^ 
Vc  =  4.025  cm.Vgr.  (Diet), 

was  computed  by  Dieterici*"^  in  1904,  from  the  empirical  law  of 
Young ^  that^  for  "normal "  substances,  the  ratio  of  the  actual  to  the 
gas-law  density  at  the  critical  pressure  and  density  is  3.8.  Dieterici's 
belief  that  water  becomes  a  "  normal "  substance  at  high  temperatures, 
even  though  it  is  known  to  be  very  abnormal  at  ordinary  temperatures, 
is  based  on  the  &ct  that  the  ratio  of  the  change  of  internal  energy  dur- 


FiouBB  17.  The  pol3rmerization  factor  for  liquid  water  as  a  function  of 
the  temperature.  The  small  circles  below  150®  are  Ramsay's  earlier  values; 
the  large  circles  below  150^  are  his  revised  values;  the  circle  at  365^  is  the 
value  indicated  by  the  critical  volume.        , 

ing  evaporation  to  the  whole  heat  of  evaporation,  L,  seemed  to  ap- 
proach a  value  which  he  had  predicted  for  "  normal "  substances.  The 
present  determination  of  Vc  shows  that  water  is,  as  one  would  have  ex- 
pected, still  abnormal  at  the  critical  point.  K  interpreted  in  the  usual 
way,  it  would  indicate  a  polymerization  factor  of  1.3.  Figure  17  shows 
how  well  this  number  fits  a  smooth  curve  through  Bamsay's  earlier 
large  values  of  the  polymerization  £BK)tor  at  ordinary  temperatures  ;^7 

••  Wied.  Ann.,  1904, 16,  864. 

••  Phil.  Mag.,  1892,  34,  507,  and  Jour.  Chem.  Soc.,  Papers,  1893,  63,  1251. 

w  Phil.  Trans.,  1893, 184A,  647;  translated  in  Zeitsch.  Phys.  Chem.,  1893, 
12,  433;  second  paper  in  Jour.  Chem.  Soc.,  1893,  63,  1089;  translated  in 
Zeitsch.  Phys.  Chem.,  1893, 12,  458. 


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310  PKOCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

there  seems,  however,  to  be  little  chance  of  reconciling  it  with  his  later 
"corrected"  values.^  This  is  an  example  of  the  uncertainty  that 
seems  to  characterize  the  whole  subject  of  polymerization  in  liquids, 
especially  on  its  quantitative  side. 

The  equation  of  the  mean  diameter  which  has  just  been  obtained 
can  also  be  used  for  the  computation  of  a  rough  but  useful  extension  of 
certain  columns  of  the  ordinary  steam  tables  up  to  the  critical  point 
As  was  mentioned  on  page  306,  the  extrapolation  formula  for  L  of  Sec- 
tion 3  determines  the  change  of  volume  during  evaporation  at  all  tem- 
peratures between  320^  and  th^  critical  temperature.  From  these  and 
the  mean  densities  given  by  the  equation  of  the  diameter,  it' is  easy  to 
compute  each  of  the  densities  separately,  and  to  fill  in  the  rest  of  the 
steam  dome  on  the  t  s  (temperature-density)  planes.  The  results  are 
shown  by  the  dotted  lines  in  Figure  16,  and  are  given  in  detail  at  the 
end  of  Table  I  in  the  Steam  Tables  already  mentioned.  Any  values 
obtained  in  this  way  are,  of  course,  only  rough  approidmations  to  the 
truth  and  should  not  be  too  much  relied  on. 

Summary  of  the  Results  in  this  Paper. 

1.  It  presents  a  new  set  of  values  for  the  difference  between  the 
total  heat  of  saturated  steam  at  certain  temperatures  between  65^  and 
190°C.  and  its  value  at  100°. 

2.  It  shows  that  these  differences  can  be  represented  within  their 
limit  of  error  by  the  first  three  terms  of  a  Taylor's  series,  but  that  such 
a  development  should  not  be  extrapolated  far  in  either  direction.  The 
best  direct  measurements  of  H  indicate  that  its  value  at  100°  is  639.11 
mean  calories.     If  this  be  accepted,  the  proposed  formula  for  H  is 

H  =  639.11  -h  0.3745  (t  -  100)  -  0.000990  (t  —  100)*  mean  calories. 

The  last  two  terms  of  the  formula  are  the  real  contribution  of  this 
paper,  and  may  still  be  valid,  even  if  the  first  term  is  later  found  to  be 
wrong. 

3.  Thiesen's  formula  for  L  with  recomputed  constants  is  shown  to 
represent  satis£a<;torily  all  of  the  reliable  values  of  Z,  including  those 
in  this  paper.  It  is  believed  to  be  the  safest  known  means  of  extrapo- 
lating to  high  temperatures. 

4.  The  literature  on  the  specific  heat  of  superheated  steam  is  sys- 
tematically discussed  and  revised  in  the  light  of  the  new  values  of  ff 

••  Third  paper;  Proe.  Roy.  See.,  1894,  56,  171;  translated  in  Zeitsch. 
Riys.  Chem.,  1894, 16,  106. 


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DAVIS.  —  CEKTAIN  THERMAL  PROPEBTIES  OF  STEAM.  311 

and  of  the  Joule-Thomson  coefficient  presented  in  an  earlier  paper.  In 
particular  the  choice  of  Knoblauch's  values  of  C>  as  the  foundation  of 
the  determination  of  H  in  this  paper  is  justified. 

5.  It  is  shown  that  Glausius'  specific  heat  of  saturated  steam 
passes  its  maximum  without  becoming  zero  or  positive,  so  that  the 
temperature-entropy  diagram  for  steam  must  be  essentially  simpler 
than  that  for  either  ether  or  chloroform. 

6.  The  extrapolation  formula  for  L  mentioned  in  3  above  is  made 
the  basis  of  a  determination  of  the  critical  density  of  water  by  the 
method  of  Cailletet  and  Mathias.    The  result  is 

Vc  =  3.04  cmVgr. 

The  specific  volumes  of  water  and  of  saturated  steam  at  other  high 
temperatures  have  also  been  computed  and  embodied  in  a  steam  table 
running  up  to  the  critical  temperatura 

Jeffebson  Physical  Labobatobt, 
Cambridge,  Mass., 

December,  1909. 


pi 


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G^im^ 


Frooeedings  of  fhe  Amerioan  Aoademy  of  Arts  and  Soienoei. 
Vol.  XLV.  No.  10.  — March,  1910. 


CONTRIBUTIONS  FROM  THE  JEFFERSON   PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 


THE  SPECTRUM  OF  A  CARBON  COMPOUND  IN  THE 
REGION  OF  EXTREMELY  SHORT  WAVE-LENGTHS. 


Bt  Theodore  Ltman. 


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f 


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CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 

THE  SPECTRUM  OF  A  CARBON   COMPOUND  IN  THE 
REGION  OF  EXTREMELY  SHORT  WAVE-LENGTHS. 

Bt  Theodorb  Ltman. 
Presented  December  8,  1909.    Received  Januaiy  3, 1910. 

In  the  region  of  extremely  short  wave-loDgths  discovered  by 
Schamann  the  spectra  of  two  gases  only  are  easily  ol)taiQed ;  the  one 
is  due  to  hydrogen,  the  other  to  some  compound  of  carbon.^  The 
hydrogen  spectrum  consists  of  a  great  number  of  fine  lines  extending 
firom  X  1675  to  X  1030 ;  the  wave-lengths  of  the  most  prominent  of 
these  lines  have  been  determined.^  The  carbon  spectrum  consists 
of  a  considerable  number  of  bands  extending  from  the  less  refrangible 
end  of  the  Schumann  region  to  the  neighborhood  of  X  1300.  The 
purpose  of  the  present  investigation  was  to  measure  the  position  of 
these  bands. 

The  results  are  chiefly  valuable  because  the  bands  in  question  fill 
the  gap  between  X  1854  and  X  1675  and  form  convenient  standards  of 
wave-length  in  a  region  which  up  to  this  time  has  lacked  points  of 
reference. 

The  appearance  of  the  spectrum  is  shown  in  Plate  VIII,  Volume  13, 
of  the  Memoirs  of  this  Academy.  It  is  marked  "  Air."  The  bands 
are  most  intense  in  the  less  refrangible  region,  but  they  are  all  of  the 
same  general  type  with  heads  directed  toward  the  region  of  shorter 
wave-length.  The  strongest  bands  are  evidently  double.  The  system, 
at  least  throughout  its  less  refrangible  part,  forms  a  continuation  of 
the  "  Fourth  group  "  as  described  by  Deslandres  in  his  paper,  "  Spectre 
de  bandes  ultra-violet  des  composes  hydrog^n^s  et  oxyg^n^  du  car- 
bone."^  The  spectrum  under  mvestigation  is  thus  related  to  the 
series  of  bright  bands  in  the  visible  and  ultra-violet  attributed  to  car- 
bon monoxide  and  oflen  observed  in  ill-prepared  vacuum  tubes. 

*  Smithsonian  Contributions,  1903,  29,  No.  1413. 

■  Lyman,  Memoirs  of  this  Academy,  1906,  13,  125. 

•  Comptes  Rendus,  1888,  106,  842. 


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316  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

It  is  only  too  easy  to  obtain  the  bauds  in  the  region  of  short  wave- 
lengths, for,  to  quote  Schumann  himself,*  they  are  "  the  unwelcome 
attendants  of  all  my  spectra.''  In  order  to  determine  the  cause  of  the 
phenomenon,  however,  experiments  were  made  with  both  carbon  mon- 
oxide and  carbon  dioxide  and  with  a  variety  of  conditions  in  the  dis- 
charge tube.  The  results  of  these  experiments  may  be  stated  as  fol- 
lows :  Exactly  the  same  bands  are  obtained  when  carbon  monoxide  is 
used  as  when  carbon  dioxide  is  employed,  but  in  the  former  case  the 
strength  of  the  whole  spectrum  is  considerably  greater  than  in  the 
latter.  With  increased  current  strength  from  a  transformer,  between 
five  and  twenty  milliamperes  the  intensity  of  the  bands  increases  in 
a  uniform  manner  throughout  the  extent  of  the  spectrum.  When  a 
spark  gap  is  placed  in  series  with  the  tube  and  a  condenser  is  intro- 
duced in  such  a  way  as  to  produce  a  disruptive  discharge,  the  spectrum 
at  first  weakens  and  then  vanishes  altogether.  The  effect  is  accom- 
panied by  a  very  marked  decrease  in  pressure  in  the  tube  and  by  the 
formation  of  a  dark  deposit  on  the  walls  of  the  capillary.  When 
precautions  are  taken  to  exclude  the  introduction  of  carbon  monoxide 
or  prevent  its  formation,  the  spectrum  is  greatly  weakened  if  it  does 
not  vanish  altogether. 

These  data  go  to  confirm  the  results  of  Schumann,  as  they  show  that 
the  spectrum  is  due  to  carbon  monoxide.  The  occurrence  of  the  bands 
when  carbon  dioxide  is  present  may  be  explained  by  the  fact  that  this 
gas  is  known  to  be  transformed  into  carbon  monoxide  under  the  influ- 
ence of  light  and  the  electric  discharge.^  The  disappearance  of  the 
spectrum  with  the  disruptive  discharge  is  due  to  the  destruction  of 
the  carbon  monoxide.  The  oxygen  set  free  by  the  reaction  seems  to 
combine  with  the  electrodes,  while  the  carbon  is  deposited  This 
property  of  a  condenser  discharge  is  useful,  since  it  permits  the  spec- 
troscopist  to  firee  his  apparatus  of  an  annoying  impurity.  The  decrease 
in  pressure  which  accompanies  this  reaction  is  often  a  striking  and 
important  phenomenon. 

In  making  measurements  in  the  region  between  X  1880  and  X  2080 
a  concave  grating  of  six  foot  radius  with  15028  lines  to  the  inch  was 
employed.  Schumann  plates  were  used  throughout  the  work.  For 
the  experiments  in  the  region  on  the  more  refrangible  side  of  X  1880 
the  writer's  vacuum  spectroscope  was  employed  ®  in  the  same  manner  as 
when  the  hydrogen  spectrum  was  under  investigation.  An  improve- 
ment in  the  discharge  tube,  however,  has  been  introduced.    The  nature 

*  Loc.  cit.,  p.  16. 

»  Herchefinkel.  Ck)inpte8  Rendus,  1909,  149,  395. 

•  See  note  2, 


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LYMAN. — THE   SPECTRUM    OF   A    CARBON    COMPOUND.  317 

of  the  change  will  be  understood  by  consulting  the  illustration  on  page 
90  of  volume  27  of  The  Astrophysical  Journal.  The  brass  collar  A  is 
no  longer  provided  with  a  screw  thread  as  shown  in  the  illustration, 
but  it  is  now  made  to  fit  into  the  cup  B  air  tight  by  means  of  a  cone 
joint  2.8  cm.  long.  The  discharge  tube  itself  is  no  longer  cast  into  the 
collar  A  with  Khotinski  cement,  but  is  blown  on  a  platinum  tube 
3.5  cm.  long  by  1.5  cm.  in  diameter.  This  tube  is  soldered  into  the 
collar  A.  By  this  arrangement  the  gas  does  not  come  in  contact  with 
grease  in  the  joints,  and  the  danger  of  leak  is  considerably  reduced. 

Measurements  in  the  region  between  X  1850  and  X  1675  where  no 
fiducial  lines  exist  were  made  by  the  two  slit  method.^  In  the  region 
firom  X  1675  to  X  1300  direct  comparison  was  made  with  the  spectrum 
of  hydrogen. 

The  values  of  X  refer  to  the  heads  of  bands,  and  they  are  accurate  to 
0.3  of  an  Angstrom  unit  In  the  class  of  the  double  bands  marked 
"  d  "  the  wave-length  given  is  for  the  stronger  component.  The  inten- 
sities are  represented  on  a  scale  of  ten.  The  absorption  of  fluorite, 
which  begins  to  make  itself  felt  near  the  end  of  the  spectrum,  renders 
the  relative  intensities  of  the  most  refrangible  bands  rather  uncertain. 
As  usual,  the  wave-lengths  and  frequencies  are  in  vacuum. 

In  addition  to  their  value  as  standards  of  wave-length,  the  results 
are  of  some  theoretical  importanca  Deslandres  in  the  paper  just 
quoted  ®  htis  used  his  measurements  of  the  carbon  spectrum  to  test  his 
Laws.  As  the  spectrum  under  discussion  seems  to  form  a  continuation 
of  that  described  by  Deslandres,  it  is  interesting  to  see  if  its  bands  also 
show  the  numerical  relations  described  by  the  earlier  investigator. 
In  making  the  comparison,  however,  it  will  be  necessary  to  confine  the 
attention  to  those  relations  which  deal  with  the  heads  of  the  bands, 
for  the  dispersion  employed  does  not  permit  of  the  study  of  the  lines 
of  which  each  band  is  composed.  It  must  also  be  remembered  that 
the  region  of  high  firequencies  is  not  perfectly  adapted  to  such  a  test, 
since  a  small  error  in  the  wave-length  is  magnified  in  relations  which 
deal  with  firequencies. 

The  laws  under  discussion  are  two  in  number:  first,  that  a  group  of 
bands  may  be  broken  up  into  sets  of  series  such  that  the  diflferences  in 
firequency  of  the  heads  of  the  bands  in  any  one  series  form  an  arith- 
metical progression ;  second,  that  all  the  series  are  similarly  constructed. 
The  first  rule  may  obviously  be  stated  in  another  way,  — the  second 
differences  of  the  firequencies  of  the  heads  of  the  bands  in  any  one 
series  are  constant. 

^  See  note  2. 
•  Loc.  cit. 


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318 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


5 

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X 


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LYMAN.  —  THE   SPECTRUM    OF   A   CARBON   COMPOUND. 


319 


Deslandres  has  aDalysed  his  Fourth  Groap  into  five  series,  character- 
ized by  sn^^U  and  not  very  regular  second  differences.    The  writer  has 


TABLE  II.  . 
Fourth  Group. 


DXSLANDBKS. 


First  Differences. 


Series 


IV 


482 
480 
400 
512 
521 
523 
536 


472 
477 
505 
520 
530 
527 
546 
^57 


VI 


474 
501 
513 
533 
539 
549 


Ltman. 


First  Differences. 


VII    VIII 


534 
541 
547 
555 


556 
567 
576 


IX 


584 
589 
605 
607 
614 
631 


633 
652 


XI 


666 
673 


been  able  to  follow  the  arrangement  into  the  region  between  X  2000  and 
X  1600  and  has  added  seven  new  series  of  the  same  type.    Table  I. 


jk 


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320 


PBOCEEDINGS  OF  THE  AMEBICAN  ACADEBfT. 


shows  these  new  members.  They  are  numbered  from  VI.  to  XL;  series 
IV.  and  V.  of  Deslandres'  are  included  in  the  table  for  the  sake  of  com- 
parison. The  first  two  bands  in  the  fifth  series  were  measured  by  the 
writer.  When  it  is  remembered  that  the  errors  of  observation  make 
the  fifth  place  in  the  frequencies  very  doubtful,  it  will  be  seen  that  the 
law  of  constant  second  differences  is  fairly  well  obeyed. 

TABLE  III. 
Fifth  Group. 


Series 

1 

2 

3 

4 

5 

6 

Av.2d 

Diffs. 

N. 

2nd 
Diflfs. 

N. 

2nd 
Diffs. 

N. 

2nd 
Diffs. 

N. 

2nd 
Diffs. 

N. 

2nd 
Diffa. 

N. 

2nd 
Diffs. 

65772 
65531 
65181 
64721 
64131 
63432 
62602 

109 
110 
130 
109 
131 

118 

66366 
65976 
65462 
64842 

124 
106 

67527 
67204 
66765 
66194 

116 
132 

69266 
68852 
68320 
67659 

118 
129 

70852 
70721 
70472 
70121 
69657 
69109 

118 
102 
113 

84 

71649 
71372 
70972 
70472 

123 
100 

•    • 

•    • 

115 

•    • 

124 

123 

104 

112 

Table  II.,  which  gives  the  first  differences  for  each  series,  is  arranged 
to  show  the  similarity  which  exists  among  the  members.  It  will  be 
observed  that  the  second  rule  is  obeyed,  for  the  series  resemble  each 
other.  An  exact  similarity  is  not  demanded  by  the  rule  as  has  been 
recently  pointed  out  by  Deslandres  himself.^  The  arrangement  of  the 
series,  however,  does  not  permit  of  the  "second  progression  "  ^^  men- 
tioned by  Olmsted  and  others. 

In  addition  to  the  series  VI.  to  XL  there  appear  to  exist  two  others, 
in  the  region  near  X  1800.  These  show  larger  second  differences  than 
the  first  type.    They  have  not  been  included  in  the  tables. 

»  Comptes  Rendus,  1904,  138,  317. 

*•  Comptes  Rendus,  1902, 134,  748;  Zeits.  f.  Wiss.  Photographie,  1906;  4, 
255. 


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LYMAN.  —  THE   SPECTRUM   OF   A   CARBON   COMPOUND.  321 

TABLE  IV. 


A 

I. 

N. 

A. 

I. 

N. 

1335.0 

1 

74,906 

1615.1 

2 

61,916 

1339.0 

1 

74,683 

1623.4 

1 

61,599  . 

1343.0 

1 

74,460 

1629.6 

3 

61,365 

1353.6 

1 

73,877 

1630.3 

6 

61,338 

1356.1 

2 

73,741 

1648.2 

5 

60,672 

1361.3 

2 

73,459 

1653.3 

4 

60,485 

1368.0 

1 

73,099 

1666.7 

1 

59,999 

1371.8 

2 

72,897 

1669.9 

6 

59,884 

1374.1 

2 

72,775 

1685.3 

1 

59,337 

1378.1 

2 

72,564 

1688.5 

1 

59,224 

1384.4 

1 

72,233 

1698.8 

1 

58,865 

1386.4 

1 

72,129 

1705.3 

6 

58,641 

1392.2 

1 

71,829 

1712.2 

7 

58,404 

1395.7 

2 

71,649 

1723.9 

6 

58,008 

1401.1 

2 

71,372 

1729.5 

Sd 

57,820 

1404.0 

1 

71,225 

1743.5 

3 

57,356 

1405.5 

1 

71,149 

1747.3 

7 

57,231 

1409.0 

2 

70,972 

1774.9 

Sd 

56,341 

1411.4 

1 

70,852 

1785.1 

6 

56,019 

1414.0 

1 

70,721 

1792.6 

10  d 

55,785 

1419.0 

2 

70,472 

1801.9 

2 

65,497 

1426.1 

3 

70,121 

1804.9 

8 

65,405 

1435.6 

2 

69,657 

1811.0 

10  d 

55,218 

1438.7 

1 

69,507 

1825.7 

7 

64,774 

1443.7 

1 

69,266 

1830.1 

9 

54,642 

1447.0 

1 

69,109 

1837.2 

1 

54,431 

1452.4 

3 

68,852 

1841.3 

8 

64,309 

1463.7 

3 

68,320 

1846.7 

2 

64,151 

1473.0 

1 

67,889 

1849.4 

4 

54,072 

1475.4 

1 

67,778 

1859.6 

10  d 

63,775 

1478.0 

2 

67,659 

1870.3 

3 

53,467 

1480.9 

2 

67,527 

1878.5 

10  d 

63,234 

1488.0 

2 

67,204 

1891.2 

6 

52,876 

1493.8 

3 

66,943 

1898.0 

10 

52,687 

1497.8 

3 

66,765 

1914.0 

1 

52,247 

1506.8 

2 

66,366 

1918.2 

7 

52,132 

1510.7 

2 

66,194 

1931.5 

6 

51,773 

1515.7 

3 

65,976 

1933.6 

2 

51,717 

1520.4 

1 

65,772 

1950.4 

4 

51,272 

1526.0 

2 

65,531 

1951.7 

5 

51,237 

1527.6 

3 

65,462 

1953.0 

5 

51,203 

1534.2 

2 

65,181 

1970.1 

8 

50,759 

1542.2 

5 

64,842 

1991.0 

1 

60,226 

1545.1 

3 

64,721 

2007.2 

5 

49,821 

1559.3 

5 

64,131 

2012.6 

8 

49,687 

1576.5 

4 

63,432 

2026,4 

7 

49,349 

1596.1 

1 

62,653 

2031.7 

1 

49,220 

1597.4 

3 

62,602 

2035.1 

4 

49,138 

1603.3 

1 

62,371 

2047.0 

8 

48,852 

1611.7 

3 

62,046 

2068.4 

8 

48,347 

VOL.  XLV.  —  21 


Digitized  by  LjOOQIC 


322  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

On  the  more  refrangible  side  of  X  1600  matters  are  not  very  satis- 
&ctory.  The  bands  must  be  arranged  into  series  showing  very  large 
second  differences  which  are  Only  approximately  constant  These 
series,  which  are  numbered  from  1  to  7  go  to  make  up  the  Fifth  Group. 
Their  fr^uencies  together  with  the  second  differences  are  given  in 
Table  III.  No  attempt  has  been  made  to  adopt  an  arrangement  which 
would  show  the  similarity  between  the  members  of  the  group.  In  fact 
these  series  Ml  in  with  the  second  rule  only  to  a  limited  degree ;  1  and 
5  resemble  each  other,  as  do  2  and  6,  and  3  and  7,  but  the  relations 
are  not  exact 

The  writer  makes  no  claim  that  the  arrangements  given  in  this  Fifth 
Group  are  the  best  possible,  they  are  only  the  most  obvious. 

The  spectrum  contains  a  great  many  bands  which  are  either  too 
feeble  to  measure  or  whose  positions  are  made  uncertain  by  the  tails 
of  stronger  bands ;  if  these  could  be  included  in  the  series  a  better 
system  would  probably  result 

It  is  to  be  remembered  that  although  relations  similar  to  Deslandres' 
laws  have  been  proved  to  hold  vrithin  the  limit  of  error  of  observation 
for  the  distribution  of  lines  within  a  band,ii  qq  such  accuracy  of  agree- 
ment has  been  found  when  the  laws  of  the  distribution  of  the  heads  of 
the  bands  themselves  have  been  tested.  In  &ct,  the  rule  of  constant 
second  differences  as  applied  to  the  heads  of  bands  must  be  looked 
upon  as  a  first  approximation  only.  The  work  which  has  just  been 
described  indicates  that  the  approximation  holds  even  in  the  region  of 
extremely  short  wave-lengths. 

In  conclusion  the  writer  wishes  to  point  out  that  the  important  re- 
sults of  the  investigation  are  the  values  of  the  wave-lengths  contained 
in  Table  IV. 

Jefferson  Physical  Laboratory, 
Cambridge,  Mass., 
December,  1909.  * 


11  V.  Carlheim-GyllenskSld,  K.  Svensk.  Vetenskaps-Akad.,  Handl.,  1907, 
42,  No.  8. 


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GoogleJ 


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Prooeedings  of  the  Amerioan  Academy  of  Arte  and  Sdencei. 

Vol.  XLV.  No.  U.  — Mabch,  19X0. 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 


EXPERIMENTS  ON  THE  ELECTRICAL  OSCILLATIONS 
OF  A  HERTZ  RECTILINEAR  OSCILLATOR. 


Bt  George  W.  Pibrcb. 


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CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 

EXPERIMENTS  ON  THE  ELECTRICAL  OSCILLATIONS  OP 
A  HERTZ  RECTILINEAR  OSCILLATOR. 

By  Georgb  W.  Piercb. 
Presented  December  8,  1900.    Received  January  3, 1010. 

Whilb  engaged  in  oalibrating  a  wavemeter  for  electric  waves,  I  have 
made  a  series  of  measurements  of  the  wave-length  produced  by  a  long 
Hertz  rectilinear  oscillator,  consisting  of  two  oppositely  extending  hori- 
zontal wires  with  a  spark-gap  between.  By  yarpng  the  length  of  the 
oscillator,  wave-lengths  from  16  to  63  meters  were  obtained.  The  ex- 
periments were  conducted  in  a  long  room  in  the  third  story  of  the 
laboratory,  so  that  the  oscillator  was  at  a  height  of  10  meters  above 
the  sur&ce  of  the  earth,  and  represents  approximately  the  conditions 
that  exist  when  the  oscillator  is  alone  in  free  space. 

The  experimental  results,  which  give  a  rdation  of  the  wave-length 
to  the  length  of  the  oscillator,  may  be  not  without  interest ;  because  of 
the  existence  of  numerous  very  thorough  mathematical  discussions 
of  the  problem. 

Apparatus  and  Plan  qf  the  Experiment.  —  A  general  idea  of  the 
experiment  may  be  had  by  a  reference  to  Fig.  1,  which  shows  in  ground 
plan  the  arrangement  of  the  apparatus. 

The  wavemeter,  shown  at  the  left  of  the  figure,  consists  of  a  variable 
condenser  C  in  series  with  a  loop  of  heavy  wire  L  and  a  high-fr^uency 
electrodynamometer  I.  The  loop  of  wire  L  is  in  the  form  of  a  square 
30  cm.  on  a  sida  The  condenser  consists  of  two  sets  of  semicircular 
plates — one  set  fixed  and  the  other  set  movable  by  rotation  about  a 
vertical  axis  so  as  to  permit  variation  of  capacity  by  bringing  a  greater 
or  less  area  of  the  two  sets  of  plates  into  an  interlapping  position.  A 
scale  carried  by  the  top  movable  plate  passes  under  a  fixed  pointer,  so 
that  the  position  of  the  movable  plates  with  respect  to  the  fixed  plates 
can  be  read  after  any  adjustment  of  Hie  apparatus. 

The  high-firequency  dynamometer  I  is  of  the  form  jMreviously  ^n- 
ployed  by  me  in  a  series  of  experiments  on  resonance  in  wireless  tele- 


/  Google 


326 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


graph  oironits,^  and  consists  of  a  diso  of  silver,  suspended  by  a  quartz 
fibre,  so  as  to  hang  near  a  small  coil  of  a  few  turns  of  wire,  with  the 
axis  of  which  the  plane  of  the  disc  makes  an  angle  of  45°,  as  is  shown 
in  Fig.  2.    The  disc  is  at  M ;  and  the  coil,  whi<^  in 
this  experiment  consisted  of  five  turns  of  wire  wound       .  / 
on  a  vulcanite  tube,  is  shown  at  G,  Fig.  2.     The  ter- 
minals from  the  coil  are  connected  to  binding  posts 
by  which  the  coil  is  put  into  the  wavemeter  circuit 
The  front  of  the  disc  M  carries  a  small  mirror,  ena- 
bling the  deflections  of  the  disc  to  be  measured  by 
means  of  a  telescope  and  scale. 


FioimB  1.  Wavemeter  circuit  and 
Hertz  oecillator. 


ot 


The  mounting  of  the  instrument  is  shown  in  Fig.  3. 
The  disc  is  suspended  in  the  vertical  vulcanite  tube, 
which  stands  on  a  base  provided  with  leveling  screws ; 
the  support  of  the  coil  is  inserted  in  the  side  of  the 
vertical  tube,  and  is  arranged  to  be  moved  in  and 
out  by  a  micrometer  screw.  This  delicate  motion 
of  the  coil  in  or  out  brings  the  coil  nearer  to  or  &rther  from  the 
suspended  silver  disc  so  as  to  vary  the  sensitiveness  of  the  instru- 
ment to  make  it  suitable  for  measuring  small  or  large  oscillating 
currents. 


^  Phys.  Review,  1904, 19|  196;  1905, 20, 220;  1905,  21,  367;  1906,  22, 159; 
1907,  24,  152. 


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PIERCE.  —  OSCILLATIONS   OF    A   HERTZ    OSaLLATOR. 


327 


0 

Figure  2.  Coil  and  suspended 
disc  of  the  high-frequency  dy- 
namometer. 


The  action  of  the  instroment  is  as  follows  :  Osoillations  in  the  coil 
induce  oscillations  in  the  disc,  and  between  these  two  sets  of  oscilla- 
tions there  is  a  force  which  causes  the 
disc  to  tend  to  set  itself  at  right  angles 
to  the  plane  of  the  coiL  A  mathemati- 
cal theory  of  the  instrument)  together 
with  some  experiments  showing  that  the 
deflections  of  the  disc  are  proportional 
to  the  square  of  the  current  in  the  coil, 
is  given  by  me  in  volume  20,  page  226, 
of  the  Physical  Review  for  1905. 

In  place  of  the  djmamometer,  a 
Geissler  tube,  connected  to  the  two  sides 
of  the  condenser,  was  used  in  some  of 
the  experiments. 

The  Calibration  of  the  Wavemeter.  — 
For   wave-lengths    greater    than    350 

meters,  I  have  a  set  of  standard  oscillators 
whose  periods  have  been  determined  by 
spark-photographs  taken  with  the  revolv- 
ing mirror.2  These  could,  however,  not 
be  employed  in  the  present  experiments, 
where  the  greatest  length  of  oscillator 
that  could  be  set  up  in  the  room  had  a 
wave-length  of  only  63  meters.  It  was, 
therefore,  necessary  to  use  another  method 
of  calibrating  the  wavemeter  of  Fig.  1; 
namely,  by  tuning  it  to  resonance  with 
an  oscillator  consisting  of  various  lengths 
(4  to  17  meters)  of  two  parallel  wires, 
1  mm.  in  diameter  and  8  cm.  apart  It 
was  assumed  that  the  wave-length  of  such 
a  parallel-wire  oscillator  is  four  times  the 
length  of  one  of  the  wires.  This  assump- 
tion is  on  the  supposition  that  there  is  a 
loop  of  potential  at  the  iree  end  of  the 
Figure  3.  Mounting  of  oscillator,  and  that  the  velocity  of  the 
waves  on  parallel  wires  is  equal  to  the 
velocity  of  light 
In  regard  to  the  loop  at  the  free  end,  Bumpstead^  has  shown  that 
this  loop  of  potential  for  a  parallel- wire  oscillator  is  really  beyond  the 


d}rnamometer  with  variable 
sensitiveness. 


*  Phys.  Review,  1907,  24,  152. 


»  Am.  Jour.  Sci.,  1902, 14,  359. 


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328  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

free  end  by  an  amoant  a  little  less  than  half  the  distance  apart  of  the 
wires.  This  correction,  applied  to  my  experiments,  amounts  to  less  than 
one  per  cent  in  the  case  even  of  the  shortest  parallel-wire  oscillator  used 
in  the  calibration,  and  has  been  taken  into  account. 

That  the  velocity  of  the  waves  on  the  wires  is  equal  to  the  velocity 
of  light  has  its  theoretical  basis  in  the  &ct  that  for  rapid  oscillations 
guided  by  parallel  wires,  the  self-induction  per  unit  of  length  multiplied 
by  the  capacity  per  unit  of  length  is  the  reciprocal  of  the  square  of  the 
velocity  of  light.  That  the  velocity  of  propagation  on  the  parallel 
wires  is  the  velocity  of  light  has  been  shown  experimentally  by  Trow- 
bridge and  Duane  ^  and  by  Saimders.^  Recently  also  Diesselhorst®  of 
the  Reichsanstalt  has  made  some  experiments  which  indicate  that  the 
wave-length  on  the  parallel  wires  differs  from  the  wave-length  in  air 
by  less  than  one-third  of  one  per  cent  when  the  parallel  wires  are  not 
more  than  100  meters  long. 

Wave-length  of  the  Wave  Produced  by  the  Hertz  Oscillator,  —  If  now 
we  take  the  two  parallel  wires,  separate  them,  and  extend  them  out 
oppositely  so  as  to  form  a  Hertz  oscillator,  the  capacity  per  unit  of 
length  diminishes,  while  the  inductance  per  unit  of  length  increases. 
Does  the  wave-length  remain  the  same ;  namely,  four  times  the  length 
of  the  half-oscillator,  or  X  =  2  /,  where  /  is  the  length  of  the  whole 
oscillator  1  Some  theoretical  writers  (Abraham,^  Rayleigh  ®)  say  that 
it  does  remain  very  approximately  the  same  (if  the  diameter  of  the  wire 
is  a  small  fraction  of  the  length)  ;  while,  on  the  other  hand,  Macdonald  ^ 
has  concluded  that  X  is  equal  to  2.53  /,  and  he  is  supported  in  this  con- 
clusion by  Pollock  and  Close.  ^^ 

Experimental  tests  of  the  question  have  heretofore  usually  been 
made  with  very  short  vibrating  systems,  to  which  the  theoretical  de- 
ductions are  not  directly  applicable  A.  D.  Cole  ^^  finds  X  =  2.52  l^ 
for  a  Klemencic  receiver  7  to  8  cm.  long  and  3.1  mm.  in  diameter. 
This  is  in  good  agreement  with  Macdonald's  theoretical  relation.  It  is 
doubtful,  however,  if  Macdonald's  equation,  which  was  derived  by  con- 
sidering the  oscillator  or  receiver  to  be  indefinitely  thin  in  comparison 
with  its  length,  was  intended  to  apply  to  the  relatively  thick  receivers 
of  Cole's  experiment 

Another  very  admirable  set  of  measurements  with  short  oscillators 
has  recently  been  published  by  Webb  and  Woodman.^    With  an  un- 

*  Am.  Jour.  Sci.,  1895,  49,  297.  •  Phys.  Review,  1896,  24,  152. 

•  Elektrotech.  Zeits.,  1908,  29,  703.        »  Wied.  Ann.  1898,  66,  436. 
»  Phil.  Mag.,  1904,  8,  105.  •  Electric  Waves,  111. 

"  Phil.  Mag.  1904,  7,  635.  "  Phys.  Review,  1905,  20,  268. 

"  Phys.  Review,  1909,  29,  89. 


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PISBCE. — OSCILLATIONS   OF  A   HEBTZ    OSCILLATOR. 


329 


tuned  receiver  they  have  made  measurements  of  the  wave-length  pro- 
duced by  rod  oscillators  of  various  lengths  between  2  and  10  cm.,  and 
various  diameters  between  0.2  and  1.3  cm.,  and  have  obtained  the 
wave-length  a  linear  function  of  the  length  when  the  ratio  of  diameter 
to  length  is  kept  constant^  and  also  the  wave-length  is  a  linear  func- 
tion of  the  ratio  of  diameter  to  length  when  the  length  is  kept  con- 
stant By  extrapolation  from  their  measured  values  they  find  the 
limiting  value  of  the  ratio  of  the  wave-length  to  the  vibrator  length, 
as  the  diameter  approaches  zero,  to  be  2.24. 

Coming  now  to  the  experiments  that  have  been  made  with  the  longer 
oscillators,  I  find  two  measurements  mentioned  by  Drude  ^^  in  which 
he  obtains  for  a  wire  1  mm.  in  diameter  and  4  meters  long  the  wave- 
length 8.42  meters,  and  for  a  wire  2.5  meters  long  the  wave-length 
5.24.     These  two  experiments  give  X  =  2.10  £ 

Also  there  is  a  series  of  measurements  by  F.  Conrat  ^*  for  rectilinear 
oscillators  2  to  6  meters  long  (1  mm.  diameter).  These  measurements 
are  presented  in  Table  I.,  and  show  the  average  relation  X  =  2.12  /. 

TABLE  I. 
Conrat's  Values  for  Relation  op  X  to  I. 


I 

Lenffth  of 
OsciTlator 
in  Met  era. 

A. 

Wave-length 

in  Metera. 

A/I. 

•2.00 
3.84 
4.00 
5.50 
6.30 

4.20 

8.00 

8.40 

12.00 

13.40 

2.10 
2.09 
2.10 
2.18 
2.12 

Average 2.12 

My  measurements,  extending  the  experimental  records  in  the  direc- 
tion of  the  longer  waves,  are  given  in  Table  11.  The  diameter  of  the 
wire  employed  was  1  mm.  The  result  obtained  is  that  the  wave-length 
of  the  oscillator  is  2.094  times  its  length.  This  is  in  good  agreement 
with  the  results  obtained  by  Drude  and  in  fair  agreement  with  those 
of  Conrat. 


"  Ann.  d.  Physik,  1903,  11,  965. 


"  Ibid.,  1907,  22,  670. 


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330 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


Taking  the  present  observation  together  with  those  of  Dmde  and 
of  Conrat  it  appears  that  the  wave-length  of  a  Hertz  rectilinear  is  very 
close  to  2.10  times  the  length  of  the  oscillator,  provided  the  oscillator 
is  not  less  than  two  meters  long  and  is  of  comparatively  small  diam- 
eter. The  influence  of  the  diameter  in  determining  the  wave-length 
was  not  tested  further  than  by  a  single  observation,  in  which  it  was 
found  that  an  oscillator  made  of  two  brass  tubes,  each  6  meters  long 
and  22  mm.  in  diameter,  had  a  wave-length  2.14  times  its  length. 

TABLE  II. 
Results  obtained  in  Present  Experiment. 


I. 

Length  of  Oscillator 
in  Meters. 

Wave-length 
in  Meters. 

A/i. 

8.0 

16.9 

2.11 

9.0 

18.9 

2.10 

10.0 

21.2 

2.11 

11.0 

23.2 

2.11 

12.0 

24.9 

2.08 

14.0 

29.5 

2.10 

•     16.0 

33.6. 

2.10 

18.0 

38.1 

2.11 

20.0 

41.6 

2.08 

22.0 

46.1 

2.11 

24.0 

49.5 

2.07 

26.0 

53.9 

2.07 

28.0 

57.5 

2.06 

30.0 

63.0 

2.10 

Averag 

B 

.    .      2.094 

Comparison  qf  the  Result  with  Abraham* s  Theoretical  Relation.  — 
The  value  obtained  theoretically  by  Abraham,  as  a  second  approxima- 


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PIERCE. 


OSCILLATIONS   OF    A    HERTZ    OSCILLATOR. 


331 


tion  for  the  wave-lengtii  of  a  thin  rod  in  terms  of  its  length  and 
diameter,  is 

X  =  2/Cl  +  5.60» 
where 

1 


€  = 


4l0g.-^ 


in  which  /  is  the  length  of  the  whole  oscillator,  and  d  its  diameter. 
The  formula  was  derived  by  applying  Maxwell's  equations  to  a  long, 
perfectly  conductive  ellipsoid  of  revolution,  and  taking  the  limit  ap- 
proached by  X  when  the  square  of  the  minor  axis  of  the  ellipsoid 
vanishes  in  comparison  with  the  square  of  the  major  axis.  Under 
these  conditions  the  major  axis  becomes  the  length  of  the  rod-oscil- 
lator and  the  minor  axis  its  diameter. 

To  show  the  size  of  the  5.6  ^^  term  of  Abraham's  formula,  the  follow- 
ing table  (Table  III.)  has  been  computed  for  various  values  of  l/d,  cov- 
ering the  range  of  the  experiments  by  Webb  and  Woodman  and  those 
by  Conrat  and  by  ma 

TABLE  III. 

Computation  op  the  6.6«*  Term  op  Abraham's  Formula. 


l/d. 

5.6c> 

Range. 

4 

.081 

\ 

5 

7 

.065 
.050 

'  Webb  and  Woodman. 

10 

.039 

J 

160 

.011 

2000 
4000 
6000 

.005 

.0043 

.0039 

Conrat. 

8000 
12000 
20000 
30000 

.0037 
.0035 
.0031 
.0029 

I  Writer. 

It  is  seen  that  in  the  range  of  my  experiments,  the  5.6  €*  term  raises 
the  theoretical  value  of  the  wave-length  to  2.006 1,  and  in  Conrat's 
range  to  2.01  /.  This  term  is,  therefore,  entirely  inadequate  to  account 
for  the  5  per  cent  excess  of  the  experimental  values  over  the  theoretical 
values  of  Abraham. 


Digitized  by  LjOOQIC 


332  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

Also  the  presence  of  the  spark-gap  in  the  oscillator  seems  to  he 
without  influence,  as  the  values  of  Conrat  were  obtained  for  rods 
without  a  gap. 

In  discussing  the  question,  raised  by  Pollock  and  Glose,^^  as  to 
whether  a  result  obtained  for  an  infinitely  thin  ellipsoid  can  be  applied 
to  an  infinitely  thin  rod  of  uniform  section,  Lord  Rayleigh  ^®  says : 
"  It  appears  therefore  that  the  wave-length  of  the  electrical  vibration 
associated  with  a  straight  terminated  rod  of  infinitesimal  section  is 
equal  to  twice  the  length  of  the  rod,  whether  the  shape  be  cylindrical 
so  that  the  radius  is  constant,  or  ellipsoidal  so  that  the  radius  varies 
in  a  finite  ratio  at  different  points  of  the  length,  and  that  this  conclu- 
sion remains  undisturbed,  even  though  the  shape  be  not  one  of  revolu- 
tion." Lord  Rayleigh,  however,  raises  the  question  whether  a  sufficient 
reduction  of  the  diameter  of  ^e  rod  to  comply  with  Abraham's  ap- 
proximation is  experimentally  possible  without  too  greatly  diminishing 
the  conductivity,  which  is  assumed  perfect  in  the  theoretical  discussion. 

In  reply  to  this  note  by  Lord  Rayleigh,  Macdonald  ^^  expresses  the 
view  that  the  rate  of  damping  of  the  iree  vibration  associated  with  the 
terminated  straight  wire  is  very  large,  and  in  fiewjt  not  far  removed  bom 
the  order  of  magnitude  of  the  known  result  for  a  spherical  vibrator. 
This  large  damping,  if  it  exists,  and  especially  if  it  is  due  to  a  large 
radiation  firom  the  wire  near  the  ends,  would  account  for  a  distortion 
of  the  current  distribution  in  the  conductor  so  as  to  give  a  wave-length 
larger  than  twice  the  length  of  the  conductor. 

Since  the  question  of  the  conductivity  of  the  wire  and  the  damping 
of  the  oscillations  has  a  bearing  on  the  question  of  its  period,  it  is  pro- 
posed to  give  the  results  of  a  measurement  made  on  the  damping  of 
one  of  the  oscillators  used  in  the  present  experiments. 

Damping.  —  The  damping  fiwtor  of  a  rectilinear  oscillator  14  meters 
long,  consisting  of  two  oppositely-extending  horizontal  wires  7  meters 
long  and  1  mm.  in  diameter,  was  determined  by  a  method  recently 
given  by  K.  K  F.  Schmidt^®  The  spark-gap  was  3  mm.  long. 
Schmidt's  method  consists  in  determining  the  average  square  current 
in  a  low  resistance  wavemeter  circuit  for  various  adjustments  of  the 
wavemeter  in  the  neighborhood  of  resonance.  To  get  the  mean  square 
current  in  the  wavemeter  circuit  the  dynamometer  shown  in  Figs.  2 
and  3  was  employed.  The  deflections  of  this  instrument  have  been 
shown  to  be  proportional  to  the  square  of  the  current  The  values  ob- 
tained are  recorded  in  Table  IV,  which  gives  the  wave-length  adjust- 

"  Loc.  cit.  *•  Loc.  cit. 

"  Phil.  Mag.,  1904,  8,  276.  "  Phys.  Zeits.,  1908,  9,  13. 


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PIERCE.  —  OSCILLATIONS   OF   A   HERTZ  OSCILLATOR. 


333 


ment  of  the  wavemeter  and  the  correspondiiig  relative  deflections  of 
the  dynamometer. 


TABLE  IV. 
For  Determining  Damping. 


Adjustment  of 
Wavemeter. 
A  in  Meters. 

A/A«. 

D/Dm. 

Deflection  relative 
to  Maximum. 

30.3 

.992 

.99 

29.2 

.960 

.68 

27.6 

.908 

.160     . 

26.0 

.859 

.054 

32.2 

1.062 

.39 

33.9 

1.111 

.150 

81.5 

1.032 

.71 

30.5 

1.000 

1.00 

These  results  are  plotted  in  the  curve  of  Fig.  4,  in  which  the  abscis- 
sas are  A/A^  aud  the  ordinates  DjD^ 

Schmidt's  method  of  getting  the  damping  from  this  curve  consists 
in  determining  the  width  between  the  two  branches  of  the  curve  at 
ordinates  .55,  .70,  and  .85,  and  then  making  use  of  a  decrement  diar 
gram  which  he  has  computed  and  plotted  in  his  original  paper,  to  which 
the  reader  is  referred.  This  method  applied  to  the  present  case  gives 
the  values  in  Table  V. 

TABLE  V. 
Decrement  by  Schmidt's  Method. 


Ordinate. 

Width  of  Res. 

Curve,  reduced  to 

Proper  Scale, 

« 

.55 

.70 
.85 

.88 
.64 
.40 

.32 
.33 
.32 

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334 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


The  last  column  of  this  table  gives  the  logarithmic  decrement  per 
complete  oscillation.    The  value  .32,  including  the  Joulean  decrement 


af  7 

o 


".6 
ui 

^ 

S 

J 


l^ 

f      \ 

t     X 

t             ^c- 

-4              \ 

7             \^ 

J^              \ 

-7               ^ 

^^                 ^ 

•-^ 

Figure  4.  Resonance  curve  \ised  in  obtaining  logarithmic  decrement. 

as  well  as  the  radiation  decrement,  is  40  per  cent  higher  than  tiie 
logarithmic  decrement  due  to  radiation  alone,  as  computed  by 
Abraham's  formula  for  the  decrement,  which  is 


8  = 


9.74 


4loge 


2/ 


The  value  of  the  decrement  is,  however,  too  small  to  produce  a  change 
in  the  measured  value  of  the  wave-length  by  more  than  a  small  fraction 
of  one  per  cent 

Summary  qf  BemUs,  — Assuming  that  the  wave-length  produced  by 
the  parallel-wire  oscillator  is  four  times  the  length  of  one  of  the  wires, 
the  wave-length  produced  by  the  fundamental  electrical  vibration  of  a 
long,  thin,  rectilinear  Hertz  oscillator  was  found  to  be  2.094  times  the 


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PIERCE.  —  OSCILLATIONS   OF  A   HERTZ    OSCILLATOR.  335 

total  length  of  the  oscillator,  for  oscillators  of  length  between  8  and 
30  meters. 

This  result  is  4.5  per  cent  higher  than  Abraham's  theoretical  value 
computed  by  the  formulas 

X  =  2/(1 +  5.6  c^ 

4l0ge-5- 

The  results  obtained  in  the  present  experiments  are  in  approximate 
agreement  with  two  measurements  given  by  Drude  and  with  a  series  of 
measurements  obtained  by  Gonrat,  both  using  oscillators  of  length 
between  2  and  6  meters. 

Jefferson  Physical  Laboratory, 
Cambridge,  Mass., 

December,  1909. 


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Proceedings  of  the  American  Academy  of  Arts  and  Sciences. 
Vol.  XLV.  No.  12.  — April,  1910. 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 


THE    CONCEPTION    OF    THE   DERIVATIVE    OF   A 

SCALAR  POINT  FUNCTION   WITH  RESPECT 

TO  ANOTHER  SIMILAR  FUNCTION. 


Bt  B.  Osgood  Peibcb. 


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Digitized  by 


Googl( 


CX)NTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 

THE  CONCEPTION  OF  THE  DERIVATIVE  OF  A  SCALAR 
POINT  FUNCTION  WITH  RESPECT  TO  ANOTHER 
SIMILAR   FUNCTION. 

Bt  B.  Osgood  Pbirce. 

Presented  December  8, 1009.    Received  January  6,  1910. 

Ik  modern  treatises  on  Mathematical  Physics  it  is  customary  to  de- 
fine the  deriyative  of  a  scalar  function,  taken  at  a  given  point  in  space 
in  a  giyen  direction,  in  a  manner  which  emphasizes  the  fact  that  this 
derivative  is  an  invariant  of  a  transformation  of  coordinates.  Accord- 
ing to  this  definition,^  if  through  the  point  P  a  straight  line  be  drawn 
in  a  fixed  direction  («),  if  on  this  line  a  point  P  be  taken  near  P  so  that 
PP  has  the  direction  «,  and  if  Up^  Upf  be  used  to  represent  the  values 
at  these  points  of  the  scalar  point  function  ti,  then  if  the  ratio 

"^^^  '  (1) 

approaches  a  limit  as  P  approaches  P,  this  limit  is  called  the  derivative 
of  Uy  at  P,  in  the  direction  8.  If  u  happens  to  be  defined  in  terms  of  a 
system  of  orthogonal  Cartesian  coordinates,  x^  y^  Zy  and  has  continuous 
derivatives  with  respect  to  these  coordinates  ever3rwhere  within  a 
certain  region,  the  limit  just  mentioned  exists  in  this  region  and  its 
value  is 

-.cos(^,.)  +  ~.cos(y,,)  +  g.cos(^,.).  (2) 

*  Hamilton,  Elements  of  the  Theory  of  Quaternions;  Tait,  Elementary 
Treatise  on  Quaternions;  Gibbs,  Vector  Analysis;  Maxwell,  Treatise  on 
Electricity  and  Magnetism;  Webster,  Dynamics  of  Particles  and  of  Rigid, 
Elastic,  and  Fluid  Bodies;  Jeans,  Mathematical  Theory  of  Electricity  and 
Magnetism;  Lam6,  Lemons  sur  les  Coordonn^es  Curvilignes;  Peirce,  Theory 
of  the  Newtonian  Potential  Function;  Generalized  Space  Differentiation  of 
the  Second  Order;  Czuber,  Wienerberichte.  101a,  1417  (1892);  Boussinesq, 
Cours  d* Analyse  Infinit^male;  H.  Weber,  Die  PartieUen  Differential-Gleich- 
ungen  der  Mathematischen  Physik. 


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340  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

Of  all  the  numerical  valiies  which  the  derivative  of  u  can  have  at  a 
given  point,  the  greatest  is  to  be  found  by  making  s  normal  to  the  level 
sur£sboe  of  u  which  passes  through  the  point    This  maximum  value, 

is  usually  regarded  as  the  value  at  the  point  of  a  vector  point  function 
called  the  gradient  vector  of  u,  the  lines  of  which  cut  orthogonally  the 
level  surfiices  of  u^  and  the  components  of  which  parallel  to  the  coord- 
inate axes  are 

du     du     du  .V 

dx^    dy*    dz 

This  vector  is,  of  course,  lamellar. 

The  value  of  the  tensor  of  the  gradient  vector  is  often  called  simply 
the  "  gradient "  of  u  and  is  denoted  by  Au*  If  at  any  point  a  straight 
Jine  be  drawn  in  the  direction  (»)  normal  to  the  level  surfigice  of  w, 
in  the  sense  in  which  u  increases,  and  if  a  length  hu  be  laid  off  on  this 
line,  the  projection, 

Au  •  cos  (»,  «),  (5) 

of  this  length  on  any  other  direction  (s)  is  numerically  equal  to  the 
derivative  of  u  in  the  direction  8. 

Most  physical  quantities  —  such  as  temperature,  barometric  pres- 
sure, density,  inductivity  —  present  themselves  to  the  investigator  as 
single  valued  point  functions,  which,  except  perhaps  at  one  or  more 
given  surfiEbces  of  discontinuity,  are  differentiable  in  the  sense  just 
considered. 

It  is  often  desirable  to  differentiate  a  scalar  function,  ti,  at  a  pointy 
in  the  direction  in  which  another  scalar  function,  v,  increases  fSa^test^ 
and  if  (t«,  v)  represents  the  angle  between  the  gradient  vectors  of  u  and 
V  at  the  point,  the  derivative  is  evidently  equal  to 

Au»cos(tf,  v).  (6) 

It  frequently  happens  that  in  a  question  of  maxima  and  minima, 
one  wishes  to  determine  the  greatest  (or  the  smallest)  value  which  a 
quantity  U  may  have,  subject  to  the  condition  that  another  quantity 
V  shall  have  a  given  value  (  V^,  If  these  quantities  can  be  represented 
by  point  functions,  the  problem  geometrically  considered  requires  one 
to  find  the  parameter  of  a  surfeu^  of  the  constant  U  family,  which  is 
tangent  to  the  surfisu5e  of  the  V  &mily  upon  which  V  is  everywhere 


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PEIRCE.  —  DERIVATIVE   OF   A   8CALAB   POINT    FUNCTION.       341 

equal  to  Vo ;  but  at  the  point  of  tangenoy,  the  derivative  of  the  function 
U  in  any  direction  in  the  tangent  plane  of  the  V  surface  is  zero,  that 
is,  the  normals  to  the  U  and  V  surfisices  coincide,  so  that 


(7) 


and  these  &miliar  equations  usually  furnish  some  general  information 
about  the  problem  independent  of  the  value  of  F^.    As  an  extremely 


du 

du 
_  9y  _ 

du 

dz 

dv 
dx 

dv 

ay 

dv' 
dz 

,    \ 
.    1 

"IT— 

\\^ 

\\ 

\ 

1 

\ 

\ 

^^ 

\ 

\ 
\ 

\ 

V 

<^ 

I 

A 

\ 

< 

\ 

^ 

< 

<J 

s 

>v 

^ 

^ 

^^ 

^ 

^^P 

i^ 

V 

'v 

^  ^ 
>» 

^^m 

D 

C 

■B 

"^^^ 

i-n,^ 

" 

Figure  1. 

simple  example  we  may  take  the  familiar  problem  concerning  the  rela- 
tive dimensions  of  an  open  tank  of  square  base  (x  X  x)  and  height  y, 
which  shall  hold  a  given  quantity  (  r=  x^.y)  of  water  and  have  the  smaU- 
est  wet  surface  (U=a:^  +  4an/).  Here  we  have  the  curve  D  of  the  V 
family,  which  has  the  given  parameter,  Vo,  and  are  required  to  find  that 
member  of  the  P,  Q,  /?,  S  family  which  touches  D.  The  equation  (7) 
becomes  in  this  case  2^  =  ^,  and  it  appears  (Figure  1)  that  the  curves 
of  the  two  &milies  which  pass  through  any  point  of  the  line  OJ/are  at 
that  point  tangent  to  each  other. 

It  is  sometimes  necessary  to  differentiate  a  point  function,  u,  at  a 
point  P,  in  the  direction  of  the  line  through  the  point,  along  which 


Digitized  by  LjOOQIC 


342 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


two  other  point  functions,  v,  w^  are  constant ;  that  is,  along  the  line 

V  =  Vp,W  —  Wp.      If 


X  = 


dv   dv 
dy  dz 

dw  dw 

.     M  = 

dv    dv 
dz   dx 

dw  dw 

.  N-= 

dv    dv 
dx  dy 

dw  dw 

dy  dz 

dz  dx 

dx  dy 

(8) 


and  if  J?*  =  Z*  -f  M^  +  N^ — which  is  equal  to  K^  •  h^^y  if  v  and  w 
are  orthogonal  —  this  direction  is  defined  by  the  cosines  L/Rj  M/R^ 
N/Ry  and  the  derivative  required  is 


i( 


dx  dy  d. 


0- 


(9) 


If  the  maxima  and  minima  of  the  function  u—f{xy  y,  2;)  are  to  be 
found  under  the  condition  that  the  functions  v,  w  shall  have  given 
numerical  values,  the  derivative  of  u  taken  in  the  direction  in  which  v 
and  w  are  constant  must  be  made  to  vanisL    Thus,  if 

w  =  ar^  H-  y"  +  5?*, 
and  if  the  conditions  are 

ocyz  =  (?  and  x  +  y  =  d, 
equation  (9)  yields  immediately  the  required  relation 

When/'  (u)  is  positive,  the  direction  of  the  gradient  vector  o(/(u) 
coincides  with  that  of  the  gradient  vector  of  u  itself :  these  directions 
are  opposed  when/'  (u)  is  negative.  The  tensors  of  both  vectors  are 
always  positive.    If 

w  =/(w),    hy,^  =  [/'  (u)Y  ;  hu\   and    cos  {w,  s)  =  cos  {%  s)  : 
in  particular,  when 

w  =  1/m^  Av  =  Au/tt*  and  cos  (w?,  «)  =  —  cos  (u,  5), 


so  that 


ds  \uj  ds     u* 


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PEIRCB. — DERIVATIVE   OF   A    SCALAR  POINT   FUNCTION.       343 

If  u  is  the  distance  (r)  to  a  point  on  a  carve  (s)  from  a  fixed  point 
outside  the  curve, 

dr /     \    ^  ^^^_      cos  fa  r) 


dr       ,         /     X    5  /l\          cos  (« 
^^  =  +  C08(,.r).-y  = ^ 


Any  function  of  the  complex  variable  {aa  +  fiy  +  izs/a^  +  b^  has  a 
gradient  identically  equal  to  zero,  but  every  differentiable  real  point 
function  has  a  gradient  in  general  different  frt>m  zero.  The  gradient  of 
a  function  may  be  constant  throughout  a  region  of  space :  if  the 
gradient  of  u  is  constant,  the  surfaces  upon  each  of  which  u  is  constant 
form  a  parallel  system.  If  the  gradient  of  a  function,  Uy  is  either  con- 
stant or  expressible  in  terms  of  u,  any  differentiable  function  of  u  has 
a  gradient  either  constant  or  expressible  in  terms  of  u.  If  the  gradient 
of  u  is  expressible  in  terms  of  u  alone  [hu  =/(t^)],  it  is  possible  to  form 

a  function,  a  I  jj-^ ,  of  u  the  gradient  of  wliich  shall  be  constant    If 

hu  is  neither  constant  nor  expressible  in  terms  of  u,  no  function  of  u 
exists  the  gradient  of  which  is  expressible  in  terms  of  u.  The  functions 
«i  =  sin  (^  +  y  4-  5?),  1?  =  sin  (^  +  2y  —  32j),  w  =  sin  (5^  —  Ay  —  z) 
illustrate  the  fact  that  the  gradient  of  each  of  three  orthogonal  point 
functions  may  be  expressible  in  terms  of  the  function  itself. 

If  the  gradient  of  each  of  two  orthogonal  point  functions,  u,  t?,  were 
expressible  as  the  product  of  a  function  of  u  and  a  function  of  %  so  that 
A^  =  Z7i  •  Fi,  and  A»  =  Ut-  Fa,  it  would  be  possible  to  form  two  func- 
tions I    /  y^,    /  -pr     of  «*  alone  and  of  v  alone,  respectively,  the 

gradient  of  each  of  which  would  be  expressible  in  terms  of  the  other. 
If  the  gradient  vectors  of  two  functions  have  the  same  direction  at 
every  point  of  space,  one  of  these  functions  is  expressible  in  terms  of 
the  other.  If  the  gradients  of  two  real  functions,  ti,  t?,  are  ever3rwhere 
equal  while  the  directions  of  their  gradient  vectors  are  different, 

a(u+t?)  dju-v)  ^  d{u  +  v)  d{u-v)  ^K^^-v)  K^-v)  ^^     ,j^. 
dx  dx  dy  by  dz  dz  »    v     / 

and  the  functions  [w  -f  v],  [t*  —  v]  are  orthogonal,  as  are  F(u  -f  v), 
/(tt  —  r),  where  i^  and /are  any  differentiable  functions.  If  u  and  v 
are  orthogonal  functions,  the  functions  [F(u)  +/(v)],  [F(u)  — /(v)] 
have  gradients  numerically  equal  to  each  other  at  every  point. 

Two  scalar  point  functions,  the  level  sur&ces  of  which  are  neither 
coincident  nor  orthogonal,  may  have  gradients  each  of  which  is  ex- 


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344  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

pressible  in  terms  of  the  other :  the  gradient  of  t?  =  |a?*  —  A:xf  is 
equal  at  every  point  of  the  xy  plane  to  the  square  of  the  gradient  of 
u  —  a^'-y\  If  fi  and  v  are  orthogonal  functions  of  x  and  y,  the 
product  of  their  gradients  is  equal  to  the  Jacobian, 

du  dv      du  dv 
dx  By      dy  da 
The  differential  equation 


(sr-CD^dy-. 


which  leads  to  systems  of  parallel  surfaces,  is  of  standard  form.    Its 
complete  integral  is 


where  a,  &,  (2  are  arbitrary  constants,  and  from  this  the  general 
integral  may  be  obtained  in  the  usual  manner. 


If  a  direction  s  be  determined  at  every  point  of  a  given  region,  T, 
by  some  law,  the  derivative  of  the  function  u  becomes  itself  a  scalar 
point  function  in  7",  and  if  this  is  differentiable,  it  may  be  differentiated 
at  any  point  in  any  direction,  say  s.  It  is  usually  convenient  to 
defii^e  8  by  means  of  three  scalar  point  functions,  I,  m,  n,  the  sum  of 
the  squares  of  which  is  identically  equal  to  unity,  and  which  represent 
the  direction  cosines  of  s.  In  this  connection  it  is  well  to  notice  that 
if  s  has  the  direction  at  P  of  the  tangent  of  a  continuous  curve  which 
passes  through  the  point,  if  P'  be  a  point  near  P  on  the  tangent  and 
P^'  a  point  near  P  on  the  curve,  and  if  £7^  is  any  differentiable  scalar 
point  function, 

t/p//  ~  Up  Up"-  Up 

PP"     '  PP" 

have  the  same  limit,  as  JP'  and  P"  approach  P,  that  which  has  been 
defined  as  the  derivative  of  U  a,t  P  in  the  direction  8,  It,  then, 
du/d8  is  differentiable 


d  fdu\        d  f  J  du  .         du  .        du\ 


__  -  6^  d^u  d^u        du  dl      du  dm     du  dn 

""     dai^  dX'dy  dxdz     dx  dx     dy   dx      dz  dx* 

(11) 


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PEIRCE.  —  DERIVATIVE   OF   A   SCALAB   POINT   FUNCTION.       345 

and 

a^  dx^  bf  dz*  bx'dy  dy*dz  dxOz 

If  /  is  a  direction  defined  by  the  cosines  f,  m\  n\ 
=  /r  •  T-i  +mm  •  T^  +nn  • 


a^\      a^?  dy  dzj     di/\     dx  dtf  dz  J 

and  it  is  clear  that  the  order  of  differentiation  is  usually  not  com- 
mutativa  Derivatives  of  this  kind  are  often  found  in  differential 
equations  of  orders  higher  than  the  first  which  define  functions  in 
terms  of  simple  curvilinear  coordinates. 

If  for  instance  spherical  coordinates  are  to  be  used,  the  second 
derivative  of  u  taken  in  the  direction  in  which  0  increases  fisistest  is 

T-j  •  cosV  oos'<^  +  T-a  •  cos'^sin'y  +  ^  •  sm'^+           •  cos*  tf  sin  <^cos  <^ 
•  sm^cos^cos^  — r — T-'Sin^cos^sm  <f> T--sin^cos^ 


dx'dz  dydz  rdx 

■  sin  ^  sin  <^ ^  •  cos  6  (14) 


r-dj/  r-dz 

and  this,  which  contains  derivatives  of  the  first  order,  is  in  sharp  con- 
trast to  the  second  derivative  of  u  taken  in  the  direction  r,  which  is, 

r— a  •  sm*  6  Goer<^  +  r-s  •  sin"^  sm'<^  +  -z-^  •  cos'^  +  r — r-  •  surd  sm6  cos<^ 
dor  di^  dz^  dxdy 

.       2d*tt         .       >j'  /,      .        .      ,       2a'tl         ./,/,.  /,eN 

+  r r-  -Sm^OOS^Sm^  +  r r- •  Sin  ^  COS  ^  008  6.  (15) 

by-dz  OZ'OX  ^ 


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346  PROCEEDINGS  OP  THE  AMERICAN  ACADEMY. 

Sometimes  s  and  /  are  fixed  directions  so  that  /,  m,  n,  t,  m\  n\  are 
constants  throughout  T^  and  in  this  case  the  coefficients  of  du/dx^ 
du/di/^  du/dz  in  (12)  and  (13)  vanish.  The  mutual  potential  energy  TT, 
of  two  magnetic  elements,  M^  M\  of  moments,  wi,  m\  can  be  written 
in  the  form 


wi  *fn 


where  r  is  the  distance  MM*  and  «,  si  are  the  directions  of  the  axes 
of  the  elements.  The  force  (due  to  the  second  magnet)  which  tends 
to  move  the  first  magnet  in  the  direction  of  its  own  axis  is  then 

and  these  differentiations  assume  that  the  direction  cosines  of  b  and 
/  are  constants. 

In  general,  if  s  is  the  direction  perpendicular  to  the  level  surface  of 
21,  and  if  h  is  the  scalar  point  function  which  gives  the  value  of  dei/d^, 

b^u  __  fdh  ^  ,   ^  du      dh  du\  L  .     . 

ds'  ^\d~xdx^dyTy^dz'd'z)r'  ^^^^ 

In  the  case  of  oblique  Cartesian  coordinates  in  a  plane,  x  increases 
fastest  in  a  direction  which  is  not  perpendicular  to  the  line  along 
which  it  is  constant     If  the  angle  between  the  coordinate  axes  is  a>, 

—  =  Au-cos  {x,  Au),    ^  =  A„ -cos  (y,  hu\    ^  =  Au-cos  («,  hu\ 

du  _du  sin  (y,  $)      du  sin  (x,  s)  .     . 

ds       dx       sin  w         6y      sin  w  ^    ^ 


It  is  frequently  necessary  to  differentiate  one  point  function,  f7,  with 
respect  to  another,  v,  and  the  process  usually  appears  in  the  form  of  a 
kind  of  partial  differentiation.  If,  for  instance,  f/'  is  to  satisfy  a  differ- 
ential equation  in  terms  of  a  set  of  orthogonal  curvilinear  coordinates 
of  which  u  is  one,  the  derivatives  of  U  with  respect  to  t^  are  to  be  taken 
on  the  assumption  that  the  other  coordinates  remain  constant  This 
large  subject  has  been  treated  eidiaustively  in  the  many  works  on 


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PEIRCE. — DERIVATIVE   OP   A    SCALAR   POINT   FUNCTIOX.       347 

orthogonal  coordinates  which  have  been  published  since  Lamp's  clas- 
sical treatise  '  appeared. 

Given  a  function,  u,  it  is,  however,  not  generally  possible  to  find  a 
S3rstem  of  orthogonal  fiinctions  of  which  u  shall  be  one,  and  it  is  often 
convenient  for  a  physicist  to  differentiate  a  physical  function,  Uy  with 
respect  to  another,  u,  without  considering  the  existence  of  any  other 
related  functions.  A  physical  point  function  has  a  value  at  every  point 
in  space  which  is  not  altered  by  changing  the  system  of  coordinates 
which  fix  the  position  of  the  point,  and  it  is  well  to  define  the  deriva- 
tive of  U  with  regard  to  u  in  a  manner  which  shall  emphasize  the  &ct 
that  the  derivative  is  an  invariant  of  a  change  of  coordinates  and  which 
shall  not  assume  that  two  functions  (i;,  w)  can  be  found  orthogonal  to 
each  other  and  to  u.  When  U  and  u  are  considered  by  themselves  and 
not  regarded  as  coordinated  of  necessity  with  other  similar  quantities, 
it  is  usually,  if  not  always,  the  case  that  a  "  normal  **  derivative  ^  is 
required. 

The  normal  derivative,  at  any  point,  P,  of  the  diflferentiable  scalar 
point  function  U,  with  respect  to  the  difierentiable  scalar  point  function 
w,  may  be  defined  as  the  limits  when  PP'  approaches  zero,  of  the  ratio 

^^^^^.  (20) 

Upf  —  Up  ^      ^ 

where  P'  is  a  point  so  chosen  on  the  normal  at  P  of  the  surfiskce  of  con- 
stant u  which  passes  through  P,  that  up*  —  up  shall  be  positive.  If 
( Uf  u)  denotes  the  angle  between  the  directions  in  which  U  and  u  in- 
crease most  rapidly,  the  normal  derivatives  of  U  with  respect  to  u  and 
of  u  with  respect  to  U  may  be  written 

^'COq(U,u)    and    ^.cos(f7,u).  (21) 

If  hu^hu  these  derivatives  are  equal  An  example  of  this  is  the 
equality  of  dn/dr  and  dr/dn  in  a  familiar  application  of  Green's 
Theorem,  where  n  and  r  represent  the  normal  distance  from  a  given 
surface  and  the  distance  from  a  given  fixed  point  respectively.  If  U 
and  u  happen  to  be  expressed  in  terms  of  a  set  (;r,  i/,  z)  of  orthogonal 

•  Lam6,  Lemons  sur  les  Coordonn^  Curvilignes  et  leur  Diverses  Appli- 
cations; Salvert,  M^moire  sur  I'Emploi  des  Coordonn^es  Curvilignes;  Dar- 
boux,  Lemons  sur  les  Syst^mes  Orthogonaux  et  les  Coordonn^  Cundlignes; 
Goursat,  Cours  d'Analyse  Math^matique. 

'  Peirce,  Short  Table  of  Integrals,  Theory  of  the  Newtonian  Potential 
Function;  Generalized  Space  Differentiation  of  the  Second  Order. 


Digitized  by  LjOOQIC 


348  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

Cartesian  coordinates,  the  normal  derivative  of  U  with  respect  to  u 
can  be  written 

dUdudU  du      dU  du 

and  it  is  easy  to  see  that  this  is  equal  to  the  ratio  of  the  derivatives  of 
U  and  u  taken  in  the  direction  in  which  u  increases  most  rapidly. 

It  is  occasionally  instructive  to  use  the  conception  of  normal  difiFer- 
entiation  in  studjdng  some  of  the  general  equations  of  Physics  :  thus 
in  the  uncharged  dielectric  about  an  electric  distribution,  the  potential 
function,  F,  is  connected  with  the  inductivity  of  the  medium,  /x,  by  the 
&miliar  equation 

in  which  fi  is  to  be  regarded  as  a  point  function  discontinuous  in  gen- 
eral at  each  of  a  given  *Bet  of  sur&ces  at  every  point  of  which  an  equa- 
tion of  the  form 

is  satisfied.    Now  (23)  may  be  put  into  the  form 

dV    ^   hv'  ""^'  ^^^^ 

and  according  to  Lamp's  condition,  the  second  term  is  a  function  of  V 
only^  if  the  level  surfaces  of  V  are  possible  level  surfaces  of  a  harmonic 
function. 

It  is  easy  to  make  from  (25),  by  inspection,  such  simple  deductions 
as  those  which  follow  in  this  paragraph.  If  V  is  harmonic,  either  the 
dielectric  is  made  up  of  homogeneous  portions  separated  from  one  an- 
other by  equipotential  surfiswjes,  or  the  level  surfeices  of  fi  and  of  F  are 
everywhere  perpendicular  to  each  other.  If  F,  though  not  harmonic, 
satisfies  Lamp's  condition  [V^(  F)/  hp^  =  F(  F)]  the  level  surfeces  of  the 
inductivity  are  equipotential ;  and  if  the  level  surfiswes  of  F  and  fi  are 
identical,  F  satisfies  Lamp's  condition.  If  when  the  plates  of  a  con- 
denser are  kept  at  given  potentials,  the  level  sur&ices  of  the  inductivity 
of  the  dielectric  are  equipotential,  the  value  of  the  potential  function  in 


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PEIRCE. —  DERIVATIVE   OF    A   SCALAR   POINT   FUNCTION.       349 

the  dielectric  would  be  unchanged  if  ft  weie  changed  to  0.fi,  where  O  is 
any  scalar  point  function  orthogonal  to  F.  If  the  continuous  dielectric 
of  a  condenser  in  which  the  level  surfaces  of  the  inductivity,  /x,  are 
equipotential  be  changed  so  as  to  make  the  new  potential  function 
between  the  plates  a  function  [  F'  =/  ( V)]  of  the  old,  the  new  induc- 
tivity  must  satisfy  an  equation  of  the  form  /  =  Q.fi  If  (  F).  If  the  F 
and  the  ft  sur£a>ces  are  neither  coincident  nor  orthogonal,  F  cannot  be 
harmonic,  and  if  F  is  given  and  one  value  of  the  inductivity  found,  no 
other  value  of  the  inductivity  with  the  same  level  surfsu^es  as  this  can 
be  found  except  by  altering  the  old  value  at  eveiy  point  in  a  constant 
ratio.  If  F  does  not  satisfy  Lamp's  condition,  a  new  value  of  the 
inductivity  found  by  multiplying  the  old  value  by  any  point  function 
orthogonal  to  F,  will  jrield  the  same  value  of  F,  but  the  level  surfisMjes 
of  the  inductivity  will  be  altered.  If  the  F  and  the  ft  surfisices  are  not 
coincident,  no  change  of  the  inductivity  which  leaves  its  surfisices  un- 
changed can  make  these  surfaces  equipotential 

If  a  mass  of  fluid,  the  characteristic  equation  of  which  is  of  the  form 
p—fip,T)/\%  at  rest  under  the  action  of  a  conservative  field  of  force 
the  components  of  which  are  X,  F,  Z^ 

%-'-^-  %='-^-  t-'-^-  w 

It  follows  immediately  from  these  equations  that  p  and  F  must  be 
colevel,  and  the  normal  derivative  of  p  with  respect  to  F  shows  that 
equilibrium  is  impossible  unless  the  distribution  of  temperature  is  such 
that  the  equipotential  surfeuses  are  also  isothermal 

If  the  scalar  point  function,  TF,  is  expressed  in  terms  of  the  three 
orthogonal  point  functions,  tf ,  v^  w^  the  square  of  the  gradient  of  W  is 
well  known  to  be  equal  to 

If  the  vector  point  function  Q  is  expressed  in  terms  of  «,  r,  Wy  the 
diveigence  of  Q  is  equal  to 


Au  •  ^t>  •  Ai 


\^^\Khw)     ^\K'K)     ^\hu'KJs 


If  the  normal  derivatives  of  u  and  v  with  respect  to  u^  be  denoted  by 
DyaU  and  />»«?,  it  follows  from  the  definition  that 


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350  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

Dw  (w  +  v)  =  DwU  +  Du>%  Dv,u^  =  n  •  w^^  •  D^u^ 

D^/(u)=^f{u)'Dy,(u).        . 


The  normal  derivative  of  u  with  respect  to  t?  is  a  scalar  fanction 
which^  if  differentiable,  has  a  normal  derivative  with  respect  to  t?,  and 
since  by  definition 


(27) 


^^  hv^l  dx   dx       dy    dy       dz    dz 
we  may  write 


(28) 


+  A 


a^«« 


di?   dv 


d^      dv  dv 


6*t*     3^y  dv 


dx'dy  dx  dy      dy-dz  dy  dz      dz-dx  dz  dx 
A«*|dAd-2^  dx'dv)       dy\dy         dy' bv ) 


dz  \  d;^  62?    dv 


(29) 


^   ^      _      1       (  d^w  dw  dv       d^u  dw  dv      d^u  dw  dv 
^'"^'''^'^h7hJ'\d^'d^'^xW''dy'Vy^ 


+ 


1         (     dr^u   fdiv  dv      dw  dv\        d^u   f  dw  dv     dw  dv\ 
'^•kj^  \  dx'dy\dy    dx     dx   dy ) ^     dy-dzydz   dy     dy    dz ) 
d^u    fdw  dv      dw  dv\ 
dx'dz\dz    dx      dx    dz) 
duYd^v   dw 


.      d^v     dw  ,       dv      dw\ 
+  ^ — ^'"T"  +  - — ^-  I 


^v^  •  ^*  I  dx\dxr^  dx    '  dydx   dy    '   dxdz    dz  J 

^  ^  du  dvfdhv  dw      dho  dw^      dh^  dw\  ) 
hf,  dx  dx\dx    dx       dy    dy       dz    dz  J  ) 


hJ  •  hu 


idufd^v  dw        d^v 
dy\dy^' dy       dz-d^ 


dw 


dv 


'dy   dz       dydx 

2    du  dvfdho  dw      dth  ^^  i   ^^^  dw\  | 
Ih  dy  dy\dy    dy       dz    dz       dx    dx  J  ) 


i 


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PEIRCE.  —  DERIVATIVE   OP   A   SCALAR   POINT   FUNCTION.      351 

dv 


1h' 


'hu,^\dz\dz^'  dz  "^  dX'dz'  dx      dz'dy'  dy) 


2_  du  dv^dhp  ^w      aA^  dw      dh^  dw\  )         .     . 
ho  dz  dz\dz    dz        dx   dx       dy    dy  J  J         ^    ^ 


It  is  evident  that  DvDu,u  is  asually  quite  different  from  DwD^u. 


In  the  transfonnation  of  a  partial  differential  equation  from  one  set  of 
independent  variables  to  another  set  which  does  not  form  an  orthogonal 
system;  derivatives  occur  which  are  not  normal  in  the  sense  of  the  last 
paragraphs.  If  a  mass  of  fluid  is  in  motion  under  the  action  of  given 
forces,  it  is  usually  convenient  either  to  express  the  orthogonal  coordi- 
nates of  a  particle  which  at  the  time  t  has  the  position  {xy  y^  z)  in  terms 
of  t  and  the  coordinates  x^,  y^^  z^  which  the  same  particle  had  at  the 
origin  of  time,  or  to  express  Xf^y  y^  z^  as  functions  of  .r,  y,  z^  t 

^0  =/i  (^»  y.  ^»  0>  yo  =/«  (^1  y» «» 0.   ^o=/8(a,y, «,  0-  (3i) 

In  this  case,  it  fi^uently  happens  that  the  level  surfiwjes  of /i,/j,/g, 
are  not  orthogonal.  According  as  we  use  the  " historical"  or  the  "sta- 
tistical "  method  of  studjdng  the  motion,  we  shall  express  the  pressure 
and  the  density  in  terms  of  Xq,  y^,  z^^  t,  or  in  terms  of  x,  y,  z,  t  Sup- 
pose the  second  method  to  have  been  chosen,  and  dp /dx  to  have 
been  found  by  the  aid  of  Euler's  Equations  of  Motion  and  the  Equation 
of  Continuity,  and  suppose  that  dp  /  dx^  is  needed.    We  shall  then  have 


dp  __dp   dx       dp   dy       dp   dz 
dXQ      dx  dxQ      dy  dx^      dz  dx^' 

If  with  the  help  of  (31)  we  find  the  values  of  the  determinants 


(32) 


X  = 


dy  dz 

dzo  dz^ 
dy  dz 

,  M  = 

dz  dx 

dZn  dZo 
dz  dx 

,  N  = 

dx  dy 

dZo  dZo 
dx  dy 

(33) 


and  put 


Q 


■  L-'^  +  M-'p  +  N 


d^ 
> 


dz' 


IP  =  L*  +  JIP  +  IP, 


Digitized  byLaOOQlC 


352  PBOCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

we  may  write  the  results  of  differentiating  all  the  equations  of  (31) 
with  respect  to  x^  y^  z^  in  the  form 


so  that 


dp  _Bdx       Rdy  "^  R' dz 
Bdx  "^  Rdy  '^  Rdz 


(34) 


(35) 


and  this  is  evidently  equal  to  (9),  the  ratio  of  the  directional  deriva- 
tives  of  ^  and  Xq  taken  in  the  direction  (s)  in  the  (x,  y,  z)  space  in  which 
both  ^0  a>nd  z^  are  constant  If  (Sy  p\  (s,  x)  represent  the  angles  between 
8  and  the  directions  of  the  gradient  vectors  of  ^  and  x  respectively, 

dp^  ^  hp'008(s,p)  . 

dxo     Aa^-cos(«,  ;ro)'  ^    ^ 

It  is  convenient,  therefore,  to  define  the  derivative  of  a  scalar  point 
function,  u,  with  respect  to  another  scalar  point  function,  t?,  at  any 
given  point  in  any  direction  (s),  as  the  ratio  of  the  directional  deriva- 
tives of  u  and  v  taken  at  the  point  in  the  direction  8. 

Derivatives  of  this  kind  which  irequently  appear  in  two  dimensional 
problems  in  Thermodynamics  and  in  Hydrokinematics,  usually  involve, 
as  has  been  said,  a  transformation  firom  one  set  of  coordinates  to  an- 
other which  is  not  orthogonal 

Jeffebson  Physical  Laboratobt, 
Cambbidoe,  Mass. 
December,  1909. 


Digitized  by  VjOOQI^ 


Proceedings  of  the  American  Academy  of  Arts  and  Sciences. 
Vol.  XLV.  No.  13.— April,  1910. 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 


THE  EFFECT  OF  LEAKAGE  AT  THE  EDGES  UPON 
THE  TEMPERATURES  WITHIN  A  HOMOGENEOUS 
LAMINA  THROUGH  WHICH  HEAT  IS  BEING 
CONDUCTED. 


Bt  B.  Osgood  Peircb. 


Digitized  by  VjOOQIC 


Digitized  by  ^OOSl^ 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 

THE  EFFECT  OF  LEAKAGE  AT  THE  EDGES  UPON  THE 
TEMPERATURES  WITHIN  A  HOMOGENEOUS  LAMINA 
THE0U6H  WHICH  HEAT  IS  BEING  CONDUCTED. 

By  B.  Osgood  Peibce. 
Presented  December  8,  1909.    Received  January  6*  1910. 

In  many  of  the  determinatioDS  of  thermal  conductiyity  which  have 
been  made  during  the  last  few  years,  the  so  called  '*  wall  method  "  has 
been  employed.  That  is,  one  &ce  of  a  plate  or  wall  of  the  material  to 
be  experimented  upon  has  been  kept  at  one  constant  temperature  for 
a  long  time  while  the  opposite  Hb^cq  has  been  maintained  at  another 
constant  temperature,  and  the  quantity  of  heat  per  square  centimeter 
of  either  £ace,  which  under  these  circumstances  has  passed  per  second 
from  one  face  to  the  other,  has  been  measured  in  some  convenient 
way. 

In  practice  such  a  plate  is  of  limited  dimensions,  and  although  it  is 
easy  to  insure  that  the  temperatures  of  the  &ces  shall  be  nearly  uni- 
form, it  is  comparatively  difficult  to  maintain  a  steady  gradient  from 
face  to  face  at  the  edges  so  that  the  heat  flow  within  the  slab  shall  be 
the  same  as  if  the  faces  were  infinite  in  extent.  If,  however,  the  hces 
of  the  specimen  to  be  used  are  small  enough,  it  is  possible  to  prevent 
almost  entirely  the  escape  of  heat  at  the  edges  by  surrounding  the 
periphery  by  an  arrangement  like  a  Dewar  flask.  This  is  impracticable 
when  for  any  reason  the  plate  has  to  be  large,  and  in  this  case  it  is 
necessary  to  make  the  thickness  of  the  wall  so  small  compared  with  the 
dimensions  of  the  faces  that  the  lines  of  flow  of  heat  from  face  to  face 
in  the  central  portion  of  the  slab  shall  not  be  appreciably  distorted  by 
loss  of  heat  through  the  edges  of  the  wall. 

Some  time  ago,  in  an  attempt  to  obtain  an  accurate  average  value 
of  the  conductivity  of  a  given  stratum  in  a  certain  deep  mine,  I  had 
occasion  to  apply  the  wall  method  to  some  blocks  of  stone  which  were 
not  perfectly  homogeneous,  and  in  order  to  represent  the  material  feirly 
it  seemed  best  to  use  a  slab  eight  centimeters  thick  for  each  determina- 
tion.   The  slabs  were  square  and  the  edges  were  covered  with  lagging 


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356  PBOCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 

to  make  the  loss  of  heat  through  them  as  small  as  possibla  Under 
these  circamstanoes  there  waa  a  very  rough  approximation  to  a  uniform 
temperature  gradient  from  the  warm  &ce  to  the  cold  one,  at  each  edge, 
but  it  waa  difficult  to  measure  the  edge  temperatures  accurately  and  the 
areas  of  the  hoea  were  therefore  made  so  large  that  the  temperatures  of 
points  on  the  axis  of  the  slab  (that  is,  the  line  which  joins  the  centres 
of  the  &ces)  would  surely  be  tiie  same  within  one  one  hundredth  of  a 
degree  of  the  centigrade  scale,  in  the  final  state,  whether  the  whole  of 
each  edge  waa  kept  at  the  temperature  of  the  warmer  &ce  or  at  the 
temperature  of  the  colder  face. 

In  anticipation  of  some  further  work  of  the  same  kind,  I  have  been 
led  to  compute  the  final  axial  temperatures  in  a  square  slab  (axax  c) 
of  thickness  c,  when  one  boQ  is  kept  at  temperature  To  while  the  other 
boQ  and  all  the  edges  are  kept  at  the  lower  temperature  Ti,  The  work 
is  straightforward  enough,  but  the  computation  when  the  slab  is  rela- 
tively broad  is  very  laborious,  and  in  view  of  the  practical  importance 
of  the  wall  method  in  determinations  of  the  conductivities  of  poor  con- 
ductors of  heat,  it  seems  well  to  record  some  of  the  results. 

The  problem  just  stated  is  solved  (7\  -  WTi  +  WT^)  whai  one 
has  found  ^  a  solution  (W)  of  the  equation 

which  is  equal  to  unity  when  2;  =  0,  and  to  zero  when  2;  =  c  for  all 
positive  values  of  a  and  y  not  greater  than  a ;  and  which  vanishes 
when  a?  =  0,  or  y  =  0,  or  ;r  =  a,  or  y  =  a,  for  all  positive  values  of  z 
not  greater  than  c, 
A  convenient  normal  solution  of  (1)  is 

-4(e"  —  e     "     )8m sm---^,  (2) 

where  Ar*  =  tn'  +  n^  and  it  is  evident  that 

m-oDn^  .          16              .  ,  irk(c-z)  .    mwx    .     nwy\    ,«. 

^   2( F'®      — ^ — ^° — ^1   ^^ 

m- 1  n- 1  KTr^mn  siuh  —  / 
a 

where  m  and  n  are  odd  integers. 

*  Byerly,  Fourier's  series,  etc.,  p.  127. 


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PEIRCE.  —  TEMPERATUBES   WITHIN   A   HOMOGENEOUS    LAMINA.      357 

The  fonction 


r=l-W(a^,y,e-z), 


(4) 


which  satisfies  (1),  is  eqaal  to  unity  when  2;  =  0,  and  also  for  all  posi- 
tive values  of  z  not  greater  than  c,  when  a?  =  0,  or  y  =  0,  or  ar  =  a,  or 
y  =  a.    It  vanishes  when  z  =  c,  and  the  function 


or 


u=Ti-w(r-To)-  r(Ti  -  r)  (5) 

r-W(a:,y,z)-{r^To)+W{x,y,c^z)^(Ti-r)      (6) 
gives  the  temperatures  in  the  slab  if  one  &ce  is  kept  at  the  temperature 

TABLE  I. 


a 

W 

ic 

0.014 

ic 

1.176 

ic 

6.720 

ic 

9.833 

c 

16.666 

fc 

31.570 

2c 

40.708 

.      3c 

47.556 

5c 

49.905 

7oi  the  other  fSsu^  at  7i,  and  the  edges  at  7^.  In  an  infinite  slab  of 
thickness  c,  the  &ces  of  which  are  kept  at  To  and  7\,  the  temperatures 
are  given  by  the  expression 


£roo=(7\-ro)-+7i 


(7) 


so  that  the  difference  between  the  values  of  the  temperature  at  any 
point  in  the  slab  in  the  ideal  case  and  the  real  case  is 

iTr-n)[l-W(x,y,e'-z)]+(r-To)[W{x,!,,z)+W(x,if,e-z)-l]. 

(8) 


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358 


PROCEEDINGS  OP  THE  AMERICAN  ACADEBIY. 


The  last  fector  of  this  expression  has  its  maximum  yalae  at  the 
middle  point  of  the  axis  where  z^ic. 


p 

^TiT^ 

/ 

/ 

/ 

/ 

,   0 

\          > 

I 

B           C 

^        1 

) 

Figure  1.  The  ordinates  of  the  curve  show  the  temperatures,  for  dif- 
ferent values  of  a,  of  a  point  Q  in  the  centre  of  the  axis  (C^)  of  a  square  slab 
(a  X  a  X  c)  of  given  thickness  c,  when  one  face  (a  X  a)  is  kept  at  the  tem- 
perature 100®  while  the  other  face  and  the  edges  are  kept  at  0®,  The  hori- 
zontal unit  is  c,  and  it  appears  that  when  a  =  5  c,  the  temperature  (49.9°  +) 
of  Q  differs  only  slightly  from  the  temperature  (50°)  which  it  would  have  if 
a  were  infinite.  The  shaded  area  above  indicates  the  section  of  the  slab  for 
different  values  of  a. 

The  value  of  W  for  the  centre  of  the  axis  of  the  slab  is  given  for 
several  different  values  of  a  in  Table  I.  When  the  ratio  of  a  to  c  is 
large,  the  double  series  which  defines  W  converges  very  slowly.  Thus 
to  obtain  the  last  number  in  the  table  more  than  one  hundred  and  fifty 
terms  of  the  series  were  needed. 

Figure  1  represents  the  numbers  of  Table  I.  graphically. 

It  is  interesting  to  compare  these  results  with  similar  ones  for  cir- 
cular disks  which  Professor  R  W.  Willson  and  I  obtained  ^  several 
years  ago. 

«  These  Proceedings,  1898,  34,  1. 


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PEIECE. — TEMPERATUBES   WITHIN   A   HOMOGENEOUS   LAMINA.       359 


TABLE   II. 

Final  Axial  Temperatures  in  a  Homogeneous  Disk  op  Diameter  d 
AND  Thickness  c,  when  one  Face  {z  -  0)  is  kept  at  100°  C,  the 
OTHER  Face  (z  «-  c)  at  0°  C,  and  the  Edge  at  the  Uniform  Tem- 
perature 0. 


d/c 

9  C 

0^09 

tf-100° 

«=60° 

14.05 

99.88 

56.95 

1.30 

98.70 

50.00 

0.12 

85.95 

43.03 

42.32 

96.07     . 

69.20 

13.93 

86.07 

50.00 

3.95 

67.68 

30.80 

68.15 

88.83 

73.49 

28.54 

71.46 

50.00 

11.17 

41.85 

26.51 

2 

66.41 

82.86 

74.63 

2 

38.39 

61.61    ^ 

50.00 

2 

17.14 

33.59 

25.36 

3 

72.84 

77.12 

74.98 

3 

46.98 

63.02 

50.00 

3 

22.88 

27.16 

25.02 

4 

74.48 

75.51 

74.99 

4 

49.27 

50.73 

50.00 

4 

24.49 

25.52 

25.01 

6 

74.97 

75.03 

75.00 

6 

49.96 

50.04 

50.00 

6 

24.97 

25.03 

25.00 

10 

75.00 

75.00 

75.00 

10 

50.00 

50.00 

50.00 

10 

25.00 

25.00 

25.00 

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360 


PROCEEDINGS   OF   THE   AMERICAN   ACADEMY. 


FiouRB  2.  The  curves  show  the  final  temperatures  on  the  axis  (OS)  of 
a  circular  disk  of  given  thickness  (c)  and  of  diameter  d,  when  one  face  is  kept 
at  the  temperature  100^  and  the  other  face  and  the  rim  at  0^.  In  A,  B,  C,  D, 
and  E,  the  diameter  has  the  values  ^  c,  c,  f  c,  2  c,  3  c,  respectively. 

Jefferson  Physical  Laboratory, 
Cambridge,  Mass., 
December,  1909. 


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Prooeeding^  of  the  American  Aoademy  of  Arts  and  Sciences. 
Vol.  XLV.  No.  14.— April,  1910. 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 


ON  EVAPORATION  FROM   THE  SURFACE  OF 
A   SOLID   SPHERE. 


Bt  Habbt  W.  Mobsb. 


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Digitized  by' 


[Ik: 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 

ON  EVAPORATION  FROM  THE  SURFACE  OF  A 
SOLD)  SPHERK 

PRELIMINARY  NOTE. 

By  Harby  W.  Morse. 

Presented  by  John  Trowbridge,  Febnury  0, 1010.    Received  January  3,  1010. 

Thb  micro-balance  of  Salvioni  and  Nemst  permits  of  following  small 
changes  in  weight  with  considerable  accaracy,  provided  the  body  nnder 
investigation  has  a  mass  not  greater  than  a  few  milligrams.  This  bal- 
ance consists  merely  of  a  fibre  of  quartz  or  glass,  firmly  held  in  a  nearly 
horizontal  position  by  being  secured  at  one  end,  and  provided  at  the 
other  end  with  some  means  of  attaching  the  object  to  be  weighed.  The 
weight  is  then,  within  quite  wide  limits  of  deflection,  proportional  to 
the  deflection,  and  the  balance  is  easily  calibrated  by  means  of  small 
riders  of  known  weight  Deflections  are  followed  by  means  of  a  cathe- 
tometer  or  a  microscope  with  micrometer  eyepiece.  Differences  of  0.01 
millimeter  or  even  less  are  easily  determined,  and  if  the  fibre  be  so 
chosen  that  a  weight  of  1  milligram  gives  a  deflection  of  about  a  centi- 
meter, there  is  no  difficulty  in  detecting  and  measuring  changes  of 
weight  of  0.001  milligram  or  less. 

With  such  a  balance  the  change  of  weight  of  small  spheres  of  iodine 
has  been  followed  at  approximately  constant  temperature.  Evapora- 
tion was  allowed  to  go  on  in  a  large  box  with  glass  sides,  and  the  two 
side  doors  of  the  case  were  left  open  before  each  series  of  readings  to 
allow  free  circulation  of  air.  It  may  therefore  be  assumed  that  the 
partial  vapor  pressure  of  iodine  in  the  atmosphere  about  the  evaporat- 
ing spheres  was  constant  The  temperature  was  constant  within  about 
0.3<>  during  each  run. 

After  many  attempts  to  obtain  definite  geometrical  form  by  casting, 
&irly  accurate  spheres  were  made  by  pouring  molten  iodine  into  water. 
There  is  no  difficulty  in  obtaining  in  this  way  approximately  spherical 
pieces  with  radii  varying  fix)m  1  millimeter  down  to  0.2  millimeter. 


Digitized  by  LjOOQIC 


364  PBOCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 

It  was  thought  possible  that  there  might  be  a  change  in  the  character 
of  the  surface  as  evaporation  proceeded.  The  spheres  were  hard  on 
the  snrface,  and  quite  smooth  as  they  came  from  the  water,  but  they 
undoubtedly  consist  of  a  mass  of  very  small  irregular  crystals  and  any 
roughening  that  might  appear  during  the  course  of  the  experiment 
would  lead  to  a  considerable  increase  in  suriace.  That  such  changes 
do  not  occur  in  disturbing  amount  is  shown  by  the  feet  that  the  deter- 
minations made  with  small  spheres  fresh  from  formation  fall  accurately 
on  the  curve  of  me&surements  on  spheres  which  have  been  evaporating  ^ 
for  some  hours.  Microscopic  examination  corroborates  this  and  shows 
also  that  the  spherical  shape  is  maintained  practically  unchanged  until 
the  sphere  finally  disappears  completely. 

In  these  experiments  the  spheres  were  supported  on  a  nearly  flat 
scale-pan  of  thin  glass.  This  may  introduce  a  variation  in  the  surface 
exposed  to  the-air,  due  to  difference  in  the  surface  of  contact  between 
sphere  and  glass,  fi|.nd  especially  to  be  expected  if  the  particles  are  not 
closely  spherical.  This  £M3tor  is  also  shown  to  be  negligible  by  the 
closeness  with  which  the  spherical  form  is  kept  during  evaporation  and 
also  by  the  £^t  that  turning  the  particle  over  has  no  measurable  effect 
on  the  rate  of  evaporation. 

Measurements  on  three  spheres  of  different  radii  are  given  below. 

These  observations  are  plotted  in  the  curve  of  Figure  1. 

There  is  plenty  of  evidence  that  in  any  system  made  up  of  smaller 
and  larger  particles  of  the  same  substance,  whether  solid  or  liquid,  the 
smaller  particles  are  relatively  unstable.  So  far,  however,  all  of  our 
knowledge  about  solids  is  of  a  purely  qualitative  nature,  and  no  definite 
relation  has  ever  been  obtained  based  on  vapor  pressure  or  surfistce  ten- 
sion, and  expressing  quantitatively  the  change  of  vapor  pressure  or 
surface  tension  with  change  of  radius.  It  has  been  many  times  noticed 
that,  in  a  sealed  tube  containing  iodine  crystals  of  various  sizes,  the 
larger  crystals  grow  at  the  expense  of  the  smaller  ones,  which  gradually 
disappear.  In  a  few  days  this  can  be  clearly  proved,  and  the  same 
effect  has  been  noticed  for  water  drops  and  for  camphor  and  other 
rather  volatile  substances. 

In  the  case  of  liquids  it  is  possible  to  set  up  a  definite  relation  be- 
tween vapor  pressure  and  curvature  of  drop.  This  has  been  done  for 
water  and  a  few  other  liquids,  and  the  theory  has  been  tested  with  some 
accuracy  by  experiments  on  the  formation  of  fog  by  the  expansion  of 
saturated  water  vapor.  For  water  the  difference  in  vapor  pressure  be- 
tween a  drop  of  radius  0.001  millimeter  and  a  flat  surface  is  of  the 
order  of  0.001  mm.  of  mercury,  so  that  the  effect  becomes  almost  in- 
sensible for  drops  of  any  size. 


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MORSE.  —  EVAPORATION  FROM   THE    SURFACE   OF   A   SPHERE. 


365 


It  was  therefore  ezpeoted  that  any  influence  of  the  size  of  the  particle 
of  iodine  on  the  rate  of  evaporation  would  only  appear  for  very  small 


Sphere  1. 

Sphere  2. 

Sphere  3.       1 

Time. 

Weight. 

Time. 

Weight. 

Time. 

Weight. 

min. 

mgmfl. 

min. 

mgms. 

mm. 

mgms. 

0 

1.880 

20 

1.770 

63 

1.600 

103 

1.420 

131 

1.310 

140 

1.260 

150 

1.210 

169 

1.140 

178 

1.100 

189 

1.050 

187 

1.066 

198 

1.000 

214 

0.955 

295 

0.638 

228 

0.907 

308 

0.590 

247 

0.845 

319 

0.557 

263 

0.759 

335 

0.512 

283 

0.684 

287 

0.668 

358 

0.482 

300 

0.617 

297 

0.635 

381 

0.376 

318 

0.558 

307 

0.603 

438 

0.233 

328 

0.522 

319 

0.558 

456 

0.192 

338 

0.491 

330 

0.525 

468 

0.157 

355 

0.438 

340 

0.503 

484 

0.135 

375 

0.373 

498 

0.104 

390 
456 
466 
476 
486 
496 
506 
521 
531 
536 
542 
548 
554 
560 
576 

0.337 
0.160 
0.147 
0.126 
0.105 
0.087 
0.070 
0.048 
0.036 
0.028 
0.022 
0.017 
0.011 
0.006 
0.000 

spheres  indeed  and  that  for  all  particles  of  sensible  dimensions  the  rate 
would  be  proportional  to  the  surfisK^e,  so  that 

dm      , 
or  since  the  change  in  mass  is  being  followed 


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366 


PBOCEEDINGS  OF  THE  AMERICAN  ACADEMT. 


-S  =  *^"''- 


The  measurements  show  that  this  relation  does  not  hold,  even  for 
spheres  of  radius  0.5  millimeter  or  more.    The  observed  values  do, 


•• 

V 

N 

Vy 

\ 

b 

\ 

\ 

\ 

N 

»v 

N 

^M. 

^ 

^. 

^ 

^ 

Figure   1.    Evaporation  from  small  spheres  of  Iodine.     Small  circles, 
observed  values.    Large  circles,  calculated  values. 

however,  agree  accurately  with  the  assumption  that  the  rate  of  evapora- 
tion is  proportional  to  the  surfieu^e  and  at  the  same  time  inversely  as 
the  radius,  so  that 

dm       J  8               dtn      ,     , 
— Tr  =  A:-    or =-  =  k^mK 

at         r  at 

In  the  figure  the  large  circles  have  been  placed  according  to  the 
formula 


tt-h 


=  K, 


Digitized  by 


.d 


MORSE.  —  EVAPORATION   FROM  THE   SURFACE   OF   A   SPHERE.      367 

and  the  carve  has  been  drawn  through  the  points  thus  determined. 
The  constant  was  calculated  from  the  mean  of  all  the  observations  and 
shows  a  probable  error  of  a  little  less  than  0.5  per  cent  The  results 
of  the  observations  are  given  as  smaller  circles.  In  putting  in  the  re- 
sults for  the  smaller  spheres  or  for  those  in  which  a  full  run  down  to 
zero  of  weight  was  not  carried  out^  the  original  value  of  the  mass  of  the 
sphere  was  placed  on  the  curve  and  the  times  of  the  other  observations 
on  the  same  sphere  were  taken  from  this  point  It  is  very  probable 
that  this  method  of  choosing  the  highest  weight  has  somewhat  decreased 
the  accuracy  of  the  calculated  constant,  for  it  has  been  invariably  ob- 
served that  a  measurable  time  elapses  before  a  sphere  &lls  into  its 
regular  rate  of  evaporation.  It  begins  slowly,  sometimes  at  not  more 
than  half  its  fall  rate,  and  several  minutes  elapse  before  it  reaches  its 
maximum  valua  It  is  probable  that  better  agreement  would  have 
been  obtained  if  a  point  &rther  along  in  the  observations  had  been 
chosen  and  calculations  made  in  both  directions  from  this. 

It  seems  clear  that  for  spheres  of  iodine  of  mass  ranging  from  2  milli- 
grams to  very  small  values,  the  rate  of  evaporation  is  quite  accurately 
proportional  to  the  rcidivs. 

Before  taking  up  any  theory  of  this  surprising  result  it  will  be  best 
to  have  data  on  evaporation  from  masses  having  other  geometrical 
shapes,  and  especially  for  a  flat  sur£gM)e.  It  is  expected  that  data  on 
these  points  will  be  presented  to  the  Academy  in  the  near  future. 

Jeffebson  Physical  LAboratobT| 
Cambridge,  Mass., 

December,  1909. 


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Digitized  by  ^ 


Proceedings  of  the  American  Academy  of  Arts  and  Sciences. 
Vol.  XLV.  No.  16.— April,  1910. 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 


SOME  MINUTE  PHENOMENA   OF  ELECTROLYSIS. 


Bt  Harry  W.  Morse. 


Digitized  by 


G^og 


le 


Digitized  by  VjOOQlf 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,   HARVARD  UNIVERSITY. 

SOME  MINUTE  PHENOMENA  OF  ELECTROLYSIS. 

By  Harrt  W.  Morse. 
Presented  by  John  Trowbridge,  December  8,  1909.    Received  January  6,  1910. 

As  the  process  of  electrolysis  is  usually  carried  out  there  is  very 
little  opportunity  to  get  any  insight  into  its  more  minute  mechanism. 
We  are  accustomed  to  think  of  each  metal  by  having  its  own  solution 
pressure,  and  by  this  we  mean  that  it  tends  to  go  into  solution  under 
an  impetus  which  varies  with  its  position  in  the  electro-motive  force 
series.  It  is  possible  to  calculate  an  osmotic  pressure  which  would  be 
just  sufficient  to  balance  this  solution  pressure  and  which  would,  if 
applied,  cause  equilibrium  at  the  electrode.  Under  ordinary  condi- 
tions electrochemical  reactions  are  quite  perfectly  coupled.  Equiva- 
lent amounts  are  dissolved  at  the  anode  and  precipitated  at  the 
kathode,  and  it  is  not  infrequent  to  state  Faraday's  Law  in  terms  of 
the  amounts  thus  dissolved  and  precipitated.  But  cases  are  well 
known  where  much  more  care  must  be  taken  in  the  statement  of  this 
law,  as  for  example,  where  the  air  enters  into  reaction  with  one  or  both 
of  the  electrodes,  or  where  the  electroljrte  itself  attacks  them.  Very 
frequently  a  reaction  of  the  form 

M++  +  Mmeta|l=^2M+ 

causes  a  loss  or  gain  not  proportional  to  the  amount  of  current  which 
has  passed  through  the  electrolytic  cell. 

In  the  case  of  silver  electrodes  in  a  solution  of  silver  nitrate  it  is 
usual  to  sum  up  the  process  as  follows:  — 

During  any  unit  of  time  after  the  circuit  is  closed 

(1)  An  equivalent  amount  of  silver  dissolves  at  the  anode. 

(2)  Silver  migrates  (as  silver  ion)  toward  the  kathode  and  nitrate 
ion  migrates  toward  the  anode,  each  carrying  its  share  of  the  current 
in  proportion  to  its  migration  velocity. 

(3)  An  equivalent  amount  of  silver  separates  as  metal  at  the 
kathode. 


I 


Digitized 


..iisogle 


372  PBOCEEDINOS  OF  THE  AMERICAN  ACADEMY. 

In  the  case  of  silver  electrodes  in  pure  water  we  might  expect  daring 
each  unit  of  time  : 

(1)  At  the  anode,  the  formation  of  oxygen,  or  an  oxide  of  silver,  or 
the  solution  of  silver,  the  sum  total  making  one  equivalent. 

(2)  The  transfer  of  hydrogen  ion  (and  later  of  silver  ion  if  this  is 
formed)  toward  the  kathode,  and  of  either  or  both  of  the  ions  0"^  and 
OH"  toward  the  anode. 

(3)  At  the  kathode,  evolution  of  hydrogen,  and  later  precipitation 
of  metallic  silver,  the  two  together  making  up  one  equivalent 

A  case  has  recently  come  to  my  attention  in  which  some  of  the 
more  minute  phenomena  which  accompany  electrolysis  are  evident  and 
in  which  lack  of  equivalence  at  the  electrodes  is  especially  evident  So 
far  only  qualitative  observations  have  been  made,  but  the  data  secured 
seem  worthy  of  consideration. 


r//////////////A 


Figure  1.  Electrolysis  on  microscopic  slide  between  silver  electrodes. 

If  pure  water  be  electrolysed  between  small  silver  electrodes  at  vol- 
tages ranging  from  1.40  to  about  3.8  volts,  and  the  space  between  and 
about  the  electrodes  be  observed  under  the  microscope  with  powers  of 
50  or  so,  the  following  series  of  minute  phenomena  are  visible  :  — 

(1)  A  very  short  time  after  the  circuit  is  closed  a  cloud  of  brownish 
particles,  very  small  and  in  viplent  Brownian  movement,  is  formed  in 
the  neighborhood  of  the  anode.  If  silver  foil  is  used  as  anode  it  can 
be  seen  to  dissolve  rapidly  and  a  dark  film  of  silver  oxide  remains. 
The  particles  first  make  their  appearance  at  a  slight  distance  from  the 
anode,  and  appear  to  be  due  to  the  formation  of  a  silver  compound 
produced  firom  the  silver  which  has  dissolved  and  one  of  the  constitu- 
ents of  the  water. 

(2)  This  cloud  consists  of  approximately  spherical  particles  of  diam- 
eter 0.3  to  1.0  mikron.  It  is  readily  soluble  in  very  dilute  acetic  acid 
and  slightly  soluble  in  water,  forming  an  alkaline  solution.  The  par- 
ticles appear  to  be  silver  oxide. 

(3)  If  a  cell  of  form  similar  to  that  shown  in  Figure  1  is  used  for  the 
electrolysis,  the  particles  move  along  the  floor  of  the  cell  toward  the 
kathoda  During  their  migration  toward  the  kathode  they  follow 
the  current  lines,  and  Figure  2  shows  drawings  made  about  half  a 
minute  apart)  indicating  the  general  appearance  under  a  low  magni- 
fying power.    The  masses  which  move  in  this  way  are  not  the  single 


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MORSE.  —  SOME   MINUTE   PHENOMENA    OP    ELECTROLYSIS.       373 

particles,  which  would  not  be  visible  at  this  magnification,  but  are 
clumps  each  containing  a  great  many  individual  grains. 

(4)  While  the  above  is  occurring  in  the  neighborhood  of  the  anode 
a  thin  cloud  of  totaUy  different  appearance  may  appear  about  the 
kathoda  The  particles  of  this  cloud  are  metallic  in  appearance,  and 
they  later  disappear  suddenly  and  completely  when  the  growth  of 
metallic  silver  begins  at  the  front  of  the  kathoda  The  kathode  cloud 
seems  to  be  effected  by  external  conditions  in  greater  degree  than  that 


3. 


¥. 


Figure  2.  Minute  phenomena  of  electrolysis  between  silver  electrodes. 

from  the  anode.  It  is  a  function  of  the  separation  of  the  electrodes 
and  the  character  of  the  kathode  surfstce. 

(5)  The  above  described  effects  appear  in  the  purest  obtainable 
water  and  they  are  most  evident  in  the  best  conductivity  water,  which 
has  been  recently  prepared  in  quartz  vessels  and  kept  carefully 'from 
contact  with  air. 

Electrolytes  in  very  small  concentration  prevent  the  effect  completely 
and  cause  the  appearance  of  the  usual  gas  bubbles  at  the  anode  and 
kathoda  The  foUowing  brief  table  shows  how  a  few  electrolytes 
behave  in  this  respect 


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374  PROCEEDINGS   OF   THE   AMERICAN   ACADEMY. 


Sodium  Hydroxide  0.015    iV^ 
.020    N 

Cloud. 

very  slight  cloud  and  bubbles 

above  .020    N 
Sodinm  Chloride     0.0005  N 

.001    N 
above  .001    N 

at  aUuUC. 

Only  bubbles  at  anoda 

brown  cloud,  soluble  in  drop  of 

acetic  acid. 

brown  1  ^^Iq^ jg  brown  soluble 

white  J             white  insoluble 

white  cloud  only. 

(6)  While  the  above  effects  are  making  their  appearance  in  the 
electrol3rte  at  slight  distances  from  the  electrodes  nothing  whatever 
happens  at  the  kathode  itself.  The  space  between  the  electrodes  may 
be  active  for  several  minutes  without  the  appearance  of  either  a 
bubble  of  gas  or  a  crystal  of  silver.  If  very  thin  silver  foil  is  used  for 
electrodes  solvent  action  on  the  anode  is  very  evident  and  it  is  rapidly 
dissolved.  A  thin  silver  foil  kathode  shows  signs  of  dissolving  at  the 
edges  during  the  first  minute  or  so  of  the  passage  of  the  current,  but 
the  action  ceases  immediately. 

(7)  There  seems  to  be  a  limiting  voltage  below  which  these  phe- 
nomena do  not  make  their  appearance.  This  is  very  close  to  1.41 
volts  for  electrodes  1  mm.  apart.  The  upper  limit  of  voltage,  above 
which  gas  appears  at  the  electrodes,  is  about  3.8  volts. 

(8)  Even  in  purest  distilled  water  the  phenomena  are  much  more 
complicated  than  those  so  far  described.  The  anode  and  kathode 
clouds  are  quite  different  in  their  behavior.  That  from  the  kathode 
appears  to  be  composed  of  particles  shot  off  at  random,  and  these 
particles  do  not  take  any  definite  path  after  leaving  the  neighborhood 
of  their  parent  electrode.  The  anode  cloud,  on  the  contrary,  sticks 
closely  together,  and  if  the  electrodes  are  at  the  mouth  of  a  deep  test- 
tube  filled  with  water  the  anode  cloud  travels  to  the  very  bottom  of 
the  tube  in  such  close  coherence  that  it  looks  like  a  thin  brown  thread. 

(9)  The  effect  of  a  magnetic  field  on  the  behavior  of  these  particles 
has  been  tried  without  definite  result  They  are  relatively  so  large, 
and  they  move  so  slowly  that  an  effect  is  hardly  to  be  anticipated. 

Attempt  has  been  made  to  follow  the  changes  in  weight  at  each 
electrode  during  the  electrolysis.  The  micro-balance  was  adapted  for 
this  purpose  as  shown  in  Figure  3.  It  is  of  course  quite  impossible  to 
use  any  arrangement  in  which  a  fibre  passes  through  the  liquid  sur- 
face. The  effect  of  surface  tension  is  far  too  great.  But  by  placing 
both  fibres  and  conducting  wires  under  the  sur&ce  of  the  electrol)rte 


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MORSE.  —  SOME   MINUTE    PHENOMENA   OF   ELECTBOLTSIS.       375 

the  difficulty  is  easily  overcome.  The  balance  loses  but  a  small  per- 
centage of  its  sensitiveness  when  used  with  a  heavy  metal  like  silver 
or  copper.         , 

The  fibres  used  were  of  quartz  and  about  8  cm.  long.  The  conduct- 
ing wires  were  of  platinum  about  0.04  mm.  in  diameter,  and  these  were 
welded  to  small  pieces  of  silver  wire  and  held  fast  in  hooks  at  the  end 
of  the  fibres,  so  that  the  silver  electrodes  were  presented  to  each  other 
at  a  distance  of  about  1.5  mm.  The  sensitiveness  was  such  that  a 
0.1  mg.  rider  at  the  end  of  either  fibre  caused  a  deflection  of  more 
than  a  centimeter.    One  of  the  Qaxge)  divisions  of  the  micrometer 


Figure  3.  Biicrocoulometer. 

eyepiece  of  the  observing  microscope  corresponds  to  a  change  in  weight 
of  about  0.0001  mg.,  and  a  fraction  of  a  division  is  easily  read. 

With  this  instrument  the  following  qualitative  changes  were 
noticed. 

(1)  Immediately  on  closing  the  circuit  a  very  slight  decrease  in  the 
weight  of  each  electrode.  This  change  was  observed  in  four  of  six 
experiments  and  must  therefore  be  classed  as  doubtful  until  further 
proof  is  obtained  of  its  correctness. 

(2)  Thereafter  for  several  minutes  an  increase  in  the  weight  of  each 
electrode,  the  anode  gaining  much  fetster  than  the  kathode.  This 
effect  is  quite  certain  and  considerabla  It  is  accompanied  by  a 
change  in  color  at  the  anode,  which  turns  dark,  and  probably  repre- 
sents the  formation  of  silver  oxide  or  peroxide.'  The  increase  in 
weight  at  the  kathode  is  seen  to  be  due  to  the  deposition  of  silver. 

(3)  From  then  on  decrease  in  weight  at  the  anode,  and  increase  at 
the  kathode,  finally  approaching  proportionality. 

The  most  important  point  which  has  been  brought  out  in  this  pre- 
liminary exploration  seems  to  be  that  of  the  complete  lack  of  equiva- 


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376  PBOCEEDINGS  OF  THE  ABiEBICAN  ACADEMY. 

lence  at  the  two  electrodes.  As  observed  under  a  high  power,  the 
entire  anode  may  be  eaten  away,  and  the  eleotroljrte  space  filled  with 
masses  of  silver  oxide,  in  some  cases  without  a  visible  change  at  the 
kathode.  Not  even  a  bubble  of  gas  makes  its  appearanca  If  plati- 
num is  used  as  kathode  in  place  of  silver,  not  the  smaUest  amount  of 
current  can  be  sent  through  the  ceU  without  the  appearance  of  streams 
of  minute  bubbles. 

Jefferson  Physical  Laboratory, 
CAMBRmoE,  Mass., 
December,  1909. 


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Proceedings  of  the  American  Academy  of  Arts  and  Sciences. 
Vol.  XLV.  No.  16. —  May,  1910. 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 


AIR  RESISTANCE   TO  FALLING  INCH  SPHERES. 


Bt  Edwin  H.  Hall. 


/ 

/ 


^''- 


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CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 

AIR  RESISTANCE  TO  FALLING  INCH  SPHERES. 

By  Edwin  H.  Hall. 

Presented  Januazy  12,  1910;  Received  January  12,  1910. 

In  1903  ^  I  published  an  account  of  experiments  which  I  had  made 
with  &lling  bronze  spheres,  one  inch  in  diameter,  in  the  tower  of  the 
JeflFerson  Physical  Laboratory.  The  especial  object  of  these  experi- 
ments was  to  look  for  a  southerly  deviation,  from  the  plumb  line 
vertical,  of  the  course  of  the  falling  balls,  several  observers,  from  the 
time  of  Hooke,  1680,  to  Rundell,  1848,  having  reported  finding 
such  a  deviation,  though  Gauss  and  Laplace,  both  of  whom  discussed 
the  matter  theoretically  about  1803,  could  find  no  cause  for  the 
phenomenon. 

The  general  mean  of  the  deviations  observed  by  myself  in  the 
north  and  south  plane  in  the  experiments  referred  to,  experiments 
much  more  careful  and  extensive  than  those  which  any  one  else  had 
made  in  this  matter,  was  a  southerly  movement  of  about  0.005  cm.  in 
a  fall  of  about  23  m.  The  probable  error  was  about  0.004  cm.,  and  I 
should  have  regarded  the  case  as  practically  closed  in  favor  of  the 
negative  if  my  predecessors  had  not^  almost  without  exception,  reported 
a  considerable  southerly  excursion.  On  the  whole  I  was  disposed  to 
try  the  question  further,  and  accordingly  applied  in  1904  for  permis- 
sion to  make  experiments  for  this  purpose  in  the  great  monument  at 
Washington,  D.  C,  where  a  sheer  fall  of  about  165  m.  is  possible. 
The  monument  is  in  the  care  of  the  War  Department,  and  at  first  the 
authorities  applied  to  acted  favorably  upon  my  petition.  A  few  months 
later,  and  before  I  had  made  any  overt  preparations  for  the  work  pro- 
posed, some  change  of  management  or  of  mind  occurred  in  the  Depart- 
ment, and  the  permission  previously  granted  me  was  courteously  but 
firmly  withdrawn,  "  for  the  reason  that  the  monument  was  designed 
as  a  memorial  to  General  Washington."    I  have  long  since  come  to 

*  Physical  Review,  1903,  17,  179  and  245;  These  Proceedings,  1904,  39, 
339. 


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380  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

the  conclusion  that  this  action  was  a  fortunate  one  for  me,  as  the 
investigation  would  certainly  have  been  tedious  and  expensive  and 
would  probably  have  been  inconclusive. 

But  the  easterly  deviation  also  was,  incidentally,  measured  in  my 
experiments  at  the  Jefferson  Laboratory,  and  the  general  mean  value 
found  for  it  was  0.149  cm.,  whereas  the  value  given  by  the  theoretical 
formula, 

y  =  ^gucoak  X  ^, 

where  u  is  the  angular  velocity  of  the  earth's  rotation,  A.  is  the  latitude, 
and  t  is  the  time  of  fall  in  seconds,  is  0.177  ^  cm.  for  the  case  in 
hand.  The  probable  error  of  the  observed  general  mean  is  perhaps 
greater  than  that  for  the  southerly  deviation,  but  is  not  great  enough 
to  account  for  the  difference  between  the  observed  and  the  theoretical 
easterly  value.  I  did  not  give  in  any  of  my  previous  papers  on  this 
subject  the  formula  of  Gauss  or  that  of  Laplace  for  the  easterly  devia- 
tion of  a  body  &lling  in  air,  though  I  had  given  considerable  attention 
to  their  treatment  of  the  effect  of  air  resistance,  but  closed  my  discus- 
sion of  the  matter  thus  :  "  The  mean  eastetly  deviation  actually  found 
in  these  experiments,  0.149  cm.,  differs  0.03  om.  firom  this  theoretical 
value,  — a  quantity  too  large  to  be  accounted  for  by  the  resistance  of 
the  air.  I  attach  but  little  significance  to  this  discrepancy,  as  the  con- 
ditions for  determining  the  easterly  deviation  in  my  work  were  plainly 
not  so  good  as  those  for  determining  the  southerly  deviation." 

Thus  the  matter  stood  till  last  April,  when  I  received  from  Professor 
Hagen  of  the  Vaticana  Specola  Astronomica  the  suggestion  that  I  should 
make  some  experiments  to  find  out  how  much  the  resistance  of  the  air 
really  amounted  to,  in  order  to  see  whether  it  might  not  after  all  go 
some  distance  toward  explaining  the  discrepancy  between  the  observed 
and  the  calculated  easterly  deviation.  Father  Hagen  puts  the  state- 
ment of  Gauss  concerning  the  effect  of  air  resistance  so  clearly,  that  I 
shall  copy  his  words,  changing,  however,  the  nomenclature  slightly. 
He  writes : 

''  Gauss  puts  the  height  of  the  fall,  determined  by  linear  measure, 
=/  and  igt^=/+  ^,  determined  from  the  observed  time  of  the  fisJL 
The  difference  S  is  owing  to  the  resistance  of  the  air.    Then 

Deviation  y  =  |  cos  \ut  (/  —  ^  8)." 

It  was  easy  to  carry  out  the  suggestion  thus  given,  and  accordingly 
in  October  I  reestablished  the  releasing  part  of  my  apparatus  at  the  top 

*  I  have  given  this  previously  as  0.179,  but  0.177  is  more  nearly  correct. 


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HALL.  —  AIB   RESISTANCE   TO  FALLING    INCH   SPHERES.        381 

of  the  Laboratory  tower  and  had  a  new  cloth  tube  suspended  for  the 
balls  to  drop  througL  This  tube,  like  the  old  one,  which  had  wasted 
away,  was  about  35  cm.  in  diameter,  and  the  balls  fell  along  its  axis. 

At  the  bottom  of  the  tower  the  receiving  apparatus  was  n6w  a  hori- 
zontal plate  of  brass,  £si.stened  at  one  end  but  free  at  the  other,  so  as 
to  be  capable  of  up  and  down  motion.  Near  the  free  end  of  this  plate 
a  square  hole,  about  5  cm.  on  each  side,  was  cut  Over  this  hole  was 
placed  in  some  cases  a  sheet  of  lead  somewhat  narrower  than  the  hole 
but  long  enough  to  be  clamped  fAst  to  the  brass  plate  at  each  end. 
Later  a  thin  sheet  of  wood  was  placed  over  the  hole  before  each  &11. 
In  either  case  the  ball,  after  falling  from  the  top  of  the  tower,  would 
strike  the  cover  of  the  hole  and  break  through  it,  the  first  shock  of  its 
impact  pulling  the  brass  plate  down  &r  enough  to  break  the  contact 
which  made  part  of  an  electrical  circuit  including  a  chronograph.  At 
the  top  of  the  tower  the  release  of  the  ball  broke  the  same  electrical 
circuit,  which  was,  however,  closed  a  fraction  of  a  second  later.  It 
is  hardly  necessary  to  give  further  details  of  the  apparatus  except 
this,  that  the  chronograph,  which  was  driven  by  an  electric  motor  at 
the  rate  of  about  3  cm.  per  second,  was  not  under  the  best  of  control, 
and  it  was  accordingly  necessary  to  make  a  greater  number  of  trials 
than  would  otherwise  have  been  required  in  order  to  determine  the 
time  of  fall  with  sufficient  accuracy.  It  should  be  added  that  the  rate 
of  the  clock  giving  the  second  signals  at  the  chronograph  was  not  very 
accurately  known,  as  it  varied  somewhat  from  day  to  day,  probably 
because  of  changes  of  temperatura  Its  error  may  have  been  as  much 
as  half  a  minute  per  day,  but  was  probably  less  than  this.  An  error 
of  this  magnitude  is  not  serious  for  our  present  purpose,  and  the  clock 
was  in  my  calculations  assumed  to  be  correct. 

On  the  16th  of  October  17  balls  were  dropped  with  such  success  as 
to  give  usable  records.  The  mean  time  of  fall  was  2.176  seconds,  with 
a  probable  error  about  0.002  second. 

On  the  25th  of  October  I  made  another  series  of  trials,  dispensing 
with  the  protecting  cloth  tube.  In  this  series  records  were  obtained 
from  15  balls,  the  mean  time  of  &11  being  2.174  seconds,  with  a  prob- 
able error  about  0.004  second.  It  appears,  then,  that  the  presence  of 
the  tube  has  little  if  any  influence  on  the  time  of  fell. 

The  latitude  of  Cambridge  being  42°  22',  very  nearly,  and  the  eleva- 
tion above  sea  level  very  slight,  we  find  that,  according  to  the  general 
formula  for  ^  as  a  fiinction  of  X,  its  value  here  is,  to  the  first  decimal 
place,  980.4.  Accordingly  we  have  as  Grauss's  /+  8,  the  distance  a 
body  would  fell  in  vacuum  in  2.176  seconds, 

/+  8  =  J  X  980.4  X  2.176*  =  2321  cm. 


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382  PROCEEDINGS    OF  THE    AMERICAN    ACADEMY. 

The  distance/  the  actual  length  of  the  fall,  as  measured  by  a  steel 
tskpe  which  was  tested  by  a  Brown  and  Sharpe  steel  meter  rod,  was 
2285  cm.  Accordingly  8  =  36  cm.,  and  the  easterly  deviation  should 
be,  according  to  Gauss, 

6  28 
y  =  |cos42°  22'  X  — ^  X  2.176  (2285  -  18)  =  0.177  cm., 

that  is,  to  the  third  place  of  decimals  the  value  of  the  easterly  deviation 
is  not  in  our  case  aflfected  by  the  resistance  of  the  air,  if  I  have  cor- 
rectly understood  and  used  the  formulas  of  Gauss. 

Coefficient  of  Air  Resistance. 

It  is  perhaps  worth  while,  since  observations  on  the  air  resistance 
ofiFered  to  the  motion  of  spherical  bodies  are  not  over  numerous,  to 
work  out  irom  the  data  here  at  hand  the  coefficient  of  this  resistance 
for  the  spheres  here  used, — bronze  spheres,  one  inch  in  diameter, 
ground  to  a  smooth  surface,  but  left  in  a  slightly  greasy  condition  by 
their  experience  of  being  dropped  into  beds  of  tallow  in  their  use  six 
years  ago. 

The  mere  buoyant  efifect  of  air  on  bronze  may  properly  be  neglected 
in  this  discussion,  as  it  is  very  small. 

If  we  assume  that  the  resistance  of  the  air  is  proportional  to  the 
square  of  the  velocity  of  the  fistUing  sphere,  within  the  moderate  range 
of  velocity  here  considered,  we  have,  as  the  net  accelerating  force  on  a 
ball  of  m  grams,  (mg  —  kv^)  dynes,  where  k  is  the  constant  coefficient 
of  resistance.  Accordingly,  writing  c  tor  m-r-  k,  we  find  as  the  incre- 
ment of  velocity 


dv 
whence 


=  (^-?)*.  (1) 


=  dt.  (2) 


£_'     {gc  -  v") 


This  equation,  integrated  for  v  between  the  limits  0  and  t?,  and  for 
t  between  the  limits  0  and  2.176  (the  observed  value),  gives 

r^  [log  ^^]  =  i  |/i  log  ^^  =  2.176.  (3) 

2  Vgc  L      vgc  —  tj  o  ^      vgc  —  v 


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HALL.  —  AIR    RESISTANCE   TO    FALLING   INCH    SPHERES.        383 

We  have  farther,  if  « is  the  distance  &lleD,  from  (2) 

ds  =  vdt==-^-  (4) 

Integrating  this  equation  for  8  between  the  limits  0  and  2285  (the  ob- 
served value)  and  for  v  between  0  and  v,  we  get 


,  =  2285  =  -|[log(.«-^c)];=-^2log(l-^J 


(5) 


Writing  now  (3)  in  the  form 


^ =€  '  (6) 

Vgc  —  v 


and  (5)  in  the  form 


//  4570  \ 

and  substituting  for  v  in  (6),  we  get 
or 


(7) 


1  +  y  1  -  €    c      4.; 


/   "         _4570 

1- V  i-€  ^r 


,362  V  ^ 


or 


/  1984.726  

1   -f  r    1  -  10  ^         ^  ^^1.89006V^ 

/  1984.726  '  ^    ^ 

i-ri-io 

The  value  of  c  which  satisfies  this  equation  I  find  to  be  about  48000. 
The  value  of  *,  the  coefficient  in  question,  is  m,  the  mass  of  the  ball, 
which  is  about  73.8  gm.,  divided  by  c. 

k  =  73.8  -f-  48000  =  0.00154. 


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i 


384  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

In  Alger's  "  Exterior  Ballistics ''  I  find  the  following  passage  : 

"  Expressing  the  retardation  caused  by  the  resistance  of  the  air  in 

the  form  A—'t^/m  which  d  is  the  diameter  of  the  projectile  in  inches, 

w  its  weight  in  pounds  and  v  its  velocity  in  £  s.,  Mayevski's  equations 
are  as  follows  :  " 

"v  between  790  f.  s.  and  0  f.  s., 

"^  =  -  ^7 -^  log^T  =  5.669  . . .  (-  10). 

"The  coefficient  A  depends  on  the  shape  of  the  projectile.  Id 
Mayevski's  calculations  the  '  ogival '  form  [the  shape  of  an  ordinary 
artillery  '  shell ']  is  assumed,  the  '  ogival '  heads  having  two  calibers 
radius.     A  would  be  greater  with  hemispherical  heads." 

Mayevdld's  formula  is  equivalent  to 

Resistance  (poundals)  =  ""  ^  jT  =  ^^  ^  ^* 

Taking  this  formula  for  the  case  in  which  d  is  one  inch,  the  diameter 
of  the  bronze  balls,  and  the  velocity  is  1  cm.  per  second,  we  get  for  the 
"  ogival "  form, 


Besistance  (poundals)  ^  A  -^  30.5  , 

(dynes)       =A^  305^'  X  (453  X  30.5)  =  0.00069. 

This  is  about  45  per  cent  of  the  value,  0.00154,  found  above  for  k  in 
the  case  of  spherical  one  inch  balls. 

Jefferson  Physical  Laboratory, 
Cambridge,  Mass., 
January,  1910. 


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Proceedings  of  the  American  Academy  of  Arts  and  Sciences. 
Vol.  XLV.  No.  17.  — Mat,  1910. 


ISSUED. 

MAY  20  1910 


CONTRIBUTIONS  FROM  THE  GRAY  HERBARIUM 
OF  HARVARD  UNIVERSITY. 


New  Semes.— No.  XXXVIIL 


I.    A  preliminary  Synopsis  of  the  Genus  Echeandia,    By  G.  A. 
Weathebby. 

II.    Spermatophjrtes,    new    or   reclassified,  chiefly    Rubiaceae   and 
Gentianaceae.    By  B.  L.  Robinson. 

III.  American    Forms    of  Lycopodium   compUinatum,      By    G.    A. 

Weathebby. 

IV.  New  and  little  known  Mexican  Plants,  chiefly  Labtatae,    By 

M.  L.  Fernald. 

V.    Mexican  Phanerogams  —  Notes  and  new  Species.     By  G.  A. 
Weathebby. 


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CONTRIBUTIONS  FROM  THE  GRAY  HERBARIUM  OF  HARVARD 
UNIVERSITY.  — NEW  SERIES,  NO.  XXXVIII. 

i'resented  by  B.  L.  Robinson.  January  12, 1910.    Received  February  15.  1010. 

I.  A  PRELIMINARY  SYNOPSIS  OF  THE  GENUS 
ECHEANDIA 

By  C.  a.  Weatherby. 

The  genus  Echeancliay  fouDded  on  Anthericum  rejlexum  Cav.,  was 
proposed  by  Ortega  in  his  Novarum  Plantarum  Decades  in  1798,  and 
has  been  generally  maintained  by  botanists  since.  Eunth,  in  1843, 
recognized  three  species  under  it  Baker,  monographing  th6  Anther- 
iceae  in  1877,  could  find  no  clear  lines  of  demarcation  between  these 
species  and  referred  all  the  material  known  to  him  to  the  original 
species.  Hemsley,  though  suspecting  that  more  than  one  species  was 
concerned,  retained  Baker's  treatment  because  of  insufficient  material 
for  a  satisfactory  revision.  Since  the  date  of  his  work,  the  increasingly 
thorough  floristio  exploration  of  Mexico  has  revealed  a  number  of 
obviously  distinct  forms,  several  of  which  have  been  singly  described 
by  various  botanists.  The  genus  can  hardly  yet  be  considered  as 
thoroughly  understood ;  but  a  brief  synopsis,  which  shall  contrast  the 
characters  of  the  different  species  and  bring  together  the  existing 
information  concerning  them,  may  be  of  service,  even  though  it  can 
lay  no  claim  to  finality.  The  following  is  an  attempt  at  such  a 
synopsis. 

Echeandia  is,  so  far  as  known,  a  strictly  American  genus  and  chiefly 
confined  to  Mexico  and  Central  America.  The  material  at  hand  shows 
one  species  collected  in  Venezuela.  The  genus  is  very  closely  related 
to  Anthericum  L.,  irom  which,  indeed,  it  is  separated  by  only  one 
constant  character  —  its  connate  anthers.  Although  the  American 
species  of  Anthericum  are  more  numerous  than  those  of  Echeandia^ 
the  two  groups  show  a  distinctly  parallel  development,  both  con- 
taining species  with  smooth  and  with  roughened  filaments,  smooth 
and  scabrous  stems  and  ovoid  and  oblong  capsules.  In  particular, 
E.  macrocarpa  and  A.  stenocarpum,  and  E.  Pringlei  and  A,  tenue  are 
nearly  indistinguishable  except  by  the  characters  of  their  anthers. 


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388  PROCEEDINGS    OF   THE    AMERICAN   ACADEMY. 

I  have  preferred,  at  least  for  the  present^  to  regard  plants  which 
differ  only  in  comparatively  superficial  foliar  and  habital  characters  as 
varieties  of  a  single  species,  rather  than  specifically  distinct  I  have, 
however,  made  an  exception  in  the  group  of  forms  closely  related  to 
E,  reflexa.  Here,  because  of  imperfect  material  of  E,  rejiexa  and 
E,  paniculata  and  of  certain  puzzling  specimens  from  Yucatan,  I  have 
not  been  able  to  arrive  at  a  wholly  clear  conception  of  the  relationships 
of  the  different  forms ;  and  I  have  allowed  described  species  to  stand 
as  such,  rather  than  make  new  combinations  which  later  might  have  to 
be  withdrawn. 

For  the  loan  of  specimens,  and  for  other  kindly  assistance  in  the 
preparation  of  this  paper,  I  am  indebted  to  Captain  John  Donnell 
Smith,  to  Mr.  Brandegee  of  the  University  of  California,  Dr.  Rose  of 
the  National  Herbarium,  and  Dr.  Greenman  of  the  Field  Museum. 
All  specimens  cited  are  in  the  Gray  Herbarium,  unless  otherwise 
specified. 

ECHEANDIA  Ort  Perianth  rotate,  spreading  or  reflexed  in  flower, 
after  anthesis  the  withered  segments  cohering  above  the  ovary  and 
persistent  until  pushed  off  by  the  expanding  capsule;  segments  6, 
distinct,  three-nerved,  about  equal  in  length,  the  inner  often  broader. 
Stamens  6,  hypogynous,  shorter  than  the  perianth ;  filaments  filiform 
or  clavate,  smooth  or  more  or  less  papillose-  or  crispate-roughened ; 
anthers  linear,  hastate  at  base,  the  filament  attached  in  the  sinus, 
usually  equalling  or  longer  than  the  filaments,  connate  in  a  cylindrical 
tube  which  surrounds  the  style,  introrse.  Ovary  sessile,  three-lobed ; 
style  filiform,  a  little  longer  than  the  tube  of  anthers ;  stigma  small, 
capitate.  Capsule  ovoid  or  oblong,  triangular,  loculicidal.  Seeds 
numerous,  angulate-compressed,  black,  minutely  papillose.  —  Roots 
fibrous,  clustered,  often  thickened  or  fusiform.  *  Leaves  basal  or  rarely 
the  lower  part  of  the  stem  leafy.  Stem  scapiform,  bracted,  simple  or 
branched  above,  the  branches  virgate.  Flowers  yellow  or  white,  on 
usually  slender  jointed  pedicels  in  clusters  of  1-4  on  the  stem  and  its 
branches,  in  the  axils  of  chartaceous  bracts,  each  pedicel  subtended  by 
a  similar  smaller  bractlet ;  the  clusters  in  virgate  racemes. 

a.   Filaments  smooth;  leaves  strictly  basal,  not  sheathing  the  stem,  h. 

b.  Stem  scabrous,  1-4-bracted 1.  ^.  parviflora, 

b.  Stem  smooth,  6-9-bracted,  c. 
c.   Leaves  spreading,  falcate,  15  cm.  or  less  long      .     .     2.  E.  brevifolia, 
c.   Leaves  erect,  narrowed  at  base,  more  than  15  cm.  long,  d. 

d.   Leaves  broad,  2  cm.  or  more 3.  ^.  nodosa. 

d.   Leaves  narrow,  not  over  1  cm.  wide  .  3.  E.  nodosa t  var.  lanceolata. 


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WEATHERBY. — SYNOPSIS   OF  THE   GENUS   ECHEANDIA.  389 

a.  Filaments  more  or  less  crispate-  or  papillose-roughened,  e. 

c.   Leaves  broad,  O.S-3.5  cm.  wide,  membranous  in  drying,  soft,  the  prin- 
cipal nerves  usually  connected  by  conspicuous  cross- veinlets,  /. 
/.  Stem  smooth ;  flowers  chiefly  yellow,  as  far  as  known,  g, 

g.  Capsule  ovoid  or  short-oblong,  6-9  mm.  long,  5-7  mm.  broad ;  inner 
perianth-segments    oblong-lanceolate,    little    broader    than    the 
outer,  h. 
h.  Leaves  lanceolate  or  even  ovate-lanceolate,  20-25  cm.  long,  2.8-5 
cm.  wide,  not  more  than  8  times  as  long  as  wide. 

4.  E.  macrophylla. 
h.  Leaves  linear  or  narrowly  lanceolate,  24-42  cm.  long,  1.2-2.3  cm. 
wide,  at  least  1^  times  as  long  as  wide. 

4.  E.  macrophyUaf  var.  longifolia. 
g.  Capsule  oblong,  1-1.8  cm.  long,  4-6  mm.  wide;   inner  perianth- 
segments  ovate  or  ovate-lanceolate,  often  much  broader  than  the 
outer,  i. 
i.  Leaves  for  the  most  part  sheathing  the  stem  but  confined  to  its 
base;  stem  about  2-bracted,  /. 
/.  Leaves  narrow,  8-13  mm.  wide,  k. 

k.  Leaves  usually  several  (6-10),  suberect    .  6.  E,  macrocarpa^ 
k.  Leaves  few  (2-4),  spreading,  short  in  proportion  to  the  stem. 

5.  E.  macrocarpaf  var.formosa, 

;.   Leaves  broader,  1.5-2  cm.  wide 6.  ^.  reflexa. 

i.  Stem  leafy  for  about  a  third  of  its  height,  the  leaves  passing  grad- 
ually into  3-6  reduced  bracts 1,  E.  paniculata, 

/.  Stem  scabrous,  at  least  below;  flowers  white.    .    .    .  8.  ^.  aUn flora, 
e.  Leaves  narrow,  2-5  mm.  wide  or  less,  firm,  closely  and  prominently 
veined,  mostly  without  visible  cross- veinlets,  I. 
I,  Leaves  2-5  mm.  wide,  minutely  scabrous  beneath;  stem  2-bracted; 

inflorescence  mostly  branched 9.  ^.  flexuosa, 

I,  Leaves  2  (-2.5)  mm.  wide  or  less,  scabrous-ciliate  on  the  margins,  else- 
where smooth;  stem  3-6-bracted;  inflorescence  mostly  simple. 

10.  E,  Pringlei. 

1.  R  PARVIFLORA  BakoT.  Leaves  membranous,  linear,  not  very 
prominently  nerved,  4-8  mm.  wide,  6-22  cm.  long,  suberect  or  some- 
what spreading  and  fgJcate ;  stem  scabrous  or  hirtellous^at  least  below, 
simple  or  sometimes  with  as  many  as  5  branches ;  pedicels  rather  short 
and  stout,  in  fruit  6-8  mm.  long,  jointed  below  the  middle  or  toward 
the  base;  filaments  smooth;  capsule  (seen  on  the  Pringle  specimen 
only)  broadly  oblong,  3.5-5  mm.  wide,  6-9  mm.  long.  —  Engl.  Bot. 
Jahrb.  viii.  209  (1887).  —  Guatemala  :  Santa  Rosa,  alt.  900  m..  May, 
1892,  John  DonneU  Smith,  PL  Guat,  no.  3528.  Mexico  :  Mt  Orizaba, 
Cordoba,  830  m.,  Aug.  20,  1891,  Henry  E,  Seaton,  no.  485,  in  part. 
State  of  Guerrero,  dry  hillsides,  near  Iguala,  alt  915  m.,  July  29, 1907, 
Pringh,  no.  10,388. 

2.  R  BREviFOLiA  Watsou.    Leaves  membranous,  with  cross-veinlets, 


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390  PROCEEDINGS   OF   THE   AMERICAN   ACADEMY. 

short,  12-15  cm.  long,  6  mm.  wide,  acuminate,  spreading  and  some- 
what falcate,  not  sheathing  the  stem ;  stem  about  6  dm.  tall,  smooth, 
6-bracted,  with  few  (3-4)  branches;  pedicels  slender,  in  fruit  11-14 
mm.  long,  jointed  below  the  middle ;  filaments  smooth ;  capsule  short- 
oblong,  4-4.5  mm.  wide,  7-8  mm.  long.  —  Proc.  Am.  Acad.  xxi.  441 
(1886).  —  Mexico:  State  of  Chihuahua,  Hacienda  San  Miguel  near 
Batopilas,  Sept.,  1885,  Palmer^  no.  229. 

3.  E.  NODOSA  Watson.  Leaves  membranous,  with  cross-veinlets, 
linear-lanceolate,  narrowed  at  base,  not  sheathing  the  stem,  18-40  cul 
long,  2-2.7  cm.  wide ;  stem  smooth,  6-9-bracted,  with  6-7  branches, 
which  rarely  branch  again ;  pedicels  slender,  jointed  below  the  middle, 
in  fruit  11-14  mm.  long;  filaments  smooth,  shorter  than  the  anthers ; 
capsule  oblong,  3.5-4  mm.  wide,  8-9  mm.  long. — Proc.  Am.  Acad, 
xxvi.  156  (1891).  1  Phalangium  ramosissimum  Presl,  Rel.  Haenk.  i.  127 
(1825).  lAnthericum  ramosissimum  R.  &  S.  Syst  vii.  469  (1829). 
lEcheandia  Haenkeana  Kunth,  Enum.  iv.  629  (1843).  —  Mexico; 
State  of  Jalisco,  near  Guadalajara,  12  Nov.,  1888,  Pringle,  no.  2151. 
Dry  rocky  blufifs  of  barranca  near  Guadalajara,  23  Sept.,  1891,  Pringle, 
no.  3870.  —  Flowers  apparently  small  as  in  E,  macrophylla,  the  peri- 
anth-segments narrow,  whitish  in  drying.  From  Presl's  description  it 
seems  highly  probable  that  this  plant  is  the  same  as  his  Phalangium 
ramosissimum.  In  the  absence  of  authentic  material,  however,  I  hesi- 
tate to  make  the  new  combination  required  by  the  transfer  of  Presl's 
species  to  Echeandia. 

Var.  lanceolat€^  n.  var.,  a  forma  typica  recedit  habitu  graciliore, 
foliis  angustioribus  6-10  mm.  latis,  pedicellis  1  cm.  longis,  capsulis  min- 
oribus  3.5  mm.  latis  5-6  mm.  longis.  —  Mexico:  State  of  SinaJoa, 
Copradia,  Oct.  20,  1904,  Brandegee,  type  (in  Herb.  Univ.  Cal.,  sheet 
no.  119,863).  Ymala,  Sept.  28  to  Oct.  8,  1891,  Palmer,  no.  1677. 
Culiacan,  Sept.  17,  1904,  Brandegee  (in  Herb.  Univ.  Cal.,  sheet  no. 
119,856).  —  The  name  lanceolata  was  applied  to  this  plant,  on  her- 
barium labels,  ,by  Mr.  Brandegee,  who  at  that  time  was  inclined  to 
regard  it  as  a  good  species.  It  seems,  however,  hardly  specifically 
distinct  from  E.  nodosa.  The  specimen  on  sheet  no.  119,856  of  the 
University  of  California  Herbarium  has  broader  leaves  than  the  other 
two  plants  cited  and  may  be  regarded  as  a  transitional  form  between 
the  extreme  development  of  the  variety  and  typical  E.  nodosa. 

4.  E.  macrophylla  Rose,  in  hb.,  foliis  omnino  radicalibus  caulis 
basin  vaginantibus  lanceolatis  20-25  cm.  longis  2.8-5  cm.  latis  in 
apicem  acuminatum  angustatis,  caule  7  dm.  alto  glabro  2-bracteato, 
ramis  5-6  saepe  2  ex  axilla  unica,  pedicellis  infra  medium  vel  prope 
basin  articulatis,  floribus  parvis,  perianthii  segmentis  1-1.3  cm.  longis 


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WEATHERBY.  —  SYNOPSIS   OF   THE   GENUS   ECHEANDIA.  391 

lineari-  vel  oblongo-lanceolatis  latitndine  snbaequalibus,  interioribus 
paulum  latioribus  acutis,  exterioribus  obtusiusoulis,  filamentis  clavatis 
modice  crispatis  in  floribus  (novellis)  visis  qaam  antherae  duplo  brevi- 
oribus,  capsulis  ovoideis  7  mm.  longia  5  mm.  latis.  —  Mexico:  State  of 
San  Luis  Potosi,  grassy  slopes,  Las  Canoas,  16  June,  1890,  Pringle, 
no.  3183. 

Var.  longifolia,  n.  var.,  foliis  late  linearibus  24-42  cm.  longis 
1.2-2.3  cm.  latis  saepias  solum  radicalibus,  caule  6.2-9  cm.  alto,  ramis 
paucis  (1-3),  pedicellis  1-2  cm.  longis,  filamentis  antheras  aequantibus 
vel  eis  brevioribus,  capsulis  ovoideis  vel  breviter  oblongis  7-9  mm. 
longis  5-6  mm.  latis,  ceteris  praecedentis. — ^E.  temiflora  Lindley,  Bot. 
Reg.  XXV.  Misc.  no.  144  (1839),  not  Ort  E.  temiflora  Baker,  Journ. 
Linn.  Soc.  xv.  288  (1877),  in  part,  not  Ort. ;  Hemsl.  Biol.  Cent -Am. 
Bot.  iiL  376,  in  part,  not  Ort  —  Mexico:  State  of  Oaxaca,  vicinity  of 
Choapam,  alt.  1150-1400  m.,  July  28  &  29,  1894,  Nelson^  no.  910, 
type  (in  U.  S.  Nat  Herb.).  State  of  Vera  Cruz,  Zacuapan,  dry  sunny 
fields,  Nov.,  1908,  Purpus,  no.  3761.  Orizaba,  Botteri,  no.  1185. 
Ibid.,  Cordoba,  830  m.,  Aug.  20,  1891,  iT.  JK  Seaton,  no.  485,  in  part 
Valine  de  Cordova,  23  Avril,  1865-66,  Bmrgeau,  no.  2307.  Vene- 
zuela: prope  coloniam  Tovar,  1854-55,  Fendler,  no.  1549.  The  Bour- 
geau  plant  has  entirely  the  habit  and  the  fruit  of  tliis  species,  but  the 
filaments  are  nearly  smooth.  It  seems  somewhat  transitional  between 
this  and  the  preceding  group.  —  Flowers  yellow  according  to  Lindley's 
description ;  white  with  yellow  anthers  accoiding  to  a  note  on  Fendler's 
label  The  plant  seen  by  Lindley  was  possibly  E.  reflsxa,  but  from  his 
description,  seems  rather  to  belong  here. 

5.  K  MACROCARPA  Qrecuman.  Leaves  chiefly  basal,  suberect,  rather 
narrowly  linear,  (6)  8-15  mm.  broad,  membranous,  the  cross-veinlets 
usually  prominent,  long  in  proportion  to  the  stem,  usually  6-10  in 
number ;  stem  1-2-bracted,  glabrous,  simple  or  few-branched ;  pedicels 
jointed  below  the  middle,  rather  stout,  in  fruit  1-1.7  cm.  long ;  flowers 
apparently  rather  large,  the  perianth-segments  1.5-1.7  cm.  long,  the 
inner  ovate-lanceolate ;  filaments  moderately  roughened,  equalling  or 
slightly  longer  than  the  anthers ;  capsules  oblong,  1-1.8  cm.  long,  4-6 
mm.  wide.  —  Proc.  Am.  Acad,  xxxix.  73  (1903).  E.  temiflora  Hemsl. 
Biol.  Cent. -Am.  Bot  iii.  376,  in  part,  not  Ort  —  Mexico:  State  of 
San  Luis  Potosi,  near  Tancanhuitz,  May  2,  1898,  Nelson^  no.  4393, 
type ;  region  of  San  Luis  Potosi,  alt  1850-2450  m..  Parry  <t  Palmer, 
no.  890.  "Mexico,"  no  locality,  Ehrenberg,  no.  31.  "Chiapas,  etc.," 
Ghiesbreghtj  no.  875.  Valine  de  Mexico,  Santa  Fd,  6  Juillet,  1865-66, 
Boiirgeau,  no.  413.  Guanajato,  1880,-4.  Dugh.  State  of  Oaxaca, 
vicinity  of  Cerro  San  Felipe,  alt  3000-3400  m.,  1894,  I^ekan,  no.  1056 


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392  PROCEEDINGS  OF  THE  AMEEICAN  ACADEMY. 

(in  U.  S.  Nat.  Herb.).  —  A  specimen  fix)m  Mt  Orizaba,  3000  m., 
Aug.  5,  1891,  H.  E,  SeatoUf  no.  180,  is  probably  a  reduced  form  of  this 
species.  —  Flowers  yellow  according  to  Ghiesbreght's  label.  Difficult 
to  separate  from  E.  reflewa,  except  by  purely  habital  characters. 

Var.  formosa,  n.  var.,  foliis  paucis  (circa  4)  caulis  basin  extremam 
vaginantibus  patulis  caule  duplo  brevioribus  late  linearibus  circa  1  cm. 
latis  summum  2  dm.  longis,  caule  simplice,  pedicellis  gracilibus,  flori- 
bus  magnis  aureis,  ceteris  formae  typicae.  —  Mexico  :  State  of  Chiapas, 
near  San  Christobal,  alt  2100-2500  m.,  Sept.  18,  1895,  Nelson,  no. 
3143  (in  U.  S.  Nat.  Herb.  Sheet  no.  233,087).  —  Flowers  "  rich  yellow  " 
according  to  Nelson's  note. 

6.  K  REFLEXA  (Cav.)  Rose.  Leaves  rather  closely  sheathing  the 
base  of  the  stem,  broadly  linear,  27-40  cm.  long,  1.5-2.2  cm.  wide, 
acuminate,  membranous,  the  cross-veinlets  prominent ;  stem  about  7  dm. 
tall,  smooth,  rather  slender,  bearing  2-3  foliaceous  bracts,  in  the  single 
specimen  seen  with  two  branches ;  pedicels  jointed  below  the  middle, 
in  fruit  1.4-1.7  cm.  long;  perianth-segments  broad,  1.5  cm.  in  length ; 
filaments  strongly  roughened,  at  least  in  the  young  flower  shorter 
than  the  anthers ;  capsule  (immature)  oblong,  1  cm.  long,  4  mm.  wide. 

—  Contr.  U.  S.  Nat.  Herb.  x.  93  (1906).  Anthericum  reflexum  Cav.  Ic. 
PL  iii.  21,  t  241  (1795) ;  Willd.  Sp.  PL  iL  140  (1799).  Echeandia 
tefmijhra  Ort.  Nov.  PL  Dec.  90,  135,  &  136,  t.  18  (1798) ;  Redouts, 
LiL  vi,  t  313  (1812);  Kunth,  Enum.  iv.  627  (1843);  Baker,  Joum. 
Linn.  Soc.  xv.  288  (1877),  tin  part;  HemsL  BioL  Cent -Am.  Bot  iiL 
376  (1885),  in  part.  Phalangium  reflexum  Poir.  EncycL  Meth.  Bot.  v. 
249  (1804).  Conanthera  Echeandia  Pers.  Syn.  L  370  (1805)  ;  Link  & 
Otto,  Ic.  PL  Ear.  5,  t.  3  (1828).  —  Mexico  :  State  of  Morelos,  ledges. 
Sierra  de  Tepoxtlan,  near  Cuemavaca,  alt  2300  m.,  August  22,  1906, 
Prlngky  no.  10,289.  — Although  the  form  represented  by  Mr.  Pringle's 
plant  here  cited  was  the  first  of  the  genus  to  be  collected,  it  seems  not 
to  be  common.  His  specimen  is  the  only  one  I  have  seen  which,  in  its 
combination  of  broad  leaves,  few-branched  stem,  yellow,  rather  broad 
perianth-segments,  strongly  roughened  filaments  and  oblong  capsules, 
agrees  well  with  Cavanilles's  and  Ortega's  plates. 

7.  R  PANicuLATA  Rosc.  Stem  tall,  with  6-7  panicled  branches, 
leafy  above  the  base  for  about  a  third  of  its  height,  the  leaves  passing 
gradually  into  3-6  reduced  bracts ;  leaves  membranous,  with  cross- 
veiulets,  linear,  long-attenuate  at  apex,  up  to  5  dm.  long,  1.5-3  cm. 
wide;  flowers  rather  large,  yellow;  perianth-segments  1.5  cm.  long, 
the  outer  oblong-linear,  the  inner  ovate,  6  mm.  wide;  filaments  cla- 
vate,  strongly  roughened,  about  equalling  the  anthers ;  capsule  not  seen. 

—  Contr.  U.  S.  Nat.  Herb.  x.  93  (1906).  —  Mexico  :  State  of  Morelos, 


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WEATHERBY.  —  SYNOPSIS    OF   THE    GENUS    ECHEANDIA.  393 

near  El  Parque,  Sept  21,  1903,  Rose  A  Painter,  no.  844  (in  IT.  S. 
Nat  Herb.,  sheets  nos.  454,954  &  454,955).  —  No  fruit  of  this  species 
has  been  preserved,  but  its  floral  characters  place  it  clearly  very  near 
E.  reft^xa.  So  £Bir  as  the  material  at  hand  shows,  it  differs  from  that 
species  only  in  its  more  leafy  stem  and  more  branched  inflorescence  and 
may  very  probably  prove  to  be  no  more  than  a  variety  of  it  — Here  are 
doubtfully  placed  the  specimens  from  two  collections  of  C,  F,  Gaumer 
namely  from  Yucatan,  Izamal,  Sept,  1895,  na  843  and  Ghicankanab, 
no.  1995  (the  latter  in  Herb.  Field  Mus.  Nat  Hist,  sheet  no.  58,793). 
These  specimens  have  neither  fruit  nor  good  flowers  and  in  their  absence 
can  hardly  be  placed  definitely.  They  have  mostly  a  much-branched 
inflorescence,  several(7-8)-bracted  stem  and  the  leaves  pass  abruptly 
into  the  much  reduced  bracts.  In  this  respect  they  differ  from 
E,  panicuiata;  and  the  branches  of  the  inflorescence  are  more 
slender  and  the  flower-buds  smaller  than  in  either  that  species  or 
E.  refiexa^  although  the  plants  are  quite  as  robust 

8.  R  ALBiFLORA  (Schlccht  &  Cham.)  Mart  &  Gal.  Leaves  basal, 
several,  lanceolate-linear,  narrowed  to  an  acute  apex,  the  principal 
nerves  united  by  transverse  veinlets,  membranous,  glabrous,  about  36 
cm.  long,  1.8-2  cm.  wide ;  stem  scabrous  or  hirtellous  below ;  inflor- 
escence paniculate ;  pedicels  slender,  10  mm.  long,  jointed  below  the 
middle ;  flowers  white ;  perianth-segments  lanceolate ;  filaments  re- 
trorsely  papillose-crispate,  equalling  the  anthers;  capsule?  —  Bull. 
Acad.  Brux.  ix.  386  (1842)  ;  Kunth,  Enum.  iv.  628  (1843).  Conan- 
thera  aUnflora  Schlecht  &  Cham.  Linnaea,  vi.  50  (1831).  Echeandia 
leucantha  B^otzsch,  fide  Kunth,  1.  c.  —  I  have  seen  no  material  refera- 
ble to  this  species.  The  above  description  is  taken  chiefly  from  that 
of  Kunth. 

9.  K  FLEXUOSA  Greenman.  Leaves  firm,  closely  and  prominently 
veined,  suberect,  minutely  scabrous  beneath,  2-5  mm.  wide,  variable 
in  length  (reaching  8  dm.),  long-acuminate ;  stem  9  dm.  high  or  less, 
smooth,  2-3-bracted,  the  lower  bract  sometimes  elongated  and  seta- 
ceous, reaching  15  cm.  in  length ;  pedicels  jointed  near  or  below  the 
middle,  rather  stout,  in  fruit  12-16  mm.  long;  flowers  rather  large 
with  lanceolate  perianth-segments ;  filaments  moderately  roughened, 
shorter  than  or  nearly  equalling  the  anthers  ;  capsule  oblong,  6-9  mm. 
long,  3-4  mm.  wide.  —  Proc  Am.  Acad,  xxxix.  73  (1903).  —  Mexico  : 
State  of  Oaxaca,  Mts.  of  Jayacatlan,  alt  1400  m.,  10  Sept,  1894, 
Lucius  C.  Smith,  no.  188.  State  of  Jalisco,  Rio  Blanco,  July,  1886, 
Palmer,  no.  185  ;  bluffs  of  the  barranca  of  Guadalajara,  1400  m.,  19 
July,  1902,  Pringle,  no.  11,197. 

10.  K  Pringlei  Qreenman.  Leaves  firm,  closely  and  prominently 


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394  PROCEEDINGS  OF   THE   AMERICAN   ACADEMY. 

veined,  scabrous-ciliate  on  the  margins,  elsewhere  smooth,  1.5-2  (2.5) 
mm.  wide,  1-3  dm.  long;  stem  2.7-6  dm.  high,  slender,  glabrous, 
simple,  bearing  3-6  bracts ;  pedicels  jointed  near  the  base,  in  fruit 
10-14  mm.  long ;  filaments  moderately  roughened,  shorter  than  the 
anthers;  capsule  oblong,  3-3.5  mm.  wide,  7  mm.  long — Proc.  Am. 
Acad.  xl.  28  (1904).  —  Mexico  :  State  of  Jalisco,  dry  calcareous  hills 
above  Etzatlan,  2000  m.,  24  Oct.,  1904,  Pringle,  no.  8812 ;  grassy 
plains  near  Guadalajara,  1500  m.,  4  Oct.,  1903,  Pringle,  no.  11,715 ; 
hillsides  of  Zapotlan,  alt.  about  1500  m.,  Aug,  8,  1905,  P.  GoldsmitA, 
no.  122 ;  near  Etzatlan,  Oct  2,  1903,  Hose  &  Painter,  no.  7544  Tin 
U.  S.  Nat.  Herb.). 

Excluded  Species. 

E,  elmiherandra  K.  Koch,  Ind.  Sem.  Hort.  BeroL  App.  4  (1861)  = 
Anthericum  echeandioidesy  ace.  to  Baker. 

E.  graminea  Mart.  &  GaL  Bull  Acad.  Brux.  ix.  387  (1842)  = 
Anthericum  leptophyllum, 

E,  kptophylla  BentL  PL  Hartw.  25  {l%4SS)-=  Anthericum  leptophyl- 
lum. 

E,  scahreUa  Walp.  Ann.  iii.  1010  (y^h^^  Anthericum  scabrellum. 

E,  pusilla  Brandegee,  Univ.  CaL  Pub.  Bot  iii.  377  (1909)  =form  of 
Anthericum  leptophyllum. 


II.  SPERMATOPHTTES,  NEW  OR  RECLASSIFIED,  CHIEFLY 
RUBIACEAE  AND  GENTIANACEAR 

By  B.  L.  Robinson. 

Ranunculus  trieeotuB  Eastwood,  n.  sp.,^  glaber  vel  paulo  pilosus 
1-2  dm.  altus  simplex  vel  2-3-ramosus,  ramis  ascendentibus ;  foliis 
radicalibus  orbicularibus  trisectis,  diametro  2-3  cm.,  basi  reniformi- 
bus  cum  sinu  saepissime  angusto ;  segmentis  approximatis,  medio  late 
cuneato,  lateralibus  inaequaliter  bipartitis,  superiore  parte  trilobata 
ma j ore ;  omnibus  lobulis  similibus  oblongis  2-3  mm.  latis  duplo  longi- 
oribus,  apice  et  basi  callosis,  sinubus  obtusis;  petiolis  strmtis  basi 
membranaceis  dilatatis  et  persistentibus ;  foliis  caulinis  1-3  sessilibus 
vel  breviter  petiolatis  3-5-sectis,  segmentis  integris  vel  lobatis,  ultimis 
lobulis  oblongo-linearibus  ad  apicem  et  sinum  callosis,  basi  petiolorum 
vel  foliorum  membranaceo  amplexicauli ;  pedunculis  altis,  fructiferis 

*  This  species,  elaborated  by  Miss  Alice  Eastwood  from  material  in  the 
Gray  Herbarium,  is  here  published  at  her  request. 


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ROBINSON.  —  SPERMATOPHTTES,    NEW   OR   RECLASSIFIED.        395 

saepe  5-6  mm.  longis,  floriferis  multo  brevioribus ;  sepalis  purpura- 
scentibus  orbiculatis  6-7  mm.  latis  et  longis,  concavis,  cum  pilis  canis 
et  sericeis  parce  investis ;  petalis  aurantiacis  cuneatis  5-15  mm.  latis, 
sepala  multo  superantibus,  apice  undulatis  rotundatis,  basi  cum  squa- 
mula  hemicycla  supra  brevem  unguem  ;  stamiuibus  numerosis,  loculis 
antherarum  separatis,  dorso  filamentis  planis ;  acheniis  spicatis,  recep- 
taculo  subulato  albo  membranaceo  pilosello ;  stylis  purpureis  vel  flavis 
rectis  vel  curvatis  et  divaricatis,  apice  saepe  deciduis.  —  Alpine  Wal- 
lowa mountains,  eastern  Oregon,  altitude  2745  m..  growing  at  base  of 
cHflfs,  William  C.  Cusick,  16  August,  1907,  no.  3200  (type,  in  Gray 
Herb.).  Under  the  same  species  are  included  with  some  doubt  the  fol- 
lowing, all  collected  by  Mr.  Cusick  at  the  same  locality  :  —  no.  3188, 
strong  growing  plants,  some  with  smooth,  others  with  hairy  akenes 
but  otherwise  identical ;  3325  d,  with  akenes  all  hairy ;  3326  with  both 
hairy  and  smooth  akenes.  Among  the  older  specimens  in  the  Ghray 
Herbarium  are  3219  a  collected  in  1907  with  heads  of  akenes  more 
globular  and  hairy,  styles  purplish,  1513  of  1888  and  2006  of  1898. 
These  all  show  great  variability  in  size  of  flowers  and  height  of  stems 
but  the  plants  have  an  individuality  which  makes  them  appear  quite 
distinct  from  B.  Suksdorfii  with  which  they  have  been  confused.  In 
general  this  species  differs  from  B.  Suksdorfii  in  having  more  orbicular 
leaves  with  more  deeply  cut  divisions,  narrower  basal  sinus,  the  ulti- 
mate lobules  obtuse  and  narrowing  slightly  to  the  base  thus  making 
the  dividing  space  rounded  rather  than  acuta  The  akenes  are  not 
angled,  hairy  instead  of  smooth,  and  the  style  curves  outward  more 
noticeably  and  is  less  strongly  subulate. 

Tocooa  Peokiana,  n.  sp.,  fruticosa  3-6  m.  alta ;  ramis  valde  com- 
pressis  brunneis  fistnlosis  parce  praesertim  nodos  versus  glanduloso- 
hispidulis ;  foliis  late  ovatis  modice  disparibus  membranaceis  5-nerviis 
supra  appresse  setulosis  rugosis  siccitate  nigrescentibus  subtus  tomen- 
tellis  flavidi-viridibus  margine  integriusculis  hispidulis  apice  angustis- 
sime  caudato-attenuatis,  majoribns  1.4-2.2  dm.  longis  7-12  cm.  latis, 
petiolo  crasso  hispidulo  2-2.5  cm.  longo  prope  apicem  vesciculifero, 
vescicuHs  ovoideis  subcoriaceis  1-1.2  cm.  longis;  foliis  minoribus 
1.2-1.5  dm.  longis  ab  vesciculis  destitutis ;  panicula  terminali  peduncu- 
lata  ca.  8  cm.  longa,  ramis  patentibus  dichotomo-C3nniferis ;  floribus 
sessilibus;  calycis  tubo  subgloboso  4-5  mm.  diametro  parce  glandu- 
loso-hispidulo,  limbo  brevissimo  membranaceo  obscure  5-lobato ;  petalis 
ovatis  subcoriaceis  minute  papillosis.  —  British  Honduras,  in  thick- 
ets, near  Manatee  Lagoon,  16  July,  1905,  Prof.  Morton  E,  Peck,  no. 
68  (type,  in  Gray  Herb.).  A  species  of  the  §  Hypophysca  and  related 
apparently  to  T.  guyanensis  Aubl.,  from  which,  however,  it  may  be 


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396  PROCEEDINGS  OP  THE  AMERICAN  ACADEMY. 

readily  distinguished  by  its  less  unequal,  more  nearly  entire  leaves, 
smaller,  thicker-walled  vescicles,  and  especially  by  its  sessile  flowers. 

Cynoctonum  oldenlandioides  (Wall.),  n.  comb.  Mitreola  olden- 
landioides  Wall.  Cat  no.  4350  (1828),  without  description ;  6.  Don, 
Syst  iv.  172  (1837),  where  distinctions  are  slightly  indicated ;  A.DC. 
Prod.  ix.  9  (1845),  where  described  and  distinguished  chiefly  by  the 
widely  divergent  lobes  of  the  fruit;  HooL  Ic.  t.  827  (1852),  where 
admirably  figured.  The  change  from  Mitreola  to  Cynoctonum  becomes 
necessary  under  the  Vienna  Rules,  though  it  is  certainly  to  be  re- 
gretted that  the  well  established  Mitreola  was  not  included  in  the  list 
of  nomina  conservanda. 

Cjmootoniim  pcmioulatum  (Wall),  n.  comb.  Mitreola  panictdata 
Wall.  Cat.  no.  4349  (1828),  without  description;  G.  Don,  Syst.  iv. 
171  (1837) ;  A.DC.  Prod.  ix.  9  (1845) ;  Progel  in  Mart  R  Bras.  vL 
pt  1,  266,  t  71  (1868). 

Cynoctonum  pedioellatum  (Benth.),  n.  comb.  Mitreola  pedicel- 
lata  BentL  Jour.  Linn.  Soc.  i.  91  (1857). 

Centauriiim  Besrriohii  (Torr.  &  Gray),  n.  comb.  Erythraea  trt- 
chantka  P  angustifolia  Griseb.  in  DC  Prod.  ix.  60  (1845).  E,  Beyrichii 
Torr.  &  Gray  ex  Torr.  in  Marcy,  Expl.  Red  Riv.  291  (1853). 

Centaurium  cachanlahuen  (Molina),  n.  comb.  Gentiana  Cachan- 
lahuen  Molina,  Sagg.  ChiL  147  (1782);  also  in  the  German  edition 
by  Brandis,  310  (1786).  G.  peruviana  h^m.  Encycl.  ii.  642  (1786). 
Chironia  chilensis  Willd.  Sp.  PL  i.  1067  (1798).  Erythraea  chilensis 
Pers.  Syn.  i.  283  (1805).  E.  Cachanlahuan  RoeuL  &  Schultes,  Syst. 
iv.  167  (1819). 

Centaurium  calycosum  (Buckl.)  Femald,  var  nana  (Gray),  n.  comb. 
Erythraea  calycosa^  var.  nana  Gray,  Syn.  FL  ii.  pt  1,  113  (1878). 

Centaurium  floribunduxn  (Benth.),  n.  comb.  Erythraea florihunda 
Benth.  PI.  Hartw.  322  (1849). 

Centaurium  maoranthimi  (Hook.  &  Am.),  n.  comb.  Erythraea 
macrantha  Hook.  &  Am.  Bot  BeecL  438  (1841).  JE  mexicana 
Griseb.  ex  Hook.  &  Am.  L  c.  302,  438.  Gyrandra  chironioides 
Griseb.  in  DC  Prod.  ix.  44  (1845).  Erythraea  chironioides  Torr. 
Bot  Mex.  Bound.  156  (1859),  in  part 

Centaurium  madrense  (HomsL),  n.  comb.  Erythraea  madrensis 
Hemsl.  Biol.  Cent -Am.  Bot  ii.  346  (1882).  Gyrandra  chironioides 
Griseb.  in  Seem.  Bot  Herald.  318  (1856),  not  Griseb.  in  DC.  Prod.  ix. 
44  (1845). 

Centaurium  mioranthum  (Greenm.),  n.  comb.  Erythraea  mi- 
crantha  Greenm.  Proc.  Am.  Acad,  xxxix.  83  (1903). 

Centaurium  multioaule,  n.  sp.,   verisimiliter  bienne  multicaule 


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ROBINSON.  —  SPERMATOPHYTES,    NEW    OR   RECLASSIFIED.        397 

caespitostun  5-10  cm.  altam  basi  densissime  foliatum ;  ladice  simplice 
2-6  cm.  longa ;  caulibus  4-22  subsimplicibas  4-aDgulatis  gracilibus  apioe 
l-2(rarius  3)-flori8,  ramis  1-2  erectis ;  foliis  radicalibus  rosulatis  obo- 
yato-spatalatis  1-2  cm.  longis  4-8  mm.  latis  apice  rotundatis  basi  in 
petiolum  attennatis ;  foliis  caalinis  3-4jagi8  lineari-oblongis  vel 
linearibus  8-10  mm.  longis  1-2.7  mm.  latis  l-nerviis  crassiusculis ; 
pedunculis  1.5-4  cm.  longis  erectis  nadis  unifloris ;  floribus  penta- 
mens ;  calycis  lobis  linearibus  attennatis  6  mm.  longis  margine  scari- 
osis  quam  tubns  corollae  paulo  brevioribns ;  corolla  1.5  cm.  longa 
tnbo  constricto  flavido,  limbi  lobis  ellipticis  6  mm.  longis  2  mm.  latis 
apice  rotundatis  ;  filamentis  antheras  subaequantibus  gracilibus ;  stig- 
mate  capitato-subbilobo.  —  Mexico  :  most  meadow,  Hacienda  of  St. 
Diego,  Chihuabua,  2  June,  1891,  C,  V.  Hartman^  no.  717  (tjrpe,  in 
Gray  Herb.).  This  plant  of  somewhat  striking  tufted  habit  was  dis- 
tributed as  Erythraea  calycosa^  but  differs  from  that  species  rather 
markedly  in  its  lower  stature,  much  smaller  flowers,  and  clustered 
chiefly  1 -flowered  stems. 

Centaurium  nudicaule  (Engelm.),  n.  comb.  Erythraea  nudicaulis 
Engelm.  Proc  Am.  Acad.  xvii.  222  (1882). 

Centaurium  paucifloruxn  (Mart  &  Oal.),  n.  comb.  Erythraea 
paucijiora  Mart.  &  Gal.  Bull.  Acad.  Brux.  xi.  373  (1844). 

Centaurium  Pringleanimi  (Wittr.),  n.  comb.  Erythraea  Pring- 
leana  Wittr.  Bot.  Gaz.  xvi.  85  (1891). 

Centaurium  quitense  (HBK.),  n.  comb.  Erythraea  quitensis 
HBK.  Nov.  Gen.  et  Spec.  iii.  178  (1818).  Cicendia  quitensis  Griseb. 
Linnaea,  xxii.  33  (1849).  Erythraea  divaricata  Schaffner  ex  Schlecht. 
Bot.  Zeit  xiii.  920  (1855).  Erythraea  chilensis  Benth.  PI.  Hartw.  89 
(1842),  non  Pers.  Centaurium  divaricatum  Millsp.  &  Greenm.,  Field 
Columb.  Mus.  Bot  Ser.  ii.  309  (1909). 

Centaurium- retusum  (Rob.  &  Greenm.),  n.  comb.  Erythraea  retusa 
Rob.  &  Greenm.  Proc  Am.  Acad,  xxxii.  38  (1896). 

Centauriimi  setaceimi  (Benth.),  n.  comb.  Erythraea  setacea 
Benth.  Bot  Sulph.  128  (1845). 

Centaurium  tenuifolium  (Mart  &  Gal.),  n.  comb.  Erythraea 
macrantha  fi  major  Hook.  &  Am.  Bot.  Beech.  438  (1841).  E,  tenuifolia 
Mart  &  GaL  Bull  Acad.  Brux.  xi.  372  (1844).  Gyrandra  speciosa 
Benth.  Bot  Sulph.  127,  t  45  (1845). 

Centaurium  triohanthum  (Griseb.),  n.  comb.  Erythraea  tri- 
cantha  Griseb.  Gen.  et  Spec.  Gent  146  (1839). 

Centaurium  venustum  (Gray),  n.  comb.  Erythraea  chironioides 
Torr.  Bot  Mex.  Bound.  156,  t  42  (1859),  not  Gyrandra  chironioides 
Griseb.    Erythraea  venusta  Gray,  Bot  Cali£  i.  479  (1876). 


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398  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

LisiANTHUS  cuspiDATUS  Bertoloni,  Nov.  Comm.  Bonon.  iv.  408, 1 38 
(1840).  Leiantkus  cuspidatus  Griseb.  in  DC.  Prod.  ix.  82  (1845). 
This  species  is  reduced  to  a  synonym  of  Leianthus  nigrescens  (Cham« 
&  Schlecht.)  Griseb.  by  Hemsley,  Biol.  Cent. -Am.  Bot.  ii.  345  (1882) 
and  of  Lisianthtis  nigrescens  Cham.  &  Schlecht.  by  Miss  Perkins  in 
Engl.  Jahrb.  xxxi.  493  (1902).  An  examination  of  Bertoloni's  excellent 
plate  of  his  Lisianthtts  ctispidatus  leads  to  the  belief  that  it  represents 
a  species  markedly  distinct  from  L.  nigrescens.  Conspicuous  differ- 
ences are  to  be  found  in  the  following  features.  In  L.  cuspidutus  the 
leaves  are  narrowed  to  a  subcuneate  base,  the  corolla  is  much  more 
deeply  lobed,  the  lobes  distinctly  surpassing  the  pistil,  while  in  L. 
nigrescens  the  leaves  are  rounded  to  a  sQ^lewhat  amplexicaul  base 
and  the  corolla-lobes  are  only  4-11  mm.  long  being  somewhat  over- 
topped by  the  stigma.  A  specimen,  collected  in  the  Sapoti  Barranca 
near  the  City  of  Guatemala  by  Sutton  Hayes,  July,  1860,  and  now  in 
the  Gray  Herbarium,  corresponds  in  all  respects  to  the  plate  of  Berto- 
loni, and  fully  justifies  the  separation  of  the  species.  The  lobes  of  its 
corolla  are  1.7  6m.  in  length.  Lisianthus  nigrescens  Hook.,  in  Curt. 
Bot.  Mag.  t.  4043,  would  appear  to  be  L.  cuspidatus  Bert. 

Lisianthus  oreopolus,  n.  sp.,  suberectus  7  dm.  vel  ultra  altus 
perennis;  caule  tereti  (juventate  solum  plus  minusve  tretragono) 
levissime  basi  lignescenti;  foliis  sessilibus  lanceolato-oblongis  acumi- 
natis  membranaceis  8-11  cm.  longis  1.5-2.4  cm.  latis  basi  amplexicauli- 
bus  biauriculatis  subtus  pallidioribus  internodia  multo  superantibus ; 
panicula  laxa  3  dm.  longa  2  dm.  diametro ;  ramis  ramulisque  ascen- 
denti-patentibus  saepius  altemis ;  pedicellis  propriis  (supra  bracteolas) 
brevibus  1-2  mm.  longis  saepe  curvatis  ;  calyce  graciliter  ovoideo 
acutiuscule  angulato  1  cm.  longo  fere  a  basi  5-lobo,  lobis  tenuibus  at- 
tenuatis  corollae  appressis ;  corolla  infundibuliformi  4  cm.  longo  gla- 
berrima  flava,  tubo  proprio  gracili,  faucibus  longiusculis  gradatim 
ampliatis,  lobis  1.4-1.6  cm.  longis  lanceolatis  acutissimis  late  paten- 
tibus;  et  staminibus  et  stylo  exsertis;  stigmate  peltate  margine 
revoluto. — Mexico:  Temperate  region,  mountain  of  Chiapas,  flow- 
ering in  June,  Ghiesbreght,  no.  702bi3  (type,  in  Gray  Herb.).  A 
species  in  habit  similar  to  L,  nigrescens  Cham.  &  Schlecht.,  but  dif- 
fering in  its  yellow  corolla  with  considerably  longer  and  much  more 
widely  spreading  lobes. 

Lisianthus  visoidiflorus,  n.  sp.,  erectus  1-1.2  m.  altus  floribus 
exceptis  glaberrimus ;  caule  subtereti  levissimo  angulis  parvis  promi- 
nulis  2  e  costis  mediis  foliorum  decurrentibus  paululo  ancipitali ; 
interuodiis  inferioribus  brevissimis  8-12  mm.  longis,  intermediis  2-6 
cm.  longis,  superioribus  ad  19  cm.  longis;  foliis  lanceolato-oblongis 


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ROBINSON.  —  8PERMATOPHTTES,   NEW   OR   RECXAS8IFIED.        399 

sessilibus  amplexicaulibus  7-12  cm.  longis  1-2.2  dm.  latis  acutis 
crassiosculis  basi  biauricalatis ;  panicala  laxissima  3  dm.  loDga  2-3 
dm.  diametro,  ramis  patenti-ascendentibus  infra  nudis  apice  saepissime 
tricbotomis  3-5-floris,  ramulis  lateialibus  saepius  2-3.5  cm.  longis 
1-floris  apicem  versus  saepissime  arcuatis  bibracteolatis ;  floribus  vis- 
cosis;  calyce  herbaceo  breviter  subcylindrico  basi  turbinate,  lobis 
juventate  acutis  mox  apice  erosis  maturitate  obtusissimis  viscidis; 
corolla  3-3.5  cm.  longa,  tubo  rectiusculo  verisimiliter  atrornbenti, 
limbo  ca.  1  cm.  diametro  viscidissimo,  dentibus  deltoideis  3  mm.  longis 
viridescentibus ;  staminibus  inclusis  ;  stigmate  modice  exserto  peltato. 
— Guatemala:  Coban,  Dept.  Alta  Verapaz,  alt  1350  m.,  August,  1907, 
H,  von  Tuerckheimy  no.  II.  1308  (type,  in  Gray  Herb-).  Distributed  as 
Leianthus  brevidentatua  Hemsl.,  a  species  described  as  having  dense 
inflorescence,  short  pedicels,  shorter  corolla  with  lobes  scarcely  2  mm. 
long,  very  acute  caljrx-lobes  appressed  to  the  corolla,  eta,  differences 
which  would  certainly  appear  to  be  of  specific  valua  It  is,  further- 
more, scarcely  likely  that  the  viscidity  which  is  such  a  conspicuous 
feature  of  the  present  species  could  have  been  present  in  Z.  breviden- 
tatus  in  like  degree  and  have  escaped  mention. 

Schultesia  Hayeedi,  n.  sp.,  annua  erecta  gracilis  3-4  dm.  alta  gla- 
berrima  supra  ramosa ;  radice  fibrosa ;  caule  subtereti  leviter  6-angu- 
lato  foliate ;  foliis  linearibus,  inferioribus  brevibus,  superioribus  4-5  cm. 
longis  2-3  mm.  latis  angustissime  attenuatis  basi  i)aulo  angustatis 
sessilibus  3-nerviis  subtus  pallidioribus ;  ramis  patenti-ascendentibus 
simplicibus  saepissime  altemis  apice  2-bracteolati8  et  1-floris ;  bracteo- 
lis  anguste  linearibus  3  cm.  longis ;  floribus  supra  bracteolas  sessilibus 
4-meris ;  calyce  anguste  ovoideo  3-3.6  cm.  longo,  tubo  castaneo  levis- 
simo  evenio ;  alis  semilanceolatis  3  mm.  latis  viridibus  venosis  sur- 
sum  in  dentes  calycis  subsetaceos  gradatim  attenuatis ;  corolla  4  cm. 
longa  verisimiliter  purpurea,  lobis  late  ovatis  breviter  acuminatis  1  cm. 
longis  ;  ovario  4  angulari  1.4  cm.  longo  4  mm.  lato.  —  Panama  :  Rio 
Grande  Station,  Panama  railway,  13  December,  1859,  Sutton  Hayes, 
no.  160  (type,  in  Gray  Herb.).  This  species  is  closely  related  to  S. 
heterophylla  Miq.  but  differs  in  several  points.  The  stems  are  percep- 
tibly 6-angled ;  the  leaves  are  decidedly  longer  and  relatively  narrower 
than  in  S,  heterophyUa  and  the  middle  ones  equal  or  often  exceed  the 
intemodes,  while  in  S,  heterophyUa  they  are  much  exceeded  by  the 
intemodes.  Finally  the  lobes  of  the  corolla  are  only  1  cm.  long,  i.  e. 
one  third  the  length  of  the  tube,  those  of  S.  heterophyUa  on  the  other 
hand  being  1.6  cm.  long,  i.  e.  more  than  half  the  length  of  the  tube. 

Sohultesia  Peokiana,  n.  sp.,  decumbens,  verisimiliter  annua,  ha- 
bitu  S.  lisianthoidi  similis  6-7  dm.  alta  laxe  ramosa  glaberrima ;  caule 


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400  PROCEEDINGS  OF  THE  AMERICAN  ACADEBIY. 

tereti  laevissimo ;  foliis  lanceolati-ovatis  tenuibus  sessilibus  acutissimis 
basi  rotandatis ;  C3nnis  laxe  etiam  atque  etiam  dicbotomis ;  floribas  in 
dicbotomis  solitariis  1.5  cm.  longis  erectis ;  pedicellis  8-30  mm.  longis 
rectis  nudis ;  calycis  lobis  4  anguste  lanceolatis  aoutissimis  in  media 
parte  berbaceis  margine  scaiiosis  viz  carinatis  ex  alatis ;  corolla  rubes- 
centi  vel  purpurascenti  fere  ad  mediam  partem  4-secta ;  lobis  ovatis 
acutis ;  filamentis  gracilibqs,  basi  exappendiculatis ;  antberis  mucro- 
natis.  —  British  Honduras  :  about  plantations  and  in  the  openings 
of  the  forests,  near  Manatee  Lagoon,  27  January,  1906,  Prof,  Morton 
E,  Peck^  no.  318  (tjrpe,  in  Gray  Herb.).  A  species  considerably  resem- 
bling S.  Usianthoides  (Griseb.)  Benth.  &  Hook  £,  but  readily  distin- 
guished by  its  pedicelled  flowers.  * 

Evolvulus  serioeus  Sw.,  var.  firlaberrimus,  n.  var.,  ubique  gla- 
berrimus  gracillimus,  caulibus  a  basi  patenti-ramosis  suberectis  2.5-3 
dm.  altis ;  calyce  etiam  glaberrimo,  alitor  formae  typicae  simillimus.  — 
British  Honduras  :  low  pine  ridge  near  Manatee  Lagoon,  28  March, 
1906,  Prqf.  Morton  E.  Peck,  no.  372  (type,  in  Gray  Herb.).  A  form 
remarkable  for  the  complete  absence  of  the  silky  pubescence,  which  is 
to  some  extent  present  in  all  other  specimens  examined,  even  those  of 
the  form  glabratus  Ghod.  &.  HassL,  which  has  decidedly  silky-villous 
calyces. 

Sohwenkia  oxyoarpa,  n.  sp.,  perennis  erecta  sufirutescens  seoparia 
5-6  dm.  alta;  radice  fibrosa;  caulibus  teretibus  cortice  fusco-griseo 
obtectis ;  ramis  gracillimis  ascendentibus  vel  erectis  viridibus  teretibus ; 
foliis  linearibus  acutis  sessilibus  crassiusculis  subglabris  5-7  mm. 
longis  vix  1  mm.  latis  saepissime  curvatis  vel  tortis  l-nerviis;  inflo- 
rescentia  ca.  1  dm.  longa  gracillima  spiciformi;  floribus  fiai^iculatis 
sessilibus  parvis ;  calyce  turbinate  ca.  1.3  mm.  longo  obscure  strigilloso, 
dentibus  lanceolatis  acutis  tubum  subaequantibus ;  corolla  4  mm.  longa 
atrocyanea  rectiuscula,  limbi  dentibus  5  clavellatis  quam  sinuum  lobi 
obovati  crassinsculi  subbipartiti  vix  longioribus ;  staminibus  fertilibus 
4  didynamis  tubo  corollae  inclusis ;  capsula  lanceolato-ovoidea  acuta 
2  mm.  longa  firmiuscula  minute  papillosa.  —  British  Honduras  :  open 
damp  ground,  near  Sibune  River,  4  May,  1906,  Prof.  Morton  E,  Peck^ 
no.  417a  (type,  in  Gray  Herb.).  This  noteworthy  species,  through  some 
accident  associated  with  no.  417  (an  Angelonia),  is  clearly  of  §  Brachy- 
helus  and  most  nearly  approaches  the  east  Brazilian  S,  fascictUata 
BentL  It  differs,  however,  in  its  essentially  glabrous  stem  and  rha- 
chises,  its  never  fascicled  leaves  neither  perceptibly  cuneate  at  the  base 
nor  revolute  on  the  margin,  and  finally  in  its  lance-ovoid  capsule. 

Angelonia  ciliaris,  n.  sp.,  caulibus  gracilibus  inaequaliter  4-angn- 
latis  in  angulis  conspicue  ciliatis ;  foliis  sessilibus  oblongo-lanceolatis 


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ROBINSON. — 8PERMATOPHTTES,    NEW   OR   RECLASSIFIED.        401 

acutis  basi  vix  angastatis  rotnndatis  2-2.5  cm.  loDgis  ca.  5  mm.  latis 
serratis  supra  laxe  villosis  margine  ciliatis  subtus  in  costa  media  solum 
longiusoule  ciliatis  aliter  glabris;  foliis  floralibus  late  ovatis  acutis 
subcordatis  conspicue  loDgeqne  ciliatis,  inferioribus  ca.  1  cm.  longis 
pedicellum  subaequantibus,  superioribus  ca.  3  mm.  longis  pedicello 
triplo  brevioribus ;  ramis  inflorescentiae  ca.  1.  dm.  longis  racemiformi- 
bus,  pedicellis  oppositis  ascendenti-patentibus  filiformibus  ca.  1  cm. 
longis  apice  nutantibas ;  calycis  segmentis  lanceolatis  acuminatis  3.5 
mm.  longis ;  corolla  ca.  1  cm.  diametro,  sacco  lato,  appendice  interiori 
ca.  0.7  mm.  longa;  capsula  depresse  globosa  5  mm.  diametro. — 
British  Honduras  :  on  open  damp  ground,  near  Sibune  River,  4  May, 
1906,  Prof.  Morton  E,  Peck,  no.  417  (type,  in  Gray  Herb.).  This 
species  differs  firom  A.  angustifoUa  Benth.  ip  its  conspicuously  ciliated 
stem  and  leaves,  broader-based  bracts,  and  smaller  flowers;  from 
A,  salicarux^olia  H.  &  B.  it  may  be  readily  distinguished  by  its 
smaller  flowers  and  much  more  sparing  pubescence  of  much  longer 
non-glandular  hairs. 

Isidorea  pungens  (Lam.),^  n.  comb.  Emodea  pungens  Lam.  111. 
I  276  (1791).  E.  pedunculata  Poir.  Encyc.  Suppl.  ii.  581  (1811). 
Isidorea  amoena  A.  Rich.  M^m.  sur  les  Rubiac^es,  204,  t.  15,  f.  1 
(1829),  and  M^m.  Soc.  Hist.  Nat  Par.  v.  284,  t.  25  (1834). 

Bikkia  oampanulata  (Brong.),  n.  comb.  Grisia  campanulata 
Brong.  Bull  Soc.  Bot.  Fr.  xii.  406  (1865). 

Bikkia  Pancheri  (Brong.),  n.  comb.  Bikkiopsis  Pancheri  Brong. 
L  c.  405. 

Bikkia  retosiflora  (Brong.),  n.  comb.  Grisia  retusiflora  Brong. 
1.  c.  407. 

Houstonia  xnuoronata  (Benth.),  n.  comb.  Hedyotis  mtwronata 
Benth.  Bot.  Sulph.  19  (1844).  Houstonia  fruticosa  Rose,  Contrib. 
U.  S.  Nat.  Herb.  L  132  (1890),  239  (1893);  Greenman,  Proa  Am. 
Acad,  xxxii.  292  (1897). 

Houstonia  umbratilis,  n.  sp.,  herbacea  repens  multicaulis  ramosa 
obscure  strigillosa ;  caulibus  gracillimis  interplexis  subquadrangularibus 
foliosis,  nodis  radicantibus,  intemodiis  2-8  mm.  longis ;  foliis  parvis 
ovatis  membranaceis  acutiusculis  brevissime  petiolatis  utrinque  strigil- 
losis  subtus  paululo  pallidioribus  uninerviis  obscure  reticulato-venosis 
2.5-4  mm.  longis  1.8-3  mm.  latis,  stipulis  brevissimis;  pedunculis 
filiformibus  1.5  cm.  longis  terminalibus  1-floris;  calyce  basi  turbinate, 
tubo  lobos  ovato-lanceolatos  acutiusculos  anthesi  aequante;  corolla 
infundibuliformi  in  siccitate  nigrescenti,  tubo  5  mm.  longo,  lobis  ovatis 
patentibus;  staminibus  4  (eis  speciminis  observati  exsertis,  antheris 
lineari-oblongis  filamenta  aequantibus) ;  fructu  seminibusque  ignotis. 

VOL.  XLV. — 26 


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402  PROCEEDINGS   OP    THE   AMERICAN   ACADEMY. 

—  Mexico  :  shaded  cliffs  of  mountains,  near  Monterey,  Nuevo  Leon, 
25  April,  1906,  C.  G.  Pringle,  no.  13,877  (type,  in  Gray  Herb.).  An 
attractive  little  matted  plant  with  the  habit  of  H,  serpyllifolia  Michx. 
and  H.  serpyUacea  (Schlecht.)  C.  L.  Sm.  but  differing  from  the  former 
in  its  more  shortly  petioled,  more  acute  leaves,  and  much  smaller 
flowers,  and  from  the  latter  in  its  membranaceous  strigillose  but 
unciliated  leaves,  more  filiform  stems,  etc.  The  absence  of  fruit  and 
seeds  naturally  throws  a  slight  doubt  upon  the  generic  position,  but 
the  general  habit,  as  well  as  such  technical  traits  as  are  manifest,  aie 
those  of  Houstonia, 

Neuroocdyx  calyoimis  (R.  Br.),  n.  comb.  Argostemma  calycinum 
R.  Br.  in  Bennett,  PL  Jav.  Rar.  97  (1838).  Nmrocalyx  Wightii  Am. 
Ann.  Nat.  Hist  iii.  22  (;839).  N.  Hookeriana  Wightj  Ic.  i.  t  52 
(1840). 

Bondeletia  leptodictya,  n.  sp.,  fruticosa  2  m.  alta ;  ramis  gra- 
cilibus  rubro-brunneis  flexuosis  teretibus  mox  glabratis ;  foliis  oppositis 
obovato-oblongis  acuminatis  basi  modice  angustatis  tenuibus  supra 
viridibus  tenuiter  (sub  lente)  reticulatis  glabris  vel  subglabris  subtus 
juventate  griseo-tomentosis  6-11  cm.  longis  2.5-5  cm.  latis;  petiolis 
gracilibus  5-12  mm.  longis  pubescentibus ;  stipulis  ovato-lanceolatis 
acutis  brunneis  4  mm.  longis  erectis ;  pedunculis  terminalibus  4-5.5  cm. 
longis  gracilibus  arachnoideis ;  floribus  sessilibus  dense  capitatis; 
calycis  tubo  albo-lanato  subgloboso  1.8  mm.  diametro,  lobis  limbi 
4  vix  inaequalibus  oblanceolatis  viridibus  vix  2  mm.  longis;  corolla 
sanguinea,  tubo  gracili  sursum  vix  ampliato  1.4  cm.  longo  griseo- 
arachnoideo,  lobis  limbi  4  patentibus  2-3  mm.  longis,  ore  nudo ;  stylo 
exserto.  —  Mexico  :  banks  of  the  Rio  Petatlan  near  the  boundary 
between  Michoacan  and  Guerrero,  alt.  500  m.,  24  November,  1898, 
E,  Langlass^^  no.  666  (t)rpe,  in  Gray  Herb.).  Near  R.  eUmgata  BartL, 
but  with  calyx-lobes  much  shorter  (scarcely  a  fifth  the  length  of  the 
corolla-tube),  the  limb  of  the  corolla  smaller,  and  the  stipules  much 
shorter  than  the  petioles. 

Bondeletia  rufescens,  n.  sp.,  fruticosa;  ramis  teretibus  tarde 
glabratis  cortice  griseo  tectis,  ramulis  et  pedunculis  et  petiolis  dense 
rufo-tomentosis ;  foliis  lanceolato-oblongis  9-15  cm.  longis  3.2-5  cm. 
latis  apice  basique  acuminatis  tenuibus  supra  obscure  reticulatis  et 
moUiter  puberulis  subtus  albido-tomentosis,  nerviis  lateralibus  ca. 
lO-jugis ;  inflorescentiis  terminalibus  thyrsoideis  flexuosis  ca.  1.5  dm. 
longis  rufo-tomentosis ;  cymulis  superioribus  subsessilibus  inferioribus 
2-12  mm.  longe  pedicellatis  bracteis  lineari-subulatis  ca.  3  mm.  longis 
suffultis  multifloris;  floribus  brevissime  pedicellatis  aut  sessilibus; 
calycis  tubo  subgloboso  minute  hirsute,  lobis  4  linearibus  inaequalibus 


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ROBINSON.  —  SPERMATOPHYTES,    NEW   OR   RECLASSIFIED.        403 

intus  glabris ;  corollae  tube  gracillimo  in  &Qces  distincte  ampliato 
appresse  griseo-puberalo  vel  arachnoideo  1  cm.  longo ;  limbi  lobis 
4  suborbicularibus  1  mm.  longis  extus  rufo-hispidulis  intus  et  ore 
nudis ;  stylo  i)aulo  exserto,  apice  bifido  nigro.  —  Bonddetia  J.  D.  Sm. 
Enum.  PL  Guat  L  16  (1889).  R,  villosa  J.  D.  Sm.  1.  c.  ii.  94  (1891), 
not  HemsL  —  Guatemala  :  Coban,  Depart.  Alta  Verapaz,  alt  1475  m., 
March,  1881,  H,  von  Tuerckheim,  no.  582  of  Mr.  J.  Donnell  Smith's  dis- 
tribution (type,  in  Gray  Herb.).  This  plant  is  clearly  distinct  from 
B.  villosa  HemsL,  which  has  considerably  broader  (ovate)  stipules  and 
a  very  different  closely  matted  white  pubescence  on  the  lower  sur&ce 
of  the  leaves,  a  more  slender  and  denser  inflorescence,  etc. 

Var.  ovata.,  n.  var.,  minus  rufescens ;  foliis  ovatis  brevioribus  7-9  cm. 
longis  basi  rotundatis,  aliter  formae  t3rpicae  similis. — B.  villosa^ 
forma  strigosissima  J.  D.  Sm.  Enum.  PL  Guat.  vii.  15  (1905),  nomen.  — 
Guatemala  :  Tactic,  Depart  Alta  Verapaz,  alt  550  m.,  March,  1903, 
If,  von  Tuerckheim,  no.  8401  of  Mr.  J.  Donnell  Smith's  distribution. 

Rondeletia  seoundiflora,  n.  sp.,  arborescens ;  ramulis  gracilibus 
teretibus  dense  griseo-strigillosis ;  foliis  ovato-lanceolatis  apice  basique 
acuminatis  tenuissimis  7-9  cm.  longis  2-3.5  cm.  latis  utrinque  appresse 
pilosiusculis  subtus  paulo  pallidioribus,  nerviis  ca.  8-jugis;  petiolo 
gracili  4-6  mm.  longo  griseo-piloso ;  stipulis  a  basi  deltoidea  subulatis 
2  mm.  longis ;  inflorescentiis  6-8  cm.  longis  spiciformibus  plus  minusve 
recurvis  valde  secundis,  rhachi  hirsutulo,  C3rmulis  parvis  subsessilibus 
paucifloris  numerosis ;  floribus  deflexis ;  cidycis  tubo  subgloboso  dense 
patentimque  sordido-hirsuto,  lobis  4  modice  inaequalibus  minus  dense 
indutis  1.4-2  mm.  longis  erectis  spatulato-linearibus  vel  anguste 
lanceolatis ;  corolla  9  mm.  longa  extus  strigillosa,  tubo  gracili  cylin- 
drica,  limbo  4-lobo,  lobis  suborbicularibus  patulis  1.3  mm.  diametro, 
ore  nudo.  —  Guatemala:  in  woods,  cJong  the  road  ftom  Patin  to 
Esquintla,  21  July,  1860,  Dr,  Sutton  Hayes  (t3T)e,  in  Gray  Herb.). 
This  species  is  obviously  related  to  B  capitellata  HemsL  but  may  be 
readily  distinguished  by  the  shaggy-hirsute  tube  and  lance-linear  or 
spatulate  lobes  of  the  calyx. 

Rondeletia  septioidalis,  n.  sp.,  fruticosa;  ramis  teretibus  plus 
minusve  flexuosis  griseo-brunneis ;  foliis  oppositis  ovatis  vel  lan- 
ceolato-ovatis  apice  basique  acuminatis  firmiusculis  11-16  cm. 
longis  2-7  cm.  latis  utrinque  viridibus  subtus  pallidioribus  supra 
glaberrimis  subtus  basin  versus  obscure  pilosulis,  nerviis  lateralibus 
ca.  8-jugi8,  petiolo  1-2.3  cm.  longo  glabro  vel  glabriusculo;  stipulis 
anguste  lanceolatis  glabris  5  mm.  longis  acutis;  inflorescentiis  in 
axillis  superioribus  spiciformibus  1-1.5  dm.  longis,  pedunculo  1.5- 
3.5  cm.  longo  gracili  tereti,  rhachi  simillimo  obscure  arachnoideo; 


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404  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

cymuHs  vulgatim  2-3-floris  breviter  pedicellatis  bracteoHs  linearibas 
suffultis;  calyce  angnste  campanulato  basi  turbinate,  tube  griseo 
arachnoideo,  lobis  4  lanceolato-linearibus  deflexis  modice  iDaeqaalibus 
tubum  subaequantibus  glabriusculis ;  corolla  coccinea,  tubo  gracili 
suboylindrico  sarsum  paulo  ampliato  basin  versus  glabriusculo  supra 
cum  limbo  patente  plus  i](iinusve  arachnoideo  ca.  17  cm.  longo,  lobis 
4  orbicularibus  ca.  3  mm.  diametro  tenuiter  margine  crispulis;  ore 
nudo ;  staminibus  4  in  ore  affixis  paulo  exsertis,  antheris  lineari- 
oblongis;  capsula  subglobosa  ca.  4  mm.  diametro  septicidali,  valvis 
bifidis.  —  Mexico  :  Chicharras,  Chiapas,  alt.  920-1840  m.,  E.  W.  Nel- 
8on^  no.  3Y55  (tjrpe  material  in  U.  S.  Nat  Mus.  and  Gray  Herb.). 
This  plant  possesses  so  precisely  the  habit  and  most  of  the  technical 
features  of  a  Ronddetia  that  it  seems  best  to  refer*  it  to  this  genus, 
though  it  will  form  an  exception  among  the  known  species  in  the  fstct 
that  its  fruit  is  septicidaL 

Hymenodiotyon  floribundum  (Hochst.  &  Steud.),  n.  comb. 
Kurria  floribunda  Hochst  &  Steud.  Flora,  xxiv.  pt  1,  Intell.  28 
(1841),  name  only ;  ibid.  xxv.  234  (1842),  with  description.  Uymeno- 
dictyon  Kurria  Hochst  Flora,  xxvi.  71  (1843). 

Bouvardia  gracilipes,  n.  sp.,  fruticosa ;  ramis  gracilibus  teretibus 
cortice  griseo  tectis  glabris,  ramulis  valde  compressis,  intemodiis  lon- 
giusculis  glabris,  nodis  stipulisque  puberulis ;  foliis  oppositis  breviter 
petiolatis  tenuibus  ovatis  acuminatis  basi  rotundatis  5-7  cm.  longis 
2-3.5  cm.  latis  supra  laete  viridibus  glabris  subtus  pallidioribus  in 
oosta  venisque  obscure  puberulis ;  petiole  2  mm.  longo  sordide  tomen- 
tello;  ocreis  pallidis  ca.  1  mm.  longis  marginem  versus  tomentellis 
cum  appendicibus  filiformibus  breviter  pubescentibus  ca.  2  mm.  longis 
munitis  ;  inflorescentiis  terminalibus  laxis  8-12-floris  glabris ;  pedun- 
culis  2-4  cm.  longis  trichotomis,  bracteis  linearibus  1-3  mm.  longis, 
ramulis  lateralibus  3-4  cm.  longis  vicissim  trichotomis ;  pedicellis  fili- 
formibus 1.5-2  cm.  longis  apice  denique  uncinatis ;  calycis  dentibus 
4  linearibus  1  mm.  longis  erectis  in  fiructu  inflexis  persistentibus ; 
corolla  non  visa ;  fructu  6  mm.  lato  4.5  mm.  alto  pallide  viridi  sub 
lente  albido-lineato  quasi  strigilloso.  —  Mexico  :  Tepic,  5  January  to 
6  February,  1892,  Dr.  E.  Palmer,  no.  1971  (type,  in  Gray  Herb.). 
Although  this  species  is  described  from  fruiting  material  and  without 
knowledge  of  the  corolla,  it  is  believed  that  the  unusually  loose  inflor- 
escence with  filiform  at  length  hooked  pedicels  yields  characters  suffi- 
ciently distinctive  for  ready  recognition. 

Bouvardia  longiflora  (Cav.)  HBK.,  var.  indutci,  n.  var.,  foliis 
ovato-rhomboideis  acutis  supra  scabriusculo-puberulis  subtus  tomen- 
tosis ;   corolla  extus   tomentella.  —  Mexico  :    "  Chiapas,    etc."  Dr. 


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ROBINSON.  —  SPERMATOPHYTES,    NEW   OR   RECLASSIFIED.        405 

Ghiesbreghty  the  specimen  associated  la  the  Gray  Herbariam  with 
Ghiesbreght's  nos.  108  and  692  which,  however,  represent  the  more 
t3rpical  form  of  the  species,  being  nearly  glabrous.  Forms  to  some  ex- 
tent intermediate  in  their  pubescence  and  somewhat  peculiar  in  their 
thinnish  mostly  obtusish  leaves  are  shown  by  Langlass^'s  no.  1049  from 
near  the  boundary  of  Michoacan  and  Guerrero,  as  well  as  by  Purpus's 
no.  1249  from  Tehuacan,  Puebla. 

BouvARDiA  TERNiFOLiA  (Cav.)  Schlecht.,  var.  angustifolia  (HBK.), 
n.  comb.  B.  aiigustifolia  HBK.  Nov.  Gen.  et  Spec.  iii.  384  (1818). 
B.  tripkylla,  var.  angustifolia  Gray,  Syn.  FL  i.  pt  2,  24  (1884).  Al- 
though B.  angustifolia  HBK.  has  been  treated  as  an  independent  species 
in  various  works  of  recent  date,  an  increasingly  complete  series  of  in- 
tergrading  specimens  leaves  no  doubt  that  Dr.  Gray  was  right  in  re- 
garding this  plant  as  merely  a  variety.  Priority  of  the  specific  name 
of  Cavanilles  requires  the  new  combination. 

Lygistum  ignitum  (Veil.)  Ktze.,  var.  micans  (K.  Schum.),  n. 
comb.  Manettia  ignita^  var.  micans  K.  Schum.  in  Mart.  FL  Bras.  vi. 
pt  6,  171  (1889). 

Lygistiim  Bojasianum  (Ghod.  &  Hass.),  n.  comb.  Manettia 
Bcjasiana  Chod.  &  Hass.  Bull.  Herb.  Boiss.  ser.  2,  iv.  91  (1904). 

Lygistum  Smithii  (Sprague),  n.  comb.  Manettia  Smithii  Sprague, 
Bull.  Herb.  Boiss.  ser.  2,  v.  267  (1905). 

Qonzalagxinia  bracteosa  (J.  D.  Sm.),  n.  comb.  Gonzalea  brae- 
teosa  J.  D.  Sm.  Bot  Gaz.  xxxiii.  252  (1902). 

Qonzalagxinia  leptantha  (A.  Rich.),  n.  comb.  Gonzalea  leptan- 
tha  A.  Rich.  FL  Cub.  Fanerog.  ii.  16  (1853). 

Qonzalagiinia  ovatifolia  (J.  D.  Sm.),  n.  comb.  Gonzalea  ovatifo- 
Ua  J.  D.  Sm.  Bot.  Gaz.  xxvii.  336  (1899). 

Qonzalagunia  Petesia  (Griseb.),  n.  comb.  Gonzalea  Petesia 
Griseb.  Mem.  Amer.  Acad,  new  ser.  viii.  504  (1863).  Gonzalagunia 
hirsuta  y  Petesia  Ktze.  Rev.  Gen.  i.  284  (1891). 

QoDzalagunia  thyrsoidea  (J.  D.  Sm.),  n.  comb.  Gonzalea  thyrsoi- 
dea  J.  D.  Sm.  Bot  Gaz.  xiii.  188  (1888). 

Tarenna  mollis  (Wall.),  n.  comb.  Rondeletia  1  mollis  Wall.  Cat. 
no.  8454  (1847).  Webera  mollis  Hook,  f.,  FL  Brit.  Ind.  iii.  104 
(1882). 

Tarenna  mollissima  (Hook.  &  Arn.),  n.  comb.  Cupia  mollissima 
Hook.  &  Am.  Bot.  Beech.  192 '(1833).  Stylocorine  mollissima  Walp. 
Rep.  ii.  517  (1843).  Webera  mollissima  Benth.  ex  Hance,  Jour.  Linn. 
Soc.  xiii.  105  (1873). 

Tarenna  odorata  (Roxb.),  n.  comb.  Webera  odorata  Roxb.  Hort 
Bengal.  15  (1814),  and  FL  Ind.  L  699  (1832).     Cupia  odorata  DC. 


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406  PROCEEDINGS   OF  THE   AMERICAN   ACADEHT. 

Prod.  IV.  394  (1830).     Webera  macropkj/lla  Roxb.  Hort  Bengal  85 
(1814),  and  R  Ind.  i.  697  (1832).     Cupia  macrophylla  DC,  L  a 

Casasia  nigrescens  Wright  in  herb.  Randia  nigrescens  Griseb. 
Cat  PL  Cub.  123  (1866),  where  the  combination  Casasia  nigrescens 
Wright  is  implied  though  not  definitely  made.  Randia  nigrescens 
Wright  &  Sauvalle,  PL  Cub.  60  (1873).  Randia  nigricans  K.  Schum. 
in  Engl.  &  Prantl,  Nat.  Pflanzenf.  iv.  Abt.  4,  77  (1891),  by  obvious 
clerical  error. 

Hamelia  hsrpomala^a,  n.  sp.,  fruticosa  ramosa ;  ramis  curvatis 
teretibus  cortice  brunneo-griseo  lenticellifero  tectis;  ramulis  dense 
tomentellis;  foliis  temis  ovalibus  obtuse  acuminatis  basi  brevissime 
acuminatis  saepe  inaequilateralibus  6.5-9  cm.  longis  4-5.5  cm.  latis 
membranaceis  supra  laete  viridibus  obscure  puberulis  subtus  multo 
pallidioribus  molliter  griseo-tomentellis  vel  denique  glabrescentibus ; 
petiole  gracili  ca.  2  cm.  longo  tomentello ;  cymis  terminalibus  ca.  9-floris 
modice  laxis  tomentellis,  ramis  recurvis,  pedicellis  2-9  mm.  longis ; 
floribus  pro  genere  majusculis ;  calyce  tomentello,  dentibus  brevibus 
subulatis ;  corolla  flava  4  cm.  longa,  tubo  proprio  brevi,  faucibus  longis 
ampliatis,  limbi  lobis  5  late  ovatis  acuminati-mucronatis ;  iructu  im- 
mature ca.  8  mm.  longo.  —  Mexico  :  State  of  Durango,  15  August, 
1897,  Dr.  J,  N.  Rose,  no.  2304  (type,  in  U.  S.  Nat.  Mus.  and  Gray 
Herb.).  Closely  related  to  H.  ventricosa  Sw.,  but  readily  distinguished 
by  its  tomentulose  leaves,  loose  inflorescence,  and  somewhat  smaller 
flowers. 

Hoffinannia  Conzattii»  n.  sp.,  fruticosa  glabra ;  ramis  subteretibus 
obsolete  solum  et  obtuse  subtetragonis  apicem  versus  foliatis  deorsum 
longe  floriferis  ;  foliis  obovato-  vel  oblanceolato-oblongis  breviter  cau- 
dato-acuminatis  basi  longe  attenuatis  tenuiter  membranaceis  utrinque 
glaberrimis  supra  in  siccitate  nigrescentibus  subtus  pallidioribus  viri- 
dibus 11-16  cm.  longis  3.5-6  cm.  latis;  costa  media  supra  impressa, 
nerviis  lateralibus  ca.  8-jugis  oppositis  vel  alternis ;  petiole  1.8-2.5  cm. 
longo  glabro ;  stipulis  ovatis  caducis ;  cymis  subsessilibus  oppositis 
lateralibus  numerosis  subapproximatis  ca.  6*floris ;  pedicellis  calycem 
subaequantibus ;  tubo  calycis  subgloboso  2.5  mm.  longo,  limbo  brevi- 
ter patentimque  4-dentato  ;  corolla  ca.  6  mm.  longa  ad  mediam  partem 
4-fida,  lobis  anguste  oblongis  saepissime  patentibus  ;  antheris  anguste 
oblongis  exsertis ;  fiructu  ignoto.  —  Mexico  :  Colonia  Melchor  Ocampo, 
Canton  de  C6rdoba,  Vera  Cruz,  alt  120^  m.,  Prof.  C.  Conzatti,  19  June, 
1896,  no.  168  (typey  in  Gray  Herb.).  This  species  in  foliage  closely 
resembles  II.  calycosa  J.  D.  Sm.,  but  is  readily  distinguished  by  its  ex- 
ceedingly short  caljrx-lobes.  Prom  H.  Ghiesbreghtii  (Lem.)  HemsL  it 
difiers  in  its  subterete  wingless  branches.     H,  longepetiolata  Polak. 


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Goot 


ROBINSON. — ^  SPERMATOPHTTES,    NEW  OR   RECLASSIFIED.        407 

appears  by  its  description  to  have  longer  petioles  and  considerably 
larger  flowers. 

Hoffmannia  cuneatissima,  n.  sp.,  fraticosa ;  ramis  teretibus  gri- 
seis  etiam  in  lignescentia  cum  pilis  brevibus  crispis  rufescentibus  deni- 
que  sparsis  inconspicuisque  tectis ;  foliis  oppositis  vel  temis  deflexis 
tenuibus  acuminatis  oblanceolatis  1-1.6  dm.  longis  3-4.5  cm.  latis  basi 
longissime  coneatis  supra  glabriusculis  subtus  paulo  pallidioribus 
praesertim  in  nerviis  venisque  crispe  puberulis;  cymis  axillaribus 
pedunculatis  4-8-floris ;  pedunculis  ad  ca.  1  cm.  longis  ascendentibus 
gracilibus  rufo-pubescentibus  ;  pedicellis  1-2  mm.  longis ;  calyce  turbi- 
nato-subtereti  2  mm.  longo  crispe  pubescenti,  limbi  dentibus  4  lanceo- 
lati-deltoideis  primo  suberectis  denique  patentibus  ca.  1.2  mm.  longis 
cum  denticulis  4  minimis  glandulosis  altemantibus ;  corolla  flavida 
extus  puberula  ca.  1  cm.  longa  ad  mediam  partem  4-fida;  lobis 
oblongis  obtusiusculis  in  media  parte  crassiusculis  dorso  carinatis 
carina  crispe  puberula ;  bacca  nigrescenti  5  mm.  diametro ;  seminibns 
numerosis  brunneis  compressiusculis  fovcolatis.  —  Mexico  :  mountain 
cafion  near  Cuemavaca,  alt.  200  m.,  29  May,  1898,  C.  G,  Pringle,  no.  7662 
(type,  in  Gray  Herb.);  and  previously  in  the  same  locality,  20  Nov.,  1895, 
a  G,  Pringle,  no.  7075  (Gray  Herb.)  and  31  July,  1896,  C.  G.  Pringle, 
no.  7248  (Gray  Herb.).  This  species  belongs  clearly  to  the  same 
group  as  H,  affinis  Hemsl.  and  H,  lenticellata  HemsL,  but  with  its  thin, 
thoroughly  membranaceous  leaves  and  rufous-pubescent  branches  can- 
not well  be  placed  in  either  of  these  species. 

Hoffinannia  Bosei,  n.  sp.,  fruticosa  3  m.  alta ;  ramis  flexuosis  dense 
pulverulo-puberulis  et  obscure  strigillosis,  intemodiis  brevibus  5-12 
mm.  solum  longis ;  foliis  oppositis  oblanceolatis  membranaceis  acumi- 
natis basi  longe  attenuatis  6-12  cm.  longis  3.4-5  cm.  latis  utrinque 
obscure  strigilloso-puberulis  vel  supra  glabriusculis  subtus  in  costa  et 
nerviis  lateralibus  dense  minuteque  pulverulo-puberulis ;  cymis  axil- 
laribus oppositis  graciliter  pedunculatis  5-9-floris  subcircinatis;  pedun- 
culis 1-1.3  cm.  longis  pulverulis  rubescentibus ;  pedicellis  similibus  ca. 
2  mm.  longis ;  calyce  ovoideo  strigilloso,  dentibus  4  brevibus  anguste 
deltoideis  cum  glandulis  4  parvis  altemantibus ;  corolla  alba  7  mm. 
longa  pulverula  ad  partem  paulo  infra  mediam  4-fida,  lobis  limbi 
oblongis  acutis  tenuibus  nee  carinatis  nee  pubescentibus.  —  Mexico  : 
along  a  brook  near  Pedro  Paulo,  Topic,  3  August,  1897,  Dr,  J.  N, 
Rose^  no.  1968  (t3rpe,  in  U.  S.  Nat  Mus.  and  Gray  Herb.).  Very  near 
H.  cuneatissima,  described  above,  but  with  opposite  leaves,  mere 
puberulence  instead  of  pubescence,  and  unkeeled  corolla-lobes. 

Antirrhoea  chinenBis  (Champ.),  n.  comb.  Gtiettardella  chinensis 
Champ,  in  Hook.  Kew.  Joum.  Bot.  iv.  197  (1852). 


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408  PROCEEDINGS  OF  THE  AMERICAN  ACADEBfT. 

Timonius  polygamus  (Forst),  n.  comb.  Erithalis  polygama 
Forst.  Prod.  17  (1786).  E.  obouata  Forst.  L  c.  98,  mere  mention 
in  index.  Timonius  Forsteri  DC.  Prod.  iv.  461  (1830) ;  Drake  del 
Castillo,  IlL  FL  Ins.  Pacifl  193  (1890),  which  see  for  further 
synonymy. 

Stylooorine  alpestris  (Wight),  n.  comb.  Pavetta  1  lucem  R.  Br.  in 
Wall  Cat  no.  6168  (1828),  name  only.  Coffea  alpestris  Wight,  Ic.  t 
1040  (1848-1856).  Webera  lucens  Hook.  f.  FL  Brit.  Ind.  iil  106 
(1882)',  as  to  var.  1.  Stylocorine  breviflora  Schlecht.  ex  Hook.  £,  1.  c.  — 
Foliis  oblanceolatis.  Var.  grumelioides  (Wight),  n.  comb.  Coffea 
grumelioides  Wight^  Ic.  t.  1041  (1848-1856).  Webera  lucens  Hook, 
f.,  L  c.  as  to  var.  2.  —  Foliis  obovatis. 

Stylooorine  longifolia  (G.  Don),  n.  comb.  Ixora  macrophyUa  R. 
Br.  in  Wall.  Cat  no.  6165  (1828),  name  only,  not  BartL  Ixora  longi- 
folia G.  Don  Syst  iii  573  (1834).  Pavetta  longifolia  Miq.  R  Ind. 
Bot  iii.  275  (1856-1859).  Webera  longifolia  Hook.  f.  FL  Brit  Ind. 
iil  105(1882). 

Rudgea  crassiloba  (Benth.),  n.  comb.  Coffea  crassiloba  BentL  in 
Hook.  Jour.  Bot  iii.  233  (1841).  Budgea  Schomburgkiana  Benth. 
Linnaea,  xxiii.  459  (1850). 

Cephaelis  elata  Sw.  Prod.  45  (1 788).  Here  apparently  belongs  Ceph- 
afc^  j[?Mn«cfti  VahI.,EcIog.i.  19  (1796)and  consequently  Uragoga punicea 
K.  Schum.  in  Engl.  &  Prantl,  Nat  Pflanzenf.  iv.  Abt  4,  120  (1891),  a 
name  which,  through  apparent  clerical  error,  has  been  cited  by  Durand 
&  Jackson,  Ind.  Kew.  Suppl.  1,  445  (1906),  as  "  Uragoga  phoenicea 
K.  Schum,"  a  combination  said  by  them  to  equal  ^^Palicourea  punicea 
R.  &  P."  However,  Ruiz  &  Pavon  do  not  appear  to  have  created  any 
8uch  binomial,  though  DeCandoUe's  Palicourea  punicea  (Prod.  iv.  526, 
1830)  was  based  upon  Psychotria  punicea  R.  &  P.  Fl.  Per.  ii.  62,  t 
212  fig.  a  (1799),  a  species  obviously  not  of  Cephaelis,  Schumann's 
"  Uragoga  phoenicea,''  which  seems  never  to  have  been  published  by 
its  supposed  author,  appears  to  have  given  rise  to  Cephaelis  phoenicea 
J.  D.  Sm.  PI.  Guat  v.  39  (1899),  which  as  to  plants  cited  is  clearly 
C  elata  Sw. 

Cephaelis  sphaerooephala  (Muell.  Arg.),  n.  comb.  Psychotria 
sphaerocepkala  Muell.  Arg.  Flora,  lix.  550,  553  (1876). 

Nertera  Amottianisjia  (Walp.),  n.  comb.  Leptostigma  Amottia- 
num  Walp.  Rep.  ii.  463  (1843).  Hedyotis  repens  Clos'in  Gay,  FL  Chil. 
iii.  208  (1847).  Coprosma  calycina  Gray,  Proc.  Am.  Acad.  iv.  306 
(1860). 

Coprosma  australis  (A.  Rich.),  n.  comb.  Ronabea  ?  australis  A. 
Rich.  Voy.  Astrolabe  Bot  i.  265  (1832).     Coprosma  grandifolia  Hook. 


Digitized  by 


ROBINSON.  —  SPERMATOPHTTES,    NEW   OR   RECLASSIFIED.        409 

f.  Fl  N.  Z.  L  104  (1853).  Pelaphia  grandifolia  Banks  &  Soland.  ex 
HooL  f.,  1.  c. 

Coprosma  quadriflda  (Labill.),  n.  comb.  Ganthium  quadrifidum 
Labill.  Nov.  HolL  PL  i.  69,  t.  94  (1804).  Marquisia  Billardierii  A. 
RicL  Mdm.  8ur  les  Rubiac^es,  112  (1829),  &  M^m.  Soc.  Hist.  Nat 
Par.  V.  192  (1829).  Coprosma  Billardieri  HooL  f.  in  Hook.  Lond. 
Jour.  Bot.  vi.  465  [bis]  (1847).  Coprosma  microphylla  A.  Cunn.  ex 
Hook  f.,  1.  c. 

Bichardia  muricata  (Griseb.),  n.  comb.  Richardsonia  muricata 
Ghriseb.  Cat.  PL  Cub.  143  (1866).  Spermacoce  (Borreria)  richardsoni- 
oides  Wright  in  Sanv.  FL  Cub.  73  (1873). 

Crusea  hispida  (Mill.),  n.  comb.  Crucianella  hispida  MilL  Diet 
ed.  8,  no.  4  (1768).  Spermacoce  rubra  Jacq.  Hort  Schonb.  iii.  3,  t 
256  (1798).     Crusea  rubra  Schlecht  &  Cham.  Linnaea,  v.  165  (1830). 

Borreria  asperifolia  (Mart.  &  Gral.),  u.  comb.  Diphragmus  scaber 
Presl,  Bot  Bemerk.  81  (1844),  not  Borreria  scabra  (Schum.  &  Thonn.) 
K.  Schum.  Spermacoce  asperifolia  Mart.  &  Gral.  BulL  Acad.  Brux.  xi. 
pt  1,  132  (1844). 

Borreria  nesiotica  n.  sp.,  suffrutescens  glaberrima  4  dm.  vel  ultra 
alta  ramosa;  ramis  ascendentibus  subteretibns  parte  superiori  4-angu- 
latis  basim  versus  foliosissimis  saepe  purpurascentibus ;  foliis  oppositis 
anguste  lanceolatis  basi  apiceque  attenuatis  laevissimis  etiam  ad  mar- 
ginem  paulo  revolutum  2-4.5  cm.  longis  3-12  mm.  latis  modice  venosis 
subtus  paululo  pallidioribus  axillis  saepe  proliferis ;  verticillis  plerisque 
4  distantibus  9-12  mm.  diametro  hemisphaericis  a  bracteis  2  majoribus 
oppositis  1-2  cm.  longis  ovato-lanceolatis  obtusiusculis  basi  ampliato 
setoso-dentatis  et  ca.  4  minoribus  ovatis  obtusis  5  mm.  longis  suffultis ; 
calyce  glabro  breviter  et  subaequaliter  4-lobato  cum  dentibus  interme- 
diis  brevissimis;  corolla  glabra;  staminibus  exsertis;  stigmate  bre- 
vissime  bilobato ;  seminibus  papillosis  nigris  non  transverse  sulcatis.  — 
Spermacoce  (Boneria),  sp.  Vasey  &  Rose,  Proc.  U.  S.  Nat.  Mus.  xiii. 
148  (1890).  Spermacoce  sp.  Brandegee,  Zoe,  v.  27  (1900).  —Socorro 
Island  (of  the  Revillagigedo  Group),  A,  W,  Anthony^  1897  (type,  in 
Gray  Herb.) ;  previously  collected  by  C,  H,  Townsend,  March,  1889 ; 
and  later  by  F.  E.  Barkelew,  27  May  to  3  July,  1903,  no.  208.  In 
habit  somewhat  resembling  B,  verticillata  (L.)  G.  F.  W.  Mey.,  but 
readily  distinguished  by  its  4-lobed  calyx.  Also  soiuewhat  like  forms 
of  the  highly  variable  B.  tenella  (HBK.)  Cham.  &  Schlecht,  but  hav- 
ing much  shorter  cal3rx-lobes  (about  one  third  the  length  of  the  tube), 
glabrous  foliage,  etc. 

Borreria  rhadinophylla,  n.  sp.,  gracillima  ramosa  prostrata,  cauH- 
bus  elongatis  valde  flexuosis  obsolete  quadrangularibus  foliosis  tenuiter 


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410  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

patenteque  pabescentibus  plus  minusve  rabescentibus  fere  filiformibas 
sed  basim  versus  induratis  et  lignescentibus,  nodis  hirsutulis;  foliis 
anguste  linearibus  subfiliformibus  l-nerviis  glabris  margine  revolutis 
apice  acutissimis  1-2  cm.  longis ;  vaginis  brevissimis  pauci-  (saepias 
2-)  setis;  verticillis  remotis  plerumque  2  subglobosis  ca.  1  cm.  dia- 
metro;  calyce  longe  2-Iobato,  lobis  lanceolato-linearibus  acutissimis 
herbaceis  sursum  fimbriato-ciliatis,  dentibus  intermediis  multo  brevi- 
oribus  scariosis )  corolla  alba  h3rpocraterimorpha  4-loba  2.5  mm.  loDga, 
lobis  ovato-oblongis  apicem  versus  hispidis,  tubo  intus  basim  versus 
pubescente ;  staminibus  4  in  summa  parte  tubi  affixis,  leviter  exsertis  ; 
fructu  et  seminibus  non  visis.  —  British  Honduras,  on  dry  sandy 
pine  ridges,  23  October,  1905,  Frqf.  Morton  E.  Peck,  no.  180  (type, 
in  Gray  Herb.).  From  its  2-lobed  calyx  this  species  would  seem  to 
stand  near  the  polymorphous  B.  verticillata  (HBK.)  Cham.  &  Schlecht. 
but  with  all  due  recognition  of  the  extraordinary  variability  of  that 
species,  it  does  not  seem  possible  that  this  delicate  filiform  plant 
should  be  included  among  its  forms.  Among  the  distinctions  noted 
is  the  form  of  the  stigma,  which  in  B.  verticillata  is  barely  lobed,  but 
in  B,  Peckiana  distinctly  bifid  with  short  but  actually  filiform  lobes. 

BoRRERiA  VERTICILLATA  (L.)  G.  F.  W.  Mcy.,  var.  thsnaxiformis,  n. 
var.,  pumila  6-8  cm.  alta  subglabra;  caulibus  multis  gracilibus  laxis 
flexuosis  a  caudice  crassa  nigrescente  oriuntibus ;  foliis  ovato-ellipticis 
7-11  mm.  longis  2-5  mm.  latis;  capitibus  parvis  ca.  8  mm.  diametro 
terminalibus.  —  Mexico  :  about  29  km.  southwest  of  the  city  of 
Oaxaca,  alt.  2300-2900  m.,  10-20  September,  1894,  E,  W.  Nelson, 
no.  1410  (typ^  in  Gray  Herb,  and  Herb.  U.  S.  Nat  Mus.).  This 
plant,  although  maintaining  all  the  floral  traits  of  the  species,  is  so 
strikingly  different  firom  the  usual  forms  as  to  be  well  worthy  of  varietal 
distinction.  Were  it  not  connected  with  the  more  typical  forms  by 
such  intermediates  as  L.  C.  Smith's  no.  40  firom  the  Cuilapan  Moun- 
tains, it  could  certainly  pass  as  a  distinct  species. 

Erigreron  Deamii,  n.  sp.,  suifruticulus  gracillimus  pumilus  1  dm. 
altus  irregulariter  a  basi  ramosus,  ramis  teretibus  strigosis  foliosissimis 
ascendentibus  saepius  1-capitatis;  foliis  linearibus  (infimis  anguste 
oblanceolatis)  ca.  1  cm.  longis  ca.  1  mm.  latis  utrinque  strigilloso- 
hispidulis  l-nerviis  saepe  in  axillis  proliferis ;  pedunculis  filiformibus 
ca.  3  cm.  longis  rectis  vel  apicem  versus  plus  minusve  nutantibus 
1-capitatis  subappresse  pubescentibus ;  capitibus  hemisphaericis  ca. 
8  mm.  diametro ;  involucri  squamis  argute  linearibus  attenuatis  sub- 
aequalibus  media  parte  viridibus  hirsutulis  margine  pallidis  scariosis 
ca.  4  mm.  longis;  flosculis  disci  numerosis,  corollis  2.3  mm.  longis 
apicem  versus  flavidulis,  achaeniis  compressis  sparse  hirsutulis  1.3  mm. 


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ROBINSON.  —  SPERMATOPHYTES,    NEW   OR   RECLASSIFIED.        411 

loDgis,  pappi  setis  ca.  12  tenuibus  albis  2.4  mm.  longis;  flosculis 
liguliferis  ca.  40,  ligulis  angastis  albis  vel  parpureo-tinctis  tube  sub- 
aequilongis  apice  saepissime  bidentatis,  acbaeniis  et  pappi  setis  eis 
flosculorum  disci  similibus.  —  Guatemala  :  growing  on  rocks  in  bottom 
of  canon,  Fiscal,  Guatemala,  alt  1130  m.,  3  June,  1909,  Charles  C, 
Deam,  no.  6159  (type,  in  Gray  Herb.).  Tbis  species  is  obviously  of  the 
affinity  of -fi*.  mucranatus  DC,  E,  exilis  Gray,  and  E.  Karwinskianus  DC. 
From  the  first  of  these  it  differs  in  having  narrower  (linear  rather  than 
lanceolate)  leaves,  smaller  heads,  and  relatively  as  well  as  absolutely 
shorter  rays  (exceeding  the  disk  scarcely  by  one  third).  E,  exilis  Gray 
has  the  involucral  bracts  and  peduncles  very  much  more  closely  and 
finely  puberulent,  and  E,  Karwinskianus  DC.  is  described  as  having 
the  leaves  glabrous  on  both  surfia^ces. 

Veibesina  medullosa,  n.  sp.,  firutescens  1.2-1.8  m.  alta;  cauli- 
bus  crassiusculis  teretibus  foliosis  meduUosis  omnino  exalatis  juventate 
tomentellis  serius  subglabratis ;  foliis  altemis  ovatis  majusculis  1.2-1.5 
dm.  longis  4-6  cm.  latis  crenato-serratis  penninerviis  supra  scabris  puber- 
ulis  viridibus  subtus  griseo-tomentellis  apice  attenuatis  caudato-acumi- 
natis  basi  in  petiolum  alatum  biauriculatum  sensim  angustatis,  alis 
petioli  transverse  valde  rugosis  margine  integriuscula  revoluta ;  capi- 
tulis  numerosis  parvis  9  mm.  altis  in  corymbis  compositis  planiusculis 
bracteatis  dispositis  ;  involucri  subturbinati  squamis  villoso-tomen- 
teUis  pallide  viridibus  apicem  versus  purpurascentibus ;  flosculis  disci 
ca.  20,  coroUis  albidis  4  mm.  longis  tubo  extus  puberulo  dentibus 
limbi  suberectis  brevibus  deltoideis,  flosculis  liguliferis  ca.  3  fertili- 
bus,  ligulis  ovalibus  parvis  albis  tubo  vix  longioribus  ;  acbaeniis  valde 
immaturis  obovatis  valde  compressis  margine  sursum  ciliolatis  apice 
biaristatis.  — Guatemala  :  along  railway,  Fiscal,  alt  1130  m.,  9  June, 
1909,  Charles  C.  Deam^  no.  6250  (type,  in  Gray  Herb.).  This  species 
differs  in  its  wingless  stem  and  branches  from  such  forms  of  V.  turha- 
censis  HBK.  as  have  unlobed  leaves.  From  V,  sublobata  Benth.,  it 
may  be  distinguished  by  its  more  bluntly  toothed  (crenate-serrate) 
unlobed  leaves  which  are  more  gradually  narrowed  to  the  winged 
petiole. 

Trixis  Deamii,  n.  sp.,  fruticosa  1.5  m.  alta  laxe  ramosa ;  ramis 
exalatis  teretibus  gracilibus  griseis  glabratis ;  ramulis  striatulis  viridi- 
bus tomentellis  foliosis ;  foliis  rhomboideo-obovatis  acute  acuminatis 
basi  subabrupte  angustatis  subintegris  tenuibus  supra  atroviridibus  pilo- 
siusculis  planis  subtus  griseo-sericeis  3.5-7  cm.  longis  1.5-3  cm.  latis 
nullo  modo  decurrentibus ;  petiolo  ca.  4  mm.  longo  gracili  villosulo  sub- 
tus carinato ;  capitulis  prope  apicem  ramulorum  aggregatis  ca.  2  cm. 
longis  12-floris  a  foliis  longioribus  plus  minusve  excessis  et  obscuratis ; 


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412  PBOCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

bracteis  involucri  exterioris  ca.  4  elliptico-lanceolatis  alternis  acaml- 
natis  ca.  12  mm.  longis  tenuibus  foliis  similibus;  squamis  involucri 
proprii  8  lanceolati-linearibus  attenaatis  ca.  14  mm.  longis  dorse  glan- 
daloso-paberulis  medio  herbaceis  margine  subscareosis  demam  stellate- 
patentibus  divaricatis  apice  falcatis  ;  corollis  ca.  1  cm.  longis  laete 
flavis ;  achaeniis  5  mm.  longis  columnaribus  papilloso-setulosis ;  pappi 
setis  albo-fulvesoentibus  ca.  9  mm.  longis.  —  Guatemala  :  along  river, 
alt.  230  m.,  Zacapa,  19  June,  1909,  Charles  C,  Deam^  no.  6359  (type, 
in  Gray  Herb.).  This  shrub  diflFers  from  such  related  species  as 
T,  megalophyUa  Greenman,  T.  silvatica  Robinson  &  Greenman,  T.  Nd- 
sonii  Greenman,  and  T.  rugulosa  Robinson  &  Greenman,  in  its  much 
thinner,  flatter,  softer,  and  essentially  entire  leaves  of  rhombic-obovate 
form.  From  T.  frutescens  P.  Browne  and  its  relatives  the  present 
plant  is  readily  distinguished  by  its  larger  outer  involucre,  the  silky 
under  surface  of  its  leaves,  etc. 

Chaptalia  semifloscularis  (Walt),  n.  comb.  Perdicium  semiflos- 
culare  Walt.,  Fl.  Car.  204  (1788).  Chaptalia  tamentosa  Vent.  Desc. 
Jard.  Gels,  t  61  (1800).  Tussilago  integrifolia  Willd.  Sp.  PL  iii 
1964  (1804).  Gerbera  Walteri,  Sch.  Bip.  in  Seem.  Voy.  Herald.  313 
(1856).  Thyrsanthema  semiflosculare  (Walt)  Etze.  Rev.  Gen.  L  369 
(1891). 

III.    AMERICAN  FORMS  OF  LYCOPODIUM 
COMPLANATUM. 

By  C.  a.  Weathebby. 

Lycopodium  complanatum  L.  occurs  in  the  western  hemisphere  in 
two  distinct  and  geographically  isolated  areas.  In  the  norti),  it 
ranges  from  Newfoundland  to  Alaska,  and  southward  to  northern 
Idaho  and  (in  its  Y&riety  Jlabellifonne)  to  the  mountains  of  North 
Carolina.  It  is  apparently  entirely  absent  from  the  United  States 
south  of  these  points ;  but  it  reappears  in  south-central  Mexico  and 
extends  thence  through  Central  America  to  Bolivia  and  southern 
Brazil.  It  has  also  been  reported  from  the  West  Indies.  Specimens 
from  these  areas  show,  on  examination,  four  more  or  less  well-marked 
variant  tendencies  —  two  (one  with  a  subsidiary  variation)  in  the 
north,  and  in  the  south,  two  others,  separable  from  each  other  and 
from  both  of  the  northern  forms. 

The  northern  forms  have  been  clearly  distinguished  by  Prof.  Fer- 
nald.^    The  two  southern  (one  chiefly  Mexican,  the  other  chiefly 

*  Rhodora,  iii.  280  (1901). 


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WEATHERBY. —  AMERICAN  FORMS  OF  LYCOPODIUM  COMPLANATUM.  413 

South  American)  are  connected  by  various  intermediates,  but,  in 
their  extreme  development,  are  sufficiently  diverse  to  warrant  varie- 
tal distinction.  Indeed,  since  Humboldt  and  Bonpland  described  their 
Lycopodium  thyoides  in  1810,  it  has  been  recognized  by  most  botanists 
that  some,  at  least,  of  the  tropical  material  differed  from  typical  L. 
complanatum  of  northern  Europe  and  North  America ;  and  L.  thy- 
oides has  been  rather  generally  maintained  as  a  variety,  differently 
defined  by  different  authors.  Neither  its  relation  to  the  northern 
forms,  however,  nor  its  exact  identity  in  regard  to  the  other  tropi- 
cal form  seems  to  have  worked  out  with  entire  clearness.  Lloyd  and 
Underwood,  in  their  Review  of  the  North  American  Species  of  Lyco- 
podium,* called  attention  to  the  habital  difference  between  Mexican 
and  Central  American,  and  northern  specimens ;  but,  partly  owing,  no 
doubt,  to  their  reluctance  to  describe  varieties,  carried  their  studies  no 
further.  Dr.  Christ,*  in  a  brief  but  clear  note,  has  pointed  out  the 
distinctions  between  the  two  southern  forms ;  but  he  seems  to  be  in 
error  in  referring  the  prevailing  South  American  form  to  typical  L,  com- 
planatum. The  plant  of  northern  Europe  and  America  which,  as  Prof 
Femald  has  shown,  should  be  regarded  as  the  type  of  the  Linnaean 
species,  is  low,  and  habitally  as  well  as  in  the  characters  of  its  branchleta 
and  their  leaves,  quite  different  from  the  taller  South  American  plant 
Dr.  Christ  seems  also  to  have  been  in  error  in  identifying  the  other  tropi- 
cal extreme,  which  has  broad  branchlets  and  long  leaves  with  con- 
spicuously spreading  tips,  with  L.  thyoides  H.  &  B.  The  original 
description  of  this  species  in  Willd.  Sp.  PL  v.  18,  emphasizes  rather 
strongly  the  appressed  leaves.*  In  view  of  the  facts  that  the  type 
specimens  were  from  Venezuela,  and  that  the  appressed-leaved  form  is 
apparently  much  the  more  common  throughout  South  America,  it 
seems  best  to  follow  the  first  diagnosis,  and  to  restrict  L.  thyoides 
to  that  form. 

In  spite  of  their  complete  geographic  separation,  there  is  nothing  to 
warrant  the  segregation  of  the  tropical  forms  as  separate  species.  The 
characters  which  distinguish  them  are  of  too  little  importance  in  them- 
selves and  too  inconstant  They  are  rather  to  be  considered  as  ex- 
treme developments  of  tendencies  which  are  traceable  also  in  occasional 
specimens  of  the  northern  plant,  but  are  there  not  so  strongly  developed. 
The  earliest  varietal  designation  of  the  South  American  plant  and  that 
which,  under  the  Vienna  Rules,  it  should  bear,  is  L,  complanatum, 
P  tropicum  Spring,  based  on  L.  thyoides  H.  &  B.  The  other,  prevail- 
ingly Mexican,  extreme  seems  to  be  without  an  available  name. 

«  Bull.  Torr.  Bot.  Qub,  xxvii.  165  (1900). 

»  Bull.  Herb.  Boiss.,  ser.  2,  u.  707  (1902).       *  "  foliis  semper  adpreasis." 


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414  PROCEEDINGS  OP  THE  AMERICAN  ACADEMY. 

The  following  synopsis  will  serve  to  define  these  American  tenden- 
cies of  L,  complanatumy  as  understood  by  the  writer.  The  specimens 
cited  are  all  in  the  Gray  Herbarium. 

♦  Branchlets  ascending,  or,  if  spreading,  lax  and  irregular;  ultimate  branch- 
lets  often  more  or  less  elongated. 

•^Ultimate  branchlets  comparatively  broad,  2-5  mm.  wide,  conspicuously 
flattened,  usually  ascending  and  only  moderately  elongated;  their  leaves 
3-5  mm.  long. 

Lycopodium  complanatum  L.  Branches  mostly  not  over  3  dn>. 
long;  peduncles  bearing  1-2 (~4)  spikes;  tips  of  the  lateral  leaves 
usually  appressed  or  incurved.  —  Sp.  PL  1104  (1753),  excl.  citation  of 
DilL  Muse  t  59  f.  a  —  North  America  :  Newfoundland  to  Alaska, 
south  to  Maine  and  northern  Idaho.    Also  in  Eurasia. 

Var.  validum,  nom.  nov.  More  robust ;  branches  usually  3-4.5  dm. 
long ;  peduncles  bearing  4-6(-9)  spikes ;  tips  of  the  lateral  leaves 
conspicuously  spreading.  —  L,  complanatum  Foum.  Enum.  PI.  Mex.  i. 
146,  at  least  in  part,  not  L ;  Hemsl.  Biol.  Cent. -Am.  Bot  iii.  701,  at 
least  in  part,  not  L.  L.  complanatum^  var.  thujoides  Christ,  BulL  Herb. 
Boiss.  s^r.  2,  ii.  707  (1902),  not  i.  thyoides  H.  &  B.  —  Mexico  :  Chia- 
pas; Bergwald  zwischen  San  Cristobal  Las  Casas  und  Huitztan,  C.  Jb  E. 
Seler,  no.  2273;  Chiapas  "etc.,"  Ghiesbreght,  no.  600;  Oaxaca,  Cerro 
San  Felipe,  alt  2000  m.,  Gonzalez  &  Conzatti,  no.  889 ;  region  d'Ori- 
zaba,  BourgeaUy  no.  3159,  in  part;  Hidalgo,  Trinidad,  C,  G,  Pringle^ 
no.  11,856  (a  form  with  the  ultimate  branchlets  lax,  elongated,  and 
somewhat  attenuate  at  tip).  No.  3196  in  John  Donnell  Smith's  Plants 
of  Guatemala  shows  a  form  intermediate  between  this  and  the  following 
variety. 

••-  •«-  Ultimate  branchlets  narrow,  not  more  than  2  mm.  wide,  less  conspicu- 
ously flattened,  somewhat  convex  above,  sometimes  much  elongated  (to 
12  cm.)  and  loosely  spreading;  their  leaves  2-3  mm.  long,  the  tips  usually 
closely  appressed. 

Var.  TROPicuM  Spring  in  Mart:  Fl.  Bras.  i.  pt.  2,  1 16  (1840).  i.  thyoi- 
des H.  &  B.  in  Willd.  Sp.  PI.  v.  18  (1810)  ;  ?  HBK.  Nov.  Gen.  et  Sp.  i. 
38  (1815);  Presl,  Bel.  Haenk.  77  (1825) ;  Raddi,  Fil.  Bras.  80  (1825), 
at  least  in  part.  L,  complanatum  P  adpressifolium  Spring,  Monog. 
Lycopod.  i.  102  (1842),  excl.  s)m.  L,  anceps  Wallr.  L.  complanatum^ 
"var.  i.  thuyoides  HBK."  Baker,  Handb.  of  the  Fern  Allies,  28  (1887). 
L,  complanatum,  var.  thyoidss  Hieron.  Engl.  Bot.  Jahrb.  xxxiv.  576 
(1905).  —  Colombia:  Motntz;  Santa  Marta,  Purdie.  Ecuador:  in 
Andibus  quitensibus,  Jameson ;  Andibas,  Spruce^  no.  5412  (a  doubtful 
plant  which  seems  to  have  suffered  some  injary  to  its  leaves).    Peru  : 


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FEKNALD.  —  LITTLE    KNOWN    MEXICAN    PLANTS.  415 

Andes,  Jameson,  Bolivia  :  Yungas,  Bang,  no.  395.  Brazil  :  RieM ; 
Ciaussen ;  Herb.  U.  S.  So.  Pac.  Expl.  Exp.,  no.  27  ;  Prov.  Minas  Ge- 
raes,  Widgren^  no,  984 i.  Burchell's  no.  2223,  from  Brazil,  of  which 
the  specimen  in  the  Gray  Herb,  shows  only  the  tip  of  a  stem,  is  per- 
haps referable  to  var,  validum, 

**  Branchlets  spreading  or  recurved,  forming  a  regular  flabelliform  spray; 
ultimate  branchlets  usually  short,  0.5  to  4  cm.  long^  broad  as  in  L.  conv- 
planalum  but  with  shorter  leaves. 

Var.  flabelliforme  Fernald.  Peduncles  usually  bearing  4  spikes. 
—  Rhodora,  iii.  280  (1901).  Z.  complanatum  Amer.  auth.  in  part.  — 
North  America  :  Nova  Scotia  to  the  mountains  of  North  Carolina, 
Kentucky,  Iowa,  and  Minnesota. 

Var  WiBBEi  Haberer.  Peduncles  1 -spiked.  —  Rhodora,  vi.  102 
(1 904).   North  America  :  northern  Vermont  and  central  New  York. 


IV.    NEW  AND  LITTLE  KNOWN  MEXICAN  PLANTS, 
CHIEFLY  LABIATAE. 

Ey   M,   L.   Fernald. 

Juneus  albicans,  n.  sp.,  caespitosus ;  caulibus  5-7  dm.  altis  tenu- 
ibus  striatis  albido-viridibus ;  vaginis  basilaribus  laxis  albican tibus 
demum  fuscis,  auriculis  cartilagineis,  laminis  subteretibus  angnste 
canaliculatis ;  inflorescentiis  decompositis  2-6  cm.  longis,  ramis  sub- 
erectis,  floribus  subremotis  vel  aggregatis ;  brae  tea  infima  frondosa 
inflorescentiam  plerumque  superante ;  floribus  4-5  mm.  longis  albido- 
stramineis  ;  bracteolis  tenuibus  albicantibus  ;  sepalis  petalisque  subae- 
quilongis  patentibus  lanceolatis  apice  subulatis  anguste  membranaceo- 
marginatis;  staminibus  6  sepalis  circa  dimidio  brevioribus,  antheris 
filamentisque  aequantibus ;  fructibus  trigono-ellipsoideis  truncatis 
breve  mucronatis  3-4  mm.  longis  pallide  stramineis  nitidis  ;  seminibus 
0.5  mm,  longis  oblique  ellipsoideis  brevissime  albo-caudatis.  —  Chi- 
huahua :  vicinity  of  Chihuahua,  altitude  about  1300  m.,  May  1-21, 
1908,  Edward  Palmer^  no.  161  (type,  in  Gray  Herb.).  [It  should  be 
noted  that  two  plants  have  been  distributed  under  no,  161,  but,  as  the 
other  belongs  in  the  Cmciferae,  little  confusion  is  likely  to  result] 
Nearly  related  to  J,  dkhotomus  Ell.  of  the  southern  and  eastern  United 
States.  Differing  in  its  very  pale  color,  the  softer  texture  of  the  pro- 
phylla,  perianth,  and  capsule,  and  the  distinctly  white-caudate  longer 
seeds. 

Palmer^s  no.  253,  collected  May  28-31,  1906,  at  Tobar,  Durango,  is 
provisionally  placed  with  J  uncus  albicans^  though  it  may  eventually 


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416  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

prove  to  be  distinct  It  has  less  cartilaginous  auricles,  smaller  fioweni, 
and  more  ascending  sepals,  but  the  material  at  hand  is  over-mature 
and  has  lost  all  its  seeds. 

Juncus  Pringlei,  n.  sp.,  dense  caespitosus ;  caulibus  erectis  graci- 
libus  rigidis  1.5-2.5  dm.  altis  sulcatis ;  cataphyllis  basilaribus  mucro- 
niferis  stramineis,  supremis  laminigeris  lamina  4-10  cm.  longa ;  inflore- 
scentia  densa  3-7-flora  a  bractea  infima  vix  superata;  floribus  4.5-5 
mm.  longis ;  sepalis  lanceolatis  petala  subaequantibus  apice  subulatis 
dorso  crassis  viridibus  lateribus  castaneis  marginibus  membranaceis 
pallidis;  staminibus  6,  antheris  linearibus  flavidis  quam  filamentum 
longioribus;  fructibus  trigono-ellipsoideis  mucronatis  nitidis  pallida 
castaneis  vel  olivaceis  5-6  mm.  longis ;  seminibus  0.4  mm.  longis  elli- 
psoideis  mucronatis.  —  Oaxaca  :  Cuesta  de  San  Juan  del  Estado,  alti- 
tude 2125  meters,  August  31,  1894,  C.  G.  Pringle,  no.  5818  (type,  in 
Gray  Herb.).  An  interesting  addition  to  the  little  group  of  species, 
J,  Drummondii  K  Meyer,  J,  Parryi  Engelm.,  and  J,  HaUii  Engelm., 
all  of  which  are  confined  to  the  cordillera  of  western  North  America. 
J,  Pringlei  closely  simulates  J.  HaUii  of  Colorado  and  Utah,  but 
differs  in  its  blunt-pointed,  not  retuse,  capsule ;  and,  unlike  any  of  its 
three  allies,  it  has  mucronate  instead  of  caudate-appendaged  seeds. 

Scutellaria  spinesoens,  n.  sp.,  fruticosa  1-2  dm.  alta ;  caule  crasso 
tortuoso  cortice  cinereo,  ramis  implicatis  rigidis  spinescentibus  cinereo- 
hirtellis,  pilis  minutis;  foliis  ellipticis  vel  oblongis  integris  breve 
petiolatis  rugosis  cinereo-hispidulis,  majoribus  1  cm.  longis;  floribus 
axillaribus;  pedicellis  5  mm.  longis;  calyce  2.5-3  mm.  longo glanduloso- 
hispido;  corolla  curvata  pilosa  2  cm.  longa  flava  vel  rubella,  tube 
anguste  cylbdrico.  —  Coahuila  :  by  a  brook  in  San  Lorenzo  Cafion, 
near  SaltiUo,  September  21-23, 1904,  Edward  Palmer^  nos.  392  (type,  in 
Gray  Herb.)  and  394.  A  characteristic  dwarf  shrub  closely  simulating 
S,  suffrutescens  Watson,  which,  however,  has  very  minutely  pulverulent 
glandless  branches,  leaves,  and  caljrx.  The  corolla  of  S,  spinescens,  as 
shown  by  Dr.  Palmer's  material,  is  very  variable  in  color  (as  is  that  of 
S.  mffrutescens)  ;  the  material  under  no.  392  having  the  corolla  canary- 
yellow  passing  to  salmon,  with  the  galea  reddish ;  while  no.  394  has 
the  corolla  of  various  shades  of  red,  with  yellow  only  on  the  sides  of 
the  galea. 

Salvia  Sanctae-Luciae  Seem.  Bot.  Herald,  327  (1856).  In  the 
writer's  synopsis  of  Mexican  Salvias  (Proc.  Am.  Acad.  xxxv.  514),  this 
plant  was  placed  in  the  Vulgares  and  was  taken  to  be  the  same  as  a 
plant  of  that  section  collected  by  Dr.  Edward  Palmer  in  Tepia  Sub- 
sequently the  writer  has  studied  Seemann's  original  material  at  Kew  and 
it  proves  to  be,  not  a  plant  of  the  Vulgares  as  stated  by  Seemann  in  the . 


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FERNALD.  —  LITTLE    KNOWN    MEXICAN    PLANTS.  417 

original  description,  but  a  characteristic  member  of  the  Memhranaceae. 
It  is  identical  with  the  Tepic  plant  which  the  writer  has  described  as 
8.  chdixies  (Proc.  Am.  Acad.  xxxv.  497). 

Salvia  (Membranaceae)  Langlassei,  n.  sp.,  suffruticosa ;  caule 
gracile  duro  Hexiioso  obtuse  quadrangulato,  ramis  sordido-villosis  ; 
foliis  ramorum  membranaceis  lanceolatis  vel  anguste  ovatis  basi  rotun- 
datis  apice  acuminatis  3-4.7  cm.  longis  1.3-1.8  cm.  latis  acute  serratis 
supra  strigosis  venis  subtus  pilosis,  petiolis  5-10  mm.  longis ;  racemo 
elongato;  verticillis  9-14-floris  demum  2-2.5  cm.  distantibus;  bracteis 
renifbrmibus  acuminatis  6-9  mm,  longis  glabris  lucidis  purpurascenti- 
bus  ;  pedicellis  4  mm.  longis  glanduloso-hispidis ;  calyce  campanulato 
purpurascente  glanduloso-hispido  fructifero  8  mm.  longo,  labiis  subae- 
qualibus,  superiore  late  ovato  1.5  mm.  longo,  inferiore  cum  lobis  ovatis 
mucronatis ;  corolla  violacea.  —  Michoacan  or  Guerrero  :  in  argilla- 
ceous soil  of  the  Sierra  Madre  at  1700  meters  altitude,  January  27, 
1899,  Langlasse,  no.  805  {ty^e,  in  Gray  Herb.).  Closely  related  to 
8,  Sanctae-Liiciae  Seem.,  but  with  slender  stems  said  by  M.  Langlass^ 
to  be  "volubile,"  thinner  leaves  with  very  different  pubescence,  and 
with  shorter,  broader  calyx-lobes. 

Salvia  { Angustifoliae)  iirolepis,  n.  sp.,  herbacea  circa  1  m.  alta ; 
caulibus  gracilibus  retrorse  pubescentibus,  pilis  brevibus  cinereis  ;  foliis 
late  lanceolatis  vel  anguste  ovatis  basi  subcuneatis  apice  acutis  3.5-5 
(-9)  cm.  longis  crenato- serratis  supra  viridibus  puberulis  subtus  albo- 
pannosis,  petiolis  gracilibus  1-2  cm.  longis  pilosis;  racem  is  gracilibus, 
primariis  1.2  demum  3  dm.  longis;  bracteis  lanceolato-attenuatis  9-13 
mm.  longis  deciduis  ;  verticillis  12-floris  demum  3-3.5  cm.  distantibus  ; 
calyce  tubuloso-campanulato  fructifero  6-7  mm.  longo  caerulescente 
albido-piloso,  labiis  subaequalibus,  superiore  late  ovato  mucronato, 
inferiore  cum  lobis  del toideo- ovatis  subaristatis  ;  corolla  azurea  12-16 
mm.  longa,  tubo  exserto,  galea  oblonga  4-6  mm.  longa  pilosa^  labio  in- 
feriore 6-9  mm.  longo  cum  lobo  medio  valde  majore ;  stylo  piloso.  — 
NuEvo  Leon,  by  brooks  of  the  Sierra  Madre  above  Monterey,  August 
25,  1903,  September  4,  1904,  and  September  19,  1907,  C.  G.  Pringle, 
nos.  11,906,  13,281,  and  13,978  — all  collected  from  the  same  colony 
(type,  in  Gray  Herb.).  Apparently  most  nearly  related  to  ^S'.  oblongi- 
folia  Mart.  &  Gal,  which  differs  in  its  narrower  glabrous  leaves, 
shorter  and  broader  bracts,  and  the  greener  somewhat  viscid  puberu- 
lence  of  the  calyx. 

Salvia  lavanduloides  HBK.,  var.  latifolia  Benth.  PI.  Hartw.  21 

(1839),  and  in  DC.  Prodr.  xii.  303  (1848)  as  mmen  nudum;  Fernald, 

Proc.  Am.  Acad.  xxxv.  506  (1900).     A  fine  collection  of  this  plant, 

made  by  Mr.  E.  W.  Nelson  at  an  altitude  of  2125-3040  m.  on  Mt. 

VOL.  xlv.  —  27 


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418  PBOCEEDINGS   OF   THE   AMERICAN   ACADEMY. 

Patamban,  Michoacan,  January  28-31,  1903  (no.  6575),  exactly 
matches  Hartweg's  no.  171  which  is  the  type  of  the  variety.  In  study- 
ing the  variety  in  the  light  of  this  more  adequate  material  an  impor- 
tant character  is  noted  in  the  glabrous  or  glabrate  lower  sur£%ce  of  the 
leaves,  those  of  typical  S,  lavanduhides  being  canescent-tomentose 
beneath. 

Salvia  (Angustif olia«)  moniliformis,  n.  sp.,  caulibus  altis  minute 
pilosis ;  ramis  elongatis  valde  ascendentibns ;  foliis  ramorum  lanceo- 
latis  utrinque  acutis  3-4  cm.  longis  crenato-serratis  supra  viridibus  tri- 
gosis  subtus  pallidis  pilosis;  racemis  spiciformibus  demum  3-4  dm. 
longis;  verticillis  10-40-floris  demum  8-9  cm.  distantibus;  bracteis 
lanceolato-ovatis  attenuatis  caeruleis  albido-pilosis  deciduis  ;  pedicellis 
1-2  mm.  longis;  calyce  cylindrico  albido-caeruleo  piloso  costatofiructi- 
fero  8  mm.  longo,  labiis  subaequalibus  lanceolato-attenuatis  3  mm. 
longis ;  corolla  caerulea  circa  8  mm.  longa,  tube  paulo  exserto,  galea 
puberula,  labio  inferiore  multo  longiore.  —  Mexico  :  open  woods  on 
hillside  at  2735  meters  altitude,  Iztaccihuatl,  January,  1906,  C.  A. 
Pwrpu9y  no.  1720  (t3rpe,  in  Gray  Herb.).  Distributed  as  /SI  lavandu- 
hides  HBK.,  but  more  nearly  related  to  *Si.  remota  Benth.,  which,  how- 
ever, has  much  smaller  calyces  (in  maturity  4  nmi.  long)  which  are  less 
prominently  bilabiate. 

Salvia  (Vulgares)  lilacinct,  n.  sp.,  herbacea  1-1.5  m.  alta ;  cauli- 
bus minute  puberulis  valde  sulcatis  purpurascentibus ;  foliis  ovatis 
acuminatis  basi  rotundatis  4-6  cm.  longis  serratis  supra  minute  stri- 
gosis  venis  subtus  strigosis,  petiolis  5-10  mm.  longis ;  racemis 
gracilibus  permultis  6.5-12.5  cm.  longis;  verticillis  10-20-flori8 
approximatis  demum  1  cm.  distantibus ;  bracteis  lanceolato-aristatis 
1.5  mm.  longis  caducis ;  pedicellis  2-3  mm,  longis ;  calyce  purpurascente 
tubuloso-campanulato  3-3.5  mm.  longo  strigoso,  labio  superiore 
ovato  acuminate  1  mm.  longo,  labio  inferiore  cum  lobis  subaristatis ; 
corolla  lilacina  12  mm.  longa  pilosa,  tube  ventricoso  exserto,  galea 
labiam  inferiorem  subaequante;  stylo  piloso.  —  Michoacan:  near 
Uruapan,  October  15,  1904,  C,  G,  Pringle,  no.  13,279  (type,  in 
Gray  Herb.).  Closely  related  S.  Ghiesbreghtii  Femald,  which  has 
the  midrib  of  the  leaf  densely  lanate  beneath,  the  puberulence  of  the 
branches  coarser,  and  the  few  racemes  more  elongate. 

Salvia  (Vulgares)  uruapana,  n.  sp.,  herbacea  annua,  7  dm.  alta ; 
caule  gracile  minute  piloso,  pilis  retrorsis  appressis,  intemodiis  3.5-10 
em.  longis ;  foliis  ovatis  subcordatis  acuminatis  4-5  cm.  longis  2.6-3.5 
cm.  latis  crenato-serratis  supra  pallide  viridibus  minute  puberulis  vel 
glabratis  subtus  cinereis  minute  pilosis  vel  glabratis,  margine  piloso- 
ciliato ;  racemis  elongatis,  primariis  3  dm.  longis ;  verticillis  3-10-floris 


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FERNALD.  —  UTTLE    KNOWN    MEXICAN   PLANTS.  419 

demum  3  cm.  distantibus ;  bracteis  lanceolato-caudatis  demum  7-10 
mm.  longis  ;  pedicellis  demum  6-7  mm.  longis  tenuibas  albido-pilosis ; 
calyce  tubuloso-campanalato  ihictifero  9  mm.  longo  3  mm.  diametro 
cinereo-piloso  valde  bilabiato,  labio  superiore  obloDgo  acuminato  2.5 
mm.  loDgo,  inferiore  rectiuscalo  4  mm.  longo  cum  lobis  lanceolato- 
aristatis ;  corolla  azurea  12  mm.  longa,  tnbo  vix  exserto,  galea  brevis- 
sima  pilosa,  labio  iDferiore  multo  longiore ;  stylo  glabro.  —  Michoacan  : 
lava  fields,  Uruapan,  October  16,  1904,  C.  G.  Pringle,  no.  13,280 
(type,  in  Gray  Herb.).  Strongly  simulating  S.  leptostctchys  Benth.,  from 
which  it  differs  in  its  much  longer,  more  slender,  and  unequally  cleft 
greener  cal3rx,  the  longer,  more  pubescent  pedicels,  and  the  more 
copiously  pilose  leaf-margin. 

Salvia  (Vulgares)  lenta,  n.  sp.,  caulibus  lentisgracilibus  5  dm.  altis 
pilosis,  pilis  cinereis  nodulosis;  foliis  ovatis  acuminatis  basi  subcu- 
neatis  6.5-9  cm.  longis  3.5-4  cm.  latis  argute  serratis  utrinque  pilo- 
sis ;  petiolis  1-1.5  cm.  longis  ;  racemo  elongato  2  dm.  longo ;  verticillis 
8-12-floris  demum  1.5-2  cm.  distantibus;  bracteis  lanceolato-ovatis 
acuminatis  pilosis  deciduis ;  pedicellis  demum  2-3  mm.  longis  pilosis ; 
calyce  tubuloso-campanulato  circa  4  mm.  longo  dense  piloso,  pilis 
albidis  nodulosis,  labio  superiore  ovato  obtuso  1  mm.  longo,  inferiore 
breviore  cum  lobis  deltoideis  acutis ;  corolla  caerulea  minute  pilosa 
1  cm.  longa,  tubo  exserto,  labiis  subaequalibus  ;  stylo  piloso.  —  Mi- 
choacan or  Guerrero:  in  granitic  soil,  at  1100  meters  altitude, 
Real  de  Gnadelupe,  September  10,  1898,  Langlassiy  no.  343  (type,  in 
Gray  Herb.).  Nearly  related,  apparently,  to  /S.  IVarszetvicziana  Kegel, 
which  has  broad  cordate  acuminate  bracts,  a  secund  inBorescence,  and 
the  lips  of  the  corolla  very  unequal,  the  upper  glandular. 

Salvia  (Vulgares)  fallax,  n.  sp.,  fruticosa ;  ramis  gracilibus  elon- 
gatis  lignosis  brunnescentibus  juventate  dense  sordido-villosis,  pilis 
nodulosis;  foliis  ovatis  acuminatis  basi  subcuneatis  6-11  cm.  longis 
3.5-6  cm.  latis  argute  serratis  utrinque  pilosis,  pilis  albidis  nodulosis ; 
petiolis  gracilibus  villosis  2-5  cm.  longis ;  racemis  gracilibus  1-1.5  dm. 
longis ;  verticillis  3-6-floris  demum  1  cm.  distantibus ;  bracteis  atro- 
purpureis  anguste  ovato-caudatis  deciduis ;  pedicellis  demum  2  mm. 
longis;  calyce  atro-purpureo  tubuloso-campanulato  hirsute  iructifero 
5-6  mm.  longo,  labio  superiore  ascendente  ovato  acuminato,  labio 
inferiore  rectiusculo  1.5  mm.  longo  cum  lobis  deltoideo-aristatis ; 
corolla  azurea  9  mm.  longa,  tubo  vix  exserto,  galea  villosa,  labio 
inferiore  paulo  breviore;  stylo  piloso. — /S  Sanctae-Luciae  Femald, 
Proc      \k  :;     V     v.    ')14   Cl^'*<0»  not   S(N  7  tar 

the  town  of  Tepic>  January  and  February,  1892,  Edward  Palmer^ 
no.  1964  (type,  in  Gray  Herb.)-     Closely  related  to  S.  Imta  Fernald 


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420  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

and  apparently  also  to  8,  Warczewictiana  RegeL  In  the  writer's 
synopsis  of  Salvia  published  in  1900  he  mistook  this  plants  from  the 
description  alone,  for  S,  Sanctae-Luciae  Seem.;  but  he  has  since  exam- 
ined Seemann's  t3rpe  and  finds  that  it  is  not  this  plant  but  a  species 
of  the  Membranaceae  (see  above). 

Salvia  (Scorodoniae)  rupioola,  n.  sp.,  fruticosa;  ramis  gracilibus 
subteretibus  lignosis  albescentibus  cortice  fibrilloso,  juventate  brunne- 
scentibus  glanduloso-pilosis ;  foliis  oblongis  vel  anguste  ovatis  crenatis 
utrinque  obtusis  1-2  cm.  longis  supra  rugosissimis  viridibus  hispidis 
glandulosisque  subtus  pallidis  glanduloso-pilosis,  petiolo  2-3  mm. 
longo ;  racemis  gracilibus  4.5-9  cm.  longis ;  rhachi  purpurascente 
glanduloso-hispidulo ;  verticillis  circa  8-floris  remotis  demum  1.5-2 
cm.  distantibus ;  bracteis  ovatis  2  mm.  longis ;  pedicellis  2  mm.  longis ; 
calyce  tubuloso-campanulato  livido  fructifero  6  mm.  longo  glanduloso- 
hispido,  labio  superiore  obtuso  1.5  mm.  longo,  labio  inferiore  obtuso 
vix  1  mm.  longo ;  corolla  circa  1  cm.  longa,  tubo  ventricoso  exserto ; 
galea  pilosa,  labio  inferiore  paulo  breviore;  stylo  piloso.  —  Hidalgo: 
on  rocks,  Ixmiquilpan,  1903,  C.  A.  Purptis,  no.  431  (tyx)e,  in  Gray 
Herb.).  In  habit  similar  to  S.  fruticulosa  Benth.,  which  has  the  branch- 
lets,  lower  leaf-surfeces,  calyces,  etc.,  stellate-pamiose ;  nearer  related, 
apparently,  to  8.  Gonzahzii  Femald,  which  is  less  fruticose,  with  darker 
branches,  glandless  softer  pubescence,  broad-ovate  leaves,  and  larger 
calyx. 

Salvia  (Soorodoniae)  tepicensis,  n.  sp.,  caulibus  gracilibus  obtuse 
angulatis  dense  piloso-hispidis,  pilis  viscidis ;  foliis  oblongo-ovatis  ob- 
tusis supra  viridibus  rugosis  setosis  subtus  albo-villosis  3-3.5  cm. 
longis  basi  subcordatis,  petiolo  brevi  gracili  viscido-hispido ;  racemis 
simplicis  elongatis  1.5  dm.  longis ;  verticillis  G-lO-floris  remotis 
demum  2.5-3  cm.  distantibus ;  bracteis  lanceolato-ovatis  acuminatis 
dentatis  4  mm.  longis ;  calyce  azureo  anguste  campanulato  fructifero 
7-8  mm.  longo  valde  costato,  costis  glanduloso-setulosis,  labio  superi- 
ore obtuso  3  mm.  longo,  inferiore  obtuso  2  mm.  longo  ;  corolla  azurea 
1.5  cm.  longa,  tubo  paulo  ventricoso  exserto,  galea  pilosa,  labio  inferiore 
multo  longiore ;  stylo  villosissimo.  —  Tepic  :  near  the  town  of  Tepic, 
January  5-February  6,  1892,  Edward  Palmer,  no.  1984  (type,  in 
Gray  Herb.).  Related  to  8.  Gonzalezn  Femald  and  8.  rupicola 
Femald.  From  the  former  distinguished  by  its  characteristic  glandu- 
lar spreading  pubescence,  the  long  lip  of  the  corolla,  and  the  villous 
style ;  from  the  latter  by  its  more  herbaceous  character,  its  much 
longer  pubescence  (of  branches,  leaves,  and  cal3rx),  its  larger  promi- 
nently costate  calyx,  and  the  longer  corolla  with  a  comparatively  long 

lip. 


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FERNALD.  —  LITTLE    KNOWN   MEXICAN    PLANTS.  421 

Salvia  (Scorodoniae)  dasyoalyx,  n.  sp.,  fruticosa  1.5  m.  alta ; 
ramis  gracUibus  valde  quadrangulatis  superne  decussatim  bifariam  pi- 
losis ;  foliis  ramorom  lanceolatis  acuminatis  basi  sabcuneatis  3.5-5.5 
cm.  longis  pauIo  ragosis  utrinque  glabris  vel  venis  supra  pilosis  venis 
subtus  albidis,  petiolis  2-5  mm.  longis  pilosis ;  paniculis  densis  thyr- 
soideis,  secundariis  3.5-5  cm.  longis;  bracteis  lanceolato-attenuatis 
3-4  mm.  longis ;  calyce  tarbinato  circa  3  mm.  longo  purpurascente 
dense  villoso,  pilis  albidis  planis,  lobis  brevissimis  latis ;  corolla  vio- 
lacea  7-8  mm.  longa,  tubo  inclaso,  galea  pilosa  labiam  inferiorem  sub- 
aequante.  —  Michoacan  or  Guerrebo  :  in  argillaceous  soil  at  1800 
meters  altitude,  Sierra  Madre,  January  23,  1899,  LanglassS,  no.  779 
(type,  in  Gray  Herb.).  Closely  simulating  S*  thyrsifiora  Benth.,  from 
which  it  differs  in  its  glabrous  leaves  and  smaller  shaggy-villous 
calyces. 

Salvia  (Cyaneae)  .umbratilis,  n.  sp.,  fruticosa  1  m.  alta ;  ramis 
gracilibus  puberulis;  foliis  membranaceis  glabris  rhomboideo-ovatis 
acuminatis  basi  cuneatis  8  cm.  longis  crenato-serratis,  dentibus  mucro- 
natis ;  petiolis  gracilibus  1.5-3^5  cm.  longis ;  racemo  1.5  dm.  longo ; 
verticilKs  2-6-floris  demum  2  cm.  distantibus ;  bracteis  ovato-acuminatis 
2  mm.  longis  subpersistentibus ;  pedicellis  filiformibus  5-6  mm.  longis 
divergentibus  minute  hispidis;  calyce  campanulato  demum  11  mm. 
longo  valde  9-costato  costis  setulosis,  labio  superiore  ascendente  late 
deltoideo  mucronato,  labio  inferiore  4  mm.  longo  cum  lobis  porrectis 
anguste  deltoideis  aristatis ;  corolla  cyanea  2.5-3  cm.  longa  pilosa  rec- 
tiuscula,  tubo  paulo  ventricoso,  galea  7  mm.  longa,  labio  inferiore 
paulo  breviore ;  stylo  glabro.  —  Michoacan  or  Guerrero  :  in  argil- 
laceous soil  of  damp  forests,  at  1200  meters  altitude,  Sierra  Madre, 
February  19,  1899,  Langlasse,  no.  904  (type,  in  Gray  Herb.).  Nearest 
related  to  S,  phaenostemma  Donnell  Smith,  which  has  the  leaves  more 
rounded  at  base,  the  calyx  longer  and  purberulent  (with  subequal 
lobes),  and  the  pedicels  ascending. 

Salvia  (Tubiflorae)  arbuscula,  n.  sp.,  arborea  vel  fruticosa  circa 
2.5  m.  alta  ;  ramis  lanatis,  pilis  brunneis  ;  foliis  ovatis  oblique  subcor- 
datis  acuminatis  circa  1  dm.  longis  crenato-serratis  supra  yiridescenti- 
bus  tomentosis  cum  pilis  stellatis  subtus  albido-pannosis  cum  pilis 
stellatis ;  petiolis  1-1.5  cm.  longis  stellato-tomentosis ;  racemis  densis 
primario  2.5  dm.  longo  ;  verticillis  20-30-floris  demum  3  cm.  distanti- 
bus ;  bracteis  minutis  deciduis ;  calyce  tubuloso-campanulato  valde 
costato  5  mm.  longo  albido-lanato,  labio  superiore  late  deltoideo  cuspi- 
date 1  mm.  longo,  inferiore  cum  lobis  anguste  deltoideis  mucronatis ; 
corolla  purpurea  curvata  2.5-3  cm.  longa  vix  ventricosa  villosa,  galea 
rectiuscula  7  mm.  longa,  labio  inferiore  4  mm.  longo  ;  stylo  glabro.  — 


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422  PBOCEEDINQS  OF  THE  AMEBICAN  ACADEUT. 

MiGHOACAN  or  Guerrero  :  at  1500  metres  altitude  in  the  Sierra 
Madre,  January  20,  1899,  Langlasse^  no.  767  (t3rpe,  in  Gray  Herb.). 
A  handsome  species  nearest  related  to  8,  Eosei  Femald,  but  abun- 
dantly distinct  in  the  pubescence  of  its  branches,  calyx  and  corolla, 
as  well  as  the  small  calyx  and  the  glabrous  style. 

Hyptis  (Hypema,  §  Longiflorae)  Langlassei,  n.  sp.,  fruticosa  circa 
2  m.  alta ;  ramis  glabris  rufescentibus ;  foliis  crassis  coriaceis  glabris 
lanceolatis  acuminatis  basi  subcuneatis,  superioribus  1-1.7  dm.  longis 
2-3.5  cm.  latis  acute  dentatis  ;  panicula  trichotoma  ramis  1.5-2.7  dm. 
longis  cymulas  item  semel  vel  bis  trichotomas  2-7  cm.  longas  laxe 
patentes  gerentibus,  rhachi  glanduloso-puberulo ;  bracteis  ovato-lanceo- 
latis  acuminatis  integris  puberulis,  inferioribus  2.5  cm.  longis,  supe- 
rioribus 1  cm.  longis;  pedicellis  demum  4-11  mm.  longis;  calyoe 
campanulato  anthesi  4-5  mm.  fiructifero  8-9  mm.  longo  glanduloso- 
puberulo  et  glanduloso-hispido,  pilis  brevibus  albidis  squamosis ;  labiis 
patentibus  lanceolato-aristatis ;  corolla  sanguinea  puberula  2  cm.  longa, 
tubo  infundibuliforme,  galea  2-3  mm.  longa  lobis  rotundis  labiam  inferi- 
orem  subaequante;  staminibus  stiloque  exsertis  glabris.  —  Michoacan 
or  Guerrero  :  in  granitic  soil  at  1800  m.  altitude,  Sierra  Madre,  Feb- 
ruary 10,  1899,  Langlasse^  no.  854  (type,  in  Gray  Herb.).  Closely  re- 
lated to  H.  Nelsoni  Fernald,  of  the  mountains  of  Jalisco,  which  has  the 
leaves  broad  and  clasping  at  base,  the  pubescence  much  finer  (that  of 
the  caljTx  merely  a  fine  puberulence),  and  the  hardly  aristate  caljrx-lobes 
much  shorter. 


V.   MEXICAN  PHANEROGAMS  — NOTES  AND 
NEW  SPECIES. 

By  C.  A.  Weatherby. 

Anthericmn  tenue,  n.  sp.,  gracillimum  scaposum,  radicibus  fasci- 
culatis  nonnuUis  apice  nonnullis  basin  versus  tuberoso-incrassatis,  foliis 
marcidis  in  coUo  laxe  fibrose  3  cm.  longo  supra  radicem  persistentibus 
foliis  suberectis  pluribus  radicalibus  subulatis  duris  glabris  marginibus 
minute  ciliolatis  exceptis  1.5-2.8  dm.  longis  circa  1  mm.  latis  caule 
paulum  brevioribus  in  apicem  longum  acicularem  prodactis,  caulibus 
gracilibus  glabris  6-9-bracteatis  ex  speciminibus  visis  simplicibus  2.8- 
3.6  dm.  altis,  floribus  in  bractearum  axillis  2-3-fasciculatis,  pedicellis 
7-10  mm.  longis  infra  medium  articulatis,  perianthii  segmentis  1  cm. 
longis  albis  (fide  Nelsonii),  staminibus  quam  perianthium  tertiam 
partem  brevioribus,  antheris  3  mm.  longis  liberis,  filamentis  4  mm. 
longis  muricatis,  capsulis  immaturis  ovoideis  quam  perianthiam  mar- 


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WEATHERBY.  —  MEXICAN    PHANEROGAMS.  423 

cescens  daplo  brevioribus.  —  Guerrero  :  betwecD  AyoeiDara  atd 
Petatlan  altitude  1500-2000  m.,  Dec.  14,  1894,  Nelson,  no.  2120  (in 
hb.  U.  S.  Nat  Mus.).  Near  A.  leptophyUum  Baker,  from  which  it 
differs  in  its  even  more  slender  habit,  narrower  and  longer  leaves, 
and  several-bracted  stem.  Very  similar  also  to  Echeandia  Pringlei 
Greenman,  but  with  free  anthers. 

Anthericum  uncinatuxn,  n.  sp.,  scaposum,  radicibus  medio  in- 
crassatis,  collo  radicis  dense  fibrose,  foliis  (6-7)  8-12  cm.  longis 
6-10  mm.  latis  pallide  viridibus  saepius  patentibus  valdeque  fal> 
catis  in  siccis  conduplicatis  membranaceis  marginibas  manifestis  albis 
cartilagineis  ciliolatis  lente  nervatis,  caalibus  circa  3  dm.  altis  simplici- 
bus  scabris  vel  hirtellis  1-2-bracteatis  bracteis  setaceo-acuminatis 
chartaceis,  pedicellis  floriferis  5-7  mm.  longis  infra,  medium  articu- 
latis,  perianthii  flavi  (?)  segmentis  8-12  mm.  longis,  filamentis  papil- 
loso-crispatis  circa  5  mm.  longis  antheris  longioribus,  capsulis  immatu- 
ris  brevibus  ovoideis. — Durango  :  Otinapa,  July  25-Aug.  5,  1906, 
Palmer,  no.  437.  Near  A,  scabrellum  Baker,  from  which  it  differs  in 
its  cartilaginous-margined  and  strongly  falcate  leaves,  similar  to  those 
of  A.  drepanoides  Greenman.  From  the  latter  species  it  differs  in 
its  scabrous  stem,  smaller  size,  and  fewer,  chartaceous  bracts.  In  A. 
drepanoides  the  bracts  are  about  5,  and  the  lower  are  foliaceous  and 
falcate,  like  the  root-leaves. 

Nemeistylis  (§  Chlcmiydostylus)  latifolic^  n.  sp.,  bulbo  ovoideo 
tunicis  brunneis  friabilibus,  caule  simplici  subflexuoso  in  speciminibus 
visis  circa  4.5  dm.  alto  folium  unicum  erectum  bracteamque  vaginan- 
tem  gerente,  folio  radical!  uno  lineari-lanceolato  longe  acuminato  apice 
setaceo  3  dm.  longo  1-1.5  cm.  lato  plicato  valde  nervato,  folio  caulino 
simili  inflorescentia  breviore  vel  earn  aequante  ejus  vagina  3-3.5  cm. 
longa  scariosi-marginata,  bractea  acuminata  scariosi-marginata  7.5-8.5 
cm.  longa,  spatha  5.3  cm.  longa  valvis  acuminatis  aequilongis  vel  ex- 
teriore  paulum  longiore,  floribus  in  spatha  4,  pedicellis  filiformibus 
spatham  aequantibus  vel  exsertis,  perianthiis  albis  marcescentibus 
paulum  caerulescentibus  3  cm.  (?)  latis,  filamentis  brevissimis  minus 
quam  1  mm.  longis,  antheris  1  cm.  longis  connectivis  angustis,  styli 
ramis  filiformibus  antheras  subaequantibus  parte  indivisa  circa  1  mm. 
longa,  fructu  non  viso.  —  Guerrero:  hills,  near  Iguala,  alt.  915  m., 
July  29,  1907,  PringUy  no.  10,391.  Distinguished  from  all  the  other 
Mexican  species  hitherto  described  by  its  very  short,  almost  obsolete 
filaments.  In  this  respect  it  resembles  some  of  the  South  American 
species,  but  is  not  satisfactorily  referable  to  any  of  them. 

Querous  (§  Brythrobalanus)  ^ysophyll6^  n.  sp.,  arborea  magna, 
cortice  nigricante  aspera  vel  profunde  sulcata,  foliis  integris  ovato- 


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424  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

lanceolatis  14-21  cm.  longis  4.5-8  cm.  latis  basi  cordatis  vel  rarias 
truncatis  in  apicem  acotum  sensim  angustatis  apice  (in  foliis  imma- 
taris)  arista  gracili  3-4  mm.  longa  munitis  coriaceis  glabris  vel  subtus 
in  axillis  nervorum  barbatis  pallide  viridibus  subnitidis  valde  reticu- 
lato-rugosis  nervis  supra  impressis  subtus  prominentibus  marginibus 
leviter  incrassatis  durisque  sicut  nervis  marginalibus,  petiolis  5-7  mm. 
longis  crassis  supra  planis  tomentosis  vel  glabratis,  stipulis  persistenti- 
bus  linearibus  1.2-1.5  cm.  longis,  floribus  femineis  2-4  folii  in  axiUa 
singula  sessilibus,  cupulae  immaturae  squamis  late  ovatis  obtusis 
glabris  vel  minute  furfuraceis,  glandibus  non  visis.  —  Nuevo  Leon  : 
Sierra  Madre,  Monterey,  Pringle,  nos.  10,225, 10,226, 10,379.  A  well- 
marked  species,  nearest  Q.  nectandrae/olia  Liebmann. 

Mirabilis  Prpglei,  n.  sp.,  caulibus  herbaceis  circa  1  m.  altis  ramosis, 
ramis  dense  glanduloso-puberulentibus,  foliis  late  ovatis  vel  suborbi- 
culatis  7-10  cm.  longis  5-9  cm.  latis  integris  cordatis  acutis  vel 
breviter  acuminatis  ciliolatis  praeter  nervos  glanduloso-puberulentibus 
subtus  sparse  et  minute  pubescentibus  pilis  brevibus  adpressis,  in- 
florescentiae  foliis  parvis  subsessilibus,  inflorescentia  divaricato-cymosa 
non  congesta,  cymis  breviter  pedunculatis,  involucris  unifloris  campan- 
ulatis  glandulosis  ejus  laciniis  ovatis  obtusis  in  anthesi  tubam  subae- 
quantibus,  perianthiis  pallide  roseis  2.5-3  cm.  longis  cylindraceis  basi 
paulum  dilatatis  et  quam  ovarium  latioribus  limbo  angusto,  stam- 
inibus  5  longe  exsertis  perianthii  tubo  duplo  longioribus,  anthocarpiis 
glabris  tuberculatis  circa  7  mm.  altis  5  mm.  latis  pentagonis  in  angulis 
costatis  basi  late  truncatis.  —  Guerrero:  under  limestone  cliffs,  Iguala 
Cafion,  alt  915  m.,  July  23,  1907,  Pringle,  no.  10,384.  Near  M.  exserta 
Brandegee,  from  which  it  differs  in  its  tuberculate,  five-ribbed  antho- 
carp  and  in  the  shape  of  its  perianth  which,  at  base,  is  broader  than  the 
ovary.  From  M,  Jalapa  and  its  immediate  allies  it  differs,  as  does 
M.  exsertUy  in  its  long-exserted  stamens  and  style  and  in  its  more  open 
inflorescence. 

OxYBAPUUS  GLABER  Watson.  The  type  material  of  this  species  con- 
sisted only  of  a  portion  of  the  panicle.  The  following  amplified  descrip- 
tion, drawn  up  largely  from  the  specimen  of  Mr.  Pringle's  cited  below, 
may,  therefore,  be  of  service. 

Perennial ;  stem  stout,  glabrous,  8  dm.  high,  simple  below,  branch- 
ing above,  the  lower  intemodes  numerous  and  short  (2  cm.  long)  ; 
leaves  linear,  4-8  cm.  long,  3-6  mm.  wide,  thick,  glabrous ;  panicle 
large  and  open,  its  branches  opposite  and  strictly  glabrous  ;  involucres 
somewhat  campanulate,  4-8  mm.  high,  about  1  cm.  across  when 
mature,  glabrous  or  minutely  strigiUose  with  short  yellow  hairs,  on 
slender  glabrous  pedicels  4-8  mm.  long;  flowers  cleistogamous  (?), 


^ 


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WEATHERBY.  —  MEXICAN  PHANEROGAMS.  425 

the  perianth  inconspicaous,  equalling  or  shorter  than  the  involucre ; 
fruit  lance-ovate  in  outline,  acute  at  the  apex,  narrowed  at  the  base, 
with  five  narrow  but  prominent  smooth  ribs,  the  space  between  more  or 
less  strongly  tuberculate,  glabrous  or  minutely  strigillose  between  the 
ribs.— Am.  Nat  vil  302  (1873).  —  Kanab,  South  Utah,  Mrs.  A.  P, 
Thompson.  Chihuahua:  sand  hills  near  Paso  del  Norte,  Sept.  20, 
1886,  Pringle^  no.  1126.  A  specimen  from  Kansas,  sand  hills,  Eeamy 
Co.,  Aug.  29,  1897,  A.  S.  Hitchcock^  no.  421b  perhaps  belongs  here 
also. 

There  is  in  the  Gray  Herbarium  a  plant  clearly  referable  to  this 
species,  but  differing  from  the  typical  form  in  its  pubescent  pedicels 
and  involucres.  It  seems  worthy  of  recognition  as :  var.  recedeno, 
n.  var.,  a  forma  typica  differt  pedicellis  involucrisque  pubescentibus.  — 
Chihuahua  :  between  Casas  Grandee  and  Sabinal,  altitude  1550- 
1700  m.,  Sept  4-5,  1899,  Nelsoriy  no.  6351. 

In  the  course  of  a  recent  attempt  to  rearrange,  with  the  aid  of 
Mr.  Standley's  excellent  monograph,  the  Mexican  specimens  of 
Nyctaginaceae  in  the  Gray  Herbarium,  it  became  apparent  that,  under 
the  Vienna  Rules,^  several  new  combinations  in  the  genus  Oxyhaphus 
were  required.    They  are  accordingly  proposed  here,  as  follows  : 

Ozybaphus  texensis  (Coult.),  n.  comb.  AUionia  corymbosa,  var. 
teocemis  Coult  Contr.  U.  S.  Nat  Herb.  ii.  351  (1894).  AUionia  texensis 
Small,  Fl.  Southeast  U.  S.  406  {1^02^).  — Coulter's  no.  912,  from 
Mexico,  but  without  more  definite  locality,  should  apparently  be 
referred  here. 

Oxybaphus  ooahuilensis  (Standley),  n.  comb.  AUionia  coahuilen- 
sis  Standley,  Contr.  U.  S.  Nat  Herb.  xii.  347  (1909). 

Oxybaphus  melanotriohus  (Standley),  n.  comb.  AUionia  melano- 
tricha  Standley,  1.  c.  351.  The  following,  not  cited  by  Mr.  Standley, 
belongs  here :  Chihuahua  :  mountains  near  Pilares,  23  Sept,  1891, 
C.   V.  Hartman,  no.  743. 

Oxybaphus  pseudaggregatus  (Heimerl),  n.  comb.  Mirabilis 
pseudaggregata  Heimerl,  Ann.  Cons,  et  Jard.  Gen6v.  v.  183  (1901). 
AUionia  pseudaggregata  Standley,  1.  c.  356.  —  The  following  specimens 
belong  here :  San  Luis  Potosi  :  alt  1850-2500  m.,  1878,  Pan-y  <b 
Palmer^  no.  768 ;  in  montibus  San  Miguelito,  1876,  Schaffner^  no.  177. 
Valine  de  Mexico,  Guadelupe,  ler  Aodt,  1865,  Bourgeau,  no.  651. 

Urvillea  bitemata,  n.  sp.,  fruticosa  1-2  m.  alta  glabra  vel  ramulis 
minute  pulverulentibus,  ramis  3-5-co8tatis  costis  obtusis  interdum 
rubris  inter  costas  planiusculis  vel  leviter  sulcatis,  foliis  bitematis, 
foliolis  membranaceis  glabris  vel  subtus  praeter  nervos  sparse  pubes- 
centibus punctis  lineisque  pellucidis  minute  punctatis  ovatis  subtus 


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426  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

pallidioribas,  terminalibus  11-15  cm.  longis  4.5-5.5  cm.  latis  obtuse 
acuminatis  macronulatis  supra  medium  paucis  dentibus  crenatds  basi 
abrupte  angustatis  sicut  in  petiolulam  alatam  1-2  cm.  longam,  laterali- 
bus  similibus  minoribus  interdum  obliquis  acumine  breviore,  inflores- 
centiae  paniculis  angnstid  axillaribus  longe  (ad  8  cm.)  pedunculatds 
2-cirrhosis,  sepalis  5,  3  mm.  longis  concavis  obtusis  late  ovatis  minute 
pubescentibus  duobus  ezterioribus  paulum  minoribus,  petalis  4,  3  mm. 
longis  obovatis  vel  suborbiculatis  unguiculatis  rotundatis,  duobus  supe- 
rioribus  squamas  gereutibus  latas  cucullatas  apice  in  appendicem  longam 
deflexam  productas  appendice  et  marginibus  barbatas  summo  dorso 
crista  dilatata  subflabelliforme  instructas,  duoram  inferiorum  squamis 
minoribus  margine  barbatis  summo  dorso  cuspidatis,  disci  glandis  duobus 
oblongis  basi  latioribus  et  callosis  inter  callos  concavis,  staminibus  8, 
filamentis  crassis  extra  sparse  villosis,  antheris  introrsis,  fiructu  trialato 
subobovato  1.8  cm.  longo  1.3  cm.  lato  apice  leviter  emarginato  vel 
rotundato  basi  subacute.  —  Ouerrebo  :  Iguala  Gaiion,  alt.  915  m.,  July 
24,  1907,  Pringle,  no.  10,380.  An  anomalous  species,  distinguished 
from  all  the  other  species  of  Urvillea  by  its  bitemate  leaves.  In  habit 
it  resembles  some  species  of  Serjania^  but  has  the  fruit  of  Urvillea, 

Euphorbia  (§  Anisophyllum)  ohedicophila.,  n.  sp.,  erecta  annua  (?) 
basi  ramosa,  caulibus  teretibus  gracilibus  3.5-4  dm.  altis  dichotome 
ramosis  pilis  albis  crispatis  dense  vestitis,  foliis  oppositis  lanceolatis 
basi  valde  obliquis  subcordatis  fftlcatis  acutis  vel  obtusiusculis  brevissime 
petiolatis  ab  apice  fere  ad  basin  serrulatis  pilosis,  caulinis  15-19  mm. 
longis  3-5  mm.  latis,  involucris  brevissime  pedicellatis  in  cymosulaa 
paucifloras  bracteatas  ad  apices  ramulorum  congestis  turbinatis 
0.6  mm.  altis  extus  glabris  intus  hirtellis  non  fissis,  lobis  ovato- 
lanceolatis  pectinatis,  glandulis  transverse  ellipticis  0.5  mm.  longis  sub- 
concavis  appendice  rubra  vel  rubella  0.5  mm.  lata  integra  vel  emar- 
ginata,  capsulis  1.5  mm.  altis  brevipedunculatis  glabris  vel  sparse 
pilosis,  seminibus  laevibus  griseis  ovatis  baud  angulatis  1  mm.  longis. 
—  Jalisco  :  gravelly  banks  of  gullies  near  Guadalajara,  alt.  1525  m., 
October  12,  1903,  Pringle^  no.  11,846.  In  habit  and  in  the  characters 
of  the  involucre  very  like  narrow-leaved  forms  oi  E,  brasiltensis  Lam., 
but  differing  in  being  pilose  throughout  and  in  its  smooth  seeds. 

Euphorbia  (§  Anisophylluxxi)  chamaecaulai,  n.  sp.,  perennis  rube- 
scens,  caulibus  ex  apice  radicis  pluribus  prostratis  ramosis  compressis 
infra  nodes  paulum  dilatatis  glabris,  foliis  oppositis  brevissime  petio- 
latis late  ovatis  basi  subcordatis  obliquis  apice  obtusis  integris  glabris 
vel  &cie  superiore  sparse  pilosis,  caulinis  6-8  mm.  longis  4.5-6  mm. 
latis,  ramulinis  minoribus,  involucris  in  axillis  foliorum  solitariis  vel 
apicibus  ramulorum  in  cymosulas  paucifloras  aggregatis  pedicellatis 


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WEATHERBY.  —  MEXICAN  PHANEROGAMS.  427 

campanulatis  extus  intusque  glabris,  lobis  parvis  ovatis  fimbriatis, 
glandulis  ellipticis  0.6  mm.  longis,  appendice  conspicua  alba  flabelli- 
forme  integra  vel  crenalata  0.5  mm.  lata,  pedicellis  2.5  mm.  longis  vel 
brevioribus,  capsulis  2  mm.  longis  1.5  mm.  latis  subacute  carinatis 
omnino  glabris,  seminibus  pallidis  oblongis  apice  apiculatis  quadraogu- 
laribus  inter  angulos  subtransverse  vel  irregalariter  rngosis.  — Jalisco  : 
gravelly  plain  near  Guadalajara,  Oct  14,  1903,  Pringle^  no.  11,848. 
Near  K  prostrata,  from  which  it  differs  as  follows  :  E.  prostrata,  plant 
green,  leaves  strictly  oblong,  abruptly  rounded  at  apex,  capsules  hairy 
on  the  angles,  glands  with  very  short  or  no  appendages.  E.  chamae- 
cauUiy  leaves  mostly  ovate,  tapering  somewhat  to  the  obtuse  apex, 
plant  reddish,  capsule  entirely  glabrous,  glands  with  conspicuous  white 
&n-shaped  appendages. 

Manihot  intermedia,  n.  sp.,  fruticosa  erecta  1-2  m.  alta  omnino 
glabra,  foliis  orbiculatis  palmatis  non  peltatis  fere  ad  petiolam  pro- 
funde  7-8-lobatis,  supra  viridibus  subtus  pallidis  venis  albis  reticula- 
rs, lobis  medianis  foliorum  inferiorum  lanceolatis  sinuata-lobatis  infra 
apicem  late  et  abrupte  rhombeo-dilatatis  apice  setaceo-mucronatis, 
dnobus  lobis  lateralibus  parvis  lanceolatis  integris,  lobis  medianis  foli- 
orum superiorum  leviter  sinuatis  nee  lobatis  nee  rhombeo-dilatatis,' 
petiolis  limbo  brevioribus  vel  eum  subaequantibus  glaucis,  racemis 
brevibus  3-4  cm.  longis  3-4  ad  apicem  ramulorum  fasciculatis  patulis,  ' 
bracteis  pedicellas  aequantibus  vel  paulum  superantibus  lineari-seta- 
ceis,  pedicellis  5-10  mm.  longis  saepe  bracteas  duas  oppositas  parvas 
infra  medium  gerentibus,  florum  masculorum  perianthiis  gamophyllis 
5-lobatis  campanulatis  circa  15  mm.  altis  basi.rotundatis  extus  glauco- 
oaerulescentibus  intus  flavescentibus  venosis  extus  intusque  glabris, 
laciniis  deltoideis  tube  triple  brevioribus,  staminibus  longioribus  peri- 
anthium  aequantibus,  capsulis  glabris  globosis  in  siccitate  rugosis,  semi- 
nibus laevibus  ellipticis  latere  interiore  planis  vel  obtusissime  angulatis 
exteriore  convexis.  —  Guerrero  ;  limestone  cliffs  of  Iguala  Cafion,  alt. 
915  m.,  July  29,  1907,  Pringle,  no.  13,938.  Intermediate  between  M. 
carthaginensis  and  M.  acutiloba^  having  nearly  the  foliage  of  the  former 
but  the  flowers  of  the  latter ;  and  apparently  differing  from  both  in 
its  bracted  pedicels. 

Ipomoea  (§  Pharbitis)  igucdensis,  n.  sp.,  volubilis  tota  papilloso- 
hirsuta  pilis  plus  minusve  flavescentibus  2-3  mm.  longis  vel  caulibus 
glabrescentibus,  marginibus  foliorum  bractearnm  sepalorumque  pilis 
similibus  dense  papilloso-ciliatis,  foliis  longe  petiolatis  (ad  2  dm.)  ovato- 
orbiculatis  cordatis  breviter  acuminatis  7.5-12  cm.  longis  7-13  cm.  latis, 
pedunculis  petioles  subaequantibus  vel  superantibus  3-flori8,  inflore- 
scentia  capitata  congesta,  ejus  bracteis  duabus  late  ovatis  cuspidatis 


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428  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

venosis  membranaceis  17  mm.  longis  pedicellas  brevissimas  floriferas 
sicut  involucrum  includentibus  et  occultantibus,  sepalis  circa  13  mm. 
longis  acutis,  duobus  exterioribus  latioribus  ovatis  5  mm.  latis  intns 
circa  10-nervatis,  tribus  interioribus  lanceolatis  2-2.5  mm.  latis,  corolla 
5  cm.  longa  pallide  purpurea  tube  angusto  infundibuliforme,  tubo  et 
plicis  dense  pilosis,  limbo  glabro,  capsulis  non  visis.  —  Guerrero  ; 
Iguala  Canon,  alt  760  m.,  September  21,  1905,  Pringle,  no.  10,054. 
Apparently  near  /.  hirtijlora  Mart.  &  (Sal.,  from  which  it  diflFers  in  its 
almost  setose  pubescence. 

JusTiciA  PAcmcA  (Oerst)  Hemsl.  Mr.  Pringle's  no.  10,145,  from 
Balsas  in  the  state  of  Guerrero,  agrees  excellently  with  Oersted's  de- 
scription. The  original  specimens  were  in  fruit  only  and  the  species 
was  doubtfully  referred  to  Justicia  by  Hemsley.  Mr.  Pringle's  plant 
shows  a  glabrous  corolla  2.5  cm.  long  with  the  short  tube  and  broad 
limb  characteristic  of  Justicia,  The  species  would  seem,  then,  to  be 
certainly  a  Justicia  and  allied  to  J,  furcata,  but  differing  from  all 
forms  of  that  species  in  its  grayish-puberulent  stem,  spicate  inflores- 
cence, ciliate  bracts  and  in  the  very  broad  white  margins  of  its  calyx- 
lobes. 


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Proceedings  of  fhe  Amencan  Academy  of  Arts  and  Sciences. 
Vol.  XLV.  No.  18.  — May,  1910. 


CONTRIBUTIONS  FROM  THE  ROGERS  LABORATORY 

OF  PHYSICS,  B1ASSACHU8ETTS  INSTITUTE 

OF  TECHNOLOGY. 


LIIL  — OiST  THE  EQUILIBRIUM  OF  THE  SYSTEM 
CONSISTING  OF  LIME,  CARBON,  CALCIUM  CAR-^ 
BIDE  AND  CARBON  MONOXIDE. 


By  M.  DeKay  Thompson. 


IimrrioATioini  on  Lnnr  avd  Hsat  madb  ahd  fvblibrbd,  wbollt  ob  ni  past,  with  ApnonoATKur 
raoM  TBB  RuMfosD  Fuiro. 


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Gor, 


CONTRIBUTIONS   FROM   THE   ROGERS   LABORATORY 

OF    PHYSICS,    MASSACHUSETTS    INSTITUTE 

OF   TECHNOLOGY. 

LIIL  —  ON  THE  EQUILIBRIUM  OF  THE  SYSTEM  CONSISTING 

OF  LIME,  CARBON,  CALCIUM  CARBIDE  AND 

CARBON  MONOXIDE. 

By  M-.  deKat  Thompson. 
Presented  by  H.  M.  Goodwin.  February  0.  1010.    Received  February  20.  1010. 

1.  Introduction. 

Whilb  the  author  of  the  following  paper  was  working  on  the  subject 
indicated  in  the  title  above,  an  article  dealing  with  the  same  matter 
appeared  in  the  Electrochemical  and  Metallurgical  Industry.^  The 
present  writer's  results  did  not  agree  with  those  in  the  article  referred 
to,  and  it  was  therefore  thought  best  to  publish  a  preliminary  paper  on 
the  subject^  which  was  accordingly  presented  at  the  October  meeting 
of  the  American  Electrochemical  Society  in  New  York  As  the  work 
has  now  been  brought  to  a  close,  the  following  article  will  be  made 
complete,  including  all  of  the  preliminary  publication  that  is  necessary 
for  clearness. 

According  to  the  Phase  Rule  *  the  substances  taking  part  in  the  re* 
action  CaO  +  30  ;=±  CaC,  +  CO  form  a  monovariant  sjrstem,  that  is  to 
say,  for  any  given  temperature  there  is  a  definite  pressure  of  carbon 
monoxide  which  will  preserve  equilibrium.  In  order  that  equilibrium 
can  exist  the  reaction  must  be  reversible.  The  fi^^t  that  this  reaction 
is  reversible  has  been  shown  by  Rothmund  ^  and  others.*  Rothmund 
also  attempted  to  measure  the  temperature  of  formation  of  carbide  by 
heating  to  different  temperatures  lime  and  carbon,  and  testing  the 
charge  immediately  afterwards  to  see  if  it  reacted  with  water,  giving 
off  acetylene.    The  furnace  used  consisted  of  a  carbon  tube  through 

*  C.  A.  Hansen,  Electrochem.  Met.  Ind.  1909,  7,  427. 
«  See  Findlay,  "The  Phase  Rule,"  p.  16. 

»  Zeitschr.  f.  anorg.  Chem.  1902,  31,  136. 

*  A.  Frank,  Zeitschr.  f.  angew.  Chem.  1905,  44,  1733. 


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432  PROCEEDINGS  OF  THE  AMERICAN  ACADEBdY. 

which  an  electrical  current  was  passed.  The  assamption  that  must  be 
made  with  regard  to  the  partial  pressure  of  the  carbon  monoxide  is 
that  it  is  constant  and  is  due  to  oxygen  of  the  air  acting  on  the  carbon 
tube,  giving  one-third  of  an  atmosphere.*  Unless  the  temperature  is 
raised  above  that  corresponding  to  one-third  of  an  atmosphere,  no  car- 
bide would  be  found.  By  repeated  trials  this  temperature  could  be 
located  within  certain  limits,  if  the  above  assumption  is  trua  In  this 
way  Rothmund  found  1620°  G.  as  the  temperature  of  formation.  Sim- 
ilar experiments  were  repeated  later  by  Rudolphi,®  who  found  the  tem- 
perature of  formation  to  lie  between  1800  and  1819*^  C,  that  is,  about 
200^  higher  than  Rothmund's  value.  The  temperature  measurements 
were  made  by  an  optical  method,  as  were  also  Rothmund's.  Finally, 
Lampen,^  by  a  method  similar  to  the  above,  using  a  Wanner  pyrometer 
for  temperature  measurements,  found  1725°  C.  for  the  temperature  of 
formation.  It  seemed  evident,  from  the  poor  agreement  of  these  results, 
all  obtained  by  the  same  method,  that  some  other  method  would  have 
to  be  used  in  which  the  pressure  of  the  carbon  monoxide  could  also  be 
measured,  as  these  differences  might  be  due  simply  to  different  values 
of  this  quantity.  It  was  the  object  of  the  following  investigation  to 
make  these  measurements. 

2.  Method  and  Results. 

The  method  decided  on  was  to  heat  the  charge  in  a  vacuum  furnace 
connected  with  a  mercury  manometer  and  to  measure  the  temperature 
of  the  charge  and  pressure  of  the  carbon  monoxide  when  equilibrium  is 
reached.  A  small  Arsem  ^  vacuum  furnace,  made  by  the  General  Elec- 
tric Company,  was  the  apparatus  used.  It  consists  of  a  cylindrical 
bronze  casting  24  centimeters  in  inside  diameter  and  39  centimeters  in 
length.  Parallel  to  the  axis  in  the  center  of  the  casting  and  Sskstened 
to  the  lid,  is  a  graphite  helix,  27  centimeters  in  length,  5.1  in  outside 
diameter  and  0.5  in  thickness  of  wall.  The  helix  is  clamped  at  each 
end  by  water-cooled  electrodes.  The  lid  is  fastened  to  the  casting  with 
a  number  of  cap-screws  and  a  leaSi  washer.  The  whole  furnace  is  im- 
mersed in  water  with  the  exception  of  a  tower  projecting  from  the  center 

•  Rothmund  erroneously  assumes  the  pressure  of  the  carbon  monoxide  to 
be  1/5  atmosphere,  probably  because  this  is  the  partial  pressure  of  oxygen  in 
the  atmosphere.  Taking  into  consideration  that  every  mole  of  oxygen  pro- 
duces two  of  carbon  monoxide,  1  /3  atmosphere  is  the  result  obtained. 

«  Zeitschr.  f.  anorg.     Cliem.  1907,  64,  170. 

f  Jour.  Am.  Chem.  Soc.,  1906,  28,  864. 

8  Trans.  Am.  Electrochem.  Soc.,  1906,  9,  163. 


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I'HOMPSON.  —  ON   THE    EQUIUBRIUM    OF  THE   SYSTEM. 


433 


of  the  lid  containing  a  mica  window,  making  it  possible  to  see  the  hot 
material  held  in  the  center  of  the  spiral  The  support  for  the  crucible 
is  a  graphite  rod  held  by  the  lower^  electrode,  but  insulated  by  lava 
rings.  The  lid  also  contains  a  pipe  by  which  the  furnace  may  be  ex- 
hausted. A  Oeryk  oil  pump  was  used  for  obtaining  the  vacuum.  The 
pressure  could  be  read  by  a  wooden  scale  divided  in  millimeters  on  a 
mercury  gauge  completely  evacuated  and  sealed  off  at  one  end,  thus 


laAn 

• 

/ 

1600 

/ 

r 

/ 

r 

1400 

/ 

/ 

o  VXO 

/ 

/ 

|iooo 

S 

/ 

1 

800 

/ 

. 

/ 

Ann 

/ 

oOO 

/ 

400 

/ 

400 


600 


800  1000  1200 

Temperature  Indicated 


1400 


1600 


Figure  1.  Calibration  of  Thermoelectric  Junction. 

making  a  siphon  barometer.  The  temperature  of  the  gas  contained  in 
the  furnace  is  not  constant,  but  all  that  determines  the  equilibrium 
besides  the  pressure  is  the  temperature  of  the  solid  substances  and  of 
the  gas  in  contact  with  it  Of  course  the  pressure  must  be  constant 
throughout  the  furnace. 

In  the  first  experiments  the  temperature  was  measured  by  a  Wanner 
pyrometer^  which  rendered  it  necessary  to  replace  the  mica  window  by 
one  of  glass  clamped  between  rubber  and  sealed  up  with  paruflin.  In 
calibrating  the  p3nx>meter  a  similar  piece  of  glass  was  placed  between 
the  amylacetate  standard  and  the  instrument.    The  Wanner  was  found 

VOL.  XLV. — 28 


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434 


PROCEEDINGS  OF  THE   AMERICAN   ACADEMY. 


TABLE  I. 
Calibration  of  Thermoelectric  Junction. 


Temperature  read  directly  from 
scale. 


1065°  C. 

1075°  C. 

655°  C. 

650°  C. 

445°  C. 

440°  C. 

True  Temperature. 

Melting  point  of  (Jold  .  . 
Melting  point  of  Alaminnm 
Boiling  Sulphur    .... 

to  be  unreliable,  however,  apparently  due  to  inconstibncy  in  the  amyl- 
acetate  standard.^  The  furnace  was  therefore  calibrated  by  means  of  a 
platinum  platinum-rhodium  junction,  that  is,  the  temperature  of  the 
crucible  was  measured  while  the  power  was  held  constant    The  tem- 

TABLE  II. 
Calibration  of  Furnace. 


Kilowatto. 

lemperature  oy  inermo- 
electric  junction. 

Remarka. 

3.60 

968° 

7.03 

8.98 

1185° 
1325° 

1st  spiral 

9.71 

1368° 

3.12 

925° 

4.99 

1062° 

7.10 
8.03 

1180° 
1225° 

2d  spiral 

9.00 

1262° 

9.81 
7.68 
6.15 

1325° 

1180° 
1100° 

2d  spiral 
repeated  on 
following  day 

perature  was  then  subsequently  determined  by  measuring  the  power 
applied.  Heating  was  furnished  by  an  alternating  current  with  a  fre- 
quency of  sixty  cycles  per  second.  This  was  taken  from  a  transformer- 
switchboard  so  arranged  that  the  voltage  could  be  varied  in  steps  of 
about  twelve  volts.  For  the  finer  regulation  a  carbon  plate  rheostat,  in 
which  current  regulation  could  be  obtained  by  varying  the  compres- 

•  The  temperatures  measured  in  the  former  article  on  this  subject  are  ac- 
cordingly from  100®  to  150°  too  low,  but  the  general  conclusions  there  reached 
are  not  affected. 


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THOMPSON.  —  ON   THE    EQUIUBRIUM    OF   THE   SYSTEM. 


435 


sion  on  the  plates  was  found  satisfactory.    The  tenninals  were  copper 
boxes  filled  with  water. 
Figure  1  gives  the  calibration  of  the  junction.     The  galvanometer 


/ 

1500 

> 

'A 

A 

/  / 

/ 

1il/Vl 

• 

A 

V 

1400 

A 

> 

// 

f 

1900 

^ 

'/ 
f 

lonA 

/^ 

;;'' 

• 

1290U 

/ 

\^A 

4 

f 

1100 

/ 

inno 

>>> 

y 

/ 

V 

900 

/ 

84667S9        10       1112 
Kilowatts 

Figure  2.  Calibration  of  Furnace. 

was  a  Siemens  and  Halske  instrument  made  for  this  special  purpose, 
but  which  did  not  read  as  high  as  the  melting  point  of  platinum. 

In  Table  II  and  Figure  2  the  calibration  of  the  furnace  is  given.  The 
power  was  obtained  from  voltmeter  and  ammeter  readings.  The  am- 
meter scale  read  to  five  amperes  and  was  connected  to  a  current  trans- 
former with  a  ratio  of  60  to  1.     This  instrument  was  not  calibrated. 


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436  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

Two  voltmeters  with  scales  from  0-65  and  40  to  160  were  used.  These 
were  calibrated  so  as  to  make  them  comparable  with  each  other.  The 
alternating  current  instruments  were  of  the  Thomson  type  made  by 
the  (General  Electric  Company. 

In  calibrating  the  furnace  the  wires  of  the  pyrometer  were  protected 
by  fused  silica  tubes  which  extended  up  into  the  tower  in  the  lid  of  die 
fumaoa  The  tubes  were  covered  at  the  junction  by  a  short  graphite 
tube.  This  projected  through  a  hole  in  the  cap  of  the  crucible  con- 
taining the  charge  and  rested  in  the  charge.  The  bare  wires  were 
brought  out  of  the  furnace  at  the  top  of  the  tower  between  rubber 
washers ;  the  furnace  was  then  evacuated  and  the  calibration  taken. 

TABLE  III. 
Variation  of  Temperature  in  Crucible. 


JBtance  of  junction  from 

Temperature. 

bottom  of  crucible. 

0.0  cm. 

1220° 

0.6 

1220° 

1.8 

1225° 

3.3 

1225° 

4.0 

1220° 

4.4 

1215° 

4.8 

1205° 

The  power  was  8.36  kilowatts. 

The  carbon  shield  surrounding  the  spiral  was  not  used  in  these  ex- 
periments on  account  of  the  fact  that  carbon  absorbs  a  large  amount  of 
gas  which  is  not  easily  removed.  It  will  be  evident  from  the  method 
of  experimenting  described  below  that  its  use  would  not  be  permissible. 

In  the  figure  a  circle  is  put  around  those  points  taken  with  the  first 
spiral.  It  is  evident  from  this  figure  that  this  method  of  obtaining  the 
temperature  is  not  as  accurate  as  the  Wanner  pyrometer  would  be 
were  it  in  good  condition. 

It  will  be  seen  that  there  is  no  regular  diflferenoe  in  th^  calibration 
of  the  two  spirals,  except  that  all  the  points  of  the  first  coil  lie  on  the 
upper  dotted  line,  while  some  of  the  points  for  the  second  coil  lie  on 
the  upper  as  well  as  the  lower.  This  is  probably  due  to  the  fiM^t  that 
the  second  spiral  was  calibrated  more  than  once.  It  was  thought  best 
under  the  circumstances  to  draw  the  solid  line  midway  between  the 
two  extremes  and  take  this  for  estimating  the  temperature. 

A  further  test  was  made  to  see  how  constant  the  temperature  was 
throughout  the  length  of  the  crucible.    For  this  purpose  the  junction, 


Digitized  by 


c^ 


THOMPSON.  —  ON   THE    EQUILIBRIUM    OF   THE    SYSTEM.         437 

protected  by  silica  tubes,  was  lowered  through  the  window  in  the  tower 
into  the  crucible  and  the  furnace  heated  without  pumping  out  the  air. 
There  was  ho  lid  on  the  crucible  in  this  experiment.  The  results  are 
given  in  Table  III. 

It  is  seen  tiiat  without  the  lid  and  with  no  charge  in  the  crucible 
the  temperature  is  quite  constant,  which  would  be  improved,  if  any- 
thing, when  the  charge  is  in  the  crucible  and  the  lid  in  position. 

The  carbide  used  in  the  following  experiments  was  made  from  Merk's 
lime  and  Acheson  graphite  powder  in  the  form  of  turnings  from 
graphite  electrodes.  Carbide  was  made  by  heating  a  mixture  of  the 
two  in  an  arc  furnace  consisting  of  a  graphite  electrode  and  graphite 
crucible.  By  the  loss  in  weight  method  ^^  it  analyzed  78  per  cent 
pure.  The  impurities  must  have  been  carbon  and  lime  which  were  not 
harmfril  for  these  experiments. 

The  first  experiments  were  carried  out  at  from  1700®  to  2000**,  but 
no  consistent  results  could  be  obtained.  After  a  run  at  these  temper- 
atures it  was  found  that  the  walls  of  the  furnace  were  alwa3rs  lined 
with  a  white  powder,  whether  lime  and  carbon  were  heated  alone  or 
when  carbide  was  in  an  atmosphere  of  carbon  monoxida  It  was 
found  when  carbide  was  heated  in  carbon  monoxide  to  about  1800® 
only  graphite  was  left  in  the  crucible  and  the  white  powder  was  formed 
on  the  walls.  When  carbide  was  heated  alone  in  a  vacuum  the  walls 
of  the  furnace  were  lined  with  a  thin  sheet  of  calcium,  which  easily 
peeled  o£f  and  took  fire  when  brought  in  contact  with  moisture. 
Graphite  was  left  behind  in  the  crucible.  These  two  &cts  taken 
together  show  that  calcium  reduces  carbon  monoxide  according  to  the 
equation : 

Ca  +  CO  =  CaO  +  C. 

Therefore,  if  carbide  is  to  be  produced,  it  must  either  be  below  the 
temperature  where  it  breaks  up  into  its  elements,  or  the  velocity  of 
the  reaction 

CaO  +  3  C  =  CaC,  +  CO 

must  be  greater  than  the  velocity  of  the  preceding  reaction.  The 
latter  is  evidently  the  state  of  affairs  in  the  manufacture  of  carbide, 
but  equilibrium  measurements  could  hardly  be  made  under  this 
condition. 

^*  Lunge,  Chemische-tcchnische  Untersuchungs  Methoden,  5te  Auflage, 
Band  II,  711.  The  drying  tube  contained  a  layer  of  PjOs  besides  one  of 
Ca  Clj,  which  the  escaping  gas  had  to  pass  first. 


Digitized  by  LjOOQIC 


438  PROCEEDINGS   OF  THE  AMERICAN  ACADEMY. 

From  a  number  of  eicperiments,  which  it  is  not  necessary  to  repro- 
duce here,  it  seemed  that  IdOO""  G.  was  about  the  highest  temperature 
at  which  equilibrium  could  be  measured.  This  conclusion  was  based 
on  the  quantity  of  white  powder  found  on  the  walls  of  the  furnace  after 
runs  at  different  temperatures.  Some  further  experiments  at  about 
this  temperature  showed  that  it  would  be  impossible  to  differentiate 
between  the  pressure  of  carbon  monoxide  and  occluded  gases  that 
came  out  of  the  carbon  spiral  and  the  charge  on  heating  in  a  vacaum. 
It  was  therefore  decided  to  heat  the  charge  in  some  indifferent  gas, 
which  could  be  drawn  off  and  analyzed  for  the  amount  of  carbon  mo- 
noxide present.  Hydrogen  was  of  course  the  only  gas  available.  Ni- 
trogen could  not  be  used  on  account  of  the  fact  that  it  is  absorbed  by 
calcium  carbide  forming  calcium-cyanamide.  Hydrogen  would  have 
no  action  on  carbide,^^  but  it  does  enter  into  an  equilibrium  with 
carbon  monoxide  according  to  the  reaction 

HaO  +  C  ^  Ha  +  CO 

which  is  the  reaction  of  water-gas  formation.  If  an  appreciable  quan- 
tity of  water  were  produced  from  hydrogen  and  carbon  monoxide  this 
would  react  with  the  carbide  and  form  acetylene  and  in  analyzing  for 
carbon  monoxide  by  absorption  in  cuprous  chloride  solution,  acetylene 
would  be  mistaken  for  the  former.  It  can  be  shown,  however,  that  the 
quantity  of  water  vapor  formed  is  too  small  to  have  any  effect  The 
free  energy  of  this  reaction  is  given  by  the  equation  ^^ 

Ai^=  -  27950  +  31.76  T -{-  4.58  T  log  -^«5_ 

where  T  is  the  absolute  temperature  and  the  /?'s  are  partial  pressures. 
At  equilibrium  ^F  =  0,  therefore  placing  the  right-hand  side  of  the 
equation  equal  to  zero,  and  substituting  for  Tits  value  1773^  absolute, 
we  find  that  for  1500°  C. 

^^'^    =  0.000324. 
PcoPh, 

lipm  equals  about  90  centimeters  of  mercury  as  it  does  in  the  follow- 
ing experiments, 

^^  =  0.0029 
^co 

"  Moisson,  **The  Electric  Furnace,"  p.  211. 

"  Hodlander,  Zeitschr.  f.  Elektrochem.  1902,  8,  833. 


Digitized  by  LjOOQli| 


THOMPSON.  —  ON   THE    EQUILIBRIUM    OF    THE    SYSTEM.       439 

or  pu^o  =  0.003  pco,  which  is  a  negligible  quantity.  The  tempera- 
ture of  the  gas,  however,  is  not  all  at  1500°,  but  falls  off  to  the  tem- 
perature of  the  water  cooled  walls  of  the  furnace.  At  1000°  C.  pn%o 
=  .063  pco  which  is  still  a  relatively  small  amount.  What  actually 
happens  is  that  at  the  higher  temperatures  where  the  velocity  of  the 
reaction  is  great,  the  equilibrium  varies  uniformly  with  the  tempera- 
ture, but  as  the  gas  reaches  the  cooler  portions  of  the  furnace,  due  to 
convection  currents,  it  suddenly  becomes  chilled  to  a  point  where  the 
reaction  practically  stops,  leaving  the  concentrations  at  values  corre- 
sponding to  the  higher  temperatures. 

Experiment  1. 

The  charge  consisted  of  lime,  carbon,  and  calcium  carbide  mixed  to- 
gether. A  loosely  fitting  lid  with  a  quarter-inch  hole  in  the  center 
covered  the  crucible.  The  mixture  was  placed  in  the  furnace,  the 
furnace  was  evacuated,  and  the  charge  heated  to  1000°  for  an  hour  to 
drive  off  gases  that  invariably  come  off  on  the  first  heating,  and  par- 
ticularly to  get  rid  of  any  water  contained  as  hydrate  of  calcium.  If 
this  were  not  done  water  would  come  off  during  the  run  and  react  with 
the  carbide  present.  The  furnace  was  then  evacuated  to  a  pressure  of 
0.05  centimeters  of  mercury  and  carbon  monoxide  let  in  to  1.25  centi- 
meters. This  was  generated  from  strong  sulphuric  acid  and  potassium 
ferrocyanide  and  was  washed  with  two  drjdng  towers  of  soda  lime  and 
a  phosphorous  pentoxide  tube.  Hydrogen  was  then  admitted  to  a 
final  pressure  of  63.6  centimeters.  This  was  generated  from  hydro- 
chloric acid  and  zinc  and  was  purified  by  two  bottles  of  permanganate, 
a  hot  copper  gauze,  two  towers  of  soda  lime,  and  a  phosphorus  pen- 
toxide tube.  The  furnace  was  fiUed  with  hydrogen  in  three  quarters 
of  an  hour.  The  volume  of  the  furnace,  after  allowing  for  the  solids 
present  during  a  run  was  19.9  liters.  The  run  began  at  9.45  a.  m.  and 
lasted  till  4.00  p.  m.  The  power  was  held  constant  at  12.0  kilowatts 
corresponding  to  1485°  C.  The  following  table  gives  the  analysis  for 
carbon  monoxide,  made  by  drawing  off  100  cubic  centimeters  into  a 
Hempel  burette  and  absorbing  with  acid  cuprous  chloride  solution. 

Time.  Per  cent  Carbon  Monoxide. 

9.45  A.  M.      Sample  taken  as  furnace  1.05 

warmed  up. 
1.42  p.  M.  Less  than  0.1 

It  was  evident  fi-om  this  result  that  the  quantity  of  gas  corresponding 
to  equilibrium  at  this  temperature  could  not  be  analyzed  by  a  Hempel 


Digitized  by  VjOOQIC 


440  PROCEEDINGS  OF  THE  AMEBICAN  ACADEBIY. 

apparatus.  The  experiment  was  continued  till  4.00  p.  li.  to  make  sure 
equilibrium  had  been  reached.  The  method  used  to  determine  the 
smaU  quantity  of  carbon  monoxide  present  in  this  and  all  the  following 
experiments  was  to  draw  about  half  the  gas  in  the  furnace  through 
two  Liebig  bulbs  sealed  together  and  filled  with  cuprous  chloride  solu- 
tion. These  were  tilted  at  an  angle  so  the  gas  bubbled  through  the 
liquid  on  leaving  each  of  the  five  spheres  of  which  a  Liebig  bulb  is 
composed.  The  gas  then  passed  a  column  seven  centimeters  long  of 
soda  lime  and  another  similar  one  of  phosphorous  pentoxide.  This 
whole  apparatus  was  made  entirely  of  glass  closed  by  two  glass  stop- 
cocks. The  bulbs,  in  which  the  air  was  displaced  by  hydrogen,  were 
hung  in  the  balance  case  by  a  platinum  wire  the  day  before  the  final 
weight  was  taken.  The  air  in  the  balance  case  was  dried  by  two 
beakers  of  sulphuric  acid  and  the  temperature  was  read  firom  a  ther- 
mometer in  the  case.  The  volume  of  the  bulbs  was  determined  by  the 
bottle  method  for  specific  gravity,  in  which  a  large  desiccator  took 
the  place  of  the  bottle.  This  was  necessary  in  order  to  be  able  to 
reduce  the  weighings  to  vacuo.  From  the  total  weight  in  grams  of 
carbon  monoxide  absorbed  the  number  of  moles  is  formed  by  dividing 
by  28,  the  molecular  weight  of  the  gas.  This,  however,  gives  only  a 
fhbction  of  the  total  amount  in  the  furnace.  The  total  amount  is  cal- 
culated as  follows.  If  Ui  s  the  total  number  of  moles  in  the  furnace 
before  any  gas  is, removed,  nt  the  number  after  a  certain  amount  had 
been  drawn  ofiF  through  the  absorption  bulbs,  /?i  =  the  pressure  in  the 
furnace  when  the  absorption  began  and  pt  tiie  pressure  at  the  end, 


piv  =  fiiRTi 
p%v  =  n%RT% 

where  v  equals  the  volume  of  the  furnace.  The  temperatures  were 
equal  to  those  of  the  water  surrounding  the  furnace  and  were  made 
equal  to  each  other  at  the  start  and  finish. 

Therefore  ^  =  ^ 

1H       Pt 
also  m  —  Wa  =  fTl 

if  ^  =  the  number  of  moles  absorbed. 

m 


Solving  fix  = 


i-pi 


pi 


Digitized  by 


G^gle 


THOMPSON.  —  ON   THE    EQUIUBRIUM    OF   THE    SYSTEM.  441 

If  p^  =  the  total  pressure  during  the  run,  which  is  greater  than  p  on 
account  of  the  higher  tcimperature,  the  pressure  in  millimeters  of  carbon 
monoxide  is  computed  by  the  formula 

_mX  .0821  X  y  X  760  X  jp, 
^  ""  19.9  X  pi 

in  which  T  is  the  absolute  temperature  of  the  gas  in  the  furnace  at  the 
beginning  and  at  the  end  of  the  absorption. 

At  the  end  of  the  absorption  the  pressure  of  hydrogen  in  the  absorp- 
tion bulbs  was  only  about  half  an  atmosphere,  consequently  enough 
hydrogen  had  to  be  let  in  to  bring  the  pressure  to  one  atmosphere, 
after  which  the  bulbs  were  again  hung  in  the  balance  case  and  weighed 
the  following  day.  The  variation  due  to  temperature  and  pressure 
change  in  the  weight  of  hydrogen  filling  the  bulbs  was  negligible.  All 
weighings  given  in  the  following  are  reduced  to  vacuo.  The  data  thus 
obtained  after  the  above  run  were  the  following : 

Initial  weight  bulbs  175.3392  grams 

Final         "         "  175.3482      " 

Gain  in  weight  0.0090      " 

The  time  taken  for  absorbing  the  gas  was  6  hrs. 

jth  =  68.5  cm.  of  mercury 
j»j  =  38.6   "     ".      " 
/?8  =  89.0  "     " 

,                       .00074  X  .0821  X  285  X  760  X  89 
^^^"^  ^co  = 19.9  X  68.5 ^ 

=  0.86  mm.  of  mercury. 
On  opening  the  furnace  white  powder  was  found  on  the  lid. 

Experiment  2. 

The  same  charge  as  used  in  Experiment  1  was  ground  up  and  re- 
placed in  the  crucible.  Part  was  tested  with  water  and  gave  off  acet- 
ylene vigorously.  It  was  heated  for  an  hour  to  1000°  and  evacuated 
to  a  pressure  of  0.05  centimeter  of  mercury.  No  carbon  monoxide  was 
admitted.     Hydrogen  was  let  in  to  6.72  centimeters  in  1  hr.  40  min. 


Digitized  by  VjOOQIC 


442  PROCEEDINGS  OF  THE  AMERICAN  ACADEMT. 

Duration  of  run  :  6  hrs. 
Power:  11.7  K.  W. 
Temperature :  1465*^  C. 

Initial  weight  bulbs  182.5989  grams 

Final         "         "  182.6061      " 

Gain  0.0072      " 

Time  taken  for  absorption  4^  hours. 

pi  =  67.2  cm.  of  mercury 
P2  =38.1  "     " 

jE>8  =  91.8    "       " 

.000589  X  .0821  X  288  X  760  X  91.8      ^    „ 
•'*^CO  = 19.9  X  67.2 =  ^-^^  °^°"- 

On  opening  the  furnace  somewhat  more  white  powder  found  on  the 
walls  than  in  Experiment  1. 

This  experiment  was  carried  out  with  the  idea  of  approaching  the 
equilibrium  from  the  side  which  generates  carbon  monoxide.  To  decide 
whether  this  had  been  done  in  the  above  experiment  it  was  necessary 
to  see  whether  the  bulbs  would  gain  no  weight  if  the  furnace  were  filled 
with  hydrogen  and  part  then  drawn  through  the  bulbs.  The  following 
blank  experiment  was  therefore  carried  out.  The  furnace  was  evacu- 
ated to  a  pressure  of  0.15  centimeter  of  mercury,  hydrogen  was  let  in 
to  1  centimeter  and  again  evacuated  to  0.15.  This  operation  was  re- 
peated and  hydrogen  then  let  in  to  67.6  centimeters.  The  final  filling 
took  1  hr.  40  min. 

The  gas  then  drawn  through  the  weighed  bulbs  for  3  hrs.  45  min. 

Pi  =  67.1  cm.  of  mercury 
/?2  =  38.1   "     " 

Initial  weight  reduced  182.606  grams 

Final         "  "  182.627      " 

Gain  0.021      " 

If  the  whole  amount  of  gas  could  have  been  drawn  through  the  gain  in 
weight  would  have  been  0.049  gram.  This  gain  in  weight  must  have 
been  due  to  oxygen,  which  might  not  have  been  removed  or  which 
might  have  gotten  in  while  filling  the  furnace.  This  would  have  been 
converted  to  carbon  monoxide  by  the  hot  carbon  spiral  giving  too  high 
a  pressure  for  equilibrium.    Equilibrium  in  Experiment  2  was  therefore 


Digitized  by  LjOOQIC 


THOMPSON.  —  ON   THE    EQUILIBRIUM    OF    THE    SYSTEM.  443 

approached  from  the  same  side  as  in  Experiment  1.    This  remark  holds 
good  for  all  the  following  experiments. 

Experiment  3. 

As  the  previous  experiments  agreed  fairly  well,  it  was  thought  desir- 
able to  try  a  lower  temperature,  to  make  sure  that  the  gain  in  weight 
of  the  absorption  bulbs  was  really  due  to  carbon  monoxide  and  not  to 
some  impurity  in  the  hydrogen. 

The  charge  consisted  of  fresh  carbide,  lime  and  carbon.  The  furnace 
was  evacuated  to  0.15  centimeter  and  was  heated  to  1000°  till  the 
occluded  gases  coming  off  gave  a  pressure  of  6  centimeters,  which  re- 
quired about  ten  minutes.  It  was  then  evacuated  to  0.15  centimeter 
with  the  furnace  still  at  1000°.  Hydrogen  was  let  in  to  2.4  centimeters 
and  evacuated  to  0.15.  The  furnace  was  then  cooled  and  filled  with 
hydrogen  to  a  pressure  of  67.0  in  1  hr.  40  min. 

Power  :  8.24  K.  W. 
Temperature  :  1250° 
Duration  of  run  :  6  hrs. 

The  solution  of  cuprous  chloride  had  been  used  in  a  previous  ex- 
periment 

Initial  weight  of  absorption  bulbs     183.6340  grams 
Final        "       "  "  "         183.6372      " 

Gain  0.0032      " 

px  =  67.2  cm.  of  mercury 

;?2  =  34.8  "     " 

j^3  =  90.4   "     "        " 

0.000248  X  .0821  X  286  X  760  X  90.4       ^  „^ 
•••^CO  = 19.9->r67.2 =  ^-^^  °^°"- 

Experiment  4. 

The  charge  was  the  same  material  as  in  the  previous  experiment 
with  some  lime  and  carbon  added  and  mixed  up  with  the  rest. 

The  furnace  was  evacuated  to  a  pressure  of  0.2  centimeter  and  heated 
to  900°  for  two  hours.  It  was  then  evacuated  to  0.15  centimeter,  hy- 
drogen was  admitted  to  2.4  and  again  evacuated  to  0.15.  It  was  finally 
filled  with  hydrogen  to  67.3  centimeters  in  1  hr.  40  min. 


Digitized  by  LjOOQIC 


444  PROCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 

Power  :  8.8  K.  W. 
Temperature:  1270° 
Duration  of  run  :  7  hrs.  10  min. 

The  absorption  bulbs  were  refilled. 

Initial  weight  182.9303  grams 

Final       "  182.9316      " 

Gain  0.0013      " 

Pi  =  66.8  cm.  of  mercury 
/?,  =  37.2    "    " 
/?,  =  90.3    «    " 

0.000103  X  .0821  X  285  X  760  X  90.3       ^  ,^ 
"Pco-  19.9^66:8 =  ^'^^  °^ 

Experiment  5. 

The  object  of  the  following  experiment  was  to  see  if  measurements 
might  not  be  carried  out  at  a  somewhat  higher  temperature  where 
the  pressure  would  be  greater  and  the  determination  therefore  more 
accurate. 

The  charge  was  the  same  carbide  used  in  experiment  4  to  which 
about  one  half  as  much  lime  and  carbon,  previously  heated  to  redness, 
was  added.  The  furnace  was  then  evacuated  to  0.2  centimeter  and 
heated  to  900""  for  1^  hours.  It  was  then  evacuated  to  0.2  centimeter 
and  hydrogen  let  in  to  2.3 ;  again  evacuated  to  0.12  centimeter  and 
filled  with  hydrogen  to  67.7. 

The  charge  was  then  heated  7  hours  with  10.0  kilowatts,  correspond- 
ing to  1370°.  This  must  have  established  equilibrium  at  this  tem- 
perature. The  power  was  then  raised  to  12.6  kilowatts  corresponding 
to  1525°  for  4J  hours. 

The  cuprous  chloride  was  the  same  used  in  Experiment  4. 

Initial  weight  182.9243  grams 

Final        **  182.9277      " 

Gain  0.0034      " 

Time  taken  for  absorption  3  hrs. 

^1  =  66.3  cm.  of  mercury 
jt>2=37.7    "     " 
j3,  =  90.0    "     " 


Digitized  by  VjOOQIC 


THOMPSON.  —  ON    THE    EQUIUBRIUM    OP   THE   SYSTEM.         445 

.000280  X  .0821  X  285  X  760  X  90.0      ^  „, 
•'•^co  = 19.9  X  663 =  ^-^^  °"°^- 

On  opening  the  furnace  a  larger  amount  of  powder  than  any  other 
experiments  here  given  was  found  on  the  walls.  This,  taken  in  con- 
nection with  the  small  pressure  found  and  the  experiments  referred  to 
in  the  Introduction  seem  to  indici^te  that  at  this  temperature  the  car- 
bon monoxide  was  removed  by  calcium  coming  from  the  decomposition 
of  carbide. 

It  is  true  that  this  equilibrium  was  really  approached  from  the  side 
of  too  little  carbon  monoxide,  but  as  the  velocity  of  the  reaction  is  the 
same  in  both  directions  at  equilibrium,  this  cannot  account  for  the  low 
pressure  of  carbon  monoxida 

Experiment  6. 

The  hydrogen  used  in  the  following  experiments  was  generated 
electroljrtically  on  platinum  electrodes  dipping  into  sulphuric  acid 
of  1.2  specific  gravity.  The  cathodes  were  contained  in  a  porous  cup 
closed  at  the  top  by  a  cork  stopper  covered  with  paraffin,  through 
which  projected  glass  tubes,  into  which  the  electrodes  were  sealed. 
There  was  also  a  tube  through  which  hydrogen  could  escapa  The 
porous  cup  stood  in  a  small  battery  jar.  The  hydrogen  tube  was  con- 
nected to  a  mercury  manometer  so  that  the  pressure  in  the  cathode 
compartment  could  be  kept  from  0.1  to  1.0  centimeter  above  the 
atmosphere,  thereby  preventing  air  from  leaking  in.  In  Experiment  6 
only  (me  such  electroljrtic  cell  was  used,  but  for  the  last  two  experi- 
ments another  cell  was  connected  in  series  with  the  first,  thus  requir- 
ing only  half  the  time  for  filling  the  furnace.  The  hydrogen  first 
passed  through  a  soda  lime  tube,  then  the  hot  copper  gauze  used  in 
the  previous  experiments,  then  two  soda  lime  towers  and  phosphorous 
pentoxide  tube.  Hydrogen  was  passed  over  the  hot  copper  for  at 
least  half  an  hour  before  any  was  let  into  the  frimace,  in  order  to 
sweep  out  the  air  in  the  tube.  The  object  in  using  electrolytic  hydro- 
gen was  to  show  that  the  above  gains  in  weight  were  not  due  to  im- 
purities in  the  hydrogen  generated  from  zinc  and  hydrochloric  acid. 

The  carbon  monoxide  used  in  the  following  experiments  was  gen- 
erated by  allowing  formic  acid  to  drop  from  a  separatory  funnel  into 
concentrated  sulphuric  acid. 

In  order  to  see  if  all  the  carbon  monoxide  was  absorbed  by  the  two 
Liebig  bulbs  containing  cuprous  chloride  in  the  following  experiments 
a  second  absorbing  apparatus  similar  to  the  above  was  used  with  one 
Liebig  bulb  in  place  of  two.     This  was  filled  with  a  3  per  cent  solution 


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446  PROCEEDINGS  OF  THE  AMEBICJiN  ACADEMY. 

of  neutral  gold  chlorida  This  has  been  found  to  oxidize  carbon 
monoxide  to  dioxide  without  aflfecting  hydrogen.^^  Gold  chloride  in 
an  excess  of  potassium  hydrate  is  even  more  sensitive  to  carbon  mo- 
noxide, but  it  was  found  that  hydrogen  reduced  the  gold  in  the  alkaline 
solution  to  a  black  powder  if  left  in  contact  with  the  solution  over 
night. 

The  charge  consisted  of  about  equal  portions  of  powdered  carbide 
and  a  mixture  of  lime  and  carbon.  It  had  been  used  in  a  previous 
rqn. 

The  cuprous  chloride  in  the  Liebig  bulbs  had  been  used  in  the  three 
previous  experiments,  but  as  a  little  was  tested  with  water  and  gave  a 
heavy  white  precipitate  it  was  not  thought  necessary  to  change  the 
solution. 

The  furnace  was  evacuated  to  a  pressure  of  0.28  centimeter  and 
hydrogen  was  let  in  to  1.0  centimeter;  then  evacuated  to  0.1  and 
carbon  monoxide  let  in  to  0.3  centimeter.  Hydrogen  was  then  ad- 
mitted to  67.3  centimeters  requiring  three  hours  with  a  current  of 
about  14  amperes. 

Duration  of  run:  6^  hours. 
Power:  11.8  K.  W. 
Temperature:  1475° 

Initial  weight  cuprous  chloride  bulbs        173.1312  grams 
Final        "  "  "  "  173.1383      " 

Gain  0.0073       " 

Initial  weight  gold  chloride  bulb  116.8119  grams 

Final        "  "        "  "  116.8158 

Gain  0.0036       " 

Total  gain  0.0110      ** 

The  gain  in  the  gold  chloride  bulbs  was  relatively  large,  probably  on 
account  of  the  cuprous  chloride  having  taken  so  much  carbon  monoxide 
into  solution  that  it  was  not  so  good  an  absorber  as  when  fresh. 

p^  =  65.7  cm.  of  mercury 

/?a  =  92.0    " 

0.000703  X  0.0821  X  287  X  760  X  92       ^  _^ 
...;,co  = f9.9X65.7" =  0.88  mm. 

"  Phillips,  Am.  Chem.  Joum.  1894.  16,  273. 


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THOMPSON.  —  ON   THE    EQUIUBRIUM    OF   THE    stSTEM.  447 

Experiment  7. 

The  charge  consisted  of  powdered  carbide  with  some  coarser  pieces 
OD  top.  It  was  heated  in  the  furnace  at  1050°  for  an  hour  and  a 
quarter  and  evacuated  to  0.1  centimeter.  Hydrogen  was  then  let  in 
to  a  pressure  of  1.6  centimeters,  the  furnace  was  evacuated  to  0.10  and 
carbon  monoxide  let  in  to  0.25  oentimeterr  FinaUy  hydrogen  was  let 
in  to  68.3  centimeters  requiring  one  hour  and  a  half  with  14  amperes. 

Duration  of  run:  6  honrs 
Power:  11.8  K.  W. 
Temperature:  1475** 

The  cuprous  chloride  bulbs  were  refilled,  but  not  the  gold  chlorida 

Initial  weight  cuprous  chloride  bulbs  173.7646  grams 

Final        "  **  "  "  173.7695      " 

Gain  0.0049      " 

Initial  weight  gold  chloride  bulb  116.8121  grams 

Final        "        "          "        "  116.8126      " 

Gain  0.0005      " 

Total  gain  0.0054      " 
Time  required  for  absorption,  3  hours. 

0.00065  X  0.0821  X  291  X  760  X  95       ^  „, 

.*•  vcci  = =  0.81  mm. 

^^  19.9  X  69.3 

Experiment  8. 

The  charge  was  the  same  material  as  used  in  Experiment  7. 

The  furnace  was  evacuated  and  heated  for  an  hour  and  fifty  minutes 
at  1050°.  It  was  then  evacuated  to  a  pressure  of  0.12  centimeter  and 
hydrogen  let  in  to  2.0,  again  evacuated  to  0.15  and  carbon  monoxide 
let  in  to  0.28  centimeter.  Hydrogen  was  then  admitted  to  77.6  centi- 
meters requiring  an  hour  and  a  quarter. 

Duration  of  run :  6  hours,  10  minutes* 
Power:  11.4  K.  W. 
Temperature:  1445°  C. 
The  cuprous  chloride  bulbs  were  refilled. 
Initial  weight  of  cuprous  chloride  bulbs        167.4274  grams 
Final         "      "         "  "  "  167.4312      " 

0.0038      " 


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448 


PtoCEEDINOS    OF   THE    AMEBICAN    ACADEMY. 


The  tube  previonsly  used  for  gold  chloride  was  filled  with  caproos 
chloride. 

Initial  weight  of  second  cnprous  chloride  tube        119.3358  grams 
Final        "      "      "  "  '*  "  119.3363      " 

Gain  0.0005      " 

Total  gain  0.0043 

Pi  =  67.1  cm  of  mercury 
j»a  =  37.7    ** 
/>a  =  92.7    " 
The  time  taken  for  absorption  was  3  J  hours. 

.000350  X  0.0821  X  287  X  760  X  92.7       ^  , , 
••^  = 19.9  X  67.1 =0.44  mm. 

3.    Discussion  of  Results. 

For  convenience  the  results  obtained  above  are  collected  in  the 
following  table. 


TABLE 

IV. 

No. 

of 

Exp. 

Dura- 
tion in 
Houre. 

KUo- 
watta. 

Temp. 

Centi- 
grade. 

Gain  in 
Weight  of 
IstBulb. 

Gain  in 
Weight  of 
2dBulb. 

Time 

taken  for 

Absoip- 

tion  m 

Houra. 

Initial 
Pressure 

coin 
mm.  Hg. 

Final 
Premure 

coin 
mm.  Hg. 

1 

6J 

12.0 

1485 

0.0090 

6 

12.5 

0.86 

2 

6 

11.7 

1465 

0.0072 

4i. 

0.0 

0.73 

3 

6 

8.2 

1250 

0.0032 

3i 

0.0 

0.30 

4 

7 

8.8 

1270 

0.0013 

2| 

0.0  . 

0.13 

5 

4J 

12.6 

1525 

0.0034 

3 

0.0 

0.34 

6 

6i 

11.8 

1475 

0.0073 

0.0036 

4 

2.0 

0.88 

7 

6 

11.8 

1475 

0.0049 

0.0005 

3 

1.5 

0.81 

8 

6 

11.4 

1445 

0.0038 

0.0005 

3i 

1.3 

0.44 

In  all  of  these  experiments,  even  at  1250^,  there  was  some  white 
powder  on  the  walls  of  the  furnace.  Whether  a  slight  decomposition 
of  carbide  into  its  elements  takes  place  at  this  temperature  could  not 
be  decided  by  this  means,  as  the  white  powder  may  have  been  due  to 


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THOMPSON.  —  ON   THE    EQUILIBRIUM    OF   THE   STSTEM.         449 

two  causes,  both  the  decomposition  of  carbide  and  to  volatilization  of 
some  imparity  in  the  lime  or  carbon.  The  best  evidence  .that  the  car- 
bide does  not  break  up  at  1475'^  and  does  break  up  at  1525°  is  that 
equilibrium  could  be  measured  at  the  former  but  not  at  the  latter 
temperature.  Attention  was  called  to  the  possibility  of  lime  itself 
being  somewhat  volatile  at  1500°,  since  a  piece  of  Merk's  lime  heated 
at  the  melting  point  of  platinum  for  an  hour  also  produced  a  layer  of 
white  powder  on  the  walls  of  the  furnace. 

As  Experiments  1  and  2  were  carried  out  at  temperatures  equally 
above  and  below  the  temperature  in  experiments  6  and  7,  the  average 
of  these  four  may  be  taken,  with  the  result 

p^  at  1475°C.  =  0.82  ±  .02  mm. 

Through  these  results  were  obtained  from  the  same  side  of  the  equilib- 
rium, different  amounts  of  carbon  monoxide  were  present  at  the 
beginning  in  each  case,  which  makes  the  evidence  that  equilibrium  had 
been  reached  conclusive. 

From  this  result,  the  pressure  obtained  in  Experiment  8  at  a  tem- 
perature 30°  lower  may  be  checked  by  the  integrated  van't  Hoff 
equation : 


4.i 


where  pt  and  pi  and  the  pressures  of  carbon  monoxide  corresponding 
to  the  absolute  temperatures  7i  and  Tt  and  Q  is  the  heat  absorbed  by 
the  reaction,  when  it  proceeds  from  left  to  right.  Q  has  been  calcu- 
lated 1*  to  be  121000  calories  at  room  temperature,  with  a  negative 
temperature  coefficient  of  3.3  calories  per  degree. 
Therefore  Q  =  121000  —  3.3  t, 

where  t  equals  centigrade  degrees  above  room  temperature,  which  for 
high  temperatures  may  be  considered  as  degrees  above  zero.  For 
1460°  C.  Q  therefore  equals  116000  calories.  Substituting  in  the 
above  equation  the  absolute  temperatures  corresponding  to  1475° 

and  1445°,  the  value  of  —  comes  out  1.79.    The  ratio  between  the 

pressures  found  by  experiment  is  1.86,  which  is  very  satis&ctory 
agreement 

If  the  pressure  at  1270°  is  calculated  from  that  at  1475°,  using  the 
value  of  Q  corresponding  to  the  mean  temperature  1370°,  the  result  is 

"  Trans.  Am.  Electrochem.  Soc.,  1909,  16,  197. 
VOL.  XLV. — 29 


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450 


PROCEEDINGS    OF   THE    AMERICAN    ACADEMY. 


0.0093  millimeter,  that  is,  it  is  below  a  measurable  quantity.  The 
fact  that  in  one  case  0.13  and  in  another  0.3  millimeters  were  found 
'  is  due  to  the  insufficient  time  allowed  to  absorb  this  very  small  amount 
of  carbon  monoxide. 

From  the  value  of  the  equilibrium  pressure  obtained  at  1475°  it  is 
possible  by  the  above  formula  to  calculate  the  pressure  at  higher  tem- 
peratures and  see  approximately  what  is  the  shape  of  the  pressure  tem- 
perature curve.  The  value  of  Q  corresponding  to  the  mean  of  each 
set  of  temperatures  is  used.  1475"^  is  always  taken  as  thb  lower  temper- 
ature. The  results  of  this  computation  are  given  in  Table  IV  and 
Figure  3. 

TABLE  V. 

Pressures  of  Carbon  Monoxide  Computed  from  the  Value 
Determined  at  1475°. 


Temperature 
Degrees  Centigrade. 

Equilibrium  Pressure  of  Carbon  Monoxide  in 
Centimeters. 

I 
Lower  Limit. 

II 
Mean. 

III 
Upper  Limit. 

1475 
1575 
1675 
1775 
1875 
1975 

0.05 
0.31 
1.54 
6.6 

25.0 

81. 

0.08 
0.50 
2.53 
10.7 
40.5 
133.0 

0.13 
0.79 
4.00 
17. 
64. 
210. 

It  is  evident  that  the  error  in  this  curve  is  due  practically  entirely 
to  the  error  in  the  temperature  measurements,  for  while  the  value  of 
Pi  is  accurate  to  2.5  per  cent,  the  temperature  is  uncertain  by  25**,  and 
the  value  0.82  millimeters  might  correspond  to  1500°  or  1450°  as  the 
two  extremes.  This  would  mean  the  true  value  at  1475°  might  be 
1.3  or  0.5  millimeters  as  the  two  extremes.  If  now  the  curve  be  com- 
puted first  with  the  value  1.3  in  place  of  0.82,  and  again  with  0.5,  the 
values  under  I  and  III  in  Table  V  are  obtained.  The  values  are  plotted 
in  Figure  3  in  broken  curves.  From  these  curves  it  is  seen  the  tem- 
perature corresponding  to  1/3  of  an  atmosphere  lies  between  1800°  and 


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THOMPSON.  —  ON   THE    EQUIIJBRIUM    OF    THE    SYSTEM. 


451 


1875°,  with  which  Rudolphi's  values  agrees  the  best  of  all  the  three 
referred  to  in  the  Introduction. 


140 

t 

/ 

120- 

/ 

i 

100 

/ 

/ 

•!•. 

80 

/ 

1 

+ 
/ 

/ 

/ 

60 

// 

/ 

/ 

/ 

/ 
/ 

40 

t 

1 

/, 

/ 
1 

/ 

'a 

/ 

20 

y 

^y. 

9 

^ 

y^ 

:>- 

1400 


1500 


1600 


1700    1800 
Temperature 


1900 


2000 


Figure  3.  Pressure  of  Carbon  Monoxide  Computed  from  the  Value  Deter- 
mined at  1475°  C. 

The  free  energy  increase  of  the  reaction  taken  from  left  to  right  at 
1475^  C.  is 

'^= *'■'<«  s 

=  4.57  X  1748  logio  927 
=  +  23700  calories 

As  the  temperature  rises  A  i^  decreases  till  at  1920°,  where  the  equi- 
librium pressure  equals  an  atmosphere,  A  i^=  0.  Above  1920°  A  F 
becomes  negative. 


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452  PROCEEDINGS   OF   THE    AMERICAN    ACADEMY. 

Summary  of  RESULTa 

1.  The  equilibrium  pressure  of  carbon  monoxide  in  the  reaction 

CaO  H-  3  C  rt  CaC,  X  CO 

was  measured  at  1475^  and  1445^.    The  results  were  in  good  thermo- 
dynamic agreement 

2.  A  little  below  1445°  C.  the  pressure  hecomes  too  small  to  meas- 
ure; a  little  above  1475'^  decomposition  of  calcium  carbide  into  its 
elements  prevents  measurement  of  equilibrium. 

3.  With  the  aid  of  the  heat  of  the  reaction  the  vapor  pressure  curve 
at  higher  temperatures  was  computed  which  cannot  be  realized  experi- 
mentally on  account  of  the  decomposition  of  calcium  carbida 

4.  The  free  energy  increases-  of  the  reaction 

CaO  +  3C  =  CaC2  +  CO^ 

at  1475°  is  +23700  calories. 

Electrochemical  Laboratory,  Rogers  Laboratory  op  Physics, 
Massachusetts  Institute  op  Technoloqy,  -  . 

Boston,  Mass. 


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Proceedings  of  fhe  ^mfp^^^  Academy  of  Arti  and  Sdencea. 
Vol.  XLV.  No.  19.  — May,  1910. 


CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 


DISCHARGES  OF  ELECTRICITY   THROUGH 
HYDROGEN. 


Bt  John  Trowbridge. 


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CONTRIBUTIONS  FROM  THE  JEFFERSON  PHYSICAL 
LABORATORY,  HARVARD  UNIVERSITY. 

DISCHARGES  OF  ELECTRICITY  THROUGH  HYDROGEN. 

Bt  John  Trowbridge. 

Presented  December  8, 1909.    Received  Febmaiy  24, 1910. 

1.  Reflection  of  cathode  rays 466 

2.  Striae        456 

3.  The  Doppler  effect 462 

4.  Conclusions        462 

1.  Reflection  op  Cathode  Rays. 

In  the  course  of  this  paper  I  shall  refer  to  certain  hydrodjmamical 
analogies  which  the  discharges  of  electricity  through  gases  present ; 
not  with  the  conviction  that  in  these  discharges  we  have  to  deal  with 
questions  of  flow  alone.  The  complicated  phenomena  give  large  scope 
both  to  theories  of  flow  and  molecular  theories:  the  hydrodjmami- 
cal  analogies  are  more  striking  in  discharges  through  gases  at  com- 
paratively high  pressures; 
while  molecular  theories 
apply  best  in  highly  rare- 
fied gases.  There  seems 
.to  be  a  certain  continuity 
here  similar*  to  that  be- 
tween motions  of  matter 
in  the  liquid  state  and  in  Figure  1. 

the  gaseous  state,  when 

such  matter  is  subjected  to  forces  which  ca^  produce  movement  or 
flow  of  the  particles. 

The  conditions  of  electrical  discharges  in  a  tube  represented  in  Fig- 
ure 1  remind  one  of  the  flow  of  a  fluid  interrupted  by  a  plane  lamina. 
A  is  a  cathode,  K  an  anode,  D  a  diaphragm,  P  a  plsine  lamina  which 
can  be  moved  about  an  axis  perpendicular  to  the  plane  of  the  paper; 
Figure  1  being  a  plan  of  the  discharge  tube.  P  can  also  serve  as  an 
anode. 

At  the  stri8B  stage  the  electrical  conditions  in  the  tube  are  very 
little  modified  by  turning  the  lamina  tlirough  small  inclinations  to  the 


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456 


PROCEEDINGS  OF  THE  AMERICAN   ACADEMY. 


line  of  discharge.  The  striae  remain  practically  unaffected  in  shape 
and  position  until  the  angle  between  the  normal  to  the  lamina  and  the 
axis  of  flow  reaches  50^.  This  phenomenon  is  analogous  to  the  case 
of  a  lamina  subjected  tp  the  flow  of  a  liquid  (Lamb's  Hydrodjmamics, 
pages  94  and  111).  It  is  also  analogous  to  the  conditions  presented 
by  the  impact  of  wind  on  vanes. 

By  means  of  a  side  adjunct  a  thermo  pile,  T,  was  introduced  in 
order  to  measure  the  heat  excited  by  the  reflection  of  the  cathode 
rays  passing  through  the  diaphragm  D  and  reflected  from  the  lamina, 


Figure  2. 

when  the  latter  was  inclined  to  the  axis  of  the  cathode  rays  at  yar3nng 
angles.  Here  also  there  was  an  action  similar  to  the  reflection  of  a 
stream  of  liquid  from  the  lamina,  proceeding  in  the  direction  of  the  cath- 
ode rays.  The  angle  between  the  normal  to  the  lamina  and  the  axis 
of  flow  or  discharge  could  vary  largely  without  affecting  the  amount 
of  heat  from  the  reflected  cathode  beam  shown  by  the  thermopile. 

2.   Stbi^ 

The  striae,  or  stratifications,  in  Geissler  tubes  constitute  a  very  beau- 
tiful and  mysterious  phenomenon  of  the  discharge  of  electricity 
through  gases,  and  if  one  could  follow  the  mechanism  involvbd  per- 
fectly one  could  feel  sure  of  having  penetrated  far  into  questions  of 
the  method  of  propagation  of  electricity.  There  seems  no  reason  to 
doubt  that  the  strise  are  phenomena  of  ionization ;  but  the  regularity 


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TROWBRIDGE.  —  DISCHARGES   OF  ELECTRICITY. 


457 


c 


3 


of  the  striae  leads  one  to  ask  if  this  regularity  coold  arise  from  some  pul- 
sation or  rhythmical  action,  —  the  ionization  being,  so  to  speak,  on  top 
of  such  a  rhythmical  action.  When  the  strise  are  excited  by  a  storage 
battery,  they  are  perfectly  steady,  and  when  one  is  sure  that  there  are 
no  breaks  in  the  circuity  a  telephone  introduced  into  the  circuit  is 
silent ;  moreover,  self-induction  included  in  the  circuit  does  not  affect 
the  stnsB. 

Under  certain  conditions 
the  current  from  a  storage 
battery  oscillates  or  pul- 
sates, but  such  oscillations 
or  pulsations  do  not  seem 
to  modify  the  appearance 
of  the  stratifications.  If,  on 
the  other  hand,  there  is  a 
flow  from  the  cathode  which 
pulsates  at  a  different  rate  from  a  supposititious  flow  from  the  anode, 
one  might  expect  striae,  or  accumulation  of  ionic  disturbances  at  regular 
intervals.  An  hydrodjmamical  analogy  is  afforded  by  the  motion  of 
two  pistons  moving  against  each  other  at  different  rates  in  a  channel 
filled  with  water. 

Figure  2  represents  an  apparatus  by  means  of  which  two  pistons 
driven  in  opposite  directions  by  a  motor  cause  waves  in  a  trough 
filled  with  water. 


Figure  3. 


9sm 


Figure  4. 

Figure  3  shows  the  arrangement,  in  plan,  by  means  of  which  the 
ripples  are  studied.  M  is  a  mercury  lamp  of  the  Cooper  Hewitt  form. 
This  is  placed  directly  behind  the  ^ugh  containing  the  pistons.  The 
sur&ce  of  the  water,  totally  reflecting  the  light,  forms  a  dark  line  which 
under  the  motion  of  the  pistons  undulates  in  waves,  which  can  be  stud- 
ied by  instantaneous  photography.  P  and  V  are  the  pistons,  and  D  is 
a  diaphragm  with  a  rectangular  orifice.  Figure  4  represents  a  case  in 
which  P  moves  twice  as  fast  as  V.  The  waves  are  formed  nearer  the 
slower-moving  piston. 

All  who  have  worked  in  the  field  of  discharge  of  electricity  through 
gases  must  recognize  the  suggestiveness  of  the  theory  of  ionization  by 
collision,  especially  in  reference  to  strise ;  but  one  who  was  ignorant 
of  this  theory,  in  seeing  the  action  of  the  cathode  rays  in  apparently 


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458 


PBOCEEDINOS  OF  THE  AHEBICAN  ACADEMY. 


rt^ 


A' 


driviDg  ihe  striaB  into  the  anode,  might  attribute  this  action  to  an 
actual  repelling  force  arising  from  the  cathoda  When  this  suppositi- 
tioos  force  is  diverted  by  a  magnet,  the  strisB  reappear  and 
more  current  flows.  One  ignorant,  too,  of  the  many  fiEusts  of 
ionization  by  collision  might  fiirther  suppose  that  heavier 
'  particles  of  slower  motion  might  be  held  back  by  swiffcer 
particles  issuing  iroip  the  cathoda  These  views  of  a  mind 
not  biased  by  ionization  theories  would  appear  to  be  sup- 
ported by  the  phenomena  presented  by  the  tube  represented 
in  Figure  5. 

One  branch  of  this  tube  is  at  right  angles  to  the  other 
brancL  There  are  two  anodes, 
A  and  A',  and  two  perforated 
cathodes,  K  and  E^  When  a 
multiple  circuit  is  formed  by 
leading  in  the  current  to  the 
two  anodes  and  out  by  one 
cathode,  K,  strise  form  in  the 
the  branch  AE;  and  they 


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FiGUHE   5. 


branch  A'E'  after  they  disappear  in 
persist  in  the  branch  A'E'  when  the 
branch  AE  appears  to  be  nearly  at  the 
X-Ray  staga  One  looking  at  the  branch 
A'E'  would  suppose  that  the  rarefication 
of  the  entire  tube  was  low,  and  gazing  at 
the  branch  AE  would  think  it  very  high. 
The  bend  in  the  tube  acts  like  a  magnet 
in  allowing  the  strise  to  emerge  from  the 
anode  A' ;  and  it  does  this  by  enfeebling 
by  reflection  the  efiect  of  the  cathode  rays 
in  the  branch  A'E'. 

The  function  of  the  cathode  beam  seems 
to  be  twofold :  it  forces  back  the  striae, 
and  at  higher  exhaustions  it  ionizes  the 
gas ;  for  the  current  ceases  to  flow  at  high 
exhaustions  when  the  cathode  beam  is 
\r^    T""^  strongly  diverted  by  a  magnet    These 

^**T-^^^  fiinctions  are  illustrated  by  the  phenom- 

ena in  a  tube  represented  in  Figure  6. 
Between  the  anode  A  and  a  cathode  D 
the  glass  tube  is  constricted.  The  cathode  D  is  a  circular  disc  with 
an  orifice  a  little  larger  than  the  glass  orifice.  The  cathode  rests  upon 
the  ground  walls  of  this  orifice,  presenting  no  metallic  surface  toward  the 
anode  A.    The  cathode  beam  produces  an  orange  fluorescence  toward 


Figure  6. 


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459 


D',  and  is  marked  in  the  direction  toward  A  by  a  white  beam  which 
produces  hardly  a  perceptible  fluorescence.  The  latter  beam  does  not 
come  from  the  metallic  sur&ce  of  the  cathode,  but  seems  to  come 
from  the  gas  in  the  region  DD'.  At  comparatively  high  exhaustions 
this  latter  portion  of  the  cathode  beam  ceases  to  ionize  the  gas  and 
the  current  ceases ;  the  potential  between  A  and  D  rises  to  the  full 
potential  of  the  battery  —  indicating  an  open  circuit  When,  how- 
ever, jy  is  made  the  cathode,  the  current  is  immediately  re-estab- 
lished and  the  cathode  beam  from  JY  ionizes  the  gas  between  D'  and 
A.  The  tube  acts  as  a  rectifier ;  for  when  D  is  made  the  anode  and  A 
the  cathode,  a  current 
passes;  on  reversal  of 
the  current,  when  at  the 
same  exhaustion,  no  cur; 
rent  passes  in  the  op- 
posite direction. 

It  is  interesting  to 
observe  the  effect  of 
a  transverse  magnetic 
field  on  the  discharge 
in  this  tube  when  A  is 
made  a  cathode  and  J) 
an  anode,  and  strisa  ap- 
pear in  the  portion  DD'. 
The  magnetic  field 
placed  near  A  diverts  the  cathode  beam  and  striae  advance  in  the 
portion  DD^  While  this  field  is  still  on,  another  transverse  mag- 
netic field  placed  near  D'  diverts  the  strise  independently  of  the  action 
of  the  field  at  A.  This  indicates  the  well  known  fall  of  potential 
firom  strisB  to  striae. 

The  rectification  observed  under  proper  conditions  in  the  tube  (  Fig- 
ure 6  )  suggests  other  forms  of  tubes  by  which  rectification  can  be  pro- 
duced. •  Even  with  a  straight  cylindrical  tube  the  current  can  be  stopped 
at  high  exhaustions  by  touching  the  outside  of  the  tube  with  the  fin- 
ger, thus  diverting  the  cathode  beam  by  electrostatic  action ;  while  it 
readily  passes  when  the  current  is  reversed.  The  phenomenon  of  rec- 
tification is  shown  in  a  practical  way  in  the  U-shaped  tube  represented 
in  Figure  7.  It  is  provided  with  two  anodes,  A  and  A',  and  two  cath- 
odes, D  and  D.^  The  cathodes  have  orifices  at. their  centres,  l^e 
two  anodes  are  connected  together,  and  the  two  cathodes  —  the  tube 
forming  a  multiple  circuit  A  transverse  magnetic  field  can  be  so 
placed  near  one  cathode  that  no  current  will  pass  in  the  branch  of  the 


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460 


PROCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 


tube  of  which  it  is  a  part,  while  the  current  passes  freely  in  the  other 
branch  of  the  U  tuba  This  form  of  tube  rectifies  an  alternating 
current 

The  apparent  repelling  or  driving  back  action  of  the  cathode  beam 
on  BtriaB  is  shown  in  a  suggestive  manner  in  a  straight  cylindrical  tube 
when  a  diaphragm  is  inserted  between  the  anode  and  the  cathoda 
We  will  take  for  illustration  one  branch  of  the  U-shaped  tube  (Figure 


Figure  8. 

7),  and  suppose  that  the  current  is  led  into  the  tube  at  A  and  out  at  D. 
A  metallic  diaphragm  with  a  small  hole  at  its  centre  is  inserted  in  the 
tube  about  one  third  of  the  distance  beween  A  and  D,  measured  from 
the  anode  A — the  latter  also  having  an  orifice  at  its  centre.  The 
striae  are  slowly  driven  back  by  the  cathode  rays  as  the  exhaustion 
proceeds.  At  a  definite  stage  of  this  exhaustion  a  stria  takes  refrige 
behind  the  diaphragm  nearer  the  anode,  where  it  is  protected  from 
the  driving  back  action  of  the  cathode  rays ;  finally  at  higher  exhaus- 
tions this  stria  is  driven  through  the  orifice  in  the  anode  and  shelters 
itself  behind  the  anoda 


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TROWBRIDGE. — DISCHARGES   OF    ELECTMCITY.  461 

At  a  still  higher  state  of  larefisM^ion  a  stria  issues  from  the  orifioe  in 
the  anode,  and  this  also  shelters  itself  behind  the  diaphragm  on  the 
side  toward  the  anode.  There  are,  thus,  three  definite  stages  of  strati- 
fication in  this  form  of  tuba  At  a  pressure  of  four  centimetres  fine 
strise  appear  on  the  side  of  the  orifice  in  the  diaphragm  opposite  to  the 
anode.  These  soon  disappear  with  increasing  rare&ction.  At  a  pres- 
sure of  approximately  3  mm.  a  large  stria  shelters  itself  behind  the 
diaphragm.  This  &des  into  the  orifice  in  the  anode  with  diminishing 
pressure ;  and  at  a  pressure  of  approximately  .15  mm.  a  large  stria 
weUs  up  out  of  the  orifice  in  the  anode  and  taJces  a  similiar  place  near 
the  diaphragm.  When  the  state  of  canalstrahlen  is  reached,  all  striae 
have  been  driven  into  the  anoda  Can  we  regard  these  strahlen  as  a 
stratification  which  cannot  be  driven  back  by  the  cathode  rays  ?  In  this 
form  of  tube  we  find  evidence  of  successive  states  of  stratification  which 
may  depend  upon  positive  rays  of  difierent  velocity. 

When  we  turn  from  our  observation  of  stratification  in  the  neighbor- 
hood of  the  cathode  instead  of  in  the  neighborhood  of  the  anode,  we 
find  that  a  stratification  always  takes  place  on  the  glass  wall  close  to 
the  entrance  of  the  cathode,  or  to  its  sealing  in  placa  It  can  be  pro* 
duced  equally  well  by  causing  the  cathode  to  approach  the  wall  of 
the  tube  opposite  to  this  sealing  in  place.  Figure  8  represents  the 
phenomenon  in  a  tube  with  a  dome-shaped  chamber  near  the  electroda 
We  seem  to  have  two  dissected  strise :  one  on  the  wall  of  the  tube 
nearest  to  the  cathode,  which  provides  a  beautiful  light  blue  cathode 
beam  thrown  into  the  dome ;  and  another  stria  on  the  opposite  wall  of 
the  dome.  The  original  cathode  beam  excites  both  positive  and  nega- 
tive rays  in  these  striae*  In  considering  these  detached  strise  it  seems 
that  the  cathode  rajrs  in  striking  the  glass  walls  can  excite  both  posi- 
tive and  cathode  rays. 

When  a  spark  gap  is  inserted  in  a  circuit  containing  a  discharge 
tube  which  is  properly  exhausted  to  the  strise  stage,  the  latter  appar- 
ently disappear — the  light  of  the  tube  becomes  more  brilliant  and 
fluorescence  is  generally  manifested.  This  is  also  the  case  when  a  con- 
denser is  discharged  through  the  tuba  The  eye  cannot  perceive  any 
evidence  of  stratifications ;  for  the  brightness  of  the  pilot  spark,  to- 
gether with  the  fluorescence  both  of  the  gas  and  of  the  glass  walls  effect- 
ually shield  any  strise  of  lesser  radiance  which  might  be  present  It 
is  not  possible  to  employ  a  revolving  mirror.  The  only  method  which 
seemed  to  promise  any  results  in  detection  of  possible  stratifications 
was  the  emplo3rment  of  a  portrait  lens  of  large  aperture  —  four  inches 
— in  photographing  single  discharges.  Accordingly  a  discharge  tube 
was  filled  with  hydrogen  and  exhausted  to  the  strise  ^t^a    A  .con- 


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462  PROCEEDINGS   OF   THE   AMERICAN   ACADEBfT. 

denser  of  .02  m  f  capacity  was  charged  to  a  difference  of  potential  of 
100.000  volts  and  discharged  through  the  rarefied  tuhe  by  flat  oopper 
bands  of  inappreciable  self-induction.  The  photographs  showed  un- 
mistakable striae,  superposed  upon  the  general  illumination  of  the 
tube.    It  is  difficult  to  reproduce  the  photographs  by  half  tones. 

With  an  anode  consisting  of  a  ring  of  wire  placed  in  a  cylindrical 
tube  .5  mm.  internal  diameter,  a  striation  is  formed  at  a  short  distance 
from  the  anode  by  condenser  discharges,  and  there  are  traces  of 
similar  striations  at  greater  distances  along  the  tuba  If  these  stria- 
tions  are  formed  by  ionization  by  collision,  the  time  of  ionization  is 
that  of  the  duration  of  the  pilot  spark,  a  time  which  at  present  is 
beyond  our  power  of  measurement. 

3.  DoppLER  Effect. 

When  two  anodes  and  two  cathodes  are  employed  in  the  form  of 
tube  represented  in  Figure  7,  there  are  two  canalstrahlen  which  ema- 
nate from  orifices  in  the  cathodes  in  opposite  directions.  One  might 
suppose  that  the  Doppler  effect  would  be  modified  by  collision  of 
the  particles  in  these  rays  and  that  the  effect  would  certainly  be  less 
than  when  only  one  anode  and  one  cathode  were  employed  —  the  cut- 
rent  thus  passing  through  but  one  branch  of  the  U  tuba  It  is  true 
that  the  difference  of  potential  is  less  between  A  and  D  when  the 
tube  is  coupled  in  multiple  circuit  than  when  only  one  branch  of  the 
tube  is  connected  to  the  battery;  but  this  difference  in  the  case  I 
studied  was  comparatively  small.  With  both  branches  of  the  tube 
constituting  a  multiple  circuit  there  were  two  strong  canalstrahlen 
passing  through  the  orifices  in  D  which  were  undistorted  and  which 
gave  the  same  Doppler  effect  which  was  obtained  when  only  one 
branch  of  tube  was  excited ;  it  seems  difficult  to  reconcile  this  result 
with  any  theory  of  collision. 

4.  Conclusions. 

1.  The  striae  in  Geissler  tubes  are  analogous  to  waves  set  up  in 
narrow  channels  by  opposing  pulsations  of  different  periods. 

2.  Striae  are  greatly  influenced  by  the  direction  of  cathode  rays. 
Certain  forms  of  tubes,  described  in  this  article,  can  imitate  the  action 
of  a  transverse  magnetic  field  in  apparently  increasing  the  conducti- 
bility  of  the  rarefied  gas  and  restoring  the  condition  of  stratification. 

3.  Strise  can  be  formed  by  condenser  discharges;  and  such  striae 
l§|a4  one  to  suppose  a  time  of  ionization  beyond  our  power  of  measure- 


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TROWBRIDGE.  —  DISCHARGES  OF  ELECTRICITY.  463 

ment    By  means  of  a  suitably  placed  diaphragm  suooessive  stages  in 
stratification  can  be  produced. 

4.  By  modification  of  the  form  of  discharge  tubes  rectification  of 
alternating  discharges  is  possible 

5.  The  Doppler  effect  in  hydrogen  is  not  modified  by  causing  two 
canalstrahlen  to  oppose  each  other. 

Jefferson  Physical  Laboratory,  Harvard 

University,  Cambridge,  Mass., 

December,  1909. 


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Proeeedingi  of  the  Ameriean  Academy  of  Arts  and  Sdenoes. 
Vol.  XLV.  No.  20.  —  Jijnb.  1910. 


BUDDHAGHOSA'S  DHAMMAPADA  COMMENTARY, 

and  the  Titles  of  iU  three  hundred  and  ten  Stories,  together  with 
an  Index  thereto  and  an  Analysis  of  Vaggas  I- IV. 


Bt  Eugene  Watson  Bubunoame, 
HARBisoif  Fbllow,  Unitsbbitt  or  Pbmnbtlvamia. 


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Goot 


BUDDHAGHOSA'S  DHAMMAPADA  COMMENTARY. 
By  Eugene  Watson  Buhlingame. 

Presented  by  Charles  R.  Lanman,  December  8,  1909.    Received  February  5,  1910. 

Prefatory  Remarks.  —  My  interest  in  Hindu  Folk-tales  was  first 
aroused  by  Professor  Morris  Jastrow,  Jr.,  of  the  University  of  Pennsyl- 
vania, who  introduced  me  to  the  famous  Arabian  classic  Kali  la  wa 
Dimna,  giving  me  generously  of  his  time,  and  granted  me  the  privilege 
of  collaborating  in  the  preparation  of  an  English  translation  of  the 
recently  published  Cheikho  recension  of  the  text.  Professor  Morton 
W.  Easton,  of  the  same  University,  to  whom  I  am  no  less  indebted  for 
valuable  assistance  in  my  work,  then  induced  me  to  make  a  serious 
study  of  the  corresponding  Sanskrit  collections,  Paficatantra  and 
Hitopade9a,  and  encouraged  me  to  prosecute  researches  in  the  closely 
related  Pali  collections.  When,  therefore,  Provost  Harrison  of  the 
University  of  Pennsylvania,  the  giver  of  the  Harrison  Foundation, 
granted  me  leave  of  absence  from  the  University  for  this  purpose,  I 
placed  myself  under  the  direction  of  Professor  Charles  R.  Lanman,  of 
Harvard  University.  It  was  at  his  suggestion  that  I  undertook  the 
task  upon  which,  under  his  most  wise  and  kindly  guidance,  I  am  at 
present  engaged,  that  of  translating  into  English  the  important  Bud- 
dhist work  entitled  Buddhaghosa*s  Commentary  on  the  Dhammapada.* 

Diviaiona  of  the  Buddhist  Texts.  —  In  order  to  give  the  reader 
a  clear  idea  of  the  relation  in  which  Buddhaghosa's  Dhammapada 
Commentary  stands  to  the  Buddhist  Canon,  it  will  be  necessary  to 
describe  briefly  the  principal  divisions  of  the  Buddhist  Scriptures, 
They  fall  into  three  principal  divisions  called  Pitakas  (Baskets)  ;  first, 
the  Sutta  Pitaka;  secondly,  the  Vinaya  Pitaka;  thirdly,  the  Abhi- 

*  Several  years  ago  my  attention  was  first  attracted  to  this  fascinating 
collection  of  stories  by  reading  a  brief  description  of  it  in  Professor  Rhys 
Davids's  American  Lectures  on  Buddhism.  The  passage  that  caught  my  eye 
occurs  on  page  69,  and  closes  as  follows  :  "  Cannot  some  one  undertake  a 
translation  for  us  into  English  of  these  strange  and  interesting  old-world 
stories  about  a  collection  of  verses  so  widely  popular  among  Buddhists,  and 
now  attracting  so  much  attention  in  the  West?"  Nevertheless,  it  is  due 
wholly  and  entirely  to  Professor  Lanman  that  I  am  able  to  answer  *'  Ye.s." 


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468  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

dhamma  Pitaka.  Speaking  broadly,  the  first  relates  to  Doctrine ;  the 
second,  to  Discipline;  the  third,  to  what  we  may  call  Psychology. 
The  first  two  Pitakas  alone  cpncem  us.  Each  of  the  Pitakas  £bJ1s  into 
several  sobdivisions.  The  Satta  Pitaka  consists  of  five  groups,  called 
Nik&yas;  namely.  Four  Nik&yas  the  Greater,  and  One  Nikaya  the 
Less.  The  first  four  Nikayas  are  called  the  Agamas,  and  are  as 
follows  :  (1)  Digha ;  (2)  Majjhima ;  (3)  Saqyntta ;  (4)  Anguttara.  The 
Digha  and  Majjhima  consist  of  Dialogues  of  die  Buddha,  arranged 
somewhat  after  the  manner  of  the  Dialogues  of  Plato ;  the  Saqyutta 
and  Anguttara  contain  sayings  of  the  Buddhc^  arranged  according  to 
subject  and  length  respectively.  These  four  Nikayas  are  the  oldest 
parts  of  the  Canon,  and  are  the  source  of  most  of  our  knowledge  of  the 
tenets  and  history  of  primitive  Buddhism.  The  Lesser  Nik&ya,  called 
the  Ehuddaka,  consists  of  fifteen  books,  grouped  in  three  pentads.  Of 
these  fifteen  books,  perhaps  the  most  &mous  are  the  Thera-  and  Then- 
gatha  (or  Hymns  of  the  Monks  and  Nuns),  the  Sutta  Nip&ta  (a  very 
old  collection  of  poetical  dialogues  and  epic  pieces),  the  Udsna  (or 
Solemn  Utterances  of  the  Buddha),  the  Jatakas,  and  the  Dhammapada. 
As  the  above-given  titles  indicate,  the  Lesser  Nikaya  is  a  miscella- 
neous, but  none  the  less  exceedingly  important,  collection.  It  is  not 
relevant  to  our  purpose  to  consider  the  subdivisions  of  the  Vinaya. 
Suffice  it  to  say  that  it  contains  a  number  of  highly  interesting  stories, 
designed  to  explain  the  circumstances  under  which  various  rules  and 
ceremonies  were  established. 

The  Dhammapada  and  its  Commentary. — The  Dhammapada,  then, 
is  one  of  fifteen  books  belonging  to  the  Ehuddaka  Nik&ya,  which  latter 
is  the  fifth  division  of  the  Sutta  Pitaka ;  and  the  Sutta  Pitaka  is  one 
of  the  three  major  divisions  of  the  Sacred  Scriptures  of  the  Buddhists. 
The  Dhammapada  is  an  anthology  of  about  423  stanzas  uttered  by  the 
Buddha  on  a  great  variety  of  religious  subjects.  Many  such  anthol- 
ogies were  current  in  the  early  ages  of  Buddhism,  and  so  great  was 
the  popularity  they  acquired  that  in  addition  to  the  anthology  included 
in  the  Buddhist  Canon  other  similar  collections  have  come  down  to  us. 
For  example,  in  1878,  Samuel  Beal  published  a  translation  of  a  Chinese 
Dhammapada ;  in  1898,  £mile  Senart  deciphered  and  published  part 
of  a  Eharosthi  Ms.  of  the  Dhammapada,  the  fruit  of  the  mission  of 
Dutreuil  de  Rhins ;  and  Richard  Pischel,  shortly  before  his  death, 
brought  out  specimens  of  a  Central  Asiatic  Dhammapada.  The  precise 
relation  between  the  Dhammapada  of  the  Buddhist  Canon  and  the 
other  collections  has  not  yet  been  determined ;  nor  is  it  important  for 
our  immediate  purpose.  It  is  sufficient  to  say  that  by  a  fortunate 
circumstance  one  of  these  anthologies  was  included  in  the  Buddhist 


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BUKLINGAME.  —  BUDDHAGHOSA's   DHAMMAPADA    CX)MBiENTARY.      469 

Canon.  This  Anthology  consists  of  twenty-six  parts,  or  books  (vaggas), 
the  arrangement  of  the  stanzas  being  by  subjects,  such  as  Heedfubess, 
The  Fool,  The  Wise  Man,  The  Baddha,  Pleasure,  Anger,  and  so  on. 
The  relation  between  the  Anthology  and  its  Commentary  will  at  once 
become  clear  from  an  example.  Suppose  we  had  a  collection  of  detached 
sajdngs  of  Christ ;  such  as,  for  example,  "  Labor  not  for  the  meat  which 
perisheth ;"  or,  "  He  that  is  without  sin  among  you,  let  him  first  cast 
a  stone  at  her."  The  Commentary  bears  much  the  same  relation  to 
the  Sacred  Stanzas  as  the  Gk>spel  narrative  to  the  Sacred  Sentences. 
The  parallel  is  not  a  perfect  one,  for  the  Commentary  does  not  rank  as 
canonical ;  besides  which,  there  are  certain  other  important  differences. 
The  Commentary  consists  of  upwards  of  three  hundred  stories  (vat- 
thus),  distributed  in  twenty-six  books  (vaggas),  corresponding  to  the 
parts  of  the  Dhammapada  described  above.  Ordinarily  each  story 
consists  of  eight  subdivisions,  as  follows :  (1)  quotation  of  the  stanza 
(gath&)  to  illustrate  which  the  Buddha  told  the  story;  (2)  a  brief 
statement  of  the  occasion  and  the  person  or  persons  about  whom  the 
story  was  told ;  (3)  the  story  proper ;  or,  more  strictly,  the  Story  of 
the  Present  (paccnppanna-vatthu),  closing  with  the  utterance  of 
(4)  the  stanza  or  stanzas ;  (5)  word-for-word  commentary  or  gloss  on 
the  stanza ;  (6)  a  brief  statement  of  the  spiritual  benefits  which  accrued 
to  the  hearer  or  hearers ;  (7)  the  Story  of  the  Past ;  or,  more  accu- 
rately, the  Story  of  Previous  Existences  (atlta-vatthu);  (8)  identification 
of  the  personages  of  the  Story  of  the  Past  with  those  of  the  Story  of  the 
Present  Sometimes  the  Story  of  the  Past  is  omitted,  together  with  the 
accompanying  Identification ;  but  it  is  so  much  expected  as  a  matter 
of  course,  that  at  the  end  of  the  story  of  Nanda  the  Herdsman  (iii.  8), 
whei'e  none  occurs,  the  author  is  at  some  pains  to  say  that,  as  no  one 
asked  the  Teacher  about  Nanda's  deed  in  a  previous  existence,  the 
Teacher  said  nothing  about  it  It  will  readily  be  seen  that  the  Dham- 
mapada Commentary  closely  resembles,  both  in  form  and  content^  the 
commentary  on  the  fiimous  J&taka  collection ;  indeed,  so  close  is  the 
connection  between  the  two  that  it  would  not  be  inappropriate  to  call 
the  Commentary  a  supplement  to  the  J&taka.  The  Commentary 
constantly  refers  to  the  J&taka,  every  now  and  then  borrows  a  story 
from  it^  sometimes  showing  interesting  variants,  and  as  often  gives  a 
different  version  of  some  fiimiliar  J&taka  story.  The  stories  of  the 
Dhammapada  Commentary  stand  in  precisely  the  same  relation  to 
the  stanzas  of  the  Dhammapada  as  the  J&taka  stories  do  to  the  J&taka 
stanzas.  The  Dhammapada  Commentary  has  sometimes  been  referred 
to  as  a  sort  of  Buddhist  Acta  Sanctorum ;  it  would  perhaps  be  more 
appropriate  to  speak  of  it  as  a  Collection  of  Stories  about  Buddhist 


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470  PROCEEDINGS   OF  THE   AMERICAN   ACADEMY. 

Saints  and  Sinners,  designed  to  illastiate  the  maxim,  ''  Whatsoeyer  a 
man  soweth,  that  shall  he  also  reap." 

Bditioiis  of  the  Dhammapada  Commentary.  —  In  1855,  extracts 
from  the  Commentary  were  published  by  FaasboU  in  his  edition  of  the 
Dhammapada.  The  seoond  edition  of  this  work,  published  in  1900,  con- 
tains only  the  text  and  translation  of  the  Dhammapada.  In  1906-9 
appeared  the  first  two  instahnents  of  the  F&li  Text  Society  edition 
of  the  Commentary,  edited  by  Professor  H.  C  Norman  of  Benares. 
These  two  parts  together  make  up  Volume  I,  and  contain  the  first 
four  vaggas.  Since  the  publication  of  FausboU's  first  edition  of  the 
Dhammapada,  editions  of  the  Commentary,  in  whole  or  in  part»  printed 
in  Burmese  or  Cingalese  letters,  have  appeared;  and  at  present  H. 
R.  H.  Frince  Vajira-fi&na  is  engaged  in  publishing  an  editioh  of  the 
work  at  Bangkok.  The  editions  which  form  the  basis  of  my  work  are 
as  follows :  (1)  Fali  Text  Society,  Vol.  I,  Farte  1-2,  London,  1906-9 ;  (2) 
Burmese,  edited  by  IT  Yan,  Rangoon,  1903 ;  (3)  Cingalese,  edited  by 
W.  Dhammdnanda  Mah&  Thera  and  M.  Ndnissara  Thens  Colombo, 
1898-1908. 

Translations  of  parts  of  the  Commentary.  —  Only  a  few  of  the 
stories  have  ever  been  translated  into  any  European  language.  Such 
of  the  Jfttaka  stories  as  are  identical  with  stories  contained  in  the 
Commentary,  or  similar  to  them,  will  be  found  in  the  Cambridge  trans- 
lation of  the  Jfttaka.  An  English  version  of  three  of  the  stories  will 
be  found  in  Warren's  Buddhism  in  Translations:  Fatipujikft  (iv.  4), 
pp.  264-7 ;  Visakha  (iv.  8),  pp.  451-481 ;  Godhika  (iv.  11),  pp. 
380-3.  Four  more  stories  were  translated  into  French  by  Godefroy  de 
Blonay  and  Louis  de  la  Vall^  Foussin  under  the  title  Contes  Bond- 
dhiques,  and  were  published  in  the  Revue  de  Y  Histoire  des  Religions* 
Volume  xxvi  (1892)  contains  two  of  these  stories  :  Cakkhupala  (i.  1), 
pp.  180-193 ;  and  Matthakundall  (i.  2),  pp.  193-200 ;  Volume  xxix 
(1894),  the  two  others :  Kosambika  bhikkhu  (i.  5),  pp.  329-337 ; 
Vidudabha  (iv.  3),  pp.  195-211.  In  1870,  Captain  T.  Rogers  pub- 
lished, under  the  title  Buddhaghosha's  Farables,  an  English  translation 
of  a  late  Burmese  version  of  a  few  of  the  stories.  References  to  the 
Jatakas  and  to  Rogers's  Farables  are  given  in  the  Analysis. 

Purpose  of  thia  paper.  —  The  purpose  of  this  paper  is  two-fold 
First,  it  b  hoped,  by  means  of  a  Table  giving  the  titles  of  the  stories, 
and  by  an  Alphabetic  Index  to  those  titles,  to  render  the  work  in  its 
entirety  more  accessible  to  scholars.  In  particular,  it  is  hoped  that 
the  proper  names  of  eminent  Buddhists  and  the  information  about 
them  may  prove  of  special  value  as  material  for  the  Buddhist 
onomasticon  of  Frofessor  Rhys  Davids.    That  the  contents  of  the  last 


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BUKUNGAME.  —  BUDDHAGHOSA's   DHABfMAPADA   COMMENTARY.       471 

two  thirds  of  the  Commentary  are  virtoally  almost  ioacoessible  to 
Oocidental  students  is  a  &ct  that  deserves  especial  emphasis  as  an 
ample  jastification  of  the  present  paper.  Norman's  edition  of  the 
first  third  is  of  coarse  easily  had ;  bat  it  may  well  be  doobted  whether 
there  are  more  than  two  or  three  copies  of  the  Cingalese  edition  in  the 
western  hemisphere,  or  more  than  one  copy  of  the  Burmese.  And 
there  is  probably  not  one  bookseller  in  the  United  States  who  would 
even  attempt  to  procure  directly  such  rare  exotics.  And  even  if  a 
considerable  number  of  copies  were  to  be  found  in  the  great  libraries 
of  America,  it  is  still  true  that  the  Burmese  and  Cingalese  letters  are 
so  troublesome  that  very  few  Occidentals,  even  among  the  students 
of  Fftli,  have  learned  to  read  these  native  editions  with  facility. 
Secondly,  it  is  hoped,  by  means  of  an  Analysis  of  the  first  third  of 
the  work,  to  afford  some  idea  of  its  structure,  contents,  and  style,  not 
only  to  professed  students  of  Sanskrit  and  Fftli,  but  also  to  students 
of  Comparative  Literature,  and  to  tiie  general  reader  as  well 

In  case  the  paper  shall  subserve,  to  however  small  a  degree,  the 
purpose  for  which  it  is  intended,  a  large  share  of  the  credit  belongs, 
not  to  me,  but  to  my  firiend  and  teacher.  Professor  Lanman,  who,  in 
the  midst  of  pressing  duties,  has  given  me  unreservedly  of  his  time 
and  labor,  and  has  assisted  me  in  countless  wajrs.  I  wish  to  thank 
him  most  heartily  for  his  many  kindnesses  to  me  during  the  progress 
of  my  work. 

Note  on  the  Table  of  Contents  and  Alphabetical  Index.  —  Unfor- 
tunately, FausboU  has  numbered  the  stanzas  of  the  Dhammapada  from 
the  beginning  continuously ;  and  this  bad  example  has  been  followed 
by  the  Burmese  edition;  and,  to  make  a  bad  matter  worse,  its 
numeration  (firom  163  to  208,  and  from  416  to  424)  disagrees  with 
that  of  FausbolL  The  Cingalese  edition  does  not  number  the  gd^th^s. 
In  the  following  table,  the  numbers  of  the  gftth&s  are  given  in  heavy 
type  and  in  square  brackets  immediately  after  the  title  of  the 
story  :  firsts  the  number  of  the  gftthft  as  counted  from  the  beginning 
of  its  vagga^;  second,  the  number  as  counted  continuously  from  the 
beginning.  If,  for  the  latter  numeration,  on  account  of  the  disagree- 
ment just  mentioned,  more  than  one  number  has  to  be  given,  or  if, 
on  account  of  variation  in  the  titles,  more  than  one  title  has  to  be 
given,  they  are  distinguished  by  a  prefixed  F  (meaning  FausboU),  or  B 
(meaning  Burmese),  or  C  (meaning  Cingalese).  The  stories  are 
numbered  from  the  beginning  of  each  book.    The  number  as  counted 

■  This  is  the  only  proper  method.  To  ignore  such  important  and  histori- 
cally significant  native  divisions  is  extremely  reprehensible  and  unpractical. 


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472  PROC£:£DINGS  OF  THE  AMERICAN  ACADEMY. 

oontinuously  from  the  beginning  to  the  end  of  the  work  is  ignored 
of  a  purpose  and  apon  principla  In  the  columns  at  the  right  are 
given  the  numbers  of  the  pages  on  which  the  stories  begin  (not  end). 
PTS  means  P&li  Text  Society,  B  Burmese,  G  Cingalese.  In  the 
Alphabetical  Index,  the  stories  are  cited  by  book  (vagga :  in  Roman 
numerals)  and  story  (vatthu :  in  Arabic).  Thus,  xiv.  3  means  the 
third  story  of  the  fourteenth  book.  Exponential  numbers  indicate 
imbedded  storiea    Thus,  in  ii.  1  are  imbedded  il  1%  1^  1®,  !<*,  1«,  1'. 

TITLES  OF  STORIES  OF  THE  DHAMMAPADA  CX)MMENTARY. 

Tamaka-vagga  —  Book  I. 

Btorj 

1.  Cakkhupala  thera  [1  -  1] 

2.  MaUhakundali  [2  »  2] 

3.  Tissa  thera  (B)  -  Thulla  Tissa  thera  (PTS  and  C) 

[3^-3-4] 

4.  Kali  yakkhini  [5  -  5] 
6.  Kosambika  bhikkhu  [6  -  6] 

6.  Cula  Kala  and  Maha  Kala  [7-8  -  7-8] 

7.  Devadatta  [9-10  -  9-10] 

8.  Aggaiavaka  (PTS  and  C)  -  SSriputta  thera  (B) 

[11-12-11-12] 
0.  Nanda  thera  [13-14  -  13-14] 

10.  Conda  sukarika  [15  -  15] 

11.  Dhammika  upaiaka  [16  - 16] 

12.  Devadatta  [17  -  17] 
18.  Sumana  devi  [18  »  18] 
14.  Dye  sahayaka  bhikkhu  [19-20  -  19-20] 


Appamftda-vagga  -  Book  n. 

Story 

k  Udena  (PTS  and  C)    Samarati  (B)  [1-3-21-23] 

1*  Udena-uppatti 

1*"  Ghosaka-eefthi-uppatti 

1*  Samavati-uppatti 

1**  Vasuladatta 

1*  MSgandiya 

1'  Marana-paridipaka 
2.  Kumbhaghosaka  setthi  [4  —  24] 
8.  Cula  Panthaka  thera  [5  -  25] 
4.  Bala-nakkhatta-ghuttha  [6-7  »  26-27] 
6.  Maha  Kassapa  thera  [8  -  28] 

6.  Dve  sahSyakS  bhikkhu  (PTS)  -  Pamatt-appamattft  dve 

sahayaka  bhikkhu  (B  and  C)  [9  -  29] 

7.  Mahali-pafiha  (PTS  and  C)  ->  Magha  (B)  [10  -  30] 

8.  AfifiaUra  bhikkhu  [11 «  31] 

9.  Nigamayasi  Tissa  thera  [12  »  32] 


PTS 

B   0 

8 

44   1 

26 

68  12 

]  87 

67  18 

45 

72  22 

68 

77  26 

66 

84  33 

77 

91  38 

83 

95  41 

115 

116  58 

125 

123  64 

129 

125  e» 

188 

128  68 

151 

189  77 

154 

141  78 

PT8 

B   C 

161 

145   81 

161 

145   81 

169 

150   85 

187 

162   95 

191 

166   97 

199 

170  101 

203 

178  108 

281 

190  116 

289 

195  120 

256 

206  128 

258 

207  180 

260 

208  181 

268 

210  182 

281 

221  140 

288 

222  141 

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BURUNGAME.  —  BUDDHAGHOSA's   DHAMMAPADA   COMMENTARY.      473 
Citta-vagga  -  Book  in. 

8tOT7 

1.  Meghiyathera  [1-2 -33-34] 

2.  AfillAtara  bhikkhu  [3  -  35] 

3.  Ukkan|hit«fiiiatara-bhikkhu(PT8andC)-Anfiatara 

ukkanthita  bhikkha  (B)  [4  -  36] 

4.  BhSginej7a-€afigharakkhita  thera  (PTS  and  C)  ->  Sangha- 

rakkhita-bhaginejya  thera  (B)  [5  —  37] 
6.  Clttahattha  thera  [6-7  -  38-39] 

6.  Palicasata  yipassaki  bhikkhu  (FTS  and  C)  -  Paficaiata 

bhikkhu  (B)  [8 -40] 

7.  PQtigatta  Tissa  thera  [9  -  41] 

8.  Nanda  gopSU  [10  -  42] 

9.  Soreyya  thera  [11-43] 

Puppha-vagga  -  Book  IV. 

Story 

1.  PathaW-kathS-pasutS  palicasata  bhikkhii  [1-2  -  44-5] 

2.  Marici-kammatthSnika  thera  [3  -  46] 

8.  Vidudabha  (PTS  and  C)  -  Vimfibha  (B)  [4  -  47] 
4.  PatipujikS  (PTS  and  C)  -  PSUpujiki  kumSriki  (B) 

[5-48] 
6.  Maccharija  Kosiya  setthi  [6  -  49] 

6.  Pi^hikSjlTaka  (PTS  and  C)  -  PSreyyakSjiTaka  (B) 

[7-50] 

7.  Chattapani  upSsaka  [8-9  -  51-^52] 
a  Vi»akha[i0-53] 

9.  2nanda-thera-paliha  [11-12 -54-55] 

10.  Maha-Kassapa-thera-pindapSta-dinna  [13  -  56] 

11.  Godhika-thera-parinibbSna  [14-57] 

12.  Garahadinna  [15-16  -  58-59] 

Bfila-TTagga  -  Book  V. 

Btory 

1.  Kumuduppal&tita-duggata-«eyaka  (C)  —  Afifiatara 

puri8a(B)[l-60] 

2.  MahS-Kasiapa-thera^addhiTihirika  [2  -  61] 

8.  Ananda  se^hi  [3  -  62] 
4.  Ganthi-bhedaka  cora  [4  -  63] 
6.  Udkyi  thera  [5  -  64] 

6.  Bhadda-yaggiyS(C)  -  Tugsa-matta-pSreyyaki  bhikkhii  (B) 

[6- 

7.  Suppabuddha  kutthi  [7  -  66] 

8.  Kassaka  [8-67] 

9.  Sumana  mala-kSra  [9  -  68] 

10.  UppalavannS  ther!  [10-69] 

11.  Jambukajivaka  (C)  -  Jambuka  thera  (B)  [U  -  70] 

12.  Ahipeta  [12-71] 

13.  Sa|0iikuta  peta  [13  -  72] 

14.  Sudhamma  thera  (C)  -  Citta  gahapaU  (B)  [14-15  -  73-4] 
16.  Vanayisi  TUsa  thera  (C)    V.  T.  iSmanera  (B)  [16  -  75] 

*  The  Colombo  edition  has  no  page  153. 


PTB 

B 

0 

287 

224 

143 

290 

226 

145 

297 

282 

149 

800 

243  151 » 

805 

236 

154 

818 

241 

158 

819 

245 

160 

822 

248 

162 

825 

249 

164 

PTB 

B 

0 

888 

254 

167 

835 

256 

168 

887 

257 

169 

862 

272 

181 

866 

274 

183 

376 

280 

187 

880 

288 

189 

884 

286 

191 

420 

308 

209 

423 

810 

210 

431 

815 

214 

434 

317 

216 

B 

0 

60] 

324 

221 

335 

230 

389 

233 

342 

235 

843 

285 

65] 

344 

236 

345 

237 

847 

288 

849 

240 

353 

243 

855 

245 

863 

251 

366 

258 

869 

256 

376 

261 

Digitized  by  VjOOQIC 


B 

0 

889 

271 

802 

273 

893 

274 

894 

276 

408 

281 

416 

291 

416 

292 

418 

294 

420 

296 

422 

296 

474  PROCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 


Pan<Uta-Tragga  -  Book  VI. 

story 

1.  RSdha  thera  [1  -  76]  • 

2.  Assaji-panabbasuka  [2  -  77] 
8.  Channa  thera  [3  »  78] 
4.  Mah&  Kappina  thera  [4  -*  79] 
6.  Pandita  samanera  [5  *»  80] 

6.  Lakuntaka-bhaddiya  thera  [6  -*  81] 

7.  Kana-'matS  [7  ->  82] 

8.  Vighasada  dosa-yutta  pafScasata  bhikkhu  (C)  ^  Paffcasata 

bhikkhu(B)  [8-83] 

9.  Dhammika  thera  [9  -  84] 

10.  Dhamma-eavana  [10-11  <-*  85-86] 

11.  Agantoka  paficasata  bhikkha  (C)  -*  PaBcasata  SgantukS 

bhikkhu  (B)  [12-14  «  87-^89]    423    297 

Arahanta-vagga  -  Book  VII. 

story 

1.  JIvaka-pafiha  [1  -  90] 

2.  Maha  Kassapa  thera  [2  -  91] 
a  BeUt^ha^isa  thera  [3  -  92] 
4.  Anuruddha  thera  [4  » '93] 
6.  MahS  Eaccajana  thera  [5  —  94] 

6.  Sariputta  thera  [6  »  95] 

7.  Kosambivasi-Tissa-thera-sSmanera  [7  »  96] 

8.  Sariputta-thera-paffha-vissajjana  [8  -  97] 

9.  Khadiraraniya  Rerata  thera  [9  »  98] 
10.  A&Satara  itthi  [10  -  99] 

SahaBsa-vagga  -  Book  Vm. 

Stoiy 

1.  Tamba-d&thika-cora-ghStaka  [l-lOO] 

2.  Daru-ciriya  thera  (C)  —  Bahiya^Sru-ciriya thera  (B)  [2—101] 

3.  Kundala-kesUheri  [3-4  -  102-3] 

4.  *  Anattha-pucchaka  brShmana  [5-6  —  104-5] 
6.  Sariputta-therassa  matula-brShmana  [7  —  106] 

6.  Sariputta-therassa  bhagineyya  [8  —  107] 

7.  Sariputta-therassa  sahayaka  brahmana  [9  —  108] 

8.  DIghayu  kumara  (C)  -  Ayuvaddhana  kumSra  (B)  [10  —109] 

9.  Sankicca-samanera  [U  - 110] 

10.  Khanu-kondafifia  thera  [12  -  lU] 

11.  Sappa-dasa  thera  [13  -  112] 

12.  PatScara  then  [14  »  113] 

13.  KisSGotaini  [15-114] 

14.  Bahu-puttika  then  [16  - 115] 

Pftpa-TTagga  -  Book  IZ. 

Stocy 

1.  Giileka^Itaka  brahmana  [1  -  116] 

2.  Seyyasaka  thera  [2  -  il7] 

3.  LSjS  deyadhitS  [3  - 118] 


B 

0 

424 

298 

426 

299 

428 

801 

429 

802 

431 

808 

432 

804 

436 

306 

437 

308 

438 

309 

446 

314 

B 

0 

446 

316 

460 

318 

464 

322 

469 

320 

461 

827 

462 

328 

463 

328 

464 

329 

466 

331 

474 

337 

476 

338 

478 

840 

484 

844 

487 

847 

B 

0 

488 

348 

491 

360 

492 

361 

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BURLINGAME.  —  BUDDHAGHOSA's   DHAMMAPADA   COMMENTARY.  475 

Btory                                                                                                                                 B  0 

4.  Anftthapindika  setthi  [4-5  -  U»-120]  404  353 

6.  Asallfiata-parikkhara  bhikkhu  [6  -  121]  497  365 

6.  BilSla-padaka  se^bi  [7  -  122]  498  356 

7.  Mah&dhana  vSnija  [8  -  123]  501  358 

8.  Kukkuta-mitta-nesada  [9  -  124]  502  359 

9.  Koka-sonakha-luddaka  [10  - 125]                                              .      507  362 

10.  ManikSra  kulupaga  Tissa  thera  [11  - 126]  509  364 

11.  Tayo  bhikkhu  (C)  -  Tajo  janS  (B)  [12  - 127]  511  366 

12.  Su-ppabuddhaSakja  [13-128]  515  360 

Dan^a-vagga  »  Book  Z. 

8tOT7                                                                                                                                 B  0 

1.  Chab-baggijS  [1  -  129]  517  370 

2.  Chab-baggija  [2  -  130]  518  371 

3.  Sambahula  kumaraka  [3-4  -  131-2]  510  371 

4.  Kundadhana  thera  [5-6  -  133-^]  519  372 

5.  VisakhSdinaq  upisikSnai]  aposatha-kamma  [7-135]  523  375 

6.  A jagara  peta  [8  -  136]  524  376 

7.  MahS  Moggallana  thera  [9-12, 137-140]  527  378 

8.  Bahubhandika  thera  (C)  -  B.  bhikkhu  (B)  [13  -  141]  531  381 

0.  Santati  ma'hamatU  [14  -  142]  535  384 

10.  Pilotika-thera  (C)  - -Tissa-thera  (B)  [15-16  -  143-4]  538  387 

11.  Sukha  samanera  [17  -  145]  540  388 

Jarft-vagga  -  Book  XL 

Btoxy                                                                                                                                     B  0 

1.  Visakhaya  sahajrikS  [1  -  146]  548  304 

2.  SiriroS  [2  -  147]  550  396 

3.  UtUrS  therl  [3  -  148]  554  398 

4.  Adhimanika  bhikkhu  (C)  —  SambahuUL  adhim&nika 

bhikkhu  (B)  [4  -  149]    555  399 

5.  Janapada-kalyanl-rupa-nanda  theri  [5  -  150]  556  400 

6.  Mallika  devi  [6- 151]  550  403 

7.  Laludayi  thera  [7  -  152]  561  404 

8.  Ananda-therassa  udSna-gath&  [8-9  -  153^]  564  406 

0.  Mahadhanasetthi-putta  [10-11 -155-6]  565  407 

Atta-vagga  -  Book  XIL 

Btoij                                                                                                                                     B  0 

1.  Bodhi  rajakumSra  [1  -  157]  568  400 

2.  Upananda  Sakyaputta  [2  -  158]  571  412 

3.  Padhanika  Tissa  thera  [3  -  159]  573  414 

4.  Kumara  Kassapa  thera  (C)  —  KumSra-Kasiapa-matu- 

then  (B)  [4  -  160]    574  415 

5.  Mah&  KSla  up&saka  [5  -  161]  578  417 

6.  Deradatta  [6  -  162]  570  419 

7.  Sangha-bheda-parisakkana  «  [F7,  BC7-8  -  F163,  B163^]  580  410 

*  This  story  is  told  in  connection  with  the  stanzas  beginning  *'  Sukaraij 
sfldhuna  s&dhuij  "  and  "SukarSni  as&dhQni/'  B  and  C  give  both  stanzas, 
but  Fausbail  omita  the  first.     Cp.  Dh.  (1900),  p.  38. 


Digitized  h  »' 


gle 


B 

C 

681 

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683 

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431 

696 

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600 

434 

476  PROCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 

Story 

a  KaUthera[F8,BC9»F164,B165] 
9.   Cola  Kala  up&saka  [F9,  BCIO  -  n65,  B166] 
10.  Atta^^ttha  thera  [FID,  BCU  -  F166,  Bie?] 

Zioka-TTagga  -*  Book  Xlll 

Btory 

1.  AnSatara  dahara  bhikkhu  [1  -  F167,  B168] 

2.  Suddhodana-raja  (B)  -  Suddhodana  (C)  [2-3  -  n6a-9, 

B169-170] 

3.  Paficasata  yipasiakS  bhikkhu  [4  -  F170,  B171] 

4.  Abhaja  rajakamara  [5  -  F171,  B172] 

5.  Sammufijani  thera(C)  -  Sammajjana  thera  (B)  [6  -^  F172, 

B173] 

6.  AnguUmala  thera  [7  -  P173,  B174] 

7.  Pesakara^lhlta  [8  -  n74,  B175] 

8.  Tigsa  bhikkhu  [9  -  n75,  B176] 

9.  CiBca  manavika  [10  -  P176,  B177] 

10.  A-sadisardana  [11  -  F177,  BITS] 

11.  Kala  nama  AnSthapindika-putta  (C)  -  An&thapindika- 

putta  K&la  (B)  [12  -  PITS.  B179]    603    437 

Buddha-vagga  -  Book  XIV. 

Story  B  G 

1.  M5ra-dhItaro  (C)  -  MSgandiyS  (B)  [1-2  -  n79-lS0, 

BlSO-181]    606    439 

2.  Yamaka-patiharija  (C)  -  Dey-orohana  (B)  [3  »  FlSl,  B1S2]        609    442 
8.  Erakapatta  nagarSja  [4  -*  F1S2,  BiS3]  628    466 

4.  Ananda-thera-uposatha-paSha  [P5-7,  C5-6  > -^  F183-5, 

B1S4-6]    632    459 

5.  ADabhiratibhikkhu[FS-9,C7-S-FlS6-7,B187-S]  688    460 

6.  Kosala-rafiBo  purohita  Aggidatta-brihmana  (C)  »  Aggidatta- 

brahmana(B)[F10-14,C^13-FlSS-192,B189-193]  686  462 

7.  Ananda-thera-pucchita-pa&ha  [F15,  C14  -  F193.  B194]  639  465 

8.  Sambahula  bhikkhu  [F16,  C15-  F194,  B195]  640  466 

9.  Eassapa-dasabalassa  suTanna-cetija  \T17~1B,  C16-17  - 

F195-6]      ♦      466 

Sukha-vagga  -*  Book  ZV. 
8*<wy 

1.  Nati-kalaha-Tupasamana  [1-3  -  F197-9,  B196-S] 

2.  Mara  [4  -  F200,  B199) 

3.  Kosala-rafifio  parajaya  [5  -  F201,  B200] 

4.  AfiEtatara  kuladarika  [6  -[F202,  B201] 
6.  Gonattha  upasaka  (B)  -^  AfifiaUra  upSsaka  (C)  [7«F203, 

B202]    646    472 

"  C  omits  the  stanza  beginning  '*  KhantI  paramai]  tapo  titikkhA  "  (F184). 
*  B  omits  the  stanzas  beginning  **  Poj&rahe  pOjayato  "  and  *J  Te  t&dise  pQja- 
yato,"  and  the  story  connected  tberewi^. 


B 

0 

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468 

648 

470 

644 

470 

645 

471 

Digitized  by  LjOOQIC 


BURUNGAME. — BXTDDHAOHOSA's   DHAMMAPADA   COMMENTARY.      477 


Story  B 

6.  Pasenadi-KosaU  rSjS  [8  -  F204,  B203]  648 

7.  TUsa  thera  (B)  -  AiUlatara  bhikkhu  (C)  [9  -  F205,  B204]  QtO 

8.  Sakka  deyaraji  (C)  -  SakknpanhSna  (B)  [10-12,  BlO-13  » 

F206-a06,  3205-206  •]  651 

Piya-vagga  -  Book  ZVI. 

Story 

1.  Tajo  janS  pabbajiti  (B)  -  Tayo  bhikkhu  (C)  [1-3  -  209-211] 

2.  Afiiiatara  kutnmbika  [4  -  212] 
8.  VisSkhS  [5  -  213] 

4.  Licchavi  [6  -  214] 

5.  Anitthigandha-kumara  [7-*  215] 

6.  Afiftatara  brShmana  [8  »  216] 

7.  PaQcasata  diraki'[9  -  217] 

8.  AnagSmi  thera  [10  -  218] 
0.  Nandiya  [11-12  -  219-220] 

Kodha-vagga  -  Book  XVIL 


Btoiy 
1. 
2. 


Rohin!  khattiya-kafins  [1  -  221] 
ABIiatara  bhikkhu  [2  -  222] 

3.  Uttara  upasikS  [3  -  223] 

4.  Mahfi-MoggallSna-thera-paRha-pucchita  [4  -  224] 

5.  SSketalui-brShmana  (C)  »  Buddha-pitu-brihmana  (6)  [5  > 

6.  PunnS  nSma  RSjagaha-setlhi-disi  [6  »  226] 

7.  Atul'a  upSsaka  [7-10  -  227-230] 

8.  Chab-baggiya-bhikkbu  [11-14  -  231-234] 


225] 


0 

473 
474 

476 


BCala-vagga  »  Book  XVUL 

Story 

1.  Go-gh5taka-putU  (1-4  -  235-8] 

2.  ASnatara  brShmana  [5  »  239] 

3.  Tissa  thera  [6  -  240] 
'   4.  LaludSyi  thera  [7  -  241] 

6.  AnSatara  kulaputta  [8-9  »  242-3] 

6.  Sariputta-therassa  saddhi-yihSrika  (C)  -  Cu\a  SSri  (B) 

[lO-U  -  244-5] 

7.  PaficasaU  upisakS  [12-14  -  246-8] 

8.  Tissa  dahara  [15-16  -  249-250] 
0.  Pafica  upSsakS  [17  -  251] 

10.  Mendaka  setthi  [18  -  252] 

11.  Ujjb&Da-sailBi  thera  [19  -  253] 

12.  Subhadda  paribbSjaka  [20-21-254-5] 

•  B  divides  F207-8  into  three  stanzas,  thus: 

B206    B&lasaijgatac&rl  hi  digham  addhftna  socati 

Dukkho  bidehi  saijvftso  amitteneva  sabbadft 
B207    Dhiro  ca  8ukhasai]vft8o  fifttlnai]  va  samfigamo 

Tasmft  hi:  Dhlrai]  pafifiafi  ca  bahussutaA  ca  dhorayha 
B208    Silai)  vatavantam  ftriyan  tag  t&disai)  sappurisai) 

Sumedhaq  bhajetha  nakkhattapathaii  va  candimft. 
^  Pages  522-529  of  the  Ck)lombo  edition  are  numbered  (by  a  printer's 
error)  122-129. 


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478  PROCEEDINGS   OF  THE   AMERICAN   ACADEBfT. 


Dhamma^tfia-vasga  —  Book  ZZZ. 

BUrrj 

1.  Vinicchaya-mahimacci  [1-2  «  256-7] 

2.  Chab-baggija-bhikkhu  [3  -  258] 
8.  Ekudana-thera-khinSsaya  (B)  -  EkaddSna-khi^SsaTa-thera  (C) 

[4  -  259] 
4.  Laknnlaka-bhaddijarthera  [5-6  »  260-261] 
6.  SambahulS  bhikkhu  [7-6  -  262-3] 

6.  Hatthaka  [9-10  -  264-5] 

7.  AMatara  brShmana  [11-12  -  266-7] 

8.  Titthija  [13-14  -  268-9] 

0.  BSlUika  (C)  -  Arija-bSHBika  (B)  [15  -  270] 
10.  Sambahula  bhikkhu  (C)  —  Sambahuli  sIladi-MmpannS 

bhikkhu  (B)  [16-17  »  271-2]    722    630 

Magga-vagga  -  Book  XJL, 

Story 

1.  PaScasata  bhikkhu  [1-4  -  273-6] 

2.  Paficasata  bhikkhu  (C)  - Anicca^lakkhana  (B)  [5-277] 
8.  PaScasata  bhikkhu  (C)  -  Dukkha-lakkhana  (B)  [B6, 

[C6-7S-B278] 

B4.  Anatta-Ukkhana  [B7  -  B279] 

B6  C4.  PadhSna-kammika  Tissa  thera  [8  «  280] 

B6  C6.  Sukara-peta  [9  -  281] 

B7  C6.  PotthiU  thera  [10  -  282] 

B8  07.  PaBca  mahaUaka  therS  [U  -12  -  283-4] 

BO  C8.  SuvannakSra  thera  [13  »  285] 

BIO  CO.  Mahadhana  ySnija  [14  -  286] 

Bll  CIO.  Kisa  Gotam!  [15  -  287] 

B12  Cll.  PatacarS  [16-17  -  288-9] 

Paki^naka-vagga  '  Book  XXT. 

Story 

1.  GaSgSrohana  (C)  -*  Attano  pubba-kamma  (B)  \X  -  290] 

2.  Eukkutanda-khSdikS  [2  -  291] 

8.  Bhaddiya  bhikkhu  [3-4  «  292-3] 
4.  Lakuntaka-bhaddija  thera  [5-6  -  294-5] 
6.  DSru-flkkatika-putta  [7-12  -  296-301] 

6.  Vaj ji-puttaka  bhikkhu  (13  «  302] 

7.  CitU  gahapati  [14  -  303] 
Cf.  Cula  Subhadda  [15  -  304] 

9.  £ka-yihSri  thera  [16  -  305] 

Niraya-vagga  *  Book  XXTT. 

Story 

1.  Sundari  paribbSjikS  [1  -  306] 

2.  Duccarita-phalSnubhavana-satta  [2  -  307] 

8.  Vaggu-muda-tiri7a4)hikkhu  [3  -  308] 

*  In  the  Colombo  edition  the  story  entitled  '' Dukkha-lakkhana"  is  told 
in  connection  with  stansas  6-7,  and  the  story  entitled  1*  Anatta-lakkhana  **  is 
omitted. 


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BURLINGAME. — BUDDHAGHOSA's   DHAMMAPADA   COMMENTARY.      479 


Story 


4.  AnSthapindikarbhSginejya-EhemakA-setthi-patta  (B)  » 

Khema  (C)  [4-5  -  309-310] 

5.  Dubbacabhikkhn  [6-8-311-313] 

6.  iMS-pakaU  itthi  [9  ->  314] 

7.  Sambahuli  Sgantukft  bhikkhu  [10  -  315] 

8.  Nigantha  [11-12  -  316-317] 

9.  Titthiji  sSyaka  [13-14  -  318-319] 


Story 
1. 
2. 
3. 

4. 
6. 
6. 
7. 

8. 


Story 
1. 
2. 

a 

4. 
5. 

6. 
7. 

8. 

0. 
10. 
11. 
12. 


Nftga-vagga  ->  Book  Xiiiii. 

Atanaq  Srabbha  kathita  [1-3  -  320-322] 
HatthScarija-pubbaka  bhikkhu  [4  -  323] 
Parijinnarbrahmana-putta  (B)  —  A&fiatararbrlhmana- 

putta  (C)  [5  -  324] 
Pasenadi-Kosala  [6  -  325] 
Sana  samanera  [7  ->  326] 

Psirejyaka'hatthi  (B)  -  Baddheraka  hatthi  (C)  [8-327] 
Sambahula  bhikkhu  (B)  -  Paficasata  disS-ySsi  bhikkhii  (C) 

[9-11  -  328-330] 
MSra  [12-14  -  331-333] 

TanhA-vagga  -  Book  XZIV. 

Kapila-maccha  [1-4  -  334-7] 

Sukara-potiki  [5-10  -  338-343] 

Vibbhanta  bhikkhu  [U  -  344] 

Bandhaoagara  [12-13  -  345-6] 

KhemS  then  [14  -  347] 

Uggasena^tt^ii-putta  [15  -  348] 

Cula  Dhanuggaha  pandita  (B)  —  Daharaka  bhikkhu  (C) 

[16-17  -  349-350] 
MSra  [18-19  -  351-2] 
Upakajivaka  [20  -  353] 

Sakka-pamia  (B)  -  SakkadeyarSjS  (C)  [21  -  354] 
Aputtaka  setthi  [22  ->  355] 
Ankura  [23^26  -  356-9] 


Bhikkhu-vagga  -  Book  ZZV. 

Story 

1.  PaSca  bhikkha  [1-2  -  360-361] 

2.  Ha2)8a-ghataka  bhikkhu  [3  -  362] 
8.  KokSlika  [4  -  363] 

4.  Dhammarama  thera  [5  -  364] 

6.  Yipakkha^evaka  bhikkhu  [6-7  -  365-6] 

6.  PaSc-aggadayaka  brahmana  [8  -  367] 

7.  Sambahula  bhikkhu  [9-17  -  368-376] 

8.  Paficasata  bhikkhu  [18-377] 

9.  SantakSya  thera  [19  -  378] 

10.  Nangala-kula  thera  [20-21  -  379-380] 

11.  VakkaU  thera  [22  -  381] 

12.  3umaDa  sSmanera  [23  —  382] 


767 

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480  PB0CEEDING8   OF   THE   AMERICAN   ACADEMY. 

Brfihma^a-vagga  -*  Book  ZZVL 

Btoiy 

1.  PasSda-bahola-brShmana  [1  -  383] 

2.  8ambahul&  bhikkhu  [2  -  384] 
8.  Mara  [3  -  385] 
4.  Af&fiatara  brShmana  [4  »  386] 
6.  Ananda  thera  [5  -  387] 

6.  ASnatara  brahmana  pabbajita  [S  ->  388] 

7.  Sariputta  thera  [7^  -  389-390] 

8.  Mah&  Pajapati  Gotami  [9  -  391] 

9.  S&riputta  thera  [10  -  392] 

10.  Jatila  brShmana  [U  *-  393] 

11.  Kuhaka  brahmana  [12  -  394] 

12.  Kisa  Gotam!  [13  -  395] 
18.  Eka  brShmana  [14  -*  396] 

14.  Uggasena-eetthi-pntta  [15  -*  397] 

15.  Dre  brShmanS  [16  -  398] 

16.  Akkosalabbaradyaja  [17  »  399] 

17.  Sariputta  thera  [18  -  400] 

18.  Uppalavanna  theri  [19  -  401] 

19.  Afifiatara  brShmana  [20  -  402] 

20.  KhemS  bhikkhuni  [21  -  403] 

21.  PabbharavSsi  Tissa  thera  [22  -  404] 

22.  AiinaUra  bhikkhu  [23  -  405] 
28.  SSmanerS  (B)  -  Cattaro  samanerS  (C)  [24  -  406] 

24.  MahS  Panthaka  thera  [25  -  407] 

25.  Pilindavaccha  thera  [26  »  408] 

26.  Afinatara  thera  [27  -  409] 

27.  SSriputta  thera  [28  -  410] 

28.  Maha  MoggaUSna  thera  [29  -  411] 

29.  ReraU  thera  [30-412] 

80.  CandSbha  thera  [31  -  413] 

81.  Sivali  thera  [32  -  414] 

82.  Sundara-eamudda-thera  [33  ->  415] 
88.  Jatila  thera  [34  -  416] 

88*.  Jotikassa  uppatti 
88\  Jatila  thera 

84.  Jotika  thera  [34  -  F416,  B417^ 

85.  Nata-puttaka  thera  (B)-Nata-pubbaka  (C)  [35-F417,B418] 

86.  Nata-puttaka  thera  [36  -  F418,  B419] 

87.  Vangisa  thera  [37-38  -  F419^20,  B420-421] 

88.  DhammadinnS  ther!  [39  ->  F421,  B422] 

39.  AngulimSU  thera  [40  -  F422,  B423] 

40.  Deyahita  brShmana  (B)  *»  Deva&gika  brShmana  (C) 

[41  -  F423,  B424]    911    676 

*  Pages  642-677  of  the  Colombo  edition  are  numbered  (by  a  printer's  error) 
624-659. 
^®  Story  34  repeats  the  stansa  of  Story  33. 


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BURUNGAME.  —  BUDDHAGHOSA's    DHAMMAPADA  COBiMENTART.       481 


ALPHABETIC  INDEX  TO  THE  TITLES  OF  THE  STORIES  OF 
THE  DHAMMAPADA  COMMENTARY. 


AkkosalabharadrSja,  xxvi.  16. 
Aggadayaka  brShmana,  see  PaSc  a.  b. 
Aggasaraka  (PTS  and  C)  —  Sariputta 

thera  (B)  i.  8. 
Aggidatta  brahmana  (B)  —  KosalaraBiio 

purohita   Aggidatta  brShmana    (C), 

xiv.  6. 
Ankura,  xxiy.  12. 

ASgulimSla  thera,  xiii.  6 ;  xxvi.  39. 
Ajagara  peta,  x.  6. 
Annatara  ukkanthita  bhikkhu  (B)  » 

Lltkanthita  aS&atara  bhikkhu  (PTS 

and  C),  ili.  3. 
A&natara  upasaka  (C)  *»  Gonat^ha  upS- 

saka  (B),  xy.  5.  « 

Afinatara  kafumbika,  xri.  2. 
Afinatara  kulaputta,  xviii.  5. 
Aiiuatara  thera,  xxvi.  26. 
ARBatara  dahara  bhikkhn,  xiii.  1. 
Anfiatara  purisa  (B)  -  KnmuduppalS- 

tit«  duggata  sevaka  (C),  y.  1. 
AnSatara  brahmana,  xvi.  6;   xriiL  2; 

xix.  7 ;  xxvL  4 ;  xxvi.  19. 
Aiiiiatara  brahmana  pabbajita,  xxvi.  6. 
Annatara  brahmana-putta  (C)  »  Pari- 

jinna  brahmana-putta  (B),  xxiii.  3. 
Anuatara  bhikkhu,  ii.  8;  iii.  2 ;  xvii.  2; 

xxvi.  22 ;  (C)  -  Tissa  thera  (B),  xv.  7. 
ABiiatara  itthi,  vii.  10. 
AHiiatarS  kuladarika,  xv.  4. 
Atula  upSsaka,  xvii.  7. 
Attadattha  thera,  xiL  10. 
Attano    pubbakamma   (B)  «-  GangSro- 

hana  (C),  xxi.  1. 
Attanai)  firabbha  kathita,  xxiii.  1. 
Anatta  lakkhana  (lacking  in  C),  xx.  B4. 
Anattha-pucchaka  brahmana,  viii.  4. 
Anabhiratibhikkhu,  xiv.  5. 
AnagamI  thera,  xvi.  8. 
Anathapindika-putta  Kala  (B)  »-  Kala 

nama  A.-p.  (C),  xiii.  11. 
Anathapindika  -  bhagineyya-Khemaka- 

set^hi-putta  (B)  -  Khema  (C),xxii.4. 
Anathapindika  setthi,  ix.  4. 
Anicca-lakkhana  (B)  -*  PaScasata  bhik- 
khu (C),  xx. '2. 
Anitthigandha^kumara,  xvi.  6. 
Anuruddha  thera,  vii.  4. 
VOL.  XLV.  —  31 


Apnttaka  setthi,  xxiv.  11. 

Abhaya  rajakumSra,  xiii.  4. 

Asafifiata-parikkhara  bhikkhu,  ix.  6. 

Asadisadana,  xiii.  10. 

Assaji-punabbaauka,  vi.  2. 

Ahipeta,  v.  12. 

Agantuka  paBcasata  bhikkhu  (C)  -*  P. 

a.  bh.(B),  vi.  11. 
^nanda  thera,  xxvi.  5. 
Xnanda-thera-udSna-gatha,  xi.  8. 
Jnanda-thera-paBha,  iv.  9;  ^iv.  4;  xiv.  7. 
Luanda  setthi,  v.  3. 
^yuvaddhana  kumara  (B)  »■  DIghayu 

k.  (C),*viii.8. 
Itthi,  see  ASnatarS  itthi. 
Issa-pakata-itthi,  xxii.  6. 
Ukkan|hit-aBiiatara^bhikkhu  (PTS  and 

C)  -  A.  u.  bh.  (B),  m.  8. 
Uggasena-eetthi-putta,  xxiv.  6;    xxvi. 

14. 
UjjhSna^aSSI  thera,  xviii.  11. 
UttarS  upSsika,  xvii.  3. 
UttarS  theri,  xL  8. 
Udiyi  thera,  v.  6. 
Udena,  ii.  1 
Udenaruppatti,  ii.  1». 
Upakajivaka,  xxiv.  9. 
Upananda  Sakyaputta  thera,  xii.  2. 
Upasaka,  see  AfiSatara-,   Pafica-,  and 

Pancasata-u. 
Uppalavanna  theri,  v.  10;  xxvi.  18. 
EkS  kukkutanda-khadika,  xxi.  2. 
Eka  brShmana,  xxvi.  13. 
EkavihSri  thera,  xxi.  9. 
EkuddSna-khinSsava-thera  (C)  «*  Eku- 

dSna-th.-kh.  (B),  xix.  3. 
Erakapatta  nSgarajS,  xiv.  3. 

KaccSyana,  see  MahS  K. 

Kapila  maccha,  xxiv.  1. 

Kappina,  see  Maha  K.  ' 

Kassaka,  v.  8. 

Kassapa,  see  Kumara  K.  and  MahS  K. 

Kassapa-  dasabalassa    siivanna    cetiya 

(lacking  in  B),  xiv.  9. 
KSna-mStS,  vi.  7. 
KSla,  see  Cilia  K.  and  MahS  K. 
Kala  thera,  xii.  8. 


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PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


Eala  nSma  Anathapindika-putta  (C)  — 

A..p..K.  (B),  xiii.  ll!  * 
KSli  jakkliinl,  i.  4. 

Kisa  Gotami,"  viiL  13;  xx.  11 ;  xxri.  12. 
Kukkutanda-khadika,  see  £kS  k.-kh. 
Kukkuta-mitta-nesada,  ix.  8. 
Kutumbika,  see  ASilatara  k. 
Kundadhana  thera,  x.  4. 
Kondala-kesi-theri,  yiii.  8. 
Kumara    Kassapa   thera  (C)  «  K.-K.- 

matu-theri  (B),  xii.  4. 
Kurauduppalatita-duggata-seyaka     (C) 

->  A&Satara  purisa  (B),  v.  1. 
Kumbhaghosaka  setthi,  ii.  2. 
Kuladarika,  Itulaputta,  see  ASSatarS,-a. 
Kuhaka  brahmana,  xxvi.  11. 
Ku^  peta,  see  Satthi-k.  p. 
Koka-sunakha^luddaka,  ix.  0. 
Kokalika,  xxy.  3. 
KoDdadhana    thera,  see   KundadhSna 

thera. 
KosambikS  bhikkhu,  i.  5. 
Kosambiyasi-Tissarthera-samanera,  yii. 
•  7. 

Kosala-ra&So  parajaja,  xy.  3. 
Kosala-rafiBo  purohita  Aggidatta-brah- 

mana  (C)  -  A.-b.  (B),  xiy.  6. 
Ehadirayanija  Reyata  thera,  yii.  9. 
Khanu-kondafi8a  thera,  yiii.  10. 
Ehema      (C)   —  Anathapindika-bhagi- 

neyya-Ehemaka-setthi-putta  (B)f  xxii. 

4. 
Kheroa  then,  xxiy.  6. 
Khema  bhikkhunl,  xxyi.  20. 
Gangarohana    (C)   -  Attano    pubba- 

kamma  (B),  xxi.  1. 
Ganthi-bhedaka  corS,  y.  4. 
Garahadinna,  iy.  12. 
Goghataka  putta,  xyiii.  1. 
Gotaroi,  see  KisS  G.  and  Maha  Paja- 

pati  G. 
Godhika-thera^parinibbina,  iy.  11. 
Gonattha  apasaka  (B)  «-  AfiBatara  upi- 

saka  (C),  xy.  5. 


Ghosaka-setthi-uppatti,  ii.  P. 

Cakkhupala  thera,  i.  1. 

Cattaro  samanera  (C)  -  Samanera  (B), 

xxyi.  23. 
Candfibha  thera,  xxyi.  30. 
CiSca  manayika,  xiii.  9. 
Citta  gahapati  (B)  -  Sudhamma  therm 

(C),  y.  14. 
Citta  gahapati,  xxi.  7. 
Cittahattha  thera,  iii.  6. 
Cunda  siikarika,  i.  10. 
Cilia  Kala  upasaka,  xii.  9. 
Cula  Kala  and  Maha  Kala,  i.  6. 
Cula  Dhanuggaha  pandita  (B)  ^  Daha- 

raka  bhikkhu  (C),  xxiy.  7. 
Cilia  Panthaka  thera,  ii.  3. 
Cola  Sari   (B)  -  SSriputta-therassa  sa- 

ddhiyihSrika  (C),  xyiiL  6. 
Cola  Subhadda,  xxi.  8. 
Ciilaka-sStAka-brahmana,  ix.  1. 
Chab-baggiya,  x.  1;  x.  2;  xyii.8;  xix.2. 
Chattapani  upasaka,  iy.  7. 
Channa  thera,  yi.  3. 

Janapada-kalyani-riipa-nanda  theri,xi.5. 
Jatila  thera,  xxyi.  38  and  83^. 
Jatila  brahroana,  xxyi.  10. 
Jana,  see  Tajo  jana. 
Jambuka   thera  (B)  —  JambukSjiyaka 

(C),  y.  11. 
Jfyaka-pailha,  vii.  1. 
Jotika  thera,  xxyi.  34. 
Jotika-uppatti,  xxyi.  S3*. 
NSti-kalaha-yiipasamana,  xv.  1. 
Tamba-da|hika-cora-ghStaka,  yiii.  1. 
Tayo  jana  (B) -Tayo  bhikkhu  (C),  ix. 

11. 
Tayo  janS  pabbajitS  (B)  -  Tayo  bhi- 
kkhu (C),  xvi.  1. 
Tayo  bhikkhii,  ix.  11;  (C)  -  Tayo  jana 

pabbajiti  (B),  xyi.  1. 
TiQsa  bhikkhu,  xiii.  8. 
Tiqsa-matta-payeyyaka  bhikkhu,  t.  6. 
Titthiya,  xix.  8. 
TitthiyS  sSyaka,  xxii.  9. 


"  Mailer,  in  his  Glossary  of  P&li  Proper  Names  (JPTS.  1888),  gives  only 
one  Kis&  GotamI,  as  does  also  Kem  in  his  Manual  of  Indian  Buddhism  (page 
16,  note  3).  But  are  not  the  virgin  of  the  Warrior  caste  who  greeted  the 
Buddha  from  the  roof  of  her  palace  (J&.  i.  OC'-OP^),  and  the  frail  widow, 
daughter  of  a  poverty-stricken  house,  described  in  these  passages  as  sorrowing 
over  the  loss  of  her  first-bom  son,  two  entirely  different  persons? 


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BURUNQAME.  —  BUDDHAGHOSa's  DHAMMAPADA  COMMENT ABY.   483 


Tissa  thera,  i.  3;  xv.  7;  xviii.  3;  see  also 

Kosambivisi  Tissa,  vii.  7 ; 

Nigamayisi  T.,  ii.  9 ; 

Fadhana-kammika  T.,  xx.  B5,  C4; 

FadhanikaT.,  xii.  3; 

FabbharaySsi  T.,  xxvi.  21 ; 

Manikara  kulupaga  T.,  ix.  10 ; 

Vanavasi  T.,  v.  16. 
Tissa  dahara,  xyiii.  8. 
TImlla  Tissa,  see  Tissa  thera. 
Thera,  passim ;  see  ASBatara  thera. 
Dakaraka  bhikkhu  (C)  »  Cula  Dbano. 

ggaha  pandita  (B),  xxiy.  7. 
DarakS,  see  PaScasata  d. 
Baru-cirija  thera  (C)  —  BShiyard.-c.-th. 

(B)  yiii.  2. 
DSru-saka^ika-putta,  xxi.  5. 
Bisa-yasi-bhikkhu,  see  Paficasata  d.-y.- 

bh. 
DigkSyu  kumira  (C)  —  ^jayaddhana 

kumara  (B),  yjii.  8. 
Bukkha  lakkhana  (B)  -FaBcasata  bhi- 
kkhu (C),  xx.  a 
Duccarita-phalanubhayana-satta,  xxii.  2. 
Dubbaca  bhikkhu,  xxii.  6. 
Deyangika-brShmana  (C)   -*  Deyahita 

brahmana  (B),  xxyi.  40. 
Devadatta,  i.  7 ;  1.  12;  xii.  6. 
Deyahita  brShmana   (B)  —  Deyafigika 

brahmana  (C),  xxyi.  40. 
Dev-orohaua  (B)  »  YamakarpStiharija 

(C),  xiy.  2. 
Dye  brahmanS,  xxyi.  15. 
Dye  sahayaka-bhikkhB,  i.  14;  Pamatt- 

appamattS  d.  s.-bh.  (B  and  C),  ii.  6. 
Dhana-,   see    Maha-dhana-   and    Ciila- 

dhana-. 
Dhammadinn&  then,  xxyi.  38. 
Dhamma-sayana,  yi.  10. 
Dhammarama  thera,  xxy.  4. 
Dhammika  upasaka,  i.  11. 
Dhammika  thera,  yi.  9. 
Nangalakula  thera,  xxy.  10. 
Nanda  gopila,  iii.  8. 
Nanda  thera,  i.  9. 
Nandija,  xyi.  9. 
Na|a-puttaka  thera  (B)  -^  Na^>pubbaka 

(C),  xxyi.  86. 
Na^-puttaka  thera,  xxyi.  86. 
KiganthS,  xxii.  8. 
Nigamay&si  Tissa  thera,  ii.  9. 


FaSca  upSsakS,  xyiii.  9. 
PaBc-aggadajakS  brahman&,  xxy.  6. 
PaBca  bhikkhii,  xxy.  1. 
PaBca  mahallaka  thera,  xx.  8. 
PaBcasata  Sgantuka  bhikkhu  (B)  -  A. 

p.  bh.  (C),  yi.  11. 
PaBcasata  up&saka,  xyiii.  7. 
PaBcasata  dSrakS,  xyi.  7. 
FaBcatfata  disiSySsi-bhikkhu    (C)   Sam- 

bahulS  bhikkhii  (B),  xxiii.  7. 
PaBcasata  bhikkhii,  xx.  1,  2,3;  xxy.  8. 
PaBcasata   bhikkhii    (B)  «  PaBcasata 

yipassaka-bhikkhii  (C),  iii.  6. 
PaBcasata  bhikkhu    (B)  -  VighSsSda 

dosa-yutti  p.  bh.  (C),  yi.  8. 
PaBcasata  yipassaka-bhikkhii  (C)  »  P. 

bh.  (B),  iii.  6. 
PaBcasata  yipassaka-bhikkhn,  xiii.  3. 
Pajapati  Gotami,  see  Maha  P.  G. 
PatipujikS  kumarika  (B)  =«  PatipujikS 

(PTS  and  C),  iy.  4. 
Pathayi-katha-pasuta   paBcasata  bhik- 
khu, iy.  1. 
Padhana-kammika  Tissa  thera,  xx.  B5, 

C4. 
Padhanika  Tissa  thera,  xii.  3. 
Panthaka,  see  Cula  Panthaka  and  MahS 

Panthaka. 
Pa^acira  theri,  yiii.  12 ;  xx.  12. 
Pandita-saraanera,  yi.  6. 
Pabbharayasi  Tissa  thera,  xxyi.  21. 
Famatt-appamatta  dye  sahayakS-bhik- 

khu  (B  and  C)  -  Dye  s.bh.  (PTS), 

ii.  6. 
Parijinna  brShmana-putta  (B)  ->  ABBa- 

tara  brahmana-putta  (C),  xxiii.  3. 
Pasada-bahula-brabmana,  xxvi.  1. 
Pasenadi  Kosala,  xxiii.  4. 
Pathikajiyaka  (PTS  and  C)  -  Payey- 

yakSjfyaka  (B),  iy.  6. 
PayeyyakSjIyaka  (B)  -  Pathikajiyaka 

(PTS  and  C).  iy.  6. 
Payeyyaka   hatthi    (B)  -*  Baddheraka 

hatthi  (C),  xxiii.  6. 
Pilindayaccha  thera,  xxyi.  26. 
Filotika  thera  (C)  -  Pilotika  Tissa  thera 

(B).  X.  10. 
PunnS  nama  Rajagaha-setthi-d&sl,  xyii 

6. 
Piitigatta  Tissa  thera,  iii.  7. 
Pesakara-dbltS,  xiii.  7. 


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484 


PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 


Potthila  thera,  xx.  B7,  C6. 
Baddheraka   hattlii    (C)  -*  PSyejyaka 

hatthi  (B),  xxiii.  6. 
Bandhanfigara,  xxiv.  4. 
Bahuputtika  theri,  Tiii.  14. 
Bahu-bkandika  bhikkhu    (B)  -  B.-bh. 

thera  (C),  x.  8. 
Bala-nakkhatta-ghu||ha,  ii.  4. 
BSlisika,  xix.  0. 
Bahiya-daru-cirija  thera  (B)  —  D^.  th. 

(C),  viii.  2. 
Bilala-padaka  setthi,  ix.  6. 
Buddha-pi tu-brahmana  (B)  *  Saketaka 

brahmana  (C),  xrii.  5. 
Behi|tha-8isa  thera,  vii.  3. 
Bodhi  rajakumara,  xii.  1. 
Brahmana,  paftsim;  see  AfiSlatara  and 

Eka  brahmana  and  Dve  brahmana. 
Bhadda-vaggiya    (C)  »  TiQsa-matta-pS- 

yeyyaka-bhikkhu  (B),  v.  6. 
Bhaddiya  bhikkhu,  xxi.  3. 
Bhagineyya-flangharakkhita  thera  (PTS 

and  C)  -  S.-bh.  th.  (B),  iii.  4. 
Bhikkhu,  passim ;  see  Afinatara-,  Tayo-, 

Tiigsar,  FaBca-,  and  Paiicasata-bh. 

Magha  (B)  -  MahSli-paSha  (PTS  and 

C),  ii.  7. 
Macchariya  Kosiya  setthi.  It.  6. 
Ma|thakundali,  i.  2. 
ManikSra-kuliipaga  Tissa  thera,  ix.  10. 
Matta-paveyyaka   bhikkhii,  see   Tigsa 

matta-pSveyyakS  bh. 
Marana-paridlpaka,  ii.  1'. 
Marici-kammaf ^hanika  thera,  iv.  2. 
Mahallaka  thera,  see  PaBca  m.  th. 
Mallika  devi,  xi.  6. 
Maha  KaccSyana  thera,  rii.  6. 
Maha  Kappina  thera,  ri.  4. 
Maha  Kassapa  thera,  ii.  5 ;  vii.  2. 
Maha- Kassapa  •  thera  •  pindapata -dinna, 

iv.  10. 
MaharKa88apa-thera-0addhiviharika,y.2. 
Maha  Kala,  see  Cula  Kala. 
Mahi  K&la  upSsaka,  xii.  5. 
Mahadhana  vSnija,  ix.  7 ;  xx.  10. 
MahSdhana  se^thi-putta,  xi.  9. 
MahS  Panthaka  thera,  xxvi.  24. 
MahS  Pajapati  Gotami,  xxvi.  8. 
MahS  Moggallfina  thera,  x.  7 ;  xxvi.  28. 
Maha-Moggall&na*thera-paiiha,  xvii.  4. 


Mahali-paSha  (PTS   and   C)  «  Magha 

(B),  il  7. 
MagandiyS.  ii.  1* ;  -  MSnKihitaro  (C), 

xiv.  1. 
Mara,  xv.  2:  xxiii.  8;  xxiv.  8;  xxvi.  3. 
Mara-dhitaro  (C)  -  Magandiya  (B),  xiv. 

1. 
Meghiya  thera,  iii.  1. 
Mendaka  se^thi,  xviiL  10. 
Moggallana,  see  MahS  MoggallSna. 

RajS  Pasenad!  Kosala,  xv.  0. 

Radha  thera,  vi.  1. 

Revata  thera,  xxvi.  20;  see  also  Kha- 

diravaniya  R.  th.,  viL  0. 
Rohini  khattiya-  kaSSS,  xvii.  1. 
Lakuntaka-bhaddiya  thera,  vi  6;  xix. 

4 ;  xxi.  4. 
Lakkhana,  see  xx.  2.  3.  4. 
LajS  devadhtta,  ix.  3. 
La}udayi  thera,  xi.  7 ;  xviii.  4. 
Licchavi,  xvi.  4. 
Vakkali  thera,  xxv.  11. 
Vaggiya,  see  Chab-baggiyS  and  Bhadda- 

vaggiya. 
VaggumudStiriyS  bhikkhu,  xxii.  3. 
Vangisa  thera,  xxvi.  87. 
Vajji-puttaka  bhikkhu,  xxi.  6. 
Vanavasi  Tissa   thera   (C)  -  V.-v.  T. 

samanera  (B),  v.  15. 
VSsuladattS,  ii.  1*. 

VighasSdS  dosa-vuttS  paBcasata  bhik- 
khu (C)-P.  bh.  (B),  vi.8. 
Vitatiibha  (B)  =  Vidiidabha  (PTS  and 

C),  see  next. 
Vidudabha,  iv.  3. 
Vinicchaya-mahamaccS,  xix.  1. 
Vipakkha-sevaka  bhikkhu,  xxv.  6. 
VipassakS  bhikkhu,  see  PaBcasata  v.  bh. 
Vibbhanta  bhikkhu,  xxiv.  3. 
VisakhS,  iv.  8;  xvi.  3. 
VisSkhadinaQ    upSsikanaq     uposathji- 

kamma,  x.  5. 
VisKkha-sahSyikS,  xi.  1. 
VihSri-thera,  see  EkavihSri  thera. 

Sakka  deva-rSjS  (C)  -Sakka^pafiha  (B), 

xxiv.  10. 
Sakka  deva-rSjS  (C)  -  Sakk-upa((hSna 

(B),  XV.  8. 
Sankicca  samanera,  viii  9. 


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Sangha-bheda-parisakkana,  xii.  7. 
Saogharakkhita-bhaginejja   thera   (B) 

-  Bh.-e.  th.  (PTS  and  C),  iii  4. 
Santakaya  thera,  xxv.  9. 
Santati  mahamatta,  x.  9. 
Satthiku^  peta,  t.  la 
SappadSsa  thera,  viii.  11. 
Sambahula  adhimanika  bhikkhu  (B)  — 

Adhimanika  bh.  (C),  xi.  4. 
Sambahula  agantuka  bhikkhu,  xxii.  7. 
Sambahula  kumaraka,  x.  3. 
Sambahula  bhikkhu,  xi.  4 ;  xlv.  8 ;  xix. 

5 ;  xix.  10 ;  xxii.  7 ;  xtiiL  7 ;  xxv.  7 ; 

xxvi.  2. 
Sambahifla    siladi-saropanna    bhikkhu 

(B) -Sambahula  bh.  (C),  xix.  10. 
Sammajjana   thera    (B) »  Sammufijani 

th.  (C),  xiiL  5. 
SahSyaka  bhikkhu,  see  Dve  s.  bh. 
Sataka  brahmana,  see  Cula  s.  b. 
Sanu  sSmanera,  xxiii.  5. 
SSmanerS  ('B)-Cattaro  s.  (C),  xxvi.  23 
Samavati  (B)  -  Udena  (PTS  and  C), 

ii.  1. 
SSmavati-uppatti,  ii.  1*. 
Sari,  see  Ciila  Sari. 
SSriputta  thera  (B) »  AggasSvaka  (PTS 

and  C),  i.  8. 
Sariputta  thera,  i.  8 ;  vii.  6.8 ;  viii  6. 6. 7 ; 

xviiL6;  xxvi.  7.  9.  17.27. 


SSriputta-thera-pafiha-visBajjana,  vii.  8. 
Sariputta-thera-bbagineyya,  viii.  6. 
SSriputta-thera-matula  brahmana,  viiL 

6. 
Sariputta-thera-saddhiviharika,  xviii.  0. 
Sariputta  -  thera  -  sahayaka    brahmaj^ 

viii  7. 
Sirima,  xi.  2. 
Sivali  thera,  xxvi.  31. 
Sukha  samanera,  x.  11. 
Suddhodana  raja,  xiii.  2. 
Sudhamma  thera,  v.  14. 
Sundara-samudda  thera,  xxvi.  82. 
Sundari  paribbajika,  xxii.  1. 
Su-ppabuddha  kutthi,  v.  7. 
Su-ppabuddha  Sakja,  ix.  12. 
Subhadda  paribbajaka,  xviii.  12. 
Subhadda,  see  Ciila  S. 
Sumana  malakara,  v.  9. 
Suifiana  samanera,  xxv.  12. 
Sumana  devi,  i.  13. 
Suvannakara  thera,  xx.  B9,  C8. 
Siikara  peta,  xx.  B6,  C6. 
Siikara-potikft,  xxiv.  2. 
Sejjasaka  thera,  ix.  2. 
Soreyya  thera,  iii.  9. 
Haqsa-ghataka  bhikkhu,  xxv.  2. 
Hatthaka,  xix.  6. 
Hatthacarija-pubbaka  bhikkhu,  xxiii.  2. 


ANALYSIS  OF  THE  STORIES  OF  THE  DHAMMAPADA  COMMEN- 
TARY, BOOKS  I-IV. 
Ayai}  pan'  ettha  saSkhepo. 
Book  I.    Story  1.    Cakkhupftla,  Xader.  ^ 

ILLUSTRATING  STANZA   1-1. 

Mah&snvanna,  a  rich  householder  of  Savatthi,  made  a  vow  to  a  tree- 
spirit,  whereby  be  became  the  &ther  of  two  sons.  Since  the  tree  had 
been  protected  (palitai))  by  him,*  he  named  them  Maha  Pftla^^  and 
Culla  P&la.  When  they  reached  manhood,  their  parents  set  them  up 
in  households  of  their  own.  i*    (3-4) 

"  Of.  Rogers,  pp.  1-11. 

"  Call^  Cakkhupala  after  he  wins  Arahatship  by  sacrificing  his  eyes. 
Cakkhu  is  the  Pali  word  for  "  eye." 

**  The  numbers  printed  in  heavy  type  and  in  parentheses  at  the  end  of 
each  paragraph  indicate  the  pages  of  Norman's  text  which  are  summarized 
in  the  paragraph  concerned. 


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_T_ 


486  PBOCEEDINOS  OF  THE  AMERICAN  ACADEMY. 

At  this  time  the  Teacher  was  in  residence  at  Jetavana  monastery. 
(He  spent  one  rainy  season  at  Banyan-tree  monastery,  erected  by  his 
relatives ;  nineteen  at  Jetavana,  erected  by  An&thapindika ;  six  at 
Eastern-grove,  erected  by  Visakha.)  An&thapindika  and  Visakha  went 
to  the  monastery  twice  each  day  with  the  usual  o£ferings.  One  day 
the  former  refrained  from  asking  questions  for  fear  of  wearying  the 
Teacher.  Knowing  this,  Buddha  preached  with  such  vehemence  that 
fifty  of  the  seventy  million  inhabitants  of  Savatthi  became  noble  dis- 
ciples. The  noble  disciples  performed  two  duties  daily:  before  break- 
fast, they  dispensed  alms ;  after  break&st,  bearing  the  usual  o£ferings, 
they  went  to  hear  the  Law.    (^5) 

Mahapala  followed  them  one  day  and  was  so  afibcted  by  the  dis- 
course that  he  asked  Buddha  to  mcJce  him  a  monk.  Taking  leave  of 
his  brother,  who  did  his  utmost  to  dissaade  him,  he  was  admitted  and 
professed.  After  five  years  had  passed,  he  came  to  Buddha  and  asked 
him  how  many  were  the  Burdens  of  the  Religious  Life.  On  being  told 
that  there  were  two,  namely,  the  Burden  of  memorizing  and  preaching 
the  Scriptures,  and  the  Burden  of  the  development  of  Spiritual  Insight 
by  ascetic  practices  and  meditation,  he  chose  the  latter  as  being  better 
suited  to  his  advanced  years.  The  Teacher  instructed  him  in  the 
ascetic  practices  leading  to  Arahatship,  and  he  set  out  with  sixty  dis- 
ciples.    (5-8) 

The  inhabitants  of  a  village  120  leagues  distant  received  them  hos- 
pitably, obtained  the  privilege  of  entertaining  them  during  the  rainy 
season,  and  built  them  a  monastery.  A  physician  also  o£fered  his 
services.  Mahapala,  on  learning  that  the  monks  purposed  to  avail 
themselves  of  the  four  postures  (walking,  standing,  sitting,  and  reclin- 
ing), announced  that  he  should  content  himself  with  the  first  three, 
and  vowed  not  to  stretch  his  back  in  repose.  After  encouraging  each 
other  to  be  vigilant,  they  entered  upon  the  observance  of  the  rainy 
season.    (^^) 

At  the  end  of  the  first  month  Mah&pala's  eyes  began  to  trouble  him. 
The  physician  treated  him,  but  as  he  never  lay  down  to  rest,  the  treat- 
ment did  him  no  good.  However,  he  resolutely  kept  his  vow,  until 
finally,  one  night  at  the  end  of  the  middle  watch,  he  lost  simultane- 
ously his  eyesight  and  the  Depravities,  and  became  an  Arahat  The 
monks  and  villagers,  learning  that  he  had  lost  his  eyesight,  expressed 
their  sjrmpathy,  and  assured  him  that  they  would  take  care  of  him. 
At  the  end  of  the  rainy  season,  the  monks  also  attained  Arahatship. 
(d-13) 

When  the  monks  expressed  a  desire  to  see  the  Teacher,  Mahapala, 
knowing  that  there  was  a  forest  on  the  way  haunted  by  evil  spirits,  and 


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BURUNGAME.  —  BUDDHAGHOSA's  DHAMMAPADA    COMMENTARY.       487 

fearing  that  he  would  be  a  hindranoe  to  the  monks,  sent  them  on  ahead, 
directing  them  to  ask  his  brother  to  send  some  one  to  lead  him,  and  to 
greet  Buddha  and  the  eighty  abbots  in  his  name.  After  taking  leave 
of  the  villagers,  who  were  reluctant  to  part  with  them,  they  went  and 
did  their  master's  bidding.  Gullap&la  sent  his  nephew  Pftlita,  first 
admitting  him  as  a  monk,  that  he  might  escape  the  dangers  of  the 
journey.     (13-15) 

Palita,  after  waiting  upon  Mah&p&la  for  a  fortnight,  led  him  to  the 
village.  In  spite  of  the  protests  of  the  inhabitants,  they  continued  on 
their  journey  until  they  reached  the  forest,  where  the  youth,  hearing 
the  voice  of  a  woman,  left  his  uncle  and  broke  the  vow  of  chastity. 
Returning,  he  confessed  his  sin,  removed  his  yellow  robes,  and  assumed 
the  garb  of  a  householder.  But  Mah&pala  would  have  nothing  more  to 
do  with  him,  and  he  departed  in  tears.     (15-17) 

So  intense  was  Mahftpftla's  morality  that  Sakka's  throne  showed 
signs  of  heat  Looking  about,  he  beheld  the  Elder.  Fearing  that  if 
he  &iled  to  go  to  his  assistance,  his  head  would  split  into  seven  pieces, 
he  disguised  himself  as  a  wayiOsirer,  went  to  him,  and  ofiered  to  lead 
him  to  Savatthi.  Shortening  the  distance  by  his  magic  power,  Sakka 
brought  him  to  his  destination  that  very  evening.  Cullapala  cared  for 
him  tenderly  and  gave  him  two  novices  to  wait  on  him.     (17-19) 

One  night  after  a  heavy  rain  Gakkhupala  took  a  walk  in  the  cloister 
and  trampled  many  insects  to  death.  Some  visiting  monks  reported 
the  matter  to  the  Teacher,  who  replied  that  as  Gakkhupala  did  not  see 
the  insects,  he  was  innocent  of  offense.  The  monks  ^en  asked  how 
it  was  that  the  Elder,  though  destined  to  attain  Arahatship,  became 
blind.  Buddha  replied  that  it  was  because  of  a  sin  he  committed  in  a 
previous  existence.  The  monks  asked  the  Teacher  to  tell  them  about 
it,  and  he  did  so.    (19-20) 

Story  of  Gakkhupala's  sin  in  a  previous  existence.  A  woman  of 
Benares  promised  a  physician  that  she  and  her  children  would  become 
his  slaves  in  case  he  succeeded  in  curing  her  of  an  affection  of  the  eyes. 
He  did  so ;  biit  she,  repenting  of  her  bargain,  attempted  to  deceive  him 
by  telling  him  that  her  eyes  were  worse  than  ever.  He  discovered  that 
she  was  deceiving  him,  and  got  revenge  by  giving  her  an  ointment 
that  made  her  blind.    That  physician  was  Gakkhupftla.     (20-21) 

The  Teacher,  warning  his  hearers  to  take  the  lesson  to  heart,  pro- 
nounced Stanza  1,  at  the  conclusion  of  which,  thirty  thousand  monks 
attained  Arahatship.    (21-4) 


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PBOCEEDINGS   OF   THE   AMERICAN   ACADEMT. 
Book  L    Story  2.    Matfhakan<Uai  ^^ 

ILLUSTRATINO  STANZA  2-2. 

At  S&vatthi  lived  a  Brahman  of  a  disposition  so  niggardly  that  peo- 
ple called  him  Adinnapubbaka  (Never-gave-a-ferthing).  He  had  an 
only  son,  whom  he  dearly  loved.  Desiring  to  give  the  boy  a  pair  of 
earrings,  but  at  the  same  time  to  avoid  unnecessary  expense,  he  beat 
out  the  gold  himself,  made  him  a  pair,  and  gave  them  to  him ;  where- 
fore people  called  the  boy  Matthakundall  (The-boy-with-the-burnished- 
ear-rings).  When  the  boy  was  sixteen  years  old  he  had  an  attack  of 
jaundice.  The  mother  wished  to  have  a  physician  called,  bat  the 
father  demurred  at  the  thought  of  paying  him  his  fee,  inquired  of 
various  physicians  what  remedies  they  were  accustomed  to  prescribe 
for  such  and  such  an  Ailment,  and  treated  him  himself  The  boy  grew 
steadily  worse  and  was  soon  at  the  point  of  death.  Realizing  this,  and 
fearing  that  those  who  came  to  see  his  son  would  also  see  the  wealth 
the  house  contained,  the  Brahman  carried  his  son  outside  and  laid  him 
down  on  the  terrace.     (25-6) 

That  very  morning  the  Exalted  One,  arising  from  a  Trance  of  Oreat 
Compassion,  and  surveying  the  world  with  the  eye  of  a  Buddha,  beheld 
Matthakundall  lying  on  the  terrace  at  the  point  of  death.  Foreseeing 
that  Matthakundall,  and  through  him  many  others,  would  attain  the 
Fruit  of  Conversion,  Buddha  visited  him  on  the  following  day.  The 
youth  made  an  Act  of  Faith  in  Buddha,  died,  and  was  reborn  in 
the  world  of  the  Thirty-three.    (26-8) 

Adinnapubbaka,  after  having  the  body  of  his  son  cremated,  went  daily 
to  the  cemetery  and  bewailed  his  loss.  Matthakundall,  desiring  to 
convert  his  father,  assumed  the  form  he  had  borne  upon  earth,  and 
went  and  wept  also.  The  Brahman  asked  the  youth  why  he  was  weep- 
ing. The  latter  replied ;  "  I  need  a  pair  of  wheels  for  my  chariot 
The  sun  and  moon  are  just  what  I  want,  and  I  weep  because  I  cannot 
get  them.'*  The  Brahman  told  him  he  was  a  fooL  "  But  which  of  as 
is  the  bigger  fool,"  said  the  youth,  "I,  who  weep  for  what  exists,  or 
you,  who  weep  for  what  does  not  exist  ? "  The  youth  then  told  him 
that  he  was  his  son,  and  that  he  had  attained  his  present  glory  by 
making  an  Act  of  Faith  in  the  Buddha.  Thereupon  the  &ther  sought 
refuge  in  the  Buddha,  the  Law,  and  the  Order,  and  took  upon  himself 
the  Five  Precepts.  The  son,  after  urging  his  father  to  visit  the 
Buddha,  disappeared.     (28-33) 

The  Brahman  invited  Buddha  and  his  monks  to  dine  with  him. 

»  a,  Rogers,  pp.  12-17. 


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BURUNGABIE.  —  BUBDHAGHOSA's   DHAMMAPADA   COMMENTARY.       4S9 

Buddha  accepted  the  invitatioD.  The  Brahman  asked  him  whether  it 
was  possible  to  attain  rebirth  in  heaven  by  a  simple  Act  of  Faith. 
Buddha  instanced  the  case  of  Matthaknndali,  and  then  said :  "  It  is 
not  one  hundred,  or  two  hundred,  — there  is  no  counting  the  number 
of  those  who  have  attained  rebirth  in  heaven  by  making  an  Act  of 
Faith  in  me."  To  convince  the  bystanders,  he  summoned  Mattha- 
kundall,  who  appeared  in  all  his  glory  and  confirmed  the  Buddha's 
words.  Buddha  then  dwelt  upon  the  importance  of  a  right  attitude  of 
the  thoughts  and  of  a  believing  heart,  and  pronounced  Stanza  2. 
(33-5) 

At  the  conclusion  of  the  stanza  eighty-four  thousand  persons 
obtained  Comprehension  of  the  Law.  The  god  Matthakundall  was 
established  in  the  Fruit  of  Conversion ;  likewise  Adinnapubbaka,  who 
devoted  his  great  wealth  to  the  religion  of  Buddha.    (37) 

Book  I.    Story  3.    Tiasa  the  Fat,  Xnder.^® 

ILLUSTBATING  STANZAS  3-4-3-4. 

Tissa,  a  son  of  the  sister  of  Buddha's  father,  became  a  monk  late  in 
life.  He  lived  well  on  the  Buddha's  alms,  and  spent  most  of  his  time 
sitting  in  smoothed  garments  in  the  Buddha's  own  room.  He  grew  to 
be  &t  and  well-liking.  One  day:-he  so  far  presumed  on  his  kinship 
with  the  Buddha  as  to  snub  some  monks  who  came  to  pay  their  re- 
jects. The  monks  resented  this;  whereupon  the  Elder,  informing 
them  who  he  was,  threatened  to  extirpate  their  whole  race,  and  went 
and  complained  to  the  Buddha.  The  latter,  after  asking  him  a  few 
questions  about  his  behavior,  told  him  that  he  was  in  the  wrong,  and 
directed  him  to  apologize  to  the  monks.  This  he  refused  to  do.  The 
monks  remarked  that  he  was  strangely  obstinate  and  intractable; 
whereupon  the  Buddha,  informing  them  that  it  was  not  the  first  time 
he  had  so  conducted  himself  related  the  following  story  of  the  past: 
(37-9) 

Devala  and  N&rada.  Once  upon  a  time,  when  Brahmadatta  reigned 
at  Benares,  two  ascetics,  Devala  and  Narada,  obtained  lodging  for  the 
night  in  Potter's  HalL  After  N&rada  had  lain  down,  Devala,  in  order 
to  start  a  quarrel,  lay  down  in  the  door- way.  N&rada,  having  occasion 
to  go  out  during  the  night,  trod  on  Devala's  matted  locks.  Devala 
then  changed  his  posture,  putting  his  head  where  his  feet  had  been. 
When  N&rada  returned,  he  trod  on  his  neck.  In  spite  of  Nftrada's 
protests  that  it  was  all  an  accident,  Devala  cursed  him,  saying,  "  When 

»•  a.  Rogers,  pp.  18-24. 


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490  PROCEEDINGS  OF  THE  AMEBICAN  ACADEMT. 

the  sun  rises  to-morrow  may  your  head  split  into  seyen  pieces.'' 
N&rada  then  pronounced  the  curse,  "  When  the  sun  rises  to-morrow 
may  the  head  of  the  guilty  person  split  into  seven  pieces ; "  but  fore- 
seeing that  the  curse  would  ML  upon  Devala,  he  took  pity  on  him  and 
by  his  supernatural  power  prevented  the  sun  fix>m  rising.     (39-41) 

The  people,  who  were  unable,  by  reason  of  the  darkness,  to  pursue 
their  wonted  occupations,  went  to  the  king  and  begged  him  to  make 
the  sun  rise  for  them.  The  king,  after  surveying  his  own  actions  and 
perceiving  that  he  had  been  guilty  of  no  sin,  concluded  that  the  dark- 
ness must  have  been  caused  by  a  quarrel  of  the  monks.  He  learned 
the  circumstances  of  the  quarrel  from  Nftrada,  who  told  him  that 
Devala  might  escape  the  consequences  of  the  curse  by  begging  his 
pardon.  The  king  pleaded  with  Devala  to  do  this;  but  the  latter 
obstinately  refused  until  finally  the  king,  losing  his  patience,  forcibly 
compelled  him  to  do  sa  Narada  forgave  him,  but  said  to  the  king, 
''Since  this  man  did  not  beg  my  pardon  of  his  own  free  will,  take  him 
to  the  pond  near  the  city,  place  a  lump  of  clay  on  his  head,  and  make 
him  stand  in  the  water  up  to  his  neck.  He  then  said  to  Devala,  "  I 
will  send  forth  my  magical  power  and  cause  the  sun  to  rise ;  at  that 
moment  duck  in  the  water,  rise,  and  go  your  way."  As  soon  as  the 
sun's  rays  touched  Devala,  the  lump  of  clay  split  into  seven  pieces ; 
whereupon  he  ducked  in  the  water,  rose,  and  made  his  escapa     (41-3) 

"At  that  time,"  said  the  Teacher,  "  Ananda  was  the  king,  Tissa  was 
Devala,  and  I  was  N&rada.  At  that  time  too  he  was  just  as  obsti- 
nate." And  admonishing  Tissa,  he  spoke  Stanzas  3-4.  At  the  con- 
clusion of  the  discourse,  a  hundred  thousand  monks  obtained  the 
Fruits.  The  multitude  derived  profit  from  the  instruction  given,  and 
the  obstinate  Elder  became  amenable  to  discipline.    (43-^) 

Book  I.    Story  4.    Ka)l,  the  Ogress. 

ILLUSTRATING  STANZA  6-5. 

The  only  son  of  a  widow  did  all  the  &rm  and  household  work,  and 
cared  for  bis  mother  to  boot.  One  day  the  mother  proposed  to  pro- 
cure him  a  wife.  The  son  protested  that  he  was  able  to  care  for  his 
mother  himself,  but  finally  told  her  of  a  young  woman  that  suited  him 
and  allowed  her  to  bring  her  home  and  install  her  in  the  house.  She 
turned  out  to  be  barren.  Thereupon  the  mother  proposed  to  procure 
him  another  wife.  The  son  objected.  The  barren  wife  overheard  the 
discussion,  and  fearing  that  she  might  be  supplanted  by  a  wife  of  their 
selection,  procured  him  another  wife  herself    (**-^) 

It  then  occurred  to  the  barren  wife  that  if  her  rival  bore  a  child  she 


k 


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BURUN6AME. — BUDDHAQHOSA's  DHAMMAPADA   COMMENTARY.        491 

would  become  sole  mistrees  of  the  household.  Accordingly  she  said  to 
the  new  wife,  "As  soon  as  you  've  conceived,  let  me  know."  To  this 
the  other  agreed,  and  when  she  conceived,  told  the  barren  wife.  The 
latter  mixed  a  drug  in  her  rival's  food,  and  caused  an  abortion.  After 
this  had  happened  twice,  the  new  wife,  on  the  advice  of  the  women  of 
the  neighborhood,  held  no  further  communication  with  her  fellow. 
The  latter,  suddenly  discovering  that  her  rival  was  great  with  child, 
employed  the  same  tactics  as  before,  with  the  result  that  she  killed 
both  child  and  mother.     (4S-7) 

Just  before  the  mother  died,  she  uttered  the  prayer  that  she  might 
be  reborn  as  an  Ogress,  able  to  devour  the  children  of  her  persecutor. 
Thereafter,  in  three  successive  existences,  the  fruitful  and  the  barren 
wife  returned  hatred  for  hatred.    (47) 

The  Fruitful  Wife  was  first  reborn  as  a  Gat.  The  Barren  Wife  was 
reborn  as  a  Hen.  The  Gat  ate  the  eggs  of  the  Hen,  who  prayed  that 
in  her  next  existence  she  might  be  able  to  devour  the  o£fspring  of  her 
enemy.    (48) 

The  Bsurren  Wife,  at  the  end  of  her  existence  as  a  Hen,  was  reborn 
as  a  Leopardess.  The  Fruitful  Wife,  at  the  end  of  her  existence  as  a 
Cat,  was  reborn  as  a  Doe.  Thrice  the  Doe  brought  forth  young,  and 
thrice  the  Leopardess  went  and  devoured  the  Doe's  offspring.  The 
Doe  prayed  that  in  her  next  existence  she  might  be  able  to  devour  the 
offspring  of  her  enemy.    (48) 

The  Fruitful  Wife,  at  the  end  of  her  existence  as  a  Doe,  was  reborn 
as  an  Ogress.  The  Barren  Wife,  at  the  end  of  her  existence  as  a 
Leopardess,  was  reborn  at  Savatthi  as  an  Heiress.  The  Ogress  de- 
voured the  first  and  the  second  child  of  the  Heiress ;  but  when  the  latter 
was  about  to  be  delivered  of  her  third  child,  she  eluded  her  enemy  by 
retiring  to  the  house  of  her  &ther.  Here  she  was  safely  delivered  of  a 
son.  A  few  da3rs  later,  while  the  mother  was  sitting  in  the  grounds  of 
the  Monastery,  suckling  the  child,  she  saw  the  Ogress  approaching. 
The  terrified  mother,  seizing  the  child  in  her  arms,  fled,  closely  pursued 
hyi  the  Ogress,  into  the  very  presence  of  the  Teacher.     (48-50) 

When  the  Teacher  learned  the  circumstances  of  the  quarrel,  he  said 
to  the  Ogress  :  "  Why  do  you  return  hatred  for  hatred  ?  Love  your 
enemies ;  **  and  he  pronounced  Stanza  5,  at  the  conclusion  of  which  the 
Ogress  was  established  in  the  Fruit  of  Conversion.     (50-51) 

The  Teacher  said  to  the  mother,  "  Give  your  child  to  this  Ogress." 
"  I  am  afiraid  to.  Venerable  sir."  "  Be  not  afi^id ;  you  have  nothing  to 
fear  firom  her."  The  mother  obeyed.  The  Ogress  kissed  the  child, 
caressed  him,  returned  him  to  the  arms  of  his  mother,  and  began  to 
weep.    The  Teacher,  learning  that  she  had  suffered  greatly  in  the 


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492  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

past,  comforted  her,  and  directed  the  Heiress  to  take  her  home  with 
her  and  care  for  her  tenderly.  Thenceforth  tiiey  befriended  each  other 
in  every  possible  way.  It  was  Kali  who  established  the  Eight  Ticket- 
Foods,  which  are  kept  up  even  to  this  day.     (51-3) 

Book  L    Story  5.    The  Monks  of  Kosambi.  17 

ILLUSTRATINO  STANZA  6=6. 

Two  monks  with  a  retinae  of  five  hundred  monks  each  resided  at 
Eosambi ;  one  a  stadent  of  the  Vinaya,  the  other,  of  the  Suttas.  One 
day  the  latter  committed  the  sin  of  leaving  water  standing  in  the  bath- 
room,  for  which  he  was  reproved  by  his  brother,  who,  however,  on 
being  informed  that  the  offense  was  unintentional,  assured  him  that  he 
was  guiltless.  The  Vinaya  scholar  then  proceeded  to  tell  his  pupils 
that  the  Sutta  scholar  had  committed  sin  and  had  no  conscience  about 
it.  The  latter,  hearing  of  this,  declared  the  former  to  be  a  liar,  and 
was  shortly  thereafter  excommunicated.  Then  ensued  a  quarrel  in 
which  monks,  nuns,  unconverted  persons,  and  deities  from  Uie  lowest 
heaven  to  the  highest  were  involved.     (53-4) 

The  circumstances  of  the  quarrel  among  the  monks  were  reported  to 
Buddha,  who  sent  word  to  them  to  patch  up  their  differences.  Twice 
he  did  this,  and  twice  the  answer  came  back  that  they  would  not. 
Then  he  went  in  person,  pointed  out  to  both  fiwjtions  the  wrong  in- 
volved in  their  actions,  and  laid  down  rules  of  conduct  for  their 
observance.  Hearing  that  they  were  quarrelling  again,  he  went  to 
them  the  second  time,  urged  them  to  be  united,  and  spoke  to  them 
long  and  earnestly  on  the  unprofitableness  of  discord,  illustrating  his 
remarks  by  telling  the  Latukika  Jataka,  the  Sammodamana  Jataka,^® 
and  the  story  of  Brahmadatta,  Dighati,  and  Dlghavu.^®  But  in  spite 
of  his  best  efforts,  he  was  unable  to  restore  harmony.     (^*-€) 

Disheartened  by  his  &ilare  to  reconcile  their  differences,  he  left 
them,  went  quite  alone  to  the  village  of  Balaka  the  salt-maker,  where 
he  discoursed  to  the  Elder  Bhagu  on  the  solitary  life ;  thence  to  Ea^ 
em  Bamboo  Deer-park  where  he  discoursed  to  the  three  noble  youths 
on  the  bliss  to  be  found  in  the  sweets  of  concord  ;  and  from  there  to 
Protected  Forest,  where  he  spent  the  rainy  season  pleasantly,  attended 
by  the  elephant  Parile3ryaka.     (56-7) 

*»  Cf.  Ja.  iii.  486-490. 

w  The  text  says  simply  "  Vattaka-jataka, "  i.  e.,  "Quail  Jataka,"  of 
which  there  are  several. 

"  Vmaya  i.  342-349  (translated  SBE.  xvii,  293-305). 


|d  by  Google 


BURUNGAME.  —  BUBDHAGHOSA's  PHAlfMAPADA   COMMENTARY.      493 

The  lay  brethren  of  Eosambi,  learning  the  reason  of  the  Teacher's 
departure,  snubbed  the  monks  until  they  came  around  to  a  proper  view 
of  things  and  asked  to  be  pardoned  This  the  laymen  declined  to  do 
until  the  monks  apologized  to  the  Teacher.  But  as  the  rainy  season 
was  then  at  its  height,  they  were  unable  to  go  to  the  Teacher,  and  had  a 
very  unpleasant  time  as  a  result  The  Teacher,  however,  spent  the 
time  pleasantly,  attended  by  an  elephant,     (fil) 

Buddha,  the  Elephant,  and  the  Monkey.  A  noble  elephant  named 
P&rilejryaka,  who  had  left  his  herd  on  account  of  the  excessive  annoy- 
ances to  which  he  had  been  subjected,  came  to  Protected  Forest,  paid 
obeisance  to  the  Teacher,  swept  the  ground  with  the  branch  of  a  tree, 
gave  the  Teacher  water  to  drink,  heated  water  for  his  bath,  and 
brought  him  wild  fruits.  When  the  Teacher  went  to  the  village  to 
collect  alms,  the  elephant  took  his  bowl  and  robe,  put  them  on  the  top 
of  his  head,  and  accompanied  him  as  &r  as  the  village.  Then  he  gave 
him  his  bowl  and  robe,  and  waited  right  there  until  he  returned ; 
whereupon  he  advanced  to  meet  him,  took  his  bowl  and  robe  as  before, 
deposited  them  in  his  place  of  abode,  performed  the  usual  courtesies, 
and  &nned  him  with  the  branch  of  a  tree.  During  the  night  he 
paced  back  and  forth  in  the  interstices  of  the  forest  with  a  big  club  in 
his  trunk,  protecting  the  Teacher  from  attacks  of  beasts  of  prey. 
(Thus  the  forest  came  to  be  called  Protected  Forest.)  At  sunrise  he 
gave  him  water  to  rinse  his  mouth  with,  and  in  the  same  manner 
performed  all  the  other  duties.     (57-9) 

The  elephant's  courteous  attentions  to  the  Teacher  excited  in  a 
monkey  the  desire  to  do  likewise.  One  day  he  found  some  honey  and 
presented  it  to  the  Teacher.  The  latter  accepted  it,  but  refrained 
from  eating  it  It  turned  out  that  there  were  some  insects'  eggs  in  it 
These  the  monkey  carefully  removed ;  the  Teacher  then  ate  the  honey. 
The  monkey  was  so  delighted  that  he  leaped  from  one  branch  to 
another  and  danced  about  in  great  glee.  A  branch  broke,  down  he  fell 
on  the  stump  of  a  tree,  and  a  splinter  pierced  his  body.  So  he  died. 
But  because  of  his  faith  in  the  Teacher  he  was  reborn  in  the  world  of 
the  Thirty-three.    (59-60) 

When  it  became  known  thatjbhe  Teacher  was  living  there,  Anfttha- 
pindika  and  others  requested  Ananda  to  procure  for  them  the  privi- 
lege of  hearing  the  Teacher.  Ananda,  accompanied  by  five  hundred 
monks,  went  to  the  forest  Not  knowing  how  Buddha  would  feel 
about  receiving  so  many  visitors,  he  left  the  monks  outside,  and 
approached  the  Teacher  alone.  P&rileyyaka  assumed  a  threatening 
attitude,  but  abandoned  it  at  the  command  of  his  master.  Learning 
that  Ananda  had  come  with  five  hundred  monks,  Buddha  instructed 


Digitizi 


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494  PROCEEDINGS   OF   THE   AMERICAN   ACADEMY. 

him  to  ask  them  to  come  in.  He  tiien  spoke  to  them  in  praise  of  the 
solitary  life,  pronouncing  Stanzas  328-330,  at  the  conclusion  of  which 
all  were  established  in  Arahatship.  Ananda  announced  the  request  of 
Anathapindika  and  the  others,  and  Buddha  bade  the  monks  take  bowl 
and  robe  and  set  out.     (60-e2) 

Parileyyaka  went  and  stood  cross- wise  on  the  road.  The  Teacher, 
knowing  that  he  wished  to  give  alms  to  the  monks,  ordered  them  to 
wait.  The  elephant  went  into  the  forest,  gathered  a  great  quantity  of 
fruit,  and  presented  it  to  the  monks.  When  they  had  finished  eating, 
Buddha  took  bowl  and  robe  and  set  out  The  elephant  again  went 
and  stood  cross- wise  on  the  road.  Buddha,  knowing  that  he  wished  to 
hinder  his  departure,  reproved  him.  The  elephant  thrust  his  trunk  in 
his  mouth  and  retreated  weeping.  When  Uiey  reached  the  village, 
Buddha  ordered  the  elephant  to  go  no  further.  As  Buddha  passed  out 
of  sight  the  elephant's  heart  broke,  and  he  died ;  but  because  of  his 
faith  in  the  Teacher  he  was  reborn  in  the  world  of  the  Thirty-three. 

(62-3) 

When  the  Teacher  arrived  at  S&vatthi,  the  monks  of  Kosambi  went 
thither  to  beg  his  pardon.  The  king  of  Eosala  and  An&thapindika 
threatened  to  keep  them  out,  but  were  dissuaded  from  so  doing.  Bud- 
dha humiliated  the  quarrelsome  monks  by  assigning  them  places  sepa- 
rate from  the  others ;  and  when  they  threw  themselves  at  his  feet  and 
begged  for  pardon,  he  reproved  them  for  their  sinful  conduct,  related 
the  story  of  Brahmadatta,  Dighati,  and  Digh&vu  ^  once  more,  and 
pronounced  Stanza  6,  at  the  conclusion  of  which  the  assembled  monks 
were  established  in  Uie  Fruits.    (63-5) 


Book  I.    Story  6.    ClUa  Kft}a  and  MaU  Kft}a.21 

ILLUSTRATING  STANZAS  7-8  «  7-8. 

Gula  Kftla,  Majjhima  Eala,  and  Maha  Eala,  were  three  brothers 
who  lived  in  Setavya.  Gula  Eala  and  Maha  EsJai  the  youngest  and 
oldest  respectively,  drove  a  caravan,  and  Majjhima  Eala  sold  the  wares. 
One  day  the  caravan  halted  between  Savatthi  and  Jetavana,  and 
Maha  Eala,  leaving  the  wagons  in  charge  of  Gtila  Ea}a,  went  and 
listened  to  the  Teacher.  He  was  so  affected  by  the  discourse  that  he 
resolved  to  become  a  monk,  turned  over  his  property  to  GtOa  Eala, 
and  in  spite  of  the  latter's  protests  carried  out  his  resolution.    Gtda 

*•  See  note  19,  p.  492.    The  text  calls  this  story  "  Devakoeambika-jataka;" 
another  instance  of  the  loose  use  of  titles. 
«*  a.  Rogers,  pp.  25-31. 


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BUBUNGAME.  —  BUBDHAOHOSA's  DHAIJMAPADA   COMMENTARY.      495 

Eala  also  became  a  monk,  but  with  the  intention  of  leaving  the  Order 
and  taking  his  brother  with  him.    (66-6) 

After  Mah&  K&la  had  been  professed,  he  inquired  of  the  Teacher 
how  many  were  the  Burdens  of  tiie  Religious  Life,  and  upon  being  told 
that  there  were  two :  namely,  the  Burden  of  Study  and  the  Burden  ot 
Insight,  he  chose  the  latter  as  being  better  suited  to  his  advanced 
years.  He  had  the  Teacher  instruct  him  in  the  ascetic  practices  that 
one  performs  in  a  cemetery,  and  at  the  end  of  the  first  watch,  while 
the  others  were  asleep,  he  went  to  the  cemetery  and  spent  the  night  in 
meditation,  returning  to  the  monastery  before  the  others  had  risen. 
(68) 

For  some  time  Mahft  Eftla  followed  the  routine  laid  down  for  him  by 
the  cemetery-attendant  without  success.  Meanwhile  Gula  E&la  won- 
dered at  his  brother's  perseverance  and  pined  for  son  and  wifa 
Finally  Maha  Kala  attained  Arahatship  by  contemplating  the  destruc- 
tion by  fire  of  the  corpse  of  a  beautiful  girl.     (68-71) 

At  this  time  the  Teacher,  accompanied  by  the  Congregation  of 
Monks,  visited  Setavya.  Maha  K&la  sent  Ctda  E&la  to  attend  to  the 
seating  arrangements.  Gtlla  E&la's  wives  subjected  him  to  such 
ridicule  that  he  then  and  there  left  the  Order.  Maha  E&la's  wives 
then  laid  plans  to  recover  their  husband.  Now  Gula  E&la  had  only 
two  wives,  while  Mah&  E&la  had  eight  The  monks  therefore  openly 
expressed  the  opinion  that  Mah&  Eftla  would  succumb  to  their  wiles. 
The  Teacher,  however,  told  them  that  they  were  wrong ;  and  compar- 
ing Gula  E&la  to  a  feeble  tree  standing  on  the  edge  of  a  precipice,  and 
Mahft  Eftla  to  a  rocky  mountain,  pronounced  Stanzas  7-8.  Mahft 
Eftla  escaped  fix)m  the  clutches  of  his  wives  by  soaring  through  the 
air.  At  the  conclusion  of  the  stanzas,  the  assembled  monks  were 
established  in  the  Fruits.     (71-7) 

Book  L    Story  7.    Devadatta. 

ILLUSTRATING  STANZAS  9-10  —  9-10. 

One  day  the  Venerable  Sftriputta  preached  a  sermon  on  the  two-fold 
duty  of  giving  alms  and  urging  others  to  do  likewise.  Thereupon  a 
lay  brother  invited  him  to  bring  his  retinue  of  a  thousand  monks  and 
take  a  meal  with  him.  Sftriputta  accepted  the  invitation ;  and  the  lay 
brother,  with  the  assistance  of  the  inhabitants  of  Rftjagaha,  each  of 
whom  responded  to  his  request  to  give  alms  according  to  his  ability, 
entertained  the  monks  handsomely.  Now  a  certain  householder  had 
given  the  lay  brother  a  costly  robe,  with  the  understanding  that  if  the 
supply  of  food  proved  insufficient,  he  was  to  sell  it  and  buy  more  food 


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496  PROCEEDINGS  Oi  THE  AMERICAN  ACADEMY. 

with  the  proceeds;  otherwise  he  might  give  it  to  whomsoever  he 
wished  It  tamed  out  that  there  was  an  ample  supply  of  food,  and 
the  question  arose  what  to  do  with  the  robe.  The  lay  brother  sub- 
mitted the  question  to  popular  vote,  with  the  result  that  as  between 
Sariputta  and  Devadatta  there  was  a  majority  of  four  in  &vor  of  the 
latter.  But  as  soon  as  Devadatta  put  on  the  robe  everybody  remarked 
that  it  was  not  at  all  becoming  to  him,  and  would  have  suited  Sari- 
putta much  better.  This  incident  was  reported  to  the  Teacher,  who 
replied  that  it  was  not  the  first  time  Devadatta  had  worn  unbecoming 
robes,  and  then  told  the  following  story  of  the  past :    (77-80) 

The  Elephant  Hunter  and  the  Noble  Elephant.  Once  npon  a  time, 
when  Brahmadatta  reigned  at  Benares,  there  lived  an  elephant  hunter 
who  made  his  living  by  killing  elephants  and  selling  their  tusks.  One 
day  he  saw  thousands  of  elephants  go  into  a  forest  and  £all  on  their 
knees  before  some  Private  Buddhas.  Gonduding  that  it  was  the 
yellow  robe  that  inspired  their  reverence,  he  went  to  a  pond  where  a 
Private  Buddha  was  bathing,  stole  his  robes,  and  went  and  sat  down 
on  the  elephant  path  with  spear  in  hand  and  upper  robe  drawn  over 
the  head.  The  elephants,  supposing  that  he  was  a  Private  Buddha, 
made  obeisance  to  him  and  went  on  their  way.  The  last  elephant  to 
come  he  killed  with  a  thrust  of  his  sx>ear ;  then,  removing  the  tusks, 
he  buried  the  rest  of  the  carcass,  and  departed.     (80-81) 

A  little  while  later,  the  Future  Buddha  was  born  as  a  young  ele- 
phant, and  in  the  course  of  time  he  became  the  leader  of  the  herd. 
The  hunter  was  still  engaged  in  his  nefarious  business.  The  noble 
creature,  observing  the  diminution  of  his  herd,  and  suspecting  who 
was  at  the  bottom  of  it,  sent  the  other  elephants  on  ahead  and  brought 
up  the  rear  himself,  walking  with  a  long,  slow  strida  The  hunter 
threw  his  spear  at  him  and  darted  behind  a  trea  The  elephant  re- 
sisted the  temptation  to  encircle  man  and  tree  with  his  trunk  and 
crush  the  offender,  and  contented  himself  with  oapng,  "  Why  did  you 
commit  so  grievous  a  sin  ?  You  have  put  on  robes  suited  to  those 
that  are  free  fix>m  the  Depravities^  but  unbecoming  to  you.''    (81-2) 

"At  that  time,"  said  the  Teacher,  "Devadatta  was  the  elephant 
hunter,  and  I  was  the  noble  elephant  This  is  not  the  first  time  he 
has  worn  unbecoming  robes."  Then  he  pronounced  Stanzas  9-10,  at 
the  conclusion  of  which  many  of  his  hearers  were  established  in  the 
Fruits.    (82-3) 


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BURLINGAME.  —  BUDDHAGHOSA's   DHAMMAPADA  COMMENTARY.       497 


Book  I.    Story  8.    The  Chief  Disciples. 

I LLUSTRATING   STAK ZAS    11-12=11-12. 

The  Future  Buddha,  after  receiving  recognition  at  the  hands  of 
twenty-four  Buddhas  beginning  with  Dipankara,  and  after  fulfiliitigtbe 
Perfections,  was  reborn  in  the  Tusita  heaven.  Urged  by  the  deities  to 
save  the  world,  he  made  the  Five  Great  Observations,  was  born  of 
Queen  Maya,  passed  his  youth  in  the  enjoyment  of  great  magnificence 
in  three  mansions  suited  to  the  three  seasons,  beheld  the  Four  Omin- 
ous Sights,  resolved  to  become  a  monk,  renounced  son  and  wife,  was 
greeted  by  Kisa  Gotami,  made  the  Great  Retirement  and  the  Great 
Struggle,  defeated  the  hosts  of  Mara,  and  attained  omniscience  under 
the  Bo-tree.  At  the  request  of  Brahma  he  proclaimed  the  Law  and 
converted  the  Five  Monks,  Yasa  and  Fifty-four  Companions,  the  Thirty 
Young  Nobles,  and  the  Three  Brothers ;  after  which  he  visited  King 
Bimbisara  and  accepted  from  him  the  grant  of  Bamboo  Grove  monas- 
tery, where  he  took  up  his  abode  and  Sariputta  and  Moggallana  came 
to  him.     (83^) 

Upatissa  (Sariputta)  and  Kolita  (Moggallana)  were  born  on  the 
same  day  and  brought  up  in  great  luxury.  They  acquired  a  sense  of 
the  impermanence  of  things  while  witnessing  Mountain-top  festivities, 
and  were  for  a  time  disciples  of  Safijaya.  Desiring  something  more 
than  he  could  give  them,  they  travelled  about  India  listening  to  vari- 
ous teachers,  and  were  converted  to  the  religion  of  Buddha  by  Assaji. 
After  making  an  unsuccessful  attempt  to  persuade  Safijaya  to  accom- 
pany them,  they  went  to  the  feet  of  Buddha,  who  admitted  and  pro- 
fessed them  as  members  of  the  Order  and  made  them  his  chief 
disciples.     (88-96) 

The  other  disciples  accuse  Buddha  of  showing  favoritism  in  bestow- 
ing the  highest  dignity  on  new-comers  and  passing  over  what  they 
allege  to  be  the  prior  claims  of  the  Five  Monks,  Yasa  and  his  Fifty- 
fuar  Companions,  the  Thirty  Young  Nobles,  and  the  Three  Brothers. 
Buddha  denies  the  charge  and  declares  that  it  is  his  wont  to  bestow  on 
every  man  that  for  which  he  has  made  his  wish.  By  way  of  illustra- 
tion he  relates  the  following  stories  of  the  past :     (96-7) 

Maha  Kala  and  Cula  Kala.  Anuakondafina  in  his  existence  as 
Cfda  Kala  bestowed  the  gift  of  first-fruits  nine  times  on  the  Buddha 
Vipassi  and  for  seven  days  bestowed  great  largess  on  the  Buddha 
Fadumuttara,  making  the  wish  that  he  might  be  the  first  to  compre- 
hend the  Law.  The  fact  of  his  attaining  this  distinction  was  no  proof 
of  favoritism,  but  rather  the  fruit  of  that  earnest  wish.     (97-9) 

VOL.  XLV,  —  32 


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J 


498  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

Tasa  and  his  Fifty-foar  Companions  perfonned  many  meritorioQS 
deeds  in  the  dispensation  of  a  previous  Buddha,  making  the  wish  that 
they  might  thereby  attain  Aiahatship.  In  a  later  dispensation  they 
banded  themselves  together  for  the  performance  of  good  works,  and 
went  about  caring  for  the  dead  bodies  of  paupers.  One  day  they  came 
upon  the  dead  body  of  a  pregnant  woman.  They  carried  the  body  to 
the  cemetery,  Yasa  and  four  others  undertook  the  duty  of  cremating  it, 
and  the  rest  returned  to  the  village.  While  Yasa  was  engaged  in 
turning  the  body  over  and  over,  he  acquired  a  sense  of  the  impurity  of 
the  body.  This  he  communicated  to  the  four  others,  who  in  turn 
communicated  it  to  the  rest.  Yasa  also  went  and  communicated  it  to 
his  mother,  his  &ther,  and  his  wife.  It  was  due  entirely  to  this  that 
Yasa  obtained  in  the  women's  apartments,  the  disposition  of  mind  re- 
quisite to  Conversion  and  that  he  and  the  others  developed  Specific 
Attainment.     (99-100) 

The  Thirty  Toung  Nobles  made  their  wish  to  attain  Arahatship 
under  previous  Buddhas  and  performed  works  of  merit  In  a  later  dis- 
pensation they  gave  themselves  up  to  the  pleasures  of  sense,  but  on 
hearing  the  admonition  addressed  to  Tundila  they  kept  the  Five 
Precepts  for  seventy  thousand  years.     (100) 

The  Three  Brothers,  Uruvela  Kassapa,  Nadi  Eassapa,  and  Oaya 
Kassapa,  entertained  the  Buddha  Phussa,  their  oldest  brother,  and 
made  the  wish  to  attain  Arahatship  thereby.  After  undergoing  rebirth 
as  gods  during  ninety-two  cycles  of  time,  they  obtained  the  fulfilment 
of  their  wish.  (At  that  time  Bimbisftra  was  their  superintendent,  the 
lay  brother  Vis&kha  their  steward,  and  the  three  ascetics  with  matted 
locks  were  the  three  royal  princes.)  Their  serving  men  had  a  very 
different  experience.  The  latter  diverted  to  their  own  use  the  food 
they  had  been  ordered  to  bestow  in  alms.  After  undergoing  rebirth  as 
ghosts  during  four  Buddha-intervals,  they  came  and  begged  food  and 
drink  of  the  Buddha  Kakusandha,  who  referred  them  to  the  Buddha 
Konagamana,  who  referred  them  to  the  Buddha  Kassapa,  who  com- 
forted them  with  the  assurance  that,  in  the  dispensation  of  his  suc- 
cessor Gotama,  their  kinsman  Bimbis&ra  would  be  king,  and  would 
obtain  relief  for  them  by  transferring  to  them  the  merit  he  would  earn 
by  giving  alms  to  the  Teacher.  Thus  at  last  they  obtained  celestial 
food,  drink,  and  robes,  and  became  gods.     (100-104) 

Sarada  and  Sirivaddha.  S&riputta  and  Moggall&na  were  bom  as 
Sarada  and  Sirivaddha  respectively  at  the  time  when  the  Buddha 
AnomadassI  appear^  in  the  world.  Sarada  retired  fix>m  the  world 
with  seventy-four  thousand  followers,  entertained  AnomadassI,  and 
held  the  flower  parasol  over  him  for  seven  days,  making  the  wish  that 


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BURUNGAME.  —  BUDDHAGHOSA's   DHAMMAPADA   COMMENTARY.      499 

he  might  thereby  become  the  chief  disciple  of  a  Buddha.  Upon  receiv- 
ing assarance  that  his  wish  would  bd  fulfilled,  he  sent  word  to  Siri- 
vaddha  to  make  his  wish  for  the  place  of  second  disciple.  Thereupon 
Sirivaddha  entertained  Anomadassi  and  made  his  wish.  So  what 
Sariputta  an^  Moggallana  obtained  was  only  that  for  which  they  had 
made  their  wish  under  Anomadassi.     (10^112) 

Sariputta  and  Moggallana  then  related  their  experiences  from  the 
Mountain-top  festivities  to  their  final  interview  with  Safijaya.  Buddha 
then  contrasted  the  attitude  of  Sanjaya  with  that  of  his  own  faithful 
followers,  and  pronounced  Stanzas  11-12,  at  the  conclusion  of  which 
many  of  his  hearers  were  established  in  the  Fruits.    (113-114) 

Book  I.    Story  9.    Nanda,  Elder.  28 

ILLUSTRATINO  STANZAS   13-14  -  13-14. 

After  the  events  related  in  the  last  story,  Buddha  visited  his  father 
Suddhodana  and  established  him  in  the  Fruits  of  the  First  Two  Paths 
by  pronouncing  Stanzas  168-169.  On  the  following  day,  while  the  fes- 
tivities connected  with  Nanda's  marriage  were  going  on,  Buddha  went 
into  the  house  to  collect  alms,  placed  his  bowl  in  Nanda's  hands, 
wished  him  happiness,  and  then  went  out  without  taking  the  bowl. 
So  profound  was  Nanda's  reverence  for  the  Teacher  that  he  did  not 
dare  ask  him  to  take  the  bowl ;  but,  expecting  that  the  Teacher  would 
ask  for  it  sooner  or  later,  he  followed  him  first  to  the  head  of  the  stairs, 
then  to  the  foot  of  the  stairs,  then  to  the  court-yard.  Here  Nanda 
wished  to  turn  back.  But  the  Teacher  went  straight  ahead,  and 
Nanda,  much  against  his  will,  followed.  When  Nanda's  bride,  Country 
Beauty,  learned  what  had  happened,  she  ran  after  him  as  fast  as  she 
could,  with  tears  streaming  down  her  face  and  hair  half  combed,  and 
begged  him  to  return.  This  caused  a  quaver  in  Nanda's  heart,  but 
the  Teacher  still  gave  no  indication  that  he  wished  to  have  the  bowl 
returned,  and  Nanda  kept  right  on.  When  they  reached  the  Monas- 
tery, the  Teacher  said  :  "  Nanda,  would  you  like  to  become  a  monk  ? " 
That  was  the  last  thing  in  the  world  Nanda  wanted  to  do  just  then ; 
but  his  reverence  for  the  Teacher  was  so  profound  that  he  promptly 
said  "Yes."  Thereupon  the  Teacher  admitted  him  to  the  Order. 
(115-116) 

After  receiving  his  son  Rahula  into  the  Order,  and  establishing  his 
father  in  the  Fruit  of  the  Third  Path,  the  Teacher,  accompanied  by  the 
Congregation  of  Monks,  went  into  residence  at  Jetavana.    By  this  time 

»  Of.  Ja.  ii.  92-4. 


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500  PBOCEEDINQS  OF  THE  AMERICAN  ACADEMY. 

Nanda  had  become  thoroughly  dissatisfied  with  the  Religions  Life^ 
and  one  day  he  told  his  brethren  that  he  was  going  to  return  to  the 
World.  When  this  was  reported  to  the  Teacher,  he  asked  Nanda 
what  was  the  matter.  Nanda  told  him  that  he  was  so  deeply  in 
love  with  Country  Beauty  that  he  could  not  keep  his  mind  on  his  re- 
ligious duties.  The  Teacher,  taking  him  by  the  arm,  led  him  to  a 
burnt  field,  and  showed  him  a  singed  monkey  that  had  lost  ears,  nose, 
and  tail,  sitting  on  a  charred  stump ;  then,  by  his  supernatural  power, 
conducting  him  to  the  world  of  the  Thirty-three,  he  showed  him  five 
hundred  pink-footed  celestial  ^nymphs.  Then  said  the  Teacher: 
"  Nanda,  which  do  you  regard  as  being  the  more  beautiful.  Country 
Beauty  or  these  five  hundred  pink-footed  celestial  nymphs  ? "  Nanda 
replied :  "  Venerable  sir.  Country  Beauty  is  as  far  inferior  to  these 
n3rmphs  as  she  is  superior  to  that  singed  monkey."  "  Cheer  up,  Nanda  ; 
I  guarantee  that  you  will  win  these  n)rmphs  if  you  only  persevere  in 
the  Religious  Life."  The  Teacher  allowed  it  to  become  generally 
known  that  he  had  made  this  promise  to  Nanda ;  whereupon  the  latter 
was  subjected  to  such  intense  ridicule  by  his  brethren  that  he  returned 
to  his  religious  duties  with  redoubled  energy.  In  a  short  time  he  at- 
tained Arahatship;  whereupon  he  went  to  the  Teacher  and  said, 
"  Venerable  sir,  I  release  the  Exalted  One  from  his  promise."  "  But," 
said  the  Teacher,  "  when  you  attained  Arahatship,  at  that  moment  I 
was  released  from  my  promise."     (116-121) 

One  day  Nanda  told  the  other  monks  that  he  no  longer  had  any 
desire  to  go  back  to  the  life  of  a  householder.  The  monks  reported 
this  statement  to  the  Teacher,  who  compared  Nanda's  former  state  to 
that  of  an  ill-thatched  house,  and  his  latter  state  to  that  of  a  well- 
thatched  house,  and  pronounced  Stanzas  13-14,  at  the  conclusion  of 
which  many  of  his  hearers  were  established  in  Fruits.     (121-2) 

The  monks  were  amazed  at  the  Teacher's  complete  success  in  win- 
ning Nanda's  obedience  by  employing  the  nymphs  as  a  lure.  But  the 
Teacher  said :  "  This  is  not  the  first  time  Nanda  has  been  won  to 
obedience  by  the  lure  of  the  opposite  sex.  The  same  thing  happened 
once  before."     And  he  told  the  following  tale  of  the  pcist :  (122-3) 

Kappata  and  the  Donkey.  Once  upon  a  time,  when  Brahmadatta 
reigned  at  Benares,  there  lived  in  that  city  a  merchant  named  Kap- 
pata; and  he  had  a  donkey.  Every  day  the  merchant  loaded  the 
donkey  down  with  pottery  and  made  him  go  at  least  seven  leagues. 
One  day  he  made  a  trip  to  Takkasilft ;  and  while  he  was  engaged  in 
disposing  of  his  wares,  he  let  the  donkey  run  loose.  The  donkey,  see- 
ing a  female  of  his  species,  went  up  to  her.  She  greeted  him  in  a 
friendly  way  and  said,  "  Where  have  you  come  from  ? "    "  From  Ben- 


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ares."  "  On  what  errand  1 "  "  On  business."  "  How  big  a  load  do 
you  carry  1 "  "A  big  load  of  pottery."  "  How  many  leagues  do  you 
go,  cixrr)aMg  a  big  load  like  that  ? "  "  Seven  leagues."  "  In  the  vari- 
ous places  you  go  to,  do  you  have  anybody  to  rub  your  feet  and  back  1 " 
"No."  "If  that's  the  case,  you  must  have  a  mighty  hard  time." 
(Of  course  animals  don't  have  anybody  to  rub  their  feet  and  back  ;  she 
talked  the  way  she  did  simply  to  strengthen  the  bonds  of  love  between 
them.)  As  the  result  of  her  talk,  he  became  dissatisfied  with  his  job. 
After  the  merchant  had  disposed  of  his  wares,  he  returned  to  the 
donkey,  and  said,  "  Come,  Jack,  let 's  be  off."  "  You  go  yourself ;  I  'm 
not  going."  The  merchant  tried  without  success  to  persuade  him,  and 
then  said,  "  I  will  beat  you  till  I  break  every  bone  in  your  body ;  think 
that  over."  Said  the  donkey,  "  If  you  beat  me,  I  will  plant  my  fore 
feet,  and  let  fly  with  my  hind  feet,  and  knock  out  your  teeth ;  think 
that  over."  The  merchant  was  at  a  loss  to  account  for  the  donkey's 
conduct,  until  he  saw  the  female.  Then  he  changed  his  tactics  and 
said,  "  If  you  will  go  with  me,  I  will  bring  you  home  a  mate  like  that." 
**  In  that  case,"  said  the  donkey,  **  I  '11  go  home  with  you  and  travel 
fourteen  leagues  a  day  hereafter."    And  off  he  went.     (123-5) 

"At  that  time,"  said  the  Teacher,  "  Country  Beauty  was  the  female 
donkey,  Nanda  was  the  donkey,  and  I  was  the  merchant.  In  former 
times,  too,  Nanda  was  won  to  obedience  by  the  lure  of  the  female  sex." 
(125) 

Book  I.    Story  10.    Cunda,  the  Pork-butcher. 

ILLUSTRATING   STANZA    15  =  15. 

Cunda,  the  pork-butcher,  was  a  selfish,  brutal,  irreligious  man. 
After  a  course  of  evil  conduct  lasting  fifty-five  yeiirs,  he  was  attacked 
by  a  frightful  disease,  and  while  he  yet  lived,  the  Avici  hell  yawned 
before  him.  He  went  stark  mad,  and  began  to  crawl  about  the  house 
on  his  hands  and  knees,  squealing  and  grunting  like  a  pig.  His  kins- 
men ran  out  of  the  house,  barricaded  the  doors,  and  mounted  guard. 
After  he  had  raved  for  seven  days  he  died,  and  was  reborn  in  the 
Avici  hell.     (125-7) 

Some  monks  who  passed  the  house  during  his  madness  thought  that 
preparations  for  a  big  entertainment  were  in  progress,  and  so  reported 
the  matter  to  the  Teacher.  The  latter  told  them  the  real  facts  of  the 
case,  remarked  that  the  irreligious  man  sorrows  both  here  and  here- 
after, and  pronounced  Stanza  15,  at  the  end  of  which  many  were 
established  in  the  Fruits.     (127-9) 


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502  PB0CEEDIN08   OF   THE   AMERICAN   ACADEMY. 

Book  I.    Story  U.    The  Faithful  Lay  Brother. 

ILLUSTRATING  STANZA   16  -  16. 

A  certain  lay  brother  distinguished  for  his  benefiftctions  and  religions 
zeal,  was  attacked  by  mortal  illness,  and  desiring  to  hear  the  Law,  re- 
quested the  Teacher  to  send  him  some  monks.  Just  as  the  monks 
were  beginning  the  recitation,  a  host  of  deities  drove  up  in  their  chari- 
ots and  said,  "  We  would  take  you  with  us."  The  layman,  wishing  to 
hear  the  Law,  said  to  the  deities  "  Hold ; ''  whereupon  the  monks,  mis- 
taking his  meaning,  arose  and  departed.  The  layman's  children,  to 
whom  the  deities  were  invisible,  began  to  weep ;  whereupon  the  lay- 
man, to  confirm  their  faith,  performed  a  miracle,  urged  them  to  follow 
the  example  he  had  set  in  performing  good  works,  and  then,  stepping 
into  a  celestial  chariot,  was  reborn  as  a  deity.     (129-131) 

When  the  monks  told  the  Teacher  that  Uie  layman  had  refused  to 
hear  the  Law,  he  informed  them  of  the  real  fiicts  of  the  case,  assured 
them  that  the  religious  man  rejoices  both  here  and  hereafter,  and  pro- 
nounced Stanza  16,  establishing  many  in  the  Fruits.    (131-2) 

Book  I.    Story  12.    Devadatta. 

ILLUSTRATING  STANZA   17  -  17. 

The  story  of  Devadatta  from  the  time  he  retired  from  the  world  to 
the  time  he  was  swallowed  up  by  the  earth  is  related  in  detail  in  the 
Jatakas ;  ^  the  following  is  an  abridgment  of  it :    (133) 

When  the  Future  Buddha  lived  at  Anupiya  Mango-grove,  eighty 
thousand  kinsmen  observed  on  his  person  the  marks  and  characteristics 
of  a  Tathagata,  and  each  dedicated  a  son  to  his  service.  In  the  course 
of  time,  all  of  these  young  men  became  monks,  with  the  exception  of 
Bhaddiya,  Anuruddha,  Ananda,  Bhagu,  Kimbila,  and  Devadatta.  One 
day  Anuruddha's  brother  Mahftnama  went  to  Anuruddha  and  said, 
**  There  is  n't  one  of  our  &mily  that  has  become  a  monk ;  you  beoome  a 
monk,  and  I  'U  follow  your  example."     (133) 

(Now  Anuruddha  had  been  brought  up  in  softness  and  luxury,  and 
had  never  heard  the  word  isn't  Once  the  six  princes  engaged  in  a 
game  of  ball,  wagering  a  cake  on  the  result  Anuruddha  lost  and  sent 
word  to  his  mother  to  send  him  a  cake,  which  she  did.  This  happened 
three  times.  The  fourth  time  his  mother  sent  word :  "There  isn't 
cake  to  send."  The  son  replied,  "Send  me  some  isn't  cake."  The 
mother,  in  order  to  teach  her  son  a  lesson,  sent  him  an  empty  bowl 

M  Ja.  vi.  129-131;  v.  333-7;  iv.  158-9. 


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covered  with  another  empty  bowl.  The  tutelary  deities  of  the  city 
filled  the  bowl  with  celestial  cakes.  The  mother  found  out  what  had 
happened,  and  thereafter,  whenever  her  son  sent  for  cakes,  sent  him  an 
empty  bowl,  which  the  deities  filled  with  celestial  cakes.  How  could  a 
youth  who  was  ignorant  of  the  meaning  of  the  word  is  nt^  be  expected 
to  know  the  meaning  of  monk  1 )     (133-5) 

Anuruddha  replied  to  Mahanama  :  "  What  does  this  word  monk 
mean  ? "  Mahanama  told  him.  Anuruddha  replied  that  he  was  too 
delicate  to  become  a  monk.  "Well  then,"  said  Mahanama,  "learn 
farming,  and  adopt  the  life  of  a  householder."  Anuruddha  replied, 
"  What  does  this  word  farming  mean  ? "     (135-6) 

(How  could  you  expect  a  youth  to  know  the  meaning  o^  farming 
who  did  n't  know  where  rice  comes  from  ?  Once  a  discussion  arose 
among  the  three  princes  Kimbila,  Bhaddiya,  and  Anuruddha,  as  to 
where  rice  comes  from.  Kimbila  thought  it  came  from  the  granary  ; 
Bhaddiya,  from  the  kettle  ;  Anuruddha,  from  the  golden  bowl.)     (i36) 

Mahanama  explained  to  Anuruddha  what  was  implied  by  the  term 
farming;  whereupon  Anuruddha,  aghast  at  the  endless  routine  of 
manual  labor,  said,  "Well  then,  live  the  householder's  life  yourself;  I 
have  no  use  for  it"  He  went  to  his  mother  and  said,  "  Mother,  give 
me  your  permission  to  become  a  monk."  "All  right,  if  your  friend 
King  Bhaddiya  will  do  the  same."  Anuruddha  had  no  little  difficulty 
in  persuading  Bhaddiya  to  do  this ;  but  finally  the  latter  agreed  to 
retire  from  the  world  in  seven  days.  Then  Bhaddiya,  Anuruddha, 
Ananda,  Bhagu,  Kimbila,  and  Devadatta,  together  with  the  barber 
Upali,  set  out  with  four-fold  array,  and  crossed  over  into  foreign  terri- 
tory. Here  the  six  princes  sent  back  the  army,  took  off  their  orna- 
ments, made  a  bundle  of  them,  gave  them  to  Upali,  and  ordered  him 
to  return.  When  Upali  had  gone  a  little  way,  he  was  overcome  with 
fear  that  the  fierce  Sakyans,  thinking  that  he  had  put  their  princes  to 
death,  would  retaliate  by  killing  him;  accordingly  he  untied  the 
bundle,  hung  the  ornaments  up  on  a  tree,  and  returned  to  his  masters. 
Then  the  six  princes,  taking  Upali  with  them,  went  to  the  Teacher, 
and  said  :  "  We,  Venerable  sir,  are  proud  Sakyans  ;  this  man  has  been 
a  servitor  of  ours  for  a  long  time  ;  admit  him  to  the  Order  first ;  to  him 
first  we  will  ofi*er  respectful  salutations  ;  so  will  our  pride  be  humbled." 
Thereupon  the  Teacher  first  admitted  Upali  to  the  Order,  and  after 
him  the  others.  Bhaddiya  attained  Threefold^nowledge,  Anuruddha 
Sui>eniatural  Vision,  afterwards  Arahatship,  Ananda  was  established 
in  the  Fruit  of  Conversion,  and  Bhagu  and  Kimbila  by  the  develop- 
ment of  Insight  attained  Arahatship.  Devadatta  attained  the  lower 
grade  of  Magic  Power.     (136-8)      .      ^ 


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I 


604  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

When  the  Teacher  and  the  monks  went  into  residence  at  Kosambi 
great  numbers  of  people  flocked  thither  and  said,  '^  Where  is  the 
Teacher?  Where  is  Sd,riputta?  MoggallOna?  Kassapa?  Bhaddijat 
Anuruddha  ?  Ananda  1  Bhagu  ?  Kimbila  1 "  But  nobody  said,  "  Where 
is  Devadattal"  Thereupon  Devadatta  said  to  himself  "I  retired 
from  the  world  with  these  monks ;  I,  like  them,  belong  to  the  Warrior 
caste ;  but  unlike  them,  I  am  the  object  of  nobody's  solicitude.  With 
whom  can  I  make  common  cause,  that  I  may  obtain  gain  and  honor 
for  myself?  BimbisSra?  He  will  have  nothing  to  do  with  me.  The 
king  of  Kosala?  Neither  will  he.  What  about  BimbisSra's  son 
Ajfitasattu  ?  He  does  n't  know  anybody's  virtues  or  vices.  He 's  the 
very  man  ! "     (138-9) 

Accordingly  Devadatta  assumed  the  form  of  a  child  girded  about 
with  snakes,  and  descending  from  the  sky,  sat  in  Ajfttasattu's  lap. 
Perceiving  that  he  was  frightened,  Devadatta  told  him  who  he  was, 
and  resumed  his  proper  form.  Ajfitasattu  bestowed  all  manner  of 
attentions  upon  Devadatta,  until  there  arose  in  the  latter's  mind,  over- 
mastered by  gain  and  honor,  the  evil  thought,  "  It  is  I  who  ought  to 
run  the  Congregation  of  Monks."  Thereupon  he  went  to  the  Teacher 
and  said :  "  Venerable  sir,  the  Exalted  One  is  stricken  in  years ;  let 
him  live  a  life  of  ease  in  this  world ;  I  will  run  the  Congregation  of 
Monks ;  make  over  the  Order  to  me."  But  the  Teacher  repulsed  De- 
vadatta, called  him  a  "lick-spittle,"  and  caused  proclamation  to  be 
made  concerning  him  at  Rajagaha.2*  Thereupon  Devadatta  cherished 
resentment  against  the  Teacher,  and  resolved  to  make  trouble  for  him. 
(139-140) 

So  Devadatta  went  to  Ajatasattu  and  said  :  "Youth,  aforetime  men 
were  long-lived,  but  nowadays  they  don't  live  long;  this  makes  it 
probable  that  you  won't  live  long.  You  kill  your  fether  and  become 
king,  and  I  '11  kill  the  Buddha  and  become  Buddha."  When  Aja- 
tasattu  was  established  in  the  kingdom,^^  Devadatta  made  three 
attempts  on  the  life  of  the  Buddha.  First  he  hired  some  men  to  kill 
him,  but  they  deserted  their  posts  and  obtained  the  Fruit  of  Conver- 

**  Oldenberg,  relyinn;  on  Fausbdll's  faulty  text,  says  regarding  this  procla- 
mation (SBE.  XX.  p.  239,  note  2) :  "  It  is  not  referred  to  by  the  Dhammapada 
commentator."    Norman,  however,  gives  the  same  reading  as  the  Vinaya. 

*•  It  is  interesting  to  note  that  this  account  does  not  say  that  Ajfttasattu 
killed  his  father.  The  Vinaya  says  (ii.  190-191)  that  Ajatasattu's  designs 
were  discovered  and  that  Bimbisfira  abdicated  in  favor  of  his  son.  The  J&taka 
(vi.  129,  lines  20-22)  refers  to  the  section  of  the  Vinaya  quoted  above,  and 
then  goes  on  to  say  that  Ajatasattu  killed  his  father !  In  the  Digha  (i.  85  »»-*«) 
Ajatasattu  confesses  to  the  Buddha  that  he  killed  his  father. 


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BURUNOAME.  —  BUDDHAOHOSA's  DHAMMAPADA    COMMENTARY.       505 

sion.  Then  he  climbed  to  the  top  of  Vulture  Peak  and  hurled  down  a 
rock,  but  succeeded  only  in  wounding  the  Teacher.  Lastof  all  he  des- 
patched the  elephant  Nd.lligiri  against  the  Teacher,  but  Ananda  stood 
in  the  breach  and  the  Teacher  subdued  the  elephant  Buddha  in- 
formed the  monks  that  this  was  not  the  first  time  Ananda  had  risked 
his  life  for  him,  and  related  the  Gulahagsa,  Mahahagsa,  and  Eakkata 
Jatakas.     (140-141) 

After  that  neither  the  people  nor  the  king  would  have  anything 
more  to  do  with  Devadatta.  Then  the  latter  went  to  Buddha  and 
made  the  Five  Demands,  but  was  again  repulsed.  Finally  Devadatta 
caused  a  schism  in  the  Order  by  persuading  five  hundred  monks  to 
make  common  cause  with  him,  but  Sftriputtaand  Moggall&na  convinced 
them  of  the  error  of  their  ways  by  preaching  and  performing  miracles 
before  them,  and  returned  with  them  throu^  the  air.  When  the 
Teacher  saw  Sariputta  returning  with  this  splendid  retinue,  he  re- 
marked that  this  was  not  the  first  time  he  had  done  so,  and  related 
the  Lakkhana  Jataka.ae    (141-4) 

During  the  Teacher's  residence  at  Rajagaha,  he  related  many  Jftta- 
kas  about  Devadatta's  evil  deeds  in  previous  existences.  For  example 
when  the  monks  told  him  that  Devadatta  was  imitating  him,  he  related 
the  Vlraka^  KaiTdaga1aka>  and  Virocana  Jatakas ;  with  reference  to  his 
ungratefulness,  he  related  the  Javasakuna  Jataka ;  commenting  on  his 
wickedness,  he  told  the  Eurunga  J&taka;  hearing  the  remark  that 
Devadatta  had  renounced  the  joys  of  the  householder's  life  only  to 
fall  away  from  the  estate  of  a  monk,  he  told  the  Ubhatobhattha  J&taka. 
The  Teacher  then  retired  firom  lUjagaha  to  Sftvatthi  and  took  up  his 
residence  at  Jetavana  Monastery.     (144-6) 

Devadatta  suffered  fix)m  sickness  for  nine  months,  at  the  end  of 
which,  realizing  that  his  end  was  near,  he  was  overwhelmed  with  re- 
morse, and  resolved  to  make  his  peace  with  the  Teacher.  So  he  caused 
himself  to  be  carried  on  a  litter  to  Jetavana.  The  Teacher  refused  to 
see  him.  When  Devadatta  raised  himself  from  the  litter  and  assumed 
a  sitting  posture  with  both  feet  resting  on  the  ground,  the  earth  gave 
way  under  his  feet,  and  slowly  swallowed  him  up.  As  his  jaws  touched 
the  earth,  he  cried  out^  "  I  seek  refuge  in  Buddha ; "  whereupon  the 
Teacher  made  him  a  monk,  prophesjdng  that  at  the  end  of  a  hundred 
thousand  cycles  of  time  he  would  be  reborn  as  a  Private  Buddha  named 
Atthissara.    After  the  earth  had  swallowed  up  Devadatta,  he  was  re- 

••  Jft.  1.  142.  Chalmers  remarks:  "Unlike  this  J&taka,  the  Vinajra  .  .  . 
gives  a  share  of  the  credit  to  Moggall&na."  But  elsewhere  (J&.  iv.  158, 
lines  3-4)  the  J&taka  distinctly  says  that  it  was  S&riputta  and  Moggall&na. 


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506  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

boFD  in  the  Avici  hell,  where  he  suffered  excmoiating  tortares,  being 
encased  in  an  iron  shell  and  impaled  on  iron  stakes.     (146-6) 

When  the  monks  commented  on  what  had  happened  to  Devadatta, 
the  Teacher  told  them  that  Devadatta  had  suffered  similar  experiences 
in  previous  existences,  and  related  the  Sllavan&ga,  Ehantivddi,  and 
Gulla  Dhammapftla  J&takas.  When  the  multitude  rejoiced  at  his 
death,  the  Teacher  told  them  that  the  same  thing  had  happened  before, 
and  related  the  Mah&pingala  Jataka.  Finally  the  monks  inquired 
where  he  had  been  reborn.  The  Teacher  replied,  "  In  the  Avici  hell ;" 
and  reminding  them  that  irreligious  men  suffer  both  here  and  hereafter, 
he  pronounced  Stanza  17,  at  the  end  of  which  many  were  established  in 
the  Fruits.     (148-150) 

Book  I.    Story  13.    Snmanft. 

ILLUSTRATING   STANZA   18  —  18. 

And^thapindika  and  VisftkhS  were  so  intimately  acquainted  vnih  the 
needs  of  the  monks  that  they  were  much  sought  after  to  accompany 
those  who  desired  to  carry  alms  to  the  monks.  When  VisSkhS  left  her 
house,  she  appointed  a  granddaughter  to  dispense  alms  in  her  place, 
Anathapindika  assigned  a  similar  duty  to  his  oldest  "daughter.  The 
latter  attained  the  Fruit  of  Conversion,  married,  and  was  succeeded  by 
a  younger  sister.  She  also  attained  the  Fruit  of  Conversion,  married, 
and  was  succeeded  by  the  youngest  daughter  Sumand%     (1^1) 

Suman^  attained  the  Fruit  of  the  Second  Path,  but  remained  un«> 
married.  Thereat  she  sickened,  would  eat  nothing,  and  sent  for  her 
fatlier.  When  the  latter  asked  her  what  was  the  matter,  she  addressed 
him  as  "  youngest  brother,"  and  died.  An&thapindika,  unable  to  quiet 
his  grief,  went  to  the  Teacher  and  told  him  what  had  happened. 
"  Why  do  you  grieve  ? "  said  the  Teacher.  "  Know  you  not  that  death 
is  certain  for  all ? "  "I  know  that,  Venerable  sir ;  but  my  daughter 
talked  incoherently  when  she  died,  addressing  me  as  'youngest 
brother.' "  "  She  spoke  quite  correctly,"  replied  the  Teacher,  "  for  she 
had  attained  the  Fruit  of  the  Second  Path,  while  you  have  attained 
only  the  Fruit  of  Conversion."  ^  Thereupon  the  Teacher  informed 
Anathapiiidika  that  Suman&  had  been  reborn  in  the  Tusita  heaven, 
and  pronounced  Stanza  18,  at  the  conclusion  of  which  many  were 
established  in  the  Fruits.    (151-4) 

*v  Compare  the  story  of  Eavi  in  Manu,  ii.  150  (Lanman's  Reader,  61  ^. 


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BURUNGAME.  —  BUDDHAGHOSA's   DHAMMAPADA   COMMENTARY.       507 
Book  I.    Story  14.    The  Two  Brethren. 

ILLUSTRATING  STANZAS    19-20  =  19-20. 

Two  noble  youths  who  had  been  friends  retired  from  the  world  to- 
gether. The  older  of  these  assumed  the  Burden  of  Insight  and  attained 
Arahatship ;  the  younger  assumed  the  Burden  of  Study,  acquired  the 
Tipitaka,  and  became  renowned  as  a  master  of  the  Law.  One  day  the 
younger  monk  learned  from  some  pupils  of  his  older  brother  that 
the  latter  knew  only  one  Nikaya  and  one  Pitaka,  and  that  of  the  four- 
lined  Stanzas  he  knew  none  at  all.  Becoming  greatly  puffed  up  at  the 
thought  of  his  own  superior  learning,  he  resolved  to  seize  the  first 
opportunity  to  ask  his  older  brother  some  embarrassing  questions, 
(154-5) 

Somewhat  later  the  older  monk  came  to  pay  his  respects  to  the 
Teacher.  The  latter,  knowing  what  was  in  the  mind  of  the  younger 
monk,  anticipated  his  designs,  and  asked  both  monks  several  questions. 
The  younger  monk  answered  all  the  questions  about  the  Trances  and  the 
Eight  Attainments,  but  failed  to  answer  a  single  question  the  Teacher 
asked  him  about  the  Paths.  The  older  monk,  however,  answered  all  the 
the  questions  correctly.  The  Teacher  praised  the  older  monk  highly, 
and  pronounced  Stanzas  19-20,  at  the  end  of  which  many  were 
established  in  the  Fruits.     (155-9) 

Book  n.    Story  1.    Udena.28 

ILLUSTRATING  STANZAS    1-3  =  2 1-23, 

la.  RiBe  and  Career  of  Udena. 

Once  upon  a  time  two  kings  named  Allakappa  and  Vethadipaka, 
who  had  been  friends  since  boyhood,  retired  from  the  world  and  be- 
came forest  hermits.  One  day  Vethadipaka  died  and  was  reborn  as  a 
powerful  spirit.  Desiring  to  see  his  brother,  he  disguised  himself  as  a 
wayfarer  and  paid  him  a  visit.  Allakappa  told  him  that  the  elephants 
were  giving  him  a  lot  of  trouble ;  whereupon  Vethadipaka  gave  him  a 
lute  to  charm  elephants  with,  and  taught  him  the  proper  spells. 
"  Twang  this  string  and  utter  this  spell,"  said  he,  "and  the  elephants 
will  run  away  without  so  much  as  taking  a  look  behind  them ;  twang 
this  string  and  utter  this  spell,  and  they  will  retreat,  eyeing  you  as 
they  go ;  twang  this  string  and  utter  this  spell  and  the  leader  of  the 
herd  will  come  up  and  offer  you  his  back."    Vethadipaka  then  departed, 

"  Cf.  Rogers,  pp.  32-00. 


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508  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

and  after  that  Allakappa  got  along  fiunoosly  with  the  big  beasts. 
(161^) 

At  this  time  Parantapa  was  king  at  Eosambi.  One  day  the  king 
and  the  queen  were  sitting  out  in  the  open  air  sonning  themselTes. 
The  qneen,  who  was  great  with  child,  was  wearing  the  king's  scarlet 
blanket ;  and  as  they  chatted  together  the  queen  removed  the  king's 
signet  ring  from  his  finger  and  slipped  it  on  her  own.  Jost  then  a 
monster  vulture,  mistaking  the  queen  for  a  piece  of  meat^  swooped 
down,  caught  up  the  queen  in  his  talons,  carried  her  off  to  the  forest, 
and  deposited  her  in  the  fork  of  a  banyan  tree.  The  following  morn- 
ing she  gave  birth  to  a  son,  whom  she  called  Udena.     (164-5) 

Now  the  banyan  tree  was  not  &r  from  the  hermitage  of  Allakappa. 
The  latter,  discovering  mother  and  child,  escorted  them  to  the  hermit- 
age and  cared  for  them  tenderly.  After  a  time,  the  mother,  fearing 
that  if  the  hermit  went  away  she  and  her  child  would  be  left  alone  in 
the  forest  to  die,  tempted  the  hermit  to  break  his  vow  of  chastity. 
The  latter  yielded  to  the  temptation,  and  thereafter  the  two  lived 
together  as  man  and  wife.    (165-^) 

One  day  Allakappa  read  it  in  the  stars  that  the  king  of  Eosambi 
was  dead.  He  told  the  queen,  and  the  latter  burst  into  tears.  Then 
said  the  hermit,  "  Why  do  you  weep  1 "  "  Because  he  was  my  hus- 
band." "  Weep  not ;  death  is  certain  for  all."  "  I  know,  sir."  "  But 
why  do  you  continue  to  weep  1 "  "  Because  of  my  son ;  if  he  could 
only  be  there,  he  would  be  crowned  king."  "Cease  weeping;  I  will 
arrange  all  that"  Thereupon  the  hermit  gave  the  boy  the  lute  to 
charm  elephants  with  and  taught  him  the  proper  spells.  The  her- 
mit then  said  to  the  mother,  "  Give  your  son  the  necessary  instruc- 
tions, that  he  may  go  hence  and  become  king."  The  mother  told  the 
boy  that  he  was  the  son  of  Parantapa,  king  of  Eosambi ;  that  a  monster 
bird  had  carried  her  off  just  before  he  was  bom ;  that  he  was  to  go 
forth  and  claim  his  kingdom ;  and  that  in  case  the  ministers  refused  to 
believe  him,  he  was  to  show  them  his  fistther's  scarlet  mantle  and  signet 
ring.  Then  the  prince  bade  farewell  to  his  fie^ther  and  mother,  mounted 
the  back  of  the  oldest  elephant  of  the  herd,  and  whispered  in  his  ear, 
"  My  lord,  I  am  the  son  of  Parantapa,  king  of  Eosambi ;  obtain  for  me 
the  kingdom  of  my  &ther."  The  elephant  trumpeted,  saying,  "  Let  all 
the  hosts  of  the  elephants  assemble ;  **  and  immediately  all  tJbe  hosts  of 
the  elephants  assembled.  Then  the  elephant  trumpeted  again,  sajring, 
"Let  the  old  elephants  retire,  and  the  young  elephants  withdraw;" 
and  immediately  the  old  elephants  retired,  and  the  young  elephants 
withdrew.  So  Udena  set  out  with  a  prodigious  host  of  warrior  ele- 
phants, and  going  to  the  gates  of  Eosambi,  cried  out  with  a  loud  voices 


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Googl^^^ 


BURUNGAME.  —  BUDDHAOHOSA's   DHAMMAPADA   COBiMENTART.       509 

''Oive  me  battle  or  my  kingdom.''  Then  he  cried  ont  again,  ''I  am 
the  king's  son ; "  and  held  up  the  mantle  and  the  ring,  that  all  might 
see  them  ;  whereupcJn  the  citizens  opened  the  gates,  and  hailed  him  as 
their  king.     (166-9) 

lb. •Rise  and  Career  of  the  Treasurer  Qhosaka. 

Once  upon  a  time  there  was  a  &mine  in  the  kingdom  of  Ajita,  and  a 
certain  man  named  Kotuhalaka  took  his  wife  and  in£Gmt  son  and  set 
out  for  Kosambi  in  search  of  food.  When  the  provisions  for  the  jonr- 
ndy  &iled,  the  bithev  proposed  to  the  mother  to  cast  the  child  away, 
but  the  mother  protested  vigoronsly,  and  suggested  that  they  carry 
the  child  by  turns.  While  the  fie^ther  was  carrying  the  child  in  his 
arms,  the  child  fell  asleep ;  whereupon  the  &ther,  allowing  the  mother 
to  precede  him,  laid  the  child  on  a  couch  of  leaves  under  a  bush,  and 
went  on  his  way.  When  the  mother  discovered  what  had  happened, 
she  begged  her  husband  to  restore  the  child  to  her,  and  he  did  so.  (In 
consequence  of  having  cast  his  child  away  on  this  occasion,  Kotuhalaka 
was  himself  cast  away  seven  times  in  a  later  existence.  Let  no  one 
regard  a  sinful  deed  as  a  small  matter.)    (169-170) 

Continuing  on  their  journey,  they  arrived  at  the  house  of  a  herds- 
man. One  of  the  herdsman's  cows  had  just  calved,  and  a  festival  was 
being  held  in  honor  of  the  event  The  herdsman  received  the  visitors 
hospitably,  set  abundant  food  before  them,  and  then  sat  down  to  eat 
his  own  meaL  Kotuhalaka  watched  the  herdsman  feed  a  bitch  that 
lay  under  his  stool,  and  thought  to  himself :  "  How  fortunate  is  that 
bitch  to  get  food  like  that  to  eat ! "  During  the  night  Kotohalaka 
died  of  indigestion,  and  was  conceived  in  the  womb  of  the  bitch  whose 
lot  he  envied.     (170-171) 

Now  a  Private  Buddha  was  accustomed  to  take  his  meals  in  the 
house  of  the  herdsman ;  and  Kottihalaka's  widow,  realizing  what  an 
opportunity  she  had  to  store  up  merit  for  the  fdture,  bestowed  alms  on 
him  &ithfully  every  day.  By  and  by  the  bitch  gave  birth  to  a  single 
pup.  The  herdsman  reserved  the  milk  of  one  cow  for  the  pup,  and  in 
a  short  time  the  latter  grew  to  be  a  fine  big  dog.  The  Private  Bud- 
dha fed  him  every  day  with  his  own  hand,  and  the  dog  became  so  fond 
of  the  Private  Baddha  that  he  performed  all  manner  of  services  for 
him.  Some  time  later  the  Private  Buddha  took  leave  of  the  herdsman, 
and  setting  his  fiskce  towards  (JandhamSdana,  soared  into  the  air. 
Thereupon  the  dog  set  up  a  howl  of  grie(  and  when  the  Private  Bud- 
dha passed  out  of  sight,  his  heart  broke,  and  he  died.  (Dogs,  they 
say,  are  straightforwa^ ;  men  think  one  thing  with  their  heart,  but  say 


k. 


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510  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY 

another  with  their  lips.)  The  dog  was  reborn  in  the  world  of  the 
Thirty-three  with  a  retinae  of  a  thousand  celestial  njonpha  (If  yon 
ask,  "  Of  what  was  this  the  conseqaence  1 "  it  wa6  becanse  he  barked 
so  affectionately  at  the  Private  Buddha.)    (171-3) 

In  consequence  of  having  devoted  himself  to  sensual  pleasures,  he 
fell  from  the  world  of  the  Thirty-three,  and  was  conceived  in  the  womb 
of  a  harlot  of  Kosambi.  When  the  child  was  bom,  and  the  harlot 
learned  that  it  was  a  boy,  she  had  him  oast  away  on  a  dust-hec^).  A 
man  who  happened  to  pass  by  took  a  &ncy  to  the  child,  and  saying  to 
himself,  **  I  have  gained  a  son,"  took  him  home  with  him.    (173-4) 

That  day  there  was  a  conjunction  of  the  moon  with  a  certain  luifar 
mansion ;  and  a  treasurer  of  Kosambi,  meeting  an  astrologer,  asked 
him  what  the  sign  betokened.  The  astrologer  said,  "  This  day  is  bom 
in  Kosambi  a  child  who  will  become  the  principal  treasurer  of  the 
city/'  It  so  happened  that  the  treasurer's  wife  was  at  that  very  time 
great  with  child ;  and  he  immediately  sent  word  to  find  out  whether 
she  had  been  delivered  or  no.  When  the  messenger  brought  back 
word  that  she  had  not,  the  treasurer  summoned  a  female  slave  and 
said  to  her,  "  Here  are  a  thousand  pieces  of  money ;  scour  the  city  and 
find  a  boy  that  was  bom  to<day  and  bring  him  hither  to  ma"  The 
slave  retumed  with  the  foundling.  The  treasurer  thought  to  himself : 
"  If  a  daughter  is  bom  to  me  I  will  marry  her  to  this  boy  and  m^ke 
him  treasurer ;  but  if  a  son  is  bom  to  me,  I  will  kill  this  boy."  A  few 
days  later  his  wife  gave  birth  to  a  son.  The  treasurer  then  set  i^at 
to  carry  out  his  plan.     (174-5) 

[The  reader  will  bear  in  mind  that  the  adopted  son  of  the  treasurer 
was  none  other  than  the  harlot's  son  who  had  been  cast  away  on  the 
dast-heap,  and  that  he  must  needs  be  cast  away  six  times  more  in 
consequence  of  the  evil  deed  he  committed  when,  in  his  exi/itence  as 
Eotuhalaka,  he  cast  away  his  own  son ;  that  he  must  needs  be  rescued 
through  the  effect  of  the  merit  he  eamed  in  his  existence  as  a  dog  by 
barking  so  affectionately  at  the  Private  Buddha ;  and  that,  inasmuch 
as  all  the  hosts  of  heaven  and  earth  cannot  interfere  with  the  operation 
of  the  law  of  cause  and  effect*  the  astrologer's  prophecy  concerning 
him  was  at  last  to  be  fulfilled.    The  boy's  name  was  Ohosaka.] 

First  the  treasurer  had  Ohosaka  laid  at  the  door  of  the  cattle-pen, 
hoping  that  he  would  be  trampled  to  death.  But  the  bull  stood  over 
him,  allowing  the  cows  to  pass  out  on  either  side  of  him,  and  the  herds- 
man took  him  homa     (l75) 

The  treasurer  recovered  Ghosaka,  and  then  had  him  placed  on  the 
caravan  trail,  expecting  that  he  would  either  be  trampled  by  the  oxen, 
or  crushed  by  the  wheels  of  the  carts.    But  when  tiie  oxen  saw  the 


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BURTJNOAME.  —  BUDDHAGHOSA's   DHAMMAPADA   COMMENTARY.       511 

boy,  they  stopped  with  one  accord,  and  the  whole  caravan  stood  stock 
still  until  its  leader  discovered  what  was  the  matter  and  rescued  the 
boy.    (176) 

Ghosaka  was  recovered  by  the  treasurer,  who  then  had  him  cast 
away  under  a  bush  in  the  cemetery.  Along  came  a  goatherd  with  his 
goats.  The  goatherd's  suspicions  were  aroused  by  the  peculiar  actions 
of  a  she-goat;  whereupon  he  made  an  investigation, 'discovered  the 
boy,  and  rescued  him.    (176-7) 

Ghosaka  was  again  recovered  by  the  treasurer  and  thrown  down  a 
precipica  He  fell  into  a  clump  of  bamboo,  and  a  basket-maker  rescued 
him.     (177) 

In  spite  of  the  treasurer's  attempts  on  his  life,  Ghosaka  lived  and 
thrived  and  grew  to  manhood.  ^  He  was  a  thorn  in  the  flesh  of  the 
treasurer,  who  could  not  look  him  straight  in  the  &ce.  Finally  the 
treasurer  resorted  to  desperate  measures.  He  went  to  a  potter,  gave 
him  a  thousand  pieces  of  money,  and  said  to  him,  "  I  have  a  job  for 
you."  "What  is  it?"  "I  have  a  base-bom  son;  I'll  send  him  to 
you  to-morrow ;  get  him  into  a  room,  take  a  sharp  razor,  cut  him  into 
bits,  and  throw  them  into  the  chatty."  '"All  right"  The  next  day 
the  treasurer  said  to  Ghosaka,  "  Go  and  tell  the  potter  to  finish  up  the 
job  I  gave  him  yesterday."  "Very  well,"  said  Ghosaka ;  and  started 
out  When  he  had  gone  a  little  way,  the  treasurer's  own  son,  who 
was  playing  ball  with  some  other  boys,  stopped  him  and  said  to  him, 
"  Where  are  you  going  1 "  Ghosaka  told  him.  "  Let 's  change  places," 
said  the  treasurer's  son ;  "these  boys  have  won  a  lot  of  money  from  me, 
and  you  're  such  a  good  ball-player  that  you  can  easily  win  it  back  for 
me."  So  Ghosaka  took  his  foster-brother's  place  in  the  game,  and  the 
treasurer's  own  son  carried  his  fie^ther's  message  to  the  potter.  That 
night  the  despised  Ghosaka  returned  home ;  the  treasurer's  son  did  not 
The  treasurer  cried  out,  "  Woe  is  me !  "  and  rushed  to  the  potter,  who 
said  to  him,  "Master,  make  no  noise;  I  have  done  the  job."  The 
wicked  treasurer  was  overwhelmed  with  sorrow  and  grief  at  the  thought 
that  he  had  shed  innocent  blood,  even  as  Buddha  says  in  Stanzas 
137-140.    (177-9) 

The  treasurer  made  one  more  attempt  on  Ghosaka's  life.  He  wrote 
a  letter  to  the  superintendent  of  his  estate,  saying,  "  This  is  my  base- 
born  son ;  kill  him,  and  I  will  do  what  is  right  for  you ; "  pinned  it  to 
the  hem  of  Ghosaka's  clothing,  and  ordered  Ghosaka  to  carry  it  to  the 
superintendent  (The  treasurer  had  never  taught  Ghosaka  to  read, 
for  he  expected  sooner  or  later  to  kill  him.)  When  Ghosaka  remarked 
that  he  needed  provisions  for  the  journey,  the  treasurer  said,  "  Not  at 
all;  in  such  and  such  a  village  livesafriend  of  mine  who  is  a  treasurer; 


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512  PROCEEDINGS  OF  THE  AMERICAN  ACADEMT. 

he  will  give  you  something  to  eat"  When  Ghosaka  stopped  at  the 
village  treasurer's  hoase,  the  treasurer's  wife  took  a  &ncy  to  him,  and 
the  daughter  of  the  household  fell  madly  in  love  with  him.  (It  was 
she  that  had  been  his  wife  in  his  former  existence  as  Eottihalaka,  and 
it  was  through  the  merit  she  acquired  by  bestowing  alms  on  the  Private 
Buddha  that  she  was  reborn  as  the  treasurer's  dau)^hter.  No  wonder 
that  her  old  passion  for  him  returned !)  When  the  treasurer's  daugh- 
ter discovered  that  Ghosaka  was  carrying  his  death-warranty  she 
secretly  removed  it  and  substituted  another  letter  of  her  own  compo- 
sition, which  read  as  follows :  "  This  is  my  son  Ghosaka.  Bestow 
treasure  upon  him ;  prepare  for  the  festival  of  his  marriage  to  the 
daughter  of  the  village  treasurer ;  build  him  a  splendid  palace ;  and 
provide  him  with  a  strong  guard  of  soldiers.  When  you  have  so  done, 
send  me  word,  saying,  *  I  have  done  this  and  that.' "  When  the 
superintendent  read  Uie  letter  he  immediately  did  as  he  was  told. 

(180-182) 

When  the  treasurer  learned  how  miserably  his  last  attempt  had 
fisdled,  he  cried  out,  "  What  I  would  do,  that  I  do  not ;  what  I  would 
not  do,  that  I  do,"  sickened,  and  was  soon  at  the  point  of  deatit 
Ghosaka  and  his  bride  visited  him  in  his  last  moments.  Just  as  the 
treasurer  was  about  to  die,  he  lifted  up  his  voice,  intending  to  say, 
"  These  my  treasures  shall  never  be  Ghosaka's ; "  but  by  a  slip  of  the 
tongue  said  instead,  "  These  my  treasures  shall  ever  be  Ghosaka's." 
King  Udena  confirmed  Ghosaka  in  his. inheritance  and  made  him  the 
principal  treasurer  of  the  city.  When  the  treasurer  Ghosaka  learned 
from  his  wife  how  narrow  had  been  his  escape  from  death,  he  resolved 
to  forsake  the  life  of  Heedlessness,  and  to  live  the  life  of  Heedfulness, 
and  thereafter  he  dispensed  a  thousand  pieces  of  money  daily  in  alms 
to  the  poor.    (182-7) 

lo.  Rise  and  Career  of  SftmSlvatl. 

At  this  time  the  treasurer  Ghosaka  learned  from  some  merchants 
who  had  lately  returned  from  BhaddavatI  that  there  lived  in  that  city 
a  merchant  of  great  wealth  and  high  standing,  named  Bhaddavatiya ; 
and  desiring  to  be  friends  with  him,  Ghosaka  sent  him  a  present. 
Bhaddavatiya  returned  the  compliment ;  and  thus,  though  they  had 
never  seen  each  other,  they  became  fast  friends.  A  little  later  a  pesti- 
lence broke  out  in  Bhaddavatiya's  city ;  and  the  treasurer,  taking  his 
wife  and  daughter,  set  out  for  Eosambi,  intending  to  ask  Ghosaka  to 
help  them.  After  a  hard  journey  they  reached  Eosambi,  and  secured 
lodgings  in  a  hall  near  the  city  gate.  Bhaddavatiya  told  his  wife  that 
Ghosaka  was  accustomed  to  dispense  a  thousand  pieces  of  money  daily 


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BURUNGAME.  —  BUDDHAGHOSA's   DHAMMAPADA   COMMENTARY.       513 

iu  alms  to  the  poor,  and  suggested  that  they  send  their  daughter  to 
him  to  procure  food  until  they  reoovered  sufficient  stiength  to  pay  him 
a  visit    (lp7-8) 

So  it  happened  that  the  daughter  of  a  wealthy  house  accompanied 
poor  folk  to  Ohosaka's  hall  for  alms.  "  How  many  portions  will  you 
have  ? "  "  Three."  That  night  her  fether  died.  "  How  many  portions 
will  you  have?"  "Two."  That  night  her  mother  died.  "How 
many  portions  will  you  have?"  "One."  A  householder  named 
Mitta,  who  remembered  that  she  had  taken  more  on  the  two  previous 
days,  said  to  her,  "  I  suppose  that  is  all  you  can  hold  to-day."  This 
cruel  remark  cut  her  to  ihe  quick,  and  she  said,  "Sir,  don't  think  I 
took  more  for  myself;  before  we  were  three,  yesterday  two,  to-day  I  am 
left  alona"  She  then  told  him  the  whole  story,  whereupon  he  took 
pity  on  her  and  adopted  her  as  his  oldest  daughter.  She  rendered 
such  valuable  assistance  in  the  administration  of  the  hall  where  Gho- 
saka's  alms  were  distributed  as  to  attract  the  attention  of  Ghosaka 
himself,  who,  upon  learning  that  she  was  the  daughter  of  Bhadda- 
vatiya,  gave  her  a  retinue  of  five  hundred  women  and  made  her  as  his 
own  oldest  daughter.  One  day  King  Udena  saw  her,  fell  in  love  with 
her,  and  married  her.  She  became  one  of  his  queen-conscHrts,  and  the 
women  of  her  retinue  ladies-in-waiting.    (188-191) 

Id.  Vftsoladattft. 

Another  of  Udena's  queen-consorts  was  VSsuladattS^  daughter  of 
Candapajjota,  king  of  Ujjeni.  Udena  gained  possession  of  her  in  the 
following  way :    (191-2) 

One  day  King  Candapajjota  said  to  his  ministers,  "Is  there  any 
other  monarch  so  powerful  as  I  am?"  "Of  course  not,"  said  they; 
"  but  yet  King  Udena  of  Kosambi  is  pretty  powerful."  "  Well  then, 
let 's  take  him  prisoner."  "  It  can't  be  done ;  he  understands  how  to 
charm  elephants,  and  has  more  elephants  at  his  disposal  than  any  other 
king."  "  I  suppose  it  can't  be  done."  "  Well,  if  your  heart  is  set  on 
doing  it,  you  might  try  this  stratagem :  Have  a  wooden  elephant 
made,  and  send  it  out  somewhere  near  him ;  he  will  go  a  long  way 
after  a  good  mount,  and  you  can  take  him  prisoner  as  he  approaches." 
"  That  is  a  stratagem ! "     (192) 

Thereupon  Candapajjota  had  a  mechanical  elephant  made  of  wood, 
and  turned  it  loose  where  Udena  would  be  sure  to  see  it  It  looked 
exactly  like  a  real  elephant ;  moreover,  it  was  fitted  with  mechanical 
appliances  worked  from  the  inside,  so  that  it  moved  hither  and  thither 
just  like  a  real  elephant;  its  belly  held  sixty  men,  who  worked  the 
mechanism,  and  every  now  and  then  dumped  out  a  quantity  of  ele- 

VOL.  XLV.  —  33 


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514  PROCEEDINGS   OP   THE    AMERICAN    ACADEMY. 

phant  dung.  Udena  immediately  mounted  his  elephant  and  started 
oat  in  pursuit  jCandapajjbta  posted  an  ambuscade.  Udena  tried  to 
charm  the  wooden  elephant  by  twanging  his  lute  and  uttering  spells, 
but  the  wooden  elephant  paid  no  attention  to  him,  and  only  made  off 
faster  than  ever.  Udena,  unable  to  keep  up  with  the  wooden  elephant, 
mounted  his  horse,  left  his  army  behind,  and  started  out  alone. 
Thereupon  he  was  drawn  into  the  ambuscade  and  captured.     (192-3) 

Gandapajjota  kept  Udena  in  prison  for  three  days,  and  then  offered 
to  release  him  if  Udena  would  divulge  the  charm.  "  I  will  do  so," 
said  Udena,  "provided  you  will  pay  me  homage."  "That  I  will  not 
do,"  replied  Gandapajjota ;  "  but  will  you  divulge  it  to  another,  if  the 
other  will  pay  you  homage  ? "  "  Yes."  "  Well  then,  there  is  a  hunch- 
backed woman  in  this  house ;  I  will  have  her  sit  inside  a  curtain ;  you 
remain  outside  and  teach  her  the  charm."  "Very  welL"  Ganda- 
pajjota then  went  to  his  daughter,  the  beautiful  Princess  Vdsuladatt^ 
and  said  to  her,  "  There  is  a  leper  who  knows  a  priceless  charm ;  you 
sit  inside  a  curtain  ;  he  will  remain  outside,  and  teach  you  the  charm ; 
then  tell  me  what  it  is."  (Gandapajjota  employed  this  stratagem  to 
protect  his  daughter's  chastity.)     (193-4) 

One  day  Udena  repeated  the  charm  over  and  over  again  to  Vasula- 
datta,  but  the  latter  was  unable  to  reproduce  it  correctly.  Thereupon 
Udena  lost  his  patience,  and  cried  out,  "  What 's  the  matter  with  you, 
you  thick-lipped  hunchback  1 "  VSsuladatta  retorted  angrily,  "  How 
dare  you  speak  thusi  do  I  look  like  a  hunchback?"  Udena  raised 
the  curtain,  and  immediately  they  both  knew  why  Gandapajjota  had 
deceived  them.  VSsuladattd.  jrielded  her  chastity  to  Udena ;  and  after 
that  there  were  no  more  lessons.  The  king  frequently  asked  his 
daughter,  "  How  are  you  getting  along  with  your  lessons  1 "  and  always 
received  the  answer,  "Very  well."    (194-5) 

One  day  Udena  said  to  Vasuladatta,  "  If  you  will  save  my  life,  I  will 
make  you  queen-consort  and  provide  you  with  five  hundred  ladies-in- 
waiting."  "  Very  well,"  replied  Vasuladatta ;  and  she  went  and  said  to 
her  father,  "  Father,  in  order  that  I  may  perfect  myself  in  this  charm, 
it  will  be  necessary  for  me  to  dig  a  certain  medicinal  root  in  the  dead 
of  night  at  a  time  indicated  by  the  stars ;  therefore  please  have  one 
door  left  open,  and  put  an  elephant  at  my  disposal."     (195-6) 

(Now  King  Gandapajjota,  in  consequence  of  having  bestowed  alms 
on  a  Private  Buddha  in  a  previous  existence  as  a  slave,  was  possessed 
of  the  five  conveyances :  a  female  elephant,  which  could  travel  50 
leagues  a  day ;  a  slave,  who  could  travel  60  leagues ;  two  horses,  100 
leagues ;  and  an  elephant  named  NalSgiri,  120  leagues.)     (196-6) 

One  day,  when  Gandapajjota  was  absent,  Udena  filled  several  big 


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BURUNGAME.  —  BUDDHAGHOSa's   DHAMMAPADA   COMMENTARY.       515 

leather  sacks  with  gold  and  silver,  put  them  on  the  back  of  the  female 
elephant,  assisted  VOsuladattft  to  mount,  and  away  they  went  As 
soon  as  Candapajjota  learned  what  had  happened,  he  sent  out  a  force 
in  pursuit.  Udena  opened  the  sacks  and  scattered  coins  along  the 
route ;  Candapajjota's  men  delayed  pursuit  to  pick  them  up ;  so  Udena 
easily  escaped.  It  was  thus  that  VOsuladattft  came  to  be  one  of  King 
Udena's  queen-consorts.     (198-9) 

le.  MAgandiya. 

Magandiyft  was  another  of  Udena's  queen-consorts.  She  was  the 
daughter  of  a  Brahman  named  MAgandiya,  who  lived  in  the  Eiiru 
country.  Mfigandiyft  was  the  name  of  her  mother,  and  she  had  an 
uncle  named  MSgandiya.  She  was  as  beautiful  as  a  celestial  nymph. 
One  after  another  the  sons  of  the  most  prominent  &milies  presented 
themselves  as  suitors  for  her  hand ;  but  the  Brahman  refused  them  all^ 
telling  them  that  they  were  not  worthy  of  her.     (199) 

One  day  the  Teacher,  knowing  that  the  Brahman  and  his  wife  were 
capable  of  attaining  the  Fruit  of  the  Third  Path,  went  to  the  place 
where  the  Brahman  was  tending  the  sacred  fire.  The  Brahman  was  so 
impressed  with  the  majestic  appearance  of  his  visitor  that  he  then  and 
there  offered  him  his  daughter  in  marriage.  The  Teacher  said  nothing. 
The  Brahman  went  home  in  great  haste,  told  his  wife  that  he  had 
found  a  husband  for  their  daughter,  caused  the  latter  to  be  dressed  in 
gala  attire,  and  then  all  three  went  to  the  Teacher.    (199-200) 

By  this  time  the  Teacher  had  moved  away  from  the  place  of  his  in- 
terview  with  the  Brahman,  leaving  a  foot-print  "  Where  can  he  have 
gone ! "  said  the  Brahman ;  and  then,  seeing  the  foot-print,  he  said  to 
his  wife,  "There  is  his  foot-print."  Now  the  Brahman's  wife  was  well 
versed  in  the  Three  Vedas ;  and  after  considering  the  foot-print,  and 
turning  over  in  her  mind  the  texts  relating  to  foot-prints,  she  said, 
"  Husband,  that  is  not  the  foot-print  of  one  who  follows  the  Five  Lusts." 
**  Hush,  wife,  you  're  always  seeing  alligators  in  the  water- vessel  and 
thieves  hiding  in  the  house."  Then  the  Brahman  saw  the  Teacher  and 
said,  "There  is  the  man."  The  Brahman  immediately  went  to  him 
and  said,  "  I  bestow  my  daughter  upon  you ;  cherish  her  tenderly." 
The  Teacher  replied,  "  Brahman,  I  have  something  to  say  to  you ; " 
and  then  told  him  that  from  the  time  of  the  Great  Retirement  to  the 
time  of  the  Session  under  the  Banyan-tree  Mftra  had  pursued  him  re- 
lentlessly, only  to  be  defeated  at  every  point,  that  Mftra's  daughters 
had  then  tempted  him  in  various  forms  without  exciting  in  him  the 
lust  of  the  flesh,  and  that  nothing  would  induce  him  to  touch  the 
maiden  who  stood  before  him  with  so  much  as  the  sole  of  his  foot 


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516  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

Thereupon  the  Brahman  and  his  wife  were  established  in  the  Fmit  of 
the  Third  Path.  Md^^diy^  however,  cherished  the  most  bitter 
hatred  of  the  Teacher  ever  after.     (200-202) 

The  Brahman  and  his  wife  entrusted  Md*gandiy&  to  ihe  care  of  her 
uncle,  who  adorned  her  with  all  the  adornments  and  presented  her  to 
King  Udena.  The  king  immediately  fell  in  love  with  her  and  married 
her,  making  her  queen-consort  and  giving  her  a  retinue  of  five  hundred 
ladies-in-wfidting.     (202-203) 

If.  Death  of  SflmAvatl. 

At  this  time  there  were  living  in  Kosambi  three  treasurers,  Qhosita, 
Eukkuta,  and  P&v&riya.  At  the  beginning  of  the  rainy  season  five 
hundred  monks  returned  fix)m  the  Him&laya  country  and  went  about 
the  city  collecting  alms.  The  three  treasurers  saw  them  and  provided 
them  with  food  during  the  four  rainy  months.  When  the  rains  were  at 
an  end  the  monks  took  leave  of  their  hosts  and  retired  to  Him&laya, 
promising  to  return  the  following  year.  And  this  became  an  estab- 
lished custom.  Several  years  later,  the  monks  on  their  return  from 
Himalaya  took  up  their  abode  in  the  forest  under  a  gigantic  banyan 
tree.  The  oldest  monk  thought  to  himself :  '*  This  tree  must  be  ten- 
anted by  a  very  powerful  tree-spirit ;  I  wish  he  would  give  us  some 
water  to  drink ; "  and  immediately  the  spirit  gave  them  water  to  drink 
Then  the  monk  thought,  "  I  wish  he  would  give  us  some  water  to  bathe 
in  ; "  and  immediately  the  spirit  gave  them  water  to  bathe  in.  Then 
the  monk  thought  of  food,  and  there  it  was !  "  Well ! "  said  the  monk, 
"  this  spirit  gives  us  everything  we  think  of;  let  *s  have  a  look  at  him.'* 
Immediately  the  tree  split  open,  and  out  came  the  spirit  Said  the 
monks,  "  Spirit,  you  have  great  power ;  what  did  you  do  to  get  it  I " 
But  it  was  a  very  modest  spirit;  and  so  said,  "Don't  ask  me." 
•*  Please  tell.'*    After  considerable  urging,  the  spirit  told  his  story. 

(203-204) 

It  seems  that  the  spirit  had  once  been  a  servant  of  An&thapindika. 
One  fast-day  An&thapindika,  on  learning  that  his  servant  had  not  been 
told  the  significance  of  the  day,  ordered  a  meal  to  be  prepared  for  him. 
The  servant  observed  that  no  one  else  was  eating,  learned  why,  and 
followed  suit  He  then  went  out  and  did  his  day's  work,  was  taken 
sick,  and  died  that  very  night  "  My  master,"  said  the  spirit,  "  was 
devoted  to  Buddha,  the  Law,  and  the  Order ;  and  it  was  through  him 
and  in  consequence  of  the  fast  I  observed  that  I  was  reborn  as  a  tree- 
spirit."     (204-206) 

Thereupon  the  monks  sought  refuge  in  Buddha,  the  Law,  and  the 
Order,  and  on  the  following  day,  aft;er  conferring  with  the  three  treas- 


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BURLINGAME.  —  BUDDHAGHOSa's    DHAMMAPADA    COMMENTARY.      517 

urers,  visited  the  Teacher,  attained  Arahatship,  and  were  admitted  to 
the  Order.  A  little  later  Ghosita,  Kukkuta,  and  Pavariya  came  to 
the  Teacher,  bearing  rich  offerings,  and  were  established  in  the  Fruit 
of  Conversion.  For  two  weeks  the  treasurers  remained  with  the 
l^eacher,  giving  generously  of  their  store,  and  then,  after  obtaining 
the  Teacher's  promise  to  visit  them,  returned  to  Kosambi.  Here  they 
erected  Ghosita,  Kukkuta,  and  FavS-riya  monasteries,  and  here  the 
Teacher  visited  them,  dividing  his  time  equally  among  the  three. 
After  the  treasurers  had  entertained  the  Teacher  for  some  time,  their 
gardener  Sumana  asked  and  received  permission  to  entertain  him  for  a 
single  day.     (20e-208) 

Now  at  this  time  King  Udena  was  in  the  habit  of  giving  Queen 
Samavati  eight  pieces  of  mt)ney  every  day  to  buy  flowers  with.  This 
money  the  queen  turned  over  to  a  female  slave,  Khujjuttara,  who  went 
regularly  to  the  gardener  Sumana's  and  bought  flowers.  On  the  day 
appointed  for  the  Teacher's  visit  Sumana  said  to  her  :  "  To-day  I  ex- 
pect to  entertain  the  Teacher,  and  shall  have  use  for  my  flowers ;  wait 
and  listen  to  the  Law,  and  then,  if  there  are  any  flowers  left,  you  may 
have  them."  Khujjuttara  barkened  to  the  Law,  and  was  established 
in  the  Fruit  of  Conversion.  Now  hitherto  it  had  been  Khujjuttarfi's 
practice  to  spend  only  four  pieces  of  money  on  flowers,  and  to  pocket 
the  rest  That  day,  however,  she  spent  the  entire  amount  on  flowers, 
and  returned  with  so  many  that  the  queen's  curiosity  was  aroused,  and 
the  whole  story  came  out.  From  that  time  on  Khujjuttara  stole  no 
more ;  but  becoming  as  it  were  a  mother  to  Sam^vatl,  went  regularly 
every  day  to  hear  the  Teacher,  and  returned  and  preached  the  Law  to 
the  queen  and  her  retinue  exactly  as  she  had  heard  it.  She  soon 
knew  the  Tipitaka  so  well  as  to  win  from  the  Teacher  the  title  of 
"  Pre-eminent."  Queen  Samavati  and  her  retinue  were  established  in 
the  Fruit  of  Conversion.     (208-210) 

One  day  Samavati  expressed  to  Khujjuttara  a  desire  to  see  the 
Teacher.  Khujjuttara  said,  "  It 's  a  serious  matter  to  live  in  a  king's 
palace ;  once  in,  you  can't  get  out."  The  queen  begged  her  to  arrange  . 
it  in  some  way.  Khujjuttara  then  told  her  to  make  holes  in  the  walls 
of  the  palace  and  to  render  homage  to  the  Teacher  from  within. 
Magandiya  came  to  know  of  this.     (210-211) 

Now  Magandiya  had  cherished  the  most  bitter  hatred  of  the  Teacher 
and  his  followers  ever  since  the  Teacher  refused  to  marry  her ;  and  as  * 
soon  as  she  learned  that  Samavati  and  her  attendants  were  making  a 
practice  of  rendering  homage  to  the  Teacher  through  holes  in  the  walls 
of  the  palace,  she  said  to  herself,  "  I  know  what 's  to  be  done  to  him  ; 
I  know  what 's  to  be  done  to  them."     Thereupon  Magandiya  went  to 


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518  PROCEEDINGS    OF   THE   AMERICAN   ACADEMY. 

King  Udena  and  told  him  that  S&m&vatl  was  plannbg  to  kill  him,  and 
had  made  holes  in  the  walls  of  the  palace  for  that  purpose.  The  king, 
however,  refused  to  believe  her ;  and  when  he  learned  what  the  real 
bucta  were,  had  the  holes  sealed  up  and  windows  made  in  the  upper 
storey.     (Upper-storey  windows  came  in  at  this  time,  we  are  told.) 

(211) 

Magandiy^  then  determined  to  drive  the  Teacher  out  of  the  city, 
and  to  this  end  employed  ruffians  to  follow  him  about  and  heap  abuse 
upon  him.  Ananda  proposed  to  the  Teacher  that  they  should  go  else- 
where ;  but  this  the  Teacher  declined  to  do,  and  comparing  himself  to 
an  elephant  engaged  in  the  fray,  pronounced  Stanzas  320-322.  After 
seven  days  the  uproar  ceased;  and  Mftgandiyft,  perceiving  that  she 
could  do  nothing  against  the  Teacher,  renewed  her  determination  to 
destroy  the  women  who  were  his  supporters.     (211-213) 

Md*gandiy&  then  procured  from  her  uncle  eight  live  cocks  and  eight 
dead  cocks,  and  presented  the  live  cocks  to  Udena,  suggesting  that  he 
ask  Sd^mftvati  to  cook  them  for  him.  Udena  did  so,  and  S&m&vatI  re- 
plied,  "  I  and  my  followers  do  not  take  life."  "  Now,"  said  Magandiya, 
**  see  whether  she  will  cook  them  for  the  hermit  Gotama."  MSgandiya 
then  substituted  the  dead  cocks  for  the  live  cocks,  and  Samftvatl  imme- 
diately obeyed  directions.  "See,"  said  Magandiya,  "  they  won't  do  it 
for  the  like  of  you,  but  they  '11  do  it  readily  enough  for  outsiders." 
The  king,  however,  still  refused  to  believe  her.    (213-215) 

Now  the  king  was  accustomed  to  divide  his  time  equally  among  his 
three  consorts,  spending  a  week  at  a  time  in  the  apartment  of  each. 
MagandiyO,  knowing  that  the  king  would  go  to  Samavatl's  apartment 
on  the  following  day,  carrying  with  him,  as  was  his  custom,  the  lute 
Allakappa  had  given  him,  procured  a  snake  from  her  uncle  and  placed 
it  in  the  cavity  of  the  lute,  stopping  the  end  of  the  lute  with  a  bunch 
of  flowers.  Then  she  said  to  him,  "  Whose  apartment  do  you  visit  to- 
day?" The  king  told  her.  "Don't  do  it,"  said  she;  "last  night  I 
had  a  bad  dream,  and  I  fear  that  something  will  happen  to  you."  But 
the  king  went,  just  the  same,  and  Magandiya,  much  against  his  wishes, 
followed  after.  The  king  placed  the  lute  beside  his  pillow  and  lay 
down  on  the  bed.  Magandiya  secretly  removed  the  bunch  of  flowers 
from  the  lute,  and  out  came  the  snake.  Magandiya  screamed  as  if  in 
terror,  and  after  reproaching  the  king  for  disregarding  her  warning, 
turned  to  SamavatI  and  her  attendants  and  reviled  them,  saying, 
"  You  wretched  scoundrels,  what  do  you  hope  to  gam  by  killing  your 
most  gracious  sovereign  t "  The  kbg  was  consumed  with  anger,  and 
now  believed  all  that  Magandiya  had  said.     (215-216) 

SamavatI  urged  her  attendaiits  to  remain  true  to  the  principles  of 


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their  religion,  and  to  cherish  no  bitter  feelings  toward  the  king  or 
M%andiyd^  The  king  took  his  bow,  which  required  a  thousand 
soldiers  to  string,  and  shot  a  poisoned  arrow  at  S&mavatl's  breast. 
But  so  great  was  the  power  of  S^m&vatl's  love  that  the  arrow  turned 
back  and,  as  it  were,  penetrated  the  king's  heart  Thereupon  the  king 
threw  himself  at  SSmavatf  s  feet  and  cried  out,  "  Be  thou  my  refuge." 
Sd.m&yatl  replied,  "  In  whom  I  have  myself  sought  refuge,  in  him  do 
thou  also  seek  refuge."  Then  the  king  sought  refuge  in  Buddha  and 
thereafter  was  a  most  generous  benefsu^tor  of  the  Order.    (216-220) 

Magandiya  thought  to  herself:  "Everything  I  do  turns  out  badly ; 
what  shaU  I  do  next  ? "  Finally  she  resorted  to  the  desperate  expedi- 
ent of  directing  her  uncle  to  fire  Samftvatf  s  palace.  Her  uncle  wrapped 
the  palace  in  cloths  saturated  with  oil,  barred  the  doors,  set  fire  to  the 
building  in  several  places  at  once,  and  Sdmftvatl  and  her  five  hundred 
attendants  perished  in  the  flames.  By  devoting  themselves  to  earnest 
meditation  on  the  element  of  pain,  some  of  the  victims  obtained  the 
Fruit  of  Conversion,  others  the  Fruit  of  the  Second  Path,  still  others 
the  Fruit  of  the  Third  Path.  (According  to  a  passage  in  the  Udana, 
the  monks  reported  to  the  Teacher  what  had  happened  and  questioned 
him  regarding  the  future  state  of  the  victims.  The  Teacher  assured 
them  that  none  &iled  to  obtain  a  suitable  reward,  and  warned  them 
that  all  beings  are  constantly  experiencing  botii  happiness  and  misery.) 
(220-222) 

When  the  king  learned  what  had  happened,  he  was  overwhelmed 
with  grief,  and  at  once  perceived  that  Magandiya  was  at  the  bottom  of 
it.  But  knowing  that  he  could  not  intimidate  the  latter,  he  resorted 
to  artifice  and  said  to  his  ministers,  "  Now  that  Samftvatl  is  dead,  I 
can  sleep  in  peace ;  whoever  did  this  deed  must  have  loved  me  greatly." 
Magandiya  overheard  this  remark  and  said  triumphantly,  "  It  was  I  " 
"  Well,"  said  the  king,  "  I  am  delighted.  Send  for  your  relatives,  and 
I  will  reward  you  properly."  The  king  bestowed  handsome  presents 
on  Magandiya  and  her  relatives ;  whereupon  many  persons  who  were  in 
no  way  related  to  her  came  forward  and  claimed  relationship.  When 
the  king  had  caught  them  all,  he  had  them  subjected  to  excruciating 
tortures  and  put  to  death.    (222-4) 

One  day  the  Teacher  overheard  the  monks  remark  that  the  cruel 
death  of  SamavatI  and  her  attendants  was  undeserved.  "  Quite 
right,"  said  the  Teacher,  "  if  you  regard  only  this  existence ;  but  their 
sad  end  was  the  result  of  an  evil  deed  committed  in  a  previous  exist- 
ence ; "  and  he  went  on  to  tell  them  that  in  a  previous  existence  Sama- 
vati  and  her  attendants  had  once  attempted  to  bum  a  Private  Buddha 
to  death.    (224-5) 


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520  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

Then  the  monks  asked  the  Teacher  :  "How  did  Khujjattard.  oome 
to  be  a  hunchback  ?  how  did  she  become  so  wise  ?  how  did  she  obtain 
the  Fruit  of  Conversion  ?  how  did  she  come  to  be  an  errand-girl  T  " 
The  Teacher  told  them  that  she  became  a  hunchback  through  mocking 
a  Private  Buddha,  that  she  acquired  wisdom  by  waiting  on  some 
Private  Buddhas,  and  the  Fruit  of  Conversion  by  giving  them  her 
bracelets,  and  that  she  became  an  errand-girl  because  she  once  asked  a 
nun  to  do  a  menial  service  for  her.     (22S-7) 

Again  the  monks  asked  the  Teacher  :  "  Skmftvati  and  her  attendants 
perished  by  fire  and  Magandiya  and  her  kinsfolk  by  torture ;  which  of 
these  live  and  which  of  these  are  dead  ? "  The  Teacher  replied  : 
"  They  that  are  heedless,  though  they  live  a  hundred  years,  yet  are 
they  dead  ;  they  that  are  heedful,  be  they  dead  or  alive,  yet  are  they 
alive.  MSgandiya^  while  she  yet  lived,  was  dead  already;  Simavatl 
and  her  attendants,  though  they  be  dead,  yet  are  they  alive;  the 
heedful  never  die."  Then  he  pronounced  Stanzas  21-23,  at  theconcla- 
sion  of  which  many  were  established  in  the  Fruits.     (227-231) 

Book  n.    Story  2.    Kumbhaghosaka. 

ILLUSTRATINQ  STANZA  4-24. 

A  pestilence  once  broke  out  in  Rajagaha  and  a  certain  treasurer  and 
his  wife  were  attacked  by  the  disease.  Realizing  that  they  were  about 
to  die,  they  bade  fistrewell  to  their  son  Kumbhaghosaka,  directing  him  to 
bury  their  treasure  in  the  earth,  flee  for  his  life,  and  return  later  and 
dig  it  up  again.  Kumbhaghosaka  buried  the  treasure,  fled  to  a  jungle, 
and  after  twelve  years  returned.  No  one  recognized  him ;  and  tins 
made  him  fear  that  if  he  dug  up  the  treasure,  he  might  be  subjected 
to  annoyance;  therefore  he  decided  to  make  his  own  living,  and 
obtained  a  position  as  a  cart-driver.     (231-2) 

One  day  King  Bimbisara  heard  the  sound  of  Kumbhaghosaka's  voice, 
and  immediately  exclaimed,  "  That  is  the  voice  of  some  rich  man."  A 
female  slave  heard  the  remark,  made  an  investigation,  and  reported  to 
the  king  that  it  was  only  a  cart-driver.  The  king  refused  to  believe 
her ;  whereupon  she  said,  "  Give  me  a  thousand  pieces  of  money,  and  I 
will  make  you  master  of  his  wealth.*'  The  king  complied  with  her 
request     (232-3) 

Now  the  female  slave  had  a  daughter  whom  she  resolved  to  employ 
in  the  accomplishment  of  her  design.  Accordingly  she  obtained  lodg- 
ing for  herself  and  her  daughter  in  Kumbhaghosaka's  house,  and  con- 
trived to  seduce  Kumbhaghosaka  to  violate  her  daughter.  When  she 
had  so  fox  succeeded  in  her  purpose,  she  contracted  a  marriage  betweea 


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BURLINGAME.  —  BUDDHAGHOSA's   DHAMMAPADA  COBIMENTARY.       521 

Kumbhaghoeaka  and  her  daaghter,  and  Kumbbaghosaka  was  obliged 
to  dig  up  some  of  his  money  to  defray  the  expenses  of  the  wedding  fes- 
tivities. In  this  way  the  whole  story  came  oat ;  bat  the  king,  instead 
of  confiscating  Eambhaghoeaka's  wealth,  praised  him  for  his  indastry, 
confirmed  him  in  his  inheritance,  and  gave  him  his  daughter  in 
marriage.    (233-8) 

When  the  Teacher  heard  this  stoiy,  he  commented  on  it  and 
pronoanced  Stanza  24,  establishing  many  in  the  Fraits.    (238-9) 

Book  n.    Story  3.    Little  Roadling.29 

ILLUSTRATINO  STANZA   5  -  25. 

The  daaghter  of  a  rich  treasurer  of  Rajagaha  yielded  her  chastity  to 
a  slave,  and  fearing  that  she  woald  be  discovered,  fled  with  her  lover  to 
a  distant  place.  When  the  time  of  her  delivery  was  near  at  hand  she 
expressed  a  desire  to  return  home ;  but  her  lover,  fearing  to  accompany 
her,  put  her  ofi"  from  one  day  to  another,  until  finally  she  took  matters 
into  her  own  hands  and  started  out  alone.  The  pains  of  travail  came 
upon  her  by  the  way,  and  she  was  delivered  of  a  son.  Just  then  her 
lover,  who  had  learned  her  destination  firom  the  neighbors,  arrived  on 
the  scene,  and  found  her  quite  willing  to  go  back  with  him.  As  the 
child  had  been  bom  by  the  road,  they  agreed  to  call  him  Roadling. 
After  a  time  the  same  thing  happened  again,  and  again  they  called 
the  second  child  Roadling,  distinguishing  between  the  two  by  calling  the 
older  "  Big  Roadling,"  and  the  younger  *'  Little  Roadling."  (239-241) 

One  day  Big  Roadling  heard  some  other  boys  talking  about  their 
uncles  and  grandfathers,  and  said  to  his  mother,  "  Have  n't  we  any  1 " 
"  Oh,  yes  I "  said  she ;  ^^  you  have  a  grandfrither  who  is  a  rich  treasurer, 
living  at  R&jagaha,  and  many  other  relatives  there  besides."  "  Why 
don't  we  go  and  see  them ! "  The  mother  evaded  the  question  and 
spoke  of  the  matter  to  her  husband.  "  Why  won't  you  take  the  chil- 
dren to  their  grandfather's  1  Ton  don't  suppose  my  parents  are  going 
to  eat  you  alive,  do  you ! "  "I  should  never  dare  to  buce  them,  but  I 
am  willing  to  take  them  as  far  as  the  city."  ''  That  will  do ;  all  I  want 
is  to  have  them  see  their  grandparents."  So  all  four  started  out  for 
Rdjagaha,  and  when  they  reached  the  city,  the  mother  sent  word  to 
her  parents  that  she  had  returned.  Her  parents  refrised  to  see  her, 
but  sent  her  a  sufficient  sum  of  money  for  her  support^  and  told  her 
that  she  might  go  with  her  husband  and  Hve  wherever  she  desired. 
The  children,  however,  they  consented  to  receive  into  their  house ;  and 

»  a.  Ja.  i.  114-120.    Rogers,  pp.  Gl-71. 


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522  PROCEEDINGS  OF  THE  AMEBICAN  ACADEliT. 

that  is  how  Big  Roadling  and  Little  Roadling  came  to  be  brought  np 
in  their  grand&ther's  house.     (241-2) 

Big  Roadling  used  to  accompany  his  grandfiGither  to  hear  the  Teacher 
preach  the  Law,  and  one  day  told  his  grand&ther  that  he  would  like 
to  become  a  monk.  His  grand&ther  was  greatly  delighted,  and  took 
him  to  the  Teacher,  who  received  him  as  a  monk,  and  somewhat  later 
professed  him.  After  a  time  Big  Roadling  attained  Arahatship,  and 
desiring  to  have  his  brother  attain  what  he  had  attained,  went  to  his 
grandfather  and  asked  permission  to  receive  Little  Roadling  into  the 
Order.  The  grandfather  readily  gave  his  consent,  and  so  Little 
Roadling  also  became  a  monk.     (242-4) 

Now  in  a  previous  existence  under  the  Buddha  Eassapa,  Little 
Roadling  had  once  made  fun  of  a  dullard  monk ;  and  in  consequence  of 
this  act,  he  was  now  unable  to  master  a  single  stanza  in  the  course  of 
four  whole  months.  Big  Roadling  was  so  disgusted  that  he  expelled 
him  from  the  monastery.  Little  Roadling,  however,  was  greatly 
attached  to  the  religion  of  Buddha,  and  did  not  give  up  the  monastic 
life.    (244) 

One  day  Jivaka  Eomftrabhacca  went  to  Big  Roadling  and  asked  him, 
"  How  many  monks  are  there  under  the  Teacher ! "  "  Five  hundred." 
"  I  invite  them  all  to  take  a  meal  with  me  to-morrow."  "  The  la3rman 
Little  Roadling  is  a  dullard ;  I  accept  the  invitation  for  everybody  but 
him."  When  Little  Roadling  heard  his  brother  speak  thus,  he  decided 
to  give  up  the  monastic  life  on  the  morrow.  The  Teacher  became 
aware  of  his  intention,  led  him  into  his  own  perfumed  chamber,  gave 
him  a  piece  of  cloth,  and  said  to  him,  '*  Little  Roadling,  £stce  towards 
the  East,  rub  this  cloth,  and  say  as  you  do  so,  '  Removal  of  Impurity* 
Removal  of  Impurity.' "  The  Teacher  then  went,  accompanied  by  the 
monks,  to  Jivaka's  house.     (244-6) 

Af^r  Little  Roadling  had  rubbed  the  cloth  for  a  time,  he  perceived 
that  it  had  become  soiled,  and  a  sense  of  the  impermanenoe  of  things 
came  to  him.  At  that  moment  an  apparition  of  the  Teacher  appeared 
before  him  and  pronounced  the  Stanzas  beginning  with  the  words, 
"  Impurity  is  Lust  .  .  .  Impurity  is  Hatred  .  .  .  Impurity  is  Infi&tu- 
ation."  At  the  conclusion  of  the  Stanzas  Little  Roadling  attained 
Arahatship,  acquired  Four-fold  Knowledge,  and  became  a  master  of 
the  Three  Fitakas.  (This  was  because,  in  a  former  existence  as  a 
king,  he  gained  a  sense  of  impermanence  by  contemplating  a  cloth 
which  had  become  soiled  with  the  sweat  of  his  brow.)     (246-7) 

When  Jivaka  offered  the  Water  of  Donation  to  the  Teacher,  the 
latter  placed  his  hand  over  the  vessel,  and  said,  "Are  there  no 
monks  in  the  monastery  1"    Big  Roadling  replied,  "No,  indeed." 


BX7RLINGAME.  —  BUDDHAGHOSA's  DHAMMAPADA    COMMENTARY.       523 

The   Teacher  said,   "Tes,    there  are."    Jlvaka  sent   a  servant  to 

find  out.  At  that  moment  Little  Roadling,  aware  of  what  his 
brother  had  said,  exercised  his  supernatural  power  and  filled  the 
Mango-grove  with  a  thousand  monks.  Jivaka's  servant  returned  and 
said,  "The  whole  Mango-grove  is  full  of  monks."  The  Teacher  said 
to  him,  "Go  and  tell  Little  Roadling  to  come  hither."  The  servant 
went  to  the  grove  and  called  out,  "Little  Roadling,  come  hither." 
Thereupon  the  cry  went  up  from  a  thousand  throats,  "  Here  I  am ! 
Here  I  am  ! "  The  servant  went  back  to  the  Teacher  and  said,  "  They 
all  say  they  're  Little  Roadling."  "  Well,  then/'  said  the  Teacher,  "  go 
back  and  take  by  the  hand  the  first  one  who  says  he 's  Little  Roadling, 
and  the  rest  will  vanish."  The  servant  did  as  he  was  told  and  soon 
returned  with  his  man.     (247-8) 

After  the  meal  Little  Roadling  returned  thanks,  and  the  Teacher, 
accompanied  by  the  monks,  withdrew.  When  the  monks  assembled  in 
the  evening,  they  discussed  Little  Road  ling's  expulsion  from  the  mon- 
astery and  subsequent  attainment  of  Arahatship,  and  were  loud  in 
their  praises  of  the  Buddha.  All  of  a  sudden  the  Buddha  appeared 
in  their  midst  and  said  to  them,  "  This  is  not  the  first  time  Little 
Roadling  has  shown  himself  a  dullard  ;  aforetime,  too,  he  was  a  dullard. 
Nor  is  it  the  first  time  I  have  assisted  him ;  aforetime,  too,  I  assisted 
him,  and  by  my  assistance  he  attained  no  less  success  in  the  things  of 
this  world  than  he  has  just  attained  in  higher  things."  "Tell  us  all 
about  it,"  said  the  monks ;  whereupon  the  Teacher  began  the  following 
story  of  the  past :     (248-250) 

The  World-renowned  Teacher,  the  Young  Man,  and  the  King  of 
Benares.  A  young  man  of  Benares  once  went  to  Takkasila  and  became 
a  pupil  of  a  World-renowned  Teacher.  He  was  most  faithful  in  the 
performance  of  his  duties  as  a  pupil,  but  such  a  dullard  was  he  that 
after  a  long  term  of  residence  he  was  unable  to  repeat  a  single  Stanza, 
Finally  he  became  discouraged,  and  went  to  his  Teacher  and  told  him 
that  he  was  going  to  give  it  up  as  a  bad  job  and  go  back  home.  The 
Teacher  had  by  this  time  become  much  attached  to  his  pupil  by  reason 
of  the  latter^s  dutifulness  to  him ;  so  he  took  him  to  the  forest  and 
taught  him  a  charm,  telling  him  that  it  would  insure  him  a  living,  and 
impressing  it  upon  him  that  he  must  recite  it  over  and  over  again  to 
avoid  the  possibility  of  forgetting  it.  And  this  is  the  way  the  charm 
went :  "  You  're  at  it,  you  're  at  it ;  why  are  you  at  it  1  /  know  what 
you  're  at."  When  the  young  man  had  mastered  the  charm  he 
returned  to  Benares.     (250-251) 

It  so  happened  just  at  this  time  that  the  King  of  Benares  made  a 
careful  examination  of  his  thoughts,  words,  and  deeds,  for  the  purpose 


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524  PBOCEEDINQS  OF  THE  AMERICAN  ACADEICT. 

of  disooyering  in  what  partioalars  he  might  have  £uled.  So  £sur  as  he 
ooald  see,  his  oondact  had  been  quite  ooireot ;  bat  then  he  reflected, 
"  A  person  never  sees  his  own  &ults ;  it  takes  another  person  to  see 
them."  Accordingly,  he  decided  to  find  oat  jast  what  was  the  candid 
opinion  of  his  subjects ;  and  after  mghtfaJl  he  put  on  a  disguise,  and 
went  about  the  streets  eavesdropping.    (251-2) 

The  first  house  the  king  came  to  was  that  of  the  young  man  who  had 
just  returned  from  Takkasila.  The  king  observed  that  some  robbers 
were  in  the  act  of  breaking  into  the  house ;  so  he  took  his  stand  in  the 
shadow  of  the  house  and  awaited  developments.  The  robbers  made 
such  a  noise  effecting  an  entrance  that  they  woke  up  the  young  man ; 
whereupon  the  latter  began  to  recite  his  chiurm :  '*  Tou  're  at  it^  yon  're 
at  it ;  why  are  you  at  it !  /  know  what  you  're  at"  The  robbers  ex- 
claimed, "  We  're  discovered ;  run  for  your  lives ! "  dropped  their  spoils, 
and  fled.  The  next  day  the  king  sent  for  the  young  man,  got  bun  to 
teach  him  the  spell,  and  presented  him  with  a  thousand  pieces  of 
money.    (252-3) 

That  very  day  the  Prime  Minister  went  to  the  royal  barber,  presented 
him  with  a  thousand  pieces  of  money,  and  said,  **  The  next  time  you 
go  to  shave  the  king,  cut  his  throat  with  a  rasor ;  then  you  shall  be 
Prime  Minister,  aud  I  shall  become  king."  "Agreed,"  said  the  barber. 
A  day  or  two  later  the  barber  went  in  to  shave  the  king ;  and  as  he 
sharpened  his  razor,  he  said  to  himself,  "  One  stroke,  and  it 's  all  dona" 
Just  at  that  moment  the  king  began  to  recite' the  charm :  "  Tou  're  at 
it,  you  're  at  it ;  why  are  you  at  it !  /  know  what  you  're  at"  Beads 
of  sweat  stood  out  on  the  forehead  of  the  barber ;  he  threw  his  razor 
away  in  terror,  and  flung  himself  at  the  feet  of  the  king.  Now  kings 
know  a  thing  or  two ;  and  the  King  of  Benares  immediately  exclaimed, 
"  Villain,  you  thought  I  did  n't  know."  "  Sire,  spare  my  life."  "  Have 
no  fear ;  only  tell  me  the  trutL"  "  It  was  the  Prime  Minister  that 
put  me  up  to  this."  Thereupon  the  king  banished  the  Prime  Minister, 
and  appointed  in  his  place  the  young  man  who  taught  him  the  spelL 

(253-4) 

"At  that  time,"  said  the  Teacher,  "Little  Roadling  was  the  young 
man,  and  I  was  the  World-renowned  Teacher.  Aforetime,  too.  Little 
Roadling  was  a  dullard,  and  I  helped  him."  The  Teacher  closed  his 
discourse  by  telling  the  Gtilakasetthi  J&taka  and  identifying  the  births. 
On  a  later  occasion  the  monks  commented  on  Little  Roadling's  deter- 
mination never  to  give  up ;  whereupon  the  Teacher  assured  theili  that 
the  highest  reward^  are  within  reach  of  the  persevering  disciple,  and 
pronounced  Stanza  25,  establishing  many  in  the  Fruits.    (254-^) 


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BURUNGAME.  —  BUDDHAGHOSA^S   DHAMMAPADA   COMMENTARY.       525 
Book  n.    Story  4.    When  Foolish  Folk  BSade  Holiday. 

ILLUSTBATINO  STANZAS  fr-7  -  26-27. 

On  a  certain  oocasion  the  foolish,  ignorant  people  of  S&vatthi  used 
to  smear  themselves  with  cow-dung,  and  give  themselves  up  to  license 
for  a  period  of  seven  days.  They  went  about  the  city  insulting  every- 
body they  met,  even  their  own  kinsmen,  and  persons  devoted  to  the 
religious  life ;  and  would  desist  only  on  the  payment  of  a  forfeit  Dur- 
ing this  period  of  disorder  the  Teacher  and  the  monks  remained  within 
the  walls  of  the  monastery.  When  the  noble  disciples  told  him  of  the 
insults  to  which  they  had  been  subjected,  he  expressed  his  disapproval 
of  the  misconduct  of  the  foolish  folk,  and  pronounced  Stanzas  26-27, 
at  the  conclusion  of  which  many  were  established  in  the  Fruits. 

Bookn.    Story  5.    KaMapa  the  Great,  IRder. 

ILLUSTRATING  STANZA  8-28. 

On  a  certain  occasion,  during  the  time  when  the  Elder  Eassapa  was 
living  in  Pipphali  Cave,  he  went  to  R&jagaha  to  collect  alms ;  and  after 
he  had  eaten  his  meal,  he  sat  down  and  endeavored  to  obtain  by  Su- 
pernatural Vision  a  comprehension  of  Birth  and  Rebirth.  The  Teacher, 
seated  at  Jetavana,  exercised  Supernatural  Vision,  and  at  once  per- 
ceived what  E^assapa  was  about.  '*  That  is  beyond  your  range,  Eas- 
sapa,"  said  he ;  '*  only  a  Buddha  is  able  to  comprehend  the  Totality  of 
Existences."  Then  the  Teacher  sent  forth  an  apparition  of  himself, 
which  went  to  Kassapa  and  pronounced  Stanza  28.  At  the  conclusion 
of  the  Stanza,  many  were  established  in  the  Fruits.    (258-260) 

Book  n.    story  6.    The  Two  Brethren. 

ILLUSTRATING  STANZA  9  -  29. 

Two  brethren  obtained  a  subject  of  meditation  from  the  Teacher, 
and  retired  to  the  forest.  One  of  them  was  heedful  and  zealous,  and 
in  a  short  time  attained  Arahatship.  The  other  was  heedless  and  lazy. 
When  the  two  brethren  returned  to  the  Teacher,  and  the  latter  learned 
how  they  had  spent  their  time,  he  compared  the  zealous  monk  to  a  race- 
horse and  the  lazy  monk  to  a  hack,  and  pronounced  Stanza  29,  estab- 
lishing many  in  the  Fruits.    (260^263) 


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526  PB0CEEDIN08  OF  THE  AHEBICAN  ACADEMY. 

Book  n.    Story  7.    Mahftli'B  Question. 

ILLUSTRATING  STANZA   10  —  30. 

One  day  a  Licchavi  prince  named  Mahali,  who  had  heard  ihe  Sat- 
tanta  entitled  Sakka's  Question  recited  by  the  Teacher,  went  to  the 
latter  and  asked  him,  "  Did  you  ever  see  Sakka  1 "  "  Oh,  yes,"  replied 
the  Teacher.  "  It  must  have  been  a  counterfeit  of  Sakka,"  returned 
Mahali,  "  for  it  is  a  difficult  matter  to  get  a  look  at  Sakka."  "  Never- 
theless," said  the  Teacher,  "I  am  well  acquainted  with  Sakka;  and 
what  is  more,  I  know  all  about  the  meritorious  deeds  by  means  of 
which  he  rose  to  the  lordship  of  the  gods."  Then  the  Teacher  enum- 
erated Sakka's  meritorious  deeds  in  his  human  existence  as  Magha. 
"  Tell  me  all  about  Magha,"  said  MahalL  "  Well,  then,  listen,"  replied 
the  Teacher,  and  then  told  the  following  story  of  the  past :     (263-5) 

Maglia.30 

Once  upon  a  time  a  youth  named  Magha  went  about  his  native  vil- 
lage in  the  kingdom  of  Magadha  doing  all  manner  of  good  works ;  and 
in  the  course  of  time  gathered  others  about  him,  until  finally  there 
were  thirty-three  persons  in  the  village  keeping  the  Five  Precepts  and 
doing  works  of  merit  The  village  headman  observed  their  actions, 
and  said  to  himself,  "  If  these  men  would  only  drink  strong  drink  u&d 
do  as  other  men  do,  I  should  ght  something  out  of  it"  Accordingly 
he  said  to  them,  "  What 's  this  you  're  doing  1 "  "  Treading  the  Heav- 
enly Path."  "  That 's  no  occupation  for  housfeholders ;  why  don't  you 
eat  fish  and  flesh,  drink  strong  drink,  and  have  a  good  time ! "  Magha 
and  his  companions  rejected  his  suggestion ;  whereupon  he  determined 
to  destroy  them.     (265-7) 

The  village  headman  went  to  the  king  and  told  him  that  there  was 
a  band  of  robbers  in  the  village.  The  king  immediately  ordered  them 
to  be  trampled  to  death  by  elephants.  But  the  elephants  refused  to  go 
near  them.  When  this  was  reported  to  the  king,  he  concluded  that 
there  must  be  a  reason  for  it;  accordingly  he  had  the  thirty-three 
youths  summoned  before  him,  told  them  the  charge  the  village  head- 
man had  brought  against  them,  and  listened  to  their  story.  The  result 
was  that  he  begged  their  pardon  for  having  so  misunderstood  them, 
made  the  village  headman  their  slave,  gave  them  an  elephant  to  ride 
on,  and  placed  the  entire  resources  of  the  village  at  tiieir  disposal 
(267-8) 

At  this  the  youths  rejoiced  greatly  and  resolved  to  abound  yet  more 

»  a.  J&.  i.  199-206. 


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BURLINGAME.  —  BUDDHAGHOSA's   DHAMMAPADA   COMMENTARY.        527 

in  good  works.  So  they  summoned  a  carpenter,  and  had  him  erect  a 
rest-house  for  the  multitude  at  the  junction  of  four  highways.  As 
they  had  lost  all  desire  for  women,  ihey  would  not  allow  women  to 
share  in  the  work     (26a-9) 

Now  there  were  four  women  living  in  Magha's  house,  Joy,  Thought- 
ful, Goodness,  and  Wellborn.  One  day  Goodness  bribed  the  carpenter 
to  give  her  the  chief  share  in  the  erection  of  the  hall.  The  carpenter 
made  a  pinnacle,  cut  this  inscription  on  it,  "  This  Hall  is  named  for 
Goodness,''  wrapped  the  pinnacle  in  a  cloth,  and  laid  it  aside.  When 
the  hall  was  nearly  completed,  the  carpenter  said  to  his  masters,  "  We 
have  forgotten  something."  "  What  is  it  ? "  said  they.  "A  pinnacle." 
"  Let 's  get  one."  "  But  it 's  too  late  to  season  the  wood."  "  Well, 
what  19  to  be  done?"  "Perhaps  we  might  find  one  ready-made." 
The  carpenter  immediately  procured  the  pinnacle  he  had  made  for 
Goodn^s ;  and  thus  (Goodness  obtained  the  chief  share  in  the  erec- 
tion of  the  halL    (269-270) 

The  thirty-three  youths  prepared  thirty-three  wooden  seats,  and 
entertained  visitors  handsomely,  the  elephant  going  out  to  meet  each 
arrival  and  performing  the  usual  courtesies.  Magha  planted  an  Ebony- 
tree  near  the  hall,  and  under  the  tree  set  up  a  stone  seat  Joy 
provided  a  lotus  tank,  and  Thoughtful  a  flower  garden.  Wellborn, 
thinking  that  it  was  a  sufficient  distinction  to  be  a  cousin  of  Magha, 
did  nothing  but  adorn  herself.  Magha,  having  fulfilled  the  Seven 
Injunctions,  was  at  the  end  of  his  allotted  term  of  life  reborn  in  the 
world  of  the  Thirty-three  as  Sakka^  king  of  the  gods ;  Magha's  com- 
panions were  also  reborn  there,  as  was  also  the  carpenter,  who  became 
Vissakamma.  (270-272) 

Now  at  this  time  there  were  Asuras  dwelling  in  the  world  of  the 
Thirty-three;  and  when  they  became  aware  that  some  entirely  new 
gods  had  been  born  in  their  midst,  they  prepared  strong  drink  to  wel- 
come them.  Sakka  forbade  his  companions  to  touch  it^  and  they 
obeyed  him ;  but  the  Asuras  got  very  drunk.  Then  Sakka  gave  the 
signal,  and  his  companions  picked  up  the  Asuras  by  the  heels,  and 
flung  them  down  into  the  abyss.  Thereupon  there  sprang  up  at  the 
foot  of  Mount  Sineru  the  Palace  of  the  Asuras  and  the  Tree  that  is 
called  Pied  Trumpet-flower.  And  when  the  conflict  between  the  Gods 
and  the  Asuras  was  over,  and  the  Asuras  had  been  defeated,  there 
sprang  into  existence  the  City  of  the  Thirty-three,  crowned  with  a 
magnificent  palace  called  the  Palace  of  Victory.  A  Coral-tree  sprang 
up  to  correspond  with  the  Ebony-tsee  Magha  had  planted,  and  at  the 
foot  thereof,  to  correspond  with  the  stone  seat  he  had  set  up,  stood 
Sakka's  Yellowstone  Throna    The  elephant  was  reborn  as  the  god 


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528  PB0CEEDIN08  OF  THE  AMEBICAN  ACADEMY. 

Erftvana ;  since  there  are  no  animals  in  the  world  of  the  Thirty-three, 
whenever  Er&vana  wished  to  go  into  the  garden  to  play,  he  would  lay 
aside  his  godhead  and  become  an  elephant  for  the  time  being.  Er&vana 
created  gigantic  water-pots  for  each  member  of  Sakka's  retinaa 
Each  vessel  held  seven  tusks;  each  task,  seven  tanks;  each  tank, 
seven  lotas  plants;  each  plant,  seven  flowers;  each  flower,  seven 
leaves;  each  leaf,  seven  celestial  njrmphs,  who  danced  unceasingly. 
For  Sakka  he  created  a  water-pot  much  larger  than  the  others.  Above 
hang  a  canopy  with  a  fringe  of  bells  whose  sound  was  as  the  masic  of 
the  celestial  choir.  Beneath  it  was  a  jewelled  couch,  where  Sakka 
reclined  in  state.  Such  was  the  splendor  in  the  enjoyment  of  which 
Sakka  lived.  (272-4) 

When  Goodness,  Joy,  and  Thoughtfi^l  died,  they  were  reborn  in  the 
world  of  the  Thirty-three ;  and  through  the  effect  of  their  respective 
benefisu^tions  there  arose  a  mansion  named  Groodness,  a  lotus  tank 
named  Joy,  and  a  creeper-grove  named  Thoughtful  When  Wellborn 
died,  she  was  reborn  as  a  crane  in  a  mountain  cave.    (274-5) 

Sakka  surveyed  his  handmaidens,  and  desiring  that  Wellborn  should 
be  reborn  as  one  of  th^n,  went  to  her  in  disguise,  conducted  her  to  the 
world  of  the  Thirty-three,  let  her  see  her  friends,  and  assured  her  that 
she  could  attain  equal  happiness  by  keeping  the  Five  Precepts.  This 
she  promised  to  do.  After  a  few  days  Sakka^  desiring  to  test  her 
sincerity,  lay  down  on  the  sand  in  the  form  of  a  fish.  The  crane, 
thinking  that  it  was  dead,  seized  it  in  her  beak.  Just  as  she  was 
about  to  swallow  it,  it  wiggled  its  tail,  whereupon  the  crane  dropped  it. 
Three  times  Sakka  tried  this  stratagem,  and  three  times  the  crane,  dis- 
covering that  the  fish  was  alive,  refused  to  eat  it  Then  Sakka  re- 
sumed his  proper  form,  praised  the  crane,  and  departed.     (275-7) 

At  the  end  of  her  existence  as  a  crane,  Wellborn  was  reborn  at 
Benares  as  the  daughter  of  a  potter.  Sakka  disguised  himself  as  a 
peddler,  filled  a  cart  with  precious  jewels  disguised  as  cucumbers,  went 
to  the  city,  and  cried  out, "  Cucumbers  in  exchange  for  Five  Precepts." 
The  inhabitants  of  the  city  brought  kidney-beans,  and  when  the  peddler 
refused  them,  they  said,  "What  are  these  *  precepts'  like!  are  they 
black  or  brown  1 "  "  Neither,"  said  the  peddler.  "  Oh,"  said  they, 
"  we  have  heard  a  potter's  daughter  say,  '  I  keep  the  precepts ; '  you 
might  try  her."  So  Sakka  went  to  the  potter's  daughter,  revealed 
himself  to  her,  gave  her  the  jewels,  praised  her,  and  departed.    (277-8) 

At  the  end  of  her  existence  as  a  potter's  daughter.  Wellborn  was 
reborn  in  the  world  of  the  Asuras  as  the  daughter  of  Vepacitti,  king  of 
the  Asuras,  a  bitter  enemy  of  Sakka.  One  day  Vepacitti  assembled  all 
the  hosts  of  the  Asuras,  and  giving  hia  daughter  a  wreath  of  flowers, 


BURLINGAME.  —  BUDDHAGHOSA's  DHAMMAPADA  COMMENTARY.       529 

directed  her  to  choose  a  bnsband.  At  that  moment  Sakka,  disguised 
as  an  aged  Asura,  sat  down  in  the  oater  fringe  of  the  assembly.  The 
maiden  immediately  threw  the  wreath  of  flowers  over  his  head  and 
chose  him  for  her  husband.  He  took  her  by  the  hand,  shouted  out, 
"  I  am  Sakka,"  and  flew  up  into  the  air.  The  Asuras  cried  out,  "  We 
have  been  fooled  by  old  Sakka,"  and  started  up  in  pursuit     (278-9) 

Sakka's  charioteer,  Matali,  brought  up  the  chariot  Victory,  and  Sakka, 
after  assisting  Wellborn  to  mounts  set  out  for  the  city  of  the  gods. 
When  they  reached  the  Forest  of  the  Silk-cotton  Trees,  the  fledglings 
of  the  Garula  birds,  fearing  that  they  were  going  to  be  crushed  to 
death,  shrieked  aloud ;  whereupon  SaUca  said  to  his  charioteer,  "  Let 
not  these  creatures  perish  on  my  account;  turn  back  the  chariot.'' 
At  this  the  Asuras  concluded  that  reinforcements  must  have  come  np, 
and  abandoned  the  pursuit  Sakka  bore  Wellborn  to  the  city  of  the 
gods  and  made  her  chief  among  twenty-five  millions  of  celestial 
nymphs.  Thereafter,  when  the  Asuras  made  preparations  to  attack 
Sakka,  the  latter  placed  at  the  gates  of  his  city  images  of  Indra  bear- 
ing the  thunderbolt.  When  the  Asuras  saw  the  images,  they  invariably 
concluded  that  Sakka  was  no  longer  there,  and  departed.    (279-280) 

The  Teacher  extolled  Magha's  earnestness,  and  pronounced  Stanza 
80,  at  the  conclusion  of  which  Mahali  was  established  in  the  Fruit  of 
Conversion,  and  many  others  were  established  in  the  Three  Fruits. 
(280-281) 

Book  n.    Story  8.    A  Certain  Monk. 

ILLUSTRATING    STANZA    11-31. 

A  certain  monk  had  the  Teacher  instruct  him  in  the  ascetic  practices 
which  lead  to  Arahatship,  and  retired  to  the  forest  to  meditate.  In 
spite  of  his  best  efibrts,  he  was  unable  to  attain  Arahatship ;  therefore 
he  decided  to  return  to  the  Teacher  and  ask  him  to  assign  him  a 
specific  subject  of  meditation.  On  the  way  he  caught  sight  of  a  forest 
fire ;  whereupon  he  hastily  climbed  a  bare  mountain,  and  as  he  watched 
the  fire,  concentrated  his  mind  on  the  following  thought :  "  As  this 
fire  goes  its  way  consuming  all  obstacles  both  great  and  small,  so  also 
ought  I  to  go,  consuming  all  obstacles  l)oth  great  and  small  with  the 
fire  of  knowledge  of  the  Noble  Path."    (281-2) 

As  the  Teacher  sat  in  his  Perfumed  Chamber,  he  became  aware  of 
what  the  monk  was  doing,  and  sent  forth  an  apparition  of  himself, 
which  went  to  the  monk  and  pronounced  Stanza  31.  At  the  conclu- 
sion of  the  Stanza,  the  monk  attained  Arahatship.    (282-3) 

VOL.  XLV.  — 34 


I 


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530  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

Book  n.    Story  9.    Tissa  of  the  Market  Town,  Elder. 

ILLUSTRATING  STANZA    12=32. 

A  certain  noble  youth  who  was  bom  and  brought  up  in  a  market 
town  not  &r  from  SS.vatthi,  was  received  into  the  Order  by  the 
Teacher,  and  was  thereafter  known  as  Tissa  of  the  Market  Town, 
Elder.  He  wanted  little,  was  satisfied  with  what  he  had,  and  lived 
an  active,  blameless  life.  All  his  life  long  he  remained  within  the 
borders  of  his  native  village,  in  spite  of  the  fact  that  in  near-by 
Ss.vatthi,  Pasenadi  Kosala,  An^thapindika,  and  others  were  bestowing 
alms,  the  like  of  which  had  never  been  seen  before.  One  day  the 
Teacher  sent  for  him,  and  said  to  him,  "  Monk,  it  is  no  wonder  that 
you,  who  have  such  a  one  as  I  am  for  your  Master,  should  want  littla'' 
When  the  other  monks  asked  the  Teacher  to  explain  himself  the 
latter  told  them  the  following  story  of  the  past :  (283-4) 

Sakka  and  the  Parrot.  ^^  Once  upon  a  time  a  great  many  parrots 
lived  in  a  grove  of  fig-trees  in  the  Himalaya  country.  The  king-parrot, 
when  the  fruit  of  the  tree  in  which  he  lived  had  come  to  an  end,  ate 
whatever  he  could  find,  drank  the  water  of  the  Ganges,  and  being  very 
happy  and  contented,  stayed  where  he  was.  In  &ct,  he  was  so  happy  and 
contented  that  the  abode  of  Sakka  began  to  shake.  Thereupon  Sakka 
decided  to  put  him  to  the  test,  and  by  his  supernatural  power  withered 
up  the  tree.  When  Sakka  perceived  that  this  made  no  difiierence  at 
all  to  the  parrot,  he  decided  to  give  the  parrot  his  choice  of  a  boon  ; 
whereupon,  taking  the  form  of  a  royal  goose,  and  preceded  by  Well- 
bom  in  the  form  of  an  Asura  n3rmph,  he  went  to  the  parrot  and  asked 
him  why  his  heart  delighted  in  a  tree  that  was  withered  and  rotten. 
(This  story  is  identical  with  the  Mahdsuka  Jataka,  which  will  be  found 
in  the  Tenth  Nip^ta ;  ^^  only  the  setting  is  different.  The  Jataka  goes 
on  to  say  that  the  parrot  replied,  "  This  tree  has  been  good  to  me  in 
the  past ;  why  should  I  forsake  it  now  ? "  Thereupon  Sakka  caused 
the  tree  to  bloom  anew,  and  to  bear  ambrosial  fruit.)     (284-5) 

"  At  that  time,"  said  the  Teacher,  "  Ananda  was  Sakka,  and  I  was 
the  parrot  It  is  no  wonder  that  Tissa  wants  little,  having  found  a 
Teacher  like  me."  Then  he  pronounced  Stanza  3^,  at  the  end  of  which 
Tissa  attained  Arahatship,  and  many  others  were  established  in  the 
Fruits.     (285-6) 

w  Cf.  Jft.  iii.  491-4. 

'*  Norman  calls  attention  to  the  fact  that  it  actually  occurs  in  the  Ninth 

Nip&ta. 


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GoQQle 


BURUNGAME.  —  BUDDHAGHOSA's   DHAMMAPADA   COMHIENTART.       531 
Book  m.    story  1.    Meghiya,  Elder. 

ILLUSTBATINO  STANZAS   1-2  "-  33-34. 

According  to  a  story,  the  details  of  which  will  be  found  in  the  Sat- 
tanta  entitled  Meghiya,  the  Elder  Meghiya  made  little  progress  in 
wrestling  with  the  flesh  until  the  Teacher  impreased  upon  him  the  im- 
portance of  bringing  the  thoughts  into  subjection,  by  pronouncing 
Stanzas  33-34 ;  whereupon  Meghiya  was  established  in  the  Fruit  of 
Conversion,  and  many  others  in  the  Three  Fruits.    (287-9) 

Book  in.    Story  2.    A  Certain  Monk. 

ILLUSTBATINO  STANZA  3  »  35. 

Seventy  monks  once  had  the  Teacher  instruct  them  in  the  ascetic 
practices  which  led  to  Arahatship,  and  went  to  a  certain  village  named 
M&tika  in  the  kingdom  of  Kosala  to  collect  alms.  A  lay  sister,  mother 
of  the  owner  of  the  village,  offered  them  hospitality,  and  provided 
them  with  food  and  lodging  during  the  three  rainy  months.  At  her 
request  the  monks  instructed  her  in  the  ascetic  practices,  which  she 
performed  with  such  diligence  that  in  advance  of  her  instructors  she 
attained  the  Three  Paths  and  Fruits  and  the  Supernatural  Faculties. 
As  she  was  thus  enabled  to  know  the  precise  needs  of  the  monks, 
thereafter  she  ministered  to  them  so  successfully  that  in  a  short  time 
they  too  attained  Arahatship.  At  the  close  of  the  rainy  season  they 
took  leave  of  their  hostess  and  returned  to  the  Teacher.  When  the 
latter  remarked,  "  You  look  as  if  you  had  fared  well,"  the  monks 
replied,  **  We  did,  indeed ;  our  hostess  knew  the  secret  desires  of  our 
hearts,  insomuch  that  no  sooner  did  we  think  of  our  needs  than  she 
immediately  supplied  them."    (290-293) 

A  certain  monk  heard  this  and  was  immediately  seized  with  a  desire 
to  enjoy  so  pleasant  an  experience.  Accordingly  he  had  the  Teacher 
instruct  him  in  the  ascetic  practices,  went  to  the  house  of  the  lay 
sister,  and  accepted  her  offer  of  food  and  lodging.  He  found  every- 
thing exactly  as  the  monks  had  represented  it.  But  then  the  thought 
occurred  to  him,  "  If  I  should  entertain  a  sinful  thought,  she  would 
doubtless  seize  me  by  the  top-knot,  and  treat  me  as  people  treat 
thieves;  I  had  best  get  away  from  here."  So  he  returned  to  the 
Teacher  and  told  the  latter  what  had  made  him  change  his  plans. 
The  Teacher  admonished  him  to  control  his  thoughts,  pronounced 
Stanza  35,  thereby  establishing  many  in  the  Fruits,  and  sent  the  monk 
back  to  the  house  of  the  lay  sister.  The  latter  ministered  to  the  needs 
of  the  monk  so  successfully  that  in  a  short  time  he  attained  Arahat- 


532  PBOCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 

ship.  One  day,  while  the  moDk  was  experiencing  the  bliss  of  the  Path 
and  the  Fruit,  he  was  filled  with  gratitude  towards  the  lay  sister,  ajid 
became  curious  to  know  whether  she  had  befriended  him  in  previoujs 
existeiioes.  So  he  called  up  before  his  mind  ninety-nine  previous  ex- 
istences, and  to  his  horror  perceived  that  in  each  of  these  existences 
she  had  murdered  him.  "  Oh,  what  a  sinner  she  has  been  I  "  thought 
he.  At  the  same  moment  the  lay  sister,  sitting  in  her  own  chamber, 
became  aware  of  what  was  passing  through  his  mind.  "  Call  up  one 
more  existence,"  said  she.  By  the  power  of  Supernatural  Audition  the 
monk  immediatdy  heard  what  she  said ;  whereupon  he  called  up  before 
his  mind  the  hundredth  existence,  and  perceived  that  in  that  existence 
she  had  spared  his  life.  Then  he  rejoiced  greatly,  and  straightway 
passed  into  Nibbftna.     (293-7) 

Book  in.    Btory  3.    A  Certain  Diacontented  Monk. 

ILLUSTRATINQ  STANZA   4  =  36. 

The  son  of  a  certain  treasurer  of  S&vatthi  performed  the  duties  of 
a  lajnnan  so  fiuthfully  as  to  win  the  appellation  "  Faithful"  But  after 
he  had  become  a  monk  he  grew  discontented  over  the  multitudinous 
duties  imposed  upon  him,  and  said  so  to  the  Teacher.  The  latter 
replied,  "  You  have  only  one  duty  to  perform ;  and  that  is  to  guard 
your  thoughts ;  if  you  do  that,  you  have  done  all."  The  Teacher  then 
pronounced  Stanza  36,  at  the  conclusion  of  which  the  discontented 
monk  was  established  in  the  Fruit  of  Conversion,  and  many  others 
were  established  in  the  Three  Fruits.    (297-300) 

Book  m.    Story  4.    Sangharakkhita'a  Nephew,  Elder. 

ILLUSTRATING  STANZA   5  -=  37. 

A  certain  noble  youth  of  Savatthi  retired  from  the  world,  was  ad- 
mitted to  the  Order,  and  in  a  short  time  attained  Arahatship.  His 
name  was  Sangharakkhita.  About  this  time  a  son  was  born  to  his 
youngest  sister  and  named  after  him.  When  Sangharakkhita's  nephew 
reached  the  age  of  manhood,  he  followed  his  uncle's  example  and 
entered  the  Order.  At  the  beginning  of  the  rainy  season  the  younger 
monk  procured  two  sets  of  monastic  robes,  intending  to  present  one  of 
them  to  his  uncle,  and  for  this  purpose  set  out  for  his  uncle's  quarters. 
When  he  arrived  at  his  destination,  he  discovered  that  the  older  monk 
had  not  yet  returned ;  so  he  swept  the  place  carefully,  procured  water 
for  washing  the  feet,  prepared  a  seat,  and  sat  down,  awaiting  his  uncle's 
return.  When  he  saw  his  uncle  coming  he  went  out  to  meet  him,  took 
his  bowl  and  robe,  seated  him,  femned  him  with  a  palm-leaf  fiui^  gave 


^ 


y  ^  \  '''"""^'"^^^^^^^  Digitized^GoOgle 


BURLINOAME.  —  BUDDHAGHOSA's    DHAMMAPADA    COMMENTARY.       533 

him  water  to  drink,  washed  his  feet,  brought  him  the  set  of  robes  he 
had  procured  for  him,  formally  presented  them  to  him,  and  then,  taking 
the  palm-leaf  hn  into  his  hands,  resumed  &nning  him.  Said  the  older 
monk,  "  Nephew,  I  have  a  complete  set  of  robes ;  use  these  yourself 
The  younger  monk  pleaded  with  his  uncle  to  reconsider  his  answer,  but 
the  older  monk  remained  obdurate.  The  younger  monk  was  so  bitterly 
disappointed  that  he  then  and  there  decided  to  give  up  the  monastic 
life  and  return  to  the  life  of  a  householder.  So  as  he  stood  there  beside 
the  older  monk,  swinging  the  palm-leaf  &n  to  and  fro,  he  pondered  in 
his  mind  ways  and  means  of  earning  a  living.  Finally  the  following 
thought  occurred  to  him  :     (300-302) 

"  I  will  sell  this  set  of  robes,  and  buy  me  a  ewe ;  ewes  are  very  pro- 
lific ;  every  lambkin  the  ewe  drops  I  will  sell ;  in  this  way  I  shall  be 
able  to  accumulate  a  lot  of  money.  When  I  have  done  that,  I  will 
procure  me  a  wife.  She  will  bear  me  a  son,  whom  I  will  name  after 
my  uncle.  I  will  put  my  son  in  a  go-cart,  and  taking  son  and  wife 
aloDg>  go  and  pay  my  respects  to  my  uncle.  As  I  journey  by  the  way 
I  will  say  to  my  wife,  *  Just  hand  me  my  son ;  I  wish  to  carry  him.' 
She  will  reply,  *  What 's  the  need  of  your  canying  the  boy  ?  go  ahead 
and  push  this  go-cart ; '  then  she  will  take  the  boy  into  her  arms  and 
say,  'I'll  carry  him  myself;'  whereupon,  finding  the  child  too  heavy 
for  her,  she  will  let  him  fiaJl.  Then  I  will  say  to  her,  *  You  would  n't 
let  me  carry  the  child,  in  spite  of  the  fact  that  you  could  n't  carry  him 
yourself;'  and  having  thus  said,  I  will  bring  down  my  stick  on  her 
back "...  At  that  moment  the  younger  monk  swung  his  fan  with 
great  force,  and  brought  it  down  on  the  head  of  his  uncle. ^^ 
(302-303) 

The  older  monk  considered  within  himself  "  Why  did  my  nephew 
strike  me  on  the  head  ? "  and  immediately  became  aware  of  what  was 
passing  through  his  nephew's  mind.  So  he  said,  "  Nephew,  you  did  n't 
succeed  in  hitting  the  woman ;  but  why  should  an  aged  Mder  sufier 
for  it?"  The  younger  monk  was  so  ashamed  of  himself  that  he 
immediately  threw  his  £mi  away  and  started  to  run  off.  But  the 
novices  and  young  monks  ran  after  him,  caught  him,  and  brought  him 
before  the  Teacher,  who  said  to  him,  "  Be  not  disturbed ;  only  guard 
your  thoughts  hereafter,"  and  pronounced  Stanza  37,  establishing  the 
young  monk  in  the  Fruit  of  Conversion,  and  many  others  in  the  Three 
Fruits.     (303-305) 

"  Compare  the  story  of  the  Brahman  and  his  Jar,  in  the  Paficatantra, 
Hertel's  ed.,  v.  7. 


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534  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

Bookm.    Story  5.  Cittahattha,  Elder.^ 

ILLUSTRAHNQ  STANEAS  6-7  -  38-39. 

A  noble  youth  of  Savattbi  oDce  became  a  monk  for  no  other  reason 
than  to  obtain  an  easy  livelitood.  After  a  few  days  he  tired  of  the 
monastic  life  and  returned  to  the  world.  Six  times  he  became  a  monk, 
and  as  many  times  returned  to  the  life  of  a  householder ;  wherefore  his 
brethren  called  him  Gittahattha  (Thought-controlled).  In  the  mean- 
time his  wife  became  great  with  child.  Once  more  he  decided  to 
become  a  monk,  and  entered  the  inner  chamb^  of  his  house  to  pro- 
cure his  yellow  robe.  There  on  the  bed  lay  his  wife  asleep.  Her 
garments  were  in  disarray,  saliva  was  flowing  from  her  mouth,  she  was 
snoring,  her  mouth  was  wide  open.  Her  appearance  remind^  him  of 
a  bloated  corpse.  At  that  moment  he  obtained  a  sense  of  impeima- 
nence,  and  taking  the  yellow  robe,  left  the  house  and  went  to  the 
monastery.  A  short  time  after  this,  his  seventh  reception  into  the 
Order,  he  attained  Arahatship.  The  Teacher,  contrasting  Cittahattha's 
former  and  latter  states,  pronounced  Stanzas  38-39.  The  monks  said, 
"  How  could  a  youth  destined  to  Arahatship  abandon  the  monastic 
life  six  times  ? "  *'  Easily  enough,"  said  the  Teacher ; ''  I  did  the  same 
thing  myself."    Then  he  told  the  following  story  of  the  past :  (305-311). 

Kuddaia  and  his  Spade.  Once  upon  a  time,  when  Brabmadatta 
reigned  at  Benares,  a  Pandit  named  Eudd&la  was  admitted  to  a  cer- 
tain heretical  Order,  but  after  a  few  months  renounced  the  monastic 
life,  all  because  of  his  attachment  for  a  blunt  spade  with  which  he  used 
to  till  the  ground.  This  happened  six  times.  Finally  Euddala  made 
up  his  mind  to  put  temptation  out  of  his  way ;  so  he  took  the  spade  to 
the  bank  of  the  Ganges,  closed  his  eyes,  and  threw  it  into  the  water. 
As  he  did  so  he  shouted  as  loud  as  he  could,  "  I  have  conquered ! " 
At  that  moment  along  came  the  King  of  Benares,  returning  from  a 
successful  expedition.  When  the  King  heard  Kuddala's  exclamation 
of  victory,  he  went  up  to  him  and  asked  him  what  he  meant  by  it 
Kuddaia  replied,  "Those  whom  you  have  conquered  will  have  to  be 
conquered  again ;  but  I  have  conquered  myself  for  good  and  alL"  At 
that  moment  Kudd&la  attained  Specific  Attainment  by  gazing  on  the 
water ;  whereupon  he  sat  cross-legged  in  the  air  and  instructed  the 
king  in  the  Law.  The  King  of  Benares  then  and  there  retired  from 
the  world  with  all  his  followers,  and  shortly  afterwards  his  royal  enemy 
followed  his  example.     (311-313) 

"At  that  time,"  said  the  Teacher,  "I  was  the  Pandit  Knddftla." 
(313) 

»*  a.  Jft.  i.  311-313. 


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BURLINQAME. — BUDDHAGHOSa's    DHAfilMAPADA   COMMENTARY.       535 
Book  m.    Btory  6.    How  Five  Hundred  Monka  Attained  Insight 

ILLUSTRATING  STANZA  8 -40. 

Five  hundred  monks  once  had  the  Teacher  instruct  them  in  the 
ascetic  practices  that  lead  to  Arahatship,  and  retired  to  a  certain 
forest  In  this  forest  lived  a  great  many  powerful  tree-spirits,  who  took 
a  dislike  to  the  monks  and  determined  to  get  rid  of  them.  Accord- 
ingly the  spirits  caused  the  monks  to^see  bodiless  heads  and  headless 
trunks,  to  hear  the  voices  of  demons,  and  to  catch  all  manner  of 
diseases.  After  a  time  the  monks  returned  to  the  Teacher  and  related 
their  experiences.  "I  will  provide  you  with  a  weapon,"  said  he; 
whereupon  he  rehearsed  the  Sutta  entitled  Metta,  and  told  them  to 
return  to  the  forest  and  do  the  sama  When  they  did  so,  the  hearts 
of  the  spirits  were  suffused  with  love,  and  the  monks  quickly  attained 
Insight.  The  Buddha,  seated  in  his  Perfumed  Chamber,  became  aware 
of  what  had  happened  in  the  forest,  and  sent  forth  an  apparition  of 
himself,  which  went  to  the  monks  and  pronounced  Stanza  40.  At  the 
conclusion  of  the  Stanza  the  five  hundred  monks  attained  Arahatship, 
and  returned,  praising  the  golden  body  of  the  Teacher.     (313-318) 

Book  m.    Story  7.    Tisaa  of  the  Diaeaaed  Body,  Elder. 

ILLUSTRATING  STANZA  9»41. 

A  noble  youth  of  Savatthi  once  became  a  monk  and  was  thereafter 
known  as  Tissa.  As  time  went  on,  he  was  attacked  by  boils,  and  his 
condition  grew  steadily  worse  until  finally  his  brethren,  unable  to  do 
anything  for  him,  abandoned  him  and  left  him  to  his  fate.  Now  the 
Buddhas  are  wont,  twice  a  day,  to  survey  the  world ;  at  early  dawn,  from 
the  Rim  of  the  World  to  the  Perfumed  Chamber ;  and  in  the  evening, 
from  the  Perfumed  Chamber  to  the  outer  world.  One  evening,  accord- 
ingly, as  the  Tathagata  surveyed  the  world,  Tissa  of  the  Diseased 
Body  appeared  within  the  net  of  his  knowledge.  He  immediately 
went  to  him,  and,  assisted  by  the  monks,  bathed  him  with  warm  water, 
alleviating  his  sufferings.  Then  the  Teacher  pronounced  Stanza  41,  at 
the  conclusion  of  which  Tissa  attained  Arahatship  and  passed  into 
Nibb&na,  and  many  of  the  bystanders  were  established  in  the  Three 
Fruits.  When  the  monks  expressed  surprise  that  a  noble  youth 
destined  to  attain  Arahatship  should  have  been  visited  with  such  an 
affliction,  the  Teacher  told  them  that  it  was  no  more  than  he  deserved, 
and  related  the  following  story  of  the  past:  (3ld-32l) 

The  Cmel  Fowler.  In  the  dispensation  of  the  Buddha  Eassapa, 
Tissa  was  a  fowler.    In  order  that  the  birds  he  caught  might  not  be 


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536  PBOCEEDINGS  OF  THE  AMEBIGAN  ACADEMT. 

able  to  escape,  he  was  in  the  habit  of  breaking  their  legs  and  wing- 
bones  and  throwing  them  all  together  in  a  heap.  This  was  the  cause 
of  his  su£fering  in  a  later  existence.  One  day,  however,  he  bestowed 
alms  on  a  monk,  saying,  ''May  I  obtain  ihe  highest  Fruits  of  the 
religion  you  profess."  In  consequence  of  this  meritorious  deed  be 
was  enabled  to  attain  Arahatship  in  a  later  existence.    (322) 

Book  m.    Story  8     Nanda  the  HerdsmaiL 

ILLUSTRATING  STANZA   10-42. 

Nanda  was  a  herdsman  of  And.thapindika.  One  day  he  went  to  his 
master's  house  to  listen  to  the  Teacher  and  was  established  in  the 
Fruit  of  Conversion.  He  entertained  the  Teacher  for  seven  days,  and 
when  the  latter  departed,  accompanied  him  on  his  way  for  a  consider- 
able distance,  and  finally  bidding  him  fieurewell,  turned  back  *  He  had 
not  gone  far  when  he  was  shot  and  killed  by  the  stray  arrow  of  a 
hunter.  The  monks  reported  the  incident  to  the  Teacher,  and  re- 
marked that  if  the  latter  had  not  gone  to  visit  Nanda^  Nanda  would 
not  have  died.  "  You  are  greatly  mistaken,"  said  the  Teacher ;  "  there 
is  no  such  thing  as  escape  from  death."  Then  the  Teacher  solemnly 
warned  them  that  ill-regulated  thoughts  do  a  man  much  more  harm 
than  external  enemies,  and  pronounced  Stanza  42,  at  the  conclusion 
of  which  many  were  established  in  the  Fruits.  (No  one  asked  the 
Teacher  about  Nanda's  deed  in  a  previous  existence ;  therefore  the 
Teacher  said  nothing  about  it.)    (322-5) 

Book  in.    story  9.    Soreyya,  Elder. 

ILLUSTRATING  STANZA   11  -  43. 

When  the  Teacher  was  in  residence  at  SS-vatthi,  there  was  a  treas- 
urer's son  named  Soreyya  living  in  the  city  of  Soreyya,  One  day, 
accompanied  by  a  friend,  he  entered  a  splendid  carriage,  and,  surrounded 
by  a  considerable  retinue,  drove  out  of  the  city  for  a  dip  in  the  swim- 
ming-pool. As  they  passed  out  of  the  city  gate  Soreyya  caught  sight 
of  the  Elder  Mahd,  Kacc^yana  in  the  act  of  putting  on  his  monastic 
robes.  The  golden  hue  of  the  Elder's  body  attract^  the  attention  of 
Soreyya,  who  immediately  exclaimed,  "  Would  that  this  Elder  were 
my  wife ;  or  else  that  the  hue  of  my  wife's  body  were  like  the  hue  of 
his  body."  In  consequence  of  this  wicked  wish  Soreyya  was  instantly 
transformed  into  a  woman.  Sore3rya,  much  embarrassed,  immediately 
left  the  carriage,  joined  a  caravan-train  bound  for  TakkasiU  and  was 
eventually  married  to  the  son  of  a  treasurer  of  that  city,  becoming  tiie 
mother  of  two  sons.     (325-7) 


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BURIJNGAME.  —  BUDDHAGHOSA's   DHAMMAPADA   COMMENTARY.       537 

(There  are  no  men  who  have  not  been  women  at  some  time  or  other ; 
and  no  women  who  have  not,  at  some  time  or  other,  been  men.  For 
example,  men  who  commit  adultery  endnre  punishment  in  hell  for  a 
hundred  thousand  years,  and  on  returning  to  human  estate  at  the  end 
of  that  period,  have  to  spend  a  hundred  existences  as  women.  Even 
the  Elder  Xnanda,  who  fulfilled  the  Perfections  for  a  space  of  a  hun- 
dred thousand  cycles  of  time,  once  committed  adultery  in  an  existence 
as  a  blacksmith,  and  as  a  result  was  obliged  to  spend  fourteen  exis- 
tences as  a  woman,  and  seven  existences  more  before  the  effect  of  his 
evil  deed  was  completely  exhausted.  Women  may  obtain  rebirth  as 
men  by  such  works  of  merit  as  almsgiving,  ready  obedience  to  their 
husbands,  and  so  on.)    (327) 

So  Soreyya,  who,  as  a  treasurer  of  Soreyya,  was  already  the  &ther 
of  two  sons,  became,  as  the  wife  of  a  treasurer  of  Takkasilft,  the  mother 
of  two  more,  making  four  children  in  all.  Now  just  at  this  time, 
Soreyya's  carriage-companion  paid  a  visit  to  Takkasila ;  and  Soreyya, 
who  happened  to  see  him  from  the  window,  invited  him  to  the  house 
and  entertained  him  handsomely.  "  Madam,"  said  the  guest,  "  I  never 
saw  you  before ;  why  is  it  that  you  have  been  so  kind  to  me  ?  do  you 
know  me  f "  Soreyya  then  told  him  the  whole  story.  "  Oh,"  said  the 
guest,  "  it  is  easy  enough  to  remedy  all  this ;  the  Elder  Maha  Eac- 
cftyana  lives  near  by;  just  beg  his  pardon,  and  everything  will  be 
all  right  again."  Soreyya  did  so,  and  immediately  became  a  man 
again.  Maha.  Kaccd.yana  admitted  him  to  the  Order,  and  Soreyya, 
after  committing  his  two  youngest  sons  to  the  care  of  the  treasurer  of 
Takkasil&,  went  back  to  S^vatthi  with  Mahft  Kacc&yana.    (327-330) 

When  the  natives  learned  what  had  happened,  they  were  much  ex- 
cited, and  went  to  Soreyya  and  said,  "  This  is  a  strange  state  of  affairs ; 
you  are  the  mother  of  two  sons,  and  the  father  of  two  more ;  which 
pair  of  children  have  you  the  stronger  affection  for  ? "  Soreyya  replied, 
"  For  the  pair  of  which  I  am  the  mother."  After  a  time  Soreyya 
attained  Arahatship.  The  next  time  he  was  asked  this  question  he 
replied,  "  My  affection  is  set  nowhere."  When  Soreyya's  latest  reply 
was  reported  to  the  Teacher,  the  latter  remarked  that  Sore3rya,  having 
now  obtained  mastery  over  his  thoughts,  was  accomplishing  for  others 
what  neither  father  nor  mother  had  power  to  accomplish.  The  Teacher 
then  pronounced  Stanza  43,  at  the  conclusion  of  which  many  were 
established  in  the  Fruits.    (330-332) 


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538  FROCEEDINOS  OF  THE  AMERICAN  ACADEMY. 

Book  rv.    Story  1.    The  Monks  who  talked  about  tilling  the  Boil. 

ILLU8TBATING  STANZAS   1-2  -  44-45. 

One  evening  five  handred  monks  who  had  accompanied  the  Teacher 
on  his  rounds  began  to  talk  about  the  varieties  of  soil  they  had  seen. 
The  Teacher  told  them  that  they  might  better  be  occupied  with 
tilling  the  soil  of  their  hearts,  and  pronounced  Stanzas  44-45, 
at  the  end  of  which  all  five  hundred  monks  attained  Arahatship. 
(333-5) 

Book  rv.    Btory  2.    The  Elder  who  contemplated  a  Mirage. 

ILLUSTBATINQ  STANZA  3  -  46. 

A  certain  monk  who  had  made  little  progress  in  the  practice  of 
meditation  once  saw  a  mirage.  He  immediately  concentrated  his 
mind  upon  the  following  thought :  "Just  as  this  mirage  appears  sab- 
stantial  to  those  that  are  &r  off,  but  vanishes  on  nearer  approach,  so 
also  is  this  existence."  Then,  seeing  a  waterM,  he  thought^  "Just 
as  this  spray  is  dissipated  and  no  more  seen,  so  also  is  this  existence." 
The  Teacher,  sitting  in  his  Perfumed  Chamber,  became  aware  of  the 
monk's  Attainment^  and  pronounced  Stanza  46 ;  whereupon  the  monk 
attained  Arahatship  and  returned,  praising  the  golden  body  of  the 
Teacher.    (335-7) 

Book  rv.    Btory  3.    Vi^fifabha. 

ILLUSTRATING  STANZA  4  «  47. 

At  S^vatthi,  lived  Prince  Pasenadi,  son  of  the  King  of  the  Eosalans ; 
at  Ves^l!,  a  prince  of  the  Licchavi  Une,  named  Mahali ;  at  Eusin&rd^ 
Prince  Bandhula,  son  of  the  King  of  the  Mallas.  These  three  princes 
resorted  to  a  world-renowned  teacher  at  Takkasila.  for  instruction,  and, 
chancing  to  meet  in  a  hall  outside  of  the  city,  became  warm  friends. 
After  acquiring  the  various  branches  of  learning,  they  took  leave  of 
their  teacher,  departed  together,  and  went  to  their  several  homes. 
Pasenadi's  father  was  so  pleased  with  his  son's  attainments  that  he 
made  him  king.  Mah&li  devoted  himself  to  the  task  of  educating  the 
Licchavi  princes,  but  over-exerting  himself  lost  the  sight  of  his  eyes ; 
whereupon  the  princes  erected  a  gate  for  him,  and  ever  afterwards 
remained  his  most  devoted  and  loyal  pupils.  Bandhula  received  a 
slight  at  the  hands  of  the  Malla  princes,  which  made  him  so  angry 
that  he  determined  to  kill  them  and  seize  the  throna  When  he  in- 
formed his  mother  and  &ther  of  his  plan,  they  told  him  that  it  was 
bound  to  fail,  inasmuch  as  the  kingdom  of  the  Mallas  was  an  heredi- 


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tary  kingdom.  Thereapon  he  decided  to  go  to  Sftvatthi  and  live  with 
his  friend  Pasenadi.  King  Pasenadi  leceived  him  with  distinguished 
honors,  and  made  him  Commander-in-chief  of  his  army.  Bandhula 
sent  word  to  his  mother  and  fiftther  to  come  and  live  with  him,  and 
they  did  so.    (337-9) 

One  day  King  Pasenadi  saw  from  his  terrace  a  great  company  of 
monks  passing  along  the  street  *'  Where  are  they  going  f "  said  he. 
One  of  his  retinue  replied,  "Sire,  every  day  two  thousand  monks  go 
to  the  house  of  An&thapindika  to  obtain  food,  medicine,  and  the  other 
requisites;  five  hundred,  to  Cula  An&thapindika's ;  a  like  number  to 
Visakha's  and  to  Suppavisa's."  "  I,  too,  will  serve  the  Congregation 
of  Monks,"  thought  the  king ;  and  immediately  went  to  the  Teacher 
and  asked  to  be  allowed  the  privilege.  For  seven  days  the  king  enter- 
tained Buddha  and  the  monks,  and  when  he  bade  fiurewell  to  the 
Teacher,  he  invited  the  latter  to  come  regularly  to  his  house  thereafter. 
The  Teacher  declined  the  invitation,  however,  on  the  ground  that 
many  other  persons  desired  his  presence,  and  sent  Ananda  in  his 
place.  For  seven  days  the  king  served  Ananda  and  the  monks  in 
person ;  during  the  three  following  days  he  was  so  remiss  in  the  per- 
formance of  his  du^  to  the  monks  that  the  latter  dropped  off,  one  by 
one,  until  finally  Ananda  was  the  only  one  left.  The  king  was  so 
provoked  at  the  conduct  of  the  monks  that  he  went  to  the  Teacher 
and  complained.  The  Teacher  exonerated  the  monks  from  blame,  and 
told  the  king  that  the  monks  lacked  confidence  in  him.     (339-341) 

"A  family  must  possess  nine  distinctive  marks,"  said  the  Teacher, 
"  to  be  entitled  to  the  privilege  of  entertaining  monks.  They  must 
rise  courteously  to  meet  them ;  greet  them  pleasantly ;  seat  them  com* 
fortably ;  conceal  not  what  they  possess ;  possessing  much,  give  much ; 
possessing  good  things,  give  good  things ;  present  their  offerings  with 
deference ;  sit  to  hear  the  Law ;  speak  in  an  agreeable  tone  of  voice. 
It  was  doubtless  because  you  frkiled  in  your  duty  to  the  monks  that 
they  left  your  house.  Just  so  the  wise  men  of  old  time  went  to  a 
place  where  they  felt  secure."  The  Teacher  then  told  the  following 
story  of  the  past:  (341-2) 

E^ava,  Kappa,  NIrada,  and  the  King  of  BenareB.34  Once  upon  a 
time,  when  Brahmadatta  reigned  at  Benares,  a  hermit  named  Eesava, 
accompanied  by  his  following,  accepted  the  offer  of  the  King  to  enter- 
tain them  during  the  rainy  season.  The  monks  were  so  annoyed  by 
the  cries  of  elephants,  however,  that  they  dropped  off,  one  by  one,  un- 
til finally  Eesava  was  left  alone  with  his  fidthful  pupil  Kappa.    After 

M  a  Ja.  iu,  142-145. 


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540  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

a  time  even  Kappa  was  unable  to  stand  tiie  noise  any  longer,  and  left 
his  master.  Thereupon  Kesavir  fell  sick,  and  begged  the  King  to  send 
him  back  to  his  followers.  The  King  immediately  did  so,  sending 
N&rada  and  three  other  ministers  with  him.  As  soon  as  Kesava  was 
restored  to  his  companions  he  recovered  his  health,  and  was  soon  weU 
and  happy.  When  N&rada  asked  him  how  he  liked  a  hermit's  &re 
after  enjoying  the  hospitality  of  a  king,  Kesaya  replied  that  he  was 
now  completely  happy  since,  after  all,  a  sense  of  secarity  and  confi- 
dence was  the  main  thing.     (342^) 

''At  that  time,"  said  the  Teacher,  "tiie  King  was  Moggalllna; 
N&rada  was  S&ripatta ;  the  pupil  Kappa  was  Ananda ;  while  the  hermit 
Kesava  was  I  myself"    (344-5) 

Thereupon  King  Pasenadi  bethought  himself  how  he  might  regun 
the  confidence  of  the  monks,  and  concluded  that  the  best  way  would 
be  to  take  to  himself  as  ¥rife  the  daughter  of  some  kinsman  of  the 
Buddha.  Accordingly  he  sent  ambassadors  to  the  Sakyans,  request- 
ing one  of  their  daughters  in  marriage.  The  King  of  the  Sakyans, 
fearing  that  he  would  incur  the  enmity  of  King  Pasenadi  by  refusing 
his  request,  put  the  matter  before  his  nobles.  Mah&nftma  said,  "  I 
have  a  daughter  by  one  of  my  slave-women,  and  she  is  very  beauti- 
ful ;  why  not  send  her  ? "  Accordingly  the  King  of  the  Sakyans  sent 
MahSn&ma's  daughter  to  King  Pasenadi,  and  the  latter  married  h^. 
Her  name  was  VSaabhakhattiya.    (345-6) 

In  due  time  Vftsabhakhattiyft  became  the  mother  of  a  son.  Pasenadi 
sent  to  his  grandmother,  asking  her  to  give  the  child  a  name.  She 
selected  the  name  Vallabha  (Beloved) ;  but  the  messenger,  being  a 
little  deaf,  understood  her  to  say  Vidudabha,  and  so  reported  to  the 
King  of  Kosala.  Accordingly  the  child  was  named  Vidudabha.  When 
Vidudabha  was  seven  years  old,  he  said  to  his  mother,  "  Mother,  the 
other  boys  get  presents  firom  their  maternal  grandfathers;  why  is  it 
that  I  don't  get  any  ?  have  n't  you  any  mother  or  &ther  t "  "  Oh, 
yes  !  "  said  she ;  **  your  grandparents  are  Sakyan  kings ;  but  they  live 
a  long  way  off,  and  that 's  the  reason  why  you  don't  get  any  presents." 
When  Vidudabha  was  sixteen  years  old,  he  expressed  one  day  a  desire 
to  visit  his  grandparents.  At  first  Vdsabhakhattiy^  demurred  at  his 
request ;  but  afterwards  she  consented  to  let  him  go,  taking  the  pre- 
caution, however,  to  send  the  following  letter  ahead  of  him:  "I  am 
happy  where  I  am  ;  for  the  sake  of  my  husband,  say  nothing  to  him/' 
So  Vidudabha  took  leave  of  his  &ther  and,  accompanied  by  a  large 
retinue,  set  out    (346-7) 

When  the  Sakyan  princes  learned  of  Vidtidabha's  approaching  visits 
they  decided  not  to  render  homage  to  hiip,  and  therefore  sent  away 


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BURUNGAME.  —  BUDDHAQHOSa's   DHAMMAPADA   COMMENTARY.       541 

all  the  prinoes  who  were  younger  than  he.  Vidudabha  rendered 
homage  to  his  grandfiEktheor  and  the  other  prinoes,  bnt  noticed  that  no 
one  rendered  homage  to  him.  When  he  apoke  of  this  it  was  explained 
to  him  that  all  those  about  him  were  his  seniors ;  and  this  explanation 
satisfied  him.  One  day,  however,  a  female  slave,  while  engaged  in 
scrubbing  the  seat  on  which  Vidudabha  was  wont  to  sit,  remarked, 
"  Here 's  where  the  son  of  the  slave- woman  Vd8abhakhattiy&  sits ! "  A 
soldier  happened  to  overhear  what  she  said,  and  in  a  short  time  the 
remark  became  common  gossip.  When  it  came  to  the  ears  of  Vidu- 
dabha, he  swore  the  following  oath,  "Just  as  these  Sakyans  now  wash 
my  bench  with  water,  so  also,  when  I  am  king;  will  I  wash  my  bench 
with  their  blood."    (347-8) 

When  Vidudabha  returned  to  Sftvatthi,  and  the  King  of  Eosala 
learned  that  V3.sabhakhattiy&  was  really  the  daughter  of  a  slave- 
woman,  he  was  filled  with  rage  at  the  King  of  the  Sakyans,  and  de- 
graded Vidudabha  and  his  mother  to  the  position  of  slaves.  About 
that  time  tiie  Teacher  went  to  visit  the  King  of  Kosala ;  and  upon 
learning  that  the  truth  had  leaked  out,  said  to  the  king,  "  What  does 
the  £Bimily  of  the  mother  matter  ?  the  fieimily  of  the  &ther  is  the  only 
thing  worthy  of  consideration."  Thereupon  King  Pasenadi  restored 
Vidudabha  and  Vd^bhakhattiyS.  to  their  former  rank.     (348-9) 

Just  at  this  time  Bandhula,  the  Commander-in-chief  of  King  Pase* 
nadi's  army,  dismissed  his  wife  Mallikd.  on  the  ground  of  barrenness* 
The  Teacher  bade  her  return  to  her  husband,  and  Bandhula  took  her 
back ;  whereupon  she  conceived  a  child  in  her  womb.  One  day  the 
longing  of  pregnancy  came  upon  her,  and  she  said  to  her  husband,  "  I 
long  to  bathe  in  the  lotus  tank  of  Ves&ll,  and  to  drink  the  water 
thereof"  "  Very  well,"  said  Bandhula.  So  he  took  his  bow,  which 
required  a  thousand  men  to  string, '  assisted  Mallik^  to  mount  the 
chariot,  and  drove  to  Vesall,  entering  the  city  by  the  gate  erected  in 
honor  of  Mah&li.  Now  Mah&li  lived  near  this  gate;  and  when  he 
heard  the  rumble  of  Bandhula's  chariot,  he  said  to  himself  "  There  is 
trouble  brewing  for  the  Licchavi  princes."  Now  the  lotus  tank  was 
guarded  within  and  without  by  strong  guards,  and  fenced  in  with  an  iron 
grating  the  meshes  of  which  were  so  fine  that  not  even  birds  could  get 
through.  Bandhula  alighted  from  his  chariot,  drove  the  guards  away, 
tore  down  the  grating,  and  admitted  his  wife  to  the  tank.  So  Mallika 
bathed  in  the  lotus  tank  of  Ves&ll,  and  drank  the  water  thereof. 
Then  Bandhula  assisted  her  to  mount  the  chariot,  and  drove  back  by 
the  way  he  came.    (349-351) 

The  guards  reported  Bandhula's  insolence  to  the  Licchavi  princes, 
who  were  exceedingly  angry,  and  immediatdy  mounted  their  chariots, 


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542  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY, 

five  hundred  strong,  and  set  out  to  capture  Bandfaula.  Mahdli  warned 
them  that  Bandhula  would  slay  them  all,  but  the  princes  paid  no  at- 
tention to  his  warning.  Bandhula  waited  until  the  file  of  chariots  was 
so  straight  that  but  one  chariot-fit)nt  appeared  to  view ;  and  then, 
stringing  his  mighty  bow,  he  let  an  arrow  fly.  The  arrow  passed 
through  the  body  of  every  one  of  the  five  hundred  men.  Not  realizing 
what  had  happened,  they  continued  the  pursuit ;  but  Bandhula  imme- 
diately stopped  his  chariot  and  cried  out,  "  Tou  are  all  dead  men  ;  I 
will  not  fight  with  the  dead,"  "  Do  we  look  like  dead  men  ! " 
"  Loosen  your  girdles."  They  did  so,  and  the  instant  they  did  so,  five 
hundred  dead  men  lay  on  the  ground.    (351-3) 

Bandhula  returned  to  S&vatUii  with  Mallik^  Sixteen  times  Mallik^ 
bore  twin  sons  to  Bandhula,  and  all  of  them  became  mighty  men. 
Bandhula  by  his  upright  conduct  incurred  the  hostility  of  the  unjust 
judges,  who  went  to  the  king  and  fslsely  accused  him  of  designs  on 
the  throne.  Thereupon  the  king  ordered  Bandhula  and  his  sons  to 
proceed  to  the  firontier  and  put  down  an  insurrection,  and  at  the  same 
time  suborned  men  to  lie  in  wait  for  them  on  their  return,  kill  them, 
and  bring  back  their  heads.  Bandhula  and  his  sons  quickly  put  the 
marauders  to  flight,  and  were  murdered  on  their  return.*  News  of 
the  murder  was  brought  to  Mallikd.  on  the  morning  of  the  day  on 
which  she  had  invited  the  Chief  Disciples  to  be  her  guests.  As  she 
was  entertaining  the  monks,  one  of  the  servants  dropped  a  dish  and 
broke  it  S&riputta  said  to  her,  "  Heed  it  not"  Mallika  drew  fix)in 
the  folds  of  her  dress  the  letter  she  had  received  that  morning,  and 
replied,  "  If  I  heed  not  the  murder  of  my  husband  and  two  and  thirty 
sons,  I  am  not  likely  to  heed  the  breaking  of  a  mere  disL"  After  the 
departure  of  the  monks  Mallika  addressed  her  sons'  wives,  assuring 
them  that  their  husbands,  having  lived  blameless  lives,  had  obtained 
only  the  firuit  of  deeds  in  previous  existences,  and  uiged  them  to 
cherish  no  bitter  feelings  against  the  king.  The  king  soon  learned 
that  the  charges  brought  against  Bandhula  were  fiilse ;  whereupon  he 
made  amends  to  Mallikd^  and  at  her  request  permitted  her  to  return 
to  her  family,  and  to  send  back  her  sons'  wives  to  theirs.     (353-5 

King  Pasenadi  appointed  to  the  post  of  Commander-in-chief  a 
nephew  of  Bandhula,  Dlghak^r&yana  by  nama  Dlghakftrftyana  did 
not  forget  that  Pasenadi  had  caused  his  nnde  to  be  murdered,  and 
waited  for  a  chance  to  get  even.  Now  at  that  time  the  Teacher  was 
residing  in  a  village  near-by ;  and  Pasenadi,  being  greatly  troubled  in 
spirit,  set  out  with  a  small  body-guard  to  pay  him  a  visit  As  Pas- 
enadi was  about  to  enter  the  Perfumed  Chamber,  he  handed  ihe  royal 
insignia  to  Dlghakarayana^  who  immediately  hurried  back  to  S&vatthi 


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BURUNGAME.  —  BUDBHAGHOSA's   DHAMMAPADA   COMMENTARY.       543 

and  proclaimed  Vidudabha  king.  That  night  Pasenadi  died,  and 
when  the  news  was  brought  to  Vidudabha,  the  latter  ordered  the 
funeral  rites  to  be  performed,    (355-6) 

Vidudabha  remembered  the  oath  he  had  sworn  against  the  Sakyans, 
and  set  out  with  a  large  force,  intending  to  kill  them  alL  The  Teacher, 
aware  of  the  impending  destruction  of  his  kinsmen,  seated  himself 
under  a  small  tree  near  Kapilavatthu.  Vidudabha  was  surprised  to 
see  him  there,  and  said  to  him,  "  Why  do  you  sit  here  rather  than 
under  the  great  banyan  tree  that  grows  in  my  kingdom  ? "  "  The 
shade  of  my  kinsmen  refreshes  me,"  replied  the  Teacher.  Then 
Vidudabha  knew  that  the  Teacher  had  gone  there  to  protect  his 
kinsmen,  and  immediately  returned  to  Sflvatthi.  The  Teacher  rose 
and  returned  to  Jetavana.  Three  times  this  happened.  Then  the 
Teacher,  realizing  tliat  his  kinsmen  must  needs  be  slain  through  the 
effect  .of  the  evil  deed  they  committed  in  a  previous  existence  when 
they  threw  poison  into  the  water,  went  no  more  to  the  tree.  So 
Vidudabha  went  forth  to  slay  his  enemies.  The  Sakyans,  as  kinsmen 
of  the  Buddha,  were  unwilling  to  kill  any  of  their  enemies,  and  there- 
fore made  only  a  show  of  resistence,  with  the  result  that  VidQdabha 
destroyed  them  utterly,  and  washed  his  bench  with  their  blood. 
(357-9) 

MahS.nS.ma,  rather  than  eat  with  Vidudabha>  attempted  suicide; 
but  such  was  the  effect  of  the  merit  he  had  accumulated,  that  he 
was  translated  to  the  palace  of  the  NSgas,  where  he  remained  for 
twelve  years.  Vidudabha  searched  for  him  in  vain,  and  then  set  out 
on  his  return  journey.  At  nightfisdl  Vidudabha  pitched  his  camp  in 
the  bed  of  the  river  AciravatI ;  during  the  night  a  violent  storm  arose, 
the  river  bed  was  filled  with  a  raging  torrent,  and  Vidudabha  and  his 
retinue  perished  in  the  waters.     (359-360) 

When  the  monks  referred  to  the  destruction  of  the  Salqrans,  the 
Teacher  told  them  that  it  was  the  effect  of  their  throwing  poison  into 
the  river  in  a  previous  existence.  When  they  commented  on  the  &ct 
that  Vidudabha  was  swept  away  in  the  height  of  his  glory  the  Teacher 
pronounced  Stanza  47,  establishing  many  in  the  Fruits,     (360-362) 

Book  IV.   Story  4.    Patlpfljika. 

ILLUSTBATINQ  STANZA  5-48. 

Once  upon  a  time,,  while  the  god  Mftlabh&rl  was  amusing  himself  in 
the  company  of  a  thousand  celestial  nymphs  in  the  Garden  of  the 
Thirty-three,  one  of  the  njrmphs  fell  from  that  existence,  and  was 
reborn  in  a  noble  £unily  of  S&vatthi.    Remembering  her  former  es** 


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544  PROCEEDINGS  OF  THE  AMEBICAN  ACADESfT. 

tate,  she  made  the  wish  that  she  might  be  reborn  as  M^bhdrl's  wiie^ 
and  her  life  abounded  in  good  works.  When  she  married,  her  devo- 
tion to  her  husband  was  so  conspiouoos  that  she  became  known  as 
Patipujikft  (Husband-honorer).  On  her  death  she  was  reborn,  accord- 
ing to  the  wish  she  had  made,  as  M&labhflrl's  wifa  It  was  now  even- 
ing in  the  world  of  the  Thirty-three.  When  she  told  the  other  nymphs 
that  men  lived  only  a  thousand  years,  they  were  greatly  surprised, 
but  when  she  added  that  in  spite  of  the  shortness  of  human  life,.men 
were  heedless  and  sluggish,  they  hardly  credited  her  words.  The 
Teacher,  drawing  a  lesson  from  Patiptijikft's  history,  warned  the  monks 
of  the  shortness  of  human  life,  and  pronounced  Stanza  48,  at  the  con- 
clusion of  which  many  were  established  in  the  Fruits.    (382-6) 

Book  rv.    Story  5.    Koaiya,  the  Niggardly  Treasurer.^ 

ILLUSTRATINa  STANZA  6  «  49. 

There  once  lived  not  &r  from  R&jagaha  a  treasurer  named  Eosiya, 
who  was  as  niggardly  as  he  was  wealthy ;  and  that  was  saying  a  great 
deal  So  niggardly  was  he,  in  fact^  that  on  a  certain  occasion  he  com- 
pelled his  wife  to  carry  her  cooking  implements  up  to  the  seventh 
storey  of  the  house  to  prepare  a  cake  for  him,  for  fear  that  otherwise  he 
might  have  to  share  his  treat  with  the  neighbors.  The  Teacher,  aware 
of  what  was  going  on,  bade  Moggallana  transport  the  treasurer,  his  wife, 
and  the  cake  to  Jetavana.  Suddenly  the  treasurer  saw  MoggaHSna, 
poised  in  the  air,  looking  in  through  the  window.  Moggall&na  indicated 
that  he  wished  to  have  something  to  eat  After  a  good  deal  of  hesi- 
tation, the  treasurer  said  to  bis  wife,  "  Cook  him  just  one  tiny  little  cake, 
and  let 's  get  rid  of  him."  One  after  another,  the  cakes  they  baked 
grew  to  an  enormous  size,  until  finally,  out  of  sheer  desperation,  the 
treasurer  presented  them  all  to  Moggalldna.  The  latter  then  preached 
the  Law  to  the  treasurer  and  his  wife,  dwelling  on  the  importance  of 
almsgiving,  after  which  he  transported  them,  together  with  the  cakea, 
to  Jetavana.  The  cakes  provided  an  ample  meal  for  the  whole  Con- 
regatiop  of  Monks.  After  the  meal  the  Teacher  delivered  his  custom- 
ary d'dcourse,  at  the  end  of  which  the  treasurer  and  "his  wife  were 
established  in  the  Fruit  of  Conversion.  The  treasurer  then  devoted 
his  entire  wealth  to  the  religion  of  Buddha.  The  latter,  referring  to  the 
subject  in  the  course  of  a  conversation  with  the  monks,  gave  high 
praise  to  Moggallftna  for  his  share  in  the  conversion  of  the  niggardly 
treasurer,  and  pronounced  Stanza  49,  establishing  many  in  the  Fruita. 

Cf.  J&.  i.  345-349. 


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BURLINGAME.  —  BUDDHAGHOSA's  DHAMMAPADA    COMMENTARY.       645 

Gontinaing  his  discourse,  the  Teacher  informed  the  monks  that  this 
was  not  the  first  time  Moggalld.na  had  converted  the  treasurer,  and 
then  related  the  Illlsa  Jataka.     (366-376) 

Book  rv.    Story  6.    Pftfhika,  the  Naked  Ascetio. 

ILLUSTRATING  STANZA  7  —  50. 

The  wife  of  a  certain  householder  of  S&vatthi  was  accustomed  to 
give  food  to  a  naked  ascetic  named  Pathika.  One  day  she  expressed 
a  desire  to  go  and  hear  the  Teacher ;  but  the  ascetic,  desiring  to  retain 
his  place,  urged  her  not  to  do  so.  Accordingly  she  decided  to  invite 
the  Teacher  to  be  her  guest,  and  sent  her  young  son  to  deliver  the 
messaga  Pd,thika  found  out  where  the  boy  was  going,  and  told  him 
to  give  the  Teacher  wrong  directions,  saying  that  in  case  the  latter 
&iled  to  come,  he  and  the  boy  would  have  all  the  more  to  eat.  The 
boy  did  as  the  ascetic  told  him ;  but  the  Teacher,  knowing  the  way 
himself  came  ao  the  appointed  tima  The  ascetic  was  greatly  pro- 
voked, reviled  his  bene&ctor,  and  left  the  housa  The  Teacher,  ob- . 
serving  that  the  mind  of  his  hostess  was  agitated,  and  learning  the 
reason  why,  urged  her  to  pay  no  attention  to  the  sins  of  others,  but 
rather  to  heed  her  own  shortcomings ;  and  pronounced  Stanza  50,  at 
the  conclusion  of  which  she  was  established  in  the  Fruit  of  Conversion. 
(376-380) 

Book  rv.    Story  7.    ChattapSni,  Lay  Disciple. 

ILLUSTRATING  STANZAS  8-9  —  51-52. 

Chattapd.ni  was  a  lay  disciple  of  Sd.vatthi  who  had  entered  upon 
the  Third  Path.  When  King  Pasenadi  Eosala  came  to  pay  his  re- 
spects to  the  Teacher,  Chattapani,  out  of  respect  for  the  Teacher, 
withheld  homage.  This  irritated  the  king,  but  the  Teacher  justified 
Chattap^ni's  conduct,  and  the  king  said  no  more  about  it.  One  day 
the  king  saw  Chattapani  pass  through  the  courtyard  with  a  parasol  in 
his  hand  and  sandals  on  his  feet  He  caused  ChattapSni  to  be  sum- 
moned ;  whereupon  ChattapSni  laid  aside  his  parasol  and  sandals,  and 
came  into  the  king's  presence  without  them.  The  king  said,  "  Why 
did  you  lav  aside  parasol  and  sandals  ? "  ChattapSni  replied,  "  Be- 
cause I  was  summoned  into  the  presence  of  a  king."  "  01^"  said  the 
king,  "  so  at  last  you  know  that  I  am  a  king."  "  I  always  did,"  replied 
ChattapSni.  "  Why,  then,  did  you  withhold  homage  fix)m  me  on  the 
day  I  went  to  see  the  Teacher  ? "  **  Out  of  respect  for  the  Teacher." 
"  Very  well ;  we  11  let  the  past  rest"  The  king  then  requested  Chat- 
tapSni to  preach  the  Law  in  the  palace,  but  ChattapSni,  not  being  a 

VOL.  XLV.  —  35 


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546  PROCEEDINGS   OF    THE    AMERICAN   ACADEMY. 

monk,  declined  Then  King  Pasenadi  sent  word  to  the  Teacher,  say- 
ing, "  Mallikd,  and  Vasahhakhattiyd.  of  the  Royal  Household  desire  to 
hear  the  Law."  The  Teacher  deputed  Ananda  to  preach  the  Law  in 
the  palace.  Somewhat  later  Ananda  reported  to  the  Teacher  that 
Vd.sabhakhattiyd,  unlike  MallikS^  had  made  little  progress;  where- 
upon the  Teacher,  contrasting  their  attitudes,  pronounced  Stanzas 
51-52,  establishing  many  in  the  Fruits.     (380-3M) 

Book  rV.    Story  8.    ViB&kh2L 

ILLUSTRATING  STANZA    10  ->  53. 

Visd'khd.  was  the  daughter  of  Dhanaiijaya,  a  treasurer  of  the  city  of 
Ehaddiya  in  the  kingdom  of  Bengal.  Dhanafijaya's  father,  Mendaka^ 
was  one  of  five  persons  of  limitless  wealth  living  in  Bimhis&ra's  terri- 
tory. Now  King  Bimbis&ra  was  a  connection  by  marriage  of  King 
Pasenadi  Kosala,  and  one  day  received  a  request  from  the  latter  to 
move  one  of  the  families  of  limitless  wealth  to  the  kingdom  of  KosaLa. 
Since  this  was  too  great  an  undertaking,  Bimhis&ra  did  the  next  best 
thing,  and  sent  Dhanafijaya.  So  Dhanafijaya,  accompanied  hy  his  &m- 
ily  and  following,  removed  to  the  kingdom  of  Kosala,  and  settled  in  a 
place  called  Sd>keta^  seven  leagues  from  Sd^vatthi.  By  this  time  Visdkha^ 
who  was  established  in  the  Fruit  of  Conversion  at  the  early  age  of  seven, 
had  grown  to  womanhood.     (384-7) 

At  this  time  there  was  living  in  the  neighboring  city  of  S&vatthi  a 
young  man  named  Punnavaddhana,  son  of  the  treasurer  Migdra,  who 
had  agreed  to  marry  a  girl  possessed  of  the  Five  Beauties,  if  such  could 
be  found.  Eight  Brahmans  devoted  themselves  to  the  task  of  finding 
him  a  wife,  and  one  day  noticing  Vis&kh&,  and  discovering  that  she  was 
possessed  of  the  Five  Beauties,  they  went  to  her  &ther,  Dhananjayai 
and  asked  him  to  give  her  in  marriage  to  their  master,  Punnavaddhana. 
Dhanafijaya  consented,  and  the  Brahmans  hastened  to  inform  Mig^ra. 
Thereupon  MigSra  the  treasurer  and  King  Pasenadi  Kosala,  accompa- 
nied by  their  retinues,  paid  a  visit  to  the  treasurer  Dhanalojaya.  In 
the  meantime  Dhanafijaya  caused  a  magnificent  trousseau  to  be  made 
for  his  daughter,  and  provided  her  with  a  splendid  dowry.    (387-397) 

When  it  was  time  for  VisSkha  to  go,  her  father  enjoined  upon  her 
the  observance  of  Ten  Injunctions,  which  were  as  follows  :  The  in-door 
fire  is  not  to  be  carried  outside ;  the  out-door  fire  is  not  to  be  carried 
inside ;  give  only  to  him  that  gives ;  give  not  to  him  that  gives  not ; 
give  both  to  him  that  gives,  and  to  him  that  gives  not ;  sit  happily  ; 
eat  happily ;  sleep  happily ;  tend  the  fire ;  honor  the  household  divin- 
ities.    MigSxa  happened  to  be  sitting  in  the  next  room,  and  overheard 


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BURLINGAME.  —  BCDDHAOHOSA's  DHAMMAPADA   COMMENTARY.       547 

all  that  Dhanafijaya  said.  Dhanafijaya  then  appointed  eight  sponsors 
for  Vis&kha>  and  directed  them  to  try  her  in  case  any  charges  were 
brought  against  her.  He  then  entrusted  his  daughter  to  the  care  of 
King  Pasenadi  and  the  treasurer,  who  returned  with  her  to  S^vatthi. 
So  Vi8d,kha>  arrayed  in  a  magnificent  parure,  and  accompanied  by  a 
splendid  retinue,  entered  Sd.vatthi  in  the  train  of  the  King,  and  inmie- 
diately  won  the  hearts  of  all  the  inhabitants.     (397-9) 

That  night  Visftkha's  thoroughbred  mare  gave  birth  to  a  foal ;  where- 
upon Visakha  arose,  went  to  the  stable,  and  bathed  the  mare.  When 
her  father-in-law  learned  that  she  had  left  the  house  at  night,  he  was 
much  displeased,  but  refrained  from  making  further  inquiries.  Now 
Mig^ra  was  much  attached  to  a  certain  sect  of  naked  ascetics,  who, 
when  they  learned  that  a  disciple  of  Gotama  had  become  the  wife  of 
his  son,  urged  Migd,ra  to  put  her  out  of  the  house.  Somewhat  later, 
at  the  close  of  a  day  on  which  Migd,ra  had  entertained  the  naked  as- 
cetics, he  overheard  Vis^kha  remark  that  he  was  eating  "stale  fare." 
Mig^ra  then  and  there  ordered  her  out  of  the  house.  Visakha,  how- 
ever, claimed  the  right  of  being  tried  before  her  eight  sponsors ;  accord- 
ingly Mig^ra  had  the  sponsors  summoned,  and  brought  three  charges 
against  his  daughter-in-law  :  first,  that  she  had  accused  him  of  eating 
what  was  unclean ;  secondly,  that  she  hcbd  left  the  house  at  night ; 
thirdly,  that  she  performed  the  work  of  menials.  Visakhd,  cleared  her- 
self of  guilt  on  the  first  count  by  explaining  that  all  she  meant  to  say 
was  that  her  &ther-in-law  was  living  on  stale  merit  instead  of  acquir- 
ing fresh  merit;  then  she  explained  that  she  heA  left  the  house  at 
night  for  no  other  purpose  than  to  care  for  her  mare ;  the  third  charge 
was  withdrawn.     (399-402) 

MigSra  then  asked  Visftkha  to  explain  the  hidden  meaning  of  the  Ten 
Injunctions.  "  The  first,"  said  Visakha,  "  means  that  I  must  not  speak 
of  the  faults  of  my  mother-in-law,  or  fisither-in-law,  or  husband,  to 
others ;  the  second,  that  if  I  hear  others  speak  of  their  faults,  I  must 
not  tell  them  what  I  have  heard ;  the  third,  that  I  should  give  to  those 
only  who  return  borrowed  articles ;  the  fourth,  that  I  should  not  give 
to  those  who  fisiil  to  return  borrowed  articles ;  the  fifth,  that  I  should 
give  to  anyone  in  needy  circumstances,  whether  or  not  he  is  able  to 
repay  me ;  the  next  three  mean  that  I  must  not  sit  or  eat  or  sleep  until 
I  have  first  attended  to  the  needs  of  my  mother-in-law,  father-in-law, 
and  husband ;  the  ninth  means  that  I  must  look  upon  them  as  upon  a 
flame  of  fire ;  the  tenth,  that  I  must  look  upon  them  as  my  divinities." 
(402-404) 

Thereupon  Migara,  finding  no  fault  in  Visakha,  asked  her  to  pardon 
him.    She  did  so,  but  told  him  that  now  she  should  leave  the  house  of 


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548  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

her  own  accord.  She  consented  to  stay,  however,  on  the  condition  that 
she  should  be  allowed  to  entertain  the  Buddha.  On  the  occasion  of  ^e 
Teacher's  first  visit,  Migara  and  his  wife  were  established  in  the  Fruit 
of  Conversion.  Visakhd,'s  life  abounded  in  good  works ;  and  she  lived 
to  be  an  hundred  and  twenty  years  old.  She  endeavored  to  sell  her 
magnificent  trousseau,  intending  to  devote  the  proceeds  to  the  work 
of  the  Order ;  but  finding  that  no  one  else  was  rich  enough  to  buy  it, 
made  up  the  price  herself,  and  erected  a  splendid  monastery.  The 
Teacher  informed  the  monks  that  Vis&khd,'s  noble  life  was  the  fruit  of 
good  works  performed  in  the  dispensations  of  Padumuttara  and  Kas- 
sapa,  and  then  pronounced  Stanza  53,  establishing  many  in  the  Fruits. 
(404-420) 

Book  IV.    Story  9.    The  Elder  Ananda's  Question. 

ILLUSTRATING  STANZAS   11-12  »  54-55. 

Once  upon  a  time  the  Elder  Xnanda  pondered  the  following  thought 
in  his  mind  :  "  The  Exalted  One  possesses  three  kinds  of  perfiimes ; 
but  each  of  these  goes  with  the  wind.  Is  there,  perhaps,  a  kind  of  per- 
fume that  goes  against  the  wind  ? "  So  he  went  to  the  Teacher  aud 
put  the  question  to  him.  The  Teacher  replied,  "  Certainly  there  is  a 
kind  of  perfume  that  goes  against  the  wind."  "  Which  kind  is  itt" 
"The  perfume  of  good  works."  Then  the  Teacher  pronounced  Stan- 
zas 54-55,  at  the  conclusion  of  which  many  were  established  in  the 
Fruits.     (420-423) 

Book  rv.    Story  10.    Sakka  bestows  Alms  on  Mahft  Kassapa. 

ILLUSTRATING  STANZA   13  «=  56. 

Sakka's  five  hundred  wives  once  endeavored  to  obtain  the  privily 
of  bestowing  alms  on  Maha  Eassapa,  but  the  latter  refused  them  the 
privilege,  on  the  ground  that  he  preferred  to  allow  the  poor  to  accumu- 
late merit  by  so  doing.  When  Sakka  learned  of  this,  he  disguised 
himself  as  an  old,  broken-down  weaver,  transformed  Wellborn  into  an 
old  woman,  and  had  no  difficulty  at  all  in  persuading  Eassapa  to 
accept  his  alms.  When  Eassapa  discovered  that  it  was  Sakka  firom 
whom  he  had  accepted  alms,  he  reproached  him  for  deceiving  him  and 
defrauding  the  poor.  But  Sakka  explained  that  he  hoped  by  the  per- 
formance of  this  and  similar  works  of  merit  to  make  his  own  lustre 
equal  to  that  of  three  other  deities  who  heA  hitherto  outshone  him. 
The  Teacher,  becoming  aware  of  what  had  happened,  pronounced 
Stanza  56,  at  the  conclusion  of  which  many  were  established  in  the 
Fruits.     (423-430) 


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BURUNGAME,  —  BUDDHAGHOSA's   DHA&fMAPADA  COMMENTARY.       649 
Book  rv.    Story  U.    How  the  Elder  Qodhika  attained  Nibbfina. 

ILLUSTRATINO  STANZA   14  -  67. 

The  Elder  Godhika  found  hipiself  so  impeded  in  the  praotice  of 
ecstatic  meditation  hy  a  disease  which  had  attacked  him  that  he  drew 
a  razor  and  cut  his  throaty  passing  at  once  to  Nibbana.  Mara  searched 
everywhere  in  hope  of  discovering  where  he  had  been  reborn ;  but  the 
Teacher  informed  him  that  he  was  engaged  in  a  futile  task,  and  pro- 
nounced Stanza  57,  establishing  many  in  the  Fruits.     (431--4) 

Book  rv.    Story  12.    Oarahadinna. 

ILLUSTRATING  STANZAS   15-16  -  68-59. 

At  Sftvatthi  once  lived  two  friends,  Sirigutta  and  (jarahcbdinna ;  the 
former,  a  lay  disciple  of  the  Buddha ;  the  latter,  an  cbdherent  of  the 
Naked  Ascetics.  These  heretics  used  to  say  to  their  disciple  Oara- 
hadinna, "  Go  and  ask  your  friend  Sirigutta  why  he  visits  the  hermit 
(jotama,  and  what  he  expects  to  get  out  of  him,  and  see  if  you  can't 
persuade  him  to  transfer  his  allegiance  to  us."  So  Garahadinna  used 
to  ask  his  friend  Sirigutta  why  he  visited  the  hermit  Gotama,  and  what 
he  expected  to  get  out  of  him,  and  tried  with  all  his  might  to  persucbde 
him  to  transfer  his  allegiance  to  the  Naked  Ascetics.  After  a  time 
Sirigutta  became  very  weary  of  hearing  this  sort  of  talk,  and  one  day 
said  to  Garahadinna,  "  What  do  your  masters  know,  anyway  t "  "  Oh, 
sir,  don't  talk  that  way;  there  is  nothing  my  masters  don't  know. 
They  know  all  about  the  past,  the  present,  and  the  future.  They 
know  everybody's  thoughts,  words,  and  actions.  They  know  just  what 
is  going  to  happen,  and  just  what  is  not  going  to  happen."  "  You 
don't  say."  "Indeed  J  do."  "Well,  if  that's  the  case,  pray  convey 
my  compliments  to  your  masters,  and  tell  them  that  I  should  like  to 
have  the  privilege  of  entertaining  them."  The  heretics  at  once 
accepted.     (434-6) 

Sirigutta  had  a  long  ditch  dug,  and  had  it  filled  with  dung  and  slima 
Then  he  hcbd  cords  stretched  across,  rugs  laid  on  the  cords,  and  the 
seats  so  placed  with  one  edge  resting  on  the  ground  and  the  other  on 
the  cords,  that  the  instant  the  heretics  sat  down,  they  would  be  tipped 
over  backwards  and  precipitated  into  the  mass  of  filth  at  the  bottom 
of  the  ditch.  In  order  that  the  rugs  might  not  be  smeared  with  filth, 
Sirigutta  stationed  men  all  along  the  line  with  orders  to  pull  the  rugs 
out  from  under  when  the  heretics  sat  down.  He  didn't  take  the 
trouble  to  provide  any  food  or  drink  for  his  guests.    Thought  he,  "  If 


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550  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

Grarahadinna's  majBters  really  know  jast  what  is  going  to  happen,  they  H 
stay  away  from  here."    (436-7) 

Bat  Gurahadinna's  masters  came,  just  as  Sirigatta  expected  they 
would.  Sirigutta  told  them  to  sit  down  all  at  once,  and  when  they  did 
so,  they  were  immediately  tipped  over  backwards,  and  precipitated 
into  the  mass  of  filth  at  the  bottom  of  the  ditch.  As  they  crawled  oat, 
Sirigutta's  men  belabored  them  with  clubs  until  they  were  glad 
enough  to  escape  with  their  lives.  Garahadinna  had  Sirigutta  haled 
before  the  king  and  asked  the  king  to  give  him  the  fall  extent  of  the 
aw ;  but  when  the  king  investigated  the  matter,  he  decided  that  it  was 
Grarahadinna,  rather  than  Sirigutta,  who  deserved  to  be  punished,  and 
therefore  had  Garahadinna  beaten  soundly.    (437-9) 

Garahflbdinna  cherished  deep  resentment  against  Sirigutta  for  a  long 
time,  and  finally  determined  to  serve  Buddha  and  his  monks  somewhat 
as  Sirigutta  had  served  the  Naked  Ascetics.  He  employed  much  the 
same  stratagem,  except  that  instead  of  filling  the  ditch  with  filth,  he 
heA  it  filled  with  glowing  coals.  But  the  Buddha  caused  an  enormous 
lotus-flower  to  spring  up  from  the  bed  of  coals,  whereon  he  sat,  sur- 
rounded by  his  five  hundred  monks.  By  a  second  miracle  he  created 
an  abundant  supply  of  food,  whereof  all  partook.  Then  he  pronounced 
Stanzas  58-59,  at  the  end  of  which  the  multitude  obtained  clear  com- 
prehension of  the  law,  and  Garahadinna  and  Sirigutta  attained  the 
Fruit  of  Conversion.  In  the  evening,  referring  to  a  similar  experience 
he  had  in  a  previous  existence,  he  related  the  KhadirangSia  Jataka. 
(439-447) 


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Prooeediagi  of  fhie  Ameriean  Academy  of  Arte  and  Sdenoea. 

Vol.  XLV.  No.  21.  — Sbptembeb,  1910. 


RECORDS  OP  MEETINGS,  1909-1910. 

OFFICERS  AND  COMMITTEES  FOR  1910-1911. 

LIST     OP     THE     FELLOWS    AND    FOREIGN    HONORARY 
MEMBERS.      , 

STATUTES  AND  STANDING  VOTES; 

RUMFORD  PREMIUM. 

INDEX. 

(Title  Paok  and  Table  op  Contents.) 


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RECORDS  OF  MEETINGS. 

Nine  hundred  ninety-flnt  Meettnir* 

October  13, 1909.  —  Stated  Meeting. 

The  President  in  the  chair. 

There  were  thirty-four  Fellows  present.     . 

The  Corresponding  Secretary  announced  that  letters  had  been 
received  from  F.  J.  Furnivall  and  Hermann  Jacobi,  accepting 
Foreign  Honorary  Membership;  from  F.  G.  Benedict,  Arthur 
W.  Ewell,  J.  H.  Ropes,  W.  W,  Fenn  and  G.  M.  Lane,  accepting 
Resident  Fellowship ;  from  W.  J.  Spillman,  American  Secretary 
of  the  Universal  Scientific  Association,  suggesting  the  establish- 
ment of  technical  vocabularies  in  the  international  language, 
Esperanto,  for  the  various  sciences ;  from  Mrs.  Simon  Newcomb 
and  family,  announcing  the  death  on  July  11th,  1909,  of  Simon 
Newcomb;  from  Harvard  University,  requesting  the  presence 
of  a  delegate  at  the  inauguration  of  Abbott  Lawrence  Lowell,  as 
its  President ;  from  the  Nobel  Prize  Committees,  inviting  compe- 
tition for  the  Nobel  prizes  of  1910 ;  from  Dr.  J.  Zavodny,  en- 
closing a  pamphlet  of  the  Export-verein  fiir  Bohmen,  Mahren 
und  Schlesien,  in  Prag,  and  requesting  admission  into  the  Acad- 
emy as  Corresponding  member ;  from  Anaboli  Pavlov,  a  theory 
of  numbers  (in  Russian);  from  H.  G.  Wadlin,  E.  A.  Filene 
and  C.  Bertrand  Thompson,  suggesting  an  exhibit  at  the  "  1915  " 
Boston  Exposition  to  be  held  Nov.  1-27,  1909 ;  from  Carlos  A. 
Hesse,  suggesting  changes  in  the  Calendar ;  from  the  Aero  Club 
of  America,  inviting  the  Academy  to  take  part  in  the  proceedings 
at  the  presentation  of  medals  to  Messrs.  Wilbur  and  Orville 
Wright,  as  discoverers  of  the  art  of  flying ;  from  the  American 
Philosophical  Society,  requesting  the  Academy  to  co-operate 
with  oUier  scientific  societies  in  urging  the  government  of  the 


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554  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY- 

United  States  to  send  a  vessel  to  explore  and  survey  the  coast 
of  Wilkes  Land  and  other  parts  of  Antarctica. 

The  following  deaths  were  announced  by  the  Chair :  — 

John  M.  Ordway,  Associate  Fellow  in  Class  I,  Section  3; 
Simon  Newcomb,  Associate  Fellow  in  Class  I,  Section  1. 

On  motion  of  E.  L.  Mark,  it  was 

Voted^  that  a  committee  be  appointed  to  investigate  the  ques- 
tion of  co-operation  with  other  scientific  societies  in  urging  the 
Government  to  send  a  vessel  to  explore  the  coast  of  Wilkes 
Land. 

The  question  of  an  exhibit  at  the  Boston  *'1915"  Exposition 
was  referred  to  the  Librarian,  with  full  power. 

President  Trowbridge  gave  a  paper  entitled  "The  Future  of 
Aeroplanes." 

The  following  papers  were  presented  by  title :  — 

"  The  Principle  of  Relativity  and  Non-Newtonian  Mechanics.'* 
By  Gilbert  N.  Lewis  and  Richard  C.  Tolman.  Presented  by 
C.  R.  Sanger. 

"  Friction  in  Gases  at  Low  Pressures."  By  J.  L.  Hogg.  Pre- 
sented by  John  Trowbridge. 

"  The  Quantitative  Determination  of  Antimony  by  the  Gut- 
zeit  Method."  By  Charles  Robert  Sanger  and  Emile  Raymond 
Riegel. 

"  The  Preparation  and  Properties  of  Pyrosulphuryl  Chloride 
and  Chlorsulphonic  Acid."  By  Charles  Robert  Sanger,  Emile 
Raymond  Riegel  and  Lawrence  Haines  Whitney. 

"A  Revision  of  the  Atomic  Weight  of  Phosphorus."  By 
Gregory  P.  Baxter  and  Grinnell  Jones. 

"  The  Equivalent  Circuits  of  Composite  Lines  in  the  Steady 
State."     By  A.  E.  Kennelly. 

"  Tlepl  ^vaeay;.  A  Study  of  the  Conception  of  Nature  among 
the  Pre-Socratics."  By  William  A.  Heidel.  Presented  by  Mor- 
ris H.  Morgan. 

Nine  hundred  ninety-ieoond  Meeting* 

November  10, 1909. 

Tlie  President  in  the  chair. 

There  were  thirty-seven  Fellows  present. 


^  „..Co.,, 


RECORDS  OF  MEETINGS. 


655 


The  Corresponding  Secretary  read  the  following  letters:  an 
invitation  from  the  Museum  of  Pine  Arts,  to  the  opening  of  its 
new  building ;  from  the  Secretary  of  the  International  Congress 
of  Americanists,  a  notification  of  the  17th  Congress. 

The  Committee  on  the  proposed  action  regarding  Antarctic 
exploration  reported  as  follows :  — 

"  We  believe  that  it  is  fitting  for  governments  to  take  part  in  ex- 
ploration. Our  government  has  already  done  it  in  moderate  measure ; 
other  governments  have  done  mora 

We  believe,  also,  that  it  is  fitting  for  learned  societies  to  take  part  in 
promoting  government  exploration  by  middng  recommendations  to  this 
end. 

We  find  that  the  particular  plan  under  consideration  deserves  our 
support,  because  the  work  proposed  is  lyell  worthy  of  investigation ;  it 
touches  a  region  in  which  our  previous  national  exploration  gave  good 
results  but  left  much  to  be  done.  There- is  abundant  room  for  co- 
operative exploration  in  the  Antarctic  regions  by  various  countries. 

We  therefore  recommend  that  &vorable  action  be  taken  by  the  Acad- 
emy on  the  communication  fix)m  the  Anlerican  Philosophical  Society." 

W.  M.  DAvia 
A.  Lawrencb  Rotch. 

On  motion  of  the  Corresponding  Secretary  it  was 
Voted^  That  the  Academy  take  favorable  action  on  the  com- 
munication from  the  American  Philosophical  Society. 

The  following  letter  from  Alexander  Agassiz  regarding  his 
presentation  of  a  new  building  to  the  Academy  was  read  by  the 
President :  — 

October  16  [1909]. 
My  dear  Mr.  Trowbridge, 

I  have  at  last  bought  the  house  adjoining  the  Academy's  building 
on  Newbury  Street,  —  No.  26,  so  that  on  my  return  fix)m  the  West 
I  shall  be  ready  to  make  my  proposition  to  the  Academy  for  their  con- 
sideration and  decision.  The  house  is  let  for  2  years  but  I  fancy  we 
could  obtain  possession  earlier.  In  meanwhile  the  architects  can  per- 
fect the  plans.  It  will  be  necessary  while  building,  for  the  Academy 
to  get  shelter  fix)m  the  Historical  Society  or  Natural  History  Society 
and  to  hire  a  room  for  their  office  for  say  18  months.  As  the  Acad- 
emy will  have  ample  room,  I  think  we  could  increase  the  number  of 
members  by  150  or  200,  which  would  pay  for  increased  expense  of  run- 


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556  PROCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 

ning  the  building  when  completed.  With  the  great  increase  in  nnm- 
ber  of  Professors  at  Tafts,  Boston  University,  Institute  of  Technology, 
and  Harvard,  there  ought  to  be  no  difficulty  in  filling  our  number. 
I  leave  for  the  West  the  22d,  not  to  return  till  Nov.  12th.  In  mean- 
time, you  will  perhaps  get  one  of  our  lawyer  members  to  look  over  our 
Statutes,  By-laws  and  Charter,  and  make  out  a  plan  for  us  to  submit 
to  the  Members  at  a  properly  called  meeting  to  decide  on  my  sugges- 
tions or  such  modifications  of  them  as  are  advisable.  I  propose  to 
deliver  the  building  complete  to  the  Academy  and  hope  that  increase 
of  new  members  will  pay  running  expenses.    The  building  will  have 

1  large  Meeting  Room  4%  X  46        I 

1    "     Reading      "      "  "    "         II 

Janitx)r's  quarters  and  bed  room  3.  Ill 

Basement  Hall  1,  2  rooms  for  Committee  meetings. 

The  stack  or  shelf  room  of  I,  II  and  basement  will  give  room  for  10 
M.  additional  books  without  a  new  stack. 

As  I  go  o£f  for  the  winter  the  13th  of  December,  I  hope  we  can  have 
the  meeting  of  the  Academy  before  that  time  and  appoint  a  committee 
to  examine  the  plans  and  report  to  the  Academy  what  action  they  think 
best  for  the  Academy. 

The  location  is  excellent  —  near  all  electric  cars,  near  the  Natural 
History  Society,  the  Institute,  Tufts  Medical  School  and  Boston  Uni- 
versity, and  I  hope  the  building  may  become  a  scientific  and  literary 
club  while  remaining  the  domicile  of  the  Academy. 
Yours  very  truly, 

A  Aqassiz. 

After  discussion,  on  motion  of  Professor  Wolff,  it  was 
Voted^  That  a  committee  of  three  be  appointed  by  the  Presi- 
dent to    consider  the  general    plan  suggested    by    Professor 
Agassiz. 

On  motion  of  Professor  Webster  it  was  unanimously 
Fotedy  That  the  Academy  expresses  its  hearty  thanks  to  Pro- 
fessor Agassiz  for  his  very  generous  proposition. 

The  foUowinor  communication  was  given  by  Professor  Kit- 
trcdge,  *•  Moot  Points  about  Chaucer." 


V 


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BBCOBDS  OF  UEETINOS. 


657 


Nine  hundred  ninety-tliird  Meetlnff. 

December  8, 1909. 

Tlie  Pbesident  in  the  chair. 

There  were  fifty-six  Fellows  present 

The  Corresponding  Secretary  read  the  following  letters : — from 
the  President  of  the  8th  International  Zoological  Congress,  in- 
viting delegates  to  the  congress;  from  the  family  of  Henry 
Charles  Lea,  announcing  his  death ;  from  the  Comity  G^ologique 
de  la  Russie,  announcing  the  death  of  M.  Serge  Nikitin ;  from 
the  Koniglich  Bchmische  Gesellschaft  der  Wissenschaften,  an- 
nouncing the  death  of  Phil.  Dr.  Karl  Domal^p. 

The  death  of  Henry  Charles  Lea,  an  Associate  Fellow  in  Class 
HL,  Section  3,  was  announced  by  the  Chair. 

On  motion  of  E.  C.  Pickering  the  following  Resolution  was 
passed :  Mesohedj  That  the  American  Academy  of  Arts  and 
Sciences  desires  to  express  its  entire  approval  of .  the  recom- 
mendations of  the  President  of  the  United  States,  in  his  annual 
message  to  Congress,  regarding  the  administration  of  the  Naval 
Observatory.  The  Academy  believes  that  the  scientific  work  of 
the  Observatory  should  be  under  the  direction  of  a  scientific 
man,  and  that  in  this  way  its  efl&ciency  will  be  greatly  increased. 

Resolvedj  That  a  copy  of  these  resolutions  be  transmitted  to 
the  President  of  the  United  States,  by  the  Secretary. 

On  motion  of  Mr.  Webster  it  was 

Voted  J  To  give  the  above  Resolution  to  the  public  press. 

It  was  suggested  by  tlie  Corresponding  Secretary,  that  Stand- 
ing Vote  No.  10  precluded  giving  the  above  Resolution  to  the 
public  press. 

On  motion  of  Mr.  Bowditch,  it  was 

Votedj  That  in  the  opinion  of  the  Academy,  Standing  Vote 
No.  10  does  not  apply  to  making  public  the  vote  just  passed. 

The  President  read  the  names  of  the  Committee  appointed  at 
the  last  meeting  to  consider  the  general  plan  suggested  by  Pro- 
fessor Agassiz,  viz. :  Dr.  H.  P.  Walcott,  Professor  John  C.  Gray, 
and  President  A.  Lawrence  Lowell. 

The  President  re-read  the  letter  of  Professor  Agassiz,  read  at 
the  last  meeting  of  the  Academy,  and  after  considerable  discus- 
sion the  following  votes  were  passed :  — 


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558  PBOCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

On  motion  of  A.  G.  Webster,  it  was 

Votedy  That  the  Academy  accepts  with  profound  gratitude  the 
very  generous  gift  of  Professor  Agassiz. 

Voted^  That  a  committee  on  Policy  be  selected  to  consider  all 
questions  relating  to  the  enlarged  functions  of  the  Academy. 

On  motion  of  C.  P.  Bowditch  it  was 

Voted^  That  in  the  opinion  of  the  Academy  an  increase  of 
membership  is  desirable. 

Voted^  That  the  committee  on  the  general  plan  suggested  by 
Professor  Agassiz  be  authorized  to  apply  to  the  Legislature  for  an 
amendment  to  the  charter  which  will  permit  such  increase. 

Professor  Derr  exhibited  some  lantern  photographs  taken  in 
the  Yellowstone  National  Park. 

The  following  papers  were  presented  by  title :  — 

''  Buddha-ghosa's  Commentary  on  the  Dhammapada,  an  Analy- 
sis of  the  First  Four  Books  of  the  Buddhist  Acta  Sanctorum  in 
Pali,  with  an  Index  to  the  304  Stories  of  the  Burmese  Edition. '* 
By  Eugene  Watson  Burlingame.     Presented  by  C.  R  Lanman. 

''The  Effect  of  Leakage  at  the  Edges  upon  the  Conduction  of 
Heat  in  a  Homogeneous  Lamina."     By  B.  0.  Peirce. 

''The  Resistance  of  the  Air  to  a  Swinging  Magnet."  By 
B.   0.  Peirce. 

"The  Differentiation  of  Scalar  Point  Functions  with  Respect 
to  Other  Similar  Functions."     By  B.  0.  Peirce. 

"The  Spectrum  of  a  Compound  of  Carbon  in  the  Region  of 
Extremely  Short  Wave-Lengths. "     By  Theodore  Lyman. 

"Average  Chemical  Compositions  of  Igneous-Rock  Types." 
By  Reginald  A.  Daly. 

"Experiments  on  the  Electrical  Oscillations  in  a  Hertz 
Rectilinear  Oscillator. "     By  George  W.  Pierce. 

"On  the  Applicability  of  the  Law  of  Corresponding  States  to 
the  Joule-Thomson  Effect  in  HgO  and  COj."  By  Harvey  N. 
Davis.     Presented  by  John  Trowbridge. 

"  Notes  on  Certain  Thermal  Properties  of  Steam. "  By  Harvey 
N.  Davis.     Presented  by  John  Trowbridge. 

"Discharge  of  Electricity  through  Gases."  By  John 
Trowbridge. 

"Measurement  of  Pressure  and  Density  in  Gases  with  the 
Micro  Balance."  By  H.  W.  Morse.  Presented  by  John 
Trowbridge. 


\ 


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RECORDS  OF  MEETINGS.  559 


(( 


''Some  Minute  Phenomena  of  Electrolysis."  By  H.  W. 
Morse.     Presented  "by  John  Trowbridge. 

"  The  Reactions  of  Amphibians  to  Light."  By  Arthur  Sperry 
Pearse.     Presented  by  K  L.  Mark. 


Mliw  hnndred  ninety-fourth  Meetlnir* 

January  12,  1910. — Stated  Meeting. 

The  President  in  the  chair. 

There  were  twenty-nine  Fellows  present. 

In  the  absence  of  the  Corresponding  Secretary,  the  President 
read  the  following :  —  a  letter  from  B.  Beemaert,  Minister  of  State 
of  Belgium,  sending  three  hundred  and  seventy-five  copies  of  a 
manifesto  against  criticism  of  Belgium  concerning  its  African 
possessions;  circulars  from  the  committee  of  the  Third  Inter- 
national Congress  of  Botany  to  be  held  at  Brussels,  May  14-22, 
1910;  a  circular  from  the  Committee  of  the  First  International 
Congress  of  Entomology,  to  be  held  at  Brussels,  August  1-6, 
1910;  from  the  Museo  Nacional,  Mexico,  sending  the  felicitations 
of  the  new  year';  an  announcement  from  the  Soci^t^  d'Emulation 
d' Abbeville,  of  the  death  of  M.  P.-C.-R  Prarond  ;  an  announce- 
ment from  the  Soci^t^  Royale  Norv^gienne  des  Sciences  of 
Trondhjem  of  the  death  of  M.  M.  H.  Foslie. 

The  following  deaths  were  announced:  —  James  Barr  Ames, 
Resident  Fellow  in  Class  III. ,  Section  1 ;  F.  W.  Maitland,  Foreign 
Honorary  Member  in  Class  III.,  Section  1. 

The  following  gentlemen  were  elected  members  of  the 
Academy :  — 

Arthur  Fairbanks,  of  Boston,  as  Resident  Fellow  in  Class  III., 
Section  4. 

William  Arthur  Heidel,  of  Middletown,  as  Associate  Fellow 
in  Class  111.,  Section  2. 

On  motion  of  B.  L.  Robinson,  it  was 

Votedj  That  Professor  W.  G.  Farlow  be  appointed  delegate  to 
the  International  Botanical  Congress  to  be  held  at  Brussels,  May 
14  to  22, 1910. 

On  motion  of  C.  R.  Cross,  it  was 

Votedj  To  appropriate  the  sum  of  five  hundred  dollars  (f500) 


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560  PR0CEEDIN06  Or  THE  AMERICAN  ACADEMT. 

from  the  nnexpended  balance  of  the  income  of  the  Ramford 
Fund,  to  be  applied  at  the  discretion  of  the  Committee. 

Tlie  President  announced  that,  in  pnrsoance  of  tlie  vote  at  the 
last  meeting  of  the  Academy,  he  appointed  the  following  gentle- 
men a  Committee  on  Policy,  to  consider  all  questions  relating  to 
the  enlarged  functions  of  the  Academy  :  Messrs.  Webster,  Botch, 
Ernst,  Lyman,  Walcott,  W.  M.  Davis  and  Trowbridge. 

The  following  communication  was  given  by  Dr.  D.  6.  Lyon : 
"  Harvard  Explorations  in  Samaria." 

The  following  papers  were  presented  by  title :  — 

"Air  Resistance  to  Falling  Inch  Spheres."  By  Edwin  H. 
HalL 

"  Contributions  from  the  Gray  Herbarium  of  Harvard  Univer- 
sity. New  Series  No.  XXXVIIL"  L  A  preliminary  synopsis 
of  the  Genus  Echeandia.  By  C.  A.  Weatherby.  IL  Sperma- 
tophy  tes,  new  or  reclassified,  chiefly  Rubiaceae  and  Gentianaceae. 
By  B.  L.  Robinson.  III.  American  Forms  of  Lycopodium  com- 
planatum.  By  C.  A.  Weatherby.  IV.  New  and  little  known 
Mexican  Plants,  chiefly  Labiatae.  By  M.  L.  Femald.  V.  Mex- 
ican Phanerogams  —  Notes  and  New  Species.  By  C.  A.  Weath- 
erby.    Presented  by  B.  L.  Robinson. 

NliM  handrad  nlnetj-flllh  M «0tlBg; 

Februaby  9, 1910, 

The  President  in  the  chair. 

There  were  present  thirty-four  Fellows. 

The  Corresponding  Secretary  read  the  following:  —  a  circular 
from  the  American  Philosophical  Society,  with  Resolutions 
adopted,  urging  upon  Congress  the  establishment  of  a  National 
Bureau  of  Seismology ;  a  letter  from  Arthur  Fairbanks,  accept- 
ing Resident  Fellowship;  a  letter  from  William  A.  Heidel,  ac- 
cepting Associate  Fellowship;  a  circular  from  the  Koniglich 
Bohmische  Gesellschaft,  announcing  the  death  of  Dr.  Ottokar 
Hostinsky ;  two  letters  from  the  "  Boston  1916  Committee  " ;  a 
letter  from  A.  Biddlecombe,  showing  "  proof  of  the  truth  of  his 
theory  that  electricity  is  material  motion  in  a  special  condition, 
etc.";  a  circular  from  the  President  and  Fellows  of  Harvard 
University,  announcing  the  inauguration  of  Abbott  Lawrence 


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RECORDS  OF  ItfEETINGS.  &61 

Lowell  as  President ;  a  letter  f i-om  President  Taft  in  answer  to 
Resolutions  forwarded  to  hi  in  by  the  Academy  relative  to  the 
Naval  Observatory,  requesting  that  copies  of  the  Resolutions  be 
sent  to  the  President  of  the  Senate  and  the  Speaker  of  the 
House  of  Representatives. 

On  motion  of  Professor  Webster  it  was 

Votedy  To  send  copies  of  the  Resolutions  regarding  the  Naval 
Observatory  to  the  President  of  the  Senate  and  the  Speaker  of 
the  House  of  Representatives. 

Votedj  That  the  Librarian  be  appointed  a  delegate  to  the 
Boston  1915  Directorate  conference  to  be  held  March  8, 1910. 

Professor  W.  M.  Davis  gave  a  paper  entitled :  — 

"The  Italian  Riviera  Levante:  a  study  in  Geographical 
Description." 

Dr.  Percival  Lowell  exhibited  and  described  transparencies 
of  photographs  of  Mars  and  Saturn,  taken  at  the  Lowell 
Observatory. 

The  following  papers  were  presented  by  title :  — 

"  Evaporation  from  the  Surface  of  Small  Solid  Spheres."  By 
H.  W.  Morse.     Presented  by  John  Trowbridge. 

"  On  the  Equilibrium  of  the  System  Consisting  of  Lime,  Car- 
bon, Calcium  Carbide,  and  Carbon  Monoxide."  By  M.  de  Kay 
Thompson.     Presented  by  H.  M.  Goodwin. 

"  A  Study  of  the  Greek  Epigram  before  300  b.  c."  By  Flor- 
ence  Alden  Gragg.     Presented  by  H.  W.  Smyth. 

Nine  hondred  ninety-tlxth  Meetini;. 

March  9, 1910.  —  Stated  Meeting, 

The  President  in  the  chair. 

There  were  thirty-nine  Fellows  present. 

The  Corresponding  Secretary  read  the  following: — a  letter 
from  William  H.  Niles,  resigning  Fellowship;  a  letter  from 
H.  G.  Chase,  announcing  the  death  of  Professor  A.  E.  Dolbear ; 
a  letter  from  Dr.  Edward  Eohlrausch,  announcing  the  death  of 
W.  F.  Eohlrausch  ;  a  circular  from  Senator  Augusto  Righi,  Presi- 
dent of  the  Royal  Academy  of  Science,  Bologna,  announcing  the 
competition  for  the  Elia  De  Cyon  prize  in  1911 ;  a  circular  from 
G.  Spiller,  Secretary,  announcing  the  Universal  Race  Congress 


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562  PROCEEDINGS  OP  THE  AMERICAN  ACADEMY. 

to  be  held  in  London  in  July,  1911 ;  a  circular  from  Signor  Vito 

Volterra,  announcing  tlie  publication  of  the  mathematical  works 

of  Count  Julius  Charles  of  Fagnano. 

The  following  deaths  were  announced  by  the  Chair :  — 
William   Sellers,  Associate  Fellow   in   Class  I.,  Section  4; 

Samuel  W.  Johnson,  Associate  Fellow  in  Class  I.,  Section  3 ; 

William  Frederick  Eohlrausch,  Foreign  Honorary  Member  in 

Class  I.,  Section  2, 

The  President  announced  that  the  Massachusetts  Legislature 

had  complied  with  the  request  of  the  Academy  and  had  passed 

the  following  amendment  to  the  Charter  of  the  Academy:  — 

[Chapter  129.] 

Commonwealth  of  Massachusetts. 

In  the  year  One  Thousand  Nine  Hundred  and  Ten. 
An  Act  relative  to  the  American  Academy  of  Arts  and  Sciences. 
Be  it  enacted  by  the  Senate  and  House  of  Representatives  in  (Sen- 
'  eral  Court  assembled  and  by  the  authority  of  the  same,  as  follows  :  — 

Section  1.  Section  four  of  chapter  forty-six  of  the  acts  of  the  year 
seventeen  hundred  and  seventy-nine,  passed  May  fourth,  seventeen 
hundred  and  eighty,  which  incorporated  the  American  Academy  of 
Arts  and  Sciences,  is  hereby  amended  by  striking  out  in  the  proviso 
at  the  end  of  said  section,  the  word  "  two  "  before  the  word  "  hun- 
dred," and  inserting  in  place  thereof  the  word  : ' —  three,  —  so  as  to 
read  as  follows :  —  Section  4.  That  the  fellows  of  the  said  academy,  may 
from  time  to  time,  elect  such  persons  to  be  fellows  thereof,  as  they  shall 
judge  proper ;  and  that  they  shall  have  full  power  and  i^uthority  from 
time  to  time  to  suspend,  expel,  or  disfranchise,  any  fellow  of  the  said 
academy,  who  shall  by  his  conduct  render  himself  unworthy  of  a  place 
in  that  body,  in  the  judgment  of  the  academy  ;  and  also  to  settle  and 
establish  the  rules,  forms,  and  conditions  of  election,  suspension,  ex- 
pulsion, and  disfranchisement :  provided,  that  the  number  of  the  said 
academy  who  are  inhabitants  of  this  state,  shall  not  at  any  one  time, 
be  more  than  three  hundred,  nor  less  than  forty. 

Section  2.  Said  chapter  forty-six  is  hereby  further  amended  by 
striking  out  Section  six  and  inserting  in  place  thereof  the  following  :  — 
Section  6.  That  the  fellows  of  the  said  academy  may,  and  shall, 
forever,  hereafter,  be  deemed  capable,  in  the  law,  of  having,  holding, 
and  taking,  in  fee  simple  or  any  less  estate,  by  gift,  grant,  devise,  or 


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BECOBDS  OF  MBETINOS.  &63 

otherwise,  any  lands,  tenements,  or  other  estate,  real  and  personal : 
provided,  that  the  said  real  estate  shall  not  exceed  in  value  the  sum 
of  one  hundred  thousand  dollars,  and  the  said  personal  estate  shall  not 
exceed  in  value  the  sum  of  three  hundred  thousand  dollars ;  all  the 
sums  mentioned  in  the  preceding  section  of  this  act  to  be  valued  in 
silver,  at  the  rate  of  six  shillings  and  eight  pence  by  the  ounce ;  and 
the  annital  interest  and  income  of  the  said  real  and  personal  estate, 
together  with  the  fines  and  penalties  aforesaid,  shall  be  appropriated 
for  premiums,  to  encourage  improvementa  and  discoveries  in  agricul- 
ture, arts,  and  manufactures,  or  for  other  purposes  consistent  with  the 
end  and  design  of  the  institution  of  the  said  academy,  as  the  fellows 
thereof  shall  determine. 
Sbctiok  3.  This  act  shall  take  effect  upon  its  passaga 

House  op  Rbpresentatfvbs,  February  25,  1910. 

Passed  to  be  enacted.    Joseph  Walker,  Speaker. 

In  Senate,  February  28,  1910. 
Passed  to  be  enacted.    Allen  T.  Tbeadway,  President. 
February  28,  1910. 
Approved.  Eben  S.  Draper, 


A  true  copy. 


Office  of  the  Secretary, 

Boston,  March  1,  1910. 


Witness  the  Great  Seal  of  the  Commonwealth. 
Isaac  H.  Edgett, 
[Seal]  Deputy  and  Acting  Secretary  of  the  Commomvealth. 

The  following  gentlemen  were  elected  Members  of  the 
Academy :  — 

Clifford  Herschel  Moore,  of  Cambridge,  as  Resident  Fellow 
in  Class  III.,  Section  2  (Philology  and  Archaeology). 

Charles  Pomeroy  Parker,  of  Cambridge,  as  Resident  Fellow 
in  Class  III.,  Section  2  (Philology  and  Archaeology). 

Vbtedj  That  the  sum  of  four  hundred  dollars  from  the  unex- 
pended balance  of  the  appropriation  for  publication  from  the 
income  of  the  Rumford  fund  be  transferred  to  the  amount  avail- 
able for  use  at  the  discretion  of  the  Committee. 

The  Chair  appointed  the  following  Councillors  to  serve  as 
Nominating  Committee :  — 


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564'  PBOCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

John  E.  Wolff,  of  Class  II. 

Henry  P.  Talbot,  of  Class  I. 

George  L.  Kittredge  of  Class  III. 

The  following  gentlemen  were  appointed  a  Committee  to 
revisfe  the  Statutes :  — 

Charles  R.  Lanmau.        • 

Charles  R.  Cross. 

Frederic  J.  Stimson. 

The  following  communication  was  given :  — 

^^  Some  New  Factors  in  Determining  the  Location  of  Wineland 
the  Good."     By  M.  L.  Fernald. 

Mr.  Henry  H.  Edes  gave  an  account  of  ^<  Some  Lacunae  in  the 
Archives  of  the  Academy."  These  Lacunae  were  letters  written 
to  the  Academy  by  the  following:  — 

George  Washington,  March  22,  1781 ;  Count  Rumford,  Feb- 
ruary 15,  1797 ;  Marquis  de  Chastellux,  five  letters  in  1781  and 
'82;  Chevalier  de  la  Luzerne,  March  20, 1781*;  Peter  Wargeutin, 
March  20,  1781 ;  Marquis  de  Marbois,  May  20,  1781 ;  Richard 
Price,  three  letters  in  1781  and  '83 ;  J.  J.  L.  Delalande,  Novem- 
ber 30,  1781 ;  J.  L.  D'Alembert,  December  11, 1781 ;  Leonardus 
Euler,  March  11, 1782 ;  Count  de  Gobelin,  June  24, 1782 ;  R  S. 
Jcaurat,  three  letters  in  1782  and  '83;  Thomas  Brand  Hollis, 
two  letters  in  1783 ;  Joseph  Priestley,  June  23,  1786 ;  John  C. 
Lcttsom,  February  1,  1793;  J.  F.  Blumenbacli,  November  29, 
1795;  Nathaniel  Bowditch,  August  28,  1797,  and  were  pro- 
cured from  the  descendants  of  Joseph  Willard,  former  Secre- 
tary and  Vice  President  of  the  Academy. 

On  motion  of  Professor  Webster,  it  was 

Vbted^  That  in  view  of  the  unusual  nature  of  the  Communi- 
cation, the  Academy  depart  from  its  usual  custom  of  not  express- 
ing an  opinion  on  communications  presented  to  it,  and  give  a 
hearty  vote  of  thanks  to  Mr.  Edes  for  his  success  in  restoring 
to  the  Academy  these  valuable  documents. 

It  was  then 

Votedy  That  the  thanks  of  the  Academy  be  given  to  the  de- 
scendants of  Dr.  Joseph  Willard,  its  first  Corresponding  Secre- 
tary, for  restoring  to  its  files  a  collection  of  papers,  mostly 
letters  accepting  Fellowship  in  the  Academy. 


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RECORDS  OF  MEETINGS.  565 

Vine  hundred  nlnety-eeventh  M eetlnir. 

April  13, 1910. 

Vice-President  Thomson  in  the  chair. 

There  were  thirty-six  Fellows  and  three  guests  present. 

The  Corresponding  Secretary  read  the  following:— ^letters 
from  Charles  P.  Parker  and  Clifford  H.  Moore,  accepting  Resi- 
dent Fellowship;  a  letter  from  V.  M.  Slipher,  accepting  Associate 
Fellowship ;  a  letter  from  John  Ritchie,  Jr.,  resigning  Fellow- 
ship; a  card  from  the  Historical  Society  of  Pennsylvania,  re- 
questing the  presence  of  the  President  at  the  opening  of  the 
New  Hall  of  the  Society ;  a  letter  and  circulars  from  the  Argen- 
tine Scientific  Society,  concerning  the  International  American 
Scientific  Congress  to  be  held  in  Buenos  Aires  in  July,  1910, 
commemorating  the  Centenary  of  the  Revolution  of  May,  1810 ; 
circulars  of  the  World's  Congress  of  International  Associations 
to  be  held  under  the  patronage  of  the  Belgian  government,  in 
May,  1910 ;  circulars  of  the  eleventh  International  Geological 
Congress  and  the  second  International  Agrogeological  Confer- 
ence to  be  held  in  Stockholm  in  1910 ;  a  circular  from  the  Bos- 
ton-1915  Director,  announcing  the  publication  of  *'  The  Chronicle 
of  Boston-1915.'* 

The  Chair  announced  the  death  of  Alexander  Agassiz,  Resi- 
dent Fellow  in  Class  II.,  Section  3,  and  President  of  the  Academy 
from  1895  to  1903;  of  Morris  Hicky  Morgan,  of  Class  III., 
Section  2 ;  and  of  William  Graham  Sumner,  Associate  Fellow 
in  Class  III.,  Section  3. 

On  motion  of  the  Corresponding  Secretary,  it  was 

Votedy  To  refer  the  appointment  of  delegates  to  the  three 
International  Congresses,  to  tlte  President. 

Vice-President  Thomson  announced  that  the  Rumford  Prem- 
ium had  been  awarded  to  Professor  Robert  Williams  Wood  for 
his  discoveries  in  light,  and  particularly  for  his  researches  on 
the  optical  properties  of  sodium  and  other  metallic  vapors. 

The  two  medals  were  then  presented  to  Professor  Wood,  who 
expressed  his  appreciation  of  the  honor  conferred  upon  him. 
He  then  gave  an  address  on  "  Photography  with  Invisible  Rays.*' 

VOL.  XLV.  35 


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566  PROCEEDINGS  OF  THE  AMERICAN.  ACADEMY. 

Nine  handrad  ninety-eighth  Meeting* 

May  11, 1910.  —  Annual  Meltino. 

The  President  in  the  chair. 

Thirty -six  Fellows  and  one  guest  present. 

The  Corresponding  Secretary  read  the  following:  —  a  notice 
of  the  death  of  Alexander  Agassiz  from  The  Faculty  of  the 
Museum  of  Comparative  Zotilogy;  a  notice  from  the  clerk 
of  the  Probate  Court  of  the  City  of  Newport,  that  tlie  Academy 
is  named  as  a  beneficiary  under  the  will  of  Alexander  Agassiz ; 
a  circular  from  the  Association  des  Ing^nieurs  Electriciens 
sortis  do  Plnstitut  ^lectrotechnique  Montefiore,  giving  the 
conditions  of  a  triennial  prize;  a  circular  announcing  papers 
to  be  given  at  the  17th  Congress  of  Americanists  at  Buenos 
Aires;  a  circular  from  the  Secretary  of  the  International  Hy- 
giene exhibition  to  be  held  in  Dresden,  1911. 

The  following  report  of  the  Council  was  read :  — 

Since  the  last  report  of  the  Council  the  deaths  of  eleven  mem- 
bers have  been  noted:  three  Resident  Fellows,  —  James  Barr 
Ames,  Morris  Hicky  Morgan,  Alexander  Agassiz;  six  Associate 
Fellows, — John  Morse  Ordway,  Simon  Newcomb,  Henry  Charles 
Lea,  William  Sellars,  Samuel  William  Johnson,  William  Gra- 
ham Sumner ;  two  Foreign  Honorary  Members, — Frederic 
Willimn  Maitland,  Wilhelm  Fried  rich  Kohlrausch. 

Tw  o  Resident  Fellows  have  resigned 

New  members  elected  are:  Resident  Fellows,  8;  Associate 
Fellows,  2;  Foreign  Honorary  Members,  2. 

The  roll  of  the  Academy  therefore  now  includes  191  Resident 
Fellows,  8:1  Associate  Fellows,  and  61  Foreign  Honorary 
Members. 

The  annual  report  of  the  Treasurer  was  read,  of  which  the 
following  is  an  abstract :  — 


BECORDS  OF  MEETINGS.  «'>67 


General  Fund. 

Beceipts. 

Balance,  April  30,  1909 $507.57 

Investments 2,043.63 

Assessments  ., 1,870.00 

Admission  fees 80.00 

Rent  of  offices 756.58 

Sale  of  book  plates 265.00    $5,522.98 

Esependitutes. 

Expense  of  House       $1,358.10 

Expense  of  Library 2,691.59 

Expense  of  Meetings        141.54 

Treasurer 131.75 

Income  transferred  to  principal 224.38    $4,547.35 

Balance,  April  80,  1910 975.83 

$5,522.98 

RuMFOBD  Fund. 

Feceipts, 

Balance,  April  30,  1909 $2,155.19 

Investments 2,956.43 

Sale  of  publications 19.00 

Unexpended  balance  returned •  55.95    $5,186.57 

Ea:penditure8, 

Research $2,375.00 

Periodicals  and  binding 232.75 

Books  and  binding 50.69 

Publication 388.48 

Medals 350.00 

Sundries 287.80 

Income  transferred  to  principal 142.54    $3,827.26 

Balance  April  30,  1910 1,359.31 

$5,186.57 

C.  M.  Warren  Funix 

Jteceipts. 

Balance,  April  30,  1909    . $544.95 

Investments 406.41       $951.36 


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568  PROCEEDINGS  OF  THE  AMEBICAN  ACADEMY. 

Expendittires. 

Research SlOO.OO 

Vault  rent  (part) 4.00 

Income  transferred  to  principal 13.88 

Chained  to  redaoe  premium  on  bonds     .     .    .  50.00       $167.88 

Balance,  April  30,  1910 783.48 

$951^6 
Publication  Fund. 

Beceipts. 

Balance,  April  30,  1909 $692.99 

Appleton  Fund  investments 618.82 

Centennial  Fund  investments 2,312.17 

Sale  of  publications 402.43     $4,026.41 

Eajpenditures. 

Publication $2,545.02 

Vault  rent  (part) 12.50 

Income  transferred  to  principal 146.94    $2,704.46 

Balance,  April  30,  1910 1,321.95 

$4,026.41 

The  following  reports  were  also  presented :  — 

Report  of  the  Librarian. 

The  work  of  cataloguing  the  library  has  progressed  during  the  past 
year,  and  is  now  almost  completed.  Two  alcoves  of  Society  pub- 
lications, half  the  dictionaries  and  the  bibliography,  only,  remain 
uncatalogued. 

There  is  now  no  more  room  for  books  in  the  staok-building,  and  if 
we  remain  in  this  house,  shelving  must  be  put  up  in  the  house — 
which  is  not  fire-proof — or  another  story  must  be  added  to  the  stack- 
building. 

The  number  of  bound  volumes  in  the  library  at  die  last  report  was 
29,911.  1105  volumes  have  been  added  during  the  past  year,  making 
the  number  of  bound  volumes  now  on  the  shelves  31.016.  The  num- 
ber of  volumes  added  includes  990  gifts  and  exchanges,  70  purchased 
by  the  General  Fund,  and  48  by  the  Rumford  Fund. 

86  volumes  have  been  borrowed  from  the  library  by  30  persons, 
including  19  Fellows. 

All  books  borrowed  during  the  year  have  been  returned,  except  11, 


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RECORDS  OF  MEETINOS.  569 

5  of  which  were  borrowed  within  two  weeks ;  and  of  die  8  remaining 
oat  at  the  last  report^  all  have  been  returned  except  3- 

The  expenses  charged  to  the  library  are  as  follows :  Miscellaneous, 
8506.70  (which  includes  S153.13  for  cataloguing) ;  Binding,  $738.25 
General,  and  $84.55  Rumford,  Funds;  Periodical  subscriptions, 
$446.64  Genend,  and  $164.68  Rumford,  Funds;  making  a  total  of 
$1184.89  for  the  General,  and  $249.23  for  the  Rumford,  Funds,  as  the 
cost  of  subscriptions  and  binding. 

Of  the  Impropriation  of  $50  from  the  Rumford  Fund,  plus  $68.86, 
the  unexpended  balance  frx)m  last  year,  $50.69  has  been  paid  for  Books 
and  binding. 

A.  Lawrence  Rotch,  Librarian. 

May  11,  1910. 

Report  of  the  Rumford  Committeb. 

The  following  grants  in  aid  of  researches  on  light  and  heat  have 
been  made  by  tihe  Rumford  Committee  during  the  year  1909-10 :  — 

June  9, 1909.  Professor  W.  W.  Campbell  of  the  lick  Observa- 
tory, for  the  purchase  of  certain  parts  of  a  quartz  spectrograph    $300 

Professor  M.  A.  Rosanoff,  of  Clark  University,  in  further  aid 
of  his  research  on  the  fractional  distillation  of  binary  mixtures  .      200 

October  13,  1909.  Professor  L.  R.  Ingersoll,  of  the  Univer- 
sity of  Wisconsin,  for  the  continuation  of  his  work  on  the  opti- 
cal constants  of  metals,  additional 300 

December  8,  1909.  Professor  Joel  Stebbins,  of  the  Univer- 
sity of  Illinois,  in  further  aid  of  his  researches  with  the  selenium 
photometer 300 

Professor  W.  W.  Campbell,  of  the  Lick  Observatory,  in  fur- 
therance of  his  researches  on  the  polariscope  study  of  the  solar 
corona  by  means  of  a  Hartmann  photometer,  additional  .    .    .       125 

February  9,  1910.  Professors  C.  E  Mendenhall,  of  the  Uni- 
versity of  Wisconsin,  and  Augustus  Trowbridge,  of  Princeton 
University,  in  aid  of  their  research  on  ether  drift  upon  the  inten- 
sity of  radiation 250 

Professor  C.  R  Mendenhall,  in  frirtherance  of  a  research  on 
free  expansion  of  gases,  additional 250 

Mr.  Frank  W.  Very,  for  the  purchase  of  photographic  glass 
plates  of  the  spectrum  frx)m  George  Higgs,  London,  a  sum  not 
to  exceed 50 

Professor  M.  De  E.  Thompson,  of  the  Massachusetts  Institute 
of  Technol(^,  in  aid  of  his  research  on  the  high  temperature 
equilibrium  of  the  system  of  materials  employed  industrially  in 
the  carbide  process  for  the  fixation  of  atmospheric  nitrogen  .    .      100 


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570  PBOCEEDINOS  OF  THE  AMERICAN  ACADEMY. 

It  was  voted  on  February  9,  1910,  that  the  sum  of  $250  be  graoted 
to  Professor  Gilbert  N.  Lewis,  in  aid  of  the  preparation  of  abstracts 
of  publications  on  light  and  heat  for  the  forthcoming  IntematioDal 
Physico-chemical  Tables. 

On  March  9,  1910,  it  was  voted  to  appropriate  the  sum  of  $100  for 
the  purchase  and  binding  of  periodicals  for  the  library,  a  consider- 
able number  of  back  volumes  of  several  periodicals  including  a  complete 
set  of  the  Physikalische  Zeitschriffc  having  been  secured  :  this  sum  to 
be  paid  from  the  amount  available  for  use  at  the  discretion  of  the 
Committee. 

The  following  papers  have  been  published  in  the  Proceedings  of  the 
Academy  during  the  present  year  at  the  expense  of  the  Rumford 
Fund. 

Vol  45,  No.  8.  **  On  the  Apphcability  of  the  Law  of  Corresponding 
States  to  the  Joule-Thomson  Effect  in  Water  and  Carbon  Dioxida" 
By  Harvey  N.  Davis. 

VoL  45,  No.  9.  "  Notes  on  Certain  Thermal  Properties  of  Steam." 
By  Harvey  N.  Davis. 

Vol.  45,  No.  10.  "The  Spectrum  of  a  Carbon  Compound  in  the 
Region. of  Extremely  Short  Wave-Lengths."    By  Theodore  Lyman. 

Vol.  45,  No.  18.  "On  the  Equilibrium  of  the  System  consisting  of 
Lime,  Carbon,  Calcium  Carbide  and  Carbon  Monoxide."  By  Maurice 
De  E.  Thompson. 

Reports  of  the  progress  of  researches  which  have  been  aided  bj 
grants  fh)m  the  Rumford  Fund  have  been  received  from  Messrs  P.  W. 
Bridgman,  W.  W.  Campbell,  A.  L.  Clark,  W.  J.  Fisher,  E  B.  Frost, 
L.  R.  Ingersoll,  N.  A.  Kent,  F.  K  Kester,  C.  R  Mendenhall,  R.  & 
Minor,  J.  A.  Parkhurst,  M.  A.  Rosanoff,  F.  A.  Saunders,  J.  Stebblns, 
F.  A.  Very. 

At  a  meeting  of  the  Committee  held  on  February  9th,  it  was  unan- 
imously voted  for  the  first  time,  and  at  a  meeting  held  on  March  9th, 
for  the  second  time,  to  recommend  to  the  Academy,  the  award  of  the 
Rumford  Premium  to  Charles  Gordon  Curtis  for  his  improvements  in 
the  utilization  of  heat  as  work  in  the  steam-turbine. 

Chables  R.  Cboss,  Chairman. 

May  11, 1910. 

Report  of  thb  C.  M.  Warren  Committbr. 

The  C.  M.  Warren  Committee  beg  leave  to  report  that  grants  have 
been  made  during  the  past  year  to  the  following  persons,  in  aid  of  the 
researches  specified ;  — 


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RECORDS  OF  MEETINQS.  571 

Dr.  J.  Elliott  Gilpin,  Johns  Hopkins  University,  for  the 
study  of  the  natare  and  source  of  petroleum SlOO 

Dr.  K  W* Washburn,  University  of  Illinois,  for  the  construc- 
tion of  an  adiabatic  calorimeter  for  the  measurement  of  heats  of 
dilation  and  of  solution 150 

The  research  by  Professor  A.  W.  Foote,  of  Yale  University,  on  the 
"  Natare  of  Precipitated  Colloids,"  in  aid  of  which  a  grant  of  $300  was 
made  by  the  Warren  Committee  in  1909,  has  been  published. 

Reports  of  progress  have  been  received  from  Dr.  Frederic  Bonnet, 
Jr.,  and  from  Dr.  J.  Elliott  Gilpin  in  r^;ard  to  researches  for  which 
money  has  been  contributed  from  the  Warren  Fund,  and  the  results  of 
both  these  investigations  it  is  hoped  will  be  published  during  the  com- 
ing year. 

Leonard  P.  Kinnicutt,  Chairman. 

May  11, 1910. 

Report  of  the  Publication  Committeb. 

Between  May  1,  1909,  and  May  1,  1910,  there  were  published  nine 
numbers  of  Volume  XLIV.  (Nos.  18-26)  and  fifteen  numbers  of  Vol- 
ume XLV.  of  the  Proceedings.  In  Volume  XLIV.  there  were  included 
two  biographical  notices.  The  total  publication  amounted  to  714  4~  v 
pages,  with  four  plates,  of  which  three  numbers  (Nos.  8,  9,  10  of 
Volume  XLV.)  have  been  paid  for  by  the  income  of  the  Rumford  Fund. 

Five  numbers  of  the  Proceedings  are  in  press,  of  which  one  number 
(No.  18)  has  been  authorized  by  the  Rumford  Committee  to  be 
published  at  the  expense  of  the  Rumford  Fund. 

There  was  available  for  the  use  of  the  Committee  on  Publication  an 
unexpended  balance  from  last  year  of  $110.96,  an  appropriation  of 
82500,  and  an  amount  of  $378.55  from  the  sale  of  publications  up  to 
March  4,  1910,  — in  all  $2989.51  fix)m  the  Publication  Fund,  Bills 
against  this  fund  to  the  amount  of  $2545.02  have  been  approved  by 
the  Chairman  of  the  Committee,  and  have  been  submitted  to  the 
Treasurer.    This  leaves  an  unexpended  balance  of  $444.49. 

Bills  aggregating  $388.48,  incurred  in  publishing  Rumford  papers, 
have  been  forwarded  to  the  Rumford  Committee. 

G.  W.  PiEBGE,  Acting  Chairman. 

May  11,  1910. 

Report  of  the  House  Committee. 

During  the  year  1909-10  the  House  has  been  occupied  as  heretofore 
with  the  exception  of  the  first  floor,  which  has  been  vacant  since 


Google 


572  PROCEEDINGS  OF  THE  AMERICAN  ACADEMY. 

November  17tL    It  has  Dot  been  let  because  tenants  ooold  not  be 
given  a  lease  of  any  length  of  tima 

On  the  first  of  May,  1909,  there  was  a  balanoe  of  S109.45  to  the 
credit  of  the  House  Expenses  impropriation,  and  at  the  annual  meetiog 
of  May  12,  1900,  $1450  was  appropriated,  making  an  amount  of 
Si  559.45  for  use  during  the  year. 

Of  this  amount,  $1358.10  has  been  expended  for  current  expenses, 
leaving  a  balance  of  $201.36  toward  the  expenses  of  the  coming  year. 

The  woodwork  on  the  outside  of  the  house  should  be  painted,  and 
the  windows  re-puttied  and  painted,  if  the  building  is  to  be  occupied 
another  winter.  In  anticipation  of  the  gift  of  Mr.  Agassiz,  this  was 
not  done  last  autunm  as  it  should  have  been. 

William  R.  Wabb,  Ckatrma$L 

May  11,  1910. 

FiNANCHAL  Report  op  the  Council. 

The  income  for  the  year  1910-11,  as  estimated  by  the  Treasurer,  is 
as  follows  I '~~' 

1,       (Investments $1,660.95 

General  Fundj^^^^^^^^j^^ 1,800.00    $3,460.95 

Publication  Fund I^PP^®*^^  ^''''^  •    '    '    '      ^^^'^^ 
PUBLICATION  ruNDj^j^^^^j^^^p^^j  2,312.17    $2,926.99 

RuMFORD  Fund       Investments $2,888.18 

Warren  Fund        Investments $329.78 

The  above  estimates,  less  5  per  cent  to  be  added  to  the  ci^ital, 
leave  an  income  available  for  appropriation  as  follows :  — 

{Income $3,287.90 
Unappropriated,  1909-10  •  .  440.68 
Unexpendedapprop'tion,  1909-10       534.95    $4,263.53 

Publication  Fund 2,780.64 

RumfordFund 2,743.77 

Warren  Fund 313.29 

The  following  appropriations  are  recommended  :  — 

General  Fund. 

House  expenses $1,200 

Library  expenses 1,400 

Books,  periodicals,  and  binding 900 

Expenses  of  meetings 1^0 

Treasurer's  office 150    $3,800 


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records  of  meetings-  578 

Publication  Fund. 

Publication $2,500 

BuMFORD  Fund. 

Research $1,000 

Periodicab  and  binding 150 

Books  and  binding •    •  50 

Publication 700 

To  be  used  at  discretion  of  Committee 800 

To  be  used  at  discretion  of  Committee,  the  unex- 
pended balance  of  1909^10       350    $3,050 

Warren  Fund. 
Research $300 

In  accordance  with  the  recommendation  in  the  foregoing 
report  it  was 

Voted,  To  appropriate  for  the  purposes  named  the  following 
sums :  — 

Prom  the  income  of  the  General  Fund,  $3800. 
From  the  income  of  the  Publication  Fund,  $2500. 
From  the  income  of  the  Rumford  Fund,  $3050. 
From  the  income  of  the  Warren  Fund,  $800. 

On  motion  of  the  Treasurer,  it  was 

Voted,  That  the  assessment  for  the  ensuing  year  be  ten 
dollars  ($10). 

On  the  recommendation  of  the  Rumford  Committee,  it  was 

Voted,  To  award  -  the  Rumford  Premium  to  Charles  Gordon 
Curtis  for  his  improvements  in  the  utilization  of  heat  as  work 
in  the  steam-turbine. 

The  annual  election  resulted  in  the  choice  of  the  following 
officers  and  committees :  — 

John  Tbowbridob,  President. 
Elihu  Thomson,  Vice-President  for  Class  I. 
Henry  P.  Walcott,  Vice-President  for  Class  H. 
John  C.  Gra v,  Vice-President  for  Class  HI. 
Edwin  H.  Hall,  Corresponding  Secretary. 
WiLLTAM  Watson,  Recording  Secretary. 
Charles  P.  Bowditch,  Treasurer. 
A.  Lawrence  Rotch,  Librarian. 


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674  PROCEEDINGS  OP  THE  AMERICAN  ACADEMY. 

Councillors  for  Three  Yearn, 

Hammond  V.  Hates,  of  Class  I. 
Merritt  L.  FERiiALD,  of  Class  IL 
Henry  H.  Edbs,  of  Class  HI. 

.  Finance  Committee. 
John  Trowbridge, 
EuoT  C.  Clarke, 
Francis  Bartlbtt. 

Rumford  Committee. 
Charles  R.  Cross,  Arthur  G.  Webster, 

Edward  C.  Pickrring,     Elihu  Thomson, 
Erasmus  D  Leavitt,        Theodore  W.  Richards, 
Louis  Bell. 

C  M.  Warren  Committee. 

Leonard  P.  Kinnicutt,      Theodore  W.  Richards, 
Henry  P.  Talbot,  Arthur  A.  Noyes, 

Charles  R.  Sanger,  George  D.  Moore, 

James  F.  Norris. 

The  following  Standing  Committees  were  chosen:  — 

Publication  Committee. 

George  W.  Pierce,  of  Class  L 
Walter  B.  Cannon,  of  Class  IL 
Albert  A.  Howard,  of  Class  II L 

Library  Committee. 

Harry  M.  Goodwin,  of  Class  I. 
Samuel  Henshaw,  of  Class  IL 
Henry  W.  Haynes,  of  Class  IIL 

Auditing  Committee. 
Henry  H.  Edes^  Frederic  J.  Stimsok. 


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Goc 


BXCOBD8  OF  MEETINOS.  575 


ffaude  Committee. 


Arthur  O.  Webster,  A.  Lawrence  Botoh, 

Louis  Dbrr. 


The  following  gentlemen  were  elected  Fellows  of  the 
Academy :  -^ 

Roland  Burrage  Dixon,  of  Cambridge,  as  Resident  Fellow  in 
Class  III.,  Section  2  (Philology  and  Archaeology). 

Archibald  Carjr  Coolidge,  of  Boston,  as  Resident  Fellow  in 
Class  III.,  Section  8  (Political  Economy  and  History). 

Worthington  Chauncey  Ford,  of  Boston,  as  Resident  Fellow 
in  Class  III.,  Section  3  (Political  Economy  and  History). 

Edward  Caldwell  Moore,  of  Cambridge,  as  Resident  Fellow  in 
Class  III.,  Section  4  (Literature  and  the  Fine  Arts). 

Sir  David  Gill,  of  London,  as  Foreign  Honorary  Member  in 
Class  I.,  Section  1  (Mathematics  and  Astronomy). 

At  his  request,  Robert  Wheeler  Willson,  of  Cambridge,  Resi- 
dent Fellow  in  Class  I.,  Section  2,  was  transferred  to  Class  I., 
Section  1. 

On  motion  of  R  C.  Pickering  the  nominations  for  Associate 
Fellowship  were  referred  back  to  the  Council. 

Professor  Robert  W.  Willson  gave  a  communication  on  Halley's 
Comet 

The  following  papers  were  presented  by  title :  — 

**0n  the  Magnitude  of  an  Error  which  usually  Affects  the 
Results  of  Magnetic  Tests  upon  Iron  and  Steel  Rings."  By 
B.  0.  Peirce. 

"The  Effects  of  Sudden  Changes  in  the  Inductances  of  Certain 
Forms  of  Electric  Circuits  and  their  Mechanical  Analogies."  By 
B.  0.  Peirce. 

"  The  Influence  of  the  Magnetic  Characteristics  of  the  Iron 
Core  of  an  Induction  Coil  upon  the  Manner  of  Establishment  of 
a  Steady  Current  in  the  Primary  Circuit"     By  B.  0.  Peirce. 

"  The  Effect  of  the  Damping  due  to  the  Surrounding  Medium 
upon  the  Form  of  the  Oscillations  of  a  Swinging  Body."  By  B.  0. 
Peirce. 

"  Some  Dlustrations  of  the  Effects  of  Sudden  Changes  in  the 
Resistances  of  Inductive  Circuits."    By  B.  0.  Peirce. 


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576 


PROCEEDINQS  OF  THE  AMEBICAN  ACADEMY. 


"  The  Forms  of  the  Magnetic  Diagrams  for  Low  Fields  of  Cer- 
tain  very  Pure  Kinds  of  Soft  Iron  which  at  very  High  Excita- 
tions show  extraordinarily  Large  Values  of  L  "     By  B.  0.  Feirce. 

"  The  Reactions  of  Earthworms  to  Acids.**  By  S.  H.  Hurwitz. 
Presented  by  R  L.  Mark. 

'^  On  the  Electromagnetic  and  the  Thermomagnetic  Effects  in 
Soft  Iron."    By  Edwin  H.  Hall  and  L.  L.  Campbell 


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Class  I. 
Elihu  Thomson, 


Amerioan  Academy  of  Arte  and  Soienoes 

OFFICERS  AND  COMMITTEES   FOR   19x0-11. 


PRB8IDBNT. 

John  Trowbridge. 
VICB-PRB8IDBNT8. 

ClAM  II. 

Henry  P.  Walcott, 


Class  III. 
XoHN  C.  Gray. 


Class  I. 
William  L.  Hooper, 

William  R.  Livbrmorb, 

Hammond  V.  Hays, 


John  Trowbridge, 


CORRB8PONDINQ  8BCRSTARY. 

Edwin  H.  Hall. 

RBCORDINQ  8BCRBTARY. 

WiLUAM  Watson. 

TRSA8URSR. 

Charles  P.  Bowditch. 

UBRARIAN. 

A.  Lawrence  Rotch. 

COUNCILLORa. 
Class  IL 

Harold  C.  Ernst, 
Terms  expire  1911. 
Theobald  Smith, 
Terms  expire  191 2. 
Merritt  L.  Fernald, 
Terms  expire  191 3. 

COMMITTBB  OF  PINANCB. 

Eliot  C.  Clarke, 


in. 
Frederic  J.  Stimson. 

Charles  R.  Lanman. 

Henry  H.  Edes. 

Francis  Bartlett. 


Erasmus  D.  Leavitt, 
Arthur  G.  Webster, 


RUMFORD  COMMITTBB. 

Charles  R.  Cross,  Chairman^ 
Edward  C.  Pickering, 
Theodore  W.  Richards, 


C  M.  WARRBN  COMMITTBB. 
Leonard  P.  Kinnicutt,  Chairman, 
Henry  P.  Talbot,  Theodore  W.  Richards, 

Charles  R.  Sanger,  Arthur  A.  Noyes, 


Elihu  Thomson, 
Louis  Bell. 


George  D.  Moore, 
James  F.  Norris. 


COMMITTBB  OP  PUBLICATION. 

George  W.  Pierce,  of  Class  I,  Chairman, 

Walter  B.  Cannon,  of  Class  II,  Albert  A.  Howard,  of  Class  IIL 

COMMITTBB  ON  THB  LIBRARY. 

A.  Lawrence  Rotch,  Chairman, 
Harry  M.  Goodwin,  of  Class  I,  Samuel  Henshaw,  of  Class  II, 

Henry  W.  Haynes,  of  glass  III. 

AUDITINQ  COMMITTBB. 

Henry  H.  Edes,  Frederic  J.  Stimson. 

HOU8B  COMMITTBB. 

Arthur  G.  Webster,  Chairman, 

A.  Lawrence  Rotch,  Louis  Derr. 


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Googlf 


LIST 

or  THB 

FELLOWS  AND  FOREIGN  HONORARY  MEMBERS. 

(Oomotwl  to  July  20,  l9Uk) 


RESIDENT    FELLOWS.  — 195. 

(Number  limited  to  two  hundred.) 

Class  I.  —  Mathematical  and  Phy$ieal  Sciences.  —  79. 
Section  I.  —  Mathematics  and  Astronomy,  —  18. 

Solon  Irving  Bailey Cambridge 

William  Elwood  Byerly Cambridge 

Setb  Carlo  Chandler Wellesley  Hilkt 

Percival  Lowell Boston 

Edward  Charles  Pickering Cambridge 

William  Henry  Pickering       Cambridge 

Arthur  Searle Cambridge 

William  Edward  Story Worcester 

Henry  Taber Worcester 

Harry  Walter  Tyler Boston 

Oliver  Clinton  Wendell Cambridge 

Robert  Wheeler  Willson Cambridge 

Paul  Sebastian  Tendell Dorchester 


Section  H.  —  Physics.  —  27. 

Alexander  Graham  Bell Washington 

Louis  Bell Boston 

Clarence  John  Blake Boston 

Francis  Blake Weston 

George  Ashley  Campbell New  York 

Harry  Ellsworth  Clifford Newton 

Charles  Robert  Cross Brookline 


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580  RESIDENT   FELLOWS. 

Jjouis  Derr  BrooUine 

Alexander  Wilmer  Duff Worcester 

Arthur  Woolsey  Ewell Worcester 

Harry  Manley  Goodwin Roxborj 

Edwin  Herbert  Hall Cambridge 

Hammond  Vinton  Hayes Cambridge 

William  Leslie  Hooper SomerriUe 

William  White  Jacques Newton 

Frank  Arthur  Laws Boston 

Henry  Lefavour Boston 

Theodore  Lyman Bnx^line 

Charles  Ladd  Norton Boston 

Benjamin  Osgood  Peirce Cambridge 

Greorge  Washington  Pierce Cambridge 

Abbott  Lawrence  Rotch Bo6t<ni 

Wallace  Clement  Sabine Boston 

John  Stone  Stone Boston 

Elihu  Thomson Swampscott 

John  Trowbridge Cambridge 

Arthur  Gordon  Webster •    •  Wolcestw 


Section  IH.  —  Chemistry,  —  21. 

Gregory  Paul  Baxter Cambridge 

Arthur  Messinger  Comey Chester,  Pa. 

James  Mason  Crafts Boston 

Charles  William  Eliot Cambridge 

Henry  Fay Boston 

Charles  Loring  Jackson Cambridge 

Walter  Louis  Jennings Worcester 

Leonard  Parker  Rinnicutt Worcester 

Gilbert  Newton  Lewis Boston 

Charles  Frederic  Mabery Cleveland 

Greorge  Dunning  Moore Worcester 

James  Flack  Norris Boston 

Arthur  Amos  Noyes Boston 

Robert  Hallowell  Richards Jamaica  Plain 

Theodore  William  Richards Cambridge 

Charles  Robert  Sanger Cambridge 

Stephen  Pasohall  Sharpies «     .     .    •      Cambridge 

Francis  Humphreys  Storer Boston 

Henry  Paul  Talbot Newton 

William  Hultz  Walker Newton 

Charles  Hallet  Wing Boston 


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RESIDENT   FELLOWS.  581 


Section  IV.  —  Technology  and  Engineering.  — 18. 

Comfort  Avery  Adams Cambridge 

Alfred  Edgar  Burton Boston 

£liot  Cbanning  Clarke Boston 

Heinrich  Oscar  Hofman Jamaica  Plain 

Ira  Nelson  Hollis Cambridge 

Lewis  Jerome  Johnson Cambridge 

Arthur  Edwin  Kennelly Cambridge 

Gaetano  Lanza Boston 

Erasmus  Darwin  Leavitt Cambridge 

William  Roscoe  Liyermore New  York 

Hiram  Francis  Mills Lowell 

Cecil  Hobart  Peabody Brookline 

Andrew  Howland  Russell Paris 

Albert  Sanveur Cambridge 

Peter  Schwamb Arlington 

Henry  Lloyd  Smyth Cambridge 

George  Fillmore  Swain Boston 

William  Watson Boston 


Class  XL  —  Natural  and  Physiological  Sciences.  —  60 

Section  I.  —  Geology  ^  Mineralogy  y  and  Physics  of  the  Globe.  — 16. 

Henry  Helm  Clayton Milton 

Algernon  Coolidge Boston 

William  Otb  Crosby Jamaica  Plain 

Reginald  Aldworth  Daly Cambridge 

William  Morris  Dayis Cambridge 

Benjamin  Kendall  Emerson Amherst 

Oliver  Whipple  Huntington Newport 

Robert  Tracy  Jackson Cambridge 

Thomas  Augpistus  Jaggar,  Jr Brookline 

Douglas  Wilson  Johnson Cambridge 

Charles  Palache Cambridge 

John  Elliott  Pillsbury Washington 

Robert  DeCourcy  Ward Cambridge 

Charles  Hyde  Warren Aubumdale 

John  Eliot  Wolff Cambridge 

Jay  Backus  Woodworth Cambridge 


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582  BSSIDENT   FELXX>W& 

Section  n.  —  Botany.  —  11. 

Frank  Shipley  Collins Maklea 

William  Gilson  Farlow Cambridge 

Charles  Edward  Faxon Jamaica  Plain 

Merritt  Lyndon  Femald Cambridge 

George  Lincoln  Goodale Cambridge 

John  Greorge  Jack Jamaica  Plain 

Edward  Charles  Jeffrey Cambridge 

Benjamin  Lincoln  Robinson Cambridge 

Charles  Sprague  Sargent Brookline 

Arthur  Bliss  Seymour Cambridge 

Boland  Thaxter Cambridge 

Section  m.  —  Zodlogy  and  Physiology,  —  28. 

Bobert  Amory Boston 

Francis  Gano  Benedict Boston 

Henry  Pickering  Bowditch Jamaica  Plain 

William  Brewster Cambridge 

Louis  Cabot Brookline 

Walter  Bradford  Cannon Cambridge 

William  Ernest  Castle Cambridge 

Samuel  Fessenden  Clarke Williamstown 

William  Thomas  Councilman Boston 

Harold  Clarence  Ernst Jamaica  Plain 

Samuel  Henshaw Cambridge 

Edward  Laurens  Mark Cambridge 

Charles  Sedgwick  Minot Milton 

Edward  Sylvester  Morse Salem 

George  Howard  Parker Cambridge 

James  Jackson  Putnam Boston 

Herbert  Wilbur  Rand Cambridge 

Samuel  Hubbard  Scudder Cambridge 

William  Thompson  Sedgwick Boston 

William  Morton  Wheeler Boston 

James  Clarke  White Boston 

Harris  Hawthorne  Wilder Northampton 

William  McMichael  Woodworth Cambridge 

Section  IV.  —  Medicine  and  Surgery. — 10. 

Edward  Hickling  Bradford Boeton 

Arthur  Tracy  Cabot Boston 

Reginald  Heber  Fitz Boston 


Digitized  by  ^ 


BESIDENT   FELLOWS.  583 

SamoelJason  Hixter Boston 

William  Lambert  Richardson Boston 

Theobald  Smith Jamaica  Plain 

Oliver  Fairfield  Wadsworth Boston. 

Henry  Pickering  Walcott Cambridge 

John  Collins  Warren Bostooi 

Francis  Henry  WiUiams •    •    .  Boston^ 


Class  in.  —  Moral  and  Political  Sciences.  —  56. 

Section  I.  —  Philosophy  and  Jurisprudence.  —  7. 

Joseph  Henry  Beale Cambridge 

John  Chipman  Gray Boatcm 

Francis  Cabot  Lowell '  .  Boston* 

Hugo  Miinsterberg Cambridge 

Josiah  Royce Cambridge 

Frederic  Jesnp  Stimson Dedham 

Samuel  Williston Belmont 


Section  H.  —  Philology  and  Archasology.  — 19. 

Charles  Pickering  Bowditch Jamaica  Plain 

Luoien  Carr Cambridge 

Franklin  Carter New  Hayeu 

Roland  Barrage  Dixon Cambridge 

Jesse  Walter  Fewkes Washington 

William  Watson  Goodwin Cambridge 

Henry  Williamson  Haynes Boston 

Albert  Andrew  Howard Cambridge 

Charles  Rockwell  Lanman Cambridge 

David  Gordon  Lyon •  Cambridge 

Clifford  Herschel  Moore Cambridge 

George  Foot  Moore Cambridge 

Charles  Pomeroy  Parker Cambridge 

Frederick  Ward  Putnam Cambridge 

Edward  Robinson New  York 

Edward  Stevens  Sheldon Cambridge 

Herbert  Weir  Smyth Cambridge 

Franklin  Bache  Stephenson Boston 

John  Williams  White Cambridge 


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584  RESIDENT  FELLOWS. 

Section  EI.  —  Political  Economy  and  History.  — 12. 

Charles  Francis  Adams LanoolA 

Thomas  Nixon  Carver Cambridge 

Archibald  Cary  Coolidge Boston 

Andrew  MoFarland  Davis Cambridge 

Ephraim  Emerton Cambridge 

Worthington  Chaancey  Ford Boston 

Abner  Cheney  Goodell Salem 

Henry  Cabot  Lodge Nahant 

Abbott  Lawrence  Lowell Cambridge 

James  Ford  Rhodes Boston 

Charles  Card  Smith Boston 

Frank  William  Taussig Cambridge 

Section  IV.  —  Literature  and  the  Fine  Arts.  — 18. 

Francis  Bartlett Boston 

Arlo  Bates Boston 

Le  Baron  RusseU  Briggs Cambridge 

Henry  Herbert  Edes Cambridge 

Arthur  Fairbanks Boston 

William  Wallace  Fenn Cambridge 

Kuno  Francke Cambridge 

Edward  Henry  Hall Cambridge 

Thomas  Wentworth  Higginson Cambridge 

George  Lyman  Kittredge Cambridge 

Gardiner  Martin  Lane Boston 

William  Coolidge  Lane Cambridge 

Edward  Caldwell  Moore * Cambridge 

James  Hardy  Ropes Cambridge 

Denman  Waldo  Ross Cambridge 

William  Robert  Ware MUton 

Herbert  Langford  Warren Cambridge 

Barrett  Weuiell Boston 


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ASSOCIATE   FELLOWS.  585 


ASSOCIATE    FELLOWS.  — 80. 

(Number  limited  to  one  hundred.) 

Class  I.  —  Mathematical  and  Physical  Sciences.  —  81. 

Section  I.  —  Mathematics  and  Astronomy,  — 12. 

Edward  Emerson  Barnard Williams  Bay,  Wis. 

Sherburne  Wesley  Bornham Williams  Bay,  Wis. 

George  Davidson San  Francisco 

Fabian  Franklin Baltimore 

George  William  ffill West  Nyack,  N.  Y. 

Edward  Singleton  ii olden West  Point 

Emory  McClintock Morristown,  N.  J. 

Eliakim  Hastings  Moore Chicago 

Charles  Lane  Poor New  York 

George  Mary  Searle Washington 

Vesto  Melvin  Slipher Flagstaff,  Ariz. 

John  Nelson  Stockwell Cleveland 

Section  II.  —  Physics.  —  6. 

Carl  Bams     . Providence 

George  EUery  Hale Pasadena,  Cal. 

Thomas  Corwin  Mendenhall Worcester 

Albert  Abraham  Michelson Chicago 

Edward  Leamington  Nichols Ithaca 

Michael  Idvorsky  Pupin New  York 

Section  IH.  —  Chemistry,  —  7. 

Frank  Aastin  Grooch New  Haven 

Eugene  Waldemar  Hilgard Berkeley 

John  William  Mallet Charlottesville,  Ya. 

Edward  Williams  Morley West  Hartford,  Conn. 

Charles  Edward  Munroe Washington 

John  Ulric  Nef Chicago 

Ira  Remsen Baltimore 


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586  ASSOCIATE   FELLOWS. 

Section  IV.  —  Technology  and  Engineering,  —  6. 

Henry  Larcom  Abbot Cambridge 

Cyrus  Ballou  Comstock New  York 

William  Price  Craighill Charlestowu,  W.  Va. 

John  Fritz Bethlehem,  Pa. 

Frederick  Remsen  Hutton .  New  York 

Robert  Simpson  Woodward New  York 


Class  n.  —  Natural  and  Phonological  Sciences.  —  81. 

Section  I.  —  Geology ,  Mineralogy ,  and  Physics  of  the  Globe.  —  9. 

Cleveland  Abbe Washington 

George  Jarvis  Brush New  Haven 

Thomas  Chrowder  Chamberlin Chicago 

Edward  Salisbury  Dana New  Haven 

Walter  Gould  Davis Cordova,  Arg. 

Samuel  Frauklin  Emmons Washington 

Grove  Karl  Gilbert Washington 

Raphael  Pumpelly Newport 

Charles  Doolittle  Walcott Washington 

Section  II.  —  Botany.  —  6. 

Liberty  Hyde  Bailey Ithaca 

Douglas  Houghton  Campbell Palo  Alto 

John  Merle  Coulter Chicago 

Cyrus  Guernsey  Pringle Charlotte,  Vt 

John  Donuell  Smith Baltimore 

William  Trelease St.  Louis 

Section  IH.  —  Zoology  and  Physiology.  —  8. 

Joel  Asaph  Allen New  York 

Charles  Benedict  Davenport Cold  Spring  Harbor,  N.  Y. 

Frankliu  Paine  Mall Baltimore 

Silas  Weir  Mitchell Philadelphia 

Henry  Fairfield  Osborn New  York 

Addison  Emory  Verrill New  Haven 

Charles  Otis  Whitman Chicago 

Edmund  Beecher  Wilson New  York 


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ASSOCIATE   FELLOWS.  587 

Section  IV.  — Medicine  and  Surgery.  —  8. 

John  Shaw  Billings New  York. 

William  Stewart  Halsted Baltimore 

Abraham  Jacobi .       New  York 

William  Williams  Keen    . Philadelphia 

William  Osier Oxford 

Theophil  Mitchell  Prudden New  York 

William  Henry  Welch Baltimore 

Horatio  Curtis  Wood Philadelphia 


Class  HI.  —  Moral  and  Political  Sciences.  — 18, 

Section  I.  —  Philosophy  and  Jurisprudence,  —  4. 

Joseph  Hodges  Choate New  York 

William  Wirt  Howe New  Orleans 

Charles  Sanders  Peirce Milford,  Pa. 

George  Wharton  Pepper Philadelphia 

Section  H.  —  Philology  and  Archceology.  —  6. 

Timothy  Dwight New  Haven 

Basil  Lanneau  Gildersleeve Baltimore 

William  Arthur  Heidel Middletown 

Thomas  Raynesford  Lounsbury New  Haven 

Raf us  Byam  Richardson       New  York 

Andrew  Dickson  White Ithaca 

Section  HI.  —  Political  Economy  and  History.  —  4. 

Henry  Adams Washington 

Arthur  Twining  Hadley New  Haven 

Alfred  Thayer  Mahan New  York 

Henry  Morse  Stephens Berkeley 

Section  IV.  —  Literature  and  the  Fine  Arts.  — 4. 

James  Burrill  Angell Ann  Arbor 

Horace  Howard  Fumess Wallingford,  Pa. 

Herbert  Putnam Washington 

John  Singer  Sargent »    .    .     .     .      London 


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588  FOREIGN    HONOBABT   IfSBfBERS. 


FOREIGN  HONORARY  MEMBERS.  — 61. 

(Kamber  limited  to  0eTait7-flyo.) 

Class  I.  —  Mathematical  and  Physical  Sciences.  —  IS. 

Section  I.  —  Mathematics  and  Astronomy.  —  7. 

Arthur  Auwers      .  Berlin 

Sir  George  Howard  Darwin Cambridge 

Sir  David  Gill London 

Sir  William  HuggiDS London 

Felix  Klein Gottingen 

£raile  Picard     . , Paris 

Jules  Henri  Poincar^ Paris 

Section  H.  —  Physics.  —  4. 

Oliver  Heaviside Torquay 

Joseph  Larmor *.....   Cambridge 

John  William  Strutt,  Baron  Rayleigh Witham 

Sir  Joseph  John  Thomson  Cambridge 

Section  HI.  —  Chemistry.  —  5. 

Adolf,  Ritter  von  Baeyer Manich 

Emil  Fischer Berlin 

Jacobus  Henricus  van't  Hoff Berlin 

Wilhelm  Ostwald Leip>sic 

Sir  Henry  Enfield  Roscoe London 

Section  IV.  —  Technology  and  Engineering.  —  3. 

Maurice  L^vy Paris 

Heiurich  MUller-Breslau Berlin 

William  Cawthorne  Unwin ' .     .   London 


Class  IL — Natural  and  Physiological  Sciences,  —  22. 

Section  L  —  Geology,  Mineralogy,  and  Physics  of  the  Globe.  — 4. 

Sir  Archibald  Geikie London 

Julius  Hann Vienna 

Albert  Heim Zurich 

Sir  John  Murray Edinburgh 


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FOREIGN   HONORARY   MEMBERS.  589 

Sbction  n.  —  Botany.  —  6. 

Jean  Baptiste  Edouard  Bornet Paris 

Adolf  Engler Berlin 

Sir  Joseph  Dalton  Hooker Snnningdale 

Wilhelm  Pfeffer Leipsic 

Hermann,  Graf  zu  Solms-Laabach Strassbnrg 

£daard  Strasborger Bonn 

Section  HI. — Zoology  and  Physiology.  —  5. 

Ladimar  Hermann Konigsberg 

Hugo  Kronecker Bern 

Sir  Edwin  Ray  Lankester London 

Elias  Metschnikoff Paris 

Magnus  Gustav  Retzias Stockholm 

Section  IV.  — Medicine  and  Surgery.  — 7. 

Emil  yon  Behring Marburg 

Sir  Thomas  Lauder  Brunton,  Bart London 

Angelo  Celli Rome 

Sir  Victor  Alexander  Haden  Horsley Loudon 

Robert  Koch Berlin 

Joseph  Lister,  Baron  Lister London 

Friedrich  von  Recklinghausen Strassburg 


Class  m.  —  Moral  and  Political  Sciences,  —  20. 

Section  I.  — Philosophy  and  Jurisprudence.  —  4. 

Arthur  James  Balfour Prestonkirk 

Heinrich  Brunner Berlin 

Albert  Venn  Dicey Oxford 

Sir  Frederick  Pollock,  Bart London 

Section  H.  —  Philology  and  Archceology.  —  7. 

Ingram  Bywater London 

Friedrich  Delitzsch Berlin 

Hermann  Diels Berlin 

Wilhelm  Dorpfeld Athens 

Henry  Jackson Cambridge 

Hermann  Georg  Jacobi Bonn 

Gaston  Camille  Charles  Maspero Paris 


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590  FOREIGN  HONORABT  MEMBERS. 

Section  in.  —  Political  Economy  and  History,  —  5. 

James  Bryce .    London 

Adolf  Harnack Berlin 

John  Morley,  Viscount  Morley  of  Blackbnrn London 

Sir  Greorge  Otto  Trevelyan,  Bart London 

Pasquale  Villari Florence 

Section  IV.  —  Literature  and  the  Fine  Arts,  — 4. 

Georg  Brandes Copenhagen 

Samuel  Henry  Butcher London 

Jean  L^on  G^rdme Paris 

Rudyard  Kipling Burwash 


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STATUTES  AND  STANDING  VOTES. 


STATUTES. 

Adopted  May  80, 1854 :  amended  September  8,  1857,  November  12,  1862, 
May  24,  1864,  November  9,  1870,  May  27,  1878,  January  26,  1876, 
June  16,  1886,  October  8, 1890,  January  \\,and  May  10,  1898,  May 
9,  and  October  10,  1894,  March  13,  Jpn7  10,  and  May  8,  1895,  ifay 
8, 1901,  January  8,  1902,  May  10,  1905,  February  14  oiw?  i/arcA  14, 
1906,  January  13, 1909. 

CHAPTER  I. 
Of  Fellows  and  Foreign  Honoraby  Members. 

1.  The  Academy  consists  of  Resident  Fellows,  Associate  Fellows,  and 
Foreign  Honorary  Members.  They  are  arranged  in  three  Classes,  ac- 
cording to  the  Arts  and  Sciences  in  which  they  are  severally  proficient, 
viz.:  Class  I.  The  Mathematical  and  Physical  Sciences;  —  Class  II. 
The  Natural  and  Physiological  Sciences;  —  Class  III.  The  Moral  and 
Political  Sciences.  Each  Class  is  divided  into  foar  Sections,  viz.  : 
Class  I.,  Section  1.  Mathematics  and  Astrooomy;  —  Section  2.  Physics; 
—  Section  8.  Chemistry;  —  Section  4.  Technology  and  Engineering. 
Class  II.,  Section  1.  Geology,  Mineralogy,  and  Physics  of  the  Globe;  — 
Section  2.  Botany;  Section  8.  Zodlogy  and  Physiology;  —  Section  4. 
Medicine  and  Surgery.  Class  III.,  Section  1.  Theology,  Philosophy, 
and  Jurisprudence;  —  Section  2.  Philology  and  Archaeology;  —  Sec- 
tion 8.  Political  Economy  and  History ;  —  Section  4.  Literature  «nd 
the  Fine  Arts. 

2.  The  number  of  Resident  Fellows  residing  in  the  Commonwealth 
of  Massachusetts  shall  not  exceed  two  hundred,  of  whom  there  shall  not 
be  more  than  eighty  in  any  one  of  the  three  classes.  Only  residents  in 
the  Commonwealth  of  Massachusetts  shall  be  eligible  to  election  as  Resi- 
dent Fellows,  but  resident  fellowship  may  be  retained  after  removal  from 


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592  STATUTES  OP  THE  AMERICAN   ACADEMY 

the  Commonwealth.  Each  Resident  Fellow  shall  pay  an  admission  fee 
of  ten  dollars  and  such  annual  assessment,  not  exceeding  ten  .dollars, 
as  shall  be  voted  bj  the  Academy  at  each  annual  meeting.  Resident 
Fellows  only  may  vote  at  the  meetings  of  the  Academy. 

3.  The  number  of  Associate  Fellows  shall  not  exceed  one  hundred, 
of  whom  there  shall  not  be  more  than  forty  in  either  of  the  three  classes 
of  the  Academy.  Associate  Fellows  shall  be  chosen  from  persons  resid- 
ing outside  of  the  Commonwealth  of  Massachusetts.  They  shall  not  be 
liable  to  the  payment  of  any  fees  or  annual  dues,  but  on  removing  within 
the  Commonwealth  they  may  be  transferred  by  the  Council  to  resident 
fellowship  as  vacancies  there  occur. 

4.  The  number  of  Foreign  Honorary  Members  shall  not  exceed 
seventy-five;  and  they  shall  be  chosen  from  among  persons  most  eminent 
in  foreign  countries  for  their  discoveries  and  attainments'  in  either  of  the 
three  departments  of  knowledge  above  enumerated.  There  shall  not  be 
more  than  thirty  Foreign  Members  in  either  of  these  departments. 


CHAPTER  II. 
Op  Officers. 

1.  There  shall  be  a  President,  three  Vice-Presidents,  6ne  for  each 
Class,  a  Corresponding  Secretary,  a  Recording  Secretary,  a  Treasurer, 
and  a  Librarian,  which  officers  shall  be  annually  elected,  by  ballot,  at 
the  annual  meeting,  on  the  second  Wednesday  in  May. 

2.  There  shall  be  nine  Councillors,  chosen  from  the  Resident  Fellows. 
At  each  annual  meeting,  three  Councillors  shall  be  chosen,  by  ballot, 
one  from  each  Class,  to  serve  for  three  years ;  but  the  same  Fellow  shall 
not  be  eligible  for  two  successive  terms.  The  nine  Councillors,  with  the 
President,  the  three  Vice-Presidents,  the  two  Secretaries,  the  Treasurer, 
and  the  Librarian,  shall  constitute  the  Council.  Five  members  shall 
constitute  a  quorum.  It  shall  be  the  duty  of  this  Council  to  exercise  a 
discreet  supervision  over  all  nominations  and  elections.  With  the  con- 
sent of  the  Fellow  interested,  they  shall  have  power  to  make  transfers 
between  the  several  sections  of  the  same  Class,  reporting  their  action  to 
the  Academy. 

3.  The  Council  shall  at  its  March  Meeting  receive  reports  from  the 
Rumford  Committee,  the  C.  M.  Warren  Committee,  the  Committee  on 
PublicatioD,  the  Committee  on  the  Library,  the  President  and  Record- 


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OP  ARTS  AND  SCIENCES.  593 

ing  Secretary,  and  the  Treasurer,  proposing  the  appropriations  for  their 
work  during  the  year  beginning  the  following  May.  The  Treasurer  at 
the  same  meeting  shall  report  on  the  income  which  will  probably  be 
received  on  account  of  the  various  Funds  during  the  same  year. 

At  the  Annual  Meeting,  the  Council  shall  submit  to  the  Academy, 
for  its  action,  a  report  recommending  the  appropriations  which  in  the 
opinion  of  the  Council  should  be  made  for  the  various  purposes  of  the 
Academy. 

4.  If  any  office  shall  become  vacant  during  the  year,  the  vacancy  shall 
be  filled  by  a  new  election,  at  the  next  stated  meeting,  or  at  a  meeting 
called  for  this  purpose. 

CHAPTER  III. 
Of  Nominations  op  Officers. 

1.  At  the  stated  meeting  in  March,  the  President  shall  appoint  a 
Nominating  Committee  of  three  Resident  Fellows,  one  for  each  Class. 

2.  It  shall  be  the  duty  of  this  Nominating  Committee  to  prepare  a  list 
of  candidates  for  the  offices  of  President,  Vice-Presidents,  Corresponding 
Secretary,  Recording  Secretary,  Treasurer,  Librarian,  Councillors,  and 
the  Standing  Committees  which  are  chosen  by  ballot;  and  to  cause  this 
list  to  be  sent  by  mail  to  all  the  Resident  Fellows  of  the  Academy  not 
later  than  four  weeks  before  the  Annual  Meeting. 

3.  Independent  nominations  for  any  office,  signed  by  at  least  five 
Resident  Fellows,  and  received  by  the  Recording  Secretary  not  less  than 
ten  days  before  the  Annual  Meeting,  shall  be  inserted  in  the  call  for  the 
Annual  Meeting,  which  shall  then  be  issued  not  later  than  one  week 
before  that  meeting. 

4.  The  Recording  Secretary  shall  prepare  for  use,  in  voting  at  the 
Annual  Meeting,  a  ballot  containing  the  names  of  all  persons  nominated 
for  office  under  the  conditions  given  above. 

5.  When  an  office  is  to  be  filled  at  any  other  time  than  at  the  Annual 
Meeting,  the  President  shall  appoint  a  Nominating  Committee  in  accord- 
ance with  the  provisions  of  Section  1,  which  shall  announce  its  nomina- 
tion in  the  manner  prescribed  in  Section  2  at  least  two  weeks  before 
the  time  of  election.  Independent  nominations,  sit^ned  by  at  least  five 
Resident  Fellows  and  received  by  the  Recording  Secretary  not  later 
than  one  week  before  the  meeting  for  election,  shall  be  inserted  in  the 
call  for  that  meetmg. 


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594  STATUTES  OF  THE  AMERICAN  ACADEUT 

CHAPTER  IV. 
Op  THE  President. 

1 .  It  shall  be  the  duty  of  the  President,  and,  in  his  absence,  of  the 
senior  Vice-President  present,  or  next  officer  in  order  as  above  enumer- 
ated, to  preside  at  the  meetings  of  the  Academy ;  to  direct  the  Recording 
Secretary  to  call  special  meetings ;  and  to  execute  or  to  see  to  the  execu- 
tion of  the  Statutes  of  the  Academy.  Length  of  continuous  membership 
in  the  Academy  shall  determine  the  seniority  of  the  Vice-Presidents. 

2.  The  President,  or,  in  his  absence,  the  next  officer  as  above  enumer- 
ated, shall  nominate  members  to  serve  on  the  different  committees  of  the 
Academy  which  are  not  chosen  by  ballot 

3.  Any  deed  or  writing  to  which  the  common  seal  is  to  be  affixed 
shall  be  signed  and  sealed  by  the  President,  when  thereto  authorised 
by  the  Academy. 

CHAPTER  V. 
Op  Standing  Committees. 

1.  At  the  Annual  Meeting  there  shall  be  chosen  the  following  Stand- 
ing Committees,  to  serve  for  the  year  ensuing,  viz. :  — 

2.  The  Committee  on  Finance  to  consist  of  three  Fellows  to  be 
chosen  by  ballot,  who  shall  have,  through  the  Treasurer,  full  control  and 
management  of  the  funds  and  trusts  of  the  Academy,  with  the  power  of 
investing  and  of  changing  the  investment  of  the  same  at  their  discretion. 

3.  The  Rumford  Committee,  to  consist  of  seven  Fellows  to  be  chosen 
by  ballot,  who  shall  consider  and  report  to  the  Academy  on  all  applica- 
tions and  claims  for  the  Rumford  premium.  They  shall  also  report  to 
the  Council  in  March  of  each  year  on  all  appropriations  of  the  iueome  of 
the  Rumford  Fund  needed  for  the  coming  year,  and  shall  generally  see 
to  the  due  and  proper  execution  of  the  trust.  All  bills  incurred  on  ac- 
count of  the  Rumford  Fund,  within  the  limits  of  the  appropriation  made 
by  the  Academy,  shall  be  approved  by  the  Chairman  of  the  Rumford 
Committee. 

4.  The  C.  M.  Warren  Committee,  to  consist  of  seven  Fellows  to  be 
chosen  by  ballot,  who  shall  consider  and  report  to  the  Council  in  March 
of  each  year  on  all  applications  for  appropriations  from  the  income  of  the 
C.  M.  Warren  Fund  for  the  coming  year,  and  shall  generally  see  to  the  due 


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OF  ARTS  AND  SCIENCES.  595 

and  proper  execution  of  the  trust.  All  bilb  incurred  on  account  of  the 
C.  M.  Warren  Fund,  within  the  limits  of  the  appropriations  made  by  the 
Academy,  shall  be  approved  by  the  Chairman  of  the  C.  M.  Warren 
Committee. 

5.  The  Committee  on  Publication,  to  consist  of  three  Fellows,  one 
from  each  class,  to  whom  all  communications  submitted  to  the  Acad- 
emy for  publication  shall  be  referred,  and  to  whom  the  printing  of  the 
Proceedings  and  Memoirs  shall  be  entrusted.  This  Committee  shall  re- 
port to  the  Council  in  March  of  each  year  on  the  appropriations  needed 
for  the  coming  year.  All  bills  incurred  on  account  of  publications,  within 
the  limits  of  the  appropriations  made  by  the  Academy,  shall  be  approved 
by  the  Chairman  of  the  Committee  on  Publication. 

6.  The  Committee  on  the  Library,  to  consist  of  the  Librarian  ex 
officio,  and  three  other  Fellows,  one  from  each  class,  who  shall  examine 
the  library  and  make  an  annual  report  on  its  condition  and  management. 
This  Committee,  through  the  Librarian,  shall  report  to  the  Council  in 
March  of  each  year,  on  the  appropriations  needed  for  the  Library  for  the 
coming  year.  All  bills  incurred  on  account  of  the  Library,  within  the 
limits  of  the  appropriations  made  by  the  Academy,  shall  be  approved  by 
the  Librarian. 

7.  The  House  Committee  to  consist  of  three  Fellows.  This  Com- 
mittee shall  have  charge  of  all  expenses  connected  with  the  House, 
including  the  general  ex|)enses  of  the  Academy  not  specifically  assigned 
to  other  Committees.  This  Committee  shall  report  to  the  Council  in 
fiarch  in  each  year  on  the  appropriations  needed  for  their  expenses 
for  tlie  coming  year.  All  bills  incurred  by  this  Committee  within  the 
limits  of  the  appropriations  made  by  the  Academy  shall  be  approved  by 
the  Chairman  of  the  House  Committee. 

8.  An  auditing  Committee,  to  consbt  of  two  Fellows,  for  auditing  the 
accounts  of  the  Treasurer,  with  power  to  employ  an  expert  and  to  ap- 
prove his  bill. 

9.  In  the  absence  of  the  Chairman  of  any  Committee,  bills  may  be 
approved  by  a  member  of  the  Committee  designated  by  the  Chairman 
for  the  purpose. 

CHAPTER  VL 

Of  the  Secbetabies. 

1.  The  Corresponding  Secretary  shall  conduct  the  correspondence  of 
the  Academy,  recording  or  making  an  entry  of  all  letters  written  in  its 
name,  and  preserving  on  file  all  letters  which  are  received ;  and  at  each 


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596  STATUTES   OF  THE   AMERICAN  ACADEMY 

meeting  he  shall  present  the  letters  which  have  been  addressed  to  the 
Academy  since  the  last  meeting.  Under  the  direction  of  the  Council, 
he  shall  keep  a  list  of  the  Resident  Fellows,  Associate  Fellows,  and 
Foreign  Honorary  Members,  arranged  in  their  Classes  and  in  Sections 
in  respect  to  the  special  sciences  in  which  they  are  severally  proficient ; 
and  he  shall  act  as  secretary  to  the  Council. 

2.  The  Recording  Secretary  shall  have  charge  of  the  Charter  and 
Statute-book,  journals,  and  all  literary  papers  belonging  to  the  Academy. 
He  shall  recoid  the  proceedings  of  the  Academy  at  its  meetings;  and 
after  each  meeting  is  duly  opened,  he  shall  read  the  record  of  the  pre- 
ceding meeting.  He  shall  notify  the  meetings  of  the  Academy,  apprise 
officers  and  committees  of  their  election  or  appointment,  and  inform  the 
Treasurer  of  appropriations  of  money  voted  by  the  Academy.  He  shall 
post  up  in  the  Hall  a  list  of  the  persons  nominated  for  election  into  the 
Academy ;  and  when  any  individual  is  chosen,  he  shall  insert  in  the 
record  the  names  of  the  Fellows  by  whom  he  was  nominated. 

3.  The  two  Secretaries,  with  the  Chairman  of  the  Committee  of 
Publication,  shall  have  authority  to  publish  such  of  the  records  of  the' 
meetings  of  the  Academy  as  may  seem  to  them  calculated  to  promote 
its  interests. 

4.  Every  person  taking  any  books,  papers,  or  documents  belonging  to 
the  Academy  and  in  the  custody  of  the  Recording  Secretary,  shall  give  a 
receipt  for  the  same  to  the  Recording  Secretary. 


CHAPTER  VIL 
Op  THE  Tbeasurer. 

1.  The  Treasurer  shall  give  such  security  for  the  trust  reposed  in 
him  as  the  Academy  shall  require. 

2.  He  shall  receive  all  moneys  due  or  payable  to  the  Academy  and 
all  bequests  and  donations  made  to  the  Academy.  He  shall  pay  all  bills 
due  by  the  Academy,  when  approved  by  the  proper  officers  (except  those 
of  the  Treasurer's  office,  which  may  be  paid  without  such  approval), 
lie  shall  sign  all  leases  of  real  estate  in  the  name  of  the  Academy.  All 
transfers  of  stocks,  bonds,  and  other  securities  bek)nging  to  the  Academy 
shall  be  made  by  the  Treasurer  with  the  written  consent  of  one  member 
of  the  Committee  of  Finance,  lie  shall  keep  an  account  of  all  receipts 
and  expenditures,  shall  submit  his  accounts  annually  to  the  Auditing 


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OP   ARTS   AND   SCIENCES.  597 

Committee,  and  shall  report  the  same  at  the  expiration  of  his  term  of 
office  or  whenever  called  on  so  to  do  by  the  Academy  or  Council. 

3.  The  Treasurer  shall  keep  separate  accounts  of  the  income  and 
appropriation  of  the  Rumford  Fund  and  of  other  special  funds,  and 
report  the  same  annually. 

4.  The  Treasurer  may  appoint  an  Assistant  Treasurer  to  perform  his 
duties,  for  whose  acts,  as  such  assistant,  the  Treasurer  shall  be  responsi- 
ble ;  or  the  Treasurer  may  employ  any  Trust  Company,  doing  business 
in  Boston,  as  agent  to  perform  his  duties,  the  compensation  of  such  As- 
sistant Treasurer  or  agent  to  be  paid  from  the  funds  of  the  Academy. 


CHAPTER  VIIL 
Of  the  Librarian  and  Library. 

1.  It  shall  be  the  duty  of  the  Librarian  to  take  charge  of  the  books, 
to  keep  a  correct  catalogue  of  them,  to  provide  for  the  delivery  of  books 
from  the  Library,  and  to  appoint  such  agents  for  these  purposes  as  he 
may  think  necessary.  He  shall  make  an  annual  report  on  the  condition 
of  the  Library. 

2.  The  Librarian,  in  conjunction  with  the  Committee  on  the  Library, 
shall  have  authority  to  expend  such  sums  as  may  be  appropriated,  either 
from  the  General,  Rumford,  or  other  special  Funds  of  the  Academy,  for 
the  purchase  of  books,  periodicals,  etc.,  and  for  defraying  other  necessary 
expenses  connected  with  the  Library. 

3.  To  all  books  in  the  Libraiy  procured  from  the  income  of  the 
Rumford  Fund,  or  other  special  funds,  the  Librarian  shall  cause  a  stamp 
or  label  to  be  affixed,  expressing  the  fact  that  they  were  so  procured. 

4.  Every  person  who  takes  a  book  from  the  Library  shall  give  a 
receipt  for  the  same  to  the  Librarian  or  his  assistant. 

«5.  Every  book  shall  be  returned  in  good  order,  regard  being  had  to 
the  necessary  wear  of  the  book  with  good  usage.  If  any  book  shall 
be  lost  or  injured,  the  person  to  whom  it  stands  charged  shall  replace 
it  by  a  new  volume  or  set,  if  it  belongs  to  a  set,  or  pay  the  current 
price  of  the  volume  or  set  to  the  Librarian  ;  and  thereupon  the  remain- 
der of  the  set,  if  the  volume  belonged  to  a  set,  shall  be  delivered  to  the 
person  so  paying  for  the  same. 

6.  All  books  shall  be  returned  to  the  Library  for  examination  at 
least  one  week  before  the  Annual  Meeting. 


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598  STATUTES  OP  THE   AMEBICAN  ACADEMY 

7.  The  Libmnan  shall  have  castody  of  the  Pablicatioiis  of  tbe 
Academy.  With  the  advice  and  ooosent  of  the  Presideat,  he  may  effect 
exchanges  with  other  associations. 


CHAPTER  IX. 
Op  Meetings. 

1.  There  shall  be  annually  fonr  stated  meetings  of  the  Academy; 
namely,  on  the  second  Wednesday  in  May  (the  Annual  Meeting),  on 
the  second  Wednesday  in  October,  on  the  second  Wednesday  in  Janaarjy 
and  on  the  second  Wednesday  in  March.  At  these  meetings,  only,  or  at 
meetings  adjourned  from  these  and  regularly  notified,  or  at  special  meet- 
ings called  for  the  purpose,  shall  appropriations  of  money  be  made,  or  al- 
terations of  the  statutes  or  standing  votes  of  the  Academy  be  effected. 

Special  meetings  shall  be  called  by  the  Recording  Secretary  at  the  re- 
quest of  the  President  or  of  a  Vice-President  or  of  five  Fellows.  Notifi- 
cations of  the  special  meetings  shall  contain  a  statement  of  the  purpose 
for  which  the  meeting  is  called. 

2.  Fifteen  Resident  Fellows  shall  constitute  a  quorum  for  the  trans- 
action of  business  at  a  stated  or  special  meeting.  Seven  Fellows  shall 
be  sufficient  to  constitute  a  meeting  for  scientific  oommunicatioDa  and 
discussions. 

3.  The  Recording  Secretary  shall  notify  the  meetings  of  the  Academy 
to  each  Resident  Fellow ;  and  he  may  cause  the  meetings  to  be  adver- 
tised, whenever  he  deems  such  further  notice  to  be  needftd. 


CHAPTER  X. 
Op  the  Election  op  Fellows  and  Honorary  Members. 

1.  Elections  shall  be  made  by  ballot,  and  only  at  stated  meetings. 

2.  Candidates  for  election  as  Resident  Fellows  must  be  proposed  by 
two  Resident  Fellows  of  the  section  to  which  the  proposal  is  made,  in 
a  recommendation  signed  by  them ;  and  this  recommendation  shall  be 
transmitted  to  the  Corresponding  Secretary,  and  by  him  referred  to  the 
Council.     No  person  recommended  shall  be  reported  by  the  Coonoil  as  a 


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OP  ARTS   AND  SCIENCES.  599 

candidate  for  election,  unless  he  shall  have  received  the  approval  of  at 
least  five  members  of  the  Council  present  at  a  meeting.  All  nominations 
thus  approved  shall  be  read  to  the  Academy  at  any  meeting,  and  shall 
then  stand  on  the  nomination  list  until  the  next  stated  meeting,  and  until 
the  balloting.  No  person  shall  be  elected  a  Resident  Fellow,  unless  he 
shall  have  been  resident  in  this  Commonwealth  one  year  next  preceding 
his  election.  If  any  person  elected  a  Resident  Fellow  shall  neglect  for 
one  year  to  pay  his  admission  fee,  his  election  shall  be  void ;  and  if  any 
Resident  Fellow  shall  neglect  to  pay  his  annual  assessments  for  two 
years,  provided  that  his  attention  shall  have  been  called  to  this  article, 
he  shall  be  deemed  to  have  abandoned  his  Fellowship  ;  but  it  shall  be  in. 
the  power  of  the  Treasurer,  with  the  consent  of  the  Council,  to  dispense 
(sub  silentio)  with  the  payment  both  of  the  admission  fee  and  of  the 
assessments,  whenever  in  any  special  instance  he  shall  think  it  advisable 
so  to'  do.  In  the  case  of  officers  of  the  Army  or  Navy  who  are  out  of 
the  state  on  duty,  payment  of  the  annual  assessment  may  be  waived 
during  such  absence  if  continued  during  the  whole  official  year  and  if 
notification  of  such  absence  be  sent  to  the  Treasurer. 

3.  The  nomination  and  election  of  Associate  Fellows  shall  take  place 
in  the  manner  prescribed  in  reference  to  Resident  Fellows. 

4.  The  nomination  and  election  of  Foreign  Honorary  Members  shall 
take  place  in  the  manner  prescribed  for  Resident  Fellows,  except  that 
the  nomination  papers  shall  be  signed  by  at  least  seven  members  of  the 
Council  before  being  presented  to  the  Academy. 

5.  Three-fourths  of  the  ballots  cast  must  be  affirmative,  and  the 
number  of  affirmative  ballots  must  amount  to  eleven  to  effect  an  elec-* 
tioh  of  Fellows  or  Foreign  Honorary  Members. 

6.  If,  in  the  opinion  of  a  majority  of  the  entire  Council,  any  Fellow — 
Resident  or  Associate  —  shall  have  rendered  himself  unworthy  of  a 
place  in  the  Academy,  the  Council  shall  recommend  to  the  Academy 
the  termination  of  his  Fellowship;  and  provided  that  a  majority  of  two- 
thirds  of  the  Fellows  at  a  stated  meeting,  consisting  of  not  less  than 
fifty  Fellows,  shall  adopt  this  recommendation,  his  name  shall  be  stricken 
off  the  roll  of  Fellows. 


CHAPTER  XI. 

Op  Amendments  op  the  Statutes. 

1.  All  proposed  alterations  of  the  Statutes,  or  additions  to  them,  shall 
be  referred  to  a  committee,  and,  on  their  report  at  a  subsequent  stated 
meeting  or  a  special  meeting  called  for  the  purpose,  shall  require  for 


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600  STATUTES  OF  THE  AMERICAN  ACADEMY 

enactment  a  majority  of  two-thirds  of  the  members  present,  and  at  least 
eighteen  affirmative  votes. 

2.  Standing  votes  may  be  passed,  amended,  or  rescinded  at  a  stated 
meeting,  or  a  special  meeting  called  for  the  purpose  by  a  majority  of  two* 
thirds  of  the  members  present.  They  may  be  suspended  by  a  unanimoas 
vote. 

CHAPTER  XII. 

Op  Literary  PERPORMANCEa 

1.  The  Academy  will  not  express  its  judgment  on  literary  or 
scientific  memoirs  or  performances  submitted  to  it,  or  included  in  its 
publications. 


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OF  ARTS  AND  SaENCES.  601 


STANDING  VOTES. 

1.  Communications  of  which  notice  has  been  given  to  the  Secretary 
•hall  take  precedence  of  those  not  so  notified. 

2.  Associate  Fellows,  Foreign  Honorary  Members,  and  Resident 
Fellows,  who  have  paid  all  fees  and  does  chargeable  to  them,  are  en- 
titled to  receive  one  copy  of  each  volume  or  article  printed  by  the 
Academy  on  application  to  the  Librarian  personally  or  by  written  order 
within  two  years  of  the  date  of  publication.  Exceptions  to  this  rule 
may  be  made  in  special  cases  by  vote  of  the  Academy. 

3.  The  Committee  of  Publication  shall  fix  from  time  to  time  the  price 
at  which  the  publications  of  the  Academy  may  be  sold.  But  members 
may  be  supplied  at  half  this  price  with  volumes  which  they  are  not 
entitled  to  receive  free,  and  which  are  needed  to  complete  their  sets. 

4.  Two  hundred  extra  copies  of  each  paper  accepted  for  publication 
in  the  Memoirs  or  Proceedings  of  the  Academy  shall  be  placed  at  the 
disposal  of  the  author,  free  of  charge. 

5.  Resident  Fellows  may  borrow  and  have  out  from  the  Library  six 
volumes  at  any  one  time,  and  may  retain  the  same  for  three  months,  and 
no  longer. 

6.  Upon  special  application,  and  for  adequate  reasons  assigned,  the 
Librarian  may  permit  a  larger  number  of  volumes,  not  exceeding  twelve, 
to  be  drawn  horn  the  Library  for  a  limited  period. 

7.  Works  published  in  numbers,  when  unbound,  shall  not  be 
taken  from  the  Hall  of  the  Academy,  except  by  special  leave  of  the 
Librarian. 

8.  Books,  publications,  or  apparatus  shall  be  procured  from  the 
income  of  the  Rumford  Fund  only  on  the  certificate  of  the  Rumford 
Committee  that  they,  in  their  opinion,  will  best  facilitate  and  encourage 
the  making  of  discoveries  and  improvements  which  may  merit  the  Rum- 
ford Premium;  and  the  approval  of  a  bill  incurred  for  such  purposes 
by  the  Chairman  shall  be  accepted  by  the  Treasurer  as  proof  that  such 
certificate  has  been  given. 

9.  A  meeting  for  receiving  and  discussing  scientific  communications 
may  be  held  on  the  second  Wednesday  of  each  month  not  appointed  for 
stated  meetings,  excepting  July,  August,  and  September. 

10.  No  report  of  any  paper  presented  at  a  meeting  of  the  Academy 
shall  be  published  by  any  member  without  the  consent  of  the  author, 
and  no  report  shall  in  any  case  be  published  by  any  member  in  a  news* 
paper  as  an  account  of  the  proceedings  of  the  Academy. 


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602  STATUTES  OF  THE  AMERICAN   ACADEHT. 


RUMFORD  PREMIUM. 

In  conformity  with  the  terms  of  the  gift  of  Benjamin,  Count  Rumford, 
granting  a  certain  fand  to  the  American  Academy  of  Arts  and  Sciences, 
and  with  a  decree  of  the  Supreme  Judicial  Court  for  carrying  into  effect 
the  general  charitable  intent  and  purpose  of  Count  Rumford,  as  ex- 
pressed in  his  letter  of  gift,  the  Academy  is  empowered  to  make  from 
the  income  of  said  fund,  as  it  now  exists,  at  any  Annual  Meeting,  an 
award  of  a  gold  and  a  silver  medal,  being  together  of  the  intrinsic  value 
of  three  hundred  dollars,  as  a  premium  to  the  author  of  any  important 
discovery  or  useful  improvement  in  light  or  in  heat,  which  shall  have 
been  made  and  published  by  printing,  or  in  any  way  made  known  to 
the  public,  in  any  part  of  the  continent  of  America,  or  any  of  the 
American  islands ;  preference  being  always  given  to  such  discoveries 
as  shall,  in  the  opinion  of  the  Academy,  tend  most  to  promote  the  good 
of  mankind ;  and  to  add  to  such  medals,  as  a  further  premium  for  such 
discovery  and  improvement,  if  the  Academy  see  fit  so  to  do,  a  sum  of 
money  not  exceeding  three  hundred  dollars. 


Digitized  by 


INDEX. 


Adds,  The  Reactions  of  Earthwonns 
to,  576. 

Aero  Club  of  America,  Invitation 
from,  553. 

Aeroplanes,  The  future  of,  554. 

Agassiz,  Alexander,  Letter  from,  555; 
Death  of,  565. 

Air,  Resistance  of,  to  a  Swinging 
Magnet,  558. 

Air  Resistance  to  Falling  Inch  Spheres, 
377,  560. 

American  Philosophical  Society,  Let- 
ter from,  553,  560. 

American  Scientific  Congress,  565. 

Ames,  J.  B.,  Death  of,  559. 

Amphibians,  The  Reactions  of,  to 
Light,  159,  559. 

Antimony,  The  Quantitative  Deter- 
mination of,  by  the  Gutzeit 
Method,  19,  554. 

Antarctic  exploration,  554,  555. 

Assessment,  Annual,  Amount  of, 
573. 

Association  des  Ing^nieurs  Electri- 
ciens  sortis  de  Tlnstitut  electro- 
technique  Montefiore,  circular 
from,  566. 

Atomic  Weight  of  Phosphorus,  A  Re- 
vision of  the,  135,  554. 

Beemaert,  A.,  Letter  from,  559. 

Baxter,  G.  P.,  and  Jones,  G.,  A  Re- 
vision of  the  Atomic  Weight  of 
Phosphorus.  First  Paper.  —  The 
Analysis  of  Silver  Phosphate,  135, 
554. 

Benedict,  F.  G.,  accepts  Resident 
Fellowship,  553. 

Biddlecombe,  A.,  Letter  from,  560. 

Boston  "1915"  Director,  Circular 
from,  565. 


Boston  "1915"  Directorate  Confer- 
ence, 561. 

Boston  "1915"  Conmiittee,  Circular 
from,  553,  560. 

Bowditch,  C.  P.,  Report  of  Treasurer, 
566. 

Buriingame,  E.  W.,  Buddhaghosa's 
Dhammapada  Commentary,  and 
the  Titles  of  its  three  hundred  and 
ten  Stories,  together  with  an  Index 
thereto  and  an  Analysis  of  Vaggas 
I.-IV.,  465,  558. 

Calcium  Carbide.  On  the  Equi- 
librium of  the  System  consisting  of 
Lime,  Carbon,  Calcium  Carbide 
and  Carbon  Monoxide,  429,  561. 

Campbell,  L.  L.  See  Hall,  Edwin  H., 
and  Campbell,  L.  L. 

Carbon.  On  the  Equilibrium  of  the 
System  consisting  of  Lime,  Car- 
bon, Calcium  Carbide  and  Carbon 
Monoxide,  429,  561. 

Carbon  Compound,  The  Spectrum  of 
a,  in  the  Region  of  Extremely 
Short  Wave-Lengths,  313,  558. 

Carbon  Dioxide,  On  the  Applicability 
of  the  Law  of  Corresponding  States 
to  the  Joule-Thomson  Effect  in 
Water  and,  241,  558. 

Carbon  Monoxide.  On  the  Equilib- 
rium of  the  System  consisting  of 
Lime;  Carbon,  Calcium  Carbide 
and  Carbon  Monoxide,  429,  561. 

Charter,  Amendment  of,  558,  562. 

Chaucer,  Moot  Points  about,  556. 

Chemical  Compositions,  Average,  of 
Igneous-Rock  Types,  209,  558. 

Chemical  Laboratory  of  Harvard 
College, 'Contributions  from,  19, 
135. 


Digitized  by  LjOOQIC 


604 


INDEX. 


Chlorsulphonic  Acid,  The  Prepara- 
tion and  Properties  of,  554. 

Circuits,  The  Equivalent,  of  Com- 
posite Lines  in  the  Steady  State, 
29,  554. 

Committees,  Standing,  appointed, 
574;  List  of,  577. 

Congress  of  Americanists,  Seven- 
teenth, 566. 

Coolidge,  A.  C,  elected  Resident 
Fellow,  575. 

Council,  Report  of,  666;  Financial 
Report  of,  572. 

Cross,  C.  R.,  Report  of  the  Rumford 
Committee,  569. 

Curtis,  Charles  Gordon,  awarded 
Rumford  Premium,  573. 

Daly,  R.  A.,  Average  Chemical  Com- 
positions of  Igneous-Rock  Types, 
207,  558. 

Davis,  H.  N.,  Notes  on  Certain  Ther- 
mal Properties  of  Steam,  265,  558. 
On  the  Applicability  of  the  Law  of 
Corresponding  States  to  the  Joule- 
Thomson  Effect  in  Water  and 
Carbon  Dioxide,  241,  558. 

Davis,  W.  M.,  The  Italian  Riviera 
Levante,  561. 

Derr,  L.,  Photographs  of  Yellowstone 
National  Park,  558. 

Dhammapada  Commentary,  Buddha- 
ghosa's,  465,  558. 

Dixon,  R.  B.,  elected  Resident  Fel- 
low, 575. 

Dolbear,  A.  E.,  Death  of,  561. 

Domaldp,  K.,  Death  of,  557. 

Earthworms,  The  Reactions  of,  to 
Acids,  576. 

Echeandia,  A  Preliminary  Synopsis  of 
the  Genus,  387,  560. 

Edes,  H.  H.,  Some  Lacunae  in  the 
Archives  of  the  Academy,  564. 

Electric  Circuits  and  their  Mechani- 
cal Analogies,  The  Effects  of 
Sudden  changes  in  the  Induc- 
tances of  Certain  Forms  of,  575. 

Electrical  Oscillations  of  a  Hertz 
Rectilinear  Oscillator,  Experiments 
on  the,  323,  558. 


Electricity,  Discharges  of,  throu^ 
Hydrogen,  453,  558. 

Electrolysis,  Some  Minute  Phenom- 
ena of,  369,  559. 

Elia  De  Cyon  prize,  1910,  561. 

Evaporation  from  the  Surface  of  a 
Solid  Sphere,  On,  361,  561. 

Ewell,  A.  W.,  accepts  Resident  Fel- 
lowship, 553. 

Fairbanks,  Arthur,  elected  Resident 

Fellow,    559;     accepts    Resident 

Fellowship,  560. 
Farlow,   W.   G.,   Delegate  to  Inter- 
national Botanical  Congress,  559. 
Fellows,  Associate,  deceased,  — 

S.  W.  Johnson,  562. 

H.  C.  Lea,  657. 

Simon  Newcomb,  654. 

J.  M.  Oriway,  564. 

W.  Sellers,  562. 

W.  G.  Sunmer,  666. 
Fellows,  Associate,  elected,  — 

W.  A.  Heidel,  669. 
Fellows,  Associate,  List  of,  685. 
Fellows,  Resident,  deceased,  — 

Alexander  Agassiz,  566. 

J.  B.  Ames,  559. 

M.  H.  Morgan,  566. 
Fellows,  Resident,  elected,  — 

A.  C.  Coolidge,  675. 

R.  B.  Dixon,  576. 

Arthur  Fairbanks,  659. 

W.  C.  Ford,  676. 

C.  H.  Moore,  563. 

E.  C.  Moore,  576. 
C.  P.  Parker,  663. 

Fellows,  Resident,  List  of,  679. 

Fenn,  W.  W.,  accepts  Resident  Fel- 
lowship, 653. 

Femald,  M.  L.,  New  and  little  known 
Mexican  Plants,  chiefly  Labia tae, 
415,  660;  Some  New  Factors  in 
Determining  the  Location  of  Wine- 
land  the  Good,  664. 

Ford,  W.  C,  elected  Resident  Fellow, 
576. 

Foreign     Honorary     Members,     de- 
ceased — 
W.  F.^Kohlrausch,  662. 

F.  W.  Maitland,  559, 


Digitized  by 


Goot 


INDEX. 


605 


Foreign  Honorary  Members,  elected,  — 

Sir  David  Gill,  676. 
Foreign  Honorary  Members,  List  of, 

5S8. 
Foslie,  M.  H.,  Death  of,  559. 
Fumivall,    F.    J.,    accepts    Foreign 

Honorary  Membership,  553. 

Gases,  Friction  in,  at  Low  Pressures, 
1,  554. 

Gases,  Measurement  of  Pressure  and 
Density  in,  with  the  Micro  Bal- 
ance, 558. 

General  Fimd,  567,  672;  Appropriar 
tions  from  the  Income  of,  673. 

Gentianaceae,  Spermatophytes,  new 
or  reclassified,  chiefly  Rubiaceae 
and,  394,  660. 

Gill,  Sir  David,  elected  Foreign  Hon- 
orary Member,  675. 

Gragg,  F.  A.,  A  Study  of  the  Greek 
Epigram  before  300  b.  c,  661. 

Gray  Herbarium  of  Harvard  Uni- 
versity, Contributions  from,  385. 

Greek  Epigram,  A  Study  of  the,  be- 
fore 300  b.  c,  561 . 

Gutzeit  Method,  The  Quantitative 
Determination  of  Antimony  by 
the,  19,  554. 

Hall,  Edwin  H.,  Air  Resistance  to 
Falling  Inch  Spheres,  377,  560. 

Hall,  Edwin  H.,  and  Campbell,  L.  L., 
On  the  Electromagnetic  and  the 
Thermomagnetic  Effects  in  Soft 
Iron,  576. 

Harvard  College.  See  Harvard  Uni- 
versity. 

Harvard  University,  Invitation  from, 
553;   Announcement  of,  560. 

Harvard  University.  See  Chemical 
Laboratory,  Gray  Herbarium,  Jef- 
ferson Physical  Laboratory,  and 
Zoological  Laboratory. 

Heidel,  W.  A.,  elected  Associate  Fel- 
low, 559;  accepts  Associate  Fel- 
,  lowship,  560. 

Heidel,  W.  A.,  Tlepl  ^Unrew,  A  Study 
of  the  Conception  of  Nature 
among  the  Pre-Socratics,  77,  554. 

Hesse,  C.  A.,  Letter  from,  553. 


Historical   Society  of  Pennsylvania, 

Letter  from,  565. 
Hogg,  J.  L.,  Friction  in  Gases  at  Low 

Pressures,  1,  654. 
Hostinsky,  O.,  Death  of,  560. 
House  Committee,  Report  of,  571. 
House  expenses,  Appropriations  for, 

572. 
Hurwitz,   S.   H.,   The   Reactions   of 

Earthworms  to  Acids,  576. 
Hydrogen,  Discharges  of  Electricity 

through,  453,  558. 

Inductive  Circuits,  Some  Illustrations 
of  the  Effects  of  Sudden  Changes 
in  the  Resistances  of,  575. 

International  Agrogeological  Confer- 
ence, Second,  565. 

International  American  Scientific  Con- 
gress, 565. 

International  Congress  of  American- 
ists, 17th  Congress,  555. 

International  Congress  of  Botany, 
Third,  559. 

International  Congress  of  Entomol- 
ogy, First,  659. 

International  Geological  Congress, 
Eleventh,  565. 

International  Zoological  Congress, 
Eighth,  557. 

Iron,  Soft,  The  Forms  of  the  Magnetic 
Diagrams  for  Low  Fields  of  Certain 
very  Pure  Kinds  of,  which  at  very 
High  Excitations  show  extraordi- 
narily Large  Values  of  I.,  575. 

Iron,  Soft,  On  the  Electromagnetic  and 
the  Thermomagnetic  Effects  in,  676. 

Italian  Riviera  Levante,  The,  561. 

Jacobi,  H.,  accepts  Foreign  Honor- 
ary Membership,  553. 

Jefferson  Physical  Laboratory,  Con- 
tributions from,  1,  241,  265,  313, 
323,  337,  353,  361,  369,  377,  453. 

Johnson,  S.  W.,  Death  of,  562. 

Jones,  G.  See  Baxter,  G.  P.,  and 
Jones,  G. 

Joule-Thomson  Effect  in  Water  and 
Carbon  Dioxide,  On  the  Applica- 
bility of  the  Law  of  Correspond- 
ing States  to  the,  241,  558. 


Digitized  by  LjOOQIC 


606 


INDEX. 


Eennelly,  A.  E.,  The  Equivalent  Cir- 
cuits of  Composite  Lines  in  the 
Steady  State,  29,  554. 

Einnicutt,  L.  P.,  Report  of  C.  M. 
Warren  Committee,  570. 

Kittredge,  G.  L.,  Moot  Points  about 
Chaucer,  556. 

Kohhrausch,  W.  F.,  Death  of,  562. 

Labiatae,  New  and  little  known  Mexi- 
can Plants,  chiefly,  415,  560. 

Lacunae  in  the  Archives  of  the  Acad- 
emy, 564. 

Lamina,  Homogeneous,  The  Effect  of 
Leakage  at  the  Edges  upon  the 
Temperatures  within  a,  through 
which  Heat  is  being  conducted, 
353,  558. 

Lane,  G.  M.,  accepts  Resident  Fel- 
lowship, 553. 

Lea,  H.  C,  Death  of,  557. 

Leakage,  The  Effect  of,  at  the  Edges 
upon  the  Temperatures  within  a 
Homogeneous  Lamina  through 
which  Heat  is  being  conducted, 
353,  558. 

Lewis,  G.  N.,  and  Tohnan,  R.  C,  The 
Principle  of  Relativity  and  Non- 
Newtonian.  Mechanics,  554. 

Librarian,  Report  of,  568. 

Library,  Appropriation  for,  572. 

Light,  The  Reactions  of  Amphibians 
to,  159,  559. 

Lime,  On  the  Equilibrium  of  the 
System  consisting  of  Lime,  Carbon, 
Calcium  Carbide  and  Carbon 
Monoxide,  429,  56L 

Lines,  Composite,  The  Equivalent 
Circuits  of,  in  the  Steady  State, 
29,  554. 

Lowell,  Abbott  Lawrence,  Liaugura- 
tion,  invitation  to,  553;  Announce- 
ment of,  560. 

Lowell,  P.,  Photographs  of  Mars  and 
Saturn,  561. 

Lycodpodium  complanatum,  Ameri- 
can Forms  of,  412,  560. 

Lyon,  D.  G.,  Harvard  Explorations 
in  Samaria,  560. 

Lyman,  Theodore,  The  Spectrum  of  a 
Carbon  Compound  in  the  Region 


of  Extremely  Short  Wave-Lengths, 
313,  558. 

Magnet,  The  Resistance  of  the  Air  to 
a  Swinging,  558. 

Magnetic  Diagrams,  The  Forms  of  the, 
for  Low  Fields  of  Certain  very  Pure 
Kinds  of  Soft  Iron  which  at  very 
High  Excitations  show  extraordi- 
narily Large  Values  of  I.,  575. 

Magnetic  Tests  upon  Irqn  and  Steel 
Rings,  On  the  Magnitude  of  an 
Error  which  usually  affects  the 
Results  of,  575. 

Maitland,  F.  W.,  Death  of,  559. 

Mars*and  Saturn,  Photographs  of,  561. 

Massachusetts  Instituteof  Technology. 
See  Rogers  I^aboratory  of  Pl^ysics. 

Mexican  Phanerogams,  Notes  and 
new  Species,  422,  560. 

Mexican  Plants,  New  and  little 
known,  chiefly  Labiatae,  415,  560. 

Micro  Balance,  ^leasurement  of  Pres- 
sure and  Density  in  Gases  with 
the,  558. 

Moore,  C.  H.,  elected  Resident  Fel- 
low, 563;  accepts  Resident  Fel- 
lowship, 565. 

Moore,  E.  C,  elected  Resident  Fel- 
low, 575. 

Morgan,  M.  H.,  Death  of,  565. 

Morse,  H.  W.,  Measurement  of  Pres- 
sure and  Density  in  Gases  with 
the  Micro  Balance,  558. 

Morse,  H.  W.,  On  Evaporation  from 
the  Surface  of  a  Solid  Sphere,  361, 
561 ;  Some  Minute  Phenomena  of 
Electrolysis,  369,  559. 

Museo  Nacional,  Mexico,  559. 

Museum  of  Comparative  ZoSlogy, 
Notice  from  Faculty  of,  566. 

Museum  of  Comparative  S^oology  at 
Harvard  College.  See  Zoological 
Laboratory. 

Museum  of  Fine  Arts,  Invitation 
from,  555. 

Nature,  A  Study  of  the  Conception  of, 
among  the  Pre-Socratics,  77,  554. 

Naval  Observatory,  Resolution  con- 
cerning, 557. 


Digitized  by  LjOOQIC 


INDEX. 


607 


Newcomb,  Simon,  Death  of,  554. 

Newport,  Probate  Court,  Notice  from, 
666. 

Nikitin,  Serge,  Death  of,  557. 

Niles,  W.  H.,  resigns  Resident  Fellow- 
ship, 561. 

Nobel  Prize,  1910,  553. 

Nominating  Committee,  appointed, 
563. 

Non-Newtonian  Mechanics,  The  Prin- 
ciple of  Relativity  and,  554. 

Officers,  elected,  ;  573  List  of,  577. 

Ordway,  J.  M.,  Death  of,  554. 

Oscillations  of  a  Swinging  Body,  The 
Effect  of  the  Damping  due  to  the 
Surrounding  Medium  upon  the 
Form  of  the,  575. 

Oscillator,  Experiments  on  the  Elec- 
trical Oscillations  of  a  Hertz 
Rectilinear,  323,  558. 

Parker,  C.  P.,  elected  Resident  Fel- 
low, 563;  accepts  Resident  Fel- 
lowship, 565. 

Pavlov,  A.,  Letter  from,  553. 

Pearse,  A.  S.,  The  Reactions  of  Am- 
phibians to  Light,  159,  559. 

Peirce,  B.  O.,  The  (Conception  of  the 
Derivative  of  a  Scalar  Point  Func- 
tion with  Respect  to  Another  Simi- 
lar Function,  337,  558;  The  Effect 
of  Leakage  at  the  Edges  upon  the 
Temperatures  within  a  Homo- 
geneous Lamina  through  which 
Heat  is  being  Conducted,  353,  558; 
The  Effect  of  the  Damping  due  to 
the  Surrounding  Medium  upon 
the  Form  of  the  Oscillations  of  a 
S^finging  Body,  575;  The  Effects 
of  Sudden  Changes  in  the  induc- 
tances of  Certain  Forms  of  Electric 
Circuits  and  their  Mechanical 
Analogies,  575;  The  Forms  of  the 
Magnetic  Diagrams  for  Low  Fields 
of  Certain  very  Pure  Kinds  of  Soft 
Iron  which  at  very  High  Excita- 
tions show  extraordinarily  Large 
Values  of  I . ,  575 ;  On  the  Magnitude 
of  an  Error  which  usually  affects 
the  Results  of  Magnetic  Tests  upon 


Iron  and  Steel  Rings,  575;  The 
Resistance  of  the  Air  to  a  Swing- 
ing Magnet,  558;  Some  Illustra- 
tions of  the  Effects  of  Sudden 
Changes  in  the  Resistances  of  In- 
ductive Circuits,  575. 

Ilepi  *i;(rc«f .  A  Study  of  the  Concep- 
tion of  Nature  among  the  Pre- 
Socratics,  77,  554. 

Phanerogams,  Mexican  —  Notes  and 
New  Species,  422,  560. 

Phosphorus,  A  Revision  of  the  Atomic 
Weight  of,  135,  554. 

Pierce,  G.  W.,  Experiments  on  the 
Electrical  Oscillations  of  a  Hertz 
Rectilinear  Oscillator,  323,  558; 
Report  of  the  Publication  Com- 
mittee, 571. 

Policy  Committee,  560. 

Pre-Socratics,  A  Study  of  the  Concep- 
tion of  Nature  among  the,  77,  554. 

Publication,  Appropriation  for,  573. 

Publication  Committee,  Report  of, 
571. 

Publication  Fund,  568;  Appropria- 
tion from,  573. 

Pjrrosulphuryl  Chloride  and  Chlor- 
sulphonic  Acid,  The  Preparation 
and  Properties  of,  554. 

Records  of  Meetings,  553. 

Relativity  and  Non-Newtonian  Me- 
chanics,  The  Principle  of,  554. 

*Riegel,  E.  R.  See  Sanger,  C.  R.,  and 
Riegel,  E.  R. 

Riegel,  E.  R.  See  Sanger,  C.  R., 
Riegel,  E.  R.,  and  Whitney,  L.  H. 

Ritchie,  John,  resigns  Resident  Fel- 
lowship, 565. 

Robinson,  B.  L.,  Spermatophytes, 
new  or  reclassified,  chiefly  Rubia- 
ceae  and  Gentianaceae,  394,  560. 

Rocks,  Igneous,  Average  Chemical 
Compositions  of,  209, 558. 

Rogers  Laboratory  of  Physics,  Con- 
tributions from,  429. 

Ropes,  J.  H.,  accepts  Resident  Fel- 
lowship, 553. 

Rotch,  A.  L.,  Report  of  Librarian, 
568;  Delegate  to  Boston  ^*  1915" 
Conference,  561. 


Digitized  by  LjOOQIC 


608 


INDEX. 


Rubiaceae  and  Gentianaceae,   Sper- 

matophytes,   new  or  reclassified, 

chiefly,  394,  660. 
Rumford  Committee,  Report  of,  569, 

Reports  of  Progress  to,  570. 
Rumford  Fund,  567;   Appropriations 

from  the  Income,  559,  563,  573; 

Papers  published  by  Aid  of,  570. 
Rumford  Premium,  602;    Award  of, 

573;  Presentation  of,  565. 

Samaria,  Harvard  Explorations  in,  560. 

Sanger,  C.  R.,  and  Riegel,  E.  R.,  The 
Quantitative  Determination  of  An- 
timony by  the  Gutzeit  Method, 
19,  554. 

Sanger,  C.  R.,  Riegel,  E.  R.,  and  Whit- 
ney, L.  H.,  The  Preparation  and 
Properties  of  Pyrosulphuryl  Chlo- 
ride and  Chlorsulphonic  Acid,  554. 

Saturn  and  Mars,  Photographs  of,  561. 

Scalar  Point  Function,  The  Concep- 
tion of  the  Derivative  of  a,  with 
Respect  to  another  Similar  Func- 
tion, 337,  558. 

Sellers,  W.,  Death  of,  562. 

Silver  Phosphate,  The  Analysis  of, 
135,  554. 

Slipher,  V.  M.,  accepts  Associate  Fel- 
owship,  565. 

Spermatophytes,  new  or  reclassified, 
chiefly  Rubiaceae  and  Gentian- 
aceae,  394,  560. 

Sphere,  Solid,  On  Evaporation  from' 
the  Surface  of  a,  361,  561. 

Spillman,  W.  J.,  Letter  from,  553. 

Standing  Conmiittees,  appointed,  574; 
List  of,  577. 

Standing  Votes,  601. 

Statutes,  591 ;  Committee  on  Amend- 
ment of,  564. 

Steam,  Notes  on  Certain  Thermal 
Properties  of,  265,  558. 

Sunmer,  W.  G.,  Death  of,  565. 

Taft,  President,  Letter  from,  561. 

Thompson,  M.  De  K.,  LIII.  — On 
the  Equilibrium  of  the  System 
consisting  of  Lime,  Carbon,  Cal- 
cium Carbide  and  Carbon  Monox- 
ide, 429,  56L 


Tohnan,  R.  C.  See  Lewis,  G.  N.,  and 
Tohnan,  R.  C. 

Treasurer,  Report  of,  566. 

Trowbridge,  John,  Discharges  of  Elec- 
tricity through  Hydrogen,  453, 558; 
The  Future  of  Aeroplanes,  554. 

Universal  Race  Congress,  561. 

Vaggas  I.-IV.,  An  Analysis  of,  465, 

558. 
Volterra,  V.,  Letter  from,  562. 

Ware,  W.  R.,  Report  of  House  Com- 
mittee, 571. 

Warren  (C.  M.)  Conunittee,  Report 
of,  570. 

Warren  (C.  M.)  Fund,  567;  Appro- 
priations from  the  Income  of,  573. 

Water  and  Carbon  Dioxide,  On  the 
Applicability  of  the  Law  of  Cor- 
responding States  to  the  Joule- 
Thomson  Effect  in,  241,  558. 

Wave-Lengths,  The  Spectrum  of  a 
Carbon  Compound  in  the  Region 
of  Extremely  Short,  313,  558. 

Weatherby,  C.  A.,  American  Forms 
of  Lycopodium  comp'anatum,  412, 
560;  Mexican  Phanerogams  — 
Notes  and  new  Species,  422,  560; 
A  Preliminary  Synopsis  of  the 
Genus  Echeandia,  387,  560. 

Whitney,  L.  H.  See  Sanger,  C.  R., 
Riegel,  E.  R.,  and  Whitney,  L.  H. 

Wine  and  the  Good,  Some  New  Fac- 
tors in  Determining  the  Location 
of,  564. 

Wood,  R.  W.,  Presented  Rumford 
Medals,  565;  Photography  with 
Invisible  Bays,  565. 

World's  Congress  of  International 
Associations,  565. 

Yellowstone  National  Park,  Photo- 
graphs of,  558. 

Zavodny,  J.,  Letter  from,  553. 

Zodlogical  Laboratory  of  the  Museum 
of  Comparative  Zoology,  Contribu- 
tions from,  159. 


Digitized  by  VjOOQIC 


Digitized  by  VjOOQIC 


Digitized  by  LjOOQIC 


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8.  BamoMAH,  P.  W.  — The  Measurement  of  High  Hydrostatic  Pressure.    (I.)  A  Simple  Primary 

Gauge,    pp.  199-217.    February,  1909.    30c. 

9.  BaxoaMAii,  P.  W.  —  The  Measurement  of  High  Hydrostatic  Pressure.    (II.)  A  Secondary  Mer- 

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February,  1909.    40c. 

11.  Pbib€B,  B.  O.— Tlie  Theory  of  Ballistic  Galvanometers  of  Long  Period,    pp.  281-314.    1  pi. 

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12.  PiBBCB,  Q.  W.  —Crystal  Rectifiers  for  Electric  Currents  and  Electric  Oscillations.    (II.)  Car- 

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13.  PsxBcs,  B.  O.  —  On  the  Magnetic  Behavior  of  Hardened  Cast  Iron  and  of  Certain  Tool  Steels 

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17.  Palachb,  0 .,  and  La  Fobob,  L.  —  Notes  on  the  Crystallography  of  Leadhillite.     (I.)  LeadhilUte 

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18.  SHunDBMAOBir,  C.  L.  B.  —  Residual  Charges  in  Dielectrics,     pp.  4€<}-521.     May,  1909.    95c. 

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20.  Lbach,  H.  G.  —The  Relations  of  the  Norwegian  with  the  English  Churcli,  lOOG  1399,  and  their 

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